Phenyl Benzoate Derivative Patents (Class 252/299.67)
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Patent number: 8617420Abstract: The invention provides an optically isotropic liquid crystal composition having: a liquid crystal component comprising a liquid crystal component A consisting of one or more compounds selected from the group consisting of compounds having difluoroalkenyl and compounds having alkenyl; and chiral dopants, wherein in the liquid crystal component, the content of compounds having 3 or more ring structures is approximately 15 wt % or more.Type: GrantFiled: August 27, 2008Date of Patent: December 31, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Shin-ichi Yamamoto, Yasuhiro Haseba
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Publication number: 20130342775Abstract: The present invention relates to a high scattering smectic liquid crystal material and display device using the same. In the present invention, a series of smectic A phase liquid crystals having compact arrangement of crystal domains or a series of smectic liquid crystal mixed materials having a degree of order higher than that of the smectic A phase and an optical texture different from that of the smectic A phase are obtained by mixing a smectic liquid crystal with an organic compound having a high optical anisotropy (?n) or mixing different types of smectic phases. When used in a smectic stable state liquid crystal display pattern, these materials have high scattering properties and can effectively improve the contrast of a smectic liquid crystal display device. The present invention also improves contrast when it used in a reflective smectic liquid crystal display device.Type: ApplicationFiled: December 30, 2011Publication date: December 26, 2013Inventors: Gang Sun, Wenlei Li, Huan Yin
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Publication number: 20130341566Abstract: An embodiment provides a polymer-stabilized optical isotropic liquid crystal formulation, including 50 to 99.5 parts by weight of an optical isotropic liquid crystal material; and 0.5 to 50 parts by weight of polymer, wherein the polymer is polymerized by an acrylic monomer containing fluorine groups and an acrylic monomer with a liquid crystal phase and/or an acrylic monomer without a liquid crystal phase.Type: ApplicationFiled: May 9, 2013Publication date: December 26, 2013Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventor: Pao-Ju HSIEH
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Patent number: 8613985Abstract: According to one embodiment, a liquid crystal/polymer complex includes a liquid crystal material, a polymer, and a chiral agent. The liquid crystal material exhibits blue phase and contains liquid crystal molecules that are spirally arranged to form liquid crystal molecular cylinders having a spiral arrangement. The polymer maintains the arrangement and has a dendrimer-type structure including a dendrimer unit and a polymerizable unit bonded to an end of the dendrimer unit. The dendrimer unit contains a central atom and at least two branched structures bonded to the central atom and has a generation of two or more. The polymerizable unit contains a polymerizable group which can bond to a polymerizable group.Type: GrantFiled: July 25, 2012Date of Patent: December 24, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Yukio Kizaki, Hajime Yamaguchi, Yuko Kizu, Masao Tanaka, Akiko Hirao
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Patent number: 8603594Abstract: Provided is a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, high stability to ultraviolet light and high stability to heat, or having a suitable balance regarding at least two of the characteristics. Provided is an AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life, etc. The liquid crystal composition having a nematic phase includes a specific three-ring or four-ring compound having a high maximum temperature and a large dielectric anisotropy as a first component, and a specific compound having a small viscosity or a high maximum temperature of the nematic phase as a second component, and a liquid crystal display device contains the composition.Type: GrantFiled: January 21, 2010Date of Patent: December 10, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Makoto Hamano, Norikatsu Hattori
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Patent number: 8603356Abstract: Provided are a wholly aromatic liquid crystalline polyester resin compound and a method of preparing the same. The wholly aromatic liquid crystalline polyester resin compound comprises a first wholly aromatic liquid crystalline polyester resin with a low melting point, a second wholly aromatic liquid crystalline polyester resin with a high melting point, and an additive, wherein the amount of the first wholly aromatic liquid crystalline polyester resin is 5 to 10 parts by weight with respect to 100 parts by weight of the second wholly aromatic liquid crystalline polyester resin.Type: GrantFiled: April 2, 2010Date of Patent: December 10, 2013Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Sang Hyuk Suh, Youn Eung Lee, Young Hak Shin, Jin Kyu Lee, Mahn Jong Kim
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Patent number: 8603595Abstract: A novel liquid crystalline compound and/or a liquid crystal composition including the novel liquid crystalline compound that can be used for a variety of liquid crystal devices capable of exhibiting a blue phase with a wide temperature range are/is provided. A liquid crystalline compound represented by the general formula (G1) is provided.Type: GrantFiled: January 26, 2012Date of Patent: December 10, 2013Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Sachiko Kawakami, Yuko Kawata, Momoko Kato, Tetsuji Ishitani, Tomohiro Tamura
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Patent number: 8592007Abstract: The present invention relates to polymerizable compounds, to processes and intermediates for the preparation thereof, and to the use thereof for optical, electro-optical and electronic purposes, in particular in liquid-crystal (LC) media and LC displays, especially in LC displays of the PS (polymer stabilized) or PSA (polymer sustained alignment) type.Type: GrantFiled: September 29, 2009Date of Patent: November 26, 2013Assignee: Merck Patent GmbHInventors: Achim Goetz, Erdal Durmaz, Malgorzata Rillich, Andreas Taugerbeck
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Patent number: 8592008Abstract: To provide a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature thereof, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a large elastic constant, a high stability to ultraviolet light and heat, or a liquid crystal composition having a suitable balance regarding at least two of the characteristics; and an AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth; wherein a liquid crystal composition has a nematic phase and contains a specific compound having a high maximum temperature and a large dielectric anisotropy as a first component, and a specific compound having a small viscosity as a second component, and may contain a specific compound having a large dielectric anisotropy as a third component.Type: GrantFiled: June 11, 2012Date of Patent: November 26, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Taketo Maeda, Takayoshi Yanai, Hiroyuki Tanaka, Norikatsu Hattori
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Patent number: 8592006Abstract: A polymerizable monomer adopted to a display panel is represented as following chemical formula: wherein, m?0; “Z” is selected from oxygen, sulfur, carbonyl, caroboxyl, methyoxy, methylthio, thio, ethenylcarbonyl, carbonylethenyl, difluoromethoxy, difluoro methylthio, ethyl, difluoroethane, 1,2 difluoroethane, vinylene, difluoroethenylene, ethynyl, or single bond. “X1” and “X2” are independently selected from oxygen, sulfur, methyoxy, carbonyl, caroboxyl, -carbamoyl, methylthio, ethenylcarbonyl, carbonylethenyl, or single bond. “Sp1” and “Sp2” are independently a spacer or single bond. “P1” and “P2” are independently a polymerizable group.Type: GrantFiled: May 25, 2010Date of Patent: November 26, 2013Assignee: AU Optronics Corp.Inventors: Chung-Ching Hsieh, Yang-Chu Lin, Hsi-Chien Lin, Te-Sheng Chen
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Patent number: 8586152Abstract: A liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a large optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light, a high stability to heat and a short helical pitch is provided, wherein the liquid crystal composition has a negative dielectric anisotropy and contains a specific optically active compound as a first compound, a specific compound having a large negative dielectric anisotropy as a second component, and may contain a specific compound having a high maximum temperature or a small viscosity as a third component, a specific compound having a large negative dielectric anisotropy as a fourth component and a specific optically active compound as a fifth component, and a liquid crystal display device that contains the composition.Type: GrantFiled: September 1, 2010Date of Patent: November 19, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshimasa Furusato, Takashi Hiraoka, Masayuki Saito
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Patent number: 8586153Abstract: A liquid crystal compound and a liquid crystal medium are described. The liquid crystal compound is stable to heat and light and has a large dielectric anisotropy and a large optical anisotropy. The liquid crystal medium has a wide temperature range of liquid crystal phase, a large optical anisotropy and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase. The liquid crystal compound has 4 or 5 benzene rings, one of which is a chlorofluorobenzene ring. The liquid crystal medium is characterized in containing the liquid crystal compound and a chiral dopant and exhibiting an optically isotropic liquid crystal phase.Type: GrantFiled: November 30, 2012Date of Patent: November 19, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Yasuhiro Haseba
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Patent number: 8580143Abstract: The present invention relates to a lyotropic chromonic liquid crystal composition, a method for manufacturing a lyotropic chromonic liquid crystal coating film and a lyotropic chromonic liquid crystal coating film manufactured thereby. The lyotropic chromonic liquid crystal composition of the present invention includes chromonic liquid crystal compounds and monomers each having opposing acid-base properties. Use of the lyotropic chromonic liquid crystal composition in the formation of optical films leads to improvements in electrical and optical properties such as mechanical strength, an insulating characteristic and a refractive index.Type: GrantFiled: November 5, 2009Date of Patent: November 12, 2013Assignees: Korea Institute of Industrial Technology, Industrial Cooperation Foundation Chonbuk National UniversityInventors: Seung Han Shin, Eu Gene Chang, Myong Hoon Lee, Kwang Un Jeong, Yun Ju Bae
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Patent number: 8574688Abstract: The present invention relates to a blue phase liquid crystal composition and to a method of stabilizing a blue phase state of a liquid crystal material. Moreover, the present invention also relates to a method of lowering the operating voltage of a liquid crystal material. Furthermore, the present invention relates to a blue phase liquid crystal material stabilized by the method according to the present invention or having an operating voltage that is lowered by the method according to the present invention. Furthermore, the present invention relates to a liquid crystal cell comprising a blue phase liquid crystal material and to a liquid crystal display comprising a blue phase liquid crystal material. The present invention also relates to a method of broadening the stability temperature range of a liquid crystal material in its blue phase state.Type: GrantFiled: March 22, 2011Date of Patent: November 5, 2013Assignee: Sony CorporationInventors: Pinar Kilickiran, David Danner, Zakir Hussain, Nadine Hollfelder, Gabriele Nelles
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Patent number: 8568614Abstract: The present invention relates to a blue phase (BP) liquid crystal composition that shows reduced hysteresis behavior, and to a method of reducing and/or eliminating the hysteresis behavior of a BP liquid crystal composition. Moreover, the present invention relates to a blue phase liquid crystal composition, wherein the hysteresis has been reduced or eliminated. Furthermore, the present invention relates to a liquid crystal cell comprising a blue phase liquid crystal composition, and to a liquid crystal display comprising a blue phase liquid crystal composition.Type: GrantFiled: March 5, 2012Date of Patent: October 29, 2013Assignee: Sony CorporationInventors: Pinar Kilickiran, Gabriele Nelles
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Patent number: 8562863Abstract: A glassy cholesteric liquid crystalline composition comprising compounds with a volume-expanding core bound to one or more hybrid chiral-nematic (or Ch) pendant moieties and a method of producing oriented films of such compounds. The Ch pendant moieties are comprised of chiral spacer groups connected to the core via linker groups and nematic groups linked to the chiral spacer groups. Thin-films of the composition are morphologically stable for extended periods of time. Also, the thin-films are able to selectively interact with light from the visible to near-IR wavelength range.Type: GrantFiled: September 11, 2009Date of Patent: October 22, 2013Assignee: The University of RochesterInventors: Shaw H. Chen, Chunki Kim
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Patent number: 8545717Abstract: The present invention relates to a composition comprising a curable dichroic dye and a curable liquid crystal compound, which are used to prepare an optical component that is vertically oriented to give a narrow viewing angle, to form an optical component, and an optical component comprising an optical component layer prepared using the same. There is provided a composition for forming an optical component comprising 0.1-90 parts by weight of a dichroic dye and 10-98.85 parts by weight of a curable liquid crystal compound, and there is also provided an optical component comprising an optical component layer in which a curable liquid crystal compound and a curable dichroic dye are vertically oriented.Type: GrantFiled: July 4, 2008Date of Patent: October 1, 2013Assignee: LG Chem, Ltd.Inventors: Yong Il Cho, Dae Hee Lee, Sin Young Kim, Hee Jean Lee, Su Young Ryu
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Patent number: 8535769Abstract: Since a polymerizable liquid crystal compound represented by the general formula (1) produces polymers exhibiting high optical anisotropy and high chemical resistance, and the optical anisotropy thereof exhibits low wavelength dependence, polymers obtained from a polymerizable liquid crystal composition comprising said polymerizable liquid crystal compound are useable as an optically anisotropic film for polarizers, wave plates, and the like, and are particularly best used in pattern formation that uses photolithography in air. (n represents an integer in the range of 3 to 10, m represents an integer in the range of 0 to 5, and q represents an integer in the range of 1 to 2.Type: GrantFiled: September 16, 2010Date of Patent: September 17, 2013Assignee: Nissan Chemical Industries, Ltd.Inventor: Daniel Antonio Sahade
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Patent number: 8535768Abstract: Described is a liquid crystal composition which satisfies at least one of such characteristics as high upper limit temperature of the nematic phase, low lower limit temperature of the nematic phase, low viscosity, adequate optical anisotropy, large negative dielectric anisotropy, high resistivity, high stability to ultraviolet light and high stability to heat, or which has an adequate balance between at least two of the above-mentioned characteristics. Also described is an AM element having a short response time, high voltage holding ratio, high contrast ratio, long life and the like. The liquid crystal composition contains a specific compound having a large negative dielectric anisotropy and a low lower limit temperature as a first component, a specific compound having a low viscosity or a high upper limit temperature as a second component, and a specific compound having a polymerizable group as a third component. The AM element contains the composition.Type: GrantFiled: January 15, 2010Date of Patent: September 17, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Masayuki Saito
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Patent number: 8518299Abstract: A dichroic guest-host polarizer comprises an oriented polymerized liquid crystal host and aligned therewith a dichroic guest. The dichroic ratio of the polarizer is about 15 or more. The polarizer may have a small thickness, be manufactured using a wet deposition method, optionally in accordance with a desired pattern, and be provided on the inside of a liquid crystal cell. Polymerizable liquid crystals having a highly ordered mesophase which may be suitable used to obtain highly oriented polymer films such as polarizer films are disclosed.Type: GrantFiled: July 2, 2010Date of Patent: August 27, 2013Assignee: Sumitomo Chemical Co., Ltd.Inventors: Johan Lub, Emiel Peeters, Dirk Jan Broer
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Patent number: 8512824Abstract: A composition includes at least one organic compound of a first type of the general formula I and at least one organic compound of a second type of the general structural formula II, wherein Core in formula I is a conjugated organic unit capable of forming a rigid rod-like macromolecule, Gk is a set of ionogenic side-groups providing solubility of the organic compound of the first type in a solvent and give rigidity to the rod-like macromolecule; and wherein Sys in formula II is an at least partially conjugated substantially planar polycyclic molecular system capable of forming board-like supramolecules via ?-?-interaction, and X, Y, Z and Q are substituents. The composition is capable of forming a lyotropic liquid crystal solution, which can form a solid retardation layer of biaxial type substantially transparent to electromagnetic radiation in the visible spectral range.Type: GrantFiled: August 14, 2009Date of Patent: August 20, 2013Assignee: Crysoptix KKInventors: Irina Kasianova, Ellina Kharatiyan
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Patent number: 8501286Abstract: The present invention discloses a reactive monomer of liquid crystal. The reactive monomer of liquid crystal is added with at least one fluoro group. Because hydrocarbon bonds of a side chain of polyimide surface of an alignment film has a fluorophobic effect, the fluoro group of the reactive monomer of liquid crystal can lower the interaction between the polyimide surface of the alignment film and the reactive monomer of liquid crystal to thus evenly deposit the liquid crystal composition containing the reactive monomers of liquid crystal onto the polyimide surface of the alignment film. Thus, it can avoid from occurring the phenomenon of drop Mura defect occurred during implementing the ODF technology.Type: GrantFiled: August 11, 2011Date of Patent: August 6, 2013Assignee: Shenzhen China Star Optoelectronics Technology Co., Ltd.Inventors: Chung-Ching Hsieh, Chengming He
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Patent number: 8501285Abstract: A liquid crystal medium, which has a liquid crystal phase over a wide temperature range, a large refractive index anisotropy, and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase, is provided. The liquid crystal medium is characterized by containing a liquid crystal compound having four benzene rings and a difluoromethyleneoxy group, and a chiral reagent, and exhibiting an optically isotropic liquid crystal phase.Type: GrantFiled: October 27, 2009Date of Patent: August 6, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yasuhiro Haseba, Takafumi Kuninobu
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Patent number: 8486497Abstract: An embodiment of the invention provides a liquid crystal compound having the following formula: wherein A1, A2, and A3 are independently hydrogen, halogen, cyano, thiocyanato, or —OCF3; R1 is hydrogen, halogen, C1-C12 alkyl, C1-C12 alkoxy, C1-C12 haloalkyl, C2-C12 alkenyl, or C2-C12 alkynyl; R2 is hydrogen, halogen, C1-C6 alkyl, C1-C6 haloalkyl, cyano, or —OCF3; and Z is —O—, —CH2O—, —C(O)O—, —OCO—, —C(O)NH—, —CH?CH—, or —C?C—. In another embodiment, a liquid crystal display including the liquid crystal compound is also provided.Type: GrantFiled: December 29, 2011Date of Patent: July 16, 2013Assignee: Industrial Technology Research InstituteInventors: Jian-Wen Lin, Chun-Ming Wei, Shih-Hsien Liu, Kung-Lung Cheng, Chih-Lung Chin
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Patent number: 8481129Abstract: A liquid crystal compound of Formula (I) is provided. In Formula (I), A is benzene, naphthalene, pyridine, furan, thiophene or a single bond, D is benzene, naphthalene, pyridine, furan, thiophene or a single bond, R1 and R2 are C1-10 alkyl, C1-10 alkoxy, fluoro or trifluoro methyl, E is benzene, naphthalene, pyridine, furan, thiophene or a single bond, W is —CO—O—, —O—CO—, —O—, —CH2—CH2—, —CH?CH—, —CH2—O— or a single bond, Z is benzene, naphthalene, pyridine, furan, thiophene or a single bond, Y is hydrogen, methyl, ethyl or propyl, m is 0, 1 or 2, p is 0, 1 or 2, r is 0, 1 or 2, q is 0, 1 or 2, and n is 0, 1, 2 or 3. The invention also provides a liquid crystal display and photochromic material including the compound.Type: GrantFiled: December 29, 2011Date of Patent: July 9, 2013Assignee: Industrial Technology Research InstituteInventors: Yi-Rong Wang, Chih-Lung Chin, Wan-Chi Chen, Kung-Lung Cheng, Shih-Hsien Liu
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Patent number: 8475888Abstract: Provided is a liquid crystal compound having general physical properties necessary for a compound, stability to heat, light or the like, a wide liquid crystal phase temperature range, a high clearing point, an excellent compatibility with other liquid crystal compounds, a large refractive index anisotropy and a large dielectric anisotropy. Provided are a liquid crystal composition including the liquid crystal compound, and a liquid crystal display device containing the liquid crystal composition. The compound is represented by formula (1): wherein, for example, R1 is alkyl having 1 to 20 carbons; at least one of the rings A1 to A6 is pyrimidine-2,5-diyl or pyridine-2,5-diyl and the others are 1,4-cyclohexylene or 1,4-phenylene; Z1 to Z6 are a single bond; L1 to L4 is hydrogen or halogen; X1 is hydrogen, halogen, —C?N or alkyl having 1 to 10 carbons; and l, m, n, o, p and q are 0 or 1 and l+m+n+o+p+q=3.Type: GrantFiled: October 14, 2009Date of Patent: July 2, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Hiroyuki Tanaka, Kouki Sagou
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Patent number: 8475887Abstract: A liquid crystal medium having a wide temperature range of a liquid crystal phase, a large optical anisotropy, and a large dielectric anisotropy and having an optically isotropic liquid crystal phase is provided. The liquid crystal medium is characterized by containing a liquid crystal compound having a pyrimidine ring and a linking group —CF2O— and a chiral dopant, and exhibiting an optically isotropic liquid crystal phase.Type: GrantFiled: May 8, 2009Date of Patent: July 2, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yasuhiro Haseba, Kohki Sago, Takafumi Kuninobu
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Publication number: 20130155338Abstract: The present invention relates to a switch element, which is thermoresponsive and which switches between a less transmissive state for radiant energy and a more transmissive state for radiant energy, and which comprises a liquid-crystalline medium. The invention furthermore relates to the use of the switch element for the regulation of radiant energy flow between interior spaces and the environment and for the regulation of the temperature of interior spaces. The invention furthermore relates to a liquid-crystalline medium, characterised in that it comprises 5-95% of a compound of the formula (I), in particular for use in the switch elements according to the invention.Type: ApplicationFiled: July 27, 2011Publication date: June 20, 2013Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventor: Michael Junge
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Patent number: 8465671Abstract: There is provided a novel dichroic dye having liquid crystal properties, dichroic properties and polymerizable reactivity, the dichroic dye being used to form a color filter layer having excellent physical properties such as dichroic ratio, heat resistance, durability, high contrast ratio and polarizing properties, a composition comprising the same for color filter, a color filter array plate (an upper plate) prepared therefrom, and a liquid crystal display comprising the color filter array plate. The dichroic dye has a structure of R1-L1-M-L2-D (wherein, D is a dichroic structure, M is a structure with liquid crystal properties, R1 is a reactive end functional group, and L and L1 are linking structures that link R1, M, and D), and the composition for forming a color filter layer includes the dichroic dye.Type: GrantFiled: November 23, 2007Date of Patent: June 18, 2013Assignee: LG Chem, Ltd.Inventors: Yong-Il Cho, Sin-Young Kim
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Patent number: 8465674Abstract: A compound represented by the formula (1) is provided. In the formula (1), for example, R1 and R2 are alkyl having 1 to 10 carbons, alkoxy having 1 to 9 carbons or alkenyl having 2 to 10 carbons; the ring A and the ring B are 1,4-cyclohexylene or 1,4-phenylene; Z1 and Z2 are a single bond and Z3 is —CH2O— or —OCH2—; Y1 and Y2 are halogen, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2 or —OCH2F; and m and n is 0, 1 or 2, p is 1 or 2, and the sum of m, n and p is 1, 2 or 3.Type: GrantFiled: August 9, 2010Date of Patent: June 18, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Tokifumi Masukawa
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Patent number: 8460577Abstract: The invention provides a compound represented by formula (1). In the formula (1), R1 is hydrogen, methyl or ethyl; X1 is a single bond, —O— or —OCO—; X2 is a single bond, —O—, —COO— or —OCO—; A1 and A2 are each independently a divalent aromatic ring or a divalent cyclohexane ring, and in these rings, arbitrary hydrogen may be replaced by halogen, alkyl having 1 to 3 carbons or halogenated alkyl having 1 to 3 carbons; Z1 is independently a single bond, —O—, —S—, —COO—, —OCO—, —CH2O—, —OCH2—, —CH?CH—COO—, —OCO—CH?CH—, —CH2CH2—COO—, —OCO—CH2CH2—, —CON(R)— or —N(R)CO—; R is hydrogen or methyl; Y is a terpenoid residue or a steroid residue; m is an integer from 0 to 20; and n is an integer from 0 to 3.Type: GrantFiled: November 16, 2010Date of Patent: June 11, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Mayumi Tanabe, Yoshiharu Hirai
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Patent number: 8460766Abstract: A liquid crystal compound of Formula (1) is provided below: wherein R is hydrogen, linear or branching C1-15 alkyl, linear or branching C1-15 alkyl (wherein any one of —CH2— is replaced by —O—, —S—, —CO—, —CO—O—, or —O—CO—), linear or branching C2-15 alkenyl, or linear or branching C2-15 alkenyl (wherein any one of —CH2— is replaced by —O—, —S—, —CO—, —CO—O—, or —O—CO—), A and B are, independently, cyclohexane, cyclohexane (wherein any one of —CH2— is replaced by —O— or —NH—), benzene, or benzene (wherein any one of —CH2? is replaced by —N?), X is a single bond, —CO—O—, —O—CO—, —CH2O—, —OCH2—, —CH2CH2—, —C?C—, —C?C—, —CF2O—, or —OCF2—, Q is oxygen or CH2, Y is CF3, CF2H, or CFH2, L1, L2, and L3 are, independently, hydrogen or fluorine, and m is 0, 1, or 2.Type: GrantFiled: June 10, 2011Date of Patent: June 11, 2013Assignee: Industrial Technology Research InstituteInventors: Pei-Chen Huang, Kuo-Chang Wang, Kuo-Liang Yeh, An-Cheng Chen, Kung-Lung Cheng, Shyue-Ming Jang
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Patent number: 8454858Abstract: The invention relates to a liquid-crystalline medium based on a mixture of polar compounds having negative dielectric anisotropy, which contains at least one compound of the formula I and at least one compound of the formula II in which R1, R2, R3, R4, ring A, Z1, Z2 and m are as defined in Claim 1, and to the use thereof for an active-matrix display based on the ECB, VA, PS-VA, FFS, PALC or IPS effect.Type: GrantFiled: May 21, 2008Date of Patent: June 4, 2013Assignee: Merck Patent GmbHInventors: Norihiko Tanaka, Makoto Murakami, Shinji Nakajima
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Publication number: 20130126782Abstract: A liquid crystal composition exhibiting a blue phase, which enables higher contrast, and a liquid crystal display device including the liquid crystal composition. The liquid crystal composition contains a chiral agent and liquid crystal containing a compound having three electron-withdrawing groups as end groups of a structure where a plurality of rings including at least one aromatic ring is linked to each other directly or with a linking group laid therebetween. At least one of the three electron-withdrawing groups includes a trifluoromethyl group. The peak of the diffracted wavelength on the longest wavelength side in the reflectance spectrum of the liquid crystal composition is less than or equal to 450 nm, preferably less than or equal to 420 nm. Furthermore, a liquid crystal display device can be provided with the use of the liquid crystal composition.Type: ApplicationFiled: November 15, 2012Publication date: May 23, 2013Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.Inventor: SEMICONDUCTOR ENERGY LABORATORY CO.
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Patent number: 8440271Abstract: Providing a liquid crystal composition satisfies at least one of characteristics like a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat or has a suitable balance regarding at least two of the characteristics. Providing an AM device has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The liquid crystal composition has a negative dielectric anisotropy and contains a specific compound having large negative dielectric anisotropy as a first component, a specific three-ring compound having large optical anisotropy as a second component and a specific two-ring compound having low viscosity as a third component, and a liquid crystal display device contains the composition.Type: GrantFiled: August 16, 2010Date of Patent: May 14, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Masayuki Saito
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Patent number: 8435423Abstract: The subject is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light, a high stability to heat and a large elastic constant, or that is suitably balanced regarding at least two of the characteristics. The subject is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth.Type: GrantFiled: November 30, 2010Date of Patent: May 7, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Hiroaki Fujita
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Patent number: 8435333Abstract: Switchable gas permeation membranes in which a photo-switchable low-molecular-weight liquid crystalline (LC) material acts as the active element, and a method of making such membranes. Different LC eutectic mixtures were doped with mesogenic azo dyes and infused into track-etched porous membranes with regular cylindrical pores. Photo-induced isothermal phase changes in the imbibed mesogenic material afforded large, reversible changes in the permeability of the photo-switchable membrane to nitrogen. For example, membranes imbibed with a photo-switchable cyanobiphenyl LC material demonstrated low permeability in the nematic state, while the photo-generated isotropic state demonstrated a 16×-greater sorption coefficient. Both states obey a high linear sorption behavior in accordance with Henry's Law. In contrast, membranes imbibed with a photo-switchable phenyl benzoate LC material showed the opposite permeability behavior to the biphenyl-imbibed membrane, along with nonlinear sorption behavior.Type: GrantFiled: August 1, 2011Date of Patent: May 7, 2013Assignee: University of RochesterInventors: Kenneth L. Marshall, Eric Glowacki
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Patent number: 8425988Abstract: The main aim of the invention is to provide a polymerizable compound that is excellent in the stability of a liquid crystal phase, a polymerizable liquid crystal composition, and an anisotropic polymer in which the optical anisotropy can be adjusted and a uniform orientation is excellent. An anisotropic polymer having a uniform orientation formed by polymerization of a paint film that was prepared by application of a polymerizable liquid crystal composition including a compound represented by formula (1) having a benzyl ester moiety in the minor axis direction of the molecule to a supporting substrate; wherein at least one of Ra is a polymerizable group, A is a divalent cyclic-structure group, B is phenyl that may have a substituent, Y and Z are a single bond or alkylene, and m and n are an integer from 0 to 5.Type: GrantFiled: December 21, 2010Date of Patent: April 23, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshiharu Hirai, Takashi Kato
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Publication number: 20130087738Abstract: The present invention relates to an optical switch element, comprising a liquid-crystalline medium for the temperature-dependent regulation of radiant energy flow. The invention furthermore relates to the use of the optical switch element for the regulation of radiant energy flow between interior spaces and the environment and for the regulation of the temperature of interior spaces. The invention furthermore relates to a liquid-crystalline medium, characterised in that it comprises 5-95% of a compound of the formula (I), in particular for use in the optical switch elements according to the invention.Type: ApplicationFiled: May 4, 2011Publication date: April 11, 2013Applicant: MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNGInventor: Michael Junge
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Patent number: 8409673Abstract: A liquid crystal compound having a large refractive index anisotropy, a large dielectric anisotropy, and a low melting point, and a liquid crystal medium having a liquid crystal phase over a wide temperature range, a large refractive index anisotropy, a large dielectric anisotropy, and having an optically isotropic liquid crystal phase, are provided. The present invention is a liquid crystal compound having a chlorobenzene ring, and a liquid crystal medium characterized by containing the liquid crystal compound and a chiral reagent, and exhibiting an optically isotropic liquid crystal phase.Type: GrantFiled: May 7, 2010Date of Patent: April 2, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yasuhiro Haseba, Takafumi Kuninobu
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Patent number: 8405799Abstract: An object of the present invention is to obtain a polymer-stabilized liquid crystal composition which can suppress dependency of a driving voltage on a temperature by decreasing the driving voltage. To a low-molecular liquid crystal compound, a chiral compound, and a specific acrylate and a polymerizable liquid crystal compound as polymerizable acrylate compounds are added, to prepare a polymer-stabilized liquid crystal composition. By subjecting the polymer-stabilized liquid crystal composition to ultraviolet exposure while maintaining a desired alignment state to form a polymer chain in a liquid crystal phase, a polymer-stabilized liquid crystal display device containing a low-molecular liquid crystal in a stabilized alignment state is obtained.Type: GrantFiled: March 25, 2008Date of Patent: March 26, 2013Assignee: DIC CorporationInventors: Toru Fujisawa, Kiyofumi Takeuchi, Kazuaki Hatsusaka, Isa Nishiyama, Shunsuke Kobayashi
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Patent number: 8404317Abstract: The invention is to provide a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and heat, or a liquid crystal composition having a suitable balance regarding at least two of the characteristics; and an AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth; wherein a liquid crystal composition has a negative dielectric anisotropy and contains a specific compound having a large negative dielectric anisotropy as a first component and a specific two-ring compound having a large optical anisotropy and a low viscosity as a second component, and a liquid crystal display device contains the composition.Type: GrantFiled: December 23, 2011Date of Patent: March 26, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Masayuki Saito, Norikatsu Hattori
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Patent number: 8399073Abstract: The invention relates to a liquid-crystalline medium having negative dielectric anisotropy which comprises at least one compound of the formula I in which R1, R1* and a have the meanings indicated in Claim 1, and to the use thereof for an active-matrix display, in particular based on the VA, PS-VA, PALC, FFS or IPS effect.Type: GrantFiled: December 17, 2009Date of Patent: March 19, 2013Assignee: Merck Patent Gesellschaft mit Beschränkter HaftungInventors: Melanie Klasen-Memmer, Matthias Bremer, Konstantin Schneider, Detlef Pauluth
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Patent number: 8394468Abstract: Provided is a polymerizable compound with large solubility in a liquid crystal composition and high reactivity irradiated by ultraviolet in the longer wavelength range. Provided is a liquid crystal composition that satisfies at least one of characteristics such as high maximum temperature of a nematic phase, low minimum temperature of a nematic phase, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, large specific resistance, high stability to ultraviolet light and high stability to heat, or that is suitably balanced between at least two of the characteristics.Type: GrantFiled: May 7, 2010Date of Patent: March 12, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Maiko Ito, Keiji Kimura, Norikatsu Hattori, Eriko Saegusa
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Patent number: 8394467Abstract: The instant invention relates to dielectrically positive nematic media comprising one or more compounds of formula I and one or more compounds of formulae II and III and optionally one or more compounds of formulae IV and V and liquid crystal devices comprising these media and especially to fast switching electro-optical devices.Type: GrantFiled: March 25, 2011Date of Patent: March 12, 2013Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Yuko Arai, Takanori Takeda, Yasushi Sugiyama, Hideo Ichinose
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Patent number: 8389073Abstract: The invention provides a liquid crystal compound that has a large negative dielectric anisotropy (??) and also has at least one of characteristics such as the stability to heat, light or the like, a high clearing point, a suitable refractive index anisotropy (?n), a large negative dielectric anisotropy (??) and an excellent compatibility with other liquid crystal compounds. An excellent effect in which especially the value of the dielectric anisotropy (??) is increased negatively is achieved by use of the compound having two moieties of 1) a tetrahydropyran ring and and thus the effect is utilized.Type: GrantFiled: February 1, 2010Date of Patent: March 5, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Kenji Hirata, Tokifumi Masukawa, Junichi Yamashita, Maiko Ito
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Publication number: 20130048913Abstract: The invention is to provide a new liquid crystal compound having a high clearing point, a good compatibility with other compounds, a small viscosity, and a high stability to heat, light and so forth; compound (1) is provided: R1?CF2?nR2??(1) wherein, for example, R1 is alkyl having 4 to 10 carbons or —(CH2)2—CH?CH2, R2 is alkyl having 2 to 10 carbons, n is 8, and R1 and R2 are not allowed to be straight-chain alkyl having an identical number of carbons.Type: ApplicationFiled: August 23, 2012Publication date: February 28, 2013Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Hiroyuki TANAKA, Sayaka FUJIMORI
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Patent number: 8377520Abstract: The invention is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced between at least two of the characteristics; and is to provide a AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, wherein the liquid crystal composition includes a specific compound having a large negative dielectric anisotropy and a low minimum temperature as a first component and a specific compound having a large negative dielectric anisotropy, and the liquid crystal display device contains this composition.Type: GrantFiled: October 21, 2009Date of Patent: February 19, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Masayuki Saito
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Patent number: 8377519Abstract: The instant invention relates to liquid crystal media comprising one or more bimesogenic compounds, one or more chiral dopants and one or more additives, liquid crystal displays comprising these media, in particular displays exploiting the flexoelectric effect and to a method of improving the response time of such displays.Type: GrantFiled: May 16, 2007Date of Patent: February 19, 2013Assignee: Merck Patent GmbHInventors: Louise Diane Farrand, Harry James Coles, Mikhail N. Pivnenko, Yong-il Cho
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Patent number: 8367167Abstract: A liquid crystal composition that satisfies at least one characteristic, such as, high maximum temperature of a nematic phase, low minimum temperature of a nematic phase, small viscosity, suitable optical anisotropy, large dielectric anisotropy, large specific resistance, large elastic constant, high stability to ultraviolet light and high stability to heat, or that is suitably balanced between at least two of the characteristics; and provides an AM device that has short response time, large voltage holding ratio, large contrast ratio, long service life and so forth. A liquid crystal composition is provided that has a nematic phase and includes a specific three-ring compound having a large dielectric anisotropy as a first component, a specific four-ring compound having a high maximum temperature and a large dielectric anisotropy as a second component, and a liquid crystal display device containing the composition.Type: GrantFiled: December 7, 2011Date of Patent: February 5, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takayoshi Yanai, Norikatsu Hattori