Containing Nonsteryl Liquid Crystalline Compound Of Specified Structure Patents (Class 252/299.6)
  • Patent number: 6400429
    Abstract: A liquid crystal display device includes: a pair of substrates; polymer walls; and a display medium interposed between the pair of substrates, including a liquid crystal region partially provided with or completely surrounded by the polymer walls. The liquid crystal region includes a liquid crystal material having a helical pitch, the helical pitch being either unchanged or reduced upon rise in temperature.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: June 4, 2002
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kohichi Fujimori, Tokihiko Shinomiya, Shuichi Kozaki
  • Patent number: 6369259
    Abstract: Crystals with an average crystal size of ≦10 &mgr;m comprising compounds of the formula Ia and/or IIa A process for making said crystals.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: April 9, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Guido Steffan, Georg Hardenbicker
  • Publication number: 20020034690
    Abstract: An electrolyte composition comprising a polymer compound formed by polymerizing an ionic liquid crystal monomer containing at least one polymerizable group. Also disclosed are an electrochemical cell, a nonaqueous secondary cell and a photoelectrochemical cell, each comprising the electrolyte composition.
    Type: Application
    Filed: January 16, 2001
    Publication date: March 21, 2002
    Inventor: Michio Ono
  • Patent number: 6312618
    Abstract: A new class of asymmetric polar diphenyldiacetylene liquid crystal compounds and method for preparation are disclosed. The new class of liquid crystal compounds comprises the basic structure: Wherein R1 is an alkenyl group having the general formula (C2H2n−1), X is a cyano group, a fluoro group, CF3, OCF3, or a chloro group, Y1 is unsubstituted, a fluoro group, a chloro group or a methyl group, Y2 is unsubstituted, a fluoro group, a chloro group, or a methyl group, Z1 is unsubstituted, a fluoro group, or a methyl group, and Z2 is unsubstituted, a fluoro group, or a methyl group. The compounds disclosed exhibit high birefringence, low rotational viscosity, and have unexpectedly broad nematic ranges. Also disclosed are eutectic mixtures comprising at least one polar diphenyldiacetylene having the general structure described above. The eutectic mixtures also have unexpectedly broad nematic ranges.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: November 6, 2001
    Assignee: HRL Laboratories
    Inventors: Shin-Tson Wu, Mary E. Neubert
  • Patent number: 6251301
    Abstract: Ferroelectric liquid crystal devices having two spaced cell walls each bearing electrode structures and treated on at least one facing surface with an alignment layer, and a layer of a smectic liquid crystal material enclosed between the cell walls, exhibits a minimum in its response time versus voltage curve. The crystal material has two components, A and B.
    Type: Grant
    Filed: September 9, 1998
    Date of Patent: June 26, 2001
    Assignee: The Secretary of State for Defence in Her Brittanic Majesty's Government of the United Kingdom of Great Britian and Northern Ireland
    Inventors: Ian C. Sage, Damien G. McDonnell, John C. Jones, Andrew Slaney
  • Patent number: 6245256
    Abstract: Novel chiral swallow-tailed liquid crystals synthesized from chiral material comprised of alkyl(s)-2-{6-[4-(4′-alkyloxyphenyl)benzoyloxy]-2-naphthyl}propionates having a rigid core, a chiral center directly linked to the rigid core, a chiral tail, and a swallow-tailed group linked to the chiral tail. The chiral center and the swallow-tailed group are arranged at the same side in the molecular structure of the chiral material. These structural characteristics enable the chiral material to have same property of threadholdless antiferroelectricity, and the advantage of simple manufacturing process. The chiral material shows an optimum application effect in liquid crystal displays.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: June 12, 2001
    Assignee: Chunghwa Picture Tubes, Inc.
    Inventors: Shune-Long Wu, Jang-Jeng Liang
  • Patent number: 6231785
    Abstract: A method of producing a difluorobenzyl ether derivative (6) in which a benzene derivative (1) is reacted with a base to form carbanion which is in turn reacted with a difluoromethane derivative (2) to give a benzene derivative (3) which is further reacted with a phenol derivative (5) in the presence of a base.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: May 15, 2001
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Katsuhiko Kobayashi, Shuichi Matsui, Hiroyuki Takeuchi
  • Patent number: 6217948
    Abstract: A polymer film with a helically twisted molecular structure exhibiting at least two maxima of the selective reflection wavelength. A process of preparing such a polymer film and processes for using such polymer film in optical data storage devices, photomasks, decorative pigments, cosmetics, security devices or active and passive optical elements such as polarizers, optical retarders or color filters.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: April 17, 2001
    Assignee: Merck Patent Gesellschaft mit
    Inventors: Mark Verrall, David Coates
  • Patent number: 6214256
    Abstract: A liquid crystal composition is disclosed which comprises: as a first component at least one of the compounds of the following formulas (1-1) and (1-2); as a second component at least one of the compounds of the following formula (2); as a third component at least one of the compounds of the following formulas (3-1) and (3-2); and as a fourth component at least one of the compounds of the following formulas (4-1) to (4-3)
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: April 10, 2001
    Assignee: Chisso Corporation
    Inventors: Yoshitaka Tomi, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6210603
    Abstract: Liquid crystalline compounds are provided which have an extremely high voltage holding ratio, altered only slightly by change of temperature, and which have a low threshold voltage and a high &Dgr;n. Also provided are liquid crystal compositions containing the liquid crystalline compound; and liquid crystal display devices containing the liquid crystal composition. The liquid crystalline compound is expressed by the general formula (1) wherein R, Y1 to Y16, X and Z1 to Z3 are defined in claim 1.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: April 3, 2001
    Assignee: Chisso Corporation
    Inventors: Tomoyuki Kondo, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Shuichi Matsui, Yasusuke Hisatsune, Fusayuki Takeshita, Etsuo Nakagawa
  • Patent number: 6190576
    Abstract: The invention is to provide liquid crystalline compounds which have a low viscosity, high negative dielectric anisotropy, high resistivity, and high voltage holding ratio, and are stable against heat and ultraviolet light; to provide liquid crystal compositions comprising the liquid crystalline compound; and to provide liquid crystal display devices using the liquid crystal composition therein; the liquid crystalline compound is expressed by the general formula (1) wherein R1 and Y1 represent an alkyl group having 1 to 20 carbon atoms; X1, X2, and X3 independently represent single bond, 1,2-ethylene group, vinylene group, —COO—, —CF2O—, or —OCF2—; ring A1, ring A2, ring A3, and ring A4 independently represent trans-1,4-cyclohexylene, or 1,4-phenylene hydrogen atom on the ring may be replaced by fluorine atom or chlorine atom provided that at least one of ring A2, ring A3, and ring A4 represents 2,3-difluoro-1,4-phenylene; m and n are 0 or 1, and each elem
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: February 20, 2001
    Assignee: Chisso Corporation
    Inventors: Tugumiti Andou, Shuichi Matsui, Kazutoshi Miyazawa, Hiroyuki Takeuchi, Yasuyuki Koizumi, Yasuko Sekiguchi, Etsuo Nakagawa, Fusayuki Takeshita
  • Patent number: 6177152
    Abstract: A liquid crystal device having a pair of electrode substrates, and a liquid crystal composition disposed between the substrates. At least one of the substrates is provided with an alignment control layer having a thickness of at most 200 Å and having been subjected to a rubbing uniaxial aligning treatment. The liquid crystal composition contains at least 30 wt. % of (i) at least one species of a fluorine-containing mesomorphic compound (B) represented by a formula (II) having smectic C phase and providing a tilt angle below 30 degrees at a temperature 15° C. below an upper limit temperature of said smectic C phase (ii) at least one species of compound (C) in an amount at least 5 wt. % represented by the formula (II) having a smectic C phase and which provides a tilt angle of at least 30 degrees at a temperature 15° C. below an upper limit temperature of said smectic C phase.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: January 23, 2001
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiro Terada, Kenji Shinjo, Koichi Sato, Syuji Yamada
  • Patent number: 6174458
    Abstract: A tetracyclic compound expressed by the following general formula (1) wherein H1 to H12 represent hydrogen atom at least one of which is replaced by a halogen atom, when either H6 or H8 is replaced by a halogen atom, at least one of the remaining hydrogen atoms is replaced by a halogen atom; R1 and Y1 independently represent an alkyl group, alkoxy group, or alkoxyalkyl group having 1 to 20 carbon atoms, or an alkenyl group having 2 to 20 carbon atoms, one or more methylene group in R1 and Y1 may be replaced by oxygen atom, sulfur atom, dihydrosilylene group, dimethylsilylene group, —CH═CH—, or —C≡C—; and X1, X2, and X3 independently represent a covalent bond, 1,2-ethylene group, or 1,4-butylene group; and a novel liquid crystal composition comprising the tetracyclic compound and having, at the same time, a wide temperature range of a nematic phase, high optical anisotropy, and high chemical stability.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: January 16, 2001
    Assignee: Chisso Corporation
    Inventors: Koji Koga, Tsugumichi Ando, Hiroyuki Takeuchi, Shuichi Matsui, Kazutoshi Miyazawa, Norihisa Hachiya, Etsuo Nakagawa
  • Patent number: 6168728
    Abstract: The present invention provides new liquid crystalline compounds having a high optical anisotropy value and excellent compatibility with the other liquid crystals, and liquid crystal composition comprising the compounds. The liquid crystalline compounds are represented by the general formula (1): wherein H1, H2, H3, H4, H5, H6, H7, H8, H9, H10, H11 and H12, each independently, represent H, F or Cl, at least one of H1, H2, H3, H4, H9, H10, H11 and H12 is F or Cl, R1 represents an alkyl group of C1-20, in which methylene groups may be replaced by —O—, —S—, —Si—, —CH═CH— or —C≡C—, any hydrogen atoms may be replaced by a halogen atom, and Y1 is replaced by R1, F, Cl, Br, I or a cyano group.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: January 2, 2001
    Assignee: Chisso Corporation
    Inventors: Kazutoshi Miyazawa, Kouji Koga, Shuichi Matsui, Norihisa Hachiya, Etsuo Nakagawa