Inorganic Luminescent Compositions Patents (Class 252/301.4R)
  • Publication number: 20130277613
    Abstract: A method and apparatus for sintering flat ceramics using a mesh or lattice is described herein.
    Type: Application
    Filed: April 18, 2013
    Publication date: October 24, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventors: Hiroaki Miyagawa, Guang Pan, Hironaka Fujii, Bin Zhang, Amane Mochizuki, Toshitaka Nakamura
  • Patent number: 8551362
    Abstract: A light-emitting device is produced using a phosphor composition containing a phosphor host having as a main component a composition represented by a composition formula: aM3N2.bAlN.cSi3N4, where “M” is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, and “a”, “b”, and “c” are numerical values satisfying 0.2?a/(a+b)?0.95, 0.05?b/(b+c)?0.8, and 0.4?c/(c+a)?0.95. This enables a light-emitting device emitting white light and satisfying both a high color rendering property and a high luminous flux to be provided.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: October 8, 2013
    Assignee: Panasonic Corporation
    Inventor: Shozo Oshio
  • Publication number: 20130256599
    Abstract: The present invention relates to a ceramics composite including: a matrix phase including Al2O3 or a substance in which one selected from Sc2O3 and Ga2O3 is incorporated into Al2O3; a main phosphor phase formed in the matrix phase and including a substance represented by a general formula A3B5O12:Ce in which A is at least one selected from Y, Gd, Tb, Yb and Lu and B is at least one selected from Al, Ga and Sc; and a CeAl11O18 phase mixed in the matrix phase and the main phosphor phase.
    Type: Application
    Filed: February 7, 2013
    Publication date: October 3, 2013
    Applicant: COVALENT MATERIALS CORPORATION
    Inventor: Masaki IRIE
  • Publication number: 20130256600
    Abstract: An oxide ceramic fluorescent material is provided comprising a polycrystalline ceramic sintered body of Y3Al5O12, Lu3Al5O12, (Y, Lu)3Al5O12, (Y, Gd)3Al5O12, or Al2O3 in which a rare earth element selected from Ce, Eu and Tb has been diffused from its surface as fluorescent activator. The concentration of the rare earth element is 1 wt % at a depth of 50-600 ?m as measured from the sintered body surface and at least 1 wt % at any position nearer to the sintered body surface.
    Type: Application
    Filed: March 22, 2013
    Publication date: October 3, 2013
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Toshihiro Tsumori, Kazuhiro Wataya
  • Patent number: 8545723
    Abstract: A persistent phosphor of formula I is provided, along with methods for making and using the phosphor: AxAlyO4:Euj, REk, Bm, Znn, Coo, Scp ??I wherein: A is Ba, Sr, Ca, or a combination of these metals; x is greater than about 0.75 and less than about 1.3; y is greater than or equal to about 1.6 and less than or equal to 2; j is greater than about 0.0005 and less than about 0.1; k is greater than about 0.0005 and less than about 0.1; m is greater than or equal to 0 and less than about 0.30; n is greater than 0 and less than about 0.10; o is greater than 0 and less than about 0.01; p is greater than 0 and less than about 0.05; and RE is Dy, Nd, or a combination thereof. Applications for such phosphors include use in toys, emergency equipment, clothing, and instrument panels, among others.
    Type: Grant
    Filed: March 30, 2011
    Date of Patent: October 1, 2013
    Assignee: General Electric Company
    Inventors: Holly Ann Comanzo, Alok Mani Srivastava, William Winder Beers, Sergio Martins Loureiro, Anant Achyut Setlur, Stanley John Stoklosa, Claire Susan Henderson
  • Publication number: 20130248764
    Abstract: The invention relates to a method of making Ce3+ containing laser materials with a fast cooling rate.
    Type: Application
    Filed: December 2, 2011
    Publication date: September 26, 2013
    Applicant: KONINKLIJKE PHILIPS ELECTRONICS N.V.
    Inventors: Ulrich Weichmann, Matthias Alexander Wilhelm Fechner, Fabian Reichert, Herbert Walter Klaus Petermann, Gunter Huber
  • Publication number: 20130240787
    Abstract: A method of making a nanocrystal includes slowly infusing a M-containing compound and a X donor into a mixture including a nanocrystal core, thereby forming an overcoating including M and X on the core.
    Type: Application
    Filed: March 15, 2012
    Publication date: September 19, 2013
    Inventors: Ou Chen, Moungi G. Bawendi
  • Patent number: 8529791
    Abstract: Disclosed herein are green-emitting, garnet-based phosphors having the formula (Lu1-a-b-cYaTbbAc)3(Al1-dBd)5(O1-eCe)12:Ce,Eu, where A is selected from the group consisting of Mg, Sr, Ca, and Ba; B is selected from the group consisting of Ga and In; C is selected from the group consisting of F, Cl, and Br; and 0?a?1; 0?b?1; 0<c?0.5; 0?d?1; and 0<e?0.2. These phosphors are distinguished from anything in the art by nature of their inclusion of both an alkaline earth and a halogen. Their peak emission wavelength may lie between about 500 nm and 540 nm; in one embodiment, the phosphor (Lu,Y,A)3Al5(O,F,Cl)12:Eu2+ has an emission at 540 nm. The FWHM of the emission peak lies between 80 nm and 150 nm. The present green garnet phosphors may be combined with a red-emitting, nitride-based phosphor such as CaAlSiN3 to produce white light.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: September 10, 2013
    Assignee: Intematix Corporation
    Inventors: Yusong Wu, Dejie Tao, Shifan Cheng, Yi-Qun Li
  • Publication number: 20130207040
    Abstract: The present invention relates to long decay phosphors comprising rare earth activated strontium aluminates and methods for producing them. The phosphors comprise a matrix of the formula Sr4Al14O25 comprising europium as an activator and a further rare earth element as a co-activator, wherein the molar ratio of Al/Sr in the starting materials is in the range of 3.1 to less than 3.5 and the ratio of Eu/Sr is in the range of 0.0015 to 0.01. The process for the preparation of a phosphor comprises the steps of milling the starting materials for the synthesis of the phosphor, the starting materials comprising a boron compound selected from boric acid, boric oxide or a borate salt in an amount such that the B/Sr molar ratio is between 0.1 and to 0.3, treating the milled composition with heat, grinding the block material which is obtained through the heat treatment, ball-milling the crushed material, sieving the material, and washing the material with an aqueous solution.
    Type: Application
    Filed: February 5, 2013
    Publication date: August 15, 2013
    Applicant: ROLEX SA
    Inventor: Rolex SA
  • Patent number: 8506843
    Abstract: This disclosure features a persistent phosphor having the following formula I: Sra,Cab,BacAl2-m-n-o-pOd:Euy,REz,Bm,Znn,Coo,Scp??I where a and b each range from about 0.3 to about 0.7; c is between about 0 and about 0.1; 0.75?a+b+c+y+z?1.3; y is between about 0.0005 and about 0.1; RE is any rare earth element alone or in combination; z is between about 0.0005 and about 0.15; m is between about 0.0005 and about 0.30; n is between about 0 and about 0.10; o is between about 0 and about 0.01; p is between about 0 and about 0.10 and d ranges from about 3.945 to about 4.075. Once the persistent phosphor has been excited it appears white in an absence of ambient light. Also featured is an article of manufacture that includes the phosphor.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: August 13, 2013
    Assignee: General Electric Company
    Inventors: Alok Srivastava, Holly Ann Comanzo, Sam Camardello, William W. Beers
  • Patent number: 8496852
    Abstract: The invention relates to a phosphor in a polycrystalline ceramic structure and a light-emitting element provided with the same comprising a Light-Emitting Diode (LED) in which a composite structure of phosphor particles is embedded in a matrix, characterized in that the matrix is a ceramic composite structure comprising a polycrystalline ceramic alumina material, hereafter called luminescent ceramic matrix composite. This luminescent ceramic matrix composite can be made by the steps of converting a powder mixture of ceramic phosphor particles and alumina particles into a slurry, shaping the slurry into a compact, and applying a thermal treatment, optionally in combination with hot isostatic pressing into a polycrystalline phosphor-containing ceramic alumina composite structure.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: July 30, 2013
    Assignee: Philips Koninklijke N.V.
    Inventors: Jan De Graaf, Theo Arnold Kop
  • Patent number: 8486299
    Abstract: The invention provides phosphors composed of Eu(1-x-w)MaxMbwMgMc10O17, wherein Ma is Yb, Sn, Ce, Tb, Dy, or combinations thereof, and 0<x<0.5, Mb is Ca, Sr, Ba, or combinations thereof, and 0?w?0.5, and Mc is Al, Ga, Sc, In, or combinations thereof. The blue phosphors emit blue light under the excitation of ultraviolet light or blue light, and the phosphors may be further collocated with different colored phosphors to provide a white light illumination device. The blue phosphors of the invention can efficiently utilize light in solar cells.
    Type: Grant
    Filed: July 21, 2010
    Date of Patent: July 16, 2013
    Assignee: Industrial Technology Research Institute
    Inventors: Tien-Heng Huang, Fang-Ching Chang, Yao-Tsung Yeh, Shian-Jy Wang
  • Patent number: 8475683
    Abstract: Disclosed herein are yellow-green and yellow-emitting aluminate based phosphors for use in white LEDs, general lighting, and LED and backlighting displays. In one embodiment of the present invention, the cerium-activated, yellow-green to yellow-emitting aluminate phosphor comprises the rare earth lutetium, at least one alkaline earth metal, aluminum, oxygen, at least one halogen, and at least one rare earth element other than lutetium, wherein the phosphor is configured to absorb excitation radiation having a wavelength ranging from about 380 nm to about 480 nm, and to emit light having a peak emission wavelength ranging from about 550 nm to about 600 nm.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: July 2, 2013
    Assignee: Intematix Corporation
    Inventors: Yi-Qun Li, Jingtao Gu, Zhankun Jia, Shifan Cheng
  • Publication number: 20130161560
    Abstract: There is provided a thermoluminescent phosphor characterized in that a distribution of the emission intensity of thermoluminescence is present in a visible range that does not overlap the peak of the heating-caused emission intensity of the thermoluminescent phosphor itself and also has one peak within a temperature range in which a resin to be used as a binder can resist heat optically. There is also provided a method of producing the thermoluminescent phosphor. More specifically, there are provided a thermoluminescent phosphor that comprises lithium heptaborate as a base material and copper as a luminescent center present in the base material and which is characterized in that the distribution of the emission intensity of thermoluminescence versus temperature is a sole and monomodal distribution within the range of from 45° C. to 130° C., and a method of producing the thermoluminescent phosphor.
    Type: Application
    Filed: September 2, 2011
    Publication date: June 27, 2013
    Applicant: RIKKYO GAKUIN
    Inventors: Akio Urushiyama, Yuji Tomizawa
  • Patent number: 8470200
    Abstract: The present invention provides a production process for the production of an MAl2O4:Eu type long-lasting phosphor (M representing an alkaline earth metal). The process includes the steps of mixing a BAM (alkaline earth aluminate) phosphor with an alkaline earth compound and calcinating the resulting mixture.
    Type: Grant
    Filed: July 13, 2009
    Date of Patent: June 25, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yuji Kimura, Yasushi Takai, Hirofumi Kawazoe
  • Patent number: 8470201
    Abstract: An oxide phosphor that is highly durable and produces visible light when excited by exposure to near-ultraviolet excitation light, comprising an oxide having the composition represented by the formula (Al2O3)x.(SiO2)1-x, where 0<x<1, and an activating element M.
    Type: Grant
    Filed: June 14, 2012
    Date of Patent: June 25, 2013
    Assignee: Shibaura Institute of Technology
    Inventor: Masato Ota
  • Publication number: 20130153824
    Abstract: Provided is a silicon nitride powder for siliconitride phosphor having high luminance, a Sr3Al3Si13O2N21 phosphor and a ?-Sialon phosphor using the powder, which can be used for vacuum fluorescent displays (VFDs), field emission displays (FEDs), plasma display panels (PDPs), cathode ray tubes (CRTs), light emitting diodes (LEDs), or the like, and processes for producing these phosphors. The silicon nitride powder for the siliconitride phosphors is a crystalline silicon nitride powder for use as a raw material for producing siliconitride phosphors including a silicon element, a nitrogen element, and an oxygen element, and has an average particle diameter of 1.0 to 12 ?m and an oxygen content of 0.2 to 0.9% by weight.
    Type: Application
    Filed: July 29, 2011
    Publication date: June 20, 2013
    Applicant: UBE INDUSTRIES LTD.
    Inventors: Masataka Fujinaga, Takuma Sakai, Shinsuke Jida
  • Publication number: 20130153823
    Abstract: A rare earth-aluminium/gallate based fluorescent material and manufacturing method thereof are provided. Said rare earth-aluminium/gallate based fluorescent material comprises a core, and a shell which coats said core, wherein said core is a metal nanoparticle, and said shell is a fluorescent powder of chemical formula (Y1-xCex)3(Al1-yGay)5O12, 0<x?0.5, 0?y?1.0. Said rare earth-aluminium/gallate based fluorescent material has a uniform particle size distribution, a stable structure, a high luminous efficiency and a high luminous strength. The manufacturing method has the following properties: a simple technique, a low demand for equipments, no pollution, easily controllable reactions, material shapes and particle sizes, and being suitable for industrial manufacture.
    Type: Application
    Filed: April 30, 2010
    Publication date: June 20, 2013
    Inventors: Mingjie Zhou, Jun Liu, Wenbo Ma
  • Publication number: 20130153825
    Abstract: A luminescent material, containing yttrium oxide, oxides of rare-earth metals, as well as aluminium, gallium and indium oxides in a ratio that produces compounds corresponding to the general formula: [(Y1-x-y-zCex?(Ln-1)y?(Ln-2)z]3-?(Al1-p-qGapInq)5O12-1.5? where ? is a value varying within the 0.20???2.80 range; x is cerium atomic fraction, varying in the 0.001<x<0.15 range; ?(Ln-1)y is one or several lanthanides of the Gd, Tb, La, Lu and Sm, which—together with yttrium and cerium—form the basis of the “Cation” sub-lattice, and 0?y?0.90. ?(Ln-2)z is one or several lanthanides of the Pr, Nd, Eu, Dy, Ho, Tm, Er and Yb group. They are dopants introduced into the ‘cation’ sub-lattice at a rate of 0.0001<z<0.01; also x, y and z were selected in such a fashion that 1-x-y-z>0; p and q are atomic fractions of Ga and In in the aluminium sub-lattice. Their ranges are: 0<p<0.3 and 0<q<0.3.
    Type: Application
    Filed: October 22, 2010
    Publication date: June 20, 2013
    Inventors: Anatoly Vasilyevich Vishnyakov, Yaohui Chang, Ekaterina Analtolyevna Vishniakova
  • Publication number: 20130140492
    Abstract: Borate luminescent materials, preparation methods and uses thereof are provided. The luminescent materials are represented by the general formula: (In1-xRex)BO3:zM, wherein Re is one or two selected from Tm, Tb, Eu, Sm, Gd, Dy and Ce, M is one or two selected from metal nano particles of Au, Ag, Pt or Pd, 0<x?0.5, 0<z?1×10?2. Compared to the luminescent materials in the prior art, the said luminescent materials have higher luminous intensity and luminous efficiency, which can be used in field emission displays or light source.
    Type: Application
    Filed: August 19, 2010
    Publication date: June 6, 2013
    Inventors: Mingjie Zhou, Jun Liu, Wenbo Ma
  • Publication number: 20130105735
    Abstract: A process is disclosed for the production of persistent phosphors, comprising exposing particles of phosphor precursors for a short time to a heat source selected from a particle plasma and an open flame arising from the combustion of hydrocarbons. A process for coating a substrate with persistent phosphors is also disclosed, comprising directing a stream of phosphor precursor particles for a short time through the same types of heat source toward the substrate. Preferred phosphors are Strontium Aluminate-based doped with Dysprosium and Europium.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 2, 2013
    Inventors: Willard Scott Rader, Robert William Hepburn
  • Publication number: 20130105736
    Abstract: The invention relates to an converter material for solar cells using Sm2+.
    Type: Application
    Filed: July 5, 2011
    Publication date: May 2, 2013
    Applicant: KONINKLIJKE PHILIPS ELECTRONICS N.V.
    Inventors: Cornelis Reinder Ronda, Dirk Kornelis Gerhardus De Boer, Andries Meijerink, Nikolaos Christogiannis, Danielle Beelen, Wilhelmus Cornelis Keur
  • Patent number: 8431042
    Abstract: In an embodiment, a solid state scintillator material includes a composition represented by a general formula: (Gd1-?-?-?TB?Lu?Ce?)3(Al1-xGax)aOb, where ? and ? are numbers satisfying 0<??0.5, 0<??0.5, and ?+??0.85, ? is a number satisfying 0.0001???0.1, x is a number satisfying 0<x<1, a is a number satisfying 4.8?a?5.2 and b is a number satisfying 11.6?b?12.4 (atomic ratio), and a garnet structure.
    Type: Grant
    Filed: February 21, 2012
    Date of Patent: April 30, 2013
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Materials Co., Ltd.
    Inventors: Yukihiro Fukuta, Takao Sawa, Makoto Hayashi
  • Publication number: 20130099162
    Abstract: A borate based red light emitting material is provided, which comprises a core and a shell covering the said core. Said core is nanometer metal particle, and the shell is fluorescent powder having the chemical formula of (Y1-x-yEuxGdy)BO3, wherein 0<x?0.3, 0?y?0.7. The material has the advantages of uniform particle size, structure stability, excellent luminous intensity and luminous efficiency. The preparation method has a simple process, low demand on equipment and no pollution. The method is easily controllable for the reaction, material morphology and particle size, and suitable for industrial production.
    Type: Application
    Filed: April 30, 2010
    Publication date: April 25, 2013
    Applicant: OCEAN'S KING LIGHTING SCIENCE & TECHNOLOGY CO.,LTD
    Inventors: Mingjie Zhou, Jun Liu, Wenbo Ma
  • Publication number: 20130082208
    Abstract: Disclosed is a strontium cerate luminescent material having a chemical formula of Sr2CeO4:xM and comprising the luminescent material Sr2CeO4 and metal nanoparticle M, and the preparation method thereof, where M is at least one of Ag, Au, Pt and Pd, and x is a molar ratio of M to the luminescent material Sr2CeO4 and 0<x?1×10?2. The strontium cerate luminescent material of the present invention, through doping the luminescent material with metal particles, improves luminous intensity of the luminescent material by making use of the surface plasmon resonance generated by surface of the metal particles; besides, the doped metal ion can improve electrical conductivity of the luminescent material, and guarantee that the luminescent material has higher brightness in field emission devices or LEDs. The preparation method of the present invention has the advantages of simple operation, no pollution, easy control, low requirements for equipment, and being favorable to industrialized production.
    Type: Application
    Filed: June 17, 2010
    Publication date: April 4, 2013
    Applicant: OCEAN'S KING LIGHTING SCIENCE & TECHNOLOGY CO., LTD.
    Inventors: Mingjie Zhou, Jun Liui, Wenbo Ma
  • Publication number: 20130082207
    Abstract: In accordance with one aspect of the present invention, a core?shell phosphor composition is provided that includes a core comprising magnesium oxide; and a shell at least partially enclosing the core, wherein the shell comprises a shell material having formula (I) (Y1?xEux)2O3 ??(I) wherein, 0<x<0.95. In accordance to another aspect of the invention a method of making the core?shell phosphor and a light source including the core?shell phosphor are provided.
    Type: Application
    Filed: September 29, 2011
    Publication date: April 4, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Alok Mani Srivastava, Holly Ann Comanzo, Samuel Joseph Camardello, Florencio Garcia
  • Patent number: 8409471
    Abstract: A green phosphor including a compound represented by Formula 1 (Y3-xMx) (Al5-yM?y)O12:Cez and a pigment. The green phosphor having the compound represented by Formula 1 and a pigment has a shorter decay time than conventional phosphors, and thereby confers excellent luminescence characteristics and color purity. A display panel including the green phosphor 1 is also provided herein.
    Type: Grant
    Filed: August 12, 2010
    Date of Patent: April 2, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yu-Mi Song, Jay-Hyok Song, Ick-Kyu Choi, Young-Hun Lee, Young-Ki Kim, Mi-Ran Song, Do-Hyung Park, Yoon-Chang Kim, Young-Kwan Kim, Soon-Rewl Lee, Dong-Sik Zang
  • Publication number: 20130075660
    Abstract: Disclosed is a phosphor and a method for preparing the same. The phosphor comprises a material having a general composition formula expressed by M1Si6N8?xOx (satisfying 0?x?1), where M is alkaline earth metal.
    Type: Application
    Filed: September 23, 2011
    Publication date: March 28, 2013
    Applicant: Epistar Corporation
    Inventors: Chiao-Wen YEH, Ru-Shi Liu
  • Patent number: 8404153
    Abstract: This disclosure features a blend, or use together in at least two layers of an article of manufacture, of a first persistent phosphor, a second persistent phosphor and a third phosphor. The first persistent phosphor has a formula I: Cax-y-z-aAaAl2-m-n-o-pOd:Euy,REz,Bm,Znn,Coo,Scp??I where the variables are defined in the disclosure. The second persistent phosphor has a formula II: Srx-y-z-aAaAl14-m-n-o-pOd:Euy,REz,Bm,Znn,Coo,Scp??II where the variables are defined in the disclosure. The third phosphor is a non-persistent phosphor that is excited at a wavelength in a range of 300-500 nm. Also featured is an article of manufacture including the blend or the phosphors present in at least two layers. Once the blend or layered structure comprising the three phosphors has been excited it can appear white in an absence of ambient light.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: March 26, 2013
    Assignee: General Electric Company
    Inventors: Holly Ann Comanzo, Alok Srivastava, William W. Beers
  • Publication number: 20130062562
    Abstract: An aluminate-based fluorescent powder coated by metal nanoparticles. The formula thereof is (Y1-xTbx)3(Al1-yGay)5O12@zM, in which 0<x?1.0, 0?y?1.0, @ means coating, M is metal nanoparticles, z is mole ratio of metal nanoparticles to aluminate-based fluorescent powder and 0<z?0.01. A method for producing the aluminate-based fluorescent powder coated by metal nanoparticles is also provided.
    Type: Application
    Filed: May 25, 2010
    Publication date: March 14, 2013
    Inventors: Mingjie Zhou, Jun Liu, Wenbo Ma
  • Publication number: 20130062561
    Abstract: A phosphor is represented by below formula: AaBbCcDdEe:Mm wherein, M represents at least one activator selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and combinations thereof; A represents at least one element selected from Ca2+, Sr2+, Ba2+ and combinations thereof; B represents C4+, Si4+ or Ge4+; C represents B3+, Al3+ or Ga3+; D and E each independently represent at least one element selected from N, O, F and combinations thereof; m+a=2; 0.00001?m?0.1; 0.5?b+c?8; and 0.5?d+e?10. The phosphor has a color render index of greater than 50 and is suitable to be applied in a white LED to improve the color rendering property of the white light. A method of preparing the phosphor is also provided.
    Type: Application
    Filed: September 9, 2011
    Publication date: March 14, 2013
    Applicant: EPISTAR CORPORATION
    Inventors: Wei-Ting Chen, Ru-Shi Liu, Chien-Yuan Wang
  • Patent number: 8388862
    Abstract: InGaN-based blue LEDs and, specifically luminescent materials, are described containing yttrium oxide, oxides of rare earth metals, as well as aluminium oxide in proportions that yield a luminescent material whose average composition fits the general formula (Y1?x?yCex?Lny)3+?Al5O12+1.5?, where ?—defines increase in stoichiometric index over the known value for yttrium-gadolinium garnet and varies between 0.033 and 2; x—is atomic fraction of cerium, 0.0001-0.1; ?Lny —is one or more lanthanides from the Gd, Tb, La, Yb group, whose atomic fraction in an yttrium sub-lattice is 0.01<Gd<0.70; 0.001<Tb<0.2; 0.001<La<0.1; 0.001<Yb<0.1, respectively, while the difference for all the compositions [1?x?y]>0.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: March 5, 2013
    Inventors: Anatoly Vasilyevich Vishnyakov, Dmitry Juryevich Sokolov
  • Publication number: 20130043430
    Abstract: A polycrystalline scintillator for detecting soft X-rays, which comprises Ce as a light-emitting element and at least Y, Gd, Al, Ga and O, and has a garnet crystal structure, and a composition represented by the general formula of (Y1?x?zGdxCez)3+a(Al1?uGau)5?aO12, wherein 0?a?0.1, 0.15?x?0.3, 0.002?z?0.015, and 0.35?u?0.55, with 0.05-1 ppm by mass of Fe and 0.5-10 ppm by mass of Si by outer percentage, a ratio ?50/?100 of 3 or more, wherein ?50 is an absorption coefficient of X-rays at 50 keV, and ?100 is an absorption coefficient of X-rays at 100 keV, and afterglow of 800 ppm or less after 3 ms from the termination of X-ray irradiation.
    Type: Application
    Filed: October 25, 2011
    Publication date: February 21, 2013
    Applicant: HITACHI METALS, LTD.
    Inventors: Ryouhei Nakamura, Kenya Tanaka, Shunsuke Ueda
  • Patent number: 8377333
    Abstract: A semiconductor nanocrystal including a core comprising a first semiconductor material comprising at least three chemical elements and a shell disposed over at least a portion of the core, the shell comprising a second semiconductor material, wherein the semiconductor nanocrystal is capable of emitting light with an improved photoluminescence quantum efficiency. Also disclosed are populations of semiconductor nanocrystals, compositions and devices including a semiconductor nanocrystal capable of emitting light with an improved photoluminescence quantum efficiency. In one embodiment, a semiconductor nanocrystal includes a core comprising a first semiconductor material comprising at least three chemical elements and a shell disposed over at least a portion of the core, the shell comprising a second semiconductor material, wherein the semiconductor nanocrystal is capable of emitting light upon excitation with a photoluminescence quantum efficiency greater than about 65%.
    Type: Grant
    Filed: May 21, 2009
    Date of Patent: February 19, 2013
    Assignee: QD Vision, Inc.
    Inventors: Dorai Ramprasad, Craig Breen, Jonathan S. Steckel
  • Publication number: 20130037747
    Abstract: Aluminate fluorescent materials and preparation methods thereof are provided. The fluorescent materials include a core and a shell coating the core. The core is metal nano particle, the shell is fluorescent powder represented by the following chemical formula: (Ce1-xTbx)MgAl11O19, wherein 0<x?0.7. The aluminate fluorescent materials with high luminous efficiency are not only uniform in the aspect of particle size distribution, but also are stable in the aspect of structure. The preparation methods which have simple technique and low pollution are appropriate to be used in industry.
    Type: Application
    Filed: April 30, 2010
    Publication date: February 14, 2013
    Applicant: OCEAN'S KING LIGHTING SCIENCE & TECHNOLOGY CO.,LTD
    Inventors: Mingjie Zhou, Jun Liu, Wenbo Ma
  • Patent number: 8361347
    Abstract: The blue phosphor of the present invention includes ZrO2 and a metal aluminate that is represented by the general formula aBaO.bSrO.(1?a?b)EuO.cMgO.dAlO3/2.eWO3, where 0.70?a?0.95, 0?b?0.15, 0.95?c?1.15, 9.00?d?11.00, 0.001?e?0.200, and a+b?0.97 are satisfied. This blue phosphor has a ZrO2 content of 0.01 to 1.00% by weight. In the blue phosphor of the present invention, two peaks whose tops are located in a range of diffraction angle 2?=13.0 to 13.6 degrees are present in an X-ray diffraction pattern obtained by measurement on the blue phosphor using an X-ray with a wavelength of 0.774 ?.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: January 29, 2013
    Assignee: Panasonic Corporation
    Inventors: Kojiro Okuyama, Yayoi Okui, Seigo Shiraishi
  • Publication number: 20130015402
    Abstract: A rare earth ion doped lanthanum gallate luminous material containing metal particles and preparation method thereof are provided. The chemical formula of the lanthanum gallate luminous material is La1-xGaO3:Lnx,My, wherein Ln is one or more of Tm3+, Tb3+, Eu3+ and Sm3+, M is one of Ag, Au, Pt and Pd, the value range of x is 0.001 to 0.1, and the value range of y is 0.00002 to 0.01. The luminous performance of the lanthanum gallate luminous material can be greatly improved under the same excitation condition and the wavelength of emission light doesn't change, due to the introduction of metal particles into the rare earth ion doped lanthanum gallate luminous material. The lanthanum gallate luminous material has excellent luminous performance, and its emitting photochromic purity and light emitting luminance after excitation are high, so it can be used widely in various kinds of light emitting devices.
    Type: Application
    Filed: April 23, 2010
    Publication date: January 17, 2013
    Inventors: Mingjie Zhou, Wenbo Ma, Ting Lv
  • Publication number: 20130009097
    Abstract: An oxynitride phosphor and a method of manufacturing the same are revealed. The formula of the oxynitride phosphor is Ba3-xSi6O12N2: Yx (0?x?1). Y is praseodymium (Pr) or terbium (Tb) used as a luminescent center. The oxynitride phosphor is synthesized by solid-state reaction. The oxynitride phosphor is excited by vacuum ultraviolet light with a wavelength range of 130 nm to 300 nm or ultraviolet to visible light with a wavelength range of 300 nm to 550 nm to emit light with a wavelength range of 400 nm to 700 nm. Moreover, the full-width at half-maximum of the emission spectrum is smaller than 30 nm. Thus the oxynitride phosphor is suitable for applications of backlights, plasma display panels and ultraviolet excitation. The oxynitride phosphor has higher application value.
    Type: Application
    Filed: July 5, 2012
    Publication date: January 10, 2013
    Applicant: FORMOSA EPITAXY INCORPORATION
    Inventors: CHENG-I CHU, RU-SHI LIU, YU-CHIH LIN, CHEN-HONG LEE, WEI-KANG CHENG, YI-SHENG TING, SHYI-MING PAN
  • Publication number: 20130001470
    Abstract: A luminescent particle includes an interior portion of the luminescent particle comprising a luminescent compound that reacts with atmospherically present components and a passivating layer on an outer surface of the luminescent particle that is operable to inhibit the reaction between the luminescent compound and the atmospherically present components.
    Type: Application
    Filed: September 12, 2012
    Publication date: January 3, 2013
    Applicant: Cree, Inc.
    Inventors: Brian Thomas Collins, Jesse Colin Reiherzer, Florin A. Tudorica
  • Patent number: 8343379
    Abstract: The invention discloses a red phosphor powder which is based on strontium (Sr) aluminate and using europium (Eu) as exciting agent, and is characterized by that its chemical equivalence formula is (SrO)4(?Me+2O)1Al2O3: Eu, wherein Me+2=Mg and/or Ca and/or Ba. The present invention also discloses a manufacturing process for the red phosphor powder and a warm white light-emitting diode employing the phosphor powder. Moreover, the present invention also discloses a multi-layer polyethylene thin film using the red phosphor powder.
    Type: Grant
    Filed: June 3, 2009
    Date of Patent: January 1, 2013
    Assignees: Wei-Hung Lo, Chien-Yi Chen
    Inventors: Soshchin Naum, Wei-Hung Lo, Chi-Ruei Tsai
  • Publication number: 20120326086
    Abstract: A compound is provided containing silicon, aluminum, strontium, europium, nitrogen, and oxygen is used that enables a red phosphor having strong luminous intensity and high luminance to be obtained, and that enables the color gamut of a white LED to be increased with the use of the red phosphor. The red phosphor contains an element A, europium, silicon, aluminum, oxygen, and nitrogen at the atom number ratio of the following formula: [A(m-x)Eux]Si9AlyOnN[12+y-2(n-m)/3]. The element A in the formula is at least one of magnesium, calcium, strontium, and barium, and m, x, y, and n in the formula satisfy the relations 3<m<5, 0<x<1, 0<y<2, and 0<n<10.
    Type: Application
    Filed: March 21, 2012
    Publication date: December 27, 2012
    Applicant: SONY CORPORATION
    Inventors: Hiraku Akiho, Tsuneo Kusunoki, Takahiro Igarashi, Takamasa Izawa
  • Patent number: 8337720
    Abstract: Embodiments of the invention involve semiconductor nanoparticle capping ligands, their production and use. Ligands may have the formula with m ranging from approximately 8 to approximately 45. An embodiment provides a method of forming a compound of the formula including the steps of providing a first starting material comprising poly(ethyleneglycol) and reacting the first starting material with a second starting material comprising a functional group for chelating to the surface of a nanoparticle to thereby form the compound.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: December 25, 2012
    Assignee: Nanoco Technologies, Ltd.
    Inventors: Mark C. McCairn, Steven M. Daniels, Siobhan Cummins, Nigel Pickett
  • Publication number: 20120319049
    Abstract: Embodiments of the present disclosure relate to visible luminescent phosphors, visible luminescent nanobelt phosphors, methods of making visible luminescent phosphors, methods of making visible luminescent nanobelt phosphors, mixtures of visible luminescent phosphors, methods of using visible luminescent phosphors, waveguides including visible luminescent phosphors, white light emitting phosphors, and the like.
    Type: Application
    Filed: February 10, 2011
    Publication date: December 20, 2012
    Inventors: Zhengwei Pan, Feng Liu, Xufan Li
  • Patent number: 8323528
    Abstract: Compositions, methods of making compositions, materials including compositions, crayons including compositions, paint including compositions, ink including compositions, waxes including compositions, polymers including compositions, vesicles including the compositions, methods of making each, and the like are disclosed.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: December 4, 2012
    Assignee: University of Georgia Research Foundation, Inc.
    Inventors: Weiyi Jia, Xiaojun Wang, William Yen, Laurel C. Yen, legal representative, George D. Jia
  • Patent number: 8318044
    Abstract: A light emitting device is disclosed. The light emitting device may include a light emitting diode (LED) for emitting light and phosphor adjacent to the LED. The phosphor may be excitable by light emitted by the LED and may include a first compound having a host lattice comprising first ions and oxygen. In one embodiment, the host lattice may include silicon, the copper ions may be divalent copper ions and first compound may have an Olivin crystal structure, a ?-K2SO4 crystal structure, a trigonal Glaserite (K3Na(SO4)2) or monoclinic Merwinite crystal structure, a tetragonal Ackermanite crystal structure, a tetragonal crystal structure or an orthorhombic crystal structure. In another embodiment, the copper ions do not act as luminescent ions upon excitation with the light emitted by the LED.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: November 27, 2012
    Assignee: Seoul Semiconductor Co., Ltd.
    Inventors: Chung-Hoon Lee, Gundula Roth, Walter Tews
  • Publication number: 20120286206
    Abstract: A green luminescent material of terbium doped gadolinium borate is provided. The luminescent material has a formula of M3Gd1-xTbx(BO3)3, wherein, M is alkaline earth metal element and x is 0.005-0.5. The method for preparing the luminescent material comprises the following steps: selecting the source compounds of alkaline earth metal ion, boric acid radical ion (BO33?), Gd3+ and Tb3+ by the stoichiometric ratio, wherein, the stoichiometric ratio is the molar ratio of the corresponding element in the formula of M3Gd1-xTbx(BO3)3, and the source compound of BO33 is over 10%-30% by the molar ratio; mixing; pre-treatment by sintering; cooling; grinding; calcination; and cooling to obtain the luminescent material.
    Type: Application
    Filed: February 26, 2010
    Publication date: November 15, 2012
    Inventors: Mingjie Zhou, Xiaofang Liang, Jun Liu, Qiurong Liao
  • Patent number: 8308980
    Abstract: A light emitting device is disclosed. The light emitting device may include a light emitting diode (LED) for emitting light and phosphor adjacent to the LED. The phosphor may be excitable by light emitted by the LED and may include a first compound having a host lattice comprising first ions and oxygen. In one embodiment, the host lattice may include silicon, the copper ions may be divalent copper ions and first compound may have an Olivin crystal structure, a ?-K2SO4 crystal structure, a trigonal Glaserite (K3Na(SO4)2) or monoclinic Merwinite crystal structure, a tetragonal Ackermanite crystal structure, a tetragonal crystal structure or an orthorhombic crystal structure. In another embodiment, the copper ions do not act as luminescent ions upon excitation with the light emitted by the LED.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: November 13, 2012
    Assignee: Seoul Semiconductor Co., Ltd.
    Inventors: Chung Hoon Lee, Gundula Roth, Walter Tews
  • Patent number: 8303846
    Abstract: It is an object of the present invention to provide an infra-red light emitting phosphor having an excellent chemical stability and desirable light emitting properties. The infra-red light emitting phosphor is represented by a chemical formula: (A1-x-yNdxYby)VO4, wherein A represents at least one element selected from yttrium (Y), gadolinium (Gd), lutetium (Lu) and lanthanum (La); x and y respectively satisfy the requirements: 0.01?x?0.3 and 0.01?y?0.4, provided that (x+y)?0.5 and 0.2?(y/x)?6. This vanadate phosphor having the constitution described above can act as an infra-red light emitting phosphor having an excellent chemical stability and desirable light emitting properties.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: November 6, 2012
    Assignee: Nemoto & Co., Ltd.
    Inventors: Takeshi Takahara, Yasushi Aoki, Kaori Kanesaka, Takashi Murase
  • Patent number: 8298442
    Abstract: Disclosed herein is a method of increasing the luminescence efficiency of a translucent phosphor ceramic. Other embodiments are methods of manufacturing a phosphor translucent ceramic having increased luminescence. Another embodiment is a light emitting device comprising a phosphor translucent ceramic made by one of these methods.
    Type: Grant
    Filed: January 25, 2012
    Date of Patent: October 30, 2012
    Assignee: Nitto Denko Corporation
    Inventors: Hiroaki Miyagawa, Toshitaka Nakamura, Hironaka Fujii, Amane Mochizuki
  • Patent number: 8287759
    Abstract: A luminescent particle includes an interior portion of the luminescent particle comprising a luminescent compound that reacts with atmospherically present components and a passivating layer on an outer surface of the luminescent particle that is operable to inhibit the reaction between the luminescent compound and the atmospherically present components.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: October 16, 2012
    Assignee: Cree, Inc.
    Inventors: Brian Thomas Collins, Jesse Colin Reiherzer, Florin A. Tudorica