Inorganic Luminescent Compositions Patents (Class 252/301.4R)
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Patent number: 8287760Abstract: A light-emitting apparatus composed of a light source that emits primary light and a phosphor that absorbs the primary light and emits secondary light offers high brightness, low power consumption, and a long lifetime while minimizing adverse effects on the environment. The phosphor is formed of a III-V group semiconductor in the form of fine-particle crystals each having a volume of 2 800 nm3 or less. The light emitted from the fine-particle crystals depends on their volume, and therefore giving the fine-particle crystals a predetermined volume distribution makes it possible to adjust the wavelength range of the secondary light.Type: GrantFiled: February 22, 2010Date of Patent: October 16, 2012Assignee: Sharp Kabushiki KaishaInventors: Masaya Ishida, Tatsuya Morioka, Daisuke Hanaoka, Mototaka Taneya, Shigeo Fujita, Yoichi Kawakami, Masafumi Harada, Takatomo Sasaki, Yusuke Mori
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Publication number: 20120235094Abstract: A silica nanofiber/metal oxide nanocrystal composite is produced by a method including associating a polymer having a linear polyethyleneimine skeleton in a water-based medium in the presence of ice, adding alkoxysilane to the water-based medium obtained in the above step to form a composite nanofiber including the associate and silica that covers the associate, while the fiber spontaneously forms a disc-shaped network structure, a step of depositing a metal oxide on a surface of the fiber by mixing the disc-shaped structure obtained in the above step with a hydrolyzable metal compound, and a step of calcining the disc-shaped. structure obtained in the step above to form a silica nanofiber through removal of the polymer in the fiber, to convert the metal oxide into a nanocrystal, and to bond the nanocrystal to the fiber. When zinc oxide is used as the metal oxide, the composite functions as a luminous body.Type: ApplicationFiled: November 29, 2010Publication date: September 20, 2012Applicants: DIC Corporation, Kawamura Institute of Chemical ResearchInventors: Pei-Xin Zhu, Ren-Hua Jin
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Publication number: 20120235093Abstract: Borate luminous material is provided, wherein, comprises the compound of following structural formula: M2(Re1?xLnx)2B2O7, wherein x is in a range of 0<x?0.5, M is alkali metal element, Ln is at least one of Tm, Tb, Eu, Sm, Pr, Dy, Ce and Bi, Re is selected from one or more element of Y, Gd, Sc, Lu and La. The preparation method of borate luminous material also is provided. The borate luminous material has the advantages of good stability, high luminescence efficiency and high color purity.Type: ApplicationFiled: December 4, 2009Publication date: September 20, 2012Inventors: Mingjie Zhou, Chaopu Shi, Rong Wang, Wenbo Ma
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Patent number: 8268192Abstract: A blue phosphor, a display device including the same, and associated methods, the blue phosphor including BaMgAl10O17:Eu (BAM) phosphor particles having a surface component and an internal component, wherein an aluminum/barium (Al/Ba) molar ratio of the surface component of the phosphor particles is 1.1 to about 1.4 times the Al/Ba molar ratio of the internal component of the phosphor particles, and the Al/Ba molar ratios are continuously variable between the internal component and the surface component.Type: GrantFiled: July 31, 2009Date of Patent: September 18, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Ick-Kyu Choi, Yoon-Chang Kim, Do-Hyung Park, Mi-Ran Song, Hyun-Deok Lee, Ji-Hyun Kim, Yu-Mi Song, Jay-Hyok Song, Young-Hun Lee, Min-Ju Kim, Jin-Hyoung Seo, Young-Ki Kim
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Publication number: 20120228551Abstract: ?-Sialon comprising Eu2+ that is present in a solid solution form in P-sialon represented by Si6-zAlzOzN ?m [wherein z is 0.3-1.5], which shows, when excited with light of 450 nm in wavelength, a peak wavelength of fluorescent spectrum of 545-560 nm, a half-value breadth of 55 nm or greater, and an external quantum efficiency of 45% or greater. The p-sialon can be produced by blending at least one kind of oxide selected from aluminum oxide and silicon oxide with silicon nitride and aluminum nitride in such a manner as to give z of 0.3-1.5, further adding thereto a europium compound and a ?-sialon powder having an average particle diameter of 5 ?m or greater and an average degree of circularity of 0.7 or greater, each in a definite amount, and baking the mixture.Type: ApplicationFiled: November 4, 2010Publication date: September 13, 2012Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Hideyuki Emoto, Kazuhiro Ito
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Patent number: 8262936Abstract: A phosphor is formed with a glass coating layer on a surface of a phosphor grain to have improved moisture and/or thermal stability. A method for manufacturing the phosphor comprises preparing phosphor gains excitable by light, and forming a glass coating layer on a surface of each phosphor grain. The glass coating layer may be formed by mixing the phosphor grains with a glass composition; heat-treating a mixture of the phosphor grains and the glass composition to make the glass composition melt and surround the phosphor grains; and cooling and breaking the heat-treated mixture to provide phosphors, each comprising the phosphor grain having the glass coating layer formed on a surface of the phosphor grain.Type: GrantFiled: September 16, 2010Date of Patent: September 11, 2012Assignee: Seoul Semiconductor Co., Ltd.Inventors: Kyung Nam Kim, Tomizo Matsuoka, Mi Youn Chang
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Patent number: 8257612Abstract: The present invention relates to a composition having a first response to a first electromagnetic radiation and, after intermediate exposure to a second electromagnetic radiation, a second response to the first electromagnetic radiation, different from the first response. In one aspect, the composition exhibits a regenerated first response to the first electromagnetic radiation after exposure to a third electromagnetic radiation.Type: GrantFiled: July 5, 2007Date of Patent: September 4, 2012Assignee: Cabot CorporationInventors: Mark J. Hampden-Smith, Liam Noailles, Richard Einhorn
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Patent number: 8252203Abstract: A luminescent material is disclosed. The luminescent material may include a first compound having a host lattice comprising first ions and oxygen. A first portion of the first ions may be substituted by copper ions. In one embodiment, the host lattice may include silicon, the copper ions may be divalent copper ions and the first compound may have an Olivine crystal structure, ?-K0.2SO4 crystal structure, a trigonal Glaserite (K3Na(SO4)2) or monoclinic Merwinite crystal structure, a tetragonal Ackermanite crystal structure, a tetragonal crystal structure or an orthorhombic crystal structure. In another embodiment, the copper ions do not act as luminescent ions upon excitation with the ultraviolet or visible light.Type: GrantFiled: May 3, 2011Date of Patent: August 28, 2012Assignee: Seoul Semiconductor Co., Ltd.Inventors: Gundula Roth, Walter Tews, Chung Hoon Lee
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Publication number: 20120211700Abstract: Provided is a production method of a ?-type sialon fluorescent substance, where luminescence intensity can be improved without adding a metal element other than elements composing a ?-type sialon fluorescent substance. Namely, in a production method of a fluorescent substance containing an optically-active element as the luminescence center in a crystal of nitride or acid nitride, a ?-type sialon fluorescent substance is produced by a burning process for heat-treating a mixture including metal compound powder and an optically-active element compound; a high-temperature annealing process for heat-treating the burned product after cooling under a nitrogen atmosphere; a rare-gas annealing process for heat-treating the high-temperature annealed product under a rare gas atmosphere; and a process for treating the rare-gas treated product with an acid.Type: ApplicationFiled: October 27, 2010Publication date: August 23, 2012Inventors: Masayoshi Ichikawa, Hironori Nagasaki
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Publication number: 20120199792Abstract: The object of the invention is to increase the yield of the HPHT—(High-Pressure High-Temperature)—Technology for production of synthetic diamonds and diamond-like materials as well as to achieve the continuous production of large amounts or quantities of synthetic diamonds with perfect or high quality. The object of the invention will be reached by methods and devices according to the present invention, wherein the method comprises the following steps: cultivation or collection of biomass, preparing and chemical modification of biomass preferably by (adding or enriching with) salt or salts containing at least one catalyst, incineration of biomass to ash, adding to ash modifiers including salt or salts containing at least one catalyst, HPHT-treatment of the resulting carbon-containing matrix and the isolation of the products after the HPHT-treatment.Type: ApplicationFiled: February 1, 2012Publication date: August 9, 2012Inventor: Alexander Cherkasky
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Publication number: 20120199793Abstract: Layers of a passivating material and/or containing luminescent centers are deposited on phosphor particles or particles that contain a host material that is capable of capturing an excitation energy and transferring it to a luminescent center or layer. The layers are formed in an ALD process. The ALD process permits the formation of very thin layers. Coated phosphors have good resistance to ambient moisture and oxygen, and/or can be designed to emit a distribution of desired light wavelengths.Type: ApplicationFiled: April 23, 2012Publication date: August 9, 2012Inventors: Alan W. Weimer, Steven M. George, Koron J. Buochler, Joseph A. Spencer, II, Jarod McCormick
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Patent number: 8236200Abstract: A transparent, nano-composite material and methods for making structures from this material are provided. In one embodiment, the material is made from a polycrystalline matrix containing dispersed particles of a harder material. The particles are less then about 100 nm. In other embodiments, methods for making structures from the material are provided. In one aspect, the methods include blending precursor powders for the matrix and reinforcing phases prior to forming and sintering to make a final structure. In other aspects, a precursor powder for the matrix is pressed into a green shape, which is partially sintered and exposed to a solution containing a precursor for the reinforcing phase, prior to be sintered into the final material. In another aspect, the precursor powder for the matrix is coated with a sol-gel precursor for the reinforcing material, then pressed into a green shape and sintered to form the final structure.Type: GrantFiled: December 6, 2006Date of Patent: August 7, 2012Assignee: General Electric CompanyInventors: Sean Michael Sweeney, Sergio Martins Loureiro, Timothy Yosenick
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Patent number: 8221650Abstract: An oxide phosphor that is highly durable and produces visible light when excited by exposure to near-ultraviolet excitation light, comprising an oxide having the composition represented by the formula (Al2O3)x.(SiO2)1-x, where 0<x<1, and an activating element M.Type: GrantFiled: March 17, 2009Date of Patent: July 17, 2012Assignee: Shibaura Institute of TechnologyInventor: Masato Ota
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Patent number: 8221651Abstract: Nanoparticles having a core/shell structure consisting of a core comprising a Group III element and a Group V element at a molar ratio of the Group III element to the Group V element in the range of 1.25 to 3.0, and a shell comprising a Group II element and a Group VI element and having a thickness of 0.2 nm to 4 nm, the nanoparticles having a photoluminescence efficiency of 10% or more and a diameter of 2.5 to 10 nm; a method of producing the water-dispersible nanoparticles and a method of producing a glass matrix having the nanoparticles dispersed therein.Type: GrantFiled: April 21, 2009Date of Patent: July 17, 2012Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Norio Murase, Chunliang Li, Masanori Ando
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Patent number: 8221649Abstract: A light-emitting device is produced using a phosphor composition containing a phosphor host having as a main component a composition represented by a composition formula: aM3N2.bAlN.cSi3N4, where “M” is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, and “a”, “b”, and “c” are numerical values satisfying 0.2?a/(a+b)?0.95, 0.05?b/(b+c)?0.8, and 0.4?c/(c+a)?0.95. This enables a light-emitting device emitting white light and satisfying both a high color rendering property and a high luminous flux to be provided.Type: GrantFiled: April 8, 2008Date of Patent: July 17, 2012Assignee: Panasonic CorporationInventor: Shozo Oshio
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Publication number: 20120175559Abstract: Phosphor particles are provided in the form of spherical polycrystalline secondary particles consisting of a multiplicity of primary particles, including a garnet phase having the composition: (AxByCz)3C5O12 wherein A is Y, Gd, and/or Lu, B is Ce, Nd, and/or Tb, C is Al and/or Ga, and x, y and z are in the range: 0.002<y?0.2, 0 <z?2/3, and x+y+z=1. The phosphor particles are prepared by granulating powder oxides containing one or more of the elements A, B, and C, melting the granules in a plasma and solidifying outside the plasma, and heat treating the resulting particles in a non-oxidizing atmosphere at a temperature of higher than 800° C. to 1,700° C.Type: ApplicationFiled: December 23, 2011Publication date: July 12, 2012Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Toshihiko Tsukatani, Kazuhiro Wataya, Yasushi Takai, Takehisa Minowa
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Publication number: 20120175558Abstract: The invention relates to a process for preparing porous glass particles suitable for use as precursor materials for production of an opto-ceramic element. The process comprises: providing particles of a soluble glass composition comprising at least one soluble component, at least one component having low solubility in an aqueous solution, and at least one lasing dopant which also has a low solubility in the aqueous solution; and immersing the particles in an aqueous solution having low solubility for said at least one component and said at least one lasing dopant, to thereby dissolve substantially all of the soluble portions of the glass particles.Type: ApplicationFiled: July 25, 2007Publication date: July 12, 2012Inventors: Samuel David Conzone, Carol Click
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Publication number: 20120168678Abstract: Provided is a phosphor for scintillator that can absorb radiation and convert it into visible light, and which has a short fluorescence decay time. The phosphor contains a lutetium sulfide-containing host material and an activator agent ion, for example, a phosphor comprising a composition represented by the general formula (Lu1-xPrx)2S3, or (Lu1-xCex)2S3.Type: ApplicationFiled: August 9, 2010Publication date: July 5, 2012Applicant: MITSUI MINING & SMELTING CO., LTD.Inventors: Tsukasa Takahashi, Motoyuki Tanaka, Shunichi Hatamoto, Hiromu Watanabe
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Patent number: 8206613Abstract: Disclosed is a phosphor composite material which can be fired at low temperatures and enables to obtain a phosphor composite member which is excellent in weather resistance and reduced in deterioration after long use. Also disclosed is a phosphor composite member obtained by firing such a phosphor composite material. Specifically disclosed is a phosphor composite material composed of a glass powder and a phosphor powder, which is characterized in that the glass powder is composed of SnO—P2O5—B2O3 glass.Type: GrantFiled: May 15, 2007Date of Patent: June 26, 2012Assignee: Nippon Electric Glass Co., Ltd.Inventors: Shunsuke Fujita, Yoshio Umayahara, Masaru Iwao, Takemi Kikutani
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Publication number: 20120145962Abstract: In an embodiment, a solid state scintillator material includes a composition represented by a general formula: (Gd1-?-?-?TB?Lu?Ce?)3(Al1-xGax)aOb, where ? and ? are numbers satisfying 0<??0.5, 0<??0.5, and ?+??0.85, ? is a number satisfying 0.0001???0.1, x is a number satisfying 0<x<1, a is a number satisfying 4.8?a?5.2 and b is a number satisfying 11.6?b?12.4 (atomic ratio), and a garnet structure.Type: ApplicationFiled: February 21, 2012Publication date: June 14, 2012Inventors: Yukihiro Fukuta, Takao Sawa, Makoto Hayashi
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Publication number: 20120138856Abstract: A phosphor composition comprises a host lattice, a dopant and a decay modifying component different from the dopant and the host lattice and effective to alter the rate of decay of the radiation emitted by the phosphor composition in response to excitation by photons of a given energy. The decay modifying component is added to the phosphor composition in a predetermined amount between 1 and 10,000 parts per million of the composition. By varying the amount of the decay modifying component added to the phosphor composition, it is possible to produce a set of phosphor compositions with different, controlled rates of decay of the radiation emitted by the compositions.Type: ApplicationFiled: July 1, 2010Publication date: June 7, 2012Applicant: CABOT CORPORATIONInventors: Scott Haubrich, Jainisha Shah, Liam Noailles, Gary Darsey, Richard Einhorn, James Brewster
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Publication number: 20120132856Abstract: The present invention relates to oxide luminescent materials activated by trivalent thulium and their preparations. The luminescent materials are the compounds with the following general formula: (RE1-xTmx)2O3, wherein a range of x is 0<x?0.05 and RE is one or two selected from Y, Gd, La, Lu and Sc. These materials are Prepared by Sol-Gel Method or high temperature solid phase method using metal oxide of Tm3+, chloride of Tm3+, nitrate of Tm3+, carbonate of Tm3+ or oxalate of Tm3+, and one or two of oxide Y3+, Gd3+, La3+, Lu3+ or Sc3+, chloride Y3+, Gd3+, La3+, Lu3+ or Sc3+, nitrate Y3+, Gd3+, La3+, Lu3+ or Sc3+, carbonate Y3+, Gd3+, La3+, Lu3+ or Sc3+ and oxalate of Y3+, Gd3+, La3+, Lu3+ or Sc3+ as raw material. The present oxide luminescent materials activated by trivalent thulium have high stability, color purity and luminous efficiency, and the methods can easily be operated.Type: ApplicationFiled: March 6, 2009Publication date: May 31, 2012Inventors: Mingjie Zhou, Wenbo Ma, Zhaopu Shi
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Patent number: 8187496Abstract: A method for preparing a metal oxide phosphor contemplates preparing a solution including a metal precursor compound and an ionic material and heating the solution under pressure using microwaves.Type: GrantFiled: April 13, 2009Date of Patent: May 29, 2012Assignee: Samsung Mobile Display Co., Ltd.Inventors: Hyun-Sik Kim, Soon-Jae Kwon, Soo-Yeon Seo
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Patent number: 8187497Abstract: Disclosed are a phosphor, method for preparing the same, and light emitting diode using the same. The method comprises the steps of preparing a precursor solution by mixing strontium nitrate (Sr(NO3)2), tetraethyl orthosilicate (TEOS), and europium oxide (Eu) with each other, forming a gel by heating the precursor solution, drying the gel specimen, performing calcination by removing water and organic materials from the dried gel, and preparing a phosphor by reducing the Eu of the gel.Type: GrantFiled: January 21, 2008Date of Patent: May 29, 2012Assignee: LG Innotek Co., Ltd.Inventor: Joong In An
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Patent number: 8187498Abstract: A phosphor is formed with a glass coating layer on a surface of a phosphor grain to have improved moisture and/or thermal stability. A method for manufacturing the phosphor comprises preparing phosphor gains excitable by light, and forming a glass coating layer on a surface of each phosphor grain. The glass coating layer may be formed by mixing the phosphor grains with a glass composition; heat-treating a mixture of the phosphor grains and the glass composition to make the glass composition melt and surround the phosphor grains; and cooling and breaking the heat-treated mixture to provide phosphors, each comprising the phosphor grain having the glass coating layer formed on a surface of the phosphor grain.Type: GrantFiled: September 16, 2010Date of Patent: May 29, 2012Assignee: Seoul Semiconductor Co., Ltd.Inventors: Kyung Nam Kim, Tomizo Matsuoka, Mi Youn Chang
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Publication number: 20120126173Abstract: The invention relates to luminous substances which contain Eu2+ doping and at least one silicate mineral from the garnet group and/or a mono and/or polycrystalline yttrium-aluminum garnet (YAG) and/or a luminous substance derived from Y2Al5O12 by partial or complete substitution, and to the production and use thereof.Type: ApplicationFiled: May 7, 2010Publication date: May 24, 2012Inventor: Peter Nass
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Publication number: 20120119147Abstract: A transparent polycrystalline ceramic having scattering and absorption loss less than 0.2/cm over a region comprising more than 95% of the originally densified shape and a process for fabricating the same by hot pressing. The ceramic can be any suitable ceramic such as yttria (Y2O3) or scandia (Sc2O3) and can have a doping level of from 0 to 20% and a grain size of greater than 30 although the grains can also be smaller than 30 ?m. Ceramic nanoparticles can be coated with a sintering aid to minimize direct contact of adjacent ceramic powder particles and then baked at high temperatures to remove impurities from the coated particles. The thus-coated particles can then be densified by hot pressing into the final ceramic product. The invention further provides a transparent polycrystalline ceramic solid-state laser material and a laser using the hot pressed polycrystalline ceramic.Type: ApplicationFiled: January 13, 2012Publication date: May 17, 2012Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Jasbinder S. Sanghera, Guillermo R. Villalobos, Woohong Kim, Shyam S. Bayya, Bryan Sadowski, Jesse A. Frantz, Leslie Brandon Shaw, Ishwar D. Aggarwal
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Publication number: 20120119148Abstract: Disclosed herein is a method of increasing the luminescence efficiency of a translucent phosphor ceramic. Other embodiments are methods of manufacturing a phosphor translucent ceramic having increased luminescence. Another embodiment is a light emitting device comprising a phosphor translucent ceramic made by one of these methods.Type: ApplicationFiled: January 25, 2012Publication date: May 17, 2012Applicant: NITTO DENKO CORPORATIONInventors: Hiroaki Miyagawa, Toshitaka Nakamura, Hironaka Fujii, Amane Mochizuki
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Publication number: 20120119146Abstract: A transparent polycrystalline ceramic having scattering and absorption loss less than 0.2/cm over a region comprising more than 95% of the originally densified shape and a process for fabricating the same by hot pressing. The ceramic can be any suitable ceramic such as yttria (Y2O3) or scandia (Sc2O3) and can have a doping level of from 0 to 20% and a grain size of greater than 30 ?m, although the grains can also be smaller than 30 ?m. Ceramic nanoparticles can be coated with a sintering aid to minimize direct contact of adjacent ceramic powder particles and then baked at high temperatures to remove impurities from the coated particles. The thus-coated particles can then be densified by hot pressing into the final ceramic product. The invention further provides a transparent polycrystalline ceramic solid-state laser material and a laser using the hot pressed polycrystalline ceramic.Type: ApplicationFiled: January 13, 2012Publication date: May 17, 2012Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Jasbinder S. Sanghera, Guillermo R. Villalobos, Woohong Kim, Shyam S. Bayya, Bryan Sadowski, Jesse A. Frantz, Leslie Brandon Shaw, Ishwar D. Aggarwal
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Patent number: 8173043Abstract: The present invention provides a fluorescent substance composite glass which is chemically stable, has a large size, is reduced in wall thickness, has a uniform thickness and therefore has a high energy conversion efficiency; a fluorescent substance composite glass green sheet and a process for producing the fluorescent substance composite glass. The fluorescent substance composite glass of the present invention is produced by baking a mixture containing a glass powder and an inorganic fluorescent substance powder, in which the energy conversion efficiency to a visible light wavelength region of 380 to 780 nm is 10% or more, when light having an emission peak in a wavelength range of 350 to 500 nm is applied.Type: GrantFiled: April 25, 2011Date of Patent: May 8, 2012Assignee: Nippon Electric Glass Co., Ltd.Inventors: Masaru Iwao, Yoshio Umayahara
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Patent number: 8163203Abstract: A Ce3+ based aluminate phosphor or Ce3+ based phosphor in a solid solution can be used for white light generation when combined with a blue or ultraviolet light emitting diode.Type: GrantFiled: February 27, 2009Date of Patent: April 24, 2012Assignee: The Regents of the University of CaliforniaInventors: Won-bin Im, Ram Seshadri, Steven P. DenBaars
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Patent number: 8158028Abstract: This invention relates to luminescent materials for ultraviolet light or visible light excitation containing lead and/or copper doped chemical compounds. The luminescent material is composed of one or more than one compounds of aluminate type, silicate type, antimonate type, germanate/or germanate-silicate type, and/or phosphate type. Accordingly, the present invention is a good possibility to substitute earth alkaline ions by lead and copper for a shifting of the emission bands to longer or shorter wave length, respectively. Luminescent compounds containing copper and/or lead with improved luminescent properties and also with improved stability against water, humidity as well as other polar solvents are provided. The present invention is to provide lead and/or copper doped luminescent compounds, which has high color temperature range about 2,000K to 8,000K or 10,000K and CRI over 90.Type: GrantFiled: January 11, 2011Date of Patent: April 17, 2012Assignee: Seoul Semiconductor Co., Ltd.Inventors: Gundula Roth, Walter Tews, Chung Hoon Lee
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Patent number: 8158025Abstract: A phosphor composition including a first phosphor represented by Formula 1: Ba1-bMg1-aAl10O17:Mna,Eub??(1). In Formula 1, a and b satisfy the relations: 0.05?a?0.4, and 0.006?b<0.05.Type: GrantFiled: February 4, 2009Date of Patent: April 17, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Gyeong-Jae Heo, Mi-Ran Song, Young-Hun Lee, Yoon-Chang Kim, Yong-Chan You, Do-Hyung Park, Hyun-Deok Lee, Seon-Young Kwon, Ji-Hyun Kim, Ick-Kyu Choi, Ji-Hyun Kim, Yu-Mi Song, Jay-Hyok Song, Min-Ju Kim, Sun-Hwa Kwon, Young-Ki Kim
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Patent number: 8153025Abstract: The invention relates to an improved red light emitting material of the formula M1?yA1+xSi4?xN7?x?2yOx+2y:RE whereby M is selected out of the group comprising Ba, Sr, Ca, Mg or mixtures thereof, A is selected out of the group comprising Al, Ga, B or mixtures thereof, RE is selected out of the group comprising rare earth metals, Y, La, Sc or mixtures thereof and x is ?0 and ?1 and y is ?0 and ?0.2. This material is believed to crystallize in a novel structure type that comprises two individual lattice sites for rare 10 earth metal incorporation, which leads to an improved lighting behavior.Type: GrantFiled: January 31, 2008Date of Patent: April 10, 2012Assignee: Koninklijke Philips Electronics N.V.Inventors: Peter J. Schmidt, Walter Mayr, Joerg Meyer, Wolfgang Schnick, Cora Sieglinde Hecht, Florian Stadler
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Patent number: 8147716Abstract: A red phosphor includes yttrium (Y), gadolinium (Gd), an alkaline-earth metal element, and europium (Eu). A plasma display panel (PDP) includes the red phosphor.Type: GrantFiled: December 3, 2010Date of Patent: April 3, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Young-Ki Kim, Ick-Kyu Choi, Jay-Hyok Song, Yu-Mi Song, Young-Hun Lee, Min-kyu Kim, Soon-Rewl Lee, Yoon-Chang Kim, Dong-Sik Zang
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Patent number: 8142685Abstract: A blue fluorescent material having excellent durability and a high luminance, especially one emitting a high-luminance light by the action of electron rays. The fluorescent material comprises inorganic crystals having a crystal structure which is an AlN crystalline, AlN polycrystalline, or AlN solid-solution crystalline structure. It is characterized in that the inorganic crystals contain at least europium in solution and have an oxygen content of 0.4 mass % or lower and that the fluorescent material emits fluorescence derived from divalent europium ions upon irradiation with an excitation source. More preferably, the fluorescent material contains a given metallic element and silicon. Also provided are a process for producing the fluorescent material and an illuminator including the blue fluorescent material.Type: GrantFiled: January 11, 2008Date of Patent: March 27, 2012Assignee: National Institute for Materials ScienceInventor: Naoto Hirosaki
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Patent number: 8137585Abstract: The phosphor composition including a first phosphor represented by Formula 1: Y3?x?kCekM?xAla?yM?yO(1.5a+4.5)??(1). In Formula 1, M? includes at least one of Sc, In, and La, M? includes at least one of Ga, Sc, and In, and x, y, k, and a satisfy the relations: 0.0?x<3.0, 0.0<y?7.0, 0.0<k<0.1, 4.0?a?7.0, a?y?0.0, and x+k?3.0.Type: GrantFiled: February 4, 2009Date of Patent: March 20, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Jay-Hyok Song, Yu-Mi Song, Yoon-Chang Kim, Do-Hyung Park, Yong-Chan You, Gyeong-Jae Heo, Ick-Kyu Choi, Mi-Ran Song, Seon-Young Kwon, Hyun-Deok Lee, Ji-Hyun Kim, Jin-Hyoung Seo, Sun-Hwa Kwon, Min-Ju Kim, Young-Hun Lee, Young-Ki Kim
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Patent number: 8137587Abstract: Disclosed herein is a method of increasing the luminescence efficiency of a translucent phosphor ceramic. Other embodiments are methods of manufacturing a phosphor translucent ceramic having increased luminescence. Another embodiment is a light emitting device comprising a phosphor translucent ceramic made by one of these methods.Type: GrantFiled: February 19, 2009Date of Patent: March 20, 2012Assignee: Nitto Denko CorporationInventors: Hiroaki Miyagawa, Toshitaka Nakamura, Hironaka Fujii, Amane Mochizuki
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Patent number: 8137588Abstract: Described herein are batches of nanoscale phosphor particles having an average particle size of less than about 200 nm and an average internal quantum efficiency of at least 40%. The batches of nanoscale phosphor particles can be substantially free of impurities. Also described herein are methods of manufacturing the nanoscale phosphor particles by passing phosphor particles through a reactive field to thereby dissociate them into elements and then synthesizing nanoscale phosphor particles by nucleating the elements and quenching the resulting particles.Type: GrantFiled: March 11, 2008Date of Patent: March 20, 2012Assignees: Nitto Denko Corporation, Regents of the University of MinnesotaInventors: Jami Hafiz, Toshitaka Nakamura, Steven L Girshick, Joachim V. R. Heberlein, Amane Mochizuki, Rajesh Mukherjee
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Publication number: 20120061615Abstract: A rare earth ion doped silicate luminescence glass and preparation method thereof are provided. The luminescence glass is the material with the following formula: aM2O.bM?2O3.cSiO2.dRE2O3, wherein M is at least one of Na, K and Li, M? is at least one of Y, Gd, La, Sc and Lu, RE is at least one of Ce, Tm, Tb, Ho, Dy, Er, Nd, Sm, Eu and Pr. The preparation method is: grinding the raw material until mixed uniformly, calcining the raw material at 1200-1500° C. for 1-5 h, cooling to room temperature, annealing at 600-1100° C. for 0.5-24 h, cooling to room temperature again, molding then getting the product. The performance of the product is stable. The product is homogenous, and the luminescence performance is good. The light transmittance is high. The process of the preparation method is simple and with low cost.Type: ApplicationFiled: May 19, 2009Publication date: March 15, 2012Applicant: OCEAN'S KING LIGHTING SCIENCE & TECHNOLOGY CO., LTD.Inventors: Mingjie Zhou, Wenbo Ma, Zhaopu Shi, Yanbo Qiao, Qingtao Li
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Patent number: 8128840Abstract: A phosphor composition for a display device, including a phosphor represented by Formula 1: Y3-x-k-zCekMzM?xAla-yM?yO(1.5a+4.5)??(1). In Formula 1, M includes at least one of Tb, Dy, and Eu, M? includes at least one of Sc, Gd, In, and La, M? includes at least one of Ga, Sc, and In, and x, y, z, k, and a represent molar ratios and satisfy the relations: 0.0?x<3.0, 0.0?y?7.0, 0.0<k<0.1, 0.0<z<0.5, 4.0?a?7.0, a-y?0.0, x+k+z?3.0, and 0.01?z/k?20.Type: GrantFiled: January 29, 2009Date of Patent: March 6, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Jay-Hyok Song, Yu-Mi Song, Yoon-Chang Kim, Do-Hyung Park, Yong-Chan You, Gyeong-Jae Heo, Ick-Kyu Choi, Mi-Ran Song, Seon-Young Kwon, Hyun-Deok Lee, Ji-Hyun Kim, Jin-Hyoung Seo, Sun-Hwa Kwon, Ji-Hyun Kim, Min-Ju Kim, Young-Hun Lee, Young-Ki Kim
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Patent number: 8128839Abstract: The present invention provide a high-luminosity stress-stimulated luminescent material which emits visible light even in daylight, a manufacturing method thereof, and a typical example of the use thereof. The stress-stimulated luminescent material of the present invention satisfies conditions for light emission by at least one of: a luminescence mechanism using static electricity caused by friction; a luminescence mechanism using micro plasma caused by friction; a luminescence mechanism using a piezoelectric effect caused by strain; a luminescence mechanism using lattice defect; and a luminescence mechanism using thermal generation. For example, in case where a base material made of at least one type of aluminate is includes as the stress-stimulated luminescent material, the base material includes a crystal structure with spontaneous polarization, e.g. ?-SrAl2O4, in order to realize the luminescence mechanism using the piezoelectric effect caused by strain.Type: GrantFiled: April 8, 2005Date of Patent: March 6, 2012Assignee: National Institute of Advanced Industrial Science & TechnologyInventor: Chao-Nan Xu
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Publication number: 20120049118Abstract: A polycrystalline ceramic scintillator body includes a ceramic scintillating material comprising an oxide of gadolinium (Gd) and a second rare earth element (Re). The ceramic scintillating material has a composition, expressed in terms of molar percentage of oxide constituents, that includes greater than fifty-five percent (55%) Gd2O3 and a minority percentage Of Re2O3. The ceramic scintillating material includes an activator.Type: ApplicationFiled: December 24, 2009Publication date: March 1, 2012Applicants: Centre National de La Recherche Scientifique, Saint-Gobain Ceramics & Plastics Inc.Inventors: Brian C. LaCourse, Anne B. Hardy, Hélène Loetitia Rétot, Qiwei Chen, Xiafeng Peng, Bruno Viana, Morteza Zandí
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Patent number: 8123981Abstract: One embodiment provides a method for fabricating a translucent phosphor ceramic compact comprising: heating a precursor powder to at least about 1000° C. under a reducing atmosphere to provide a pre-conditioned powder, forming an intermediate compact comprising the pre-conditioned powder and a flux material, and heating the intermediate compact under a vacuum to a temperature of at least about 1400° C. In another embodiment, the compact may be a cerium doped translucent phosphor ceramic compact comprising yttrium, aluminum, oxygen, and cerium sources. Another embodiment may be a light emitting device having the phosphor translucent ceramic provided as described herein.Type: GrantFiled: February 19, 2009Date of Patent: February 28, 2012Assignee: Nitto Denko CorporationInventors: Hiroaki Miyagawa, Toshitaka Nakamura, Hironaka Fujii, Amane Mochizuki
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Patent number: 8119027Abstract: A green phosphor represented by Formula (A1-xTbx)a(B1-yMny)bCcOb+1.5(a+c), wherein A includes La, and Yb and/or Gd, B includes at least one kind selected from Mg, Zn, Sc, V, Cr, Co, Ni, Cu, In, Zr, Nb, Ta, Mo, and Sn, C includes at least one selected from Al, B, Ga, Si, P, Ti, Fe, B, and Ge, 0?x?1, 0?y?1, 0.8?a?1.2, 0<b?1.5, 8?c?30, and having a magnetoplumbite type crystal structure.Type: GrantFiled: January 13, 2006Date of Patent: February 21, 2012Assignee: Hitachi Plasma Display LimitedInventors: Toshiaki Onimaru, Shinya Fukuta, Shigeo Kasahara
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Patent number: 8114311Abstract: A red phosphor, including a first phosphor represented by Formula 1 (Y1-x1Mx1)2-y1O3:Euy1??(1). In Formula 1, M includes at least one of Gd, La, Sc, and Lu, and x1 and y1 satisfy the relations: 0.00?x1?0.8 and 0.025?y1?0.20.Type: GrantFiled: January 29, 2009Date of Patent: February 14, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Jay-Hyok Song, Ji-Hyun Kim, Ji-Hyun Kim, Hyun-Deok Lee, Seon-Young Kwon, Gyeong-Jae Heo, Do-Hyung Park, Yoon-Chang Kim, Yu-Mi Song
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Publication number: 20120032114Abstract: A red phosphor includes yttrium (Y), gadolinium (Gd), an alkaline-earth metal element, and europium (Eu). A plasma display panel (PDP) includes the red phosphor.Type: ApplicationFiled: December 3, 2010Publication date: February 9, 2012Inventors: Young-Ki Kim, Ick-Kyu Choi, Jay-Hyok Song, Yu-Mi Song, Young-Hun Lee, Min-kyu Kim, Soon-Rewl Lee, Yoon-Chang Kim, Dong-Sik Zang
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Patent number: 8110124Abstract: To produce fluorescent bodies providing high brightness and high energy efficiency, a method of preparing a fluorescent body precursor is provided to enable an activator having a large ionic radius to be doped arbitrarily. The problems described above are solved by a method of preparing a fluorescent body precursor, which method is characterized by comprising applying a shock pressure of 0.1 GPa or higher to a mixture consisting essentially of a fluorescent body base, an activator and a co-activating particle-growth promoter to dope the activator into the fluorescent body base in the presence of the co-activating particle-growth promoter.Type: GrantFiled: July 26, 2007Date of Patent: February 7, 2012Assignee: Kuraray Co., Ltd.Inventors: Yoshihisa Tsuji, Hideharu Iwasaki
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Patent number: 8110123Abstract: A high-brightness yellow-orange yellow phosphor for use in warm white LED (light emitting diode), the high-brightness yellow-orange yellow phosphor comprises a substrate based on a rare-earth garnet and cerium for activating said substrate. The high-brightness yellow-orange yellow phosphor has the substances of Li+1, Mg+2 and N?3 contained therein so that the overall stoichiometric equation of the substrate is: ?(Ln)3Al5?xLi(x+y)Mg(x+y)O12?3yN3y and, the high-brightness yellow-orange yellow phosphor radiates in a visible orange yellow band at ?=538˜569 nm when activated by a shortwave light from an InGaN semiconductor heterostructure.Type: GrantFiled: October 20, 2008Date of Patent: February 7, 2012Inventors: Soshchin Naum, Wei-Hung Lo, Chi-Ruei Tsai
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Patent number: 8105502Abstract: A luminescent material is provided, which includes a carbide oxynitride-based compound having a composition represented by formula 1: (M1?wRw)uAl1?xSi1+vOzNtCy??formula 1 wherein M is at least one metal element excluding Si and Al, and R is a luminescent central element. w, u, x, v, z, t and y satisfy following relationships: 0.001<w<0.5; 0.66?u?1; 0.07?x?0.73; 0.06?v?0.84; 0.04?z?0.44; 2.7?t?3.1; and 0.019?y?0.13.Type: GrantFiled: September 17, 2008Date of Patent: January 31, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Yumi Fukuda, Jun-ichi Tatami, Hironori Asai, Katsutoshi Komeya, Naotoshi Matsuda, Toru Wakihara, Keiko Albessard, Shoko Abe