Nitrogen Organic Compound Containing Patents (Class 252/394)
  • Patent number: 6464763
    Abstract: A composition for use in forming a dry film coating on metal surfaces to at least temporarily protect the surfaces from oxidation comprises at least 20% by weight of a combination of at least one saturated linear carboxylic monoacid with at least one unsaturated linear carboxylic monoacid. The monoacids are in the form of alkaline, alkaline-earth or amine salts. The carbon chain of each acid comprises an uneven number of carbon atoms varying from 5 to 21. At least 0.5% by weight of a triazole derivative can be added to enhance the anti-corrosion effect. The composition is water-soluble and the dry protective film can be formed by diluting the composition in water, applying the diluted composition to a metal surface and then air drying it.
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: October 15, 2002
    Assignee: Elf Antar France
    Inventors: Pierre Steinmetz, Jacques Cotteret, Corinne Chauvineau
  • Patent number: 6464899
    Abstract: Compositions and methods for inhibiting corrosion of metallic surfaces are disclosed. The corrosion-inhibiting compositions are cost efficient, easy to use and can be conveniently removed or replaced. The corrosion-inhibiting compositions include a putty-like base material that is pliable and has sufficient tackiness to be securely affixed to surfaces. Corrosion inhibiting compounds are combined with the base material. These compositions provide a vapor phase corrosion inhibitor for both direct and indirect contact with metallic objects.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: October 15, 2002
    Assignee: Henkel Loctite Corporation
    Inventors: Hans E. Haas, Matthew P. Burdzy
  • Patent number: 6464901
    Abstract: Non-halogen substituted, nitrogen containing, aromatic compounds are disclosed which are effective copper corrosion inhibitors in aqueous systems being treated with a halogen biocide. The materials of the present invention exhibit copper corrosion inhibition comparable to tolyltriazole in the absence of halogen, copper corrosion rates of less than about 2.5 mills per year in aqueous systems where halogen is present; and do not exhibit a detrimental effect on halogen demand in an aqueous system being treated.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: October 15, 2002
    Inventor: Longchun Cheng
  • Patent number: 6458320
    Abstract: This invention relates to a galvanized metal, typically steel, corrosion inhibitor concentrate comprising (a) an amine salt of a fatty acid or an amine salt of a derivative of a fatty acid, (b) preferably a salt of a non polymeric aromatic acid, and (c) preferably a nonionic or anionic surfactant, and water. The invention also relates to a process for inhibiting corrosion and/or stripping of galvanized steel subjected to acidic conditions, e.g. an amine citrate or citric acid cleaning solution.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: October 1, 2002
    Assignee: Ashland Inc.
    Inventors: Bruce L. Libutti, Joseph Mihelic
  • Patent number: 6432355
    Abstract: Described herein is a process of corrosion inhibition of a steel pipeline during transport of water and gas, or water and an oil, or mixtures thereof, therethrough, including introducing a copolymer of vinyl caprolactam and vinylpyridine into said pipeline.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: August 13, 2002
    Assignee: ISP Investments Inc.
    Inventors: Kirill N. Bakeev, Jui-Chang Chuang, Thomas Winkler, Michael A. Drzewinski, David E. Graham
  • Patent number: 6419857
    Abstract: A novel composition of thiazolidines of the following formula and a method to prepare the same are disclosed. The method involves reacting a dihydrothiazole with a mixture comprising formic acid and an aldehyde. These new thiazolidines are useful as corrosion inhibitors.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: July 16, 2002
    Assignee: Baker Hughes Incorporated
    Inventors: Bernardus Antonius Maria Oude Alink, Benjamin T. Outlaw
  • Publication number: 20020063241
    Abstract: Drag reducers having the formula: 1
    Type: Application
    Filed: September 11, 2001
    Publication date: May 30, 2002
    Inventors: Bernardus Antonius Maria Oude Alink, Vladimir Jovancicevic
  • Patent number: 6391257
    Abstract: This invention relates to antifreeze compositions comprising a mixture of organic acid corrosion inhibitors. The compositions comprise (a) from about 90% to about 99.89% by weight of a liquid alcohol which functions as a freezing point depressant, or mixture thereof; (b) from about 0.1% to about 5.5% by weight of a carboxylic acid selected from the group consisting of saturated and unsaturated aliphatic, and aromatic, mono-, di- and tri-carboxylic acids, and salts and isomers thereof, and any mixture thereof, and (c) from about 0.1% to about 2% by weight of a cyclohexenoic acid, or salt, isomer or mixture thereof, having the formula: wherein each of R1, R2 and R3 is, independently, selected from the group consisting of H, OH, COOH, C1-C10 alkyl groups, glycol esters, or combinations thereof.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: May 21, 2002
    Assignee: Prestone Products Corporation
    Inventor: Peter M. Woyciesjes
  • Patent number: 6372918
    Abstract: The invention relates to compounds of the formula 1 R1—O—(A—O)x—(CH2)y—R2  (1) in which R1 is branched or straight-chain C4-C30-alkyl, C4-C30-alkenyl or C4-C30-alkylaryl, A is C2-C4-alkylene, x is an integer from 1 to 100, y is 1, 2, 3 or 4 and R2 is a radical selected from structures of the formulae 2 and 3 —CO—NR3R4  (2) in which one of the radicals R3 and R4 is a hydrocarbon chain which has at least one free NH or NH2 group and the other radical is hydrogen or a hydrocarbon chain which has at least one free NH or NH2 group and R5 is hydrogen or a hydrocarbon chain which has at least one free NH or NH2 group.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: April 16, 2002
    Assignee: Clariant GmbH
    Inventors: Michael Feustel, Peter Klug
  • Patent number: 6362137
    Abstract: This invention relates to a cost effective process for preparing a corrosion inhibitor/metal passivator additive for lubricant, grease and fuel applications from waste refinery streams, comprising reacting 2,5-dimercapto-1,3,4-thiadiazole either in powder form or in solution form in polar organic solvent, with disulphide oil obtained from Merox extraction/caustic wash of the refinery streams, in the presence or absence of redox agent.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: March 26, 2002
    Assignee: Indian Oil Corporation
    Inventors: Akhilesh Bhatnagar, Deepak Kumar Tuli, Rakesh Sarin, Ajay Arora, Pankaj Kumar Mandal
  • Patent number: 6350395
    Abstract: A stabilizer composition comprising a) an N-alkyl morpholine and b) a straight-chain or cyclic aliphatic amine containing no hetroatoms other than N with a boiling point of at least 150° C. The stabilizer composition is useful for stabilizing a halogenated hydrocarbon against degradation.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: February 26, 2002
    Assignee: The Dow Chemical Company
    Inventor: Marius Kuemin
  • Patent number: 6340438
    Abstract: A corrosion inhibiting admixture for concrete is disclosed comprising a combination of organic (amines) and inorganic (nitrites) fractions that provide a synergistic effect when present at a specific ratio. Such a synergistic effect occurs when the amine:nitrite ratio (% by weight) is between 1.5 to 2.5 resulting in the admixture providing excellent corrosion inhibiting capabilities.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: January 22, 2002
    Assignee: Tomahawk, Inc.
    Inventors: Donald R. Lane, Jose A. Melendez, Violeta F. Munteanu, Frederick D. Kinney
  • Patent number: 6306201
    Abstract: This invention relates to a bivalent iron compound comprising a bivalent iron salt, an amino acid and a reducing material. It is known that bivalent iron salts exhibit specific effects in wide applications, for example, agricultural applications such as modification of soil quality, fishing applications such as quality preservation of fishes, medical applications such as treatment of diseases and industrial applications such as prevention of metal corrosion and purification of waste water and exhaust gas. However, the conventional bivalent iron salts suffer a problem that they cannot exhibit such effect for extended periods. This invention was successful in chemically stabilizing the bivalent iron salts by adding amino acids and reducing materials so as to sustain the effects inherent in the bivalent iron salts and to enable utilization thereof in industrial applications.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: October 23, 2001
    Assignee: I.B.E. Company, Ltd.
    Inventor: Shinzi Makino
  • Patent number: 6303079
    Abstract: The present invention relates to a process for making and a method for using a corrosion inhibitor composition to reduce the corrosion rate of a metal by a fluid containing a corrosion agent. The corrosion inhibitor composition comprises at least a quaternized compound having an amido moiety. An example of the quaternized compound is a quaternized amido imidazoline.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: October 16, 2001
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventor: George Richard Meyer
  • Patent number: 6299836
    Abstract: Corrosion in aqueous alkanolamine, physical solvents, or combination of alkanolamine and physical solvent solutions used to remove acid gases from natural gas, synthetic gas, or light hydrocarbon streams can be reduced by addition of mixtures of oxygen scavengers or mixtures of oxygen scavengers and sodium molybdate. The oxygen scavengers must be promoted to reduce metal surfaces in contact with the solutions to a more passive, harder, and insoluble form at the operating temperature of the treating system. The sodium molybdate provides additional passivation especially in the imperfections on the surface of the metal where corrosion accelerates.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: October 9, 2001
    Assignee: Coastal Chemical Co., L.L.C. (A Louisiana limited liability company)
    Inventors: Ray R. Veldman, David O. Trahan
  • Publication number: 20010011515
    Abstract: An anticorrosive agent containing, as essential components, (a) urea or a urea derivative and (b) a hydroxy aromatic compound.
    Type: Application
    Filed: January 25, 2001
    Publication date: August 9, 2001
    Applicant: NEC Corporation
    Inventors: Hidemitsu Aoki, Tatsuya Koito, Kenichi Nakabeppu
  • Patent number: 6261346
    Abstract: A process useful for protecting metal surfaces against corrosion in is presented involving: (a) forming a corrosion inhibitor having a compound corresponding to formula (I): where R1, R2 and R3 independently of one another represent an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms, an aryl or alkylaryl group or a group corresponding to formula (II): A− is an anion, n is the number 2 or 3, p is a number of 1 to 3 and R5 is an alkyl or alkenyl group containing 7 to 23 carbon atoms and 0, 1, 2 or 3 double bonds, and R4 is a group corresponding to formula (II) or (III): where R1, R2 and R3 are as defined above and Z is a group —(CH2)m— or a group corresponding to formula (IV):  m is an integer of 1 to 6, X is a group NH or an oxygen atom and D is a dimer fatty acid residue containing on average 36 to 54 carbon atoms; (b) combining the corrosion inhibitor with liquid aqueous, liquid non-aqueous or gaseous me
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: July 17, 2001
    Assignee: Cognis Deutschland GmbH
    Inventors: Wolfgang Breuer, Robert Schuetz, Guenther Uphues, Claus-Peter Herold, Rafael Pi
  • Patent number: 6238621
    Abstract: There are disclosed corrosion inhibiting compositions comprising (a) at least one amido acid or salt thereof and (b) at least one of an aryltriazole or 3-amino-1,2,4-triazole wherein the molar ratio of (a) to (b) is about 0.34:1 to about 5:1, and aqueous metal working fluids containing the corrosion inhibiting compositions of the invention.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: May 29, 2001
    Assignee: Solutia Inc.
    Inventors: Dennis J. Kalota, Yueting Chou, David C. Silverman
  • Patent number: 6180057
    Abstract: Corrosion inhibiting compositions and methods for inhibiting the corrosion of metal surfaces by corrosive aqueous fluids are provided. In accordance with the invention, a corrosion inhibiting composition comprised of one or more aldehyde oligomers having the general formula are combined with the corrosive aqueous fluid.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: January 30, 2001
    Assignees: Nalco/Exxon Energy Chemicals L.P., Halliburton Energy Services, Inc.
    Inventors: Grahame N. Taylor, Juanita M. Cassidy, Dennis A. Williams, Gary P. Funkhouser
  • Patent number: 6176907
    Abstract: Formulation for anti-corrosion coating materials, comprising (i) 3-30% by mass of a monomeric and/or polymeric, metal-free or metal-containing, chelate-forming compound, (ii) 10-80% by mass of a material which binds hydroxide ions, and (iii) 5-65% by mass of a conductive pigment based on carbon.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: January 23, 2001
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Ralf Glausch
  • Patent number: 6171521
    Abstract: This invention is directed to a zwitterionic water-soluble imine of formula: wherein R1 is heterocyclyl, heteroaryl, aryl, arylalkyl, cycloalkyl or lower alkyl; R2 is alkyl, alkenyl, aminoalkyl, diaminoalkyl, hydroxyalkyl, alkoxyalkyl, thioalkyl, alkylthioalkyl or arylalkyl; R3 is hydrogen and lower alkyl, or R1 and R3 taken together form a cycloalkyl, p is 2, 3, 4 or 5; and Z is CO2−, OCO2−, SO3−, OSO3−, PO3− or OPO3− which are useful as ferrous metal corrosion inhibitors.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: January 9, 2001
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventor: G. Richard Meyer
  • Patent number: 6103144
    Abstract: Non-halogen substituted, nitrogen containing, aromatic compounds are disclosed which are effective copper corrosion inhibitors in aqueous systems being treated with a halogen biocide. The materials of the present invention exhibit copper corrosion inhibition comparable to tolyltriazole in the absence of halogen, copper corrosion rates of less than about 2.5 mills per year in aqueous systems where halogen is present; and do not exhibit a detrimental effect on halogen demand in an aqueous system being treated.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: August 15, 2000
    Assignee: BetzDearborn Inc.
    Inventor: Longchun Cheng
  • Patent number: 6059992
    Abstract: Corrosion in aqueous alkanolamine, physical solvents, or combination of alkanolamine and physical solvent solutions used to remove acid gases from natural gas, synthetic gas, or light hydrocarbon streams can be reduced by addition of mixtures of oxygen scavengers or mixtures of oxygen scavengers and sodium molybdate. The oxygen scavengers must be promoted to reduce metal surfaces in contact with the solutions to a more passive, harder, and insoluble form at the operating temperature of the treating system. The sodium molybdate provides additional passivation especially in the imperfections on the surface of the metal where corrosion accelerates.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: May 9, 2000
    Inventors: Ray R. Veldman, David O. Trahan
  • Patent number: 6056896
    Abstract: The present invention provides an improved metal corrosion inhibitor for use in aqueous acid solutions which is relatively non-toxic and inexpensive. The corrosion inhibitor is a mixture comprised of oligomerized aromatic amines prepared by contacting the still bottoms residue produced in the distillation of quinoline from coal tar with oxygen in the presence of a catalyst.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: May 2, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 6045719
    Abstract: Quaternized imidazoles I ##STR1## in which R.sup.1 and R.sup.3 independently of one another are saturated or unsaturated hydrocarbon radicals of 1-12 carbon atoms which can be substituted by oxygen-functional groups or interrupted by nonadjacent oxygens,R.sup.2, R.sup.4 and R.sup.5 independently of one another are hydrogen or saturated or unsaturated hydrocarbon radicals of 1-12 carbon atoms which can be substituted by oxygen-functional groups or interrupted by nonadjacent oxygens, it being possible for R.sup.4 and R.sup.5, together with the corresponding imidazole carbons, to form a five- or six-membered ring, andX.sup..crclbar. is an anion,are used as corrosion inhibitors in the corrosion protection of nonferrous metals, especially for car radiator protection.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: April 4, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Ladislaus Meszaros, Michael Gillich, Klaus Pfitzner, Knut Oppenlander, Wolfgang Gunther
  • Patent number: 6045723
    Abstract: The subject matter of this invention is directed to compositions and compounds to minimize hydrogen charging and hydrogen induced cracking of steels comprising, in one embodiment, a propylene diamine compound and in another a carrier and propylene diamines. Preferably, the composition of that embodiment is comprised of a hydrocarbon carrier and 1,3 propylene diamines. Alternatively, compositions of the present invention may be comprised of a carrier and octadecyl trimethyl ammonium bromide. In addition, where the environment dictates, the composition of the present invention may be comprised of a carrier, at least one 1,3 propylene diamine and octadecyl trimethyl ammonium bromide.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: April 4, 2000
    Inventors: Russell D. Kane, Michael S. Cayard
  • Patent number: 6042750
    Abstract: A composition for inhibiting corrosion of metal is described, wherein the composition comprises at least one tetraalkylammonium halide, at least one alkyldiamine, at least one polyethylene aliphatic hydrocarbon amine, at least one polyethylene fatty acid ester, at least one aliphatic hydrocarbon hydroxyalkyl imidazoline, at least one polyethylene glycol aliphatic ester, and at least one trialkanolamine, and at least one amine oxyalkylate.
    Type: Grant
    Filed: April 17, 1999
    Date of Patent: March 28, 2000
    Assignee: Joan Docter
    Inventor: James O. Burlew
  • Patent number: 6022401
    Abstract: Several copolymers of aspartic acid and another monomer provide effective mild steel corrosion inhibitors and scale formation inhibitors under oil field conditions. The copolymers are polymers of modified polyaspartic acid mer units and polyaspartic acid mer units. The resulting polymers are biodegradable.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: February 8, 2000
    Assignee: Nalco Chemical Company
    Inventors: Jiansheng Tang, Shi-Liang Fu, Daniel H. Emmons
  • Patent number: 5993693
    Abstract: Zwitterionic water-soluble imine corrosion inhibitors of the general formula: ##STR1## wherein R.sup.3 is an anionically charged group. Preferred zwitterionic imines are the reaction products of the Michael addition of acrylic acid to an imine.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventor: G. Richard Meyer
  • Patent number: 5989440
    Abstract: An oxygen scavenger characterized in that the effective component thereof consists of a heterocyclic compound with N--N bond in a ring thereof An oxygen scavenger characterized in that the effective component thereof consists of a heterocyclic compound with N-substituted amino group. An oxygen scavenger characterized in that the effective component thereof consists of a heterocyclic compound represented by the following formula: ##STR1## (wherein a, b are integers between 0 and 5 to satisfy a relation "2.ltoreq.a+b.ltoreq.5"). ##STR2## An oxygen scavenger characterized in that the effective component thereof consists of azodicarbonamide. An oxygen scavenger characterized by including a heterocyclic compound with N-substituted amino group, or the salt thereof, and a hydroxybenzene derivative. Those may contain further neutral amine, alkalic agent and/or water soluble polymer.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: November 23, 1999
    Assignee: Kurita Water Industries Ltd.
    Inventors: Yukimasa Shimura, Shiro Taya
  • Patent number: 5980619
    Abstract: A description is given of compounds of the formula ##STR1## in which the general symbols are as defined in claim 1, and of their zirconium, bismuth and calcium salts, and of the salts with the compounds of the formula II ##STR2## in which the general symbols are as defined in claim 1, as corrosion inhibitors in coating compositions for protecting metallic surfaces.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: November 9, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Adalbert Braig, Andreas Kramer, Jean-Pierre Wolf, Markus Frey
  • Patent number: 5968408
    Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Specific isomers of chloro-methylbenzotriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: October 19, 1999
    Assignee: BetzDearborn Inc.
    Inventors: Sydia B. Anderson, Longchun Cheng, Michael A. Cady
  • Patent number: 5961885
    Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
    Type: Grant
    Filed: January 12, 1999
    Date of Patent: October 5, 1999
    Assignee: Champion Technologies, Inc.
    Inventors: Paul Eaton, Sumeet Kanwar
  • Patent number: 5916484
    Abstract: By the present invention, improved metal corrosion inhibited aqueous organic acid compositions and methods are provided. The compositions are basically comprised of water, an organic acid, a corrosion inhibitor comprising at least one rosin amine derivative and a low toxicity corrosion inhibitor intensifier selected from the group consisting of thioglycolic acid and derivatives thereof.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: June 29, 1999
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 5902515
    Abstract: A corrosion inhibitor comprising a dispersant, an imidazoline, an amide, an alkyl pyridine and a heavy aromatic solvent. The resultant blend effectively inhibits corrosion of flow lines containing low pH mixtures of hydrocarbons, water, and acid gases.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: May 11, 1999
    Assignee: Champion Technologies, Inc.
    Inventors: Sumeet Kanwar, Paul Eaton
  • Patent number: 5900256
    Abstract: An aqueous acidic disinfecting and sterilizing composition for medical instruments, which may include brass, copper, aluminum, stainless steel, plastic and ceramic components. The composition contains hydrogen peroxide, peracetic acid, a corrosion inhibitor system, a surfactant and a stabilizer. These compositions have in use stability and are effective as a disinfectant and/or sterilant either at room or when heated. For other applications, surfactants, sequestering agents and stabilizers may be optional.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: May 4, 1999
    Assignee: Cottrell, Ltd.
    Inventors: John R. Scoville, Jr., Inna A. Novicova
  • Patent number: 5891364
    Abstract: Compositions and methods relating to cementitious compositions are provided. The addition of an amidoamine that is the reaction product of polyalkylenepolyamines and short-chain alkanedioic acids or reactive derivatives thereof to cementitious compositions has been found useful in inhibiting the corrosion of ferrous metal articles in contact with said composition. The amidoamine is advantageously employed in combination with a hydrophobe compound that enhances corrosion inhibition. The invention also provides aqueous emulsions which contain the amidoamine, one or more hydrophobes, and an emulsifier for the hydrophobe.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: April 6, 1999
    Assignee: Geo Specialty Chemicals, Inc.
    Inventors: Michael J. Incorvia, Jr., Robert W. Chobin, Jr., Tim Hegge, Jr.
  • Patent number: 5874026
    Abstract: A method of use of a composition including either or both isomers of hydrogenated methylbenzotriazole, namely, 5-Methyl-1H-Benzotriazole or 4-Methyl-1H-Benzotriazole which have been at least about 50% hydrogenated, to form corrosion inhibiting films on metal surfaces in an aqueous environment. The hydrogenated methylbenzotriazole compositions provide both improved passivation and improved film persistence when charged to aqueous industrial systems either on a continuous or on an intermittent basis. Continuous dosing is generally kept at a constant >0.5, typically 1-2 ppm in the aqueous system to be treated; intermittent doses are generally 10-20 ppm once every week or two or more.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: February 23, 1999
    Assignee: Calgon Corporation
    Inventors: John P. Pilsits, Jr., Ann M. Cognetti, Jasbir S. Gill
  • Patent number: 5871691
    Abstract: A method and compounds for inhibiting and controlling corrosion is disclosed. The method is particularly effective at inhibiting or preventing corrosion of ferrous-based metals in contact with aqueous systems such as cooling water systems. The method comprises introducing into the aqueous system a compound of the general formula: ##STR1## wherein R is hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; R' and R" are each independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl; Z is O, S, NH, or NR, where R is as described above; n is a positive integer greater than 1; f is a positive integer; and M is hydrogen, a water soluble cation (e.g., NH.sub.4.sup.+, alkali metal), or a C.sub.1 -C.sub.3 alkyl group.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: February 16, 1999
    Assignee: BetzDearborn Inc.
    Inventors: William S. Carey, William C. Ehrhardt, Andrew Solov
  • Patent number: 5866032
    Abstract: A composition for of controlling scale formation and deposition and corrosion in aqueous systems is described wherein a treatment solution of a substoichiometric amount of a composition comprising a scale/corrosion inhibitor in combination with a substituted alkylpolycarboxylate is employed. The scale/corrosion inhibitor can be a phosphonate such as hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, hydroxyphosphonoacetic acids, amino phosphonates; terpolymers, copolymers and homopolymers of acrylic acid, maleic acid, epoxysuccinic acids such as polyepoxysuccinic acid or mixtures thereof. The substituted alkylpolycarboxylates are compounds of the general structure: R--X.sub.m --Y.sub.n wherein R is a hydrocarbon functionality having 4 to 18 carbons; X, when present, is --NH--, --NY.sup.1 --, --N-->O, --N--OC--Y.sup.1, --O-- or --S--; n is greater than or equal to 1; m=O or 1; and Y and Y.sup.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: February 2, 1999
    Assignee: BetzDearborn Inc.
    Inventors: William S. Carey, Libardo A. Perez, Donald T. Freese, Judith L. Barron
  • Patent number: 5863611
    Abstract: A lead-free composition capable of being applied as a film and hardening to form a protective layer on the back of a mirror comprises a fluid organic resin and a corrosion inhibitor selected from a compound represented by the formula: ##STR1## wherein the individual radicals R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each hydrogen, an aliphatic, cycloaliphatic, araliphatic or aromatic radical, and can be substituted or unsubstituted; A is hydrogen or C.sub.z --CR.sup.5 R.sup.6 CN; X, Y and Z are independently selected from 0-5; and R.sup.5 and R.sup.6 are as defined for R.sup.1, R.sup.2, R.sup.3 and R.sup.4 above. To inhibit the corrosion of metallic film layers on mirrors, a mirror having a glass substrate layer and metallic film layer thereover should be obtained, after which the fluid organic resin coating system containing the aforementioned corrosion inhibitor is applied over the metallic film layer.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: January 26, 1999
    Assignee: Lilly Industries (USA), Inc.
    Inventor: Timothy J. Sanford
  • Patent number: 5863463
    Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: January 26, 1999
    Assignee: BetzDearborn Inc.
    Inventors: David W. Reichgott, Sydia B. Anderson, Michael A. Cady, Roger C. May, Anita G. Monino
  • Patent number: 5863464
    Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: January 26, 1999
    Assignee: BetzDearborn Inc.
    Inventors: David W. Reichgott, Sydia B. Anderson, Michael A. Cady, Roger C. May, Anita G. Monino
  • Patent number: 5853619
    Abstract: A low toxic corrosion inhibitor comprises (A) mercaptocarboxylic acid having from 2 to 6 carbon atoms, and (B) a polyamine/fatty acid/carboxylic acid adduct. The preferred combination of (A) and (B) includes mercaptoacetic acid and ethylenetetramine/tall oil acd/acrylic acid adduct.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: December 29, 1998
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: James D. Watson, John G. Garcia, Jr.
  • Patent number: 5853620
    Abstract: The subject matter of this invention is directed to compositions and compounds to minimize hydrogen charging and hydrogen induced cracking of steels comprising, in one embodiment, a propylene diamine compound and in another a carrier and propylene diamines. Preferably, the composition of that embodiment is comprised of a hydrocarbon carrier and 1,3 propylene diamines. Alternatively, compositions of the present invention may be comprised of a carrier and octadecyl trimethyl ammonium bromide. In addition, where the environment dictates, the composition of the present invention may be comprised of a carrier, at least one 1,3 propylene diamine and octadecyl trimethyl ammonium bromide.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: December 29, 1998
    Assignee: InterCorr-CLI International, Inc.
    Inventors: Russell D. Kane, Michael S. Cayard
  • Patent number: 5811026
    Abstract: A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: September 22, 1998
    Assignee: Phillips Engineering Company
    Inventors: Benjamin A. Phillips, Eugene P. Whitlow
  • Patent number: 5811032
    Abstract: A water-soluble polymer prepared by melting and reacting a mixture of an oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, or a mixture of a plurality of oxycarboxylic acids including at least one oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, at a temperature of 170.degree. C. or less at the start of the reaction to obtain a polymer; and then hydrolyzing the polymer.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: September 22, 1998
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Ryozo Kawai, Hiroshi Kurata, Yukari Shimizu, Shoichiro Kajiwara
  • Patent number: 5785896
    Abstract: A method of combating corrosion of a metal which comprises contacting such metal with a composition containing polyamino acids, their salts and their anhydrides, together with at least one corrosion inhibitor selected from the group consisting of benzotriazole, 4-C.sub.1 -C.sub.4 -alkylbenzotriazoles and 5-C.sub.1 -C.sub.4 -alkylbenzotriazoles.
    Type: Grant
    Filed: October 31, 1995
    Date of Patent: July 28, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinz-Joachim Rother, Franz Kunisch
  • Patent number: 5785895
    Abstract: A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy, 2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: July 28, 1998
    Assignee: Petrolite Corporation
    Inventors: Richard L. Martin, Jo Ann McMahon, Bernardus A. Oude Alink
  • Patent number: RE36291
    Abstract: A method for inhibiting corrosion of metal surfaces in an aqueous medium, comprising incorporating into the medium a corrosion inhibitor in an amount sufficient to inhibit corrosion, the corrosion inhibitor comprising a water-soluble agent selected from the group consisting of compositions of the formula ##STR1## compositions of the formula ##STR2## and mixtures thereof, wherein R is R.sup.2 .paren open-st.OCH.sub.2 CH.sub.2 .paren close-st..sub.x, wherein R.sup.2 is a substituted or unsubstituted alkyl, aryl, or aralkyl group of from about five to about fifteen carbon atoms, each carbon atom having at least one hydrogen and x is an integer of from about one to about ten, and R'N is a basic nitrogen compound that is at least water-dispersible.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: September 7, 1999
    Assignee: Baker Hughes Incorporated
    Inventor: Richard L. Martin