Oxygen Organic Compound Containing Patents (Class 252/403)
  • Publication number: 20100163805
    Abstract: The present invention generally relates to various media for protecting antioxidants contained therein from degradation before use. More particularly, the present invention relates to media which are to be dissolved in a fluid before use and to protect antioxidants contained therein from ultraviolet rays and from degradation caused by a prolonged period of dissolution in the fluid. To this end, such media include various fillers to protect the antioxidants from the ultraviolet rays. The present invention also relates to various media capable of promoting mixing of the antioxidants in the fluid. The present invention also relates to various methods of protecting such antioxidants contained in the media from such rays and various methods of promoting mixing between the fluid and antioxidants and/or fillers.
    Type: Application
    Filed: December 31, 2008
    Publication date: July 1, 2010
    Inventor: Youngtack Shim
  • Publication number: 20100130396
    Abstract: The invention relates to antioxidant compositions for lubricants and organic polymers comprising a first antioxidant comprising a reaction product of p-cresol, dicyclopentadiene and isobutylene; and a second antioxidant comprising a diarylamine. The first antioxidant preferably has the structure: wherein n is 0-50, and R1 and R2 are independently hydrogen, a straight or branched C1-C30 alkyl or alkylene group optionally substituted with one or more substituents, C3-C12 cycloalkyl, C5-C12 aryl, or C6-C12 alkylaryl. The second antioxidant preferably has the formula: (R3)a—Ar1—NH—Ar2—(R4)b wherein Ar1 and Ar2 are independently aromatic hydrocarbon groups and R3 and R4 are independently hydrogen or hydrocarbyl groups having from 6 to about 100 carbon atoms and a and b are independently 0 to 3 but (a+b) is not greater than 4.
    Type: Application
    Filed: November 24, 2008
    Publication date: May 27, 2010
    Applicant: CHEMTURA CORPORATION
    Inventor: Jun Dong
  • Patent number: 7695643
    Abstract: The invention relates to novel benzotriazole UV-absorbers having a long wavelength shifted absorption spectrum with significant absorbance up to 410-420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers and the use of the new compounds as UV-light stabilizers for organic materials.
    Type: Grant
    Filed: January 23, 2006
    Date of Patent: April 13, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Katharina Fritzsche, Adalbert Braig, Markus Frey, Walter Fischer
  • Patent number: 7686980
    Abstract: Compositions for actively inhibiting corrosion are described herein that include at least one active corrosion inhibitor compound, and at least one conventional corrosion inhibitor compound. In addition, methods for producing a composition that actively reduces corrosion are described herein and include providing at least one active corrosion inhibitor, providing at least one conventional corrosion inhibitor compound or corrosion protection compound, and blending the at least one active corrosion inhibitor and the at least one conventional corrosion inhibitor compound or corrosion protection compound to form the composition. In addition, a composition for actively inhibiting corrosion is described herein that includes at least one active corrosion inhibitor compound, wherein the at least one active corrosion inhibitor compound comprises a derivative or salt of a thio-, thia- or dithiocarbarnic acid, or a combination thereof and at least one conventional corrosion inhibitor compound.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: March 30, 2010
    Assignee: Teledyne Scientific & Imaging, LLC
    Inventors: Martin Kendig, Melitta Hon, Les Warren
  • Patent number: 7683017
    Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a nitro-substituted diphenylamine and a diarylamine which together provide superior oxidation inhibition.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: March 23, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: Richard E. Cherpeck, Carrie Y. Chan
  • Patent number: 7671118
    Abstract: A stabilizer system for stabilizing halogen-containing polymers comprising a perchlorate salt and at least one indole compound, a composition comprising such a stabilizer system, process for stabilizing a chlorine-containing polymer using such a stabilizer system, and an article manufacture comprising PVC stabilized by such a stabilizer system.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: March 2, 2010
    Assignee: Chemtura Vinyl Additives, GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich
  • Publication number: 20100048774
    Abstract: A stabilizer mixture containing the components (A) and (B) wherein component (A) is for example a compound of the formula (A-1) wherein A1 is hydrogen or C1-C4alkyl, A2 is a direct bond or C1-C10alkylene, and n1 is a number from 2 to 50; and component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II); with the proviso that components (A) and (B) are different.
    Type: Application
    Filed: October 28, 2009
    Publication date: February 25, 2010
    Inventor: François GUGUMUS
  • Patent number: 7651635
    Abstract: The invention provides a composition of matter and a method of its use in preventing unwanted polymerization reactions. The composition comprises an inhibitor and a retarder. The inhibitor is highly effective. The retarder is reliable under extreme and emergency situations. The inhibitor can be an alkylhydroxylamine. The retarder can be a 7-cyano-quinone methide. The combination of the inhibitor and retarder has been found to be far more effective than expected.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: January 26, 2010
    Assignee: Nalco Company
    Inventor: Vincent E. Lewis
  • Patent number: 7652081
    Abstract: A stabilizer mixture containing (I) one low molecular weight alkylated sterically hindered amine compound; and (II) one high molecular weight alkylated sterically hindered amine compound.
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: January 26, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Publication number: 20100003748
    Abstract: The present disclosure relates to compositions, systems, and methods for stabilizing a cell (e.g. a whole cell), a biomolecule, and/or a macromolecule. A biomaterial stabilizing composition may include a chelator, a chelator enhancing component, a base (e.g., a purine base or a pyrimidine base), and optionally a protease inhibitor and/or a kosmotrope. A biomaterial stabilizing method may include contacting a cell with a biomaterial stabilizing composition. A cell stabilizing system may include a container suitable for receiving a sample containing a cell and a biomaterial stabilizing composition. A cell may be stabilized under ambient conditions (e.g., without refrigeration). A cell may include a protein, a nucleic acid, and/or another biomolecule marker of cell stabilization. A composition may be configured to stabilize one or more cells for analysis by flow cytometry and simultaneously stabilize one or more intracellular nucleic acids for molecular analysis.
    Type: Application
    Filed: July 2, 2009
    Publication date: January 7, 2010
    Inventor: Tony Baker
  • Patent number: 7642303
    Abstract: Thermoplastic composition and articles containing UV absorbers that protect the articles contents from harmful UV radiation are disclosed as well as methods for making the thermoplastic articles and methods for using the articles to contain and protect materials sensitive to UV radiation. The UV absorbers contain oxazolone and/or azine functional groups that absorb UV radiation and prevent its transmission into the article. Many of the compounds are novel compositions of matter. The generally clear thermoplastic articles of this disclosure are particularly useful for containing a variety of UV sensitive consumer products that would otherwise have to be packaged in opaque containers.
    Type: Grant
    Filed: October 13, 2005
    Date of Patent: January 5, 2010
    Inventors: Thomas L. Shakely, James John Krutak
  • Patent number: 7595008
    Abstract: A stabilizer mixture containing the components (I), (II) and (III) wherein component (I) is for example a compound of the formula (B-1-b) wherein E1 is hydrogen; component (II) is for example a compound of the formula (B-0-a) wherein E1* is hydrogen; and component (III) is for example a compound of the formula (C-1-a) wherein b1 is a number from 2 to 20 and R6 is hydrogen; is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: September 29, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Publication number: 20090184294
    Abstract: Described are antioxidant macromolecules and methods of making and using same.
    Type: Application
    Filed: January 5, 2009
    Publication date: July 23, 2009
    Inventors: Ashok L. Cholli, Rajesh Kumar
  • Publication number: 20090176686
    Abstract: A stabilizer composition comprising a) an amine and b) a compound selected from aliphatic, non-cyclic monomeric polyunsaturated hydrocarbons and terpenes is useful for stabilizing an organic solvent against degradation.
    Type: Application
    Filed: May 1, 2006
    Publication date: July 9, 2009
    Inventors: Ulrich Tribelhorn, Marius Kuemin
  • Publication number: 20090144915
    Abstract: The invention describes novel compound of the formula I, wherein the general symbols are as defined in claim 1, as stabilizers for protecting organic materials, in particular synthetic polymers, against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
    Type: Application
    Filed: February 5, 2009
    Publication date: June 11, 2009
    Inventors: Hans-Rudolf Meier, Gerrit Knobloch
  • Publication number: 20090105379
    Abstract: A stabilizer mixture containing the components (A) and (B) wherein component (A) is for example a compound of the formula (A-1) wherein A1 is hydrogen or C1-C4alkyl, A2 is a direct bond or C1-C10alkylene, and n1 is a number from 2 to 50; and component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II); with the proviso that components (A) and (B) are different.
    Type: Application
    Filed: December 18, 2008
    Publication date: April 23, 2009
    Inventor: Francois Gugumus
  • Publication number: 20090093572
    Abstract: A stabilizer mixture containing (I) two different sterically hindered amine compounds, and (II) at least one compound selected from the group consisting of an organic salt of Zn, an inorganic salt of Zn, Zn oxide, Zn hydroxide, an organic salt of Mg, an inorganic salt of Mg, Mg oxide and Mg hydroxide.
    Type: Application
    Filed: October 14, 2008
    Publication date: April 9, 2009
    Inventor: Francois Gugumus
  • Publication number: 20090048374
    Abstract: A stabilizer composition for halogenated polymers includes at least one compound from group A) and at least one compound from group B), group A) being composed of semicarbazides, carbazides, carbazones, and carbodiazones, and their salts, and group B) of guanidines and melamines, superacids and salts of superacids, epoxy and glycidyl compounds, 1,3-dicarbonyl compounds, polyols, sterically hindered amines, hydrotalcites, zeolites, and alkali metal aluminocarbonates, hydrocalumites, metal hydroxides, metal oxides, metal hydrogen carbonates, and metal carbonates, metal soaps, organotin compounds, organic phosphite esters, amino alcohols and hydroxyl-containing isocyanurates, ?,?-unsaturated ?-aminocarbonyl compounds, aminouracil compounds and aminothiouracil compounds, and compounds having at least one mercapto-functional, sp2-hybridized C atom. Polymers stabilized in accordance with the invention are notable in particular for improved initial color and also for improved color maintenance.
    Type: Application
    Filed: September 12, 2008
    Publication date: February 19, 2009
    Applicant: BAERLOCHER GMBH
    Inventors: Stefan Fokken, Frank Reichwald, Markus Willems
  • Publication number: 20090028841
    Abstract: An oxygen scavenging composition being an oxidizable ascorbic acid derivative, a multi-copper oxidase enzyme, and a free fatty acid wherein the enzyme is disposed upon the surface of the oxidizable ascorbic acid derivative, and wherein the free fatty acid is intermixed with the oxidizable ascorbic acid derivative. The invention extends to a coating composition thereof and a package or container containing the oxygen scavenging composition.
    Type: Application
    Filed: July 22, 2008
    Publication date: January 29, 2009
    Inventor: RAMESHCHANDRA M. GOHIL
  • Patent number: 7435845
    Abstract: Corrosion and gas hydrate inhibitors having improved water solubility and increased biodegradability The invention thus provides the use of compounds of the formula (1) where R1, R2 are each independently C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, R3 is C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, —CHR5—COO? or —O?, R4 is M, hydrogen or an organic radical which optionally contains heteroatoms and has from 1 to 100 carbon atoms, B is an optionally substituted C1- to C10-alkylene group, D is an ethylene group substituted by an organic radical having from 1 to 600 carbon atoms, X, Y are each independently O or NR6, R5, R6 are each independently hydrogen, C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, and M is a cation as corrosion and gas hydrate inhibitors, and also the compounds of formula 1.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: October 14, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Uwe Dahlmann, Michael Feustel
  • Publication number: 20080157025
    Abstract: The invention relates to novel benzotriazole UV-absorbers having a long wavelength shifted absorption spectrum with significant absorbance up to 410-420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers and the use of the new compounds as UV-light stabilizers for organic materials.
    Type: Application
    Filed: January 23, 2006
    Publication date: July 3, 2008
    Inventors: Katharina Fritzsche, Adalbert Braig, Markus Frey, Walter Fischer
  • Patent number: 7344588
    Abstract: The invention relates to a process for preventing skinning of a coating composition comprising adding an anti-skinning agents containing mixtures of organic compounds (combinations of additives), whereby the organic compounds are selected from the groups of organic hydroxylamines, and ?-dicarbonyl compounds and/or selected derivatives of formic acid to the coating composition.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: March 18, 2008
    Assignee: Borchers GmbH
    Inventors: Andreas Steinert, Peter Manshausen
  • Patent number: 7332535
    Abstract: A stabilizer mixture for one or more compounds of the general formula (1) and (1A) but preferably (1), wherein the groups R independently stand for an alkyl-, cycloalkyl-, aralkyl- or aryl-rest whereas the aromatic ring system may be optionally substituted by one or more groups R? which may be identical or different and which groups R? can be an aryl-, a saturated or unsaturated alkyl-, aralkyl- or cycloalkyl-group as well as halogen, an amino-, aminoalkyl-, aminocycloalkyl-, cyano-, thiocyano- or nitrogroup. and a UV-absorber, hindered amine stabilizer, sterically hindered phenol, organophosphite, organophosphonite, organophosphine, or mixtures thereof. The present invention is useful in the protection of various polymeric substrates against the damaging influence of light exposure by the long term storage of polymers. This effect can be observed especially in so-called engineering plastics (such as, for example, PC, PET, PBT, ABS, TPU).
    Type: Grant
    Filed: June 8, 2006
    Date of Patent: February 19, 2008
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Christoph Kröhnke, Joseph R. Webster, Ernst Gronmaier, Lajos Avar
  • Patent number: 7323502
    Abstract: Organic polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation of a synergistic mixture of (i) at least one compound selected from the group consisting of the (a) sterically hindered nitroxyl stabilizers, (b) sterically hindered hydroxylamine stabilizers and (c) sterically hindered alkoxyamine stabilizers and (ii) at least one phosphazene flame retardant. Advantageously, a further flame retardant may be added, without the need of adding an antimony synergist. The compositions of the invention combine good flame retardant properties with light stability and good mechanical properties.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: January 29, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Nikolas Kaprinidis
  • Patent number: 7297734
    Abstract: The present invention describes a process for preparing a synergistic stabilizer mixture comprising the components of the general formulae (I), (II) and (III) in accordance with claim 1, characterized by the reaction of compounds of the formula (V) with an epihalohydrin of the formula (VI) in the presence of a phase transfer catalyst and from 4 to 20 times the molar amount of an alkali metal hydroxide, relative to compound (V), at from 20 to 220° C. Removal of the excess epihalohydrin and phase separation are followed by polymerization at from 100 to 240° C.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: November 20, 2007
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Mathias Mehrer
  • Patent number: 7235191
    Abstract: A polypropylene composition containing the components: a) a crystallizable polypropylene homopolymer, random copolymer, alternating or segmented copolymer, block copolymer or a blend of polypropylene with another synthetic polymer, and b) 0.001 to 5% relative to the weight of component (a), of a specific trimesic acid derivative.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: June 26, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Hans-Werner Schmidt, Paul Smith, Markus Blomenhofer
  • Patent number: 7166659
    Abstract: Compounds of formula I or II where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: January 23, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Stephen D. Pastor, Andrew B. Naughton, Robert Detlefsen, Mervin G. Wood, Joseph Suhadolnik, Anthony DeBellis, Deborah DeHessa
  • Patent number: 7148274
    Abstract: where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: December 12, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Stephen D. Pastor, Andrew B. Naughton, Robert Detlefsen, Mervin G. Wood, Joseph Suhadolnik, Anthony DeBellis, Deborah DeHessa
  • Patent number: 7125920
    Abstract: The present invention relates to an ultraviolet absorber for synthetic resins composed of a triazine compound represented by the general formula (I) shown below (wherein R represents an alkyl group having 1 to 4 carbon atoms, n is 0 or an integer of up to 2, and X represents a group selected from the consisting of group (a) to (d) shown below) (wherein R1 represents an aliphatic group having 5 to 60 carbon atoms, which is an alicyclic group, an alkyl group having an alicyclic group at the terminal or in the chain thereof, an alkyl group having a branch, or a linear alkyl group, depending on the number of carbon atoms; R2 represents an alkyl group having 1 to 18 carbon atoms or a (poly)alkyleneoxyalkyl group; R? represents an aliphatic diyl group having 5 to 60 carbon atoms; R and n have the same meanings as those described in the general formula (I) above).
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: October 24, 2006
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Yoshinori Negishi, Etsuo Tobita, Takashi Ayabe
  • Patent number: 7118689
    Abstract: Polychloroethylene, e.g., trichioroethylene and perchloroethylene, is stabilized with a stabilizing amount of a stable free radical stabilizer, e.g., a material having the 2,2,6,6-tetra(lower alkyl)-1-piperidinyloxy-yl free radical group, such as 2,2,6,6-tetramethyl-4-hydroxy-1-piperidinyloxy, or the 2,2,5,5-tetra(lower alkyl)pyrrolidinyloxy group, such as 2,2,5,5-tetramethyl pyrrolidinyloxy. Stable free radical stabilizer is removed from a polychloroethylene composition containing same by contacting the composition with silica, e.g., precipitated silica.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: October 10, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Earl M. Gorton, Ronald D. Olinger
  • Patent number: 7081213
    Abstract: A stabilizer mixture for one or more compounds of the general formula (1) and (1A) but preferably (1), wherein the groups R independently stand for an alkyl-, cycloalkyl-, aralkyl- or aryl-rest whereas the aromatic ring system may be optionally substituted by one or more groups R? which may be identical or different and which groups R? can be an aryl-, a saturated or unsaturated alkyl-, aralkyl- or cycloalkyl-group as well as halogen, an amino-, aminoalkyl-, aminocycloalkyl-, cyano-, thiocyano- or nitrogroup. and a UV-absorber, hindered amine stabilizer, sterically hindered phenol, organophosphite, organophosphonite, organophosphine, or mixtures thereof. The present invention is useful in the protection of various polymeric substrates against the damaging influence of light exposure by the long term storage of polymers. This effect can be observed especially in so-called engineering plastics (such as, for example, PC, PET, PBT, ABS, TPU).
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: July 25, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Christoph Krōhnke, Joseph R. Webster, Ernst Gronmaier, Lajos Avar
  • Patent number: 7077981
    Abstract: The invention relates to stabilizer systems, containing at least: a) a perchlorate salt; b) at least one or more compounds from the group consisting of carbamides, indole derivatives and enamines of formula (I), wherein n=1 or 2 and X=O or NR1; n=3–6 and X=O; R1=H, C1–C4-alkyl, C2–C6-alkenyl, C6–C10-aryl, C7–C18-alkaryl or C7–C18-aralkyl; R2 (if n=1)=C1–C22-alkyl, C2–C22-alkenyl or aryl, preferably phenyl, optionally substituted with up to 3 hydroxy, C1–C4-alkoxy or C1–C9-alkyl; or R2 (if n=2–6)=linear or branched C1-22-alkylene, optionally interrupted by one or more O or S atoms, wherein R2 (if n=3) can also be a C2–C3-alkyl trisubstituted isocyanurate; if X=NH R2 can also be H. Said stabilizer systems are suitable for stabilizing halogen-containing polymers, more particularly PVC.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: July 18, 2006
    Assignee: Crompton Vinyl Additives GmbH
    Inventors: Wolfgang Wehner, Hans-Helmut Friedrich
  • Patent number: 7026380
    Abstract: A stabilizer mixture containing A) either (A1) at least one compound of the formula in which R1 is for example hydrogen or C1–C8alkyl; R2, R3, R5 and R6 are for example hydrogen, C1–C30alkyl or phenyl; R4 is for example C1–C30alkyl or 2,2,6,6-tetramethyl-4-piperidyl; and n1 is a number from 1 to 50; or (A2) at least one compound of the formulae wherein n2 and n2* are a number from 2 to 50; B) magnesium oxide, magnesium hydroxide, zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium; and C) either (C1) an UV absorber or (C2) a pigment or (C3) an UV absorber and a pigment; with the proviso that, when component A) is at least one compound of the formulae (IIIa) and (IIIb), component B) is magnesium oxide, magnesium hydroxide or an organic salt of zinc or magnesium. Such a stabilizer mixture is particularly useful for stabilizing a polyolefin against light-induced degradation.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: April 11, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Patent number: 7019053
    Abstract: A stabilizer mixture containing A) for example at least one compound of the formula (I) wherein the radicals R1, independently of one another, are hydrogen, C1–C8alkyl, —O?, —CH2CN, C3–C6alkenyl, C7–C9phenylalkyl, C7–C9phenylalkyl which is substituted on the phenyl radical by C1–C4alkyl; or C1–C8acyl; and B) magnesium oxide, magnesium hydroxide, zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium, or a hydrotalcite; and C) either (C1) an UV absorber or (C2) a pigment or (C3) an UV absorber and a pigment. Such a stabilizer mixture is particularly useful for stabilizing a polyolefin against light-induced degradation.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: March 28, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Patent number: 6995200
    Abstract: The present invention relates to a stabilizer composition comprising a) at least one sterically hindered phenol, b) at least one phosphorus-containing secondary antioxidant, and c) at least one Leucine compound, wherein the weight ratio of component (a) to component (b) to component (c) is from 1:5:3 to 1:0,5:0,1 for the stabilization of polyolefine-based thermoplastic polymers against degradation, crosslinking and/or discoloration due to the exposure to heat and/or light, especially in the presence of oxygen.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: February 7, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Christoph Kröhnke
  • Patent number: 6982062
    Abstract: This invention relates to a corrosion inhibiting composition comprising (a) an aliphatic amine, (b) an azole selected from the group consisting of (1) tolyltriazole, (2) benzotriazole, and (3) mixtures thereof, and (c) a benzoate. The compositions are particularly useful in inhibiting the corrosion of metal equipment, particularly equipment made from cast iron and aluminum, and more particularly, engine blocks that have been subjected to water flushing. The invention also relates to a process for inhibiting corrosion, particularly the vapor phase corrosion of metal equipment.
    Type: Grant
    Filed: July 22, 2003
    Date of Patent: January 3, 2006
    Assignee: Ashland Inc.
    Inventors: Frank L. M. DeCordt, Niklas Dahlberg, Joseph Mihelic, Michelle Blackowski
  • Patent number: 6946517
    Abstract: A stabilizer mixture containing (A) for example a compound of the formula (A-I) wherein R1 is hydrogen or C1-C4alkyl, R2 is a direct bond or C1-C10alkylene and n1 is a number from 2 to 50; (B) a sterically hindered amine compound; and (C) anatase; with the proviso that the component (B) is different from a compound of the formula (A-I).
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: September 20, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Patent number: 6913712
    Abstract: Mixtures of compounds comprising a compound G2 and at least one further compound from the group G0, G1, G3, G4, G5, G6, the compounds G0-G6 corresponding to formula (I) in which, in the compound G0, the radicals R1, R2, R3, R4, R5 and R6 are each hydrogen; G1, the radical R1 is Q and R2, R3, R4, R5 and R6 are each hydrogen; G2, the radicals R1 and R2 independently of one another are each Q and R3, R4, R5 and R6 are each hydrogen; G3 the radicals R1, R2 and R3 independently of one another are each Q and R4, R5 and R6 are each hydrogen; G4, the radicals R1, R2, R3 and R4 independently of one another are each Q and R5 and R6 are each hydrogen; G5, the radicals R1, R2, R3, R4 and R5 independently of one another are each Q and R6 is hydrogen; G6, the radicals R1, R2, R3, R4, R5 and R6 independently of one another are each Q; and Q and the other symbols are as defined in claim 1, are effective as stabilizers for organic material with respect to damaging exposure to light, oxygen and/or heat.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: July 5, 2005
    Assignee: CIBA Specialty Chemicals Corp.
    Inventor: Pascal Hayoz
  • Patent number: 6906121
    Abstract: A composition of matter is disclosed that comprises a compound of the formula AnR, wherein: A is R1 is hydrocarbyl; m is 0 or 1; n is 1, 2, or 3; R is selected from the group consisting of: mono-, di-, and trivalent aliphatic groups; mono-, di-, and trivalent aromatic groups; five- and six-membered heterocyclic rings comprising n carbon atoms bonded to A, at least one nitrogen atom, and, optionally, at least one sulfur atom; and wherein R2 and R3 are independently selected from the group consisting of hydrogen and hydrocarbyl. These compounds are useful as coupling agents in filled elastomer compositions.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: June 14, 2005
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Joseph F. Stieber, Franklin H. Barrows
  • Patent number: 6861032
    Abstract: A boiler water treatment chemical includes a heterocyclic compound with N-substituted amino group, or the salt thereof, and alkaline agent and/or water soluble polymer.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: March 1, 2005
    Assignee: Kurita Water Industries Ltd.
    Inventors: Yukimasa Shimura, Shiro Taya
  • Patent number: 6849205
    Abstract: The present invention relates to a coating composition containing an oxidatively drying binder and, as anti-skinning agents, a mixture of A) an aliphatic amine corresponding to formula (Ia) and/or its salts corresponding to formula (Ib): ?wherein R1, R2 and R3 each independently of the others represents hydrogen (H); a linear or branched C1-C20-alkyl radical which is optionally unsaturated or which is optionally mono- or poly-substituted by a hydroxyl radical, an alkoxy radical, an amine radical corresponding to the formula N(R1)(R2), or a C5-C7-cycloalkyl radical, and A? represents a salt-forming anion, and B) with a compound corresponding to formula (II) ?wherein R1 and R4 each independently of the other represents hydrogen (H), a C1-C4-alkyl radical, a C6-C24-aryl radical or a C5-C7-cycloalkyl radical, a hydroxyl radical or a C1-C4-alkoxy radical, —O? (oxygen anion), R2 represents H, a C1-C4-alkyl radical, or A? (anion), R3 represents H, a C1-C4-alkyl radical, and n represents 0, 1 or 2.
    Type: Grant
    Filed: February 21, 2001
    Date of Patent: February 1, 2005
    Assignee: Borchers GmbH
    Inventor: Andreas Steinert
  • Patent number: 6835216
    Abstract: Compounds, preferably 5-pyrimidinol and 3-pyridinol derivatives, that act as effective chain breaking antioxidants of both the lipid and water-soluble variety (analogous to the natural Vitamins E and C), many of which are more reactive toward peroxyl radicals than the most potent form of Vitamin E. These compounds may exhibit many chemopreventive effects associated with conditions in which free radical-mediated cellular damage or disruption is implicated and Vitamins E and C are shown to have protective effects. Additionally, these compounds should be excellent oxidation inhibitors as additives to fuels, lubricants, rubber, polymers, chemicals, solvents and foodstuffs.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: December 28, 2004
    Assignee: Vanderbilt University
    Inventors: Derek A. Pratt, Luca Valgimigli, Gino A. DiLabio
  • Publication number: 20040211702
    Abstract: Compositions and methods for inhibiting polymerization of ethylenically unsaturated monomers are provided. The compositions include a water-soluble phenylenediamine composition.
    Type: Application
    Filed: April 24, 2003
    Publication date: October 28, 2004
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: John Link, Sherif Eldin
  • Publication number: 20040204522
    Abstract: Synergistic stabilizer compositions are employed to stabilize halogen-containing vinyl polymers from, for example, degradation and discoloration.
    Type: Application
    Filed: March 15, 2004
    Publication date: October 14, 2004
    Inventors: Steven Christopher Austen, Paul Brian Adams, Gary Martin Conroy, Gene Kelly Norris
  • Publication number: 20040195550
    Abstract: The present invention relates to the prevention of scorching before crosslinking of a thermoplastic and/or elastomeric composition with peroxides or azo compounds. This is achieved by using a nitroxide in combination with at least one crosslinking promoter (promoter) chosen from group (P) consisting of compounds containing at least one double bond, which may be difunctional or polyfunctional.
    Type: Application
    Filed: April 3, 2003
    Publication date: October 7, 2004
    Applicant: Atofina
    Inventors: Fabien Debaud, Alfredo Defrancisci, Olivier Guerret, Jacques Kervennal
  • Patent number: 6774170
    Abstract: A heat stabilizing composition for polyolefins comprises an oxidized, non-cationized, non-silylated sulfur black pigment, a hindered phenolic antioxidant a sulfur-containing secondary stabilizer, each in stabilizing amount, and a hindered amine. The heat stabilizing composition yields polyolefin compounds and articles having improved long term heat aging stability. Preferably, the sulfur black pigment is treated by washing, to thereby reduce the concentration of soluble sodium salts.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: August 10, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Joseph R. Webster
  • Publication number: 20040140455
    Abstract: The present invention is a stabiliser composition for halogen-containing polymers, comprising a salt of a halogen-containing oxy acid and an inorganic or organic acid or an inorganic base. The present invention relates also to a process for the preparation of such stabiliser compositions and to halogen-containing polymers comprising such stabiliser compositions.
    Type: Application
    Filed: November 21, 2003
    Publication date: July 22, 2004
    Applicant: Baerlocher GmbH
    Inventors: Stefan Fokken, Jurgen Hauk, Manfred Weigl
  • Patent number: 6758990
    Abstract: Hydroxylamine solutions stabilized using tri(4-(2,3-dihydroxyphenyl)-4-oxabutyl)amine, tri(4-(2,3-dihydroxyphenyl)-4-keto-3-azabutyl)amine or salts thereof, and methods of stabilizing hydroxylamine solutions using these compounds.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: July 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Markus Weber, Hans-Josef Sterzel, Eckhard Ströfer, Otto Watzenberger
  • Patent number: 6730157
    Abstract: The invention relates to anti-skinning agents containing mixtures of organic compounds (combinations of additives), whereby the organic compounds are selected from the groups of organic hydroxylamines, and &bgr;-dicarbonyl compounds and/or selected derivatives of formic acid and also relates to compositions containing them, especially oxidatively drying paints or coating compositions.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: May 4, 2004
    Assignee: Borchers GmbH
    Inventors: Andreas Steinert, Peter Manshausen
  • Patent number: 6709724
    Abstract: An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. Also, a catalyzing agent is included in an amount sufficient to increase the rate of oxygen scavenging by the organic compound. The organic compound and catalyzing agent are preferably maintained in a dry state by freeze drying or microencapsulation until the organic compound is activated for oxygen scavenging by contact with water or water vapor.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: March 23, 2004
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Fred N. Teumac, Bruce D. Zenner, Bert A. Ross, Larrie A. Deardurff, Mahmood R. Rassouli