Oxygen Organic Compound Containing Patents (Class 252/403)
  • Patent number: 5624982
    Abstract: A stabilizer system for the suppression of yellowing in styrenic polymers, consisting essentially of a benzotriazole such as 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, a hydroxybenzocyanurate such as tris-(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate and a hindered amine light stabilizer selected from the group consisting of (i) bis (2,2,6,6,-tetramethyl-4-piperidinyl) sebacate; and (ii) bis-(1,2,2,6,6-pentamethyl-4-piperdinyl) ester of (3,5-di-tert-butyl-4-hydroxybenzyl)-butyl malonate. Additionally a dialkyl thiodipropionate and a zinc dialkyldithiocarbamate may be included in the stabilizer system.
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: April 29, 1997
    Assignee: Bayer Antwerpen SA/NV
    Inventors: Moh C. O. Chang, Chuan-Ju Chen, Allen R. Padwa
  • Patent number: 5621138
    Abstract: 4,4'-disubstituted bis-(2,6-diisopropylphenyl)carbodiimides of the formula (I) ##STR1## where R is 1-methyl-1-phenylethyl, phenoxy or tert-butyl, a process for their preparation, their use as stabilizers against hydrolytic degradation of polyaddition and polycondensation products containing ester groups, and the novel 4-(1-methyl-1-phenylethyl)-2,6-diisopropyl-, 4-phenoxy-2,6-diisopropyl- and 4-tert-butyl-2,6-diisopropylphenyl isocyanates which can be used for their preparation.
    Type: Grant
    Filed: January 30, 1996
    Date of Patent: April 15, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedhelm Lehrich, Siegmund Pohl, Bernd Bruchmann, Helmut Tesch, Roland Minges, Johann Swoboda, Manfred Genz, Guenter Scholz, Joachim Streu
  • Patent number: 5616637
    Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: April 1, 1997
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5614648
    Abstract: A method of producing an antioxidant containing derivatives of an organic compound, and in particular, an antioxidant glyceride derivative, comprises reacting a first compound with a second medium. By this reaction, a product is formed whereby an active component of the first compound, e.g., an antioxidant moiety, is covalently incorporated into the second medium.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: March 25, 1997
    Inventors: George H. Greene, Robert Miller, James L. Williams, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
  • Patent number: 5589529
    Abstract: The invention relates to dimeric 2-(2'-hydroxyphenyl)benzotriazoles of the formula I ##STR1## in which p is 0 or 1;A is C.sub.1 -C.sub.12 alkylene;R.sub.1 and R'.sub.1, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or --CN;R.sub.2 and R'.sub.2, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl or together are C.sub.2 -C.sub.12 alkylene or C.sub.2 -C.sub.12 hydroxyalkylene; andR.sub.3 and R'.sub.3, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 alkyl or C.sub.1 -C.sub.18 alkoxy.The compounds of formula I are highly suitable for the stabilization of organic material against the harmful effects of heat, oxygen and light, in particular UV radiation.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: December 31, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Dieter Reinehr, Jean-Pierre Bacher, Andr e Schmitter
  • Patent number: 5560852
    Abstract: A method of improving the light fastness of textile materials using an aqueous dispersion of a compound of formula I, ##STR1## having a first (A) and a second (B) benzoxazine-4-one ring joined by a phenylene bridging member; a variable bond between the first benzoxazine-4-one ring (A) and the phenylene bridging member, said variable bond being meta- or para- to the bond between the second benzoxazine-4-one ring (B) and the bridging member; wherein each R.sub.1 is independently hydrogen, halogen, nitro, C.sub.1-2 alkyl, C.sub.1-4 alkoxy, carboxy, sulfonic acid, C.sub.1-3 alkylcarbonyl, benzoyl or C.sub.1-4 alkoxycarbonyl and; R.sub.2 is hydrogen, chlorine, bromine, methyl, C.sub.1-2 alkoxy, phenyl, hydroxy, nitro, carboxy or sulfonic acid.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: October 1, 1996
    Assignee: Sandoz Ltd.
    Inventor: Jean-Luc Mura
  • Patent number: 5559155
    Abstract: A high yield method for the preparation of C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl, C.sub.8 -C.sub.16 alkyl quaternary ammonium hydroxide is provided whereby two reactants, a corresponding quaternary ammonium chloride and a metal hydroxide, are reacted in a solvent comprising a C.sub.1 -C.sub.4 normal alcohol. The amount of metal hydroxide reactant is that amount sufficient to yield the quaternary ammonium hydroxide and a metal chloride.Also provided are wood preservative systems which include (a) a biocidal effective amount of at least one di C.sub.8 -C.sub.12 alkyl quaternary ammonium hydroxide and (b) a solvent, as well as a method for preserving a wood substrate whereby the substrate is treated with the preservative system.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: September 24, 1996
    Assignee: Lonza Inc.
    Inventor: Leigh E. Walker
  • Patent number: 5543083
    Abstract: The present invention relates to non-surface staining, light stable antioxidant compounds which reduce the fading, decoloration and degradation of various surfaces, ie., fabrics, from sunlight. These antioxidant compounds are butylated hydroxytoluene and sorbic acid derivatives, containing at least one C.sub.8 -C.sub.22 hydrocarbon fatty amine organic moiety and are either solid materials having a melting point of less than about 80.degree. Celsius, or are liquids at a temperature of less than about 40.degree. Celsius.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: August 6, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Mark R. Sivik, John C. Severns
  • Patent number: 5534305
    Abstract: A wood processing composition comprising a dimensional stabilizer which penetrates wood and restrains its swelling and shrinkage to prevent cracking and to give it dimensional stability, and a hardening filler composed of synthetic resins which hardens after penetrating wood to prevent the dimensional stabilizer from flowing away from said wood, fills the cavity of the wood to restrain its shrinkage, and protects the wood against decay and damage by termites. It preferably further contains a flame retardant consisting of at least one of a phosphoric acid compound and dicyandiamide, and a water-soluble flame-retardant solution containing urea and a 37% aqueous solution of formaldehyde by weight. Wood is impregnated with the composition by appropriate means and, after drying, it may be impregnated with a surface reinforcing synthetic resin. The wood as processed is free of any unnatural color, is harmless, and retains a durable surface which is characteristic of wood.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: July 9, 1996
    Assignee: Az Company
    Inventors: Satoshi Fujiki, Hideo Kamata
  • Patent number: 5532414
    Abstract: 4,4'-disubstituted bis-2,6-diisopropylphenyl)carbodiimides of the formula (I) ##STR1## where R is 1-methyl-1-phenylethyl, phenoxy or tert-butyl, a process for their preparation, their use as stabilizers against hydrolytic degradation of polyaddition and polycondensation products containing ester groups, and the novel 4-(1-methyl-1-phenylethyl)-2,6-diisopropyl-, 4-phenoxy-2,6-diisopropyl- and 4-tert-butyl-2,6-diisopropylphenyl isocyanates which can be used for their preparation.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: July 2, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedhelm Lehrich, Siegmund Pohl, Bernd Bruchmann, Helmut Tesch, Roland Minges, Johann Swoboda, Manfred Genz, Guenter Scholz, Joachim Streu
  • Patent number: 5523487
    Abstract: Quaternary ammonium carbonates having the formula ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group and R.sup.2 is a C.sub.8 -C.sub.20 alkyl group have been synthesized.These compounds and compositions further comprising the corresponding quaternary ammonium bicarbonate ##STR2## wherein R.sup.1 is the same or a different C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group and R.sup.2 is the same or a different C.sub.8 -C.sub.20 alkyl group and/or the corresponding quaternary ammonium metal carbonate ##STR3## wherein R.sup.1 is the same or a different C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group; R.sup.2 is the same or a different C.sub.8 -C.sub.20 alkyl group and M is a non-coupler metal, are prepared by reacting two reactants, a C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl, C.sub.8 -C.sub.20 alkyl quaternary ammonium chloride and a metal hydroxide, in a solvent comprising a C.sub.1 -C.sub.4 normal alcohol.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: June 4, 1996
    Assignee: Lonza, Inc.
    Inventor: Leigh E. Walker
  • Patent number: 5510059
    Abstract: A melamine cyanurate powder composed of readily dispersible aggregated primary particles of melamine cyanurate surface-treated with a metal oxide.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: April 23, 1996
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Shinichi Yuki, Kouji Shishido, Masayoshi Shirakawa, Masuo Shindo
  • Patent number: 5506286
    Abstract: A hindered piperidine compound represented by the formula of ##STR1## wherein R.sup.1 is a 2,2,6,6-tetramethyl-4-piperidyl group of which the N-position is substituted or not, a hydrogen atom, a C.sub.1 -C.sub.18 alkyl group which may contain a cyclic portion, or a C.sub.7 -C.sub.18 arylalkyl group, R.sup.2 is a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group which may contain a cyclic portion, a C.sub.1 -C.sub.18 alkyloxy group which may contain a cyclic portion, or a hydroxyl group, and n is an integer of 2 to 8, effectively stabilizes organic materials having a property to deteriorate by the action of light. A method for producing the compound represented by the above formula is also disclosed.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: April 9, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Kimura, Motohiko Samizo, Shinya Tanaka, Yukihiro Honda, Manji Sasaki, Shinichi Yachigo
  • Patent number: 5503776
    Abstract: An N-acylamino acid compound represented by the general formula (1):R--CO--(NH--X--CO).sub.n --OR.sup.1 (1)wherein (NH--X--CO) is an amino acid residue, X in (NX--X--CO) is variable with the kind of amino acid to be used, R--CO is a saturated or an unsaturated fatty acid residue having 6 to 24 carbon atoms, R.sup.1 is hydrogen atom, sodium atom, potassium atom, or methyl group and n is an integer in the range of from 1 to 3, indicating that at least one histidine is contained as a component amino acid is disclosed, which is obtained by causing an N-hydroxysuccinimide ester to react with an amino acid or a peptide.The compound excels in antioxidizing power, emulsifying power, antibacterial power, chelating power, infrared absorbing power, and humidity-retaining power.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: April 2, 1996
    Assignees: National Food Research Institute Ministry of Agriculture, Forestry and Fisheries, CCI Corporation
    Inventors: Hironobu Murase, Tsutomu Kunieda, Akihiko Nagao, Junji Terao
  • Patent number: 5496875
    Abstract: The present invention relates to novel piperidine compounds of the formula (I) V5 V pV ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are as defined in the text. The compounds of the invention can be used as fight stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: March 5, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Valerio Borzatta, Roberto Scrima, Primo Carrozza
  • Patent number: 5457104
    Abstract: The invention relates to new quinolone- and naphthyridonecarboxylic acid derivatives which have hydrogen in the 6-position, to processes for their preparation, and to antibacterial compositions and feed additives containing them.
    Type: Grant
    Filed: January 12, 1994
    Date of Patent: October 10, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Stephan Bartel, Andreas Krebs, Franz Kunisch, Uwe Petersen, Thomas Schenke, Klaus Grohe, Michael Schriewer, Klaus-Dieter Bremm, Rainer Endermann, Karl-Georg Metzger
  • Patent number: 5439958
    Abstract: The present invention relates to novel piperidine compounds of the formula (I) and to their use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials.The definitions of R.sub.1, R.sub.2 and R.sub.3 are given in the text.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: August 8, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Roberto Scrima, Graziano Zagnoni, Michael H. Ackerman, James P. Galbo, Roland A. E. Winter
  • Patent number: 5439955
    Abstract: 2-(Benzotriazol-2-yl)-4-alkyl-6-(2-hydroxy-3-benzoyl-6-alkoxybenzyl)phenols are prepared by reacting a Mannich base of a 2-(2-hydroxy-5-alkylphenyl)-2H-benzotriazole with a 2-hydroxy-4-alkoxybenzophenone. The hybrid products exhibit outstanding efficacy in protecting organic substrates from light-induced deterioration as well as good resistance to loss by volatilization or exudation during the processing of stabilized compositions at elevated temperatures.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: August 8, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Robert A. Falk, John J. Luzzi, Gregory R. Coughlin
  • Patent number: 5438034
    Abstract: Quaternary ammonium carbonates having the formula ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group and R.sup.2 is a C.sub.8 -C.sub.20 alkyl group have been synthesized.These compounds and compositions further comprising the corresponding quaternary ammonium bicarbonate ##STR2## wherein R.sup.1 is the same or a different C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group and R.sup.2 is the same or a different C.sub.8 -C.sub.20 alkyl group and/or the corresponding quaternary ammonium metal carbonate ##STR3## wherein R.sup.1 is the same or a different C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl group; R.sup.2 is the same or a different C.sub.8 -C.sub.20 alkyl group and M is a non-coupler metal, are prepared by reacting two reactants, a C.sub.1 -C.sub.20 alkyl or aryl-substituted alkyl, C.sub.8 -C.sub.20 alkyl quaternary ammonium chloride and a metal hydroxide, in a solvent comprising a C.sub.1 -C.sub.4 normal alcohol.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: August 1, 1995
    Assignee: Lonza, Inc.
    Inventor: Leigh E. Walker
  • Patent number: 5424349
    Abstract: Tertiary amides have been developed which have low volatility and good thermal stability and which are effective in stabilizing organic materials that are normally susceptible to oxidative deterioration. The novel antioxidants are tertiary amides corresponding to the formula: ##STR1## wherein R is a mono-, di-, or trivalent aromatic or saturated aliphatic hydrocarbon group containing 1-20 carbons; n is an integer of 1-3 which is equal to the valence of R; R' is phenyl, benzyl, or C.sub.1 -C.sub.6 alkyl; m is an integer of 1-3; R" is a C.sub.1 -C.sub.4 alkylene group; Z and Z' are independently selected from hydrogen and alkyl; and Q is carbonyl or sulfonyl.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: June 13, 1995
    Assignee: Albemarle Corporation
    Inventor: Vincent J. Gatto
  • Patent number: 5405891
    Abstract: Novel oligomeric compounds of formula I ##STR1## wherein L is a group of formula ##STR2## wherein the oxygen atom in the group L is attached to the phosphorus atom in the structural repeating unit, and R.sub.5 or the carbon atom in 4-position of the piperidinyl ring in the group L is attached to the oxygen atom in the structural repeating unit, and the remaining symbols are as defined in claim 1, are disclosed as stabilizers for protecting organic material against oxidative, thermal or light-induced degradation.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: April 11, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Rita Pitteloud
  • Patent number: 5384348
    Abstract: A hindered piperidine compound represented by the formula of ##STR1## wherein R.sup.1 is a 2,2,6,6-tetramethyl-4-piperidyl group of which the N-position is substituted or not, a hydrogen atom, a C.sub.1 -C.sub.18 alkyl group which may contain a cyclic portion, or a C.sub.7 -C.sub.18 arylalkyl group, R.sup.2 is a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group which may contain a cyclic portion, a C.sub.1 -C.sub.18 alkyloxy group which may contain a cyclic portion, or a hydroxyl group, and n is an integer of 2 to 8, effectively stabilizes organic materials having a property to deteriorate by the action of light. A method for producing the compound represented by the above formula is also disclosed.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: January 24, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Kimura, Motohiko Samizo, Shinya Tanaka, Yukihiro Honda, Manji Sasaki, Shinichi Yachigo
  • Patent number: 5380890
    Abstract: A method of producing an antioxidant containing compound, and in particular, an antioxidant glyceride derivative, comprises reacting a first compound with a second medium. By this reaction, a product is formed whereby an active component of the first compound, e.g., the antioxidant, is covalently incorporated into the second medium.The second medium comprises glyceride derivatives, silicones, fluorocarbons and alkoxylates containing reactive groups such as hydroxy, amino, carboxyl, ester, or amides.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: January 10, 1995
    Inventors: George H. Greene, Robert Miller, James L. Williams, James C. Phillips, Jerry F. Stults, Jan P. E. Tellings
  • Patent number: 5368777
    Abstract: Reaction products of polyalkenylsuccinic anhydrides with a prereacted product of polyamine and a cyclic carbonate are used as effective antifoulants in liquid hydrocarbonaceous mediums, such as crude oils, during processing of such liquids at elevated temperatures.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: November 29, 1994
    Assignee: Betz Laboratories, Inc.
    Inventor: David R. Forester
  • Patent number: 5364555
    Abstract: An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is a salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. A reducing agent of an ascorbate compound may be added to enhance the performance of the salicylic acid chelate or complex. The oxygen scavenging compound may be added to the composition in a dry state, and is inactive until activated for oxygen scavenging by contact with water or water vapor.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: November 15, 1994
    Assignee: Advanced Oxygen Technologies, Inc.
    Inventors: Bruce D. Zenner, Fred N. Teumac, Larrie A. Deardurff, Bert A. Ross
  • Patent number: 5350449
    Abstract: 2-(2-Hydroxyphenyl)-4,6-diphenyl- and -4,6-di-p-tolyl-1,3,5-triazines are particularly suitable stabilisers, especially against light-induced degradation, for coating materials. They are superior in this respect to the corresponding 4,6-bis(2,4-dimethylphenyl) derivatives.
    Type: Grant
    Filed: January 11, 1994
    Date of Patent: September 27, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Andreas Valet, Jean-Luc Birbaum, Mario Slongo
  • Patent number: 5322872
    Abstract: Compositions of (a) a salt of a metal and a carboxylic acid having at least 6 carbon atoms and (b) at least one salt of a metal other than the metal of (a) and a carboxylic acid having at least 6 carbon atoms in a fluid medium are stabilized towards storage decomposition and precipitation by incorporating in the composition (c) a complexing agent such as a ketoxime.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: June 21, 1994
    Assignee: The Lubrizol Corporation
    Inventor: Kevin J. Quinn
  • Patent number: 5317048
    Abstract: Disclosed is a process for producing an ultra-white N,N'-ethylene-bis(tetrabromophthalimide) product useful as a flame retardant. Also disclosed is a flame retardant composition predominantly comprised of N,N'-ethylene-bis(tetrabromophthalimide) and having a yellowness index of about 4 or less.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: May 31, 1994
    Assignee: Great Lakes Chemical Corporation
    Inventors: Brian Tarbit, Brian Adger, Paul Willett
  • Patent number: 5310767
    Abstract: The present invention relates to novel tetramethylpiperidine compounds of the formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 and R.sub.3 are e.g. --(CH.sub.2).sub.2 --, R.sub.4 is e.g. --CO--, --COCO-- or --COCH.sub.2 CO--, n is e.g. 1 and R.sub.5 is e.g. hydrogen or allyl.These compounds are suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: May 10, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Valerio Borzatta, Graziano Vignali
  • Patent number: 5298662
    Abstract: The invention relates to the high temperature stabilization of polyol heat transfer fluids by the use of N-phenyl-p-phenylenediamines.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: March 29, 1994
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Bernard C. Smith, Mark C. Richardson
  • Patent number: 5298067
    Abstract: 2-(2-Hydroxyphenyl)-4,6-diphenyl- and -4,6-di-p-tolyl-1,3,5-triazines are particularly suitable stabilizers, especially against light-induced degradation, for coating materials. They are superior in this respect to the corresponding 4,6-bis(2,4 -dimethylphenyl) derivatives.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: March 29, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Andreas Valet, Jean-Luc Birbaum, Mario Slongo
  • Patent number: 5292950
    Abstract: A composition of an N,N-dialkylaminoalkyl(meth)acrylamide of the following formula (II), which has an improved storageability and which contains an N,N-dialkylhydroxylamine of the following formula (I) in an amount of from 10 to 10,000 ppm: ##STR1## where R.sub.1 and R.sub.2 each independently represent an alkyl group having ##STR2## where R.sub.3 represents a hydrogen atom or a methyl group, R.sub.4 and R.sub.5 each independently represent an alkyl group having from 1 to 4 carbon atoms; andn represents an integer of from 2 to 4.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: March 8, 1994
    Assignees: Kohjin Co., Ltd., Sumitomo Chemical Co., Ltd.
    Inventors: Hiroshi Oka, Yasutaka Doi, Takashi Maruyama
  • Patent number: 5290495
    Abstract: A process for producing granules of a 2,2,6,6-tetramethylpiperidine-containing light stabilizer, which comprises mixing a 2,2,6,6-tetramethylpiperidine-containing light stabilizer having a melting point of not less than 60.degree. C. with a lubricant selected from the group consisting of water and an aqueous solution of an alcohol having 1 to 4 carbon atoms, and granulating the resultant mixture while pressure is applied thereto. The granular light stabilizer product has low dusting property and excellent free-flowing property.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: March 1, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Norimitsu Numadate, Isao Nakamae, Hiroki Yamamoto, Manji Sasaki
  • Patent number: 5288394
    Abstract: An improved process for inhibiting the formation and deposition of polymer-based fouling materials after caustic scrubbing of hydrocarbon streams contaminated with oxygenated compounds with a basic washing solution having a pH>7 comprising adding to the hydrocarbon stream after caustic scrubbing a sufficient amount for inhibiting formation and deposition of polymer-based fouling materials of a composition comprising at least one hydrazide compound characterized by the formula ##STR1## where R is selected from the group consisting of H, NHNH.sub.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: February 22, 1994
    Assignee: Nalco Chemical Company
    Inventors: Vincent E. Lewis, Carl T. Rowe
  • Patent number: 5266320
    Abstract: The use of an aminovinyl-substituted heterocyclic compound of the general formula I ##STR1## in which R.sup.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, or halogen, and, if more than one radical R.sup.1 are present, these may be the same or different,R.sup.2 denotes cyano or C.sub.1 -C.sub.20 -alkoxycarbonyl or C.sub.3 -C.sub.6 -cycloalkoxycarbonyl,R.sup.3 denotes hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -alkoxy, halogen, cyano, C.sub.1 -C.sub.20 -alkoxycarbonyl, or C.sub.3 -C.sub.6 -cycloalkoxycarbonyl, and, if more than one radical R.sup.3 are present, these may be the same or different,X denotes NH, O or S,m is equal to 1 or 2, andn is an integer from 1 to 5,as a stabilizer for organic materials.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: November 30, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Holderbaum, Alexander Aumueller, Hubert Trauth
  • Patent number: 5258138
    Abstract: A process for stabilizing an ethylenically unsaturated monomer or oligomer from premature polymerization is disclosed whereby a stabilizing amount of an amine, preferably a substituted hindered amine, in combination with phenothiazine or other related heterocyclic moiety is added to said polymerizable monomer or oligomer. The ethylenically unsaturated monomer or oligomer encompass vinyl monomers or oligomers bearing at least one polymerizable moiety. The combination of substituted hindered amine plus phenothiazine inhibits premature polymerization in the liquid and/or vapor phase.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: November 2, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Leslie R. Gatechair, Raymond Seltzer, James L. Hyun
  • Patent number: 5250592
    Abstract: Compositions comprising an organic material liable to thermal, oxidative and/or actinic degradation and at least one compound of the formula (I) ##STR1## are described in which R is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy, halogen, nitro, phenyl-C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.18 alkanoyl, benzoyl, (C.sub.1 -C.sub.6 alkyl)benzoyl, C.sub.2 -C.sub.18 alkenoyl, --N(R.sub.7)(R.sub.7a), --OH or --CO-A, R.sub.1 has the same possibilities of meaning as R, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.3 is hydrogen or halogen, A is hydroxyl, C.sub.1 -C.sub.18 alkoxy, C.sub.5 -C.sub.12 cycloalkoxy, benzyloxy or benzyloxy substituted by C.sub.1 -C.sub.4 alkyl and/or halogen, --N(R.sub.7)(R.sub.7a), --NH--NH--R.sub.8 or leads to di-, tri- or tetrameric ring systems containing rings of the formula I via a bridging member, and in which R.sub.5 and R.sub.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: October 5, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Nesvadba
  • Patent number: 5246607
    Abstract: Methylpolysiloxanes are disclosed which have quaternary ammonium groups linked to silicon atoms via carbon atoms, wherein the ratio of the number of dimethylsiloxy groups to the number of quaternary ammonium groups has a value of 0.5 to 1.5. The methylpolysiloxanes are useful as corrosion inhibitors for preparations consisting predominantly of water, especially coolants, such as cooling lubricants mixed with water, in an amount of 0.01 to 0.1% by weight, based on the total preparation in the form suitable for use.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: September 21, 1993
    Assignee: Th. Goldschmidt AG
    Inventors: Dietmar Schaefer, Werner Hohner
  • Patent number: 5238979
    Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and R.sub.6 is hydrogen or alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 24, 1993
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5229442
    Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: July 20, 1993
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Fabio Broussard, Carlo Busetto
  • Patent number: 5221498
    Abstract: Methods and compositions are provided for inhibiting the polymerization of a vinyl monomer during elevated processing thereof or during storage or shipment of the monomer containing product. The compositions comprise a combination of a dihydroxybenzene compound and an organic amine compound.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: June 22, 1993
    Assignee: Betz Laboratories, Inc.
    Inventors: Dwight K. Reid, Rosalie B. Hart
  • Patent number: 5217686
    Abstract: An alkoxybenzotriazole, in combination with mercaptobenzothiazole, tolyltriazole, benzotriazole, a substituted benzotriazole and/or 1-phenyl-5-mercaptotetrazole, is used to inhibit the corrosion of metallic surfaces, particularly copper surfaces, in contact with an aqueous system. Systems and compositions are also claimed.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: June 8, 1993
    Assignee: Calgon Corporation
    Inventors: Daniel P. Vanderpool, Charles Y. Cha
  • Patent number: 5209858
    Abstract: The stabilization of aqueous or alkanolic solutions of choline and derivative of choline against discoloration on aging by the addition of an unsubstituted hydroxylamine salt to the choline solutions at levels of less than 1 percent.
    Type: Grant
    Filed: February 6, 1991
    Date of Patent: May 11, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George E. Heinsohn, Rudolf E. Svadlenak
  • Patent number: 5205949
    Abstract: An additive composition comprising a graft and derivatized block copolymer prepared from a styrene-ethylenebutylene-styrene characterized in that unsaturation in the styrene blocks is equal to or greater than 50 percent, and the ethylenebutylene block is hydrogenated leaving no more than 10 percent unsaturation which has been grafted with at least one olefinic carboxylic acid acylating agent and then derivatized with an aminoaromatic compound from the group consisting of aminopyridines, aminopyrazines and aminopyrimidines, and a lubricating oil composition containing same are provided.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: April 27, 1993
    Assignee: Texaco Inc.
    Inventors: Theodore E. Nalesnik, Benjamin J. Kaufman, James G. Dadura
  • Patent number: 5173213
    Abstract: The corrosion and fouling of metal surfaces in contact with corrosive acid fluids or acid salts in the presence of an aqueous medium is reduced by contacting the surfaces with a composition which comprises (a) an anti-fouling amount of a hydroxyl amine compound of the formulaR.sub.1 R.sub.2 N--OHwherein R.sub.1 and R.sub.2 are independently hydrogen or a hydrocarbyl or inertly substituted hydrocarbyl or both R.sub.1 and R.sub.2 are collectively a divalent hydrocarbyl combined with said nitrogen to form a heterocyclic ring, and (b) a corrosion-inhibiting amount of a reaction product of or a mixture for the purpose of a reaction product of a polyalkylene polyamine and an alkynediol. The polyalkylene polyamine is one that contains from 2-10 amine groups, each separated from another by an alkylene group having from 2-6 carbon atoms. The alkynediol has from 2 to 6 carbon atoms.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: December 22, 1992
    Assignee: Baker Hughes Incorporated
    Inventors: Richard F. Miller, John Petersen
  • Patent number: 5160425
    Abstract: A method for inhibiting the formation of fouling materials during the caustic washing of hydrocarbons contaminated with oxygen compounds is disclosed. The method comprises adding an effective amount of carbohydrazide to the caustic wash system.
    Type: Grant
    Filed: June 21, 1991
    Date of Patent: November 3, 1992
    Assignee: Nalco Chemical Company
    Inventor: Vincent E. Lewis
  • Patent number: 5160666
    Abstract: Liquid preservative compositions which are particularly useful for plastics dispersions and secondary products prepared therefrom are disclosed. These compositions comprise mixtures of 1,2-benzisothiazolin-3-one or a salt thereof and at least one alkyl(polyaminoalkyl)glycine compound.
    Type: Grant
    Filed: April 2, 1990
    Date of Patent: November 3, 1992
    Assignee: Riedel-De Haen AG
    Inventors: Wolfgang Lindner, Hans-Ulrich Neuber, Erich Taschenbrecker
  • Patent number: 5156762
    Abstract: Polyether polyols and polyurethane foams are stabilized by including therein a liquid stabilizer composition of (a) 2,6-di-tert-butyl-4-sec-butylphenol, (b) a reaction product of diisobutylene, styrene and diphenylamine and (c) phenothiazine or C.sub.9-26 -alkyl substituted phenothiazone and wherein the ratio of the phenol to the reaction product is about 1:5 to 5:1 and the ratio of the mixture of components (a) and (b) to the phenothiazone compound is about 5.0:0.1 to 4.0:1.0. The stabilizer composition may further contain trihydrocarbyl phosphite to stabilize the color of same.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: October 20, 1992
    Assignee: R. T. Vanderbilt Company, Inc.
    Inventors: Richard A. Suhoza, Bruce R. Garney, Robert B. Lauder
  • Patent number: 5143943
    Abstract: Polyether polyols and polyurethane foams are stabilized by including therein a liquid stabilizer composition of (a) 2,6-di-tert-butyl-4-sec-butylphenol, (b) a reaction product of diisobutylene, styrene and diphenylamine and (c) phenothiazine or C.sub.9-26 -alkyl substituted phenothiazine and wherein the ratio of the phenol to the reaction product is about 1:5 to 5:1 and the ratio of the mixture of components (a) and (b) to the phenothiazine compound is about 5.0:0.1 to 4.0:1.0. The stabilizer composition may further contain trihydrocarbyl phosphite to stabilize the color of same.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: September 1, 1992
    Assignee: R. T. Vanderbilt Company, Inc.
    Inventors: Richard A. Suhoza, Bruce R. Garney, Robert B. Lauder
  • Patent number: 5143648
    Abstract: This invention relates to a novel ascorbic acid derivative having excellent antioxidant action and a process for preparing the same.Furthermore, this invention also relates to a novel antioxidant comprising the aforementioned ascorbic acid derivative or other known ascorbic acid derivatives.
    Type: Grant
    Filed: August 20, 1991
    Date of Patent: September 1, 1992
    Assignee: Nippon Hypox Laboratories Incorporated
    Inventors: Toshio Satoh, Yasunori Niiro, Hisao Kakegawa, Hitoshi Matsumoto