Abstract: The present invention relates to photochromic benzopyrans and to the use thereof in plastics of all kinds, especially for ophthalmic purposes. The inventive compounds are photochromic benzopyran compounds in which a polycyclic aromatic is joined to the 5 and 6 positions of a benzopyran, where the bond in the 6 position is direct and the bond in the 5 position is via a mono- or diatomic bridge.

Abstract: A photochromic curable composition comprising [A] not less than 0.1 part and less than 5 parts by mass of a specific radically polymerizable monomer having an epoxy group, [B] 1.0 to 15 parts by mass of a specific polyfunctional radically polymerizable monomer, [C] 1.0 to 30.0 parts by mass of a specific di(meth)acrylate monomer, [D] more than 50.0 parts and not more than 97.9 parts by mass of a (meth)acrylate monomer except the components [A] to [C] and/or a thio(meth)acrylate monomer, and [E] 0.001 to 10 parts by mass of a photochromic compound based on 100 parts by mass of the total of the polymerizable monomers. The photochromic curable composition can provide a photochromic cured product having excellent photochromic properties for a long time and high mechanical strength, and the photochromic cured product can be manufactured from the photochromic curable composition at a low cost.

Abstract: A chromene compound represented by the following formula (1), wherein R1, R2, R3 and R4 are, respectively, hydrogen atoms, alkyl groups, aryl groups, or the like groups under a condition that at least two of R1 to R4 are not hydrogen atoms, R5, R6, R7 and R8 are, respectively, alkyl groups, aryl groups or the like groups, m and n are, respectively, integers of 0 to 4, and x and y are, respectively, integers of 0 to 5. The compound has a basic structure in which a 6-membered ring is condensed in a form of shearing a carbon atom at the fifth position and a carbon atom at the sixth position of a 2H-benzo[h]chromene skeleton. Owing to this molecular structure, the chromene compound of the invention develops a yellow color or a neutral tint by itself, exhibits favorable photochromic properties, and does not exhibit deteriorated photochromic properties even when it is used in combination with a photopolymerization initiator.

Abstract: A chromene compound represented by the following formula (1), wherein, “A” is an annulated ring, R1 and R2 are hydrogen atoms, hydroxyl groups or the like groups, R3, R4, R5 and R6 are substituents such as hydroxyl groups or the like groups, “a” and “b” are, respectively, integers of 0 to 4, and “c” and “d” are, respectively, integers of 0 to 5. The chromene compound is a photochromic compound developing a color of a neutral tint, and has a high color density per a unit amount.

Abstract: The invention provides an optical article including a substrate; and a colorant composition connected to at least a portion of the substrate. The colorant composition is a fixed-tint colorant; and a photochromic material. The article exhibits a passive state and an activated state, such that the article can switch from the passive state to the activated state in response to at least actinic radiation and to revert back to the passive state in response to thermal energy. The passive state is characterized by a transmittance ranging from greater than 30% to 70% across a wavelength range of from 460 nanometers to 500 nanometers.

Abstract: A thermochromic coloring color-memory composition which comprises a homogeneous solubilized mixture of (A) an electron donative coloring organic compound, (B) an electron accepting compound and (C) an ester compound represented by the specific formula as a reaction medium which controls color reactions of the components (A) and (B).

Abstract: The invention relates to a process for enhancing the contrast of colour filters comprising ? copper phthalocyanine or ? copper phthalocyanine, wherein a 1,4-diamino-anthraquinone dye or 1,9-annellated derivative thereof, of which the most bathochromic solution absorption peak in the visible spectrum is at from 575 to 615 nm, preferably at from 585 to 605 nm (as compared with around 630 nm for usual 1,4-diamino-anthraquinone dyes or 1,9-annellated derivatives thereof) is used in combination with ? copper phthalocyanine or ? copper phthalocyanine.

Abstract: We have designed a molecular switch based on the photoinduced opening and thermal closing of a [1,3]oxazine ring. A substituted [1,3]oxazine compound described as having a general (i.e., unsubstituted) structure with fused indoline and benzooxazine fragments such that they share a common bond in the [1,3]oxazine compound: (i) the bond connecting positions 1 and 2 of the indoline fragment and (ii) the bond connecting positions 2 and 3 of the benzooxazine fragment. Irradiation by light of suitable wavelength and intensity of this photochromic compound induces cleavage of a [C—O] bond of the [1,3]oxazine ring to form a phenolate chromophore. The photogenerated (e.g., colored) isomer may revert thermally to the starting (e.g., colorless) oxazine. Alternatively, the switch may be between isomers of the compound that absorb at different wavelengths. Reversible coloration of silica or polymeric materials and switching optical signals may involve many cycles of interconversion between different colored states.

Abstract: The present invention relates to a UV curable photochromic composition comprising a photochromic dye and an acrylate-based prepolymer having a polyol structure in which an acrylate-based functional group is introduced by using an iso-cyanate-based compound having two or more isocyanate functional groups as a linker, and to products formed by using the same.

Abstract: The invention relates to cocrystals of compounds of the formulae (I), (II) and (III), obtainable by reacting 1 mol of a succinic diester with 2 mol of a mixture of nitriles A-CN and B-CN, where A-CN and B-CN are present in the nitrile mixture in a molar ratio of 90:10 to 30:70 relative to one another, and where A-CN is 2-chlorobenzonitrile and B-CN is 4-X-benzonitrile where X=chlorine, methyl or nitrile.

Abstract: Described are non-aqueous dispersions of photosensitive polymeric microparticles, comprising: a) an organic continuous phase comprising an organic solvent; and b) photosensitive polymeric microparticles dispersed in the organic continuous phase. The microparticles comprise an at least partially polymerized component having integral surface and interior domains, wherein the surface domain comprises a polymeric material that is solubilized by the organic solvent, the interior domain comprises a polymeric material that is insoluble in the organic solvent, and the surface domain and/or interior domain is photosensitive. Also described are methods of producing such non-aqueous dispersions, curable film-forming compositions containing them, and photosensitive coated substrates.

Abstract: The present invention provides novel compositions suitable for use in an intermolecular photodeprotection reaction scheme. Such compositions include a chromophore compound and a second compound having a photocleavable group bonded to a protected functional group. Novel compounds which can used in intramolecular photodeprotection are also provided. These compounds have a chromophore moiety bonded to a photocleavable group, which itself is bonded to a protected group. The compounds and compositions disclosed herein can be used in two-photon and multi-photon excitation.

Abstract: Liquid cosmetic composition in the form of an emulsion comprising at least two distinct phases and containing at least one photochromic coloring agent and at least one non-photochromic coloring matter, characterized in that the photochromic coloring agent(s) and the non-photochromic coloring matter(s) are located in separate phases of the emulsion. Application to the make-up and/or the care of the skin and/or its appendages.

Abstract: A naphthopyran compound represented by the formula (I): wherein: n1, n2, p, q is an integer comprised from 0 to 5 inclusive; m is an integer comprised from 0 to 4 inclusive; R1 and R2 represent a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —NRbRc, —CO—Ra, and —CO2Ra1, wherein Ra, Ra1, Rb and Rc, are as defined in the description; R3 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1; R4 represents a group selected from halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, —NRaRa1, —CO—Ra, and —CO2Ra1; R5 represents a group selected from: halogen, —Ra, —OH, —ORa, —SH, —SRa, —NH2, and —NRaRa1, wherein Ra and Ra1 are as defined hereinbefore, or when q is equal to 2, then two R5 together represent further a group —O—(CH2)q1—O— wherein q1 represents an integer comprised from 1 to 3 inclusive.

Abstract: A red-colored film in which when an elliptically polarized light is incident on the film in a direction 45° aslant from a normal line direction with respect to a surface of the film, a light transmitted through the film has an average amplitude transmittance ratio (av. tan ?) in a wavelength region of 575 to 635 nm, which satisfies the following equation (1): 0.960<av. tan ?<1.040??(1). A red-colored composition contains a red pigment A having a BET specific surface area in the range from 90 to 140 m2/g, a red pigment B having a BET specific surface area in the range from 70 to 85 m2/g, and a pigment carrier formed of a transparent resin, a precursor of the transparent resin or a mixture of the tarns parent resin and precursor thereof. A color filter has the red-colored film as a red color filter segment. The liquid crystal display device includes the color filter.

Abstract: The invention relates to a composite with inverse thermochromic properties, the composite changing from a colourless into a coloured state with increasing temperature. The composite thereby contains a colourant, a developer and a fluxing agent and also an inorganic filler. The invention likewise relates to a composite material which contains a polymer-based matrix into which at least one composite with inverse thermochromic properties is doped. These composite materials are used in the field of sensor technology, solar technology, transport and communications technology and medical technology.

Abstract: Disclosed is an organic layer photosensitive resin composition and an organic layer fabricated using the same. The organic layer photosensitive resin composition includes (A) an organic binder resin, (B) a reactive unsaturated compound, (C) a polymerization initiator, (D) a black pigment including a lactam-based black pigment, and (E) a solvent.

Abstract: An ink composition for a color filter is provided. The ink composition comprises a pigment, a binder resin, a polymerizable monomer and a melamine compound. The melamine compound has a weight average molecular weight of 126 to 5,000. The melamine compound is represented by Formula 1: wherein R1, R2, R3, R4, R5 and R6 are each independently a hydrogen atom or a group including a C1-C6 alkyl group, a C1-C6 alkoxy group, a carboxyl group, a C1-C6 ether group, a C1-C6 alcohol group, an amino group, a nitro group, a hydroxyl group, a phenyl group or an acrylic group; a polymer thereof; or a mixture thereof. The use of the melamine compound in the ink composition prevents reduction of contrast ratio after high-temperature treatment and is effective in further improving the dispersibility of the ink. Further provided is a color filter produced by using the ink composition.

Abstract: The present invention provides a photochromic film which is formed by curing a photochromic composition and includes a multifunctional (metha)acrylate-based monomer that has two or more functional groups, and a photochromic dye, a product including the same, and a method for producing the photochromic film.

Abstract: Disclosed herein is an electrochromic display device comprising a pair of transparent substrates facing each other, an anode electrode and a cathode electrode respectively formed on the transparent substrates, an electrolytic layer disposed between the anode electrode and the cathode electrode, an electrochromophore layer of a nano structure formed on at least one of the anode electrode and the cathode electrode, and a redox promoter layer coated with a conductive compound, on the other electrode.

Abstract: The present invention relates a binder composition and a photosensitive composition including the binder composition. In one embodiment, a binder composition includes a copolymer of monomer M1, M2, M3, M4, an iso octyl 3-mercaptopropionate and a thermal initiator, wherein the monomer M1 can be represented by the following formula: the monomers M2, M3 and M4 can be represented by the following formula, however the monomers M2, M3 and M4 are different from each other, wherein R1, R2, R3 can be selected from the group consisting of hydrogen and alkyl group, R4 is an aromatic group, R5 can be selected from the group consisting of hydrogen, aromatic groups, alkyl groups, substituted alkyl groups and alkyl groups interrupted by an oxygen atom. The copolymer has good developing ability and a black matrices made therefrom has good mechanical properties.

Abstract: Provided is a photochromic optical articleincluding: (a) an optical substrate; (b) a thermally reversible photochromic material; and (c) reversible thermochromic material capable of at least partially filtering UV/visible light at or below room temperature and becoming less capable of filtering UV/visible light at temperatures greater than room temperature.

Abstract: A non-linear optical device comprising a polymer configured to provide a grating holding ratio of 20% or higher after about four minutes, wherein the polymer comprises a first repeating unit comprising a first moiety having formula (M-1) and a second repeating unit comprising a second moiety having formula (M-2), as defined herein.

Abstract: There is provided a laser-writable molding material containing A) at least one polymer material or at least one precursor compound which can be polymerised to give a polymer material, and B) a particulate salt-like compound or a mixture of particulate salt-like compounds, which under the influence of laser light changes its color or leads to a color change in the component A). In order to enlarge the range of matrix materials hitherto available for laser writing and to overcome the disadvantages of the previously used writing procedures for such matrix materials, the laser-writable molding material according to the invention is characterised in that the at least one polymer material of the component A) is selected from polymer compounds having siloxane crosslinking units.

Abstract: The invention relates to products, methods and devices for remote communication or control using chromogenic materials. Several samples including at least one kind of chromogenic materials are simultaneously irradiated or radiated together by an appropriate entangled radiation, e.g. gamma, X, ultraviolet or visible radiation, provided by a cascade from an atomic source, or by the target of a linear particle accelerator or by a non-linear crystal. When the samples are separated, one of them, qualified as the master, is stimulated by a traditional method that uses infrared or white radiation or by heating, and a signal is measured that represents the partially correlated excess variation of opacity or coloration of the other sample(s), qualified as slave(s). There is no known method of interference between the master and the slaves. The slave(s) are the only ones capable of instantaneously receiving the signal from the master through all media and from any distance.

Abstract: A color filter ink is adapted to be used to manufacture a color filter by an inkjet method. The color filter ink includes a colorant, a resin material, and a liquid medium that dissolves and/or disperses the colorant. The resin material includes a polymer containing a first monomer component represented by a prescribed chemical formula, a second monomer component having a carboxyl group or acid anhydride group, and a third monomer component represented by a prescribed chemical formula.

Abstract: A method is disclosed for forming a blended phosphor composition. The method includes the steps of firing precursor compositions that include europium and nitrides of at least calcium, strontium and aluminum, in a refractory metal crucible and in the presence of a gas that precludes the formation of nitride compositions between the nitride starting materials and the refractory metal that forms the crucible. The resulting compositions can include phosphors that convert frequencies in the blue portion of the visible spectrum into frequencies in the red portion of the visible spectrum.

Abstract: Selective fractionation and separation of melanin and use of fractionated or separated melanin in connection with light filters is disclosed. Further, light filters that use yellow melanin or melanin like materials prepared to have a yellow color and a melanin transmission spectrum in combination with a photochromic dye are disclosed. The yellow form of melanin has minimal impact on the perception of light intensity with transmission values greater than 80%. The combination allows for a single light filter suitable for both night driving and sunglass applications and which also preserve color perception.

Abstract: Disclosed are compositions, which are stabilized against degradation and yellowing during exposure to ultraviolet light by the presence of certain nitroxyl, hydroxyl amine and hydroxyl amine salt additives, a method of stabilizing the compositions by the addition of said additives, to the use of such compositions as media in electroactive devices such as electrochromic and electrophoteric devices, and the electroactive devices comprised of these media.

Abstract: The present invention relates to a pigment composition composed of compounds of the formula (I), (II) and (III) with a novel crystal modification, to their preparation and to the use of this novel product as a pigment. For many applications of organic pigments, for example the coloring of metallic lacquers or the use thereof in color filters, a very high transparency is required. To produce color filters, for example, particularly fine pigments are used, in order to substantially rule out the particle scattering which leads to a lowering of the contrast ratio. The commercially available products, however, do not always meet all requirements of the art. More particularly, there was a need for improvement with regard to the transparency and the associated fineness of the pigment crystals, and also the color purity (chroma).

Abstract: Disclosed are a primer composition having photochromic property and impact resistance for coating transparent materials and a photochromic transparent material having a primer layer formed by coating and curing the primer composition. The primer composition for coating transparent materials comprises: a) 5-90 parts by weight of a polyurethane containing Brønsted salt; b) 5-50 parts by weight of a polyepoxy resin; and c) 140 parts by weight of a photochromic dye, based on 100 parts by weight of the total primer composition. The photochromic transparent material having a primer layer formed by coating and curing the primer composition shows excellent photochromic property and impact resistance.

Abstract: A thermochromic coloring color-memory composition which comprises a homogeneous solubilized mixture of (A) an electron donative coloring organic compound, (B) an electron accepting compound and (C) an ester compound represented by the specific formula as a reaction medium which controls color reactions of the components (A) and (B).

Abstract: A color filter having a filter layer comprising a fluorinated phthalocyanine pigment and at least one second pigment. In one embodiment, the second pigment has a maximum absorption at a wavelength from 400 to 500 nm to create a green color filter.

Abstract: A visible light-shielding silicone rubber composition is provided comprising (A) an organopolysiloxane, (B) an organohydrogenpolysiloxane, (C) a platinum catalyst, and (D) an azo dye. The azo dye has a light transmittance?10% in a wavelength range of up to 650 nm and ?80% in a wavelength range of at least 750 nm when a solution of the azo dye in ethanol is measured by a spectrophotometer. The composition cures into a film which shields visible light, but transmits IR light and is suited for encapsulation of LED.

Abstract: A novel photochromic latex formulation is provided, in one embodiment involving the addition of a polyurethane latex to a polyphasic latex, the formulation having improved adhesion qualities, in particular, adhesion onto a hard coat layer. In a preferred embodiment, the polyurethane latex is 20% by weight of the formulation. In addition, an optical article is provided having a coating including a novel photochromic latex formulation in accordance with the present invention, applied via a Front Side Transfer process.

Abstract: A binary optical compound formed from a preparation of proteorhodopsin, is provided. The preparation is prepared by dissolving proteorhodopsin in distilled water, where the pH is adjusted to be above 11 either by using sodium hydroxide or an appropriate buffer. The preparation is then illuminated with either white light sources, lasers, or irradiation provided from light-emitting diodes. The necessary duration is intensity dependent, varying from a few seconds to a few minutes, depending upon the source and actinic wavelength. The resulting compound has a long lifespan and may be efficiently transitioned between states.

Abstract: Use for packaging items sensitive to light of a polymer composition in the form of film or moulded articles comprising a polymeric resin and one or more photochromic additive.

Abstract: A colorant molecule is provided that includes at least one switch unit. The switch unit comprises ring-based tautomers, of which there may be more than one per chromophore, and may include donor and/or acceptor moieties.

Abstract: The invention provides methods for the application of active materials onto active surfaces useful in organic electronic devices. The methods of the invention include selecting a liquid composition including an active material and a suitable liquid medium whereby when the liquid composition is deposited on the desired active surface it has no greater than about a 40° contact angle; treating the active surface to raise its surface tension before the deposition of a liquid composition containing the desired active material is deposited thereon; and combination thereof. The invention also provides organic electronic devices having at least two active layers, wherein at least one active layer comprises an active material that was deposited using at least one practice of the method of the invention.

Abstract: An ink formulation comprises a marking component and a metal salt that absorbs laser irradiation at 700-2000 mn and thereby causes the marking component to change colour. A copper salt in particular allows effective marking with a diode or CO2 laser.

Abstract: To provide a photosensitive composition with which it is possible to form partition walls (black matrix) having excellent light shielding properties and liquid repellency. A photosensitive composition, which comprises a polymer (A) having a side chain containing a fluorine atom-containing group or a silicon atom-containing group and a side chain containing an ethylenic double bond in one molecule, a black colorant (B), a photopolymerization initiator (C) which is an O-acyloxime compound, and a photosensitive resin (D) containing an acidic group and an ethylenic double bond in one molecule, wherein the proportion of the black colorant (B) in the total solid content of the composition is from 15 to 60 mass %.

Abstract: A method of producing a radiation diffractive sensor that diffracts radiation according to Bragg's law is disclosed. The sensor is produced by forming an ordered periodic array of particles on a substrate, coating the array of particles with a polymeric matrix, curing the matrix to fix the array of particles within the matrix and contacting the fixed array with an activator, wherein the activator shifts the wavelength of radiation diffracted by the sensor from a first wavelength to a second wavelength.

Abstract: Pigment compositions each contain an organic pigment and at least one compound selected from compounds represented by the following formula (II), respectively: A-N?N—CH(COCH3)—CONH-E, B—N?N—CH(COCH3)—CONH-E or C—N?N—CH(COCH3)—CONH-E, wherein A represents a substituted or unsubstituted phenyl group, B represents a substituted or unsubstituted ?-naphthyl group, C represents a substituted or unsubstituted ?-anthraquinonyl group, D represents a particular substituted aromatic group, and E represents a substituted or unsubstituted phenyl group, with a proviso that the compounds each have at least one substituent represented by —COOM or —SO3M in which M represents a hydrogen atom, metal atom, ammonium group, organic amine group or quaternary ammonium group. Colored compositions making use of the pigment compositions and color filters making use of the colored compositions are also disclosed.

Abstract: The present invention relates to a composition for preparing a curable resin, comprising a) a compound represented by Formula 1; b) glycidyl (meth)acrylate; c) acid monoanhydride; and d) a solvent, a curable resin manufactured by the composition, and an ink composition comprising the same. The curable resin has a low viscosity and excellent flow properties, and the ink composition is excellent in terms of storage stability, heat resistance and chemical resistance.

Abstract: The present invention relates to a pigment composition or pigment dispersion suitable for producing a blue pixel portion of a color filter used in a liquid crystal display device, and also relates to a color filter. An object of the present invention is to obtain a color filter having a blue pixel portion capable of achieving a liquid crystal display device, which has a high contrast for making the images on the display screen even sharper and has a high brightness for making the display screen even brighter, and to provide a pigment composition or pigment dispersion for obtaining the color filter. The object can be achieved by the pigment composition or pigment dispersion for color filters characterized by containing a copper phthalocyanine sulfamoyl compound substituted with a sulfamoyl group having a specific polyalkylene oxide group, and a blue organic pigment.

Abstract: Describes an article, e.g., an optical article such as a lens, in which the article includes (a) a rigid substrate, e.g., a transparent ophthalmic substrate, such as a thermoset or thermoplastic substrate, having at least one surface suitable for accommodating a photochromic coating, and (b) a transparent photochromic coating comprising dendritic polymeric acrylate, e.g., polyester acrylate, on at least a portion of said surface of the substrate, the coating comprising a photochromic amount of at least one photochromic material, e.g., an organic photochromic material.

Abstract: A black resin composition capable of forming a black matrix having high OD value and high adhesion as well as high resistance is disclosed. The black resin composition is a black resin composition comprising at least a light shielding agent, a resin and a solvent, which light shielding agent contains at least titanium nitride compound particles, wherein the angle of diffraction 2? of the peak originated from (200) plane of the titanium nitride compound particles when CuK? line is used as the X-ray source is not less than 42.5° and not more than 42.8°. Using this black resin composition allows a thin resin black matrix having a high light shielding property and high resistance to be readily attained.

Abstract: A crosslinked product with excellent durability is provided that can remove intermediate colors of light while preventing brightness from deteriorating and thereby can improve color tone representation. The crosslinked product of the present invention includes a J aggregate of a dye and is characterized in that the dye is at least one dye selected from the group consisting of cyanine, merocyanine, squarylium, and porphyrin, the J aggregate of the dye is formed in a matrix resin, and the matrix resin has been crosslinked.

Abstract: The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or ?-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state.

Abstract: An ink formulation comprises a marking component, e.g. ammonium octamolybdate, and a metal salt that absorbs laser irradiation at 780-2500 nm, e.g. reduced indium tin oxide, and thereby causes the marking component to change colour.