For Solid Synthetic Polymer And Reactants Thereof Patents (Class 252/609)
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Patent number: 12077666Abstract: A resin composition for casting, containing a curable component and expandable graphite. A molded body including an element and a sealing portion that seals the element, in which the sealing portion contains the resin composition or a cured product thereof.Type: GrantFiled: September 28, 2018Date of Patent: September 3, 2024Assignee: RESONAC CORPORATIONInventors: Yasunori Kawabata, Kasumi Nakamura, Tatsuhito Fukuhara, Takahide Iwaya
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Patent number: 12043702Abstract: A novel polymer having high glass transition temperature and an excellent balance between heat resistance, high refractive index and mechanical properties, and a composition and molded article containing the polymer are provided. The polymer according to the invention has a first structural unit represented by at least one of formulae (1-1), (1-2) and (1-3) below and a second structural unit having either a secondary amino structure or a tertiary amino structure at two or more terminals.Type: GrantFiled: April 5, 2022Date of Patent: July 23, 2024Assignee: JSR CORPORATIONInventors: Ryouyuu Hifumi, Toshiaki Kadota, Nobuyuki Miyaki, Shintarou Fujitomi, Yasutaka Yoshida, Ryouji Tatara
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Patent number: 11810695Abstract: A cable, in particular a power and/or telecommunication cable, has at least one elongated electrically conductive element, and at least one fire-resistant layer surrounding said elongated electrically conductive element. The fire-resistant layer is a ceramic layer in direct physical contact with the elongated electrically conductive element.Type: GrantFiled: July 9, 2020Date of Patent: November 7, 2023Assignee: NEXANSInventors: Maxime Auvergne, Franck Gyppaz
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Patent number: 11686410Abstract: A rubber composition for a cover layer of a hydraulic hose includes: ethylene vinyl acetate copolymer (EVA); and ethylene-propylene-diene terpolymer (EPDM). In an embodiment, the composition includes ethylene vinyl acetate copolymer (EVA) and ethylene-propylene-diene terpolymer (EPDM) and additives. The additives may include carbon black with a content of around 15 phr, silica with a content of around 20 phr, di-octyl adipate with a content of around 18 phr, aluminium hydroxide with a content of around 124 phr, magnesium hydroxide with a content of around 30 phr, and other chemicals with a content of around 20 phr. The other chemicals may include zinc oxide, peroxide curative, antioxidant, coagents and processing aids.Type: GrantFiled: December 20, 2018Date of Patent: June 27, 2023Assignee: DANFOSS POWER SOLUTIONS II TECHNOLOGY A/SInventors: Recep Muco, Muslum Eren, Volkan Karayazi, Tekin Coskun, Ozgur Caliskan
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Patent number: 11377517Abstract: The present invention relates to a phosphorus containing polyol, obtainable or obtained by a process comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I) as defined herein, as well as the process for preparing a phosphorus containing polyol, comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I). Furthermore, the present invention relates to the use of a phosphorus containing polyol as disclosed herein as a flame retardant, to a process for the preparation of a polyurethane and the polyurethane as such.Type: GrantFiled: April 15, 2014Date of Patent: July 5, 2022Assignee: BASF SEInventors: Marco Balbo Block, Jens Ferbitz, Christoph Fleckenstein, Birgit Hupka
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Patent number: 11136454Abstract: The present invention provides a thermosetting resin composition containing (A) a maleimide compound, (B) an epoxy resin having at least two epoxy groups in one molecule, (C) a copolymer resin having a structural unit derived from an aromatic vinyl compound and a structural unit derived from a maleic anhydride, (D) a silica treated with an aminosilane coupling agent, and (E) a flame retardant dispersion.Type: GrantFiled: December 7, 2016Date of Patent: October 5, 2021Assignee: Showa Denko Materials Co., Ltd.Inventors: Keisuke Kushida, Hiroshi Shimizu, Minoru Kakitani, Yoshikatsu Shiraokawa, Tatsunori Kaneko
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Patent number: 11084917Abstract: The invention relates to a novel flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) wherein R1, R2 are the same or different and are each C1-C8-alkyl, linear or branched, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl, or R1 and R2 form one or more rings with each other, M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; as component B, from 0 to 75% by weight of a synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 30% by weight of telomeric phosphinic acid salts as component D, from 0 to 20% by weight of organo phosphonic acid salt, as component E, from 0 to 5% by weight of phosphonic acid salt, the sum of the components always being 100% by weight, and wherein the angle of repose of said flame retardant-stabilizer combination is between 5° and 45°.Type: GrantFiled: September 6, 2017Date of Patent: August 10, 2021Assignee: Clariant Plastics & Coatings LtdInventors: Harald Bauer, Sebastian Hörold, Martin Sicken
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Patent number: 10962685Abstract: There is provided a plastic optical fiber including a core and at least one layer of a clad formed on an outer circumferential surface of the core, wherein a transmission band is 100 MHz or wider, as measured under conditions of a wavelength of 650 nm and a launch NA=0.65; and a transmission loss is 350 dB/km or less, as measured under conditions of a wavelength of 650 nm and a launch NA=0.1, after exposure to an environment of a temperature of 105° C. for 1000 hours.Type: GrantFiled: September 11, 2019Date of Patent: March 30, 2021Assignee: Mitsubishi Chemical CorporationInventors: Hideki Kihara, Noboru Fujikura
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Patent number: 10947379Abstract: The present disclosure relates to a halogen-free flame retardant additive for polymers, such as polyolefins, comprising (i) a phosphorous-nitrogen-containing component containing amine and/or ammonium groups; and (ii) a (meth)acrylic acid homo- or co-polymer selected from the group consisting of a partially or fully neutralized salt of poly((meth)acrylic acid), a partially or fully neutralized salt of a partially crosslinked poly((meth)acrylic acid), a partially or fully neutralized salt of a copolymer of an olefin and (meth)acrylic acid comprising at least 50% by weight of (meth)acrylic acid repeating units, and any combinations of the foregoing polymers. The present disclosure also relates to a flame retardant polymer composition comprising the flame retardant additive and a method of reducing the flammability of a polymer, in particular a polyolefin, using the flame retardant additive.Type: GrantFiled: December 21, 2018Date of Patent: March 16, 2021Assignee: PP POLYMER ABInventor: Swaraj Paul
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Patent number: 10672535Abstract: Halogen-free polymer composite materials, which are commonly for use in sheathing and insulation applications for wire and cable, are provided. The composite materials include a polymeric blend, which includes ethylene/?-olefin copolymer and polyolefin, a hydrated metal oxide flame-retardant, such as hydrated magnesium oxide, and an antimony compound. In some instances, the polymeric blend may include an olefin/unsaturated ester copolymer.Type: GrantFiled: February 23, 2018Date of Patent: June 2, 2020Assignees: SACO AEI Polymers, Inc., AEI Compounds Ltd.Inventors: Mike Edward Slevin, David Geraint Roberts
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Patent number: 10662308Abstract: The invention relates to a flame-retardant thermoplastic material, comprising thermoplastic base resin, a flame retardant, and an optional antioxidant, wherein the flame retardant comprises a complex of phosphine oxide and a transition metal salt. The invention also relates to flame-retardant thermoplastic expanded beads. A foam molding prepared from the flame-retardant thermoplastic expanded beads has good flame-retardant and antistatic properties, has excellent mechanical properties and is widely used.Type: GrantFiled: April 28, 2017Date of Patent: May 26, 2020Assignees: China Petroleum & Chamical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical CorporationInventors: Peng Guo, Mingfu Lyu, Yaohui Xu, Shijun Zhang, Hui Quan, Kai Xu, Fuyong Bi, Wenbo Song
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Patent number: 10543511Abstract: A material coating system for an apparatus having a housing configured to contain a fluid is disclosed herein. A multi-layer coating is applied to the housing to mitigate damage caused by external factors. The multi-layer coating includes: a layer of a primer coating having anti-corrosive properties, a layer of a mid coating having mechanical and chemical properties capable of at least partially closing a hole in the housing to avoid fluid leakage and optionally a layer of a top coating having properties that resist ultraviolet radiation from passing therethrough.Type: GrantFiled: March 10, 2017Date of Patent: January 28, 2020Assignee: ABB Power Grids Switzerland AGInventors: George K Frimpong, Alberto Prieto Colmenero, Claire Pitois
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Patent number: 10538653Abstract: A flame retardant compound is provided. The flame retardant compound includes a polymer base resin, a carbonific host compound, and a guest compound including at least one atom of a transition metal. The carbonific host compound and the guest compound form a host-guest complex, and the host-guest complex acts to inhibit at least one of smoke release and smoke formation when exposed to heat. The host-guest complex is distributed within the polymer base resin. An intumescent flame retardant compound is also provided. The intumescent flame retardant compound includes a base resin, an acid donor, a spumific agent, a cyclodextrin host compound, and a guest compound including at least one atom of molybdenum. The cyclodextrin host compound and the guest compound form a host-guest complex. The acid donor, carbonific host compound, and spumific agent react when exposed to a temperature above 280° C. to form a foam.Type: GrantFiled: August 28, 2019Date of Patent: January 21, 2020Assignee: CORNING OPTICAL COMMUNICATIONS LLCInventors: Dayue Jiang, Kirsten Langfeld, Brandon Robert Williamson
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Patent number: 10431375Abstract: A hardened inductive device and systems and methods for protecting the inductive device from impact is provided. The inductive device is hardened with protective coating and/or an armor steel housing. The hardened inductive device is protected from impact by an object such as a bullet and leakage of dielectric fluid is prevented. Acoustic and vibration sensors are provided to detect the presence and impact, respectively, of an object in relation to the inductive device housing. The measurements of the acoustic and vibration sensors are compared to thresholds for sending alarms to the network control center and initiating shut-down and other sequences to protect the active part. The acoustic sensor results are utilized to determine the location of origin of the projectile.Type: GrantFiled: October 22, 2015Date of Patent: October 1, 2019Assignee: ABB Schweiz AGInventors: George K. Frimpong, Alberto Prieto, Mirrasoul J. Mousavi, James Stoupis, Ed G teNyenhuis, Jeremy R. Schueler, Andrew Bleich, Elizabeth D. Sullivan, Claude J. Lambert, Petter A. Fiskerud, Andrew J. Wall, Gary C. McLeish, Thomas McDonald, Ronald A. Kupiec
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Patent number: 10336858Abstract: The invention relates to a process for preparing bromine-containing polymer, comprising a Friedel-Crafts alkylation reaction of tetrabromoxylylene dihalide, or tetrabromoxylylene dihalide in combination with pentabromobenzyl halide, with a reactant having one or more six-membered aromatic rings, wherein the reaction takes place in a solvent in the presence of a Friedel-Crafts catalyst, and isolating from the reaction mixture the bromine-containing polymer. The so-formed polymers and their use as flame retardants form additional aspects of the invention.Type: GrantFiled: July 7, 2015Date of Patent: July 2, 2019Assignee: Bromine Compounds Ltd.Inventors: Mark Gelmont, Michael Yuzefovich, Andrew Piotrowski, David Yoffe, Ron Frim, Yaniv Hirschsohn
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Patent number: 9879184Abstract: The invention relates to a preparation process of a flame retardant composition made from brominated bismuth and/or antimony compounds complexed with melamine, in which melamine, at least one between the bismuth carbonate and antimony sesquioxide, hydrobromic acid in aqueous solution are placed in contact with each other so as to trigger chemical reactions which lead to the formation of a complex of brominated bismuth or brominated antimony with melamine and melamine bromohydrate. The reagents are placed in contact in the presence of at least one reaction carrier defined by at least one compound chosen from the group consisting of melamine, melamine phosphate, melamine polyphosphate, ammonium phosphate, ammonium polyphosphate, triphenyl-phosphate, graphite, silica, lignin, coke and compounds containing triazine rings condensed or linked by —NH groups. The reaction carrier is not involved in the reactions. There are no polymeric compounds in quantities such as to create a polymer matrix.Type: GrantFiled: July 28, 2015Date of Patent: January 30, 2018Assignee: SICHIM ALFA S.R.L.Inventors: Anita Castellucci, Alessandro Bottoni
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Patent number: 9862615Abstract: The invention relates to the preparation of hydrated alkaline silicate compositions for making intumescent layers for fireproof glazing, said compositions being such that, when applied between glass sheets, they form a solid gel without drying, wherein the compositions are obtained from a stable and fluid solution subjected to partial dehydration at a limited temperature and under a reduced pressure for a duration shorter than that required for the mass curing of the final composition.Type: GrantFiled: November 17, 2009Date of Patent: January 9, 2018Assignee: AGC GLASS EUROPEInventors: Pierre Goelff, Eric Jordan
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Patent number: 9828503Abstract: The invention relates to the use of thermal plastic molding compositions comprising A) from 10 to 97% by weight of a thermoplastic polyamide, B) from 1 to 10% by weight of red phosphorus, C) from 0.15 to 6% by weight of a dialkylphosphinic salt, where the ratio of B) to C) is from 6:1 to 6:4, D) from 1 to 10% by weight of an ethylene copolymer as impact modifier comprisingas component D) a copolymer of D1) from 40 to 98% by weight of ethylene D2) from 2 to 40% by weight of a (meth)acrylate having from 1 to 18 carbon atoms, or/and D3) from 0 to 20% by weight of functional monomers selected from the group of the ethylenically unsaturated mono- or dicarboxylic acids or of the carboxylic anhydrides or epoxide groups, or a mixture of these, or an ethylene-(meth)acrylic acid copolymer neutralized with zinc up to an extent of 72%, E) from 0 to 5% by weight of talc powder with a median particle size (d50 value) below 7.Type: GrantFiled: April 7, 2014Date of Patent: November 28, 2017Assignee: BASF SEInventors: Michael Roth, Klaus Uske, Christoph Minges
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Patent number: 9550856Abstract: Embodiments of the invention include a polymer polyol dispersions. The polymer dispersions include a reaction product of a reaction system, where the reaction system includes: at least one polyol, at least one phosphorus based flame retardant having at least one active hydrogen attached to a nitrogen or oxygen atom, at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom, at least one catalyst, and at least one polyisocyanate.Type: GrantFiled: December 17, 2012Date of Patent: January 24, 2017Assignee: Dow Global Technologies LLCInventors: Paul Cookson, Daniel Hoehener, Francois M. Casati
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Patent number: 9453980Abstract: An optical fiber cable is formed with an optical fiber and a coating layer made up of at least one layer provided on the outer periphery of the optical fiber. The material for forming the coating layer is made of a halogen-free resin composition containing polyolefin resin (A) and melt tension enhancer (B).Type: GrantFiled: March 20, 2014Date of Patent: September 27, 2016Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Tsuyoshi Kimura, Yoshihiro Tsukamoto, Kouji Asano
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Patent number: 9422410Abstract: Provided is a recyclable flame-retardant foamed styrene resin composition having high flame-retardancy and heat stability by adding little bromine-containing flame retardant. A flame-retardant foamed styrene resin composition containing (A) a styrene resin, (B) a mixture of (B1) tetrabromobisphenol A-bis(2,3-dibromo-2-methylpropyl ether) and (B2) another bromine-containing flame retardant, (C) zinc-modified hydrotalcite, (D) zeolite, and (G) a foaming agent, containing 0.005-0.08 parts by weight of (C) the zinc-modified hydrotalcite per 100 parts by weight of (A) the styrene resin.Type: GrantFiled: December 13, 2013Date of Patent: August 23, 2016Assignee: DAI-ICHI KOGYO SEIYAKU CO., LTD.Inventors: Masahito Nishiura, Hideaki Onishi, Hisanori Semori, Naomi Toyoshima
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Patent number: 9396839Abstract: The present invention relates to a cable comprising one or more insulated conductors which are embedded in a bedding composition having improved flame retardancy. The bedding composition comprises a resin (A) and inorganic filler (B), which is a hydroxide or hydrated compound.Type: GrantFiled: January 29, 2008Date of Patent: July 19, 2016Assignee: Borealis Technology OYInventors: Bernt-Ake Sultan, James Elliott Robinson, Wendy Loyens, Susanna Lieber
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Patent number: 9089730Abstract: This invention relates to a formulation material and its method useful in forestry firefighting, the formulation material comprising: (a) an anhydride copolymer having a structural formula wherein a functional group X of said formula is at least one alkyl group selected from the family consisting of methyl, ethyl, and propyl groups! and (b) at least 0.1%, by weight, of at least one cross-linking agent for said anhydride copolymer, said agent selected from the group of cross-linking agents consisting of a biopolymer and a tannin, wherein a weight ratio of said anhydride copolymer to said cross-linking agent is at least 2:1, and wherein a total weight of said anhydride copolymer and said cross-linking agent, within the formulation, is at least 25% on an anhydrous basis.Type: GrantFiled: November 25, 2011Date of Patent: July 28, 2015Assignee: ZZAKEY TECHNOLOGIES LTDInventors: Itzhak Shalev, Mircea Bucevschi, Monica Colt
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Patent number: 9085678Abstract: Commercial thermoplastic clean flame retardant materials in wire and cable insulation are mechanically unstable due to high filler loading. In the present invention, thermoplastic, black color, clean flame retardant composition using carbon nano tubes (CNT) is made. The resultant compositions possess very low smoke and toxicity. CNT with outer diameter of 40-60 nm and length of under 20 ?m are used to increase mechanical properties and flame retardancy. Thermo plastically extruded composition consists of each component by parts by weight as follows: 100 of resin (polyolefin or 100 of polyolefin/ethylene propylene diene monomer (EPDM)), 90-150 of non halogen containing flame retardants, 1-20 of auxiliary secondary flame retardant agents, 2-4 of CNT (outer diameter of 40-60 nm) and length under 20 ?m and 0.2-1.0 of antioxidants. A reliable method for producing thermoplastic black color clean flame retardant insulation material for wire and cable without deterioration of mechanical properties is discussed.Type: GrantFiled: January 8, 2010Date of Patent: July 21, 2015Assignee: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGYInventors: Ahmed Ali Basfar, Hun Jai Bae
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Patent number: 9012546Abstract: This invention relates to a process for producing compounds derived from 9,10-Dihydro-9-Oxa-10-Phosphaphenantrene-10-oxide (DOPO). In particular, the invention relates to producing DOPO-derived compounds by reacting DOPO with diol compounds in the presence of a catalyst. This invention also relates to DOPO derived composition containing a high melting point diastereomer. The DOPO derived compounds may be useful as flame-retardants.Type: GrantFiled: March 28, 2011Date of Patent: April 21, 2015Assignee: Albemarle CorporationInventors: Qiang Yao, Junzuo Wang, Arthur G. Mack
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Patent number: 9012543Abstract: The instant invention relates to 3,3?-bis(3,4-dihydro-3-phenyl-2H-1,3-benzoxazin-6-yl)-1(3H)-isobenzofuranone and analogues based on phenolphthalein, formaldehyde and a primary amine. Such compounds are, when cured to form polymeric networks, difficultly inflammable and resistant to high temperatures. Such compounds may especially be used in the production of printed wiring boards.Type: GrantFiled: September 27, 2005Date of Patent: April 21, 2015Assignee: Huntsman Advanced Materials Americas LLCInventors: Roger Tietze, Dave Orser, Yefim Blyakhman, Mark Bryant, Bor-Sheng Lin
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Patent number: 9005761Abstract: A halogen-free resin composition includes (A) 100 parts by weight of epoxy resin; (B) 1 to 100 parts by weight of benzoxazine resin per 100 parts by weight of (A); (C) 1 to 100 parts by weight of styrene-maleic anhydride per 100 parts by weight of (A); (D) 0.5 to 30 parts by weight of amine curing agent per 100 parts by weight of (A); and (E) 5 to 150 parts by weight of halogen-free flame retardant per 100 parts by weight of (A). The composition obtains properties of low dielectric constant, low dissipation factor, high heat resistance and flame retardancy by specific composition and ratio. Thus, a prepreg or a resin film, which can be applied to a copper clad laminate and a printed circuit board, is formed.Type: GrantFiled: December 22, 2011Date of Patent: April 14, 2015Assignee: Elite Material Co., Ltd.Inventor: Yu-Te Lin
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Patent number: 8991321Abstract: The invention relates to a polyethylene composition comprising a mixture of flame retardants which are bromine-containing polymers. The polyethylene composition is useful in the manufacture of pallets. A process for making the polyethylene composition through a masterbatch route is also disclosed.Type: GrantFiled: December 23, 2010Date of Patent: March 31, 2015Assignee: Bromine Compounds Ltd.Inventors: Yoav Bar-Yaakov, Yaniv Hirschsohn, Ita Finberg, Pierre Alexandre Georlette
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Publication number: 20150080276Abstract: The present invention relates to phosphoric ester preparations with reduced hygroscopicity, to use of these as flame retardants and hydraulic fluids, and to polyurethanes which comprise the phosphoric ester preparations of the invention.Type: ApplicationFiled: September 9, 2014Publication date: March 19, 2015Inventors: Jan-Gerd HANSEL, Heiko TEBBE
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Publication number: 20150073083Abstract: Treated, inorganic, non-halogenated flame retardants, methods for treating inorganic, non-halogenated flame retardants for better dispersion and improved powder flow performance in plastics, and apyrous plastics formed from such treated, inorganic, non-halogenated flame retardants are provided. In accordance with an exemplary embodiment, a method for treating an inorganic, non-halogenated flame retardant includes providing a wax emulsion, the wax emulsion comprising a polymer wax, an alkali, and water. The wax emulsion is blended with an inorganic, non-halogenated flame retardant for a period of time to form a treated inorganic, non-halogenated flame retardant. The treated inorganic, non-halogenated flame retardant is dried.Type: ApplicationFiled: August 7, 2014Publication date: March 12, 2015Inventors: Yue Wen Liu, Megan Mao, Jun Li
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Patent number: 8968611Abstract: The present invention provides a process of solidifying a phosphoric ester-based flame retardant in which high-level purification is not required and stress load is not employed. In the process of solidifying a phosphoric ester-based flame retardant, a seed crystal is added at a temperature of not higher than 55° C. and at an amount of 1 to 50 parts by mass with respect to 100 parts by mass of a phosphoric ester compound in a molten state, which compound is represented by the following Formula (I): (wherein, R1 and R2 each independently represent a hydrogen atom or a methyl group; and n represents a number of 1 to 5). It is preferred that the amount of the phosphoric ester compound represented by the aforementioned Formula (I) wherein n is 1 be less than 90% by mass and that R1 and R2 be a hydrogen atom.Type: GrantFiled: June 9, 2008Date of Patent: March 3, 2015Assignee: Adeka CorporationInventors: Tetsuo Kamimoto, Yuki Tanaka, Tomomasa Tezuka, Hisashi Murase
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Patent number: 8969909Abstract: The present disclosure relates generally to a light emitting diode assembly and a thermal control blanket. The light emitting diode assembly and the thermal control blanket have advantageous reflective and thermal properties.Type: GrantFiled: June 1, 2011Date of Patent: March 3, 2015Assignee: E I du Pont de Nemours and CompanyInventors: Christopher Dennis Simone, Thomas Edward Carney
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Publication number: 20150044469Abstract: A mineral composition made from a mixed solid phase of calcium and magnesium carbonates, method of preparing same and use thereof. A mineral composition made from a mixed solid phase of calcium and magnesium carbonates, formed from a crystallised calcium portion and a crystallised magnesium portion in the form of platelets, the crystals of the calcium portion and those of the magnesium portion being aggregated in the form of composite aggregates, said aggregates themselves being at least partially agglomerated, said calcium portion comprising at least one carbonate chosen from the group consisting of calcite, aragonite and the mixtures thereof, said magnesium portion comprising hydromagnesite in platelet form, said mixed solid phase having a bulk density less than or equal to 250 kg/m3, and greater than or equal to 80 kg/m3, measured according to standard EN 459.2.Type: ApplicationFiled: March 22, 2013Publication date: February 12, 2015Applicant: S.A. Lhoist Recherche et DeveloppementInventors: Marion Lorgouilloux, Robert Sebastian Gartner, Marc Pelletier, Thierry Chopin
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Patent number: 8940818Abstract: Halogen-free flame retardant for incorporation into a polymer matrix, wherein the flame retardant contains at least ammonium polyphosphate(s) and/or derivatives thereof and an oligomeric or polymeric 1,3,5-triazine derivative or mixtures of several thereof and at least one compound selected from monozinc phosphate, zinc borate, trizinc phosphate, zinc pyrophosphate, zinc polyphosphate, zinc hydroxystannate, zinc stannate, boron phosphate, monoaluminium phosphate, trialuminium phosphate, aluminium metaphosphate and mixtures thereof, precondensed melamine derivatives, melamine salts and adducts, ethylenediamine phosphate, piperazine phosphate, piperazine polyphosphate, 1,3,5-trihydroxyethyl isocyanurate, 1,3,5-triglycidyl isocyanurate and triallyl isocyanurate.Type: GrantFiled: July 25, 2008Date of Patent: January 27, 2015Assignee: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Siegfried Mengel
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Publication number: 20150018453Abstract: A flame retardant composition for thermoplastic molding materials, and also moldings, fibers or films that can be prepared from the flame retardant molding materials. The composition includes 30 to 70% by weight of melamine cyanurate and of 30 to 70% by weight of porous amorphous glass particles. The composition is prepared from foam glass produced continuously in a high-temperature extruder. The sum of the components is 100% by weight.Type: ApplicationFiled: December 21, 2012Publication date: January 15, 2015Inventors: Voss Hans-Juergen, Uwe Ferner
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Publication number: 20150018464Abstract: The invention relates to mixed alkali-aluminum phosphites of the formula (I) Al2.00Mz(HPO3)y(OH)vx(H2O)w??(I) in which M represents alkali metal ions, z is 0.01 to 1.5, y is 2.63 to 3.5, v is 0 to 2, w is 0 to 4; to a process for preparation thereof and to the use thereof.Type: ApplicationFiled: November 28, 2012Publication date: January 15, 2015Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Patent number: 8933159Abstract: Described are a particular group of novel aromatic hydrocarbon telomers that, on bromination, result in the formation of novel flame retardants having a uniquely beneficial combination of properties. The resultant flame retardants and uses thereof are also described. The disclosure includes descriptions of methods for preparing both the aromatic hydrocarbon telomers and the brominated flame retardant polymers.Type: GrantFiled: November 30, 2009Date of Patent: January 13, 2015Assignee: Albemarle CorporationInventors: William J. Layman, Jr., Charles H. Kolich, Arthur G. Mack, Jonathan P. McCarney, Govindarajulu Kumar, Jorge Morice, Zhongxin Ge, Bo Liu, Douglas W. Luther, Kimberly M. White, Bruce C. Berris, Junzuo Wang
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Publication number: 20150005427Abstract: Mixtures of aluminum phosphite with sparingly soluble aluminum salts and extraneous ions, process for preparation thereof and use thereof The invention relates to mixtures of aluminum phosphite with sparingly soluble aluminum salts and nitrogen-free extraneous ions, comprising 80 to 99.898% by weight of aluminum phosphite of the formula (I) Al2(HPO3)3×H2O??(I) in which x is 0 to 4, 0.1 to 10% by weight of sparingly soluble aluminum salts and 0.002 to 10% by weight of nitrogen-free extraneous ions; to a process for preparation thereof and use thereof.Type: ApplicationFiled: November 28, 2012Publication date: January 1, 2015Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Publication number: 20150005421Abstract: The invention relates to mixtures of at least one diphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each independently H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, R5 is C1-C18-alkylene, C2-C18-alkenylene, C6-C18-arylene, C7-C18-alkylarylene with at least one dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each independently C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl. The invention also relates to a process for preparing these mixtures and to the use thereof.Type: ApplicationFiled: December 8, 2012Publication date: January 1, 2015Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
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Patent number: 8921439Abstract: A monohydroxy cyclic phosphonate substantially free of polyhydroxy phosphonate is employed as a reactive flame retardant in flexible polyurethane.Type: GrantFiled: September 19, 2011Date of Patent: December 30, 2014Assignee: ICL-IP America Inc.Inventors: Andrew Piotrowski, Anantha N. Desikan, Sophia Dashevsky
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Patent number: 8921480Abstract: An eco-friendly (meth)acrylic flame retardant copolymer includes a phosphorous-based acrylic monomer to provide a high index of refraction and excellent flame retardancy.Type: GrantFiled: April 29, 2013Date of Patent: December 30, 2014Assignee: Cheil Industries Inc.Inventors: Jin Hwa Chung, Kee Hae Kwon, Kwang Soo Park, Ja Kwan Koo, Man Suk Kim, Yong Hee Kang, Jin Seong Lee
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Publication number: 20140378565Abstract: A liquid flame retardant composition which comprises one or more flame retarding agents, which are the epoxides obtainable by reacting tetrabromobisphenol A with epichlorohydrin and their end-capped derivatives represented by Formula (1) is provided. The liquid composition is especially useful in the preparation of rigid polyurethane foams.Type: ApplicationFiled: September 9, 2014Publication date: December 25, 2014Inventors: Mark Gelmont, Michael Peled, Dina Alon, Ron Frim, Yoav Bar-Yaakov
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Publication number: 20140371361Abstract: The invention relates to aluminum hydrogenphosphites of the formula (I) Al2.00(HPO3)v(H2PO3)y×(H2O)??(I) in which v is 2 to 2.99, y is 2 to 0.01 and z 0 to 4; to a process for preparation thereof and to the use thereof.Type: ApplicationFiled: November 28, 2012Publication date: December 18, 2014Applicant: Clariant Finance (BVI) LimitedInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Publication number: 20140361230Abstract: The present invention relates to flame retardant compositions comprising (a) at least one triazine-intercalated metal phosphate with open framework structure with at least one monomer unit of the following general formula (I): (A-H)a(+)[Mbm+(H2PO4)x1(?)(HPO4)x22(?)(PO4)x33(?)(PO3)y(?)](a?)*pH2O??(I) and (b) at least one flame retardant component other than (a). The invention further relates to the use thereof, the specific compounds of the general formula (I) and to the preparation thereof.Type: ApplicationFiled: August 5, 2011Publication date: December 11, 2014Inventors: Hans-Gunter Kostler, Trupte Dave, Wolfgang Wehner
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Patent number: 8900491Abstract: A flame retardant filler having brominated silica particles, for example, imparts flame retardancy to manufactured articles such as printed circuit boards (PCBs), connectors, and other articles of manufacture that employ thermosetting plastics or thermoplastics. In this example, brominated silica particles serve both as a filler for rheology control (viscosity, flow, etc.) and a flame retardant. In an exemplary application, a PCB laminate stack-up includes conductive planes separated from each other by a dielectric material that includes a flame retardant filler comprised of brominated silica particles. In an exemplary method of synthesizing the brominated silica particles, a monomer having a brominated aromatic functional group is reacted with functionalized silica particles (e.g., isocyanate, vinyl, amine, or epoxy functionalized silica particles).Type: GrantFiled: May 6, 2011Date of Patent: December 2, 2014Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III
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Publication number: 20140350149Abstract: The invention relates to a mixture of at least one dialkylphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, with at least one different dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl, with the proviso that at least one of the R3 and R4 radicals is different than R1 and R2.Type: ApplicationFiled: December 13, 2012Publication date: November 27, 2014Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
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Publication number: 20140336318Abstract: The present invention relates to a method for preparing hierarchically ordered structures of inorganic phosphate particles, homogeneously deposited on the surface of a phyllosilicate, which is characterized in that it comprises the following steps: a) obtaining an acid solution of precursor compounds of an inorganic phosphate; b) preparing a dispersion of particles of a phyllosilicate in aqueous medium and acidifying the phyllosilicate dispersion by adding at least one acid, thereby obtaining an acid dispersion; c) mixing the acid solution obtained in step a) with the dispersion obtained in step b); and d), with stirring, adding a base to the mixture obtained in step c) until the required pH value for precipitating the corresponding inorganic phosphate on the phyllosilicate particles has been achieved, resulting in a hierarchically ordered structure of homogeneously distributed submicrometric or nanometric inorganic phosphate particles supported on the phyllosilicate surface.Type: ApplicationFiled: May 14, 2012Publication date: November 13, 2014Applicant: TOLSA, S.A.Inventors: Antonio Esteban Cubillo, Julio Santaren Rome, Eduardo Aguilar Diez, Antonio Alvarez Berenguer, Elena Palacios Zambrano, Maria Pilar Leret Molto, Jose Francisco Fernandez Lozano, Antonio Heliodoro De aza Moya, Miguel Angel Rodriguez Barbero
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Publication number: 20140336325Abstract: The invention relates to flame retardant mixtures comprising flame retardant and aluminum phosphites, to processes for preparation thereof and to the use thereof.Type: ApplicationFiled: November 28, 2012Publication date: November 13, 2014Applicant: Clariant Finance (BVI) LimitedInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Publication number: 20140329933Abstract: The invention relates to mixtures of at least one diphosphinic acid of the formula (I) in which R1, R2 are each H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl R4 is C1-C18-alkylene, C2-C18-alkenylene, C6-C18-arylene, C7-C18-alkylarylene with at least one alkylphosphinic acid of the formula (II) in which R3 is C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl. The invention also relates to a process for preparing these mixtures and to the use thereof.Type: ApplicationFiled: December 8, 2012Publication date: November 6, 2014Inventors: Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
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Patent number: 8877838Abstract: The present invention relates to flame retardant polymer compositions which comprise melamine phenylphosphinates and mixtures with dihydro-oxa-phosphaphenanthrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.Type: GrantFiled: November 16, 2009Date of Patent: November 4, 2014Assignee: BASF SEInventors: Sabine Fuchs, Thomas Weiβ