With Boron, Aluminum, Thallium, Or Indium Patents (Class 252/62.58)
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Patent number: 11551849Abstract: A sintered material contains Fe in an amount of from 8 mol % to 37 mol % in terms of Fe2O3, Zn in an amount of from 30 mol % to 60 mol % in terms of ZnO, Cu in an amount of from 1 mol % to 7 mol % in terms of CuO, Ni in an amount of from 3 mol % to 17 mol % in terms of NiO, and Si in an amount of from 7 mol % to 28 mol % in terms of SiO2. A mole ratio (SiO2/Fe2O3) of the SiO2 to the Fe2O3 is from 0.2 to 3.5. The sintered material contains B in an amount of from 0.05 mol parts to 0.5 mol parts.Type: GrantFiled: May 22, 2020Date of Patent: January 10, 2023Assignee: Murata Manufacturing Co., Ltd.Inventors: Yuki Nishikawa, Atsuo Hirukawa, Kazutoshi Sugii
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Patent number: 11348711Abstract: The invention provides a core-shell particle which can provide, by being calcinated, epsilon type iron oxide-based compound particles that have a small coefficient of variation of primary particle diameter and show excellent SNR and running durability when employed in a magnetic recording medium as well as applications thereof. The core-shell particle includes: a core including at least one iron oxide selected from Fe2O3 or Fe3O4, or iron oxyhydroxide; and a shell that coats the core, the shell including a polycondensate of a metal alkoxide and a metal element other than iron, as well as applications thereof.Type: GrantFiled: September 17, 2018Date of Patent: May 31, 2022Assignee: FUJIFILM CorporationInventors: Kenji Naoi, Masashi Shirata, Takashi Fujimoto
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Patent number: 11289254Abstract: An insulator-coated soft magnetic powder includes a core particle including a base portion containing a soft magnetic material and an oxide film that is provided on a surface of the base portion and that contains an oxide of an element contained in the soft magnetic material, and an insulating particle that is provided on a surface of the core particle and that has an insulating property, wherein an average particle diameter after heat treatment after being subjected to a heat treatment of heating at 1000° C. is 90% or more and 110% or less of an average particle diameter before heat treatment before being subjected to the heat treatment.Type: GrantFiled: April 26, 2019Date of Patent: March 29, 2022Inventor: Atsushi Nakamura
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Patent number: 11201007Abstract: A modulated inductance module includes an inductor including one or more electrical conductors disposed around a ferromagnetic ceramic element formed on a semiconductor die, wherein the inductor further has two or more metal oxides having fluctuations in metal-oxide compositional uniformity less than or equal to 1.50 mol % throughout said ceramic element, the ceramic element has crystalline grain structure having a diameter that is less than or equal to 1.5× a mean grain diameter, and the semiconductor die contains active semiconductor switches or rectifying components that are in electrical communication with the one or more electrical conductors of the inductor.Type: GrantFiled: November 11, 2019Date of Patent: December 14, 2021Inventor: L. Pierre de Rochemont
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Patent number: 11139095Abstract: A multilayer coil component including: a magnetic part that contains Fe, Zn, V, and Ni and optionally contains Mn and/or Cu; and a conductor part that contains copper. In the magnetic part, Fe is in an amount of 34.0 to 48.5 mol % expressed as Fe2O3 equivalent, Zn is in an amount of 6.0 to 45.0 mol % expressed as ZnO equivalent, Mn is in an amount of 0 to 7.5 mol % expressed as Mn2O3 equivalent, Cu is in an amount of 0 to 5.0 mol % expressed as CuO equivalent, and V is in an amount of 0.5 to 5.0 mol % expressed as V2O5 equivalent, with respect to the total amount of Fe expressed as Fe2O3 equivalent, Zn expressed as ZnO equivalent, V expressed as V2O5 equivalent, and Ni expressed as NiO equivalent, and optionally present Cu expressed as CuO equivalent and optionally present Mn expressed as Mn2O3 equivalent.Type: GrantFiled: April 24, 2017Date of Patent: October 5, 2021Assignee: Murata Manufacturing Co., Ltd.Inventors: Yoshiko Okada, Atsushi Yamamoto
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Patent number: 10236104Abstract: An inductor is provided including a multilayer body in which a plurality of magnetic layers containing a ferrite are laminated. A coil part including a plurality of conductive patterns is disposed in the multilayer body. External electrodes are electrically connected to the coil part. The ferrite may contain iron (Fe), manganese (Mn), nickel (Ni), zinc (Zn), and vanadium (V), and the ferrite may contain 40 to 55 mol % of iron (Fe) calculated as iron oxide (Fe2O3), 5 to 20 mol % of nickel (Ni) calculated as nickel oxide (NiO), 15 to 25 mol % of zinc (Zn) calculated as zinc oxide (ZnO), 15 to 30 mol % of manganese (Mn) calculated as manganese oxide (MnO), and 1 to 4 mol % of vanadium (V) calculated as vanadium oxide (V2O5).Type: GrantFiled: May 7, 2014Date of Patent: March 19, 2019Assignee: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Young Il Lee, Byeong Cheol Moon, So Yeon Song, Ic Seob Kim, Soo Hwan Son
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Patent number: 10037839Abstract: A magnetic hydrotalcite composite which is useful in fields such as wastewater treatment, ultraviolet absorption, electromagnetic wave absorption and acid gas absorption, and a production method thereof. The magnetic hydrotalcite composite comprises an inner layer and an outer layer, in which the inner layer is made of a hydrotalcite compound and the outer layer is made of a ferrite compound.Type: GrantFiled: December 2, 2014Date of Patent: July 31, 2018Assignee: KYOWA CHEMICAL INDUSTRY CO., LTD.Inventors: Xing Dong Wang, Yoshihito Iwamoto, Koichi Nedachi
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Patent number: 9881743Abstract: A first ceramic layer of a composite laminate included in a common mode choke coil is formed from a sintered body of a glass ceramic material. The glass ceramic material contains 40 to 90 percent by weight of a glass which contains 0.5 to 5 percent by weight of K2O, 0 to 5 percent by weight of Al2O3, 10 to 25 percent by weight of B2O3, and 70 to 85 percent by weight of SiO2; and 10 to 60 percent by weight of a filler containing alumina and quartz, and the content of the alumina contained in the filler is 1 to 10 percent by weight of the total amount of the glass and the filler.Type: GrantFiled: May 9, 2016Date of Patent: January 30, 2018Assignee: Murata Manufacturing Co., Ltd.Inventor: Hiroshige Adachi
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Patent number: 9460850Abstract: To provide ferrite magnetic powders for bond magnet capable of surely suppressing residual hexavalent chrome, being an environmental load substance, having no adverse influence on the magnetic characteristics, which is an obstacle in use, and without damaging productivity and at a low cost. The method includes the steps of obtaining sintered powders by sintering raw material powders; wet-pulverizing the sintered powders; wet-cleaning the sintered powders; and annealing the cleaned sintered powders, wherein in the step of the wet-pulverization and in the step of wet-cleaning, generation of the hexavalent chrome, being an environmental load substance, is suppressed by performing the pulverization and cleaning while maintaining pH of a dispersion solvent at 8.5 or less, at the time of pulverization and cleaning.Type: GrantFiled: April 17, 2014Date of Patent: October 4, 2016Assignees: DOWA F-TEC CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.Inventors: Shuichi Kohayashi, Hiroya Ikeda, Hideki Katayama, Keisuke Ayabe
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Patent number: 9378878Abstract: The method of manufacturing hexagonal ferrite magnetic particles comprises applying, in a water-based solution, an adhering matter comprising a glass component and an alkaline earth metal to iron oxide particles to which a surfactant adheres, and calcining the iron oxide particles to which the adhering matter adheres to obtain a calcined product in which a main component that is detected by X-ray diffraction analysis is hexagonal ferrite.Type: GrantFiled: July 7, 2014Date of Patent: June 28, 2016Assignee: FUJIFILM CorporationInventors: Yasushi Hattori, Yoshinori Tamada
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Patent number: 9340902Abstract: The present invention provides a magnetoelectric material in which an electric property is capable of being controlled by a magnetic field or a magnetic property is capable of being controlled by an electric field, and a method of manufacturing the same. Particularly, the present invention provides a magnetoelectric material in which a distance between magnetic ions interacting with each other is controlled by using non-magnetic ions or alkaline earth metal ions, and a method of manufacturing the same.Type: GrantFiled: November 18, 2013Date of Patent: May 17, 2016Assignee: SNU R&DB FOUNDATIONInventors: Kee Hoon Kim, Sae Hwan Chun, Yi Sheng Chai, Kwang Woo Shin
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Patent number: 9312057Abstract: Apparatus and methods for manufacturing magnets, and magnets, having magnetically oriented grains, and apparatus including such magnets. The field of a permanent magnet may be shaped by applying an external field to the material from which the magnet is made in such a way as to magnetize different regions of the material in different directions. The apparatus may include, and the methods may involve, a metal-powder press that may press metal powder in the presence of a magnetic field. The press may compress the powder in an axial direction. The field may have flux lines that are transverse to the axial direction. The field may have flux lines that are along the axial direction.Type: GrantFiled: March 14, 2013Date of Patent: April 12, 2016Assignee: Arnold Magnetic Technologies AGInventors: Gerhard Martinek, Urs Wyss
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Patent number: 9142341Abstract: An aspect of the present invention relates to a method of manufacturing hexagonal ferrite magnetic powder, which comprises preparing a melt by melting a starting material mixture comprising a hexagonal ferrite-forming component and a glass-forming component and rapidly cooling the melt to obtain a solidified product, heating the solidified product to precipitate hexagonal ferrite magnetic particles and glass components in the solidified product, subjecting the solidified product to an acid treatment following the heating to remove the glass components by dissolution, incorporating the hexagonal ferrite magnetic particles obtained following the acid treatment into an acidic aqueous solution, followed by separating the particles dispersed in the aqueous solution and the precipitated particles, and subjecting the precipitated particles to a cleaning treatment and then collecting the particles.Type: GrantFiled: May 30, 2013Date of Patent: September 22, 2015Assignee: FUJIFILM CorporationInventor: Masahiko Mori
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Publication number: 20150125717Abstract: A method and apparatus for growing truly bulk In2O3 single crystals from the melt, as well as melt-grown bulk In2O3 single crystals are disclosed. The growth method comprises a controlled decomposition of initially non-conducting In2O3 starting material (23) during heating-up of a noble metal crucible (4) containing the In2O3 starting material (23) and thus increasing electrical conductivity of the In2O3 starting material with rising temperature, which is sufficient to couple with an electromagnetic field of an induction coil (6) through the crucible wall (24) around melting point of In2O3. Such coupling leads to an electromagnetic levitation of at least a portion (23.1) of the liquid In2O3 starting material with a neck (26) formation acting as crystallization seed. During cooling down of the noble metal crucible (4) with the liquid In2O3 starting material at least one bulk In2O3 single crystal (28.1, 28.2) is formed.Type: ApplicationFiled: April 24, 2012Publication date: May 7, 2015Applicant: FORSCHUNGSVERBUND BERLIN E.V.Inventors: Zbigniew Galazka, Roberto Fornari, Reinhard Uecker
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Publication number: 20150108393Abstract: A sintered body contains Z-type hexagonal ferrite, Bi2O3, and a glass material as starting materials. The additive ratio by weight of the Bi2O3 to the Z-type hexagonal ferrite in the starting materials is within a range from 5:100 to 7:100. The sintered body is obtained by sintering of the starting materials and contains the Z-type hexagonal ferrite as a main phase.Type: ApplicationFiled: October 2, 2014Publication date: April 23, 2015Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Mitsuru ODAHARA, Yukie SHIMIZU
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Patent number: 8920670Abstract: A magnetic material of an embodiment includes: first magnetic particles that contain at least one magnetic metal selected from the group including Fe, Co, and Ni, are 1 ?m or greater in particle size, and are 5 to 50 ?m in average particle size; second magnetic particles that contain at least one magnetic metal selected from the group including Fe, Co, and Ni, are smaller than 1 ?m in particle size, and are 5 to 50 nm in average particle size; and an intermediate phase that exists between the first magnetic particles and the second magnetic particles.Type: GrantFiled: August 29, 2012Date of Patent: December 30, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Koichi Harada, Tomohiro Suetsuna, Toshihide Takahashi, Seiichi Suenaga
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Publication number: 20140295214Abstract: Hexagonal ferrite magnetic particles have an activation volume ranging from 1,000 nm3 to 1,500 nm3, and ?E10%/kT, thermal stability at 10% magnetization reversal, is equal to or greater than 40.Type: ApplicationFiled: March 25, 2014Publication date: October 2, 2014Applicant: FUJIFILM CORPORATIONInventors: Toshio TADA, Hiroyuki SUZUKI, Osamu SHIMIZU
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Patent number: 8840802Abstract: An aspect of the present invention relates to a method of manufacturing hexagonal ferrite magnetic powder. The method of manufacturing hexagonal ferrite magnetic powder comprises wet processing hexagonal ferrite magnetic particles obtained following acid treatment in a water-based solvent to prepare an aqueous magnetic liquid satisfying relation (1) relative to an isoelectric point of the hexagonal ferrite magnetic particles: pH0?pH*?2.5, wherein, pH0 denotes the isoelectric point of the hexagonal ferrite magnetic particles and pH* denotes a pH of the aqueous magnetic liquid, which is a value of equal to or greater than 2.0, adding a surface-modifying agent comprising an alkyl group and a functional group that becomes an anionic group in the aqueous magnetic liquid to the aqueous magnetic liquid to subject the hexagonal ferrite magnetic particles to a surface-modifying treatment, and removing the water-based solvent following the surface-modifying treatment to obtain hexagonal ferrite magnetic particles.Type: GrantFiled: March 22, 2012Date of Patent: September 23, 2014Assignee: FUJIFILM CorporationInventors: Masahiko Mori, Hiroyuki Suzuki
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Publication number: 20140138571Abstract: The present invention provides a magnetoelectric material in which an electric property is capable of being controlled by a magnetic field or a magnetic property is capable of being controlled by an electric field, and a method of manufacturing the same. Particularly, the present invention provides a magnetoelectric material in which a distance between magnetic ions interacting with each other is controlled by using non-magnetic ions or alkaline earth metal ions, and a method of manufacturing the same.Type: ApplicationFiled: November 18, 2013Publication date: May 22, 2014Applicant: SNU R&DB FOUNDATIONInventors: Kee Hoon KIM, Sae Hwan CHUN, Yi Sheng CHAI, Kwang Woo SHIN
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Patent number: 8679362Abstract: Disclosed herein are a nickel-zinc-copper (NiZnCu) based ferrite composition containing 0.001 to 0.3 parts by weight of bivalent metal, 0.001 to 0.3 parts by weight of trivalent metal, and 0.001 to 0.5 parts by weight of tetravalent metal based on 100 parts by weight of main component containing 47.0 to 50.0 mol % of Fe2O3, 15.0 to 27.0 mol % of NiO, 18.0 to 25.0 mol % of ZnO, and 7.0 to 13.0 mol % of CuO, and a multilayered chip device and a toroidal core using the same. According to exemplary embodiments of the present invention, a bivalent metal, a trivalent metal, and a tetravalent are contained in a NiZuCu ferrite, thereby making it possible to provide a ferrite composition having excellent quality factor (Q) characteristics. Moreover, it is possible to provide a toroidal core and a multilayered chip device having excellent sinterability, permittivity, and quality factor (Q) characteristics using the ferrite composition.Type: GrantFiled: September 6, 2012Date of Patent: March 25, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Myeong Gi Kim, Sung Yong An, Ic Seob Kim
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Patent number: 8647525Abstract: A ferrite composition includes a main component having 46.0 to 49.8 mol % of an iron oxide in terms of Fe2O3, 5.0 to 14.0 mol % of a copper oxide in terms of CuO and 8.0 to 32.0 mol % of a zinc oxide in terms of ZnO, and a remainder of the main component is composed of a nickel oxide; and as subcomponents, with respect to 100 wt % of the main component, 0.5 to 6.0 wt % of a silicon oxide in terms of SiO2 and 0.01 to 2.0 wt % of a boron oxide in terms of B2O3. Further, as a subcomponent, 0.01 to 0.17 wt % of potassium oxide in terms of K2O or 0.3 to 2.0 wt % of tin oxide in terms of SnO2 may be included.Type: GrantFiled: March 15, 2011Date of Patent: February 11, 2014Assignee: TDK CorporationInventors: Ryuichi Wada, Shou Kawadahara, Yukio Takahashi, Raitarou Masaoka, Takashi Suzuki, Hiroshi Momoi
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Publication number: 20140011055Abstract: An aspect of the present invention relates to a method of manufacturing a hexagonal ferrite magnetic particle comprising melting an Al-containing starting material mixture to prepare a melt and quenching the melt to obtain an amorphous material; subjecting the amorphous material to heat treatment to cause a hexagonal ferrite magnetic particle to precipitate in a product obtained by the heat treatment; collecting a hexagonal ferrite magnetic particle by subjecting the product to treatment with an acid and washing, wherein the hexagonal ferrite magnetic particle collected has a particle size ranging from 15 to 30 nm, comprises 0.6 to 8.0 weight percent of Al, based on Al2O3 conversion, relative to a total weight of the particle, and Al adheres to a surface of the hexagonal ferrite magnetic particle.Type: ApplicationFiled: September 10, 2013Publication date: January 9, 2014Applicant: FUJIFILM CorporationInventors: Hiroyuki SUZUKI, Nobuo YAMAZAKI
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Patent number: 8597533Abstract: The present invention relates to a multiferroic material capable of freely controlling magnetic field size at room temperature, and to a method of manufacturing the same. Said multiferroic material includes hexaferrites containing magnetic iron ions partially substituted by non-magnetic ions. Said non-magnetic ions act to change the magnetic anisotropy of said hexaferrites.Type: GrantFiled: October 1, 2009Date of Patent: December 3, 2013Assignee: SNU R&DB FoundationInventors: Kee-Hoon Kim, Yisheng Chai, Sae-Hwan Chun
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Patent number: 8597534Abstract: There are provided a composition for a ceramic electronic component having excellent sinterability and magnetic characteristics (Q), a manufacturing method thereof, and an electronic component using the same. The magnetic material composition for the ceramic electronic component is composed of ferric oxide (Fe2O3) of 47.0 to 49.0 parts by mole, nickel oxide (NiO) of 16.0 to 24.0 parts by mole, zinc oxide (ZnO) of 18.0 to 25.0 parts by mole, and copper oxide (CuO) of 7.0 to 13.0 parts by mole, wherein a portion of ferric oxide may be substituted with boron oxide (B2O3). The ceramic electronic component manufactured by using the magnetic material composition for the ceramic electronic component has an excellent Q.Type: GrantFiled: February 24, 2011Date of Patent: December 3, 2013Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Sung Yong An, Ic Seob Kim, Sung Lyoung Kim, Soo Hwan Son, Jin Woo Hahn
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Publication number: 20130257035Abstract: The present invention is related to magnetic pigments comprising a transparent flaky homogeneously composed substrate having two parallel major surfaces and a coating comprising a layered structure composed of a hematite and a magnetite layer, to a process for the production of said pigments as well as to their use.Type: ApplicationFiled: November 14, 2011Publication date: October 3, 2013Applicant: MERCK PATENT GMBHInventors: Kaiman Shimizu, Fumiko Sasaki, Yukitaka Watanabe, Masahiko Yazawa
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Publication number: 20130256584Abstract: An aspect of the present invention relates to a method of manufacturing hexagonal strontium ferrite magnetic powder, which comprises melting a starting material mixture which has a composition, as a composition converted into an oxide, lying within a region enclosed by the following four points: (a) SrO=48.0 mol %, Fe2O3=17.2 mol %, B2O3=34.8 mol %; (b) SrO=55.9 mol %, Fe2O3=17.7 mol %, B2O3=26.4 mol %; (c) SrO=41.7 mol %, Fe2O3=40.9 mol %, B2O3=17.4 mol %; (d) SrO=36.7 mol %, Fe2O3=40.1 mol %, B2O3=23.2 mol %; in a ternary diagram with SrO, Fe2O3, which may include an Fe substitution element, and B2O3 as apexes, to provide a melt, and quenching the melt to obtain a solidified product; and heat treating the solidified product to precipitate hexagonal strontium ferrite magnetic particles within the solidified product.Type: ApplicationFiled: March 15, 2013Publication date: October 3, 2013Applicant: FUJIFILM CORPORATIONInventors: Nobuo YAMAZAKI, Hiroyuki SUZUKI
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Patent number: 8545713Abstract: The present invention relates to black magnetic iron oxide particles comprising magnetite as a main component, wherein when the black magnetic iron oxide particles are molded into a tablet shape, an electric resistance value of the tablet in an alternating current electric field is controlled to produce an impedance of not less than 2×106 ?cm as measured in a characteristic frequency range thereof. The black magnetic iron oxide particles according to the present invention can provide a toner capable of exhibiting a good charging performance and a uniform charging property under the high-temperature and high-humidity conditions, so that when developing an electrostatic latent image therewith, it is possible to obtain toner images having a high resolution or definition, and further the use of heavy metal elements in the black magnetic iron oxide particles can be minimized.Type: GrantFiled: March 30, 2010Date of Patent: October 1, 2013Assignee: Toda Kogyo CorporationInventors: Ryo Iwai, Mamoru Kamigaki, Nobuya Shimo, Naoki Uchida
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Patent number: 8545714Abstract: An aspect of the present invention relates to a method of manufacturing a hexagonal ferrite magnetic particle comprising melting an Al-containing starting material mixture to prepare a melt and quenching the melt to obtain an amorphous material; subjecting the amorphous material to heat treatment to cause a hexagonal ferrite magnetic particle to precipitate in a product obtained by the heat treatment; collecting a hexagonal ferrite magnetic particle by subjecting the product to treatment with an acid and washing, wherein the hexagonal ferrite magnetic particle collected has a particle size ranging from 15 to 30 nm, comprises 0.6 to 8.0 weight percent of Al, based on Al2O3 conversion, relative to a total weight of the particle, and Al adheres to a surface of the hexagonal ferrite magnetic particle.Type: GrantFiled: March 31, 2011Date of Patent: October 1, 2013Assignee: FUJIFILM CorporationInventors: Hiroyuki Suzuki, Nobuo Yamazaki
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Patent number: 8444872Abstract: Disclosed is a magnetic material having high Hc and High Curie point, which is capable of controlling such magnetic characteristics without requiring rare or expensive raw materials. Specifically disclosed is a magnetic material composed of particles of a magnetic iron oxide which is represented by the following general formula: ?-AxByFe2?x?yO3 or ?-AxByCzFe2?x?y?zO3 (wherein A, B and C each represents a metal excluding Fe and different from each other, satisfying 0<x, y, z<1), with ?-Fe2O3 as a main phase.Type: GrantFiled: May 30, 2008Date of Patent: May 21, 2013Assignees: The University of Tokyo, Dowa Electronics Materials Co., Ltd.Inventors: Shin-ichi Ohkoshi, Shunsuke Sakurai, Takenori Yorinaga, Kazuyuki Matsumoto, Shinya Sasaki
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Publication number: 20130116339Abstract: Procedure for the magnetization of different inorganic surfaces, whether natural or synthetic, such as aluminosilicates, both synthetic and natural (natural zeolites, synthetic zeolites, alumina, allophane, among others) that give magnetic properties to those surfaces. Objectives of the present application are also the above mentioned surfaces, magnetized, and their different uses.Type: ApplicationFiled: December 27, 2010Publication date: May 9, 2013Applicant: Universidad De Santiago De ChileInventors: Marlen Gutierrez, Mauricio Escudey, José Fabris, Dora Altbir, Juliano Casagrande
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Patent number: 8416051Abstract: A magnetic material constituted by a grain-compacted body comprising a plurality of metal grains made of a Fe—Si—M soft magnetic alloy (where M is a metal element more easily oxidized than Fe) and an oxide film formed on the surface of the metal grains; wherein there are bonding portions via the oxide film formed on the surfaces of adjacent metal grains and direct bonding portions of metal grains in locations where the oxide film is not present.Type: GrantFiled: December 7, 2011Date of Patent: April 9, 2013Assignee: Taiyo Yuden Co., Ltd.Inventors: Hitoshi Matsuura, Kenji Otake
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Publication number: 20130033354Abstract: Disclosed herein are a ferrite powder having a core-shell structure, the core being made of iron (Fe) or iron-based compounds comprising iron (Fe) and the shell being made of metal oxides, a ferrite material comprising the ferrite powder and the glass, and multilayered chip components including the ferrite layer using the ferrite material, inner electrodes, and outer electrodes. According to the exemplary embodiments of the present invention, it is possible to provide the ferrite material capable of improving the change in the inductance L value in response to applied current by suppressing magnetization at high current. The multilayered chip components including the ferrite material according to the exemplary embodiment of the present invention can also be used in a band of MHz.Type: ApplicationFiled: August 1, 2012Publication date: February 7, 2013Inventors: Sung Yong An, Myeong Gi Kim, Ic Seob Kim
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Patent number: 8335037Abstract: [Problem] When a nonreciprocal device operating at 100 GHz to 300 GHz is to be realized by using a conventional magnetic material of garnet-type ferrite or spinel-type ferrite, a huge permanent magnet is required and, therefore, it is very difficult to achieve a millimeter-wave band nonreciprocal device for practical use. [Solving means] To solve this problem, there is provided a millimeter-wave band nonreciprocal device composed of a magnetic material represented by a formula ?-MxFe2-xO3 (0<x<2), wherein M is at least one of elements In, Ga, Al, Sc, Cr, Sm, Yb, Ce, Ru, Rh, Ti, Co, Ni, Mn, Zn, Zr, and Y and the magnetic material having ?-phase hematite as a principal phase exhibits strong coercive force and anisotropic magnetic field at room temperature. Dimensions of a magnetic circuit containing a permanent magnet for operations of the nonreciprocal device can be made remarkably small and, by optimum design, the use of the magnetic circuit can be made unnecessary.Type: GrantFiled: October 17, 2008Date of Patent: December 18, 2012Assignees: The University of Tokyo, Dowa Electronics Materials Co., Ltd.Inventors: Shigeru Takeda, Shin-Ichi Ohkoshi
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Publication number: 20120261606Abstract: A pearlescent pigment and a process for enhancing the magnetic properties of a pearlescent pigment. The pearlescent pigment has a layer with regions of ?-Fe2O3 and regions of ?-Fe2O3. The magnetic properties of a pearlescent pigment may be enhanced by the steps of: providing a platelet pigment with a layer of Fe2O3, with a magnetic susceptibility less than 0.1×10?5 m3/kg; reducing some or all of the Fe2O3 to Fe3O4; and oxidizing some or all of the Fe3O4 to ?-Fe2O3. The color difference (?E*) between the provided pigment and the resultant pigment is not more than about 5.Type: ApplicationFiled: June 26, 2012Publication date: October 18, 2012Inventors: Aaron M. Hollman, Philippe Schottland
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Publication number: 20120177951Abstract: An aspect of the present invention relates to a hexagonal barium ferrite magnetic particle, wherein, relative to 100 atom percent of a Fe content, an Al content ranges from 1.5 to 15 atom percent, a combined content of a divalent element and a pentavalent element ranges from 1.0 to 10 atom percent, an atomic ratio of a content of the divalent element to a content of the pentavalent element is greater than 2.0 but less than 4.0, and an activation volume ranges from 1,300 to 1,800 nm3.Type: ApplicationFiled: January 5, 2012Publication date: July 12, 2012Applicant: FUJIFILM CORPORATIONInventors: Nobuo YAMAZAKI, Hiroyuki SUZUKI
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Patent number: 8211327Abstract: A method for preparing a rare earth permanent magnet material comprising the steps of: disposing a powder comprising one or more members selected from an oxide of R2, a fluoride of R3, and an oxyfluoride of R4 wherein R2, R3 and R4 each are one or more elements selected from among rare earth elements inclusive of Y and Sc on a sintered magnet form of a R1—Fe—B composition wherein R1 is one or more elements selected from among rare earth elements inclusive of Y and Sc, and heat treating the magnet form and the powder at a temperature equal to or below the sintering temperature of the magnet in vacuum or in an inert gas. The invention offers a high performance, compact or thin permanent magnet having a high remanence and coercivity at a high productivity.Type: GrantFiled: March 22, 2005Date of Patent: July 3, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hajime Nakamura, Koichi Hirota, Takehisa Minowa
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Publication number: 20120126165Abstract: There are provided a composition for a ceramic electronic component having excellent sinterability and magnetic characteristics (Q), a manufacturing method thereof, and an electronic component using the same. The magnetic material composition for the ceramic electronic component is composed of ferric oxide (Fe203) of 47.0 to 49.0 parts by mole, nickel oxide (NiO) of 16.0 to 24.0 parts by mole, zinc oxide (ZnO) of 18.0 to 25.0 parts by mole, and copper oxide (CuO) of 7.0 to 13.0 parts by mole, wherein a portion of ferric oxide may be substituted with boron oxide (B2O3). The ceramic electronic component manufactured by using the magnetic material composition for the ceramic electronic component has an excellent Q.Type: ApplicationFiled: February 24, 2011Publication date: May 24, 2012Inventors: Sung Yong AN, Ic Seob KIM, Sung Lyoung KIM, Soo Hwan SON, Jin Woo HAHN
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Publication number: 20120119135Abstract: Disclosed herein is a method for producing a ferrite which can achieve high efficiency even in a high frequency range. The method comprises the steps of: mixing barium nitrate (Ba(NO3)2), cobalt nitrate hexahydrate (Co(NO3)2.6H2O) and ferric nitrate nonahydrate (Fe(NO3)3.9H2O) at a ratio of 3:2:24 to form a liquid-phase mixture; co-precipitating the mixture with sodium hydroxide (NaOH) so as to be metalized; washing and drying the co-precipitated mixture; heat-treating the co-precipitated mixture; and adding aluminum oxide (Al2O3) to the mixture. The method can provide a high-efficiency ferrite having reduced permittivity, permeability, dielectric loss and permeability loss.Type: ApplicationFiled: August 11, 2009Publication date: May 17, 2012Inventors: Byung Hoon Ryou, Won Mo Sung, Jun Sig Kum
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Publication number: 20120091702Abstract: The present invention is related to magnetic pigments comprising a transparent flaky homogeneously composed substrate having two parallel major surfaces and a coating comprising maghemite, to a process for the production of said pigments as well as to their use.Type: ApplicationFiled: June 8, 2010Publication date: April 19, 2012Applicant: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Kaiman Shimizu, Tamio Noguchi, Fumiko Sasaki, Yukitaka Watanabe, Masahiko Yazawa
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Publication number: 20120085963Abstract: Disclosed herein are a ferrite composition for a high frequency bead in that a part of Fe in M-type hexagonal ferrite represented by BaFe12O19 is substituted with at least one metal selected from a group consisting of 2-valence, 3-valence and 4-valence metals, as well as a chip bead material using the same. According to embodiments of the present invention, the dielectric composition is characterized in that a part of Fe as a constituent of M-type hexagonal barium ferrite is substituted by other metals, to thus decrease a sintering temperature to 920° C. or less without using any additive for low temperature sintering. Moreover, because of high SRF properties, the inventive composition is applicable to a multilayer type chip bead used at a high frequency of more than several hundreds MHz and a magnetic antenna.Type: ApplicationFiled: October 3, 2011Publication date: April 12, 2012Inventors: Sung Yong AN, Jin Woo HAHN, Jeong Wook KIM, Sung Lyoung KIM, So Yeon SONG, Soo Hwan SON, Ic Seob KIM
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Patent number: 8153097Abstract: A method for manufacturing ferrite powder comprises a step (a) of causing a precursor, obtained by a liquid-phase reaction method, to pass through a sieve with openings of 2 mm or less, and a step (b) of causing free fall, through the interior of a furnace tube heated to the range 750 to 1250° C. by a heater, of the precursor which has passed through the sieve. In the process of causing free fall through the interior of the furnace tube heated by the heater, ferrite powder, which is a single phase of hexagonal ferrite, is obtained by heating the precursor to a prescribed temperature and holding the precursor at the prescribed temperature.Type: GrantFiled: September 25, 2008Date of Patent: April 10, 2012Assignee: TDK CorporationInventor: Mamoru Satoh
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Patent number: 8142676Abstract: The invention relates to a magnetic garnet single crystal and an optical element using the same, for the purpose of providing a magnetic garnet single crystal at a reduced Pb content, and an optical element using the same, where the magnetic garnet single crystal is represented by the chemical formula Bi?M13-?Fe5-?-?M2?M3?O12 (M1 is at least one element selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and M2 is Si; and M3 is at least one element selected from Zn, Ni, Cu and Mg, provided that 0.5<??2.0, 0<?, and 0<y).Type: GrantFiled: February 9, 2007Date of Patent: March 27, 2012Assignee: TDK CorporationInventor: Atsushi Ohido
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Patent number: 8133405Abstract: Spinel-type ferrimagnetic particles having a composition represented by the formula: (MO)·n/2(Fe2O3) where M is a divalent metal and n is a molar ratio of Fe to M (n=Fe/M) which is from more than 2.05 to less than 2.5 (2.05<n<2.5). They contain a superparamagnetic component in an amount of not more than 2% by mass, has an average particle diameter of 5 to 30 nm. The particles are respectively coated on surface with a hydroxide of at least one metal Si, Al, P and Zn in an amount of not more than 10% by mass, calculated as the metal. The spinel-type ferrimagnetic particles can exhibit a high coercive force irrespective of fine particles, and are excellent in dispersibility and chemical stability, as well as the magnetic recording medium for high-density recording can exhibit not only excellent frequency characteristics and high output characteristics, but also an excellent weather resistance and a high reliability.Type: GrantFiled: May 13, 2010Date of Patent: March 13, 2012Assignee: Toda Kogyo CorporationInventors: Hiroshi Yamamoto, Tsutomu Katamoto
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Patent number: 8072365Abstract: Disclosed is a magnetic crystal for electromagnetic wave absorbing materials, having a structure of ?-MxFe2-xO3 with 0<x<1, which has the same space group as that of an ?-Fe2O3 crystal and which is derived from an ?-Fe2O3 crystal by substituting a part of the Fe site therein with M. In this, M is a trivalent element having an effect of lowering the coercive force Hc of ?-Fe2O3 crystal by the substitution. Concretely, the element M includes Al and Ga. An electromagnetic wave absorber having a packed structure of particles having such a substituent element M-added “M-substituted ?-Fe2O3 crystal” as the magnetic phase may control the electromagnetic wave absorption peak frequency depending on the degree of substitution with the element M, and for example, the invention gives an electromagnetic wave absorber applicable to a 76 GHz band for on-vehicle radars.Type: GrantFiled: August 30, 2007Date of Patent: December 6, 2011Assignees: The University of Tokyo, DOWA Electronics Materials Co., Ltd.Inventors: Shin-ichi Ohkoshi, Shiro Kuroki, Shunsuke Sakurai, Asuka Namai, Kimitaka Sato, Shinya Sasaki
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Publication number: 20110278491Abstract: Disclosed is a MnZnCo-based ferrite consisting of base constituents, accessory constituents, and inevitable impurities, which MnZnCo-based ferrite is characterized by adding silicon oxide (SiO2 conversion): 50-400 mass ppm and calcium oxide (CaO conversion): 1000-4000 mass ppm as secondary constituents to base constituents consisting of iron oxide (Fe2O3 conversion): 51.0-53.0 mol %, zinc oxide (ZnO conversion): greater than 12.0 mol % and less than 18.0 mol %, cobalt oxide (CoO conversion): 0.04-0.60 mol %, and manganese oxide (MnO conversion): remainder, and keeping phosphorus, boron, sulfur, and chlorine of the inevitable impurities to phosphorous: less than 3 mass ppm, boron: less than 3 mass ppm, sulfur: less than 5 mass ppm, and chlorine: less than 10 mass ppm. This MnZnCo-based ferrite has the superior characteristics of always having incremental permeability [mu]? of 2000 or greater across a wide temperature range of ?40 DEG C. to 85 DEG C.Type: ApplicationFiled: January 29, 2010Publication date: November 17, 2011Applicant: JFE CHEMICAL CORPORATIONInventors: Hirofumi Yoshida, Yukiko Nakamura, Satoshi Goto
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Publication number: 20110226982Abstract: A ferrite composition includes a main component having 46.0 to 49.8 mol % of an iron oxide in terms of Fe2O3, 5.0 to 14.0 mol % of a copper oxide in terms of CuO and 6.0 to 32.0 mol % of a zinc oxide in terms of ZnO, and a remainder of the main component is composed of a nickel oxide; and as subcomponents, with respect to 100 wt % of the main component, 0.5 to 6.0 wt % of a silicon oxide in terms of SiO2 and 0.01 to 2.0 wt % of a boron oxide in terms of B2O3. Further, as a subcomponent, 0.01 to 0.17 wt % of potassium oxide in terms of K2O or 0.3 to 2.0 wt % of tin oxide in terms of SnO2 may be included. According to the present invention, the ferrite composition having good initial permeability, good superposed direct current characteristic and comparatively good temperature characteristic of the initial permeability, and achieving low temperature firing; and an electronic component having the ferrite composition can be provided.Type: ApplicationFiled: March 15, 2011Publication date: September 22, 2011Applicant: TDK CORPORATIONInventors: Ryuichi WADA, Shou KAWADAHARA, Yukio TAKAHASHI, Raitarou MASAOKA, Takashi SUZUKI, Hiroshi MOMOI
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Patent number: 8021567Abstract: A sintered ferrite magnet having an M-type ferrite structure and comprising Ca, an R element which is at least one rare earth element indispensably including La, Ba, Fe and Co as indispensable elements, which is represented by Ca1-x-yRxBayFe2n-zCoz, wherein (1?x?y), x, y, z and n are numbers representing the amounts of Ca, the R element, Ba and Co and a molar ratio, meeting 0.2?x?0.65, 0.001?y?0.2, 0.03?z?0.65, and 4?n?7.Type: GrantFiled: October 12, 2010Date of Patent: September 20, 2011Assignee: Hitachi Metals, Ltd.Inventors: Takashi Takami, Hiroshi Iwasaki, Naoki Mochi
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Publication number: 20110031434Abstract: The present invention relates to a multiferroic material capable of freely controlling magnetic field size at room temperature, and to a method of manufacturing the same. Said multiferroic material includes hexaferrites containing magnetic iron ions partially substituted by non-magnetic ions. Said non-magnetic ions act to change the magnetic anisotropy of said hexaferrites.Type: ApplicationFiled: October 1, 2009Publication date: February 10, 2011Applicant: SNU R&DB FOUNDATIONInventors: Kee-Hoon Kim, Yisheng Chai, Sae-Hwan Chun
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Patent number: 7811465Abstract: The present invention relates to a magnetic garnet single crystal prepared by the liquid phase epitaxial (LPE) process and an optical element using the same as well as a method of producing the single crystal, for the purpose of providing a magnetic garnet single crystal at a reduced Pb content and an optical element using the same, as well as a method of producing the single crystal. The magnetic garnet single crystal is grown by the liquid phase epitaxial process and is represented by the chemical formula BixNayPbzM13?x?y?zFe5?wM2wO12 (M1 is at least one element selected from Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and M2 is at least one element selected from Ga, Al, In, Ti, Ge, Si and Pt, provided that 0.5<x?2.0, 0<y?0.8, 0?z<0.01, 0.19?3?x?y?z<2.5, and 0?w?1.6).Type: GrantFiled: November 17, 2005Date of Patent: October 12, 2010Assignee: TDK CorporationInventor: Atsushi Ohido
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Publication number: 20100238063Abstract: Disclosed is a magnetic crystal for electromagnetic wave absorbing materials, having a structure of ?-MxFe2-xO3 with 0<x<1, which has the same space group as that of an ?-Fe2O3 crystal and which is derived from an ?-Fe2O3 crystal by substituting a part of the Fe site therein with M. In this, M is a trivalent element having an effect of lowering the coercive force Hc of ?-Fe2O3 crystal by the substitution. Concretely, the element M includes Al and Ga. An electromagnetic wave absorber having a packed structure of particles having such a substituent element M-added “M-substituted ?-Fe2O3 crystal” as the magnetic phase may control the electromagnetic wave absorption peak frequency depending on the degree of substitution with the element M, and for example, the invention gives an electromagnetic wave absorber applicable to a 76 GHz band for on-vehicle radars.Type: ApplicationFiled: August 30, 2007Publication date: September 23, 2010Inventors: Shin-ichi Ohkoshi, Shiro Kuroki, Shunsuke Sakurai, Asuka Namai, Kimitaka Sato, Shinya Sasaki