Calcium, Barium, Strontium, Or Lead Patents (Class 252/62.63)
-
Patent number: 7255807Abstract: A ferrite magnetic powder for bond magnet that experiences only small decrease in coercivity when molded into a bond magnet is provided, which is a ferrite magnetic powder that includes an alkaline-earth metal constituent and exhibits a decrease in coercivity of not greater than 600 Oe when subjected to a prescribed molding test. The magnetic powder can be obtained by mixing a fine ferrite powder of an average particle diameter of greater than 0.50 to 1.0 ?m and a coarse ferrite powder of an average particle diameter of greater than 2.50 to 5.0 ?m at ratio to incorporate the fine powder at a content ratio of 15-40 wt %.Type: GrantFiled: April 22, 2004Date of Patent: August 14, 2007Assignee: Dowa Mining Co., Ltd.Inventors: Masayasu Senda, Shinichi Suenaga, Keisuke Ayabe, Toshiyuki Sakai
-
Patent number: 7169319Abstract: A ferrite magnet having a basic composition represented by the following general formula: (A1?xRx)O.n[(Fe1?yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba, R is at least one of rare earth elements including Y, M is at least one element selected from the group consisting of Co, Mn, Ni and Zn, and x, y and n are numbers meeting the conditions of 0.01?x?0.4, [x/(2.6n)]?y?[x/(1.6n)], and 5?n?6, and substantially having a magnetoplumbite-type crystal structure, is obtained by uniformly mixing a compound of Sr and/or Ba with an iron compound; calcining the resultant uniform mixture; adding a compound of the R element and/or the M element to the resultant calcined powder at a pulverization step thereof; and sintering the resultant mixture. The compound of the R element and/or the M element may be added at a percentage of more than 0 atomic % and 80 atomic % or less, on an element basis, at a mixing step before calcination.Type: GrantFiled: October 14, 2004Date of Patent: January 30, 2007Assignee: Neomax Co., Ltd.Inventors: Takashi Takami, Yutaka Kubota, Yasunobu Ogata
-
Patent number: 7108799Abstract: An electromagnetic wave absorber is formed of an Mn—Zn ferrite including: a spinel primary phase which contains 40.0 to 49.9 mol % Fe2O3, 4.0 to 26.5 mol % ZnO, and the remainder consisting of MnO; and a secondary phase which contains CaO as a base component. In the ferrite, the spinel primary phase accounts for 50.0 to 99.0% of the aggregate mass of the spinel primary phase and the secondary phase.Type: GrantFiled: January 30, 2004Date of Patent: September 19, 2006Assignee: Minebea Co., Ltd.Inventors: Osamu Kobayashi, Kiyoshi Ito, Masashi Norizuki
-
Patent number: 7101489Abstract: A composite magnetic material contains first magnetic particles made of a first magnetic material and second magnetic particles made of a second magnetic material, the first and second magnetic particles being mixed with each other. A frequency characteristic of the first magnetic material is different from that of the second magnetic material. The first and second magnetic particles are mixed so that, at a frequency of an intersecting point between a first curve representing a frequency characteristic of a real part of a complex magnetic permeability of the first magnetic material and a second curve representing a frequency characteristic of a real part of a complex magnetic permeability of the second magnetic material, a value of a real part of a complex magnetic permeability of the composite magnetic material is larger than a value of the intersecting point.Type: GrantFiled: May 16, 2005Date of Patent: September 5, 2006Assignee: Sanyo Electric Co., Ltd.Inventors: Takashi Umemoto, Hideki Yoshikawa, Keiichi Kuramoto, Hitoshi Hirano
-
Patent number: 7101488Abstract: An electromagnetic wave absorber is formed of an Mn—Zn ferrite including: a spinel primary phase which contains 40.0 to 49.9 mol % Fe2O3, 4.0 to 26.5 mol % ZnO, 0.1 to 4.0 mol % TiO2 and/or SnO2, and the remainder consisting of MnO; and a secondary phase which contains CaO as a base component. In the ferrite, the mass of the spinel primary phase accounts for 50.0 to 99.0% of the aggregate mass of the spinel primary phase and the secondary phase.Type: GrantFiled: January 30, 2004Date of Patent: September 5, 2006Assignee: Minebea Co., Ltd.Inventors: Osamu Kobayashi, Kiyoshi Ito, Masashi Norizuki
-
Patent number: 7025946Abstract: A soft hexagonal ferrite sintered material includes crystal particles of M-type hexagonal ferrite corresponding to a general chemical formula MFe12O19 wherein M is at least one element selected from the group consisting of Ba, Sr and Pb. Crystal particles having particle diameters of 5 ?m to 100 ?m are extracted from a sintered material produced from a precursor powder mixture. The extracted particles as seed crystals are mixed with a calcined powder comprising fine crystals having the above composition and particle diameters of 0.5 ?m to 3 ?m, then is sintered until the intended particle growth of the crystal particles in the sintered material is achieved to give an average particle diameter of 30 ?m to 500 ?m.Type: GrantFiled: August 21, 2002Date of Patent: April 11, 2006Assignees: Kitigawa Industries Co., Ltd., Japan Fine Ceramics CenterInventors: Yutaka Suematsu, Toru Matsuzaki, Yasuo Kondo, Hideaki Matsubara, Hiroshi Nomura
-
Patent number: 7011764Abstract: A magnetic device and method for making it involve a magnetic device specifically constructed of grains in a matrix. The matrix may be cement or plaster. The grains have an average diameter that is greater than their magnetic domains. The device may be applied to shielding applications for frequencies ranging from 100 kHz to 10 GHz. The shielding may be applied to walls of a building, consumer products such as magnetic disks, and the like. The grains may be any ferromagnetic material, including ferrite.Type: GrantFiled: July 25, 2003Date of Patent: March 14, 2006Assignee: Epcos AGInventors: Mauricio Esguerra, Ralph Lucke
-
Patent number: 6994797Abstract: A ferrite magnet obtained by adding at least one element selected from the group consisting of Co, Ni, Mn and Zn to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof, and then subjecting the mixture to re-calcining and/or sintering process(es). By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: GrantFiled: February 6, 2002Date of Patent: February 7, 2006Assignee: Neomax Co., Ltd.Inventors: Etsushi Oda, Sachio Toyota, Seiichi Hosokawa
-
Patent number: 6984337Abstract: An Mn—Zn ferrite includes base components of 44.0 to 49.8 mol % Fe2O3, 4.0 to 26.5 mol % ZnO, at least one of 0.1 to 4.0 mol % TiO2 and SnO2, 0.5 mol % or less Mn2O3, and the remainder consisting of MnO, and contains 0.20 (0.20 excluded) to 1.00 mass % CaO as additive. Since the Mn—Zn ferrite contains less than 50 mol % Fe2O3 and a limited amount (0.5 mol % or less) of Mn2O3, an abnormal grain growth does not occur even if CaO content is more than 0.20 mass %, and a high electrical resistance can be gained. And, since an appropriate amount of TiO2 and/or SnO2 is contained, an initial permeability is kept adequately high, whereby an excellent soft magnetism can be achieved in a high frequency band such as 1 MHz.Type: GrantFiled: January 28, 2004Date of Patent: January 10, 2006Assignee: Minebea Co., Ltd.Inventors: Osamu Kobayashi, Osamu Yamada, Kiyoshi Ito
-
Patent number: 6984338Abstract: An Mn—Zn ferrite includes base components of 44.0 to 49.8 mol % Fe2O3, 4.0 to 26.5 mol % ZnO, 0.8 mol % or less Mn2O3, and the remainder consisting of MnO, and contains 0.20 (0.20 excluded) to 1.00 mass % CaO as additive. Since the Mn—Zn ferrite contains less than 50.0 mol % Fe2O3 and a limited amount (0.8 mol % or less) of Mn2O3, an abnormal grain growth does not occur even if CaO content is more than 0.20 mass %, and a high electrical resistance can be gained thereby realizing an excellent soft magnetism in a high frequency band such as 1 MHz.Type: GrantFiled: January 28, 2004Date of Patent: January 10, 2006Assignee: Minebea Co., Ltd.Inventors: Osamu Kobayashi, Osamu Yamada, Kiyoshi Ito
-
Patent number: 6955768Abstract: A ferrite magnet obtained by adding a ferrite having a spinel-type structure to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof. By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: GrantFiled: February 6, 2002Date of Patent: October 18, 2005Assignee: Neomax Co., Ltd.Inventors: Etsushi Oda, Seiichi Hosokawa, Sachio Toyota
-
Patent number: 6933799Abstract: A non-reciprocal device includes at least one ferrimagnetic member (21 or 22). By controlling the FMR linewidth ?H of the ferrimagnetic members (21 and 22), intermodulation distortion is controlled.Type: GrantFiled: October 13, 2000Date of Patent: August 23, 2005Assignee: TDK CorporationInventors: Masako Nukaga, Naoyoshi Sato, Sakae Henmi
-
Patent number: 6929758Abstract: A ferrite magnet obtained by adding either an oxide of Mn or oxides of Mn and Co to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof, and then subjecting the mixture to re-calcining and/or sintering process(es). By adding a small amount of the element Mn or elements Mn and Co to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: GrantFiled: December 6, 2001Date of Patent: August 16, 2005Assignee: Neomax Co., Ltd.Inventors: Etsushi Oda, Sachio Toyota, Seiichi Hosokawa
-
Patent number: 6908568Abstract: An oxide magnetic material is prepared by wet molding in a magnetic field a slurry containing a particulate oxide magnetic material, water and a polyhydric alcohol having the formula: Cn(OH)nHn+2 wherein n is from 4 to 100 as a dispersant. By improving the orientation in a magnetic field upon wet molding using water, an oxide magnetic material having a high degree of orientation, typically an anisotropic ferrite magnet, is obtained at a high rate of productivity. The method is advantageous from the environmental and economical standpoints.Type: GrantFiled: June 17, 2002Date of Patent: June 21, 2005Assignee: TDK CorporationInventors: Kiyoyuki Masuzawa, Hitoshi Taguchi
-
Patent number: 6905629Abstract: An Mn—Zn ferrite wherein 0 to 5000 ppm of a Co oxide in a Co3O4 conversion is contained in a basic component constituted by Fe2O3: 51.5 to 57.0 mol % and ZnO: 0 to 15 mol % (note that 0 is not included) wherein the rest is substantially constituted by MnO; and a value ? in a formula (1) below in said ferrite satisfies ??0.93. ?=((Fe2+?Mn3+?Co3+)×(4.29×A+1.91×B+2.19×C+2.01×D))/((A?B?C?D)×100)??formula (1). Note that in the formula (1), (Fe2+?Mn3+?Co3+): [wt %], A: Fe2O3 [mol %], B: MnO [mol %], C: ZnO [mol %] and D: CoO [mol %]. According to the present invention, a highly reliable Mn—Zn ferrite used as a magnetic core of a power supply transformer, etc. of a switching power supply, etc., having a small core loss in a wide temperature range, furthermore, exhibiting a little deterioration of core loss characteristics under a high temperature (in a high temperature storage test) and having excellent magnetic stability, a transformer magnetic core and a transformer can be provided.Type: GrantFiled: August 29, 2003Date of Patent: June 14, 2005Assignee: TDK CorporationInventors: Yuji Sezai, Katsushi Yasuhara, Kenya Takagawa, Masahiko Watanabe
-
Patent number: 6902685Abstract: A ferrite magnet powder and a ferrite magnet exhibiting improved magnetic properties are provided at a reduced manufacturing cost. An application product and manufacturing methods thereof are also provided. An oxide magnetic material includes, as a main phase, a ferrite having a hexagonal M-type magnetoplumbite structure. The material includes: A, which is at least one element selected from the group consisting of Sr, Ba, Pb and Ca; R, which is at least one element selected from the group consisting of Y (yttrium), the rare earth elements and Bi; Fe; and B (boron). The constituents A, R, Fe and B of the material satisfy the inequalities of 7.04 at %?A?8.68 at %, 0.07 at %?R?0.44 at %, 90.4 at %?Fe?92.5 at % and 0.015 at %?B?0.87 at % to the sum of the elements A, R, Fe and B.Type: GrantFiled: May 21, 2002Date of Patent: June 7, 2005Assignee: Neomax Co., Ltd.Inventors: Sachio Toyota, Isamu Furuchi, Yoshinori Kobayashi
-
Patent number: 6893581Abstract: A composite magnetic material contains first magnetic particles made of a first magnetic material and second magnetic particles made of a second magnetic material, the first and second magnetic particles being mixed with each other. A frequency characteristic of the first magnetic material is different from that of the second magnetic material. The first and second magnetic particles are mixed so that, at a frequency of an intersecting point between a first curve representing a frequency characteristic of a real part of a complex magnetic permeability of the first magnetic material and a second curve representing a frequency characteristic of a real part of a complex magnetic permeability of the second magnetic material, a value of a real part of a complex magnetic permeability of the composite magnetic material is larger than a value of the intersecting point.Type: GrantFiled: January 28, 2003Date of Patent: May 17, 2005Assignee: Sanyo Electric Co., Ltd.Inventors: Takashi Umemoto, Hideki Yoshikawa, Keiichi Kuramoto, Hitoshi Hirano
-
Patent number: 6875367Abstract: Coupling components to an underlying substrate using a composition of a polymer and magnetic material particles. Upon applying the composition between the component and the printed circuit board, the composition may be subjected to a magnetic field to align the magnetic material particles into a conductive path between the component and the underlying substrate. At the same time the polymer-based material may be cured or otherwise solidified to affix the conductive path formed by the magnetic material particles.Type: GrantFiled: October 28, 2003Date of Patent: April 5, 2005Assignee: Intel CorporationInventors: George Hsieh, Terrance J. Dishongh, Norman J. Armendariz, David V. Spaulding
-
Patent number: 6872251Abstract: A method for manufacturing single crystal ceramic powder is provided. The method includes a powder supply step for supplying powder consisting essentially of ceramic ingredients to a heat treatment area with a carrier gas, a heat treatment step for heating the powder supplied to the heat treatment area at temperatures required for single-crystallization of the powder to form a product, and a cooling step for cooling the product obtained in the heat treatment step to form single crystal ceramic powder. The method provides single crystal ceramic powder consisting of particles with a very small particle size and a sphericity being 0.9 or higher.Type: GrantFiled: May 29, 2002Date of Patent: March 29, 2005Assignee: TDK CorporationInventors: Minoru Takaya, Yoshiaki Akachi, Hiroyuki Uematsu, Hisashi Kobuke
-
Patent number: 6858155Abstract: Ferrite materials, methods of forming the same, and products formed therefrom are disclosed, comprising, as main components, an iron oxide ranging from 55.5 to 58.0 mole percent calculated as Fe2O3, an amount of manganese oxide ranging from 38.0 to 41.0 mole percent calculated as MnO, and an amount of zinc oxide ranging from 3.3 to 4.7 mole percent calculated as ZnO. The present invention also includes, as minor components, an amount of calcium oxide ranging from 0.030 to 0.100 weight percent calculated as CaO, an amount of silicon oxide ranging from 0.015 to 0.040 weight percent calculated as SiO2, and an amount of niobium oxide ranging from 0.010 to 0.030 weight percent calculated as Nb2O5.Type: GrantFiled: December 12, 2001Date of Patent: February 22, 2005Assignee: Spang & CompanyInventors: Mark A. Fanton, Joseph F. Huth, III
-
Patent number: 6858156Abstract: A ferrite magnet having a basic composition represented by the following general formula: (A1?xRx)O.n[(Fe1?yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba, R is at least one of rare earth elements including Y, M is at least one element selected from the group consisting of Co, Mn, Ni and Zn, and x, y and n are numbers meeting the conditions of 0.01?x?0.4, [x/(2.6n)]?y?[x/(1.6n)], and 5?n?6, and substantially having a magnetoplumbite crystal structure, is obtained by uniformly mixing a compound of Sr and/or Ba with an iron compound; calcining the resultant uniform mixture; adding a compound of the R element and/or the M element to the resultant calcined powder at a pulverization step thereof; and sintering the resultant mixture. The compound of the R element and/or the M element may be added at a percentage of more than 0 atomic % and 80 atomic % or less, on an element basis, at a mixing step before calcination.Type: GrantFiled: January 16, 2003Date of Patent: February 22, 2005Assignee: Hitachi Metals, Ltd.Inventors: Takashi Takami, Yutaka Kubota, Yasunobu Ogata
-
Patent number: 6852245Abstract: A composition for producing granules for molding ferrite, which comprises a ferrite slurry at least having raw ferrite powders; an ethylene-modified polyvinyl alcohol whose ethylene modified amount is from 4 to 10 mol %, average polymerization degree is from 500 to 1700, and average saponification degree is from 90.0 to 99.5 mol %; and water mixed therewith, ferrite granules produced from the composition, ferrite green body produced from the granules and ferrite sintered body produced from the sintered body are disclosed.Type: GrantFiled: April 26, 2002Date of Patent: February 8, 2005Assignee: TDK CorporationInventor: Hiroshi Harada
-
Publication number: 20040229151Abstract: A carrier core material containing at least one metal oxide (MLO) having a melting point of not higher than 1000° C. and at least one metal oxide (MHO) having a melting point of not lower than 1800° C., wherein the metal (MH) for constituting the metal oxide (MHO) has an electrical resistivity of not less than 10−5 &OHgr;·cm. Also disclosed is a two-component developing agent comprising a coated carrier, which comprises the carrier core material coated with a resin, and toner particles. Further disclosed is an image forming method comprising developing an electrostatic latent image formed on a photosensitive member with the two-component developing agent using an alternating electric field. The carrier core material and the coated carrier have high magnetization and are free from occurrence of leakage of electric charge over a wide range of electric field from low electric field to high electric field.Type: ApplicationFiled: February 6, 2004Publication date: November 18, 2004Applicant: POWDERTECH CO., LTD.Inventors: Hiromichi Kobayashi, Issei Shinmura, Tsuyoshi Itagoshi, Yuji Sato
-
Patent number: 6814883Abstract: A high frequency magnetic material includes a Y or M type hexagonal ferrite, wherein the hexagonal ferrite is expressed by the composition formula (1-a-b)(Ba1-xSrx)O.aMeO.bFe2O3, where Me is at least one selected from the group consisting of Co, Ni, Cu, Mg, Mn and Zn, 0.205≦a≦0.25, 0.55≦b≦0.595, 0≦x≦1, and 2.2≦b/a<3. A high frequency circuit element includes magnetic layers and internal electrode layers, wherein the high frequency circuit element is a sintered compact and the magnetic layers include the high frequency magnetic material.Type: GrantFiled: August 27, 2002Date of Patent: November 9, 2004Assignee: Murata Manufacturing Co., Ltd.Inventor: Hiroshi Marusawa
-
Patent number: 6811718Abstract: In the method for manufacturing ferrite type permanent magnets according to the formula M1-xRxFe12-yTyO19: a) a mixture of the raw materials PM, PF, PR and PT of elements M, Fe, R and T, respectively, is formed, Fe and M being the main raw materials and R and T being substitute raw materials; b) the mixture is roasted to form a clinker; c) wet grinding of said clinker is carried out; d) the particles are concentrated and compressed in an orientation magnetic field to form an anisotropic, easy to handle green compact of a predetermined shape; and e) the anisotropic green compact D is sintered to obtain a sintered element. The surface are GS and percentage of at least one of the substitute raw materials is selected according to the surface area and percentage of the iron raw material to obtain magnets with high squareness and overall performance index properties.Type: GrantFiled: April 9, 2002Date of Patent: November 2, 2004Assignee: Ugimag SAInventors: Antoine Morel, Philippe Tenaud
-
Publication number: 20040183049Abstract: An Mn—Zn ferrite includes base components of 44.0 to 49.8 mol % Fe2O3, 4.0 to 26.5 mol % ZnO, 0.8 mol % or less Mn2O3, and the remainder consisting of MnO, and contains 0.20 (0.20 excluded) to 1.00 mass % CaO as additive. Since the Mn—Zn ferrite contains less than 50.0 mol % Fe2O3 and a limited amount (0.8 mol % or less) of Mn2O3, an abnormal grain growth does not occur even if CaO content is more than 0.20 mass %, and a high electrical resistance can be gained thereby realizing an excellent soft magnetism in a high frequency band such as 1 MHz.Type: ApplicationFiled: January 28, 2004Publication date: September 23, 2004Applicant: Minebea Co., Ltd.Inventors: Osamu Kobayashi, Osamu Yamada, Kiyoshi Ito
-
Patent number: 6790379Abstract: A magnetic ferrite composition including at least one of Mg, Ni, Cu, Zn, Mn, and Li and having a content of carbon within a predetermined range, for example, over 9.7 weight ppm to less than 96 weight ppm. The composition may be used as the magnetic core for an inductor, transformer, coil, etc. used for radios, televisions, communication devices, office automation equipment, switching power sources, and other electronic apparatuses or magnetic heads for video apparatuses or magnetic disk drives or other electronic components.Type: GrantFiled: September 12, 2003Date of Patent: September 14, 2004Assignee: TDK CorporationInventors: Takuya Aoki, Takeshi Nomura
-
Patent number: 6780555Abstract: Black magnetic iron oxide particles having an average particle diameter of 0.05 to 1.0 &mgr;m have a three-phase structure comprising: a core portion containing at least one metal element other than Fe selected from the group consisting of Mn, Zn, Cu, Ni, Cr, Cd, Sn, Mg, Ti, Ca and Al in an amount of 0.1 to 10% by weight based on whole Fe contained in the particles; a surface coat portion containing at least one metal element other than Fe selected from the group consisting of Mn, Zn, Cu, Ni, Cr, Cd, Sn, Mg, Ti, Ca and Al in an amount of 0.1 to 10% by weight based on whole Fe contained in the particles; and an intermediate layer disposed between the core portion and the surface coat portion, containing substantially none of the metal elements other than Fe.Type: GrantFiled: January 22, 2002Date of Patent: August 24, 2004Assignee: Toda Kogyo CorporationInventors: Naoki Uchida, Minoru Kouzawa, Hiromitsu Misawa, Koso Aoki, Suehiko Miura
-
Patent number: 6773620Abstract: An oxide magnetic material of the invention is an oxide magnetic material of a hexagonal ferrite containing Sr, has grain boundary phases in the surrounding of the crystal grains, contains not less than 2% by weight, preferably not less than 5% by weight, of Sr in the grain boundary phases and not less than 10% by weight, preferably not less than 25% by weight, of at least one additive element selected from Bi, V, B and Cu.Type: GrantFiled: May 30, 2003Date of Patent: August 10, 2004Assignee: Sanyo Electric Co., Ltd.Inventors: Takashi Umemoto, Hideki Yoshikawa, Hitoshi Hirano
-
Patent number: 6773619Abstract: An Mn—Zn based ferrite composition having a main component comprised of Fe2O3: 51.5 to 54.5 mol %, ZnO: 19.0 to 27.0 mol % and the rest of substantially MnO and a first sub component comprised of 0.002 to 0.040 wt % of SiO2, 0.003 to 0.045 wt % of CaO and 0.010 wt % or less of P with respect to 100 wt % of the main component. In a magnetic core for a transformer comprised of this composition, the THD of the transformer becomes −84 dB or less in a broad frequency band, so it can be preferably used as a magnetic core, for example, for an xDSL modem transformer.Type: GrantFiled: July 12, 2002Date of Patent: August 10, 2004Assignee: TDK CorporationInventors: Yuji Sezai, Ippou Hirai, Masahiko Watanabe
-
Patent number: 6761830Abstract: A method for manufacturing type M hexaferrite powders fo the formula AFe12O19 where A is Ba, Sr, Ca, Pb or a mixture thereof. An iron oxide Fe2O3 and a compound A are mixed with a molar ratio n=Fe2O3/AO, formed and calcined, and the agglomerates which result from the calcining are ground to obtain a fine ferrite powder. The mixture is formed with a ratio n ranging between 5.7 and 6.1, and with a predetermined degree of homogeneity, and before or during the grinding process, an agent controlling the microstructure is introduced.Type: GrantFiled: February 15, 2002Date of Patent: July 13, 2004Assignee: Ugimag S.A.Inventors: Antoine Morel, Eric Brando, Philippe Tenaud
-
Patent number: 6761839Abstract: A composition of material used for making hfMLCIs having a sintering temperature below 1000°. The composition comprises a major component and a minor component, said major component being a general formula: Ba3Co2-x-yZnxCuyMnxFe24-z-wO41, wherein x, z, w,=0-1.0 and y=0-0.8, and said minor component comprising at least one compound selected from the group of Bi2O3, V2O5,PbO,B2O3, Lif and CaF2. HfMLCIs made from the composition of the present invention are capable of functioning in the frequency region of 300-800 MHz.Type: GrantFiled: August 27, 2001Date of Patent: July 13, 2004Inventors: Xiaohui Wang, Longtu Li, Ji Zhou, Zhengxing Yue, Zhenwei Ma, Shuiyuan Su
-
Patent number: 6758894Abstract: A black pigment substantially free of objectionable transition metal materials is disclosed. This pigment is particularly useful for coloring glass since the absence of the transition metal gives it excellent recycling properties. The pigment is an alkaline earth (preferably strontium) iron maganese oxide material as specifically defined the in the present invention.Type: GrantFiled: April 17, 2003Date of Patent: July 6, 2004Assignee: The Shepherd Color CompanyInventor: Joel D. Houmes
-
Patent number: 6755988Abstract: A method for making ferrite magnets of formula M1−xRxFe12−yTyO19 including: a1) forming a powder mixture MP of related raw materials, a2) transforming into granules in green state A, b) calcining the granules in green state to form clinker B, c) wet grinding clinker B to obtain a homogeneous dispersion of fine particles C, d) concentrating and compressing the particles under an orienting magnetic field to form an anisotropic green compact D, and e) sintering the green compact to obtain a sintered element E. In step a1), MP is formed from a dry mixture MS of M and Fe powder elements and a dispersion DF of raw materials related to elements R and T, and in step b) the granules in green state are calcined to obtain a clinker B which is homogeneous in chemical composition and size and with apparent low density, between 2.5 and 3.5.Type: GrantFiled: July 10, 2002Date of Patent: June 29, 2004Assignee: Ugimac, S.A.Inventors: Philippe Tenaud, Eric Brando
-
Publication number: 20040121188Abstract: A ferrite magnet obtained by adding at least one element selected from the group consisting of Co, Ni, Mn and Zn to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof, and then subjecting the mixture to re-calcining and/or sintering process(es). By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: ApplicationFiled: July 24, 2003Publication date: June 24, 2004Inventors: Etsushi Oda, Sachio Toyota, Seiichi Hosokawa
-
Patent number: 6749768Abstract: Provided is magnetic ferrite powder in which a peak intensity ratio of Z phase (M3Me2Fe24O41: M=one or more kinds of alkaline-earth metal, Me=one or more kinds from Co, Ni, Mn, Zn, Mg and Cu) of hexagonal ferrite is 30% or higher in X-ray diffraction and a peak value of a grain size distribution is in a range from 0.1 &mgr;m to 3 &mgr;m.Type: GrantFiled: February 14, 2002Date of Patent: June 15, 2004Assignee: TDK CorporationInventors: Masami Endo, Atsuyuki Nakano
-
Patent number: 6737451Abstract: A magnetic compound is formed comprising: (1) 25% to 50% by volume of polyphenylene sulfide (PPS); (2) 50% to 70% by volume of coated samarium cobalt (the coating comprising 1 to 30% Kaolin by weight of the coating and 70 to 99% potassium silicate by volume of the coating); and (3) 0% to 5% by volume of an internal lubricant. The PPS polymer component of the compound renders the compound amenable to be injection molded to precise tolerances and also has a low coefficient of linear thermal expansion. The samarium cobalt constituent of the compound provides thermal stability. The potassium silicate/kaolin coating separates the PPS from the samarium cobalt, thus preventing degradation (i.e, PPS viscosity reduction) during manufacture.Type: GrantFiled: September 13, 2001Date of Patent: May 18, 2004Assignee: Arnold Engineering Co., Ltd.Inventors: James Carlberg, Paul R. Nastas
-
Publication number: 20040075075Abstract: The present invention provides a Y-type hexagonal ferrite thin film suitable for high frequency devices, having a crystal structure with the c-axis oriented perpendicular to the surface of the thin film. The present invention also provides a method of producing the Y-type hexagonal ferrite thin film, comprising the steps of preparing a viscous solution containing a metal-organic complex which is formed using a primary component including a Fe+3 ion, and a secondary component including a Ba2+ ion, at least one transition metal ion selected from the group consisting of Fe2+, Co2+, Ni2+, Zn2+, CU2+ and Mn2+; and optionally at least one metal ion selected from the group consisting of Sr2+, Ca2+ and Pb2+, forming a film having a Y-type ferrite composition on a surface made of noble metal through a coating process using the viscous solution, and burning the film at a temperature of 750° C. or more.Type: ApplicationFiled: November 4, 2003Publication date: April 22, 2004Inventors: Jun Takada, Tatsuo Fujii, Makoto Nakanishi
-
Publication number: 20040069969Abstract: Provided is magnetic ferrite powder in which a peak intensity ratio of Z phase (M3Me2Fe24O41: M=one or more kinds of alkaline-earth metal, Me=one or more kinds from Co, Ni, Mn, Zn, Mg and Cu) of hexagonal ferrite is 30% or higher in X-ray diffraction and a peak value of a grain size distribution is in a range from 0.1 &mgr;m to 3 &mgr;m.Type: ApplicationFiled: February 14, 2002Publication date: April 15, 2004Inventors: Masami Endo, Atsuyuki Nakano
-
Publication number: 20040061090Abstract: A ferrite magnet obtained by adding a ferrite having a spinel-type structure to a ferrite having a hexagonal M-type magnetoplumbite structure, in which a portion of Sr, Ba, Pb or Ca is replaced with at least one element that is selected from the group consisting of the rare-earth elements (including Y) and Bi and that always includes La, during the fine pulverization process thereof. By adding a small amount of the element such as Co, Ni, Mn or Zn to the ferrite already having the hexagonal M-type magnetoplumbite structure during the fine pulverization process thereof, the magnetic properties can be improved.Type: ApplicationFiled: July 22, 2003Publication date: April 1, 2004Inventors: Etsushi Oda, Seiichi Hosokawa, Sachio Toyota
-
Patent number: 6699332Abstract: A method of producing a magnetic recording medium comprising the steps of providing a substrate having a layer of a non-magnetic material that can be converted into a magnetic state by annealing, and then converting selected portions of the non-magnetic layer to a magnetic state by subjecting them to annealing by directing a focussed beam of radiation onto the substrate to form a patterned magnetic layer comprising an ordered array of magnetic regions separated by non-magnetic regions.Type: GrantFiled: November 13, 2000Date of Patent: March 2, 2004Assignee: Data Storage InstituteInventors: Seidikkurippu N. Piramanayagam, Jian Ping Wang
-
Patent number: 6695972Abstract: This invention relates to the formula and preparation method for a multi-layer chip inductor material used in very high frequencies. The main composition of this material is planar hexagonal soft magnetic ferrite, and ingredient is low temperature sintering aid. Preparation method is a synthetic method of solid phase reaction. The sintering aid is prepared by secondary doping. By the process of ball grinding, drying, pre-calcining, ball grinding, drying, granulating, forming, sintering, and so forth, very high frequency inductor material of superior quality is obtained, realizing low temperature sintering under a temperature lower than 900° C. This invention is of low cost, high performance, suitable for multi-layer chip inductors at very high frequencies of 300M-800 MHz.Type: GrantFiled: January 14, 2002Date of Patent: February 24, 2004Assignees: Tsinghua Tongfang Co., Ltd., Tsinghua UniversityInventors: Xiaohui Wang, Longtu Li, Ji Zhou, Shuiyuan Su, Zhilun Gui, Zhenxing Yue, Zhenwei Ma, Li Zhang
-
Publication number: 20040026654Abstract: A ferrite magnet powder and a ferrite magnet exhibiting improved magnetic properties are provided at a reduced manufacturing cost. An application product and manufacturing methods thereof are also provided. An oxide magnetic material includes, as a main phase, a ferrite having a hexagonal M-type magnetoplumbite structure. The material includes: A, which is at least one element selected from the group consisting of Sr, Ba, Pb and Ca; R, which is at least one element selected from the group consisting of Y (yttrium), the rare earth elements and Bi; Fe; and B (boron). The constituents A, R, Fe and B of the material satisfy the inequalities of 7.04 at %≦A=8.68 at %, 0.07 at %≦R≦0.44 at %, 90.4 at %≦Fe≦92.5 at % and 0.015 at %≦B≦0.87 at % to the sum of the elements A, R, Fe and B.Type: ApplicationFiled: March 24, 2003Publication date: February 12, 2004Inventors: Sachio Toyota, Isamu Furuchi, Yoshinori Kobayashi
-
Patent number: 6689287Abstract: The subject invention includes a composite material comprising a ferroelectric material and a ferromagnetic material having a loss factor (tan &dgr;) for the composite material which includes a dielectric loss factor of the ferroelectric material and a magnetic loss factor of the ferromagnetic material. The composite material achieves the loss factor of from 0 to about 1.0 for a predetermined frequency range greater than 1 MHz. The ferroelectric material has a dielectric loss factor of from 0 to about 0.5 and the ferromagnetic material has a magnetic loss factor of from 0 to about 0.5 for the predetermined frequency range. The ferroelectric material is present in an amount from 10 to 90 parts by volume based on 100 parts by volume of the composite material and the ferromagnetic material is present in an amount from 10 to 90 parts by volume based upon 100 parts by volume of the composite material such that the amount of the ferroelectric material and the ferromagnetic material equals 100 parts by volume.Type: GrantFiled: November 1, 2001Date of Patent: February 10, 2004Assignee: Delphi Technologies, Inc.Inventors: Norman W. Schubring, Joseph V. Mantese, Adolph L. Micheli
-
Patent number: 6680000Abstract: A polyamide plastic magnetic material excellent in fluidity is provided, and a plastic magnet made of the same is highly flexible with no deterioration in strength and does not crack during fabrication. The polyamide plastic magnetic material consists of: magnetic powder; polyamide resin; and a predetermined amount of bis unsaturated fatty acid amide represented by the formula: R1—CONH—R3—NHCO—R2 where R1 and R2 is an unsaturated hydrocarbon group having at least one double bond and R3 is a hydrocarbon group. The three components are kneaded into a final magnetic material.Type: GrantFiled: July 10, 2002Date of Patent: January 20, 2004Assignee: Minebea Co., Ltd.Inventors: Takahiro Sasazawa, Yoshimichi Sakama
-
Patent number: 6669861Abstract: A Y-type hexagonal oxide magnetic material is provided containing at least Fe, Co, and M (where M is at least one of Ba and Sr) as well as O, wherein the relationship of x+3&sgr;≦4 is satisfied, in which x represents the average grain size (&mgr;m) of a sintered compact thereof, and &sgr; represents the standard deviation of the grain size. When this material is used for a magnetic body of an inductor element, a high Q factor can be maintained in a high frequency range of not less than 200 MHZ.Type: GrantFiled: August 31, 2001Date of Patent: December 30, 2003Assignee: Murata Manufacturing Co. LtdInventor: Hiroshi Marusawa
-
Publication number: 20030235689Abstract: The present invention is directed to hexagonal ferrite particles coated with a dispersant and having an exceptionally uniform particle size distribution that makes them particularly useful in the manufacture of high density magnetic tape.Type: ApplicationFiled: May 29, 2003Publication date: December 25, 2003Inventors: William Rafaniello, Pete C. LeBaron, Melinda H. Keefe, Promod Kumar, Eric J. Swedburg
-
Patent number: 6666991Abstract: A fluorescent or luminous composition, comprising a multilayered film-coated powder having at least two coating films on a base particle, and a fluorescent or luminous substance; the composition, wherein at least one layer of the coating films contains the fluorescent or luminous substance; a genuine/counterfeit discrimination object, in which the fluorescent or luminous composition; and a genuine/counterfeit discrimination method, comprising recognizing fluorescence or luminescence by irradiating, with a light, the genuine/counterfeit discrimination object.Type: GrantFiled: May 29, 2001Date of Patent: December 23, 2003Assignees: Nittetsu Mining Co., Ltd.Inventors: Takafumi Atarashi, Kiyoshi Hoshino, Katsuto Nakatsuka
-
Patent number: 6660179Abstract: There is provided a sintered body at least 80% of which is constituted of a Y-type hexagonal ferrite. The sintered body contains, as main components, a cobalt oxide, a copper oxide, an iron oxide and AO (AO is at least one of BaO or SrO) in predetermined amounts in mol %, more preferably contains MO (MO is at least one of NiO, ZnO or MgO) in a predetermined amount in mol % in addition to the above components, and also contains, as additional components, bismuth oxide (Bi2O3), borosilicate glass, borosilicate zinc glass or bismuth glass in predetermined amounts in wt %. Thus, a sintered body which exhibits good magnetic properties and is usable up to a high frequency band ranging from several hundred megahertz to gigahertz, contains as few hetero phases other than a Y-type hexagonal ferrite as possible and can be calcined at a temperature of not higher than 1,000° C., particularly about 900° C., and a high-frequency circuit component using the sintered body can be provided.Type: GrantFiled: March 12, 2002Date of Patent: December 9, 2003Assignee: TDK CorporationInventors: Hidenobu Umeda, Taku Murase
-
Patent number: 6652767Abstract: In a composition for a plastic magnet, containing an Nd—Fe—B based alloy powder and a ferrite magnetic material powder mixed to a resin material, the Nd—Fe—B based alloy powder has particle sizes distributed in a range of 100 to 400 &mgr;m, and the ferrite magnetic material powder has an average particle size of approximately 1 &mgr;m. The weight ratio of the Nd—Fe—B based alloy powder to the ferrite magnetic material powder is in a range of 30:70 to 70:30. Further, the ratio of the total weight of the Nd—Fe—B based alloy powder 2 and the ferrite magnetic material powder 3 to the weight of the resin material is in a range of 90:10 to 80:20. Thus, in a plastic magnet 1 formed using the composition, peripheries of particles of the Nd—Fe—B based alloy powder 2 are surrounded by particles of the ferrite magnetic material powder 3 and the resin material.Type: GrantFiled: April 9, 2002Date of Patent: November 25, 2003Assignee: Enplas CorporationInventor: Satoshi Kazamaturi