Abstract: 1. Compounds of the formula I ##STR1## in which n is a number from 1 to 100, Y is --N(R.sup.3)--, --S-- or --S--R.sup.4 --S--, R.sup.1 is C.sub.2 -C.sub.8 -alkylene, which can be interrupted by 1 to 3 ether oxygen atoms, R.sup.2 is hydrogen, unsubstituted or hydroxyl-monosubstituted to -pentasubstituted C.sub.1 -C.sub.8 -alkyl, which can be interrupted one or more times by --O--, --S-- or --N(R.sup.5)-- as long as R.sup.2 is not unsubstituted C.sub.1 -C.sub.8 -alkyl when Y is --S-- and n is 1, R.sup.3 is hydrogen unsubstituted or hydroxylmonosubstituted to -pentasubstituted C.sub.1 -C.sub.8 -alkyl, which can be interrupted one or more times by --O--, --N(R.sup.5)-- or --S--, R.sup.4 is unsubstituted or OH-monosubstituted or -polysubstituted C.sub.2 -C.sub.8 -alkylene, which can be interrupted one or more times by --O-- or --S--, are very highly suitable for use as high pressure and antiwear additives for polar functional fluids.

Abstract: The invention relates to compositions comprising a lubricant or a hydraulic fluid and at least one compound of the general formula ##STR1## wherein n is 2, 3 or 4, X is --S--, --O--, --O--CO-- or --CH.sub.2 --, R.sup.1 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or phenyl, and R.sup.2 is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.4 alkyl which is substituted by an --OH group, or a group of the formula --CH.sub.2 --CH(OH)--CH.sub.2 --X--R.sup.1, wherein X and R.sup.1 have the given meanings, and to novel compounds of the formula indicated above. The glucamine derivatives of formula I are especially suitable for use as antiwear agents and as extreme pressure additives for mineral and synthetic lubricant oils and hydraulic fluids, and also as amphipolar ligands for imparting lipophilic properties to intrinsically hydrophilic metal salts, metal oxides, metal hydroxides and to protic acids. The complex compounds so obtained of the formulaM.sub.n.sup.m. X.sub.m.sup.n. pY.

Abstract: Water-based hydraulic fluids are thickened by admixing the fluid with a viscoelastic surfactant. Viscoelastic surfactants comprise surfactant ions and organic counterions that associate with the hydraulic fluid to form the viscoelastic surfactant. Water-based hydraulic fluids of this invention are highly shear stable and do not experience substantial viscosity loss with an increase in temperature. The hydraulic fluids are capable of providing low amounts of wear in pumping apparatus during use.

Abstract: Aqueous fluids are thickened with fatty acid modified polyoxyalkylene diamines. The polyoxyalkylene diamines are of the formula:H.sub.2 NCH(CH.sub.3)CH.sub.2 O(CH.sub.2 CH(R)O).sub.x CH.sub.2 CH(CH.sub.3)NH.sub.2wherein:R is methyl or hydrogen andx is a number selected to give the diamine a molecular weight of 3000 to 9000.The fatty acid is a hydrophobic mono- or dicarboxylaic acid of 12 to 36 carbon atoms. The ratio of amine equivalent: acid ranges from 1:0.5 to 1:1.The aqueous fluids optionally incorporate ethylene glycol. They are useful for water/glycol based hydraulic fluids, cosmetics and surfactants.

Abstract: Improved durability of shift-feel frictional characteristics in automotive transmission fluids is achieved by use of an initially substantially inert (friction-wise) compound--viz., an aliphatic tertiary amine having one long chain and two short chain groups--incorporated into a formulation which is otherwise balanced for initially good shift-feel frictional properties. When the fluid is subjected to the oxidative and thermal degradation conditions encountered under normal service conditions, the friction modifiers that give the fluid good initial shift-feel frictional properties degrade. However, as this occurs the aliphatic tertiary amine has itself been transformed by a mechanism that activates it so that in its new form it acquires the ability to provide good shift-feel properties. Thus this additive serves as a time-activated or delayed action substitute for the friction modifiers that have been degraded during service.

Abstract: Various heterocyclic compounds have been discovered that impart improved fuel economy and friction modification to lubricant and fuel compositions. These hetrocyclic compounds of the invention preferably contain nitrogen and may be further reacted with hydrocarbyl carboxylic acid acylating reactants or hydrocarbyl phenolic reactants to give higher molecular materials. These higher molecular weight materials have higher oil-solubility and impart dispersancy properties to lubricant and fuel compositions.

Abstract: A composition is disclosed which comprises water and at least one carboxylic salt dispersed or dissolved in said water, said salt being derived from:(A)(I) at least one derivative formed by reacting at least one C.sub.

Abstract: The invention relates to the use of combinations of water-soluble polymeric polyether polyols, in which at least 50% of the terminal hydroxyl groups are blocked by reaction with a monoisocyanate incorporating a long-chain aliphatic hydrocarbon radical, and certain surfactants as thickener systems for high water based functional fluids and to the thickened high water based functional fluids.

Abstract: Aqueous functional fluids, in particular hydraulic and metal-working fluids, containing a copolymer which is prepared by emulsion or solution copolymerization, initiated by free radicals, of unsaturated, copolymerizable monomers, the copolymers being built up from:(a) 1-60% by weight of ethylenically unsaturated carboxylic acids,(b) 0.5-30% by weight of a surface-active unsaturated ester,(c) 30-85% by weight of methacrylic acid esters or acrylic acid esters of aliphatic (C.sub.1 -C.sub.18)-alcohols,(d) 0-40% by weight of other ethylenically unsaturated comonomers,(e) 0-3% by weight of polyethylenically unsaturated compounds, and(f) 0-5% by weight of molecular weight regulators, and, if appropriate, the free acid groups of the copolymers subsequently having been partly or completely neutralized by addition of bases, and converted into water-soluble or colloidally water-dispersible copolymer salts.

Abstract: The use of aromatic amine or hindered phenols, and beta-thiodialkanol reaction products are described as being useful anti-oxidants.

Abstract: Aqueous fluids are thickened with epoxide modified polyoxyalkylene diamines. The polyoxyalkylene diamines are of the formula:H.sub.2 NCH(CH.sub.3)CH.sub.2 O(CH.sub.2 CH(R)O).sub.x CH.sub.2 CH(CH.sub.3)NH.sub.2wherein:R is methyl or hydrogen andx is a number selected to give the diamine a molecular weight of 3000 to 9000.The epoxide is a hydrophobic monoepoxide, diepoxide or mixture thereof.The aqueous fluid optionally incorporate ethylene glycol. They are useful for water/glycol base hydraulic fluids, cosmetics and surfactants.

Abstract: Single-phase, thermally-stable, corrosion-inhibiting heat transfer fluids comprising triethylene glycol, a corrosion-inhibiting amount of a mixture of a soluble borate compound and a soluble Group VIa metal oxygenate compound selected from the group consisting of chromate, molybdate and tungstate compounds, and, optionally, water, a copper corrosion inhibitor and sodium nitrate.

Abstract: A phosphorus free or a low phosphorus containing lubricant composition is provided by formulating the composition with an additive of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently alkyl of 1 to about 7 carbons, aryl, aralkyl or together form an alicyclic or heteroalicyclic radical in which the ring is completed through the nitrogen; X is O or S; a is 1 or 2; R.sub.3 and R.sub.4 are independently H, alkyl or aryl; and Z is ##STR2## wherein R.sub.5 is hydrogen, alkyl, or aralkyl, and ##STR3## wherein Y is H, OH, R.sub.6 where R.sub.6 is alkyl, aryl or aralkyl, OR.sub.6, OR.sub.7 --OH, where R.sub.7 is alkylene of 1 to about 7 carbon atoms, and NR.sub.8 R.sub.9 where R.sub.8 and R.sub.9 are independently hydrogen, alkyl, cycloaliphatic, heteroalicyclic or together form an alicyclic or heteroalicyclic radical in which the ring is completed through the nitrogen; with the proviso that when a is 1, Y is not OR.sub.6.

Abstract: A heat storage material is disclosed having a melting transition temperature below 5.degree. C. The invented material comprises ethylene diamine in a mixture with noncorrosive, high heat of fusion material or materials soluble therein, so that the invented material is noncorrosive to standard metal tubing refrigeration systems.

Abstract: Water-soluble corrosion-inhibiting mixtures containing(a) one or more ammonium salts of fatty acids corresponding to the following general formula ##STR1## in which n=1 or 2 while R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be the same or different and represent hydrogen, unbranched or branched C.sub.1 -C.sub.6 alkyl groups, C.sub.1 -C.sub.6 hydroxyalkylene groups or C.sub.1 -C.sub.8 aminoalkylene groups and R.sup.5 represents C.sub.6 -C.sub.10 alkyl groups, and(b) one or more polyol fatty acids and/or salts thereof corresponding to the following general formula ##STR2## in which R.sup.6 is a C.sub.1 -C.sub.19 alkyl or alkylene group and R.sup.7 represents an organic residue formed from a dihydroxy or polyhydroxy compound by elimination of a hydroxyl group, M.sup.(+) =H.sup.(+), Na.sup.(+), K.sup.(+) or an ammonium ion [R.sup.1 R.sup.2 R.sup.3 R.sup.4 N].sup.

Abstract: This invention relates to the use of tertiary butyl derivatives of toluenediamine and specifically N-tert-butyl-2,6-toluenediamine as an antioxidant material for preventing oxidation of organic materials.

Abstract: Disclosed herein is an improved coolant additive having corrosion inhibitive and scale preventative properties. In particular, the inventive additive in its various embodiments is specifically designed to avoid the use of silicates which, as is well known, form deposits which coat the surfaces and passageways of heavy duty diesel and other cooling systems, resulting in shortened life and reduced efficiency thereof. The inventive additive includes sodium hydroxide and/or alkal metal carbonate, ricinoleic acid, Reomet 41, Thiotax, various forms of SMA copolymers, sodium benzoate, sodium nitrate, chelant(s), antifoam agents, dye/pH indicator and soft water (composition solvent), mixed together in predetermined proportions with the various embodiments of the inventive additive including other constituent substances.

Abstract: Benzothiazoline derivatives having the general formula: ##STR1## wherein R.sub.1 and R.sub.2 may be a hydrogen atom, a hydrocarbyl group, a substituted hydrocarbyl group, an amino group or a halogen atom, a hydroxyl group, alkoxy or aryloxy group, or R.sub.1 and R.sub.2 together may form a cyclic group which may optionally contain a heterocyclic atom; R.sub.3 is a hydrogen atom or a hydrocarbyl group; X may be hydrocarbyl, substituted hydrocarbyl, halogen, hydroxyl, carboxyl, amino or amido two X's may be taken together to form a polycyclic compound which may be substituted in like manner; n=0 or 1-4 are useful as antioxidants for compounds subject to oxidative degradation. The compounds are prepared by reacting an appropriate o-aminothiophenol with a suitable carbonyl compound.

Abstract: Substantially oil-free aqueous industrial fluids possess superior lubricating and wear preventing characteristics and are useful as hydraulic fluids and metalworking compositions. Fluids of the invention comprise (1) an aqueous liquid and (2) a water-soluble synthetic addition copolymer of a poly-2-oxazoline or a poly-2-oxazine.The industrial fluids exhibit good Newtonian behavior and mechanical stability at high shear.

Abstract: Thermally stable heat transfer fluids are disclosed which are polyoxyethylene polymers initiated with bisphenols. These polymers do not smoke excessively, volatilize, nor form sludge in high temperature heat transfer operations in open and closed systems.

Abstract: Oil-in-alcohol microemulsion-containing composition concentrate containing oil-soluble corrosion inhibitor. The composition concentrate, when diluted with water, is useful in automotive coolant systems as an antifreeze.

Abstract: This invention relates to thickened high-viscosity water based hydraulic fluids. Such fluids are prepared by blending water, organic thickener and conventional hydraulic fluid additives. Organic thickeners tend to lose their thickening effect with time, and particularly when subjected to oxidizing agents, heat, prolonged use in a pump, etc. In accordance with the instant invention, preservation of the thickener, particularly with respect to viscosity loss, is achieved by blending with the final fluid a fluid concentrate, or the thickener itself, a compound selected from the group consisting of ethylene glycol, propylene glycol, propylene glycol polymers and copolymers containing at least 50 percent by weight of oxypropylene groups, a dimercaptothiadiazole, neodecanoic acid, a hindered phenol antioxidant and mixtures thereof.

Abstract: The pasty damping medium is used to damp mechanical and/or acoustic oscillations. The agent contains as a minimum compound a solid finely divided substance or a mixture of solid finely divided substances, as a liquid phase, a silicone oil, a polyglycol, a mineral oil and/or a saturated aliphatic or aromatic aliphatic carboxylic acid ester, an agent for increasing the interfacial surface activity or a surfactant, a finely divided magnesium and/or aluminium silicate and/or a silicon dioxide finely divided as a viscosity stabilizer and possibly a small quantity of an antioxidant. The invention concerns also a method for producing the pasty damping medium and the use of the pasty damping medium in different hydraulic damping devices or for industrial shock absorber or industrial vibration damper.

Abstract: This invention relates to synthetic polyether thickeners and thickened aqueous systems containing them. The thickeners are unique because they can be used in aqueous systems at less than ten percent weight concentration which will flow in a Vickers 104(C) Vane pump at use temperatures. These properties make them particularly useful for thickening hydraulic fluids used in high pressure vane and gear pumps. The thickeners are prepared by reacting conventional polyether polyols with alpha-olefin epoxides having an average of 6 to 12 total carbon atoms to obtain products with specific epoxide-to-hydroxyl ratios.

Abstract: A composition of aminobenzylamine is provided which is mainly composed of m-aminobenzylamine and p-aminobenzylamine in either the presence or absence of a small quantity of o-aminobenzylamine, is liquid at room temperature, and is an excellent cold-setting type curing agent useful for thermosetting resin compositions.

Abstract: An electroviscous fluid comprising more than 25% by weight of silica gel with a water content of 1 to 15% by weight, a non-conductive oily phase dispersion medium, 1 to 30% by weight of one or more polymers soluble in the dispersion medium, the weight percentage being based on the water-containing silica gel, and the polymers having a molecular weight in the range of from 5.times.10.sup.3 to 10.sup.6 and containing 0.1 to 10% by weight of N and/or OH and 25 to 83% by weight of C.sub.4 to C.sub.24 -alkyl groups. Such electroviscous fluids are useful for transmitting powerful forces by means of a low electronic output, for example, in hydraulic valves and shock absorbers.

Abstract: Aqueous functional fluids, in particular hydraulic and metal-working fluids, containing a copolymer which is prepared by emulsion or solution copolymerization, initiated by free radicals, of unsaturated, copolymerizable monomers, the copolymers being built up from:(a) 1-60% by weight of ethylenically unsaturated carboxylic acids,(b) 0.5-30% by weight of a surface-active unsaturated ester,(c) 30-85% by weight of methacrylic acid esters or acrylic acid esters of aliphatic (C.sub.1 -C.sub.18)-alcohols,(d) 0-40% by weight of other ethylenically unsaturated comonomers,(e) 0-3% by weight of polyethylenically unsaturated compounds, and(f) 0-5% by weight of molecular weight regulators, and, if appropriate, the free acid groups of the copolymers subsequently having been partly or completely neutralized by addition of bases, and converted into water-soluble or colloidally water-dispersible copolymer salts.

Abstract: Combinations of carboxylic solubilizers, made by reaction of an acylating agent with an N-(hydroxyl-substituted hydrocarbyl) amine and surfactants are useful in incorporating oil-soluble, water-insoluble functional additives into aqueous systems. Typical solubilizers are made by reacting an alkyl-substituted succinic anhydride containing about 12 to about 500 carbon atoms with an alkanol amine such as diethyl ethanol amine. Typical surfactants are nonionic hydrophilic surfactants such as ethyoxylated phenols and ionic surfactants of both the anionic and cationic type. Typical functional additives are anti-wear, extreme pressure and load-carrying agents such as dithiophosphates. The aqueous systems formed with the aid of such combinations are useful, for example, as water-based hydraulic fluids.

Abstract: A composition is disclosed which comprises a water-dispersible reaction product of (A) at least one compound represented by the formula ##STR1## wherein R is a hydrocarbyl group of from about 8 to about 40 carbon atoms, with (B) at least one water-dispersible amine terminated poly(oxyalkylene). Aqueous concentrates and water-based functional fluids comprising these compositions are also disclosed. These reaction products are useful as shear-stable thickeners for such functional fluids.

Abstract: Novel nitrile functional glycol ether acetals that are useful components of hydraulic pressure transmission fluids are described.

Abstract: A corrosion inhibitor for use in water and liquid alcohol antifreeze/coolant compositions comprising the combination of a C.sub.5 -C.sub.16 aliphatic monobasic acid or the alkali metal, ammonium, or amine salt of said acid, a C.sub.5 -C.sub.16 hydrocarbyl dibasic acid or the alkali metal, ammonium, or amine salt of said acid, and a hydrocarbyl triazole gives synergistic corrosion protection to metal surfaces as compared with formulations containing either the monoacid or diacid component alone, or formulations containing other conventional corrosion inhibitors.

Abstract: The invention relates to a water-based functional fluid thickened by an associative polyether thickener whose thickening ability is enhanced by the addition of certain fatty acid amides.

Abstract: Thickener compositions, hydraulic fluid and metalworking fluid concentrates, aqueous concentrates and water-based hydraulic fluid and metalworking fluid or lubricant compositions are thickened to an oil-like viscosity by a low solids combination of thickeners. The combination of thickeners consists of at least one polyurethane and at least one dimer ester.

Abstract: A method of indirect liquid phase heat transfer which comprises continuously circulating between a heat generating and a heating source or water-soluble or water-dispersible polymer having a viscosity of less than about 100 centistokes at 100.degree. F., of the formula:R(OAR').sub.xwhereinR is a C.sub.5 to C.sub.36 linear branched or alicyclic aliphatic hydrocarbyl group;O is oxygen;A is a polyoxyalkylene residue having oxyalkylene units derived from ethylene oxide or ethylene oxide and at least one other lower alkylene oxide having 3 or 4 carbon atoms;R' is hydrogen, a C.sub.1 to C.sub.8 alkyl group or nonbornyl; andx is an integer having a value of 1 to 6, wherein for values of x greater than 1 each AR' may be the same or different.

Abstract: A method of indirect liquid phase heat transfer utilizing as a heat transfer fluid a composition comprising polytetra(methylene oxide) or poly(trimethylene oxide) homopolymers having molecular weights of from about 300 to about 1,000.

Abstract: The friction exhibited by a flowing aqueous liquid containing a viscoelastic surfactant can be further reduced by adding to the aqueous liquid an organic electrolyte capable of associating with the surfactant ion of the viscoelastic surfactant. For example, the friction exhibited by an aqueous liquid containing cetyl trimethylammonium salicylate can be further reduced by the addition of sodium salicylate to the liquid. The resulting aqueous liquid systems exhibiting the reduced friction are shear stable and useful in a wide variety of applications.

Abstract: Novel bicyclic amide acetals having substituents in the 2, 5 and 7 positions and a process for their preparation are described.

Abstract: Non-flammable hydraulic fluids which are particularly useful for replacing existing hydraulic fluids in hydraulic systems employing acrylonitrile-butadiene rubber and fluoroelastomer seals are disclosed. The non-flammable hydraulic fluids of the present invention comprise a fluorinated chlorotrifluoroethylene oil, a refined naphthenic oil, a phenolic antioxidant, a sulfur corrosion inhibitor, a metal deactivator, and an aliphatic ester. The fluorinated chlorotrifluoroethylene oil is present in an amount of at least about 75% by volume of the hydraulic fluid. In addition to being non-flammable, such hydraulic fluids are compatible with both the seals and brass components which contact the hydraulic fluid in hydraulic systems.

Abstract: A corrosion inhibited antifreeze composition incorporating a corrosion inhibitor is described. Six dibasic salts of dicyclopentadiene dicarboxylic acid and optionally a triazole comprise the corrosion inhibitor.

Abstract: A corrosion inhibited antifreeze composition using a three-part corrosion inhibitor mixture is described. A dicarboxylic acid component, an alkali metal silicate and a triazole comprise the three corrosion inhibitors. Use of this type of mixture permits the express exclusion of amines, nitrites, nitrates, chromates, borates and phosphates and their attendant disadvantages. Nevertheless, the inventive system provides excellent corrosion resistance in alcohol-based antifreeze, particularly with respect to aluminum.

Abstract: The present invention relates to aqueous solutions having dilatant properties in which the aqueous solution contains a polymer complex which is a water soluble polymer backbone containing an anionic comonomer and a copolymer of a water soluble polymer backbone containing a cationic comonomer.

Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of an anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) mono-, di-, and trihydroxy-substituted aromatic non-carboxylic acid compounds; with(b) substituted aromatic compounds, wherein the substituents comprise mono-, di-, and trinitro groups.

Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of at least one selected anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) mono-, di-, or trihydroxy-substituted aromatic compound; with(b) an aromatic compound substituted with one to three electron-withdrawing substituents, wherein said electron-withdrawing substituents are selected from the group consisting of cyano, sulfo, and mixtures thereof.

Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of at least one selected anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) an aromatic compound containing one to three electron-releasing substituent components, wherein said electron-releasing substituents are selected from the group consisting of amino, alkyl-substituted amino having 1 to about 12 carbon atoms, amido groups of the formula --NHC(.dbd.

Abstract: A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --Ar--(OH).sub.

Abstract: A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --Ar--(OH).sub.

Abstract: A water base hydraulic fluid is disclosed. The fluid comprises 40 wt % of an amphoteric surfactant of the formula:CH.sub.3 (CH.sub.2).sub.5 --CH(CH.sub.3)--NHCH.sub.2 CH.sub.2 COOHand 10 wt % polypropylene glycol in water.The diluted hydraulic fluid is noted for its good wear characteristics, anticorrosiveness and non foaming nature.

Abstract: The invention relates to a water-based functional fluid thickened by an associative polyether thickener whose thickening ability is enhanced by the addition of certain quaternary ammonium salts.

Abstract: A water base hydraulic fluid is disclosed. The fluid comprises 40 wt % of an amphoteric surfactant of the formula: ##STR1## wherein R is a mixture C.sub.12 alkyl groups and 10 wt % polypropylene glycol in water.The diluted hydraulic fluid is noted for its good wear characteristics, anticorrosiveness and non foaming nature.

Abstract: Heat exchange fluids are improved by incorporating therein a viscoelastic surfactant composition. The viscoelastic surfactant is employed in an amount sufficient to reduce the friction experienced by the heat transfer fluid in a heat transfer apparatus while providing good heat transfer. The improved fluids are useful in district heating applications.