Heteroaromatic Compound Comprising Sulfur Or Selene (e.g., Polythiophene) (epo) Patents (Class 257/E51.029)
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Patent number: 8952364Abstract: Light-emitting devices are described herein.Type: GrantFiled: November 8, 2012Date of Patent: February 10, 2015Assignee: Nitto Denko CorporationInventors: Qianxi Lai, Shijun Zheng, David T. Sisk, Amane Mochizuki
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Patent number: 8920939Abstract: Regioregular polythiophenes having heteroatoms in the substituents can be used in hole injection layer and hole transport layers for electroluminescent devices. Copolymers and organic oxidants can be used. Homopolymers can be used. Metallic impurities can be removed. The heteroatom can be oxygen and can be substituted at the 3-position. Advantages include versatility, synthetic control, and good thermal stability. Different device designs can be used.Type: GrantFiled: September 26, 2005Date of Patent: December 30, 2014Assignee: Solvay USA, Inc.Inventors: Shawn P. Williams, Darin W. Laird, Troy D. Hammond
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Patent number: 8865025Abstract: Use of certain materials in hole injection or hole transport layers can improve the operational lifetimes in organic electronic devices. Compositions comprising a doped conjugated polymer, doped with a redox dopant, including iodonium salt, can increase lifetimes. Inks can be formulated and cast as films in organic electronic devices including OLEDs, PHOLEDs, and OPVs. One embodiment provides a composition with a conjugated polymer doped with a redox dopant. Non-aqueous based inks can be formulated. Iodonium salts can be used.Type: GrantFiled: April 10, 2009Date of Patent: October 21, 2014Assignee: Solvay USA, Inc.Inventors: Venkataramanan Seshadri, Christopher T. Brown, Jessica Benson-Smith, Edward S. Yang
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Patent number: 8802245Abstract: A polymer composition comprising 1 to 99 wt % of a copolymer (A) and 99 to 1 wt % of a copolymer (B); the polymer composition used as a light emitting material of a light emitting device having high performances; Copolymers (A) and (B) being copolymers showing fluorescence in the solid state and having a polystyrene-reduced number average molecular weight of 103 to 108, and containing a repeating unit (a) and a repeating unit (b); Copolymer (A) has a relation of 100>XaA>5, where XaA (%) is a percentage of the mol number of repeating unit (a) based on the sum of the mol numbers of repeating units (a), and Copolymer (B) satisfies a relation of XaB?XaA?5, where XaB (%) is a percentage of the mol number of repeating unit (a) based on the sum of the mol numbers of repeating units (a) and (b).Type: GrantFiled: May 31, 2006Date of Patent: August 12, 2014Assignee: Sumitomo Chemical Company, LimitedInventors: Katsumi Agata, Takeshi Yamada
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Patent number: 8791451Abstract: A composition comprising: at least one conjugated polymer, at least one second polymer comprising repeat units represented by: (I) optionally, —[CH2—CH(Ph-OH)]— and (II) —[CH2—CH(Ph-OR)]— wherein Ph is a phenyl ring and R comprises a fluorinated group, an alkyl group, an alkylsulfonic acid group, an alkylene oxide group, or a combination thereof is described. Other polymers can be used as second polymer including polymers comprising modified naphthol side groups. The composition can be used in hole injection and hole transport layers for organic electronic devices. Increased lifetime and better processability can be achieved. Versatility with useful OLED emitters can be achieved. Ink formulations can be adapted for ink jet printing. The conjugated polymer can be a polythiophene. Applications include OLEDs and OPVs.Type: GrantFiled: March 5, 2009Date of Patent: July 29, 2014Assignee: Solvay USA, Inc.Inventors: Venkataramanan Seshadri, Christopher T. Brown, Brian E. Woodworth, Edward S. Yang
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Patent number: 8765968Abstract: A polymer comprises a polymeric chain represented by formula (I) or (II). In formula (I), a, b, c, d, and n are integers, a from 0 to 3, b from 1 to 5, c from 1 to 3, d from 1 to 5, and n from 2 to 5000; R1 and R2 are side chains; R3 and R4 are each independently H or a side chain; and when a is 0, R3 and R4 are side chains. In formula (II), a, b, c, d, e, and n are integers, a from 1 to 3, b and c being independently 0 or 1, d and e being independently 1 or 2, and n from 2 to 5000; R1 and R2 are side chains except —COOalkyl; and X1, X2 and X3 are independently O, S, or Se. Semiconductors and devices comprising the polymer are also provided.Type: GrantFiled: April 30, 2010Date of Patent: July 1, 2014Assignee: Agency for Science, Technology and ResearchInventors: Zhikuan Chen, Jun Li, Beng Ong, Samarendra P. Singh, Hoi Kai Ivy Wong, Kok Haw Ong
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Patent number: 8530889Abstract: A carbon nanotube composite in which a conjugated polymer containing repeating units containing a fused heteroaryl unit having a nitrogen-containing double bond in the ring, and a thiophene unit is attached to at least a part of the surface of a carbon nanotube. The present invention reduces the hysteresis of a field-effect transistor having a semiconductor layer containing a carbon nanotube.Type: GrantFiled: May 11, 2009Date of Patent: September 10, 2013Assignee: Toray Industries, Inc.Inventors: Yukari Jo, Seiichiro Murase, Daisuke Kitazawa, Jun Tsukamoto
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Patent number: 8487298Abstract: An organic semiconductor transistor has plural electrodes and an organic semiconductor layer including at least one compound represented by the following Formula (I). In Formula (I), each R is independently a hydrogen atom or an alkyl group; and n and m are each independently an integer of from 1 to 3.Type: GrantFiled: September 9, 2009Date of Patent: July 16, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hidekazu Hirose, Koji Horiba, Akira Imai, Takeshi Agata, Katsuhiro Sato
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Patent number: 8431925Abstract: Organic electronic devices, compositions, and methods are disclosed that employ electrically conductive nanowires and conducting materials such as conjugated polymers such as sulfonated regioregular polythiophenes which provide high device performance such as good solar cell efficiency. Devices requiring transparent conductors that are resilient to physical stresses can be fabricated, with reduced corrosion problems.Type: GrantFiled: September 24, 2010Date of Patent: April 30, 2013Assignees: Plextronics, Inc., Cambrios Technologies Corp.Inventors: Sergey B. Li, Shawn P. Williams, Brian E. Woodworth, Pierre Marc Allemand, Rimple Bhatia, Hash Pakbaz
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Patent number: 8367458Abstract: The present invention relates to a process for producing an electronic device having two contacts, an anode and a cathode being completely or partly transmissive to light, one or more organic semi-conducting layers and one or more organic buffer layers between the contacts or the cathode and anode respectively. A solution is sprayed which contains organic material for applying at least one porous layer.Type: GrantFiled: September 26, 2008Date of Patent: February 5, 2013Assignee: Universität zu KölnInventors: Klaus Meerholz, Heike Klesper
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Patent number: 8313978Abstract: An exemplary organic semiconductor copolymer includes a polymeric repeat structure having a polythiophene structure and an electron accepting unit. The electron accepting unit has at least one electron-accepting heteroaromatic structure with at least one electron-withdrawing imine nitrogen in the heteroaromatic structure or a thiophene-arylene comprising a C2-30 heteroaromatic structure. Methods of synthesis and electronic devices incorporating the disclosed organic semiconductors, e.g., as a channel layer, are also disclosed.Type: GrantFiled: September 23, 2011Date of Patent: November 20, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Bang Lin Lee, Kook Min Han, Jung Han Shin, Sang Yoon Lee, Eun Jeong Jeong
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Patent number: 8289677Abstract: The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in a solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof; purifying the conductive polymer; and mixing the purified conductive polymer and an oxidant in an aqueous solvent containing a polyacid component.Type: GrantFiled: July 28, 2009Date of Patent: October 16, 2012Assignee: NEC Tokin CorporationInventors: Ryuta Kobayakawa, Tomoki Nobuta, Naoki Takahashi, Yasuhisa Sugawara, Satoshi Suzuki, Toshihiko Nishiyama
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Patent number: 8279582Abstract: The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension can be is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in an aqueous solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof, or a polyacid having a weight average molecular weight of less than 2,000 or a salt thereof.Type: GrantFiled: July 28, 2009Date of Patent: October 2, 2012Assignee: NEC Tokin CorporationInventors: Tomoki Nobuta, Ryuta Kobayakawa, Naoki Takahashi, Yasuhisa Sugawara, Satoshi Suzuki, Toshihiko Nishiyama
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Patent number: 8273460Abstract: Disclosed are a composition comprising an organic insulating polymer in which a photo-reactive functional group showing an increased crosslinking degree is introduced into a side-chain, an organic insulating film comprising the composition, an organic thin film transistor (OTFT) comprising the organic insulating film, an electronic device comprising the organic thin film transistor and methods of fabricating the organic insulating film, the organic thin film transistor and the electronic device. The OTFT comprising the organic insulating film of example embodiments may not show any hysteresis during the driving of the OTFT, and therefore, may exhibit a homogeneous property.Type: GrantFiled: April 6, 2007Date of Patent: September 25, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Eun Kyung Lee, Joo Young Kim, Sang Yoon Lee, Jung Seok Hahn
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Patent number: 8120018Abstract: A semiconductor device is disclosed. The device includes: oppositely disposed plural electrodes; a semiconductor molecule disposed such that one end part thereof binds to a surface of the electrode in each of the opposing electrodes; and a conductor for electrically connecting at least a part of the other end part of the semiconductor molecule disposed in one electrode of the opposing electrodes to at least a part of the other end part of the semiconductor molecule disposed in the other electrode of the opposing electrodes. The conductivity between the opposing electrodes is substantially determined by the conductivity of the semiconductor molecule electrically connected to the conductor between the opposing electrodes in the semiconductor molecules.Type: GrantFiled: January 31, 2008Date of Patent: February 21, 2012Assignee: Sony CorporationInventor: Daisuke Hobara
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Patent number: 8115200Abstract: There is provided an electroactive material having Formula I wherein: Q is the same or different at each occurrence and can be O, S, Se, Te, NR, SO, SO2, or SiR3; R is the same or different at each occurrence and can be hydrogen, alkyl, aryl, alkenyl, or alkynyl; and R1 through R6 are the same or different and can be hydrogen, alkyl, aryl, halogen, hydroxyl, aryloxy, alkoxy, alkenyl, alkynyl, amino, alkylthio, phosphino, silyl, —COR, —COOK, —PO3R2, —OPO3R2, or CN.Type: GrantFiled: December 9, 2008Date of Patent: February 14, 2012Assignee: E.I. du Pont de Nemours and CompanyInventors: Hong Meng, Fanping Sun
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Patent number: 8106387Abstract: Organic thin film transistors with improved mobility are disclosed. The transistor contains two interfacial layers between the dielectric layer and the semiconducting layer. One interfacial layer is formed from a siloxane polymer or silsesquioxane polymer. The other interfacial layer is formed from an alkyl-containing silane of Formula (I): where R? is alkyl having from about 1 to about 24 carbon atoms; R? is alkyl having from about 1 to about 24 carbon atoms, halogen, alkoxy, hydroxyl, or amino; L is halogen, oxygen, alkoxy, hydroxyl, or amino; k is 1 or 2; and m is 1 or 2.Type: GrantFiled: October 14, 2008Date of Patent: January 31, 2012Assignee: Xerox CorporationInventors: Yiliang Wu, Ping Liu, Yuning Li, Paul F. Smith
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Patent number: 8097694Abstract: Disclosed are organic semiconductor thin films using aromatic enediyne derivatives, manufacturing methods thereof, and methods of fabricating electronic devices incorporating such organic semiconductor thin films. Aromatic enediyne derivatives according to example embodiments provide improved chemical and/or electrical stability which may improve the reliability of the resulting semiconductor devices. Aromatic enediyne derivatives according to example embodiments may also be suitable for deposition on various substrates via solution-based processes, for example, spin coating, at temperatures at or near room temperature to form a coating film that is then heated to form an organic semiconductor thin film. The availability of this reduced temperature processing allows the use of the aromatic enediynes derivatives on large substrate surfaces and/or on substrates not suitable for higher temperature processing.Type: GrantFiled: March 6, 2009Date of Patent: January 17, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Eun Jeong Jeong, Hyun Sik Moon, Kook Min Han
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Publication number: 20110278559Abstract: Compositions comprising at least one hole transport material, such as a conjugated polymer, and at least one dopant, providing improved thermal stability. Compositions can be applied to substrates and used in HIL and HTL layers and organic electronic devices such as light emitting devices such as OLEDs or OPVs. The conjugated polymer can be a polythiophene, including a 3,4-substituted polythiophene or a regioregular polythiophene. The dopant can be a silver salt such as silver tetrakis(pentafluorophenyl)borate. Improved methods of making dopant are provided.Type: ApplicationFiled: May 10, 2011Publication date: November 17, 2011Inventors: Christopher T. Brown, Mark A. Bower, Venkataramanan SESHADRI
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Patent number: 8053764Abstract: An exemplary organic semiconductor copolymer includes a polymeric repeat structure having a polythiophene structure and an electron accepting unit. The electron accepting unit has at least one electron-accepting heteroaromatic structure with at least one electron-withdrawing imine nitrogen in the heteroaromatic structure or a thiophene-arylene comprising a C2-30 heteroaromatic structure. Methods of synthesis and electronic devices incorporating the disclosed organic semiconductors, e.g., as a channel layer, are also disclosed.Type: GrantFiled: March 24, 2008Date of Patent: November 8, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Bang Lin Lee, Kook Min Han, Jung Han Shin, Sang Yoon Lee, Eun Jeong Jeong
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Patent number: 8049209Abstract: A thin film transistor having a semiconducting layer with improved flexibility and/or mobility is disclosed. The semiconducting layer comprises a semiconducting polymer and insulating polymer. Methods for forming and using such thin-film transistors are also disclosed.Type: GrantFiled: April 11, 2008Date of Patent: November 1, 2011Assignee: Xerox CorporationInventors: Yiliang Wu, Hualong Pan, Ping Liu, Yuning Li, Paul F. Smith
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Patent number: 8026369Abstract: Disclosed herein is a composition containing hetero arylene or arylene showing a p-type semiconductor property in addition to thiophene showing a p-type semiconductor property and thiazole rings showing a n-type semiconductor property at a polymer main chain, an organic semiconductor polymer containing the composition, an organic active layer containing the organic semiconductor polymer, an organic thin film transistor (OTFT) containing the organic active layer, an electronic device containing the OTFT, and a method of preparing the same. The composition of example embodiments, which is used in an organic semiconductor polymer and contains thiazole rings, may exhibit increased solubility to an organic solvent, coplanarity, processibility and an improved thin film property.Type: GrantFiled: January 9, 2008Date of Patent: September 27, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Bang Lin Lee, Eun Kyung Lee, Joo Young Kim, Kook Min Han
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Patent number: 8017939Abstract: The present disclosure relates to an organic memory device and a fabrication method thereof. The organic memory device comprises a first electrode, a second electrode, and an organic memory layer situated between the electrodes, wherein a metallic nanoparticle layer is further situated between the first electrode and the organic memory layer. Since the organic memory device may be operated using only positive voltages, a 1D1R device composed of one diode and one resistor can be realized and a passive matrix can be realized due to the 1D1R structure. Accordingly, the organic memory device enables higher integration, ultrahigh speeds, larger capacities, lower power consumption, and/or lower prices.Type: GrantFiled: April 24, 2007Date of Patent: September 13, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Won Jae Joo, Seong Jae Choi, Jae Young Choi, Sang Kyun Lee, Kwang Hee Lee
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Patent number: 8004177Abstract: Provided are a conducting polymer composition and an electronic device including a layer formed using the conducting polymer composition. The conducting polymer composition contains: at least one compound selected from the group consisting of a siloxane compound of formula (1) below, a siloxane compound of formula (2) below, and a silane compound of formula (3) below; and a conducting polymer: where R1, R2, X1, X2, X3, X4, X5, X6, X7, X8, X9, X10, X11, X12, X13, X14, X15, X16, X17, X18, X19, X20, D, p, m, q, and r are the same as described in the detailed description of the invention. The electronic device including a layer formed using the conducting polymer composition has excellent electroluminescent characteristics and long lifetime.Type: GrantFiled: September 8, 2006Date of Patent: August 23, 2011Assignee: Samsung Mobile Display Co., Ltd.Inventors: Tae-Woo Lee, Jong-Jin Park, Yi-Yeol Lyu, Lyong-Sun Pu, Sang-Yeol Kim, Mu-Gyeom Kim, Eun-Sil Han
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Patent number: 7994497Abstract: An electronic device comprising a polymer of Formula or Structure (I) wherein R1 is hydrogen, halogen, a suitable hydrocarbon, or a heteroatom containing group; R2 is hydrogen, a suitable hydrocarbon, a heteroatom containing group, or a halogen; R3 and R4 are independently a suitable hydrocarbon, hydrogen, a heteroatom containing group, or a halogen; Ar is an aromatic component; x, y, a, b, and c represent the number of groups or rings, respectively; Z represents sulfur, oxygen, selenium, or NR wherein R is hydrogen, alkyl, or aryl; and n represents the number of repeating units.Type: GrantFiled: October 17, 2008Date of Patent: August 9, 2011Assignee: Xerox CorporationInventors: Yuning Li, Ping Liu, Yiliang Wu, Beng S. Ong
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Patent number: 7968871Abstract: Organic thin film transistors with improved mobility are disclosed. The semiconducting layer comprises a semiconductor material of Formula (I): wherein R1 and R2 are independently selected from alkyl, substituted alkyl, aryl, and substituted aryl; and R3 and R4 are independently selected from hydrogen, alkyl, substituted alkyl, aryl, and substituted aryl. A silanized interfacial layer is also present which has alkyl sidechains extending from its surface towards the semiconducting layer.Type: GrantFiled: April 11, 2008Date of Patent: June 28, 2011Assignee: Xerox CorporationInventors: Yiliang Wu, Hualong Pan, Ping Liu, Yuning Li
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Publication number: 20110108818Abstract: The present invention relates to organic electroluminescent devices which comprise ketone or phosphine oxide derivatives as matrix material and at least two phosphorescent compounds.Type: ApplicationFiled: November 18, 2009Publication date: May 12, 2011Applicant: Merck Patent GmbHInventors: Joachim Kaiser, Arne Buesing, Anja Gerhard, Philipp Stoessel, Susanne Heun
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Publication number: 20110094587Abstract: Provided is a method for controlling a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer, including: providing a polymer composition containing a block copolymer having a ?-conjugated poly(3-hexylthiophene) polymer and a non-conjugated polymer introduced thereto, and a solvent; and coating the polymer composition onto a substrate. According to the method disclosed herein, it is possible to control a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer merely by a relatively simple process including coating the poly(3-hexylthiophene)-based block copolymer onto a substrate with a selected solvent. In this manner, it is possible to control the alignment of conductive domains in the block copolymer so that it is suitable for various organic electronic devices.Type: ApplicationFiled: February 17, 2010Publication date: April 28, 2011Applicant: Korea Institute of Science & TechnologyInventors: Kyung Youl BAEK, Hoichang Yang, Seung Sang Hwang, Yeon Hee Choi, Yun-Jae Lee, Dong Yeop Oh, Han Sup Lee
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Publication number: 20110095275Abstract: Organic electronic devices, compositions, and methods are disclosed that employ electrically conductive nanowires and conducting materials such as conjugated polymers such as sulfonated regioregular polythiophenes which provide high device performance such as good solar cell efficiency. Devices requiring transparent conductors that are resilient to physical stresses can be fabricated, with reduced corrosion problems.Type: ApplicationFiled: September 24, 2010Publication date: April 28, 2011Inventors: Sergey B. Li, Shawn P. Williams, Brian E. Woodworth, Pierre-Marc Allemand, Rimple Bhatia, Hash Pakbaz
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Patent number: 7928181Abstract: A semiconducting polymer of Formula (I): wherein X is independently selected from S, Se, O, and NR, wherein R is independently selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, heteroaryl, and —CN; Ar is independently a conjugated divalent moiety; a is an integer from 1 to about 10; and n is an integer from 2 to about 5,000. The resulting semiconducting polymer is suitable for use in organic thin film transistors.Type: GrantFiled: August 18, 2008Date of Patent: April 19, 2011Assignee: Xerox CorporationInventor: Yuning Li
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Patent number: 7928433Abstract: An electronic device comprises a semiconducting polymer of Formula (I): wherein X is independently selected from S, Se, O, and NR, wherein R is independently selected from hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, heteroaryl, and —CN; Ar is independently a conjugated divalent moiety; a is an integer from 1 to about 10; and n is an integer from 2 to about 5,000. The electronic device may be an organic thin film transistor.Type: GrantFiled: August 18, 2008Date of Patent: April 19, 2011Assignee: Xerox CorporationInventor: Yuning Li
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Patent number: 7888169Abstract: A low-cost and efficient process producing improved organic electronic devices such as transistors that may be used in a variety of applications is described. The applications may include radio frequency identification (RFID) devices, displays and the like. In one embodiment, the improved process is implemented by flash annealing a substrate with an energy having wavelengths ranging from about 250 nm to about 1100 nm or higher. In this flash annealing process energy having wavelengths from about 250 nm to about 350 nm or higher is substantially prevented from irradiating the substrate.Type: GrantFiled: December 26, 2007Date of Patent: February 15, 2011Assignee: Organicid, Inc.Inventors: Siddharth Mohapatra, Robert P. Wenz
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Patent number: 7871714Abstract: A novel electroluminescent polymer is represented by the following formula. A film of the polymer represented by the following formula can be formed by electrolytic polymerization, and farther emits light in a different color by an electric field when a substituent thereof is changed. Therefore, a light-emitting device that is capable of multicolor displaying can be easily obtained.Type: GrantFiled: December 19, 2008Date of Patent: January 18, 2011Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Takako Takasu, Satoshi Seo, Ryoji Nomura
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Patent number: 7868322Abstract: Disclosed is a method for fabricating an organic thin film transistor by oxidation and selective reduction of an organic semiconductor material. According to the method, stability of interfaces between a semiconductor layer and source/drain electrodes of an organic thin film transistor may be guaranteed. Therefore, an organic thin film transistor fabricated by the method may exhibit improved performance characteristics, e.g., minimized or decreased contact resistance and increased charge carrier mobility.Type: GrantFiled: June 25, 2007Date of Patent: January 11, 2011Assignee: Samsung Electronics Co., Ltd.Inventors: Do Hwan Kim, Jung Seok Hahn, Sang Yoon Lee, Bon Won Koo
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Patent number: 7829373Abstract: Disclosed herein is an organic polymer semiconductor compound, a method of forming an organic polymer semiconductor thin film using the same, and an organic thin film transistor using the same. Example embodiments of this invention pertain to an organic polymer semiconductor having a side chain including a removable substituent, and to an organic thin film transistor using the organic polymer semiconductor for an organic active layer, which has lower leakage current, higher charge mobility, and/or a higher on/off ratio.Type: GrantFiled: November 10, 2005Date of Patent: November 9, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Eun Kyung Lee, Joo Young Kim, Bang Lin Lee, Sang-Yoon Lee, Eun Jeong Jeong
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Patent number: 7816673Abstract: A heteroacene compound includes a di-thieno-benzo-thieno-thiophene derivative, in which all six rings may be fused together, an organic thin film including the same, and an electronic device that includes the thin film as a carrier transport layer. The compound of example embodiments may have a compact planar structure to thus realize improved solvent solubility and processability. When the compound is applied to electronic devices, a deposition process or a room-temperature solution process may be applied, and as well, intermolecular packing and stacking may be efficiently realized, resulting in improved electrical properties, including increased charge mobility.Type: GrantFiled: August 8, 2007Date of Patent: October 19, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Jong Il Park, Eun Jeong Jeong, Sang Yoon Lee, Bang Lin Lee, Kook Min Han
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Patent number: 7800102Abstract: The organic TFT includes: a gate electrode; source and drain electrodes insulated from the gate electrode; an organic semiconductor layer insulated from the gate electrode and electrically connected to the source and drain electrodes; an insulating layer insulating the gate electrode from the source and drain electrodes and the organic semiconductor layer; and a self-assembly monolayer (SAM) included between the insulating layer and the organic semiconductor layer. A compound forming the SAM has at least one terminal group selected from the group consisting of an unsubstituted or substituted C6-C30 aryl group and an unsubstituted or substituted C2-C30 heteroaryl group. The organic TFT is formed by forming the above-described layers and forming the SAM on the insulating layer before the organic semiconductor layer and source and drain electrodes are formed.Type: GrantFiled: October 18, 2006Date of Patent: September 21, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Jin-Seong Park, Taek Ahn, Min-Chul Suh
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Patent number: 7767999Abstract: An electronic device containing a polythiophene wherein R represents a side chain, m represents the number of R substituents; A is a divalent linkage; x, y and z represent, respectively, the number of Rm substituted thienylenes, unsubstituted thienylenes, and divalent linkages A, respectively, in the monomer segment subject to z being 0 or 1, and n represents the number of repeating monomer segments in the polymer or the degree of polymerization.Type: GrantFiled: November 17, 2006Date of Patent: August 3, 2010Assignee: Xerox CorporationInventors: Beng S. Ong, Ping Liu, Lu Jiang, Yu Qi, Yiliang Wu
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Publication number: 20100176387Abstract: An organic thin-film transistor of the present invention has a gate electrode, a gate insulating film, a source electrode, a drain electrode, and an organic semiconductor layer provided above a substrate, and further has a thiol compound layer composed of a benzenethiol compound and provided on a surface of the source electrode and a thiol compound layer composed of a benzenethiol compound and provided on a surface of the drain electrode. This makes it possible to provide an organic thin-film transistor whose threshold voltage can be selectively controlled without greatly affecting a current characteristic other than the threshold voltage.Type: ApplicationFiled: January 6, 2010Publication date: July 15, 2010Applicants: SHARP KABUSHIKI KAISHA, THE UNIVERSITY OF TOKYOInventors: Yasutaka KUZUMOTO, Shigeru Aomori, Masatoshi Kitamura, Yasuhiko Arakawa
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Publication number: 20100136741Abstract: A composition comprising a plurality of molecules. Each of the molecules has a core comprising at least one aromatic ring and at least three pendant arms chemically bonded to the core. The pendant arms comprise a phenylene-terminated thiophene oligomer.Type: ApplicationFiled: February 5, 2010Publication date: June 3, 2010Applicants: Lucent Technologies Inc.Inventors: Ashok J. Maliakal, Ming L. Tang
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Patent number: 7718998Abstract: An electronic device, such as a thin film transistor, containing a semiconductor of Formula/Structure (I) wherein each R? is independently at least one of hydrogen, and a suitable hydrocarbon; Ar is an aryl, inclusive of heteroaryl substituents; and M represents at least one thiophene based conjugated segment.Type: GrantFiled: December 14, 2006Date of Patent: May 18, 2010Assignee: Xerox CorporationInventors: Ping Liu, Beng S. Ong, Yiliang Wu, Yuning Li, Hualong Pan
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Patent number: 7718999Abstract: An electronic device with a semiconductor layer of (I) wherein X is O or NR?; m represents the number of methylenes; M is a conjugated moiety; R and R? are selected from the group consisting of at least one of hydrogen, a suitable hydrocarbon, and a suitable hetero-containing group; a represents the number of 3-substituted thiophene units; b represents the number of conjugated moieties, and n represents the number of polymer repeating units.Type: GrantFiled: December 14, 2006Date of Patent: May 18, 2010Assignee: Xerox CorporationInventors: Yuning Li, Beng S. Ong
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Patent number: 7714320Abstract: A composition comprising a plurality of molecules. Each of the molecules has a core comprising at least one aromatic ring and at least three pendant arms chemically bonded to the core. The pendant arms comprise a phenylene-terminated thiophene oligomer.Type: GrantFiled: October 25, 2005Date of Patent: May 11, 2010Assignee: Alcatel-Lucent USA Inc.Inventors: Ashok J. Maliakal, Ming L. Tang
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Publication number: 20100065834Abstract: An integrated organic photovoltaic and electroluminescent device includes an organic light emitting diode and an organic photovoltaic. The OLED and the OPV share a common substrate building layer.Type: ApplicationFiled: September 15, 2009Publication date: March 18, 2010Inventor: Troy D. Hammond
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Publication number: 20100051927Abstract: An organic field effect transistor (OFET) having a structure of a conductor layer/an insulator layer/a semiconductor layer is provided. This OFET comprises an insulator layer formed by mixing a polymer compound produced by polymerizing or copolymerizing a monomer represented by the formula (1): CH2?CHCOO—(CH2)2—CN ??(1) and/or a monomer represented by the formula (2): CH2?C(CH3)COO—(CH2)2—CN ??(2) with a polymerizable and/or crosslinkable organic compound other than the monomer represented by the formula (1) or (2); and a semiconductor layer comprising an organic compound.Type: ApplicationFiled: August 31, 2009Publication date: March 4, 2010Inventors: Masateru TANIGUCHI, Tomoji Kawai, Hideyuki Kawaguchi, Ikuo Fukui
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Publication number: 20100035377Abstract: A method for partially coating a structure having one or more small protruding features is provided. The method includes: (a) providing a structure comprising a base and a protruding feature attached to the base of the structure, the feature having a diameter or width of about 1 mm or less; (b) contacting the protruding feature with a substantially uniform layer of viscous coating material, the layer having a pre-determined thickness, to transfer at least some of the coating material from the layer of coating material to the protruding feature, without contacting the base of the structure with the layer of viscous coating material; and (c) separating the structure from the layer of coating material to form a substantially uniformly coated protruding feature, wherein the coating occupies a desired pre-determined area on the feature.Type: ApplicationFiled: October 14, 2009Publication date: February 11, 2010Applicant: CBRITE INC.Inventors: Brian Gobrogge, Yelena Lipovetskaya, Fatt Foong
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Patent number: 7655512Abstract: Disclosed are methods for forming electrodes for organic electronic devices which allow for the use of an improved range of conductive materials for forming source/drain electrodes. The disclosed methods also allow for the use of different conductive materials for forming data lines and source/drain electrodes during the fabrication of organic electronic devices. Organic electronic devices manufactured according to the methods may provide advantages over conventional methods including, for example, improved patterning and increased accuracy in the formation of electrodes for organic electronic devices. Organic electronic devices fabricated according to the disclosed method are expected to be useful in display devices and electronic displays.Type: GrantFiled: January 5, 2007Date of Patent: February 2, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Bon Won Koo, Sang Yoon Lee
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Publication number: 20100019228Abstract: A resistivity stable aqueous dispersion and a method for making an aqueous dispersion. The dispersion including polythienothiophene and at least one colloid-forming polymeric acid having a pH of from about 3 to about 10. The method includes preparing an aqueous dispersion containing polythienothiophene and adjusting the pH of the dispersion to a sufficiently high pH to provide resistivity stability. Devices utilizing layers formed of pH adjusted polythienothiophene are also disclosed.Type: ApplicationFiled: June 8, 2007Publication date: January 28, 2010Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Xuezhong Jiang, Andrew Francis Nordquist
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Patent number: 7649211Abstract: The present invention provides a light-emitting element including an electron-transporting layer and a hole-transporting layer between a first electrode and a second electrode; and a first layer and a second layer between the electron-transporting layer and the hole-transporting layer, wherein the first layer includes a first organic compound and an organic compound having a hole-transporting property, the second layer includes a second organic compound and an organic compound having an electron-transporting property, the first layer is formed in contact with the first electrode side of the second layer, the first organic compound and the second organic compound are the same compound, and a voltage is applied to the first electrode and the second electrode, so that both of the first organic compound and the second organic compound emit light.Type: GrantFiled: May 25, 2007Date of Patent: January 19, 2010Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Nobuharu Ohsawa
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Publication number: 20090315017Abstract: An electronic device includes a substrate supporting mobile charge carriers, insulative features formed on the substrate surface to define first and second substrate areas on either side of the insulative features, the first and second substrate areas being connected by an elongate channel defined by the insulative features, the channel providing a charge carrier flow path in the substrate from the first area to the second area, the conductivity between the first and second substrate areas being dependent upon the potential difference between the areas. The mobile charge carriers can be within at least two modes in each of the three dimensions within the substrate. The substrate can be an organic material. The mobile charge carriers can have a mobility within the range 0.01 cm2/Vs to 100 cm2/Vs, and the electronic device may be an RF device. Methods for forming such devices are also described.Type: ApplicationFiled: May 9, 2006Publication date: December 24, 2009Applicant: NANO EPRINT LIMITEDInventor: Aimin Song