Transition Metal Complexes (e.g., Ru(ii) Polypyridine Complexes) (epo) Patents (Class 257/E51.044)
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Patent number: 7781074Abstract: An organic electroluminescent element comprising a pair of electrodes and at least one organic compound layer including a luminescent layer between the pair of electrodes, wherein at least one of the at least one organic compound layer comprises a compound represented by the following formula (I): wherein in formula (I), Q1 represents an atomic group necessary for forming an unsaturated ring together with the carbon atom; Q2 and Q3 each independently represent an atomic group necessary for forming an unsaturated ring together with the nitrogen atom; X represents a partial structure comprising an atom that is linked to the platinum atom; A1 represents a linking group; B1, B2 and B3 each independently represent a linking group or a single bond; m and n each independently represent 0 or 1; and at least one of m and n is not 1.Type: GrantFiled: March 10, 2006Date of Patent: August 24, 2010Assignee: Fujifilm CorporationInventors: Satoshi Sano, Tatsuya Igarashi
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Patent number: 7781075Abstract: An organic light-emitting device is provided, which comprises an anode, a cathode and a light-emitting layer between them. An organic light-emitting material having the structure of Formulas I or II is doped in the light-emitting layer. In the Formulas I and II, R1˜R9 are H, F, CF3, NO2, an alkyl group of 1 to 6 carbon atoms, an aryl group or any combinations thereof; and M is a transition metal atom.Type: GrantFiled: April 24, 2006Date of Patent: August 24, 2010Assignee: Au Optronics CorporationInventor: Chun-Hui Yang
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Patent number: 7781072Abstract: An organic electroluminescence device of a long emission life is obtained by stacking an anode, a hole transport layer comprising an organic compound, a light emitting layer comprising an organic compound, an electron transport layer comprising an organic compound, and a cathode, in which the light emitting layer comprises an organic host material of an aluminum chelating complex of a specific structure and a phosphorescent organic guest material.Type: GrantFiled: March 27, 2003Date of Patent: August 24, 2010Assignees: Pioneer Corporation, Nippon Steel Chemical Co., Ltd.Inventors: Taishi Tsuji, Hiroshi Miyazaki
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Patent number: 7781023Abstract: A method of producing an electroluminescent display is provided. A medium is obtained from a stream of commerce. The medium is activated to form a pattern such that the medium emits light by electroluminescence according to the pattern in response to electrical energization.Type: GrantFiled: October 11, 2005Date of Patent: August 24, 2010Assignee: Hewlett-Packard Development Company, L.P.Inventors: Luis Aldarondo, Terry M. Lambright, Philip S. Burkum, Darrel E. Pozzesi
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Patent number: 7781077Abstract: A phosphorescent OLED uses a phosphorescent dopant in the emissive layer, the dopant includes a metal complex containing a plurality of moieties linking to a transition metal ion. One or more of the moieties contain a ligand with a C—SP3 carbon center. The transition metal ion can be an iridium ion. The C—SP3 carbon is linked to a chalcogen atom in an ion form, a nitrogen-containing heterocylic ring and two functional groups, wherein each of the functional groups is selected from aryl, alkyl and heteroaryl. The tetrahedral structure of this carbon center hinders close packing and intermolecular interactions and, therefore, renders the transport of holes in the light-emitting device more efficient. With such chemical structure and property, the self-quenching characteristics of the dopant in high doping concentration can be effectively reduced.Type: GrantFiled: October 8, 2008Date of Patent: August 24, 2010Assignee: Au Optronics CorporationInventors: Chun-Hui Yang, Cheng-Hung Lin
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Patent number: 7776458Abstract: Silyl-substituted cyclometalated transition metal complexes have good thermal stability and enabling highly efficient phospholuminescence and an organic electroluminescent device may use the Silyl-substituted cyclometalated transition metal complexes. The transition metal complexes, which are suitably used for forming an organic layer of the organic electroluminescent device, can emit light in the wavelength range of 400-650 nm, and induce white electroluminescence when combined with green or red luminescent materials.Type: GrantFiled: April 6, 2006Date of Patent: August 17, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Das Rupasree Ragini, Hee-Kyung Kim, Young-Hun Byun, Lyong-Sun Pu, O-Hyun Kwon, Young-Mok Son, Jong-Jin Park
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Patent number: 7771844Abstract: It is an object of the present invention to provide a substance that can emit phosphorescence. Further, it is an object of the present invention to provide a light emitting element with favorable color purity. The present invention provides an organometallic complex having a structure represented by a general formula (1). A light emitting element that can exhibit red or reddish emission of light with favorable color purity can be obtained by using the organometallic complex of the present invention as aluminescent substance. In addition, a light emitting element that can emit light efficiently can be obtained by using the organometallic complex of the present invention as a sensitizer.Type: GrantFiled: November 16, 2005Date of Patent: August 10, 2010Assignee: Semiconductor Energy Laboratory Co., LtdInventors: Hideko Inoue, Satoko Shitagaki, Satoshi Seo
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Patent number: 7771845Abstract: An organic electroluminescent device contains: a pair of electrodes; and an organic compound layer containing a light-emitting layer, the organic compound layer being between the electrodes, wherein the organic compound layer contains a platinum complex including specific structure.Type: GrantFiled: March 14, 2006Date of Patent: August 10, 2010Assignee: Fujifilm CorporationInventors: Satoshi Sano, Tatsuya Igarashi, Toshihiro Ise, Takeshi Murakami, Seiji Ichijima
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Patent number: 7763365Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.Type: GrantFiled: February 6, 2008Date of Patent: July 27, 2010Assignee: Showa Denko K.K.Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takashi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
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Patent number: 7758971Abstract: An organic electroluminescent device comprising: a pair of electrodes comprising a positive electrode and a negative electrode; and a plurality of organic compound layers including a light emitting layer between the pair of electrodes, wherein at least one layer containing a metal complex having a tridentate or more ligand is provided between the light emitting layer and the negative electrode.Type: GrantFiled: April 25, 2006Date of Patent: July 20, 2010Assignee: FUJIFILM CorporationInventors: Tatsuya Igarashi, Takeshi Murakami, Ikuo Kinoshita
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Patent number: 7754346Abstract: The invention provides an organic electroluminescent device including an organic compound layer provided between a pair of electrodes. The organic compound layer has at least a luminescent layer. The luminescent layer has at least a metal complex containing a tri- or higher-dentate ligand and plurality of host compounds. The metal complex is preferably a metal complex capable of obtaining light emission from a triplet exciton. The ligand of the metal complex is preferably chained or cyclic. Further, an ionization potential of the metal complex is preferably larger than a minimum value out of ionization potentials of the plurality of host compounds.Type: GrantFiled: November 9, 2005Date of Patent: July 13, 2010Assignee: Fujifilm CorporationInventor: Hisashi Okada
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Patent number: 7745021Abstract: A light-emitting device comprising a pair of electrodes and one or more organic layers disposed between the electrodes, the one or more organic layers comprising a light-emitting layer. At least one of the organic layers comprises a transition metal complex containing a moiety represented by the following formula (1): wherein M11 represents a transition metal ion; and R11, R12, R13, R14, R15, R16 and R17 represent a substituent or a single bond, respectively, or a tautomer thereof.Type: GrantFiled: November 8, 2007Date of Patent: June 29, 2010Assignee: FUJIFILM CorporationInventor: Tatsuya Igarashi
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Patent number: 7745017Abstract: An organic electroluminescent device and a method for producing the same, the organic electroluminescent device including a luminescent layer produced by a vapor-deposition method disposed between a pair of electrodes, the luminescent layer containing at least one host material and at least one metal complex including a partial structure represented by formula (I): wherein M represents a metal atom, R1, R2 and R4 to R8 each independently represent a hydrogen atom or a substituent, and R3 represents a group represented by formula (II), an alkoxy group or an aryloxy group: wherein R11 to R13 each independently represent a hydrogen atom or a substituent, provided that at least two of them each independently represent an alkyl group or an aryl group.Type: GrantFiled: June 27, 2005Date of Patent: June 29, 2010Assignee: Fujifilm CorporationInventors: Tetsuo Nakamura, Tatsuya Igarashi, Takeshi Murakami, Masayuki Mishima
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Patent number: 7740957Abstract: Red phosphorescence compounds and organic electro-luminescence device using the same are disclosed. In an organic electroluminescence device including an anode, a hole injecting layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injecting layer, and a cathode serially deposited on one another, the organic electroluminescence device may use a compound as a dopant of the light emitting layer.Type: GrantFiled: May 13, 2005Date of Patent: June 22, 2010Assignee: LG Electronics Inc.Inventors: Jung Keun Kim, Chun Gun Park, Jeong Dae Seo, Hyun Cheol Jeong, Kyung Hoon Lee, Sang Tae Park
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Patent number: 7736756Abstract: An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer comprising a phosphorescent emitter represented by Formula (I): LnM??(I) wherein each L is a cyclometallated ligand with at least one containing a coumarin group, M is Ir or Pt, and n is 3 when M is Ir and 2 when M is Pt. The invention also comprised the compound of formula (I).Type: GrantFiled: March 1, 2007Date of Patent: June 15, 2010Assignee: Global OLED Technology LLCInventors: Xiaofan Ren, Shouquan Huo
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Patent number: 7736757Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.Type: GrantFiled: February 6, 2008Date of Patent: June 15, 2010Assignee: Showa Denko K.K.Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takashi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
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Patent number: 7737277Abstract: One embodiment of this invention is bis-cyclometalled electroluminescent complexes of iridium (III) according to Formula I. Another embodiment of this invention is electronic devices in which the active layer includes a bis-cyclometalled electroluminescent Ir(III) complex.Type: GrantFiled: May 8, 2006Date of Patent: June 15, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Alex Sergey Ionkin, William J. Marshall, Ying Wang, Viacheslav A. Petrov
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Patent number: 7736755Abstract: An organic electroluminescent device comprising: a pair of electrodes; and at least one organic compound layer including a light emitting layer between the pair of electrodes, wherein the organic compound layer contains a metal complex that has a tridentate or more ligand and two or more metal ions.Type: GrantFiled: April 24, 2006Date of Patent: June 15, 2010Assignee: FUJIFILM CorporationInventors: Tatsuya Igarashi, Toshihiro Ise, Takeshi Murakami
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Publication number: 20100140602Abstract: There is provided an organic electroluminescence device comprising a pair of electrodes on a substrate and at least one organic layer containing a luminescence layer between the electrodes, the luminescence layer comprising at least 3 luminescence materials different in luminescent color, and the at least 3 luminescence materials being platinum complexes.Type: ApplicationFiled: December 1, 2009Publication date: June 10, 2010Applicant: FUJIFILM CORPORATIONInventor: Wataru SOTOYAMA
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Patent number: 7732606Abstract: An organic electroluminescent device having a pair of electrodes and at least one organic layer including a light-emitting layer interposed between the pair of electrodes, in which the organic layer contains at least one platinum complex compound having a quadridentate ligand containing a partial structure represented by formula (I): wherein Z1 represents a nitrogen-containing heterocycle coordinated to the platinum through a nitrogen atom; L1 represents a single bond or a linking group; R1, R3 and R4 each independently represent a hydrogen atom or a substituent; and R2 represents a substituent.Type: GrantFiled: September 26, 2005Date of Patent: June 8, 2010Assignee: FUJIFILM CorporationInventors: Toshihiro Ise, Satoshi Sano, Tatsuya Igarashi
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Patent number: 7718276Abstract: An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer comprising a phosphorescent emitter represented by Formula (I): LnM??(I) wherein each L is a cyclometallated ligand with at least one containing a coumarin group, M is Ir or Pt, and n is 3 when M is Ir and 2 when M is Pt. The invention also comprised the compound of formula (I).Type: GrantFiled: July 18, 2006Date of Patent: May 18, 2010Assignee: Global OLED Technology LLCInventors: Xiaofan Ren, Shouquan Huo
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Patent number: 7718087Abstract: The present invention provides compositions comprising at least one novel polymeric organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions of the present invention are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 14, 2006Date of Patent: May 18, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye
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Patent number: 7718277Abstract: The present invention provides electronic devices comprising novel polymeric organic iridium compositions which provide for enhanced device performance. The polymeric organic iridium compositions employed comprise a polymeric organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The polymeric organic iridium compositions employed are referred to as Type (2) organic iridium compositions and are constituted such that at least one ligand of the polymeric organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (2) organic iridium compositions are referred to herein as comprising “polymeric organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 16, 2006Date of Patent: May 18, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye
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Patent number: 7709100Abstract: An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer further includes a molecule of Formula I (shown below) wherein an alkyl substituent at position R?5, which is an alkyl substituent, results in high efficiency and operational stability in the organic light emitting device.Type: GrantFiled: December 21, 2004Date of Patent: May 4, 2010Assignee: Universal Display CorporationInventors: Raymond Kwong, David Knowles, Bin Ma, Xiao-Chang Li, William Ceyrolles
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Patent number: 7704610Abstract: The present invention provides electronic devices comprising novel polymer compositions which provide for enhanced device performance. The polymer compositions employed comprise a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). In one aspect, the polymeric component may be an electroactive polymer. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 18, 2006Date of Patent: April 27, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye, Kevin Henry Janora, Gautam Parthasarathy
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Patent number: 7705528Abstract: A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.Type: GrantFiled: July 16, 2004Date of Patent: April 27, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Wanglin Yu, James J. O'Brien
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Patent number: 7695640Abstract: The present invention provides novel polymer compositions comprising a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the polymeric component may be an electroactive polymer. The novel polymer compositions of the invention are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel polymer compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 17, 2006Date of Patent: April 13, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, Kyle Erik Litz, James Anthony Cella, Joseph John Shiang, Qing Ye
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Patent number: 7691494Abstract: The present invention provides electronic devices comprising novel organic iridium compositions which provide for enhanced device performance. The novel iridium compositions employed comprise at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions employed are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 17, 2006Date of Patent: April 6, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, James Anthony Cella, Kyle Erik Litz, Joseph John Shiang, Qing Ye, Kevin Henry Janora, Gautam Parthasarathy
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Patent number: 7691493Abstract: A main chain-type or side chain-type polymeric compound having a structure wherein at least one metal complex segment having a plurality ligands is introduced into a main chain or a side chain is provided. In the case where the polymeric compound is the main chain-type polymeric compound, the metal complex segment has at least one ligand constituting a polymer main chain of the polymeric compound and having a carbon atom and oxygen atom bonded to a metal atom. On the other hand, in the case where the polymeric compound is the side chain-type polymeric compound, a polymer main chain thereof has a conjugated structure, preferably a conjugated double bond. A ligand for the polymeric compound includes a chain or cyclic ligand, of which a bidentate ligand having an organic cyclic structure is preferred, and the ligand has at least one carbon atom or oxygen atom and is bonded to a center metal atom, preferably iridium, via the carbon atom or oxygen atom.Type: GrantFiled: May 9, 2005Date of Patent: April 6, 2010Assignee: Canon Kabushiki KaishaInventors: Jun Kamatani, Shinjiro Okada, Akira Tsuboyama, Takao Takiguchi, Satoshi Igawa
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Patent number: 7691292Abstract: The present invention provides compositions comprising at least one novel organic iridium compound which comprises at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compositions of the present invention are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. The novel organic iridium compositions are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel organic iridium compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.Type: GrantFiled: August 16, 2006Date of Patent: April 6, 2010Assignee: General Electric CompanyInventors: Kelly Scott Chichak, Kyle Erik Litz, James Anthony Cella, Joseph John Shiang, Qing Ye
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Patent number: 7691495Abstract: Disclosed are electrophosphorescent organic metal complexes with formula (I) or (II), of either geometrical isomers, comprising two bidentate NN-type ligandsor a tetradentate NNNN-type ligand, and a transition metal. These electrophosphorescent materials are valuable to the application in organic light-emitting devices (OLEDs), including red-, orange-, or yellow-light OLEDs.Type: GrantFiled: March 5, 2007Date of Patent: April 6, 2010Assignee: The University of Hong KongInventors: Chi-Ming Che, Siu-Chung Chan
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Patent number: 7687155Abstract: A metal coordination compound having the following structure: wherein M? is Ir or Rh, m? is 2, and are identical to each other and are represented by a substituted or unsubstituted phenyl isoquinoline ligand. A luminescence device and a display apparatus using this metal coordination compound are provided.Type: GrantFiled: March 20, 2007Date of Patent: March 30, 2010Assignee: Canon Kabushiki KaishaInventors: Jun Kamatani, Shinjiro Okada, Akira Tsuboyama, Takao Takiguchi, Seishi Miura, Koji Noguchi, Takashi Moriyama, Satoshi Igawa, Manabu Furugori
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Patent number: 7678473Abstract: Provided is an organometallic complex that highly effectively emits a phosphorescent light and an organic electroluminescent device using the same. The organometallic complex can be used to form an organic layer of an organic electroluminescent device, is a highly effective phosphorescent material emitting light of 400 nm to 650 nm, and can be used with a green emission material or a red emission material to emit a white light. In addition, the organometallic complex can be used in a solution process due to its high solubility, and thus, is suitable for large-scale screens.Type: GrantFiled: February 3, 2006Date of Patent: March 16, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Jong-Hyoup Lee, Seok Chang, Das Rupasree Ragini, Hee-Kyung Kim, Lyong-Sun Pu
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Patent number: 7674531Abstract: The present invention relates to an organic light emitting device structure having an organic light emitting device (OLED) over a substrate, where the OLED has, for example, an anode, a hole transporting layer (HTL), a first electron transporting layer (ETL) that is doped with a phosphorescent material, a second electron transporting layer (ETL), and a cathode. The OLEDs of the present invention are directed, in particular, to devices that include an emissive layer comprised of an electron transporting host material having a triplet excited state energy level that is higher than the emissive triplet excited state energy level of the phosphorescent dopant material.Type: GrantFiled: October 31, 2003Date of Patent: March 9, 2010Assignees: The University of Southern California, The Trustees of Princeton UniversityInventors: Chihaya Adachi, Marc A. Baldo, Stephen R. Forrest
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Patent number: 7670692Abstract: A cyclometalated transition metal complex very efficiently emits phosphorescent light and an organic electroluminescent device using the same. The transition metal complex is suitable for an organic layer of an organic electroluminescent device, can emit light with a wavelength of 400 to 650 nm, and can emit white light when used with a red emissive material or a green emissive material.Type: GrantFiled: February 6, 2006Date of Patent: March 2, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Das Rupasree Ragini, Seok Chang, Eun-Sil Han, Hee-Kyung Kim, Lyong-Sun Pu, Jong-Hyoup Lee
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Cyclometalated transition metal complex and organic electroluminescent display device using the same
Patent number: 7670691Abstract: A cyclometalated transition metal complex emitting phosphorescence of high efficiency and an organic electroluminescent display device employing the same are provided. The cyclometalated transition metal complex is represented by Formula I: {[C ^N]mM[P(R1R2)][LR3R4]n}z ??(I). The cyclometalated transition metal complex can be employed in an organic film of an organic electroluminescent display device, can emit light at a wavelength range of 400 nm to 650 nm, and can emit white light as well when used with a green light emitting material and a red light emitting material.Type: GrantFiled: September 8, 2005Date of Patent: March 2, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Young-Hun Byun, Yi-Yeol Lyu, Yu-Jin Kim, Das Rupasree Ragini, Seok Chang, Lyong Sun Pu, In-Nam Kang -
Publication number: 20100044693Abstract: An organic EL light-emitting material and an organic EL light-emitting element using the same are provided. Between an anode and a cathode, there are provided a hole transport layer, a light-emitting layer constituted of an organic EL light-emitting material including at least one kind of metal pyrazole complex constituted of a metal ion that is a monovalent cation of a d10 group element and a pyrazole ligand that has a predetermined substituent at the whole or a part of 3, 4 and 5 sites, and an electron transport layer, in this order from the anode side.Type: ApplicationFiled: August 21, 2009Publication date: February 25, 2010Applicant: SONY CORPORATIONInventor: Masashi Enomoto
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Patent number: 7662486Abstract: An organic electroluminescent device including a substrate, an anode, a cathode, a hole transport layer, an electron transport layer and an emission layer is provided. The anode and the cathode are disposed on the substrate. The hole transport layer is disposed between the anode and the cathode. The electron transport layer is disposed between the hole transport layer and the cathode. The emission layer is disposed between the hole transport layer and the electron transport layer. The chemical structure of the dopant is represented by formula [I]: “M” represents a metal atom, m is smaller than or equal to the ligand number of “M”, n is smaller than m. “Y1” is selected from aryl or heteroaryl. “Y2” and “Y3” are respectively selected from nitrogen-containing heterocyclic ring. “X”, “R1”, “R2” and “R3” are respectively selected from any substituent group or hydrogen. “A” is selected from aryl, heteroaryl or nitrogen-containing heterocyclic group.Type: GrantFiled: October 18, 2005Date of Patent: February 16, 2010Assignee: AU Optronics Corp.Inventor: Pei-Chi Wu
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Patent number: 7662962Abstract: An organometallic complex. The organometallic complex has formula (I) , wherein M is a transition metal with an atomic number greater than 40 comprising Ir, Os, Pt, Pd, Re, or Ru, is a substituted or non-substituted heterocyclic ring containing at least one nitrogen atom, and is any bidentate ligand comprising bipyridyl groups. The invention also provides an organic light-emitting diode and a display including the organometallic complex.Type: GrantFiled: May 6, 2005Date of Patent: February 16, 2010Assignee: AU Optronics Corp.Inventor: Pei-Chi Wu
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Patent number: 7659010Abstract: The invention provides a cyclometallated complex comprising the structure of formula I wherein: M is a d-block transition metal; B is a five- or six-membered aryl or heteroaryl ring which is optionally substituted and optionally fused to one or more other aryl or heteroaryl rings; A is a five- or six-membered heteroaryl ring comprising at least three nitrogen atoms; R1 is a group other than hydrogen; n is zero or an integer equal to or greater than one; and A and B are optionally fused or linked by one or more covalent bonds. The invention also provides the use of such complexes in optoelectronic devices, and in particular in organic light emitting devices.Type: GrantFiled: May 17, 2004Date of Patent: February 9, 2010Assignee: Isis Innovation LimitedInventors: Paul Leslie Burn, Ifor David William Samuel, Shih-Chun Lo
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Patent number: 7655322Abstract: The present invention relates to efficient organic light emitting devices (OLEDs), and more specifically to organic materials used in such devices. More specifically, the present invention relates to materials with improved stability and efficiency when incorporated into an OLED.Type: GrantFiled: January 10, 2005Date of Patent: February 2, 2010Assignees: The University of Southern California, The Trustees of Princeton UniversityInventors: Stephen R. Forrest, Mark E. Thompson
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Patent number: 7655323Abstract: The present invention provides organic light emitting devices (OLEDs) and materials with improved stability and efficiency when incorporated into an OLED. The materials include organometallic compounds having carbene atom/donor coordinated to a metal center. The compounds may be macrocyclic electrophosphors. The compounds may also include a macrocyclic ligand coordinated to a metal center.Type: GrantFiled: January 10, 2005Date of Patent: February 2, 2010Assignees: The University of Southern California, Universal Display CorporationInventors: Robert Walters, Peter B. Mackenzie, Mark E. Thompson
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Patent number: 7652283Abstract: It is an object of the present invention to provide a substance which can emit red phosphorescence which is closer to the chromaticity coordinates of red according to the NTSC standard. The present invention provides an organometallic complex represented by the general formula (1), wherein each of R1 to R3 represents any one of hydrogen, a halogen group, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group, and at least one of R1 to R3 represents an electron-withdrawing group; and M represents a Group 9 element or a Group 10 element, and when M is the Group 9 element, n=2, whereas when M is the Group 10 element, n=1. Such an organometallic complex can emit red phosphorescence with good spectral luminous efficiency which is closer to the chromaticity coordinates of red according to the NTSC standard.Type: GrantFiled: August 4, 2006Date of Patent: January 26, 2010Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Hideko Inoue, Satoshi Seo
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Patent number: 7648778Abstract: An organic electroluminescent element comprises: a pair of electrodes; and at least one organic compound layer between the pair of electrodes, said at least one organic compound layer comprising a light-emitting layer, wherein the organic luminescent element comprises at least one complex represented by formula (1): wherein M11 represents a hexacoordinate transition metal ion, Y11 represents a nitrogen atom or a substituted or unsubstituted carbon atom, L11 represents a ligand, Q11 and Q12 each represents an atomic group for forming a nitrogen-containing heterocyclic ring, n11 represents an integer of 1 to 3, n12 represents an integer of 0 to 4, X11 represents a counter ion, and n13 represents an integer of 0 to 3.Type: GrantFiled: August 15, 2006Date of Patent: January 19, 2010Assignee: FUJIFILM CorporationInventors: Tatsuya Igarashi, Takeshi Murakami
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Patent number: 7646011Abstract: An organic light emitting display device is disclosed. The device includes a substrate; a first electrode formed on the substrate; an organic layer including at least an emission layer and formed on the first electrode; and a second electrode formed on the organic layer. The emission layer includes a host and a dopant material. The dopant is one of materials having the structure of Formula 1, where R may be one selected from the group consisting of ethylene, an ethylene derivative, stilbene, a stilbene derivative. Also, R1 to R6 may be different from or equal to each other, and each is selected from the group consisting of a hydrogen atom, a halogen atom, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C5 to C20 aryl group, a C3 to C30 heterocyclic group, and an aliphatic C3 to C30 hydrocarbon group.Type: GrantFiled: July 14, 2006Date of Patent: January 12, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Jun-Yeob Lee, Min-Seung Chun, Yong-Joong Choi
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Patent number: 7641987Abstract: An organic electroluminescent device comprising: a pair of electrodes; and at least one organic compound layer between the pair of electrodes, the at least one organic compound layer including a light emitting layer, wherein the light emitting layer contains at least one host material and at least one luminescent material, and the host material is a compound represented by the formula (I) as defined herein.Type: GrantFiled: April 5, 2007Date of Patent: January 5, 2010Assignee: FujiFilm CorporationInventors: Tatsuya Igarashi, Toshihiro Ise
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Patent number: 7642546Abstract: According to some embodiments, an article of manufacture comprises a substrate; a molecular layer on the substrate comprising at least one charge storage molecule coupled to the substrate by a molecular linker; a solid barrier dielectric layer directly on the molecular layer; and a conductive layer directly on the solid barrier dielectric layer. In some embodiments, the solid barrier dielectric layer is configured to provide a voltage drop across the molecular layer that is greater than a voltage drop across the solid barrier dielectric layer when a voltage is applied to the conductive layer. In some embodiments, the molecular layer has a thickness greater than that of the solid barrier dielectric layer. The article of manufacture contains no electrolyte between the molecular layer and the conductive layer.Type: GrantFiled: November 30, 2006Date of Patent: January 5, 2010Assignees: Zettacore, Inc., North Carolina State UniversityInventors: Veena Misra, Ritu Shrivastava, Zhong Chen, Guru Mathur
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Patent number: 7642548Abstract: Novel ruthenium, rhodium, palladium, osmium, iridium or platinum complexes of thianthrene ligands are electroluminescent compounds. According to the invention there is provided complexes of Formula (I).Type: GrantFiled: August 5, 2005Date of Patent: January 5, 2010Assignee: Merck Patent GmbHInventors: Poopathy Kathirgamanathan, Subramaniam Ganeshamurugan
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Patent number: 7635527Abstract: A polymer light emitting material, wherein the material has a light emitting mechanism based on transition from an excited triplet state to a ground state or transition through an excited triplet state to a ground state of an electron energy level, and the material comprises a nonionic light emitting part which constitutes a part of the polymer or is bound to the polymer. The polymer light emitting material exhibits high light emission efficiency above 5%, which is the limit of external quantum efficiency of fluorescence and can be designed so as to have a large area and hence are suitable for mass production of organic light emitting devices.Type: GrantFiled: February 6, 2008Date of Patent: December 22, 2009Assignee: Showa Denko K.K.Inventors: Masataka Takeuchi, Shuichi Naijo, Naoko Ito, Koro Shirane, Takeshi Igarashi, Yoshiaki Takahashi, Motoaki Kamachi
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Patent number: 7632579Abstract: A light emitting element comprising at least a light emitting layer containing a light emitting material and a host material and having a light emission maximum wavelength of 500 nm or less wherein the minimum excitation triplet energy level of the host material is higher than the minimum excitation triplet energy level of the light emitting material.Type: GrantFiled: July 26, 2005Date of Patent: December 15, 2009Assignee: FUJIFILM CorporationInventors: Toshihiro Ise, Tatsuya Igarashi, Yousuke Miyashita, Hidetoshi Fujimura, Masayuki Mishima, Hisashi Okada, Qiu Xuepeng