Abstract: A method of making a composite article of a graphite-filled polymer mixture that is robust during high shear mixing and compounding, and that exhibits relatively low electrical resistivity after molding. The mixture is formed by shear mixing a liquid polymeric material, graphitized carbon fibers having diameters of less than one micrometer, and glass fibers longer than the carbon fibers. The carbon and glass fibers constitute up to about 25 volume percent and up to about 50 weight percent, respectively, of the mixture, though the addition of as little as about 1 weight percent of the glass fibers has been shown to dramatically reduce resistivity. The mixture is then introduced into a mold so that the glass fibers are substantially oriented parallel to the direction of flow.

Abstract: A treatment method for the internal surface of a molded polyethylene plastics material container such as a drum, including the steps of: introducing an ionizable gas, such as argon, into the container; generating a plasma of the introduced gas by applying electric field of sufficient strength to the container and introduced gas, so as to cause an interaction with the internal surface of the container; coating the internal surface of the container with a curable epoxy-based first polymeric composition; and then curing the polymeric composition to form a coating on the internal surfaces of the container. A second coating, preferably with electrical conductive properties, may be applied and cured over the first coating. Conductive properties may be provided by including conductive particles such as antimony doped tin dioxide, graphite or metal powders, in the second composition.

Abstract: A carbonaceous material having a total pore volume of from 0.5 to 1.5 cm3/g per unit mass, a volume of micropores having diameters of from 10 to 20 ? of from 10 to 45% based on the total pore volume, a volume of mesopores having diameters of from 20 to 200 ? of from 35 to 65% based on the total pore volume, a volume of macropores having diameters exceeding 200 ? of not more than 15% based on the total pore volume, and a specific surface area of from 1,000 to 2,500 m2/g. The carbonaceous material is incorporated into an electric double layer capacitor to provide increased capacitance.

Abstract: A resin bonded graphite material which is especially suitable for use as an electric contact, and a method for the production of this resin bonded graphite material. According to the invention, the resin-bonded graphite material if formed from a mixture of carbon black containing electro-graphite with a unburned graphite content of RG wherein RG≧30 percent by weight, electro-graphite free of carbon black as well as binding agents. The material has a specific electrical resistance Wspec wherein Wspec≧3500 &mgr;&OHgr;m, and use of the resin bonded graphite material as an electrical contact makes possible substantial exclusion of radio interference.

Abstract: The invention provides a melt-processable conductive fluorothermoplastic composition comprising three components. The first component is at least one melt-processable, thermoplastic fluoropolymer component having its interpolymerized units derived from (i) at least 50 wt % of TFE, and (ii) one or more ethylenically-unsaturated monomers represented by the formulas (a) CF2═CF—Rf, (b) CF2═CF—O—Rf′, and (c) CH2═CR2, wherein Rf is a perfluoroalkyl of 1 to 8 carbon atoms, Rf′ is Rf or a perfluoroalkoxy of 1 to 8 carbon atoms, and R is selected from H, F, Cl, or an aliphatic group having from 1 to 8 carbon atoms which may have F or Cl substituents. The thermoplastic fluoropolymer component is substantially free of interpolymerized units derived from VDF. The second component is from about 0.1 to about 10 weight percent of a hydrocarbon polymer, and the third component is from about 1 to about 20 weight percent of conductive filler.

Abstract: A method fabricates fluid flow field plates that are suitable for use in an electrochemical fuel cell assembly. Pursuant to the method, a fluid flow field channel region such as, for example, substantially straight, parallel fluid flow field channels, is roller embossed in a sheet of compressible, electrically conductive material such as, for example, expanded graphite sheet material. A fluid distribution region such as, for example, a region containing manifold openings and supply channels, is then reciprocally embossed in the sheet material. A sheet pre-impregnated with a curable polymeric composition, such as pre-impregnated expanded graphite, can be employed, with the curing step being performed after the roller embossing and reciprocal embossing steps.

Abstract: The present invention provides a novel method whereby a thermally conductive belt is manufactured through net shape molding. Specifically the method of the present invention is for manufacturing a power transfer belt that is of a highly thermally conductive polymer composition, in contrast to the typical rubber material used to fabricate the belts of the prior art. The new and unique belt of the present invention is manufactured of a thermally conductive polymer material that is easily injection moldable into any desired shape and configuration. Further, the polymer composition is very thermally conductive, which assists in dissipating heat that is generated by the friction created during normal operation of the device. The new belt material and its construction allow heat to be conducted directly through the surface of the belt thus preventing heat buildup within the belt itself, thereby preserving and extending its life.

Abstract: The present invention provides a separator for a fuel cell in which an electrically anisotropic conductive filler can be made uniformly oriented without using a special mold or special molding apparatus, and which has excellent conductivity.

Abstract: An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure includes pretreating a dry fiber reinforcement with a composition including a carrier and a conductive element, laying out the pretreated reinforcement to form a pre-form structure, applying a resin to the pre-form structure, and curing the resin at room temperature. Another exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure includes laying out a plurality of dry fiber reinforcements, placing at least one ply between any two of the plurality of dry fiber reinforcements, the ply having a non-woven including a conductive material, applying a resin to the plurality of dry fiber reinforcements and the at least one ply, and curing the resin.

Abstract: Precisely configured, especially of geometric shape, flakes of liquid crystal material are made using a mechanically flexible polymer mold with wells having shapes which are precisely configured by making the mold with a photolithographically manufactured or laser printed master. The polymer liquid crystal is poured into the wells in the flexible mold. When the liquid crystal material has solidified, the flexible mold is bent and the flakes are released and collected for use in making an electrooptical cell utilizing the liquid crystal flakes as the active element therein.

Abstract: A method of making a polarizable electrode for an electric double layer capacitor, includes adding a binder assistant to a binder so that the binder is swollen and mixing a carbonaceous powder, a conductive assistant and thereafter the swollen binder, thereby obtaining a material mixture, kneading the material mixture into a primary forming material, forming the primary forming material into a secondary forming material, and rolling the secondary forming material into a sheet shape.

Abstract: A sheet electrode with a predetermined thickness for an electric double layer capacitor is made by carrying out a roller rolling step in which a long sheet intermediate is made from a material containing a carbonaceous powder, a conductive assistant and a binder and thereafter. The sheet intermediate is passed between a pair of rolling rollers to be wound up by a winding section while being drawn out of a drawing section. The roller rolling step includes drawing the sheet intermediate out of the drawing section under a predetermined tension applied to the sheet intermediate, and controlling a widthwise position of the sheet intermediate immediately before the rolling rollers by an edge position controller, and winding the sheet intermediate rolled by the rollers onto a winding section while the winding section is applying a predetermined pressure to a rolling side drive roller located adjacent to the winding section and rotated at a predetermined speed.

Abstract: A highly conductive thermoplastic elastomer gap filler having superior durability and EMI shielding properties. According to the preferred embodiment, the TPE comprises graphite fiber having a nickel-copper-nickel coating formed thereabout that is suspended within an elastomer, which preferably comprises polyvinylchloride. The TPE of the present invention is particularly well-suited for reducing radio frequency electromagnetic radiation reflected by gaps formed between adjacent panels of a structure, and is particularly well-suited for the maintenance and repair of low observable aircraft. The TPE of the present invention may further be modified to include carbon black filler.

Abstract: A conductive thermoplastic composition is prepared by a method in which poly (arylene ether) and, optionally, a portion of polyamide are added to a first feed port, polyamide is added to a second feed port, and a concentrate of conductive carbon black in polyamide is added to the second feed port or a third feed port. Whereas preparation of conductive poly(arylene ether)/polyamide compositions has typically required an extruder having at a screw length to diameter ratio of at least 40, the present method allows the use of extruders having a screw length to diameter ratio less than 38 and as low as 20 or lower. The conductive thermoplastic composition prepared by the method exhibits high conductivity and high impact strength, and it is useful for molding articles such as electrostatically-paintable automotive exterior panels.

Abstract: Conventional batteries have the problem that, when battery temperature rises above a temperature at which the separator melts and flows due to an internal short-circuit, a large short-circuit current is generated between the positive and negative electrodes, that further raises the battery temperature. As a result, the short-circuit current further increases. The inventive electrode increases its resistivity with increasing temperature, and a processing for producing the electrode is disclosed. The electrode of the invention has an electron conductive material containing a conductive filler and a resin and increases its resistivity with increasing temperature.

Abstract: A method of producing a fuel cell separator in which dry granules of a composition for a fuel cell separator mainly containing a conductive material, a binder, and an additive are produced by mixing raw materials including at least the conductive material, the binder, and the additive, granulating the resultant mixture to obtain granules, and drying the granules. The dry granules may be further sized. Then the granules are packed in a mold and hot-press molded. The granules have a residual volatile matter content in a range of 4 weight-% or less, and an average particle size in a range of 200 to 700 &mgr;m (60 to 160 &mgr;m for the sized granules) and a specific particle size distribution.

Abstract: A process for the manufacturing of a decorative laminate, which laminate comprises an upper decorative and abrasion resistant thermosetting laminate layer and a carrying core. The upper side of the core is provided with the abrasion resistant thermosetting laminate while the lower side of the core is provided with a balance layer. This balance layer has the purpose of preventing warping of said decorative laminate while at the same time having the purpose of acoustic dampening. The balance layer comprises a layer of a polymer. The balance layer and the thermosetting laminate are joined with said core by means of pressing. Said carrying core further is provided with a dampening foil of an elastomer arranged between the upper side of the core and the abrasion resistant thermosetting laminate. The elastomer and thermosetting laminate are joined with each other and with the core by means of pressing. The achieved laminate is then cut into panels and provided with edges intended for joining.

Abstract: A method of forming graphitic bodies comprises the steps of:—

Abstract: A method of manufacturing to increase the thermal and electrical conductivity of polymers includes layering a filled polymer with an unfilled polymer to produce a multi-layered system of alternating filled and unfilled polymer layers. The filler material comprises thermally and/or electrically conductive material. A preferred polymer is a shape memory polymer. A method of manufacturing magnetic multi-layered polymer systems is described. Articles formed from such multi-layered systems are also disclosed.

Abstract: The invention provides a resin matrix with high loadings of a conductive filler; various additional additives, such as initiators, mold-release agents, shrink control additives, and carbon black; and optionally one or more rheological agents selected from the group comprising group II oxides, alkaline earth oxides, carbodiamides, polyisocynates, polyethylene and polytetraethylene fluoroethylene. The conductive filler is an inorganic filler which is desirably particulate graphite having a significant distribution of large particles such as for example, 95% in the range of about 150 to about 1000 microns with over about 40%, and more particularly about 50% or even 60% over 200 microns, or over 300 microns, or even over 600 microns. Conductive polymers may be used as a conductivity enhancer with the graphite. In addition, silver coated ceramic fibers can be added to improve the overall electrical properties. Fuel cell plates can be made from these compositions.

Abstract: An electrically conductive composite comprising a polyvinylidene fluoride polymer or copolymer and carbon nanotubes is provided. Preferably, carbon nanotubes may be present in the range of about 0.5-20% by weight of the composite. The composites are prepared by mixing or dispersing carbon nanotubes in polymer emulsion using an energy source such as a Waring blender. The liquid in the mixture is then evaporated to obtain the composite comprising the polymer and the nanotubes.

Abstract: The present invention discloses a conductive injection molding composition. The thermally conductive composition includes a metallic base matrix of, by volume, between 30 and 60 percent. A first thermally conductive filler, by volume, between 25 and 60 percent is provided in the composition that has a relatively high aspect ratio of at least 10:1. In addition, an alternative embodiment of the composition mixture includes a second thermally conductive filler, by volume, between 10 and 25 percent that has a relatively low aspect ratio of 5:1 or less.

Abstract: Modified compositions for carbonaceous concrete conductive sheathing materials for ground electrodes are described, for use in protecting installations from electrical currents. By the incorporation of discrete fibers, superior freeze-thaw resistance is imparted. The water resistance of carbonaceous concretes according to the invention is improved by the addition of a soluble soap of long chain fatty acids. A method of precasting carbonaceous cements according to the invention allows uniform and consistent development of properties for use either in shallow trench or deep well applications.

Abstract: Disclosed herein are a mixed resin compound, a resin pipe, a process for producing said resin pipe, and a photosensitive drum. The resin compound meets at least one of the following requirements. It is a mixture of two or more kinds of resins blended in a specific manner, it undergoes annealing under specific conditions, and it has specific values of surface roughness, Vickers hardness, coefficient of linear expansion, flexural modulus, and thermal conductivity. The resin pipe is suitable for use as the cylindrical base of the photosensitive drum for electrophotographic machines, such as copying machines, facsimiles, and printers. It is superior in surface smoothness, dimensional stability, coatability, and handlability, and hence it is very little vulnerable to damage during handling and dimensional change due to resin shrinkage and is superior in heat resistance (desirable for solvent removal) and mechanical strength (desirable for flange fitting).

Abstract: A process for preparing carbon electrodes is presented. In particular, a process for preparing carbon electrodes including the steps of combining calcined coke, a liquid pitch binder and carbon fibers derived from mesophase pitch to form an electrodestock blend; extruding the electrodestock blend to form a green electrodestock; baking the green stock to form a carbonized electrodestock; and graphitizing the carbonized stock by maintaining the carbonized tock at a temperature of at least about 2500.degree. C. for no more than about 18 hours is presented. The electrodes prepared by the inventive process are also presented.

Abstract: A gas diffusion electrode is manufactured by preparing a slurry containing an electrically conductive powder, carbon fibers, organic fibers and a resin in specific proportions, forming the slurry into a sheet, and heating and drying the sheet. The electrode has the volume resistivity, thermal conductivity and gas permeability required for use in fuel cells, exhibits a flexibility conducive to continuous production, and does not break under the application of pressure during electrode production or fuel cell assembly.

Abstract: A method to produce an electrically conductive floor covering made of first particles of a polymer material which are surrounded with electrically conductive second particles and compressed in the intermediate space between the top and bottom sides of the floor covering, with the floor covering having at least one cut surface and the electrically conductive second particles forming conductive paths which connect the upper side and the lower side of the floor covering in an electrically conductive way, in which the first particles comprise at least one granulated elastomer material and form a matrix, in which the second particles form electric conductive paths along the particle boundaries of the first particles.

Abstract: The present invention provides a method of manufacturing an exfoliated graphite/phenol resin composite foam of a porosity of 50-95%, a density of 0.1-0.8 g/cm3, by forming under contact pressure or reduced pressure at a temperature of 140-200° C. a mixture comprising 100 parts by weight of powdered and/or crushed exfoliated graphite and 40-240 parts by weight of phenol resin; an exfoliated graphite/phenol resin composite foam obtained by the method; and a method of obtaining an exfoliated graphite/glassy carbon composite foam of a porosity of 50-95%, a density 0.1-0.8 g/cm3 with volumetric baking shrinkage of 10% or less by baking the exfoliated graphite/phenol resin composite foam.

Abstract: A net-shape molded heat sink is provided which includes a thermally conductive main body and a number of thermally conductive fins integrally connected to and emanating from the main body. The heat sink is formed by overmolding a carbon-carbon matrix core plate with a thermally conductive polymer composition that is filled with thermally conductive filler material. The molded heat sink is freely convecting through the part which makes it more efficient and has an optimal thermal configuration.

Abstract: A method of reinforcing a polymeric material with carbon nanofibers is provided in which carbon nanofibers are combined with a polymer and a solvent for the polymer to form a substantially homogeneous mixture, followed by removal of the solvent by evaporation or coagulation. The resulting conductive polymeric nanocomposite material exhibits high electrical and thermal conductivity, enhanced mechanical strength, abrasion resistance, and dimensional stability.

Abstract: Processes are provided for formation of complex shapes by embossing of a sheet of flexible graphite material. In one approach, a sheet of material is provided with a variable resin concentration across its width, and the position of the variable resin concentration is correlated with the position of embossing features which will result in thinner areas in the embossed articles. In a second approach, recesses are provided in the embossing rollers to accommodate material flow during embossing. These recesses result in protrusions formed on the articles, which protrusions must then be removed in a machining operation.

Abstract: The capacity of an electro-chemical power source having an initial amount of an oxidizable material and an initial amount of a reducible material, is adjusted to a target capacity by altering the initial amount of one or both of the oxidizable material and the reducible material available to participate in the source by a technique selected from the group consisting of adding, removing and isolating a known fraction of the initial amount from the power source.

Abstract: A process for extruding a thin positive electrode sheet having at least 40% /wt of solid content for a lithium polymer battery through a single or twin screw extruder is disclosed as well as a positive electrode sheet produced therefrom. A mixture of active cathodic intercalation material, lithium salt and electronic conductive material is mixed with a polymer of the polyether family in a ratio of at least 40% of total weight into the mixing chamber of an extrusion machine and extruded through a classical sheet die into a thin cathode sheet or film onto a substrate in sheet form.

Abstract: Powder of a polymer active material 1 exhibiting an electro-chemical oxidation-reduction reaction is mixed with powder of a conductivity assisting agent 2 to obtain a mixture. The mixture is molded by a thermal press into a unitary block. Thus, a cell electrode having a large film thickness is produced without causing cracks or breakage. The electrode having a large film thickness improves the energy density of the polymer secondary cell.

Abstract: A film is made of an insulating matrix resin and an electroconductive material, in which the electroconductive material is dispersed in the insulating matrix resin in such a manner that a surface resistivity of A [&OHgr;] of the film and a volume resistivity of B [&OHgr;·cm] of the film in the direction of a thickness thereof normal to the surface of the film satisfy a relationship of: A>B, and when the film has a thickness of T [cm], the electroconductive material is dispersed in the insulating matrix resin in such a manner that the surface resistivity of A [&OHgr;] of the film and the volume resistivity of B [&OHgr;·cm] of the film satisfy a relationship of; A[&OHgr;]'T [cm]>B [&OHgr;·cm]. This film can be prepared by a centrifugal molding method.

Abstract: A method of molding a rubber product from a rubber compound by a molding apparatus having a kneading region. A full amount of carbon black (CB) and a full amount of process oil, together with other auxiliary materials except vulcanizing chemicals, are compounded with raw rubber to thereby knead and prepare a granular master batch (granular MB) . The rubber product is extrusion-molded and vulcanized after vulcanizing chemicals (a vulcanizing agent and a vulcanization accelerator) are quantitatively supplied into the kneading region of the molding apparatus through a material supply port while the vulcanizing chemicals are mixed with the granular MB.

Abstract: The present invention relates to a method for continuous production of elongated carbon bodies, particularly carbon electrodes which are produced in direct connection with the smelting furnace wherein the electrodes are consumed, where a metallic casing containing unbaked carbonaceous electrode paste comprising a particulate solid carbon material and a carbonaceous binder is continuously or substantially continuously lowered through a baking furnace which is heated to a temperature between 500 and 1200° C.

Abstract: Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.

Abstract: The present invention provides a process whereby high quality, well-coalesced spandex can be made by dry-spinning a high-melting thermoplastic polyurethane, bundling the as-spun filaments into a side-by-side relationship, and passing the bundled filaments over or through a guide. The spandex made by this method has high-heat settability, high denier uniformity, good knittability and weavability, and provides fabrics having good surface uniformity.

Abstract: A metal oxide electrode for a supercapacitor and a manufacturing method thereof are disclosed. Potassium permanganate is absorbed on a conductive material, such as carbon or activated carbon, and mixed with a solution including manganese acetate so as to form amorphous manganese oxide. Amorphous manganese oxide powder is grounded to a powder which is mixed with binder to form an electrode having a predetermined shape. The electrode reduces equivalent serial resistance and enhances high frequency characteristics since the contact area and the adhesion strength between the manganese oxide and the conductive carbon are improved. Also, the electrode has high capacitance suitable for a supercapacitor, which is manufactured therefrom at a greatly reduced cost.

Abstract: A method of manufacturing material suitable for the construction of a component of a fuel cell, such as a flow field plate or electrode. Uncured resin impregnated flexible graphite sheet is ground into particles. Without re-expanding the particles, and without adding further resin to the particles, the particles are molded into the form of the desired material. The material is then cured. Additives may be mixed with the particles to improve the properties of the material.

Abstract: In a method of making an electrically conductive electrode member, a compound material, containing a binder made of polymer plastic and 80 weight % of a powdery electrically conductive material as filler, is introduced into a plasticizing screw of an injection molding machine for transforming the compound material to a plasticized material and discharging the plasticized material via a nozzle having a length of less than 15 mm for subsequent injection molding. The injection molding machine is constructed throughout a material flow passage from a point of introduction of the compound material to the injection mold to have only tapered portions which narrow a flow cross section by not more than 10:1.

Abstract: A novel adhesion adjusting additive for semiconductive dielectric shields for electric power cables is disclosed. The additive comprises a compound with a carbon-oxygen dipole, and a molecular weight less than 20,000 daltons. The additive is blended with a base polymer and conductive carbon black to form the material for the semiconductive shield.

Abstract: The present invention is directed to the realization that the dimensions and basis weight of an electrode active admixture such as a transition metal oxide, and particularly silver vanadium oxide, formed into an electrode structure from an admixture paste subjected to a calendering process are influenced by the calender direction. To obtain electrode structures of a desired low basis weight requires a secondary calendering step performed in a direction reverse or orthogonal to that used to form the initial sheet tape. Orthogonal or reverse feed of the electrode active admixture provides for fibrillation of the fluoro-polymeric binder in other than the initial direction. This lets the binder spread in directions transverse to the initial direction to form the low basis weight electrode active structure.

Abstract: According to a molding method for a conductive plate of this invention, a substrate having through holes each corresponding to each protruded portion is employed and the substrate is sandwiched between both dies. Then raw powder is filled into each housing portion provided opposing each through hole in the substrate provided in each of both dies, through the through hole in order to form each protruded portion. Then the protruded portion is formed integrally with the substrate by heating the raw powder under pressure.

Abstract: A process for the preparation of a semiconducting shield composition comprising: (i) introducing an elastomer into a melt/mixer having a melting zone and a mixing zone; (ii) introducing particulate conductive carbon black into the melt/mixer in an amount of about 10 to about 25 percent by weight based on the weight of the resin; (iii) melting the elastomer in the melting zone; (iv) mixing the carbon black and the molten elastomer in the mixing zone; (v) optionally, pelletizing the mixture of carbon black and elastomer; (vi) recycling the mixture of carbon black and elastomer from step (iv) or the pellets from step (v) to a melt/mixer; (vii) introducing additional particulate semiconductive carbon black into the melt/mixer in an amount sufficient to provide a total amount of carbon black in the range of about 25 to about 50 percent by weight based on the weight of the resin; (viii) melting and mixing the mixture from step (vii); and (ix) pelletizing or extruding the mixture from step (viii).

Abstract: The invention aims to provide an organic PTC thermistor having a lower operating temperature than prior art organic PTC thermistors and exhibiting improved characteristics. The object is attained by an organic PTC thermistor comprising a polymer synthesized in the presence of a metallocene catalyst and conductive particles having spiky protuberances.

Abstract: Conductive paste for the electrical industry based on at least one elastomer (10) and on an admixture of conducting particles in the form of fibers (20), in which the fibers (20) are flexible and have been embedded in the elastomer (10) in random orientation and with formation of a large number of contact points.

Abstract: Powder mixture is supplied into a die under a state that a center pin is located lower than the top surface of the die, after which the center pin is lifted up to a given molding position where an annular molding space is defined between the center pin and the die. The powder mixture is then compressed from upper and lower sides with an upper plunger and a lower plunger to form a pellet. The center pin and the lower plunger are simultaneously lifted up to remove the pellet out of the die.

Abstract: A method of overmolding a heat pipe includes providing an injection mold apparatus having a cavity, an input gate, a bleed off overflow gate in communication with the cavity and a tubular heat pipe charged with phase change media which is capable of being collapsed by imparting an external collapsing pressure. The tubular heat pipe is placed into the cavity in the injection mold apparatus. A net shape moldable thermally conductive material is introduced into the cavity and around the tubular pipe. The bleed off overflow gate is set to open at a predetermined pressure which less than the external collapsing pressure which would damage the heat pipe to be overmolded. Pressure is relieved in the cavity of the mold apparatus through the bleed off overflow gate when pressure in the bleed off overflow gate reaches the predetermined pressure. As a result, delicate heat pipes can be overmolded in an injection mold apparatus without damage to the heat pipe during the molding process.