Islands-in-sea (i.e., Discontinuous Phase In Continuous Phase) Patents (Class 264/172.13)
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Patent number: 7255820Abstract: Disclosed is a process for the manufacture of an elastic polyurethane fiber, including mixing one component selected from among polystyrene polymers or polystyrene copolymers having a number average molecular weight of 50,000–500,000 with polyurethane having a number average molecular weight of 15,000–100,000, to prepare a polymer mixture, which is then spun. The polyurethane elastic fiber made by the method is also provided, which is greatly increased in heat set properties, with a very low rate of change of fundamental properties as the results compared with conventional elastic polyurethane fibers. Hence, the elastic polyurethane fiber can be directly applied for preparation of end products requiring superior heat set properties with no change of conventional conditions of the process.Type: GrantFiled: November 21, 2003Date of Patent: August 14, 2007Assignee: Hyosung CorporationInventors: Tae-woo Lee, Seung-won Seo, Seung-hyun Jang
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Patent number: 7147815Abstract: A process for the preparation of a side-by-side or eccentric sheath-core bicomponent fiber wherein each component comprises a different poly(trimethylene terephthalate) composition.Type: GrantFiled: June 26, 2003Date of Patent: December 12, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Jing C. Chang, Ray W. Miller
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Patent number: 7045202Abstract: A long glass fiber filler reinforced resin material for molding includes a masterbatch formed of a composite of a matrix resin with a polypropylene (PP) component and a long glass fiber filler and a diluent resin made from an ethylene-propylene block copolymer. The above-described matrix resin of the masterbatch includes the PP component having a pentad isotactic index of at least 95%, and a melt flow rate (MFR) of the matrix resin of the masterbatch is 100 to 500 g/10 min and larger than six times a melt flow rate of the diluent resin. The long glass fiber filler is in a content of 30 to 50 mass percent with respect to a total mass thereof.Type: GrantFiled: January 28, 2003Date of Patent: May 16, 2006Assignee: Mazda Motor CorporationInventors: Chikara Tanaka, Takahiro Tochioka
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Patent number: 7025915Abstract: A method for producing an artificial leather includes mixed spinning an island polymer and a sea polymer having a different dissolving property from that of the island polymer at a predetermined temperature, producing a non-woven substrate from the fiber obtained, immersing the non-woven substrate into a polymer, dissolving and removing the sea polymer in the non-woven substrate to obtain an artificial leather as a semi-finished product, and polishing the surface of the artificial leather to obtain an artificial leather having excellent dyeability and advanced fluff-like property. The ratio of melt flow index of the sea polymer to relative viscosity of the island polymer is about 20 to about 55, in which the relative viscosity of the island polymer is about 2.7 to about 3.5 and the weight percentage of the sea polymer relative to the sum of the sea polymer and the island polymer is about 30% to about 70%.Type: GrantFiled: March 21, 2003Date of Patent: April 11, 2006Assignee: San Fang Chemical Industry Co., Ltd.Inventors: Ching-Tang Wang, Mong-Ching Lin, Chung-Chin Feng, Kuo-Kuang Cheng, Chin-Yi Lin
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Patent number: 7008586Abstract: An apparatus for extruding multiple types of liquid materials into multi-component filaments. A pair of outer manifold elements sandwich an intermediate manifold element. Respective channels are formed between opposing sides of the outer manifold elements and the respective opposite sides of the intermediate manifold element. These recesses form channels which diverge or widen away from associated inlets at the top of the manifold assembly. A die tip is coupled to the manifold assembly at a lower side and communicates with the outlets of the channels. The die tip includes a combining member for producing a desired multi-component filament configuration.Type: GrantFiled: October 17, 2002Date of Patent: March 7, 2006Assignee: Nordson CorporationInventor: Martin A. Allen
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Patent number: 6967057Abstract: A process for preparing poly(trimethylene terephthalate) fibers including (a) providing a poly(trimethylene terephthalate) composition comprising about 0.05 to about 10 weight % ionomer and (b) spinning the polymer composition to form fibers. In addition, a poly(trimethylene terephthalate) fiber including poly(trimethylene terephthalate) with about 0.1 to about 10 weight % ionomer dispersed throughout the poly(trimethylene terephthalate), and use thereof in yarns, fabrics, and carpets, as well as the yarns, fibers and fabrics.Type: GrantFiled: December 3, 2003Date of Patent: November 22, 2005Assignee: E.I. du Pont de Nemours and CompanyInventors: Jing C. Chang, Joseph V. Kurian, Sam Louis Samuels
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Patent number: 6946093Abstract: An apparatus for meltblowing multiple types of liquid materials into multi-component filaments. A pair of outer manifold elements sandwich an intermediate manifold element. Respective channels are formed between opposing sides of the outer manifold elements and the respective opposite sides of the intermediate manifold element. These recesses form channels which diverge or widen away from associated inlets at the top of the manifold assembly. A die tip is coupled to the manifold assembly at a lower side and communicates with the outlets of the channels. The die tip includes a combining member for producing a desired multi-component filament configuration and further includes air discharge passages for impinging the discharged multi-component filaments with pressurized air.Type: GrantFiled: October 17, 2002Date of Patent: September 20, 2005Assignee: Nordson CorporationInventor: Martin A. Allen
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Patent number: 6923925Abstract: A process for preparing poly(trimethylene dicarboxylate) multifilament yarns and monofilaments. One process for preparing poly(trimethylene dicarboxylate) multifilament yarns includes (a) providing a polymer blend including poly(trimethylene dicarboxylate) and about 0.1 to about 10 weight % styrene polymer, by weight of the polymer in the polymer blend, (b) spinning the polymer blend to form poly(trimethylene dicarboxylate) multiconstituent filaments containing dispersed styrene polymer, and (c) processing the multiconstituent filaments into poly(trimethylene dicarboxylate) multifilament yarn including poly(trimethylene dicarboxylate) multiconstituent filaments containing styrene polymer dispersed throughout the filaments. Another process includes spinning at a speed of at least 3,000 m/m and processing a blend including poly(trimethylene dicarboxylate) to form partially oriented poly(trimethylene dicarboxylate) multifilament yarn.Type: GrantFiled: June 27, 2002Date of Patent: August 2, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: Jing C. Chang, Joseph V. Kurian, Shekhar Subramoney
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Patent number: 6921508Abstract: A method of preparation of microfibrous non-woven fabric of the suede-finish type comprising the steps of: spinning of a bi-component fiber of the “islands in the sea” type in which the “island” comprises a polymer chosen from among those employed in textile applications while the “sea” is a polymer that can dissolve and be removed by means of treatment with water, alkaline or acidic aqueous solutions, with non-polluting organic solvents alone or in aqueous solution; preparing a felt with the bi-component fiber; impregnating the felt with aqueous solution of polyvinylalcohol with reduced solubility in water; removing the “sea” component by treatment with solvents step; impregnating with emulsion or polyurethane dispersion; removing the polyvinylalcohol; and finishing the non-woven fabric obtained.Type: GrantFiled: March 12, 2002Date of Patent: July 26, 2005Assignee: Alcantara S.p.A.Inventors: David Latini, Gianni Romani
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Patent number: 6911174Abstract: The present invention provides a multicomponent fiber containing at least two polymer components arranged in distinct zones or segments across the cross-section of the fiber wherein at least one component of the fiber contains a thermoplastic polymer and at least one component of the fiber contains a thermoset polymer. The invention also provides fabrics and fabric laminates containing the multicomponent fibers, and articles containing the fabric. Additionally provided is a process for producing the multicomponent fibers.Type: GrantFiled: December 30, 2002Date of Patent: June 28, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Christopher Cosgrove Creagan
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Patent number: 6905743Abstract: A medical balloon composed of a micro-composite material which provides for radial expansion of a balloon to a predetermined extent, but which has minimal longitudinal growing during balloon inflation. The micro-composite material includes a fibril component, a matrix component, and optionally, a compatibilizer. The fibril component may preferably be liquid crystal polymer fibers randomly scattered through out the balloon material. The liquid crystal polymers are created by extrusion at high speed. An alternative fibril component may be a PET fibers which are uniformly spaced about the balloon material and extend through out the length of the balloon material tube.Type: GrantFiled: October 25, 2000Date of Patent: June 14, 2005Assignee: Boston Scientific SciMed, Inc.Inventors: John Jianhua Chen, Lixiao Wang, Yiqun Wang, Albert C. C. Chin
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Patent number: 6884378Abstract: This invention relates to methods for manufacturing super-micro fibers to produce fibers having dimensions of between 0.003-0.0003 denier per filament. The manufacturing methods include the following steps: blending polyamide-polyester mixtures; passing said polyamide-polyester mixtures through single-path and twin-screw extrusion processes; spinning said polyamide-polyester mixtures; melting and dissolving said polyamide-polyester mixtures; and separating polyester compounds from said polyester-polyamide mixtures to form polyamide compound or super-micro fibers.Type: GrantFiled: July 5, 2002Date of Patent: April 26, 2005Assignee: Nan Ya Plastics CorporationInventor: Zo-Chun Jen
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Patent number: 6861477Abstract: A superabsorbent composition comprising a superabsorbent material and an elastomer. The superabsorbent composition has a two-phase morphology resulting in one of the superabsorbent material and elastomer being dispersed as aggregates in the other continuous material. The superabsorbent composition has a low glass transition temperature. The low glass transition temperature gives the superabsorbent composition many beneficial properties. This invention also discloses novel superabsorbent particles, fibers, films, and microporous films. Also disclosed in this invention are personal care articles comprising such particles, fibers, films and microporous films.Type: GrantFiled: December 21, 2001Date of Patent: March 1, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James Hongxue Wang, Jayant Chakravarty, Thomas Kremer, David Glen Biggs, Xiaomin Zhang
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Patent number: 6855769Abstract: The present invention relates to a thermoplastic styrenic resin composition comprises a styrenic copolymer comprising 15-100 parts by weight of a unit derived from a styrenic monomer (i-1), 0-45 parts by weight of a unit derived from a vinyl cyanide monomer (i-2), 0-40 parts by weight of a unit derived from a copolymerizable vinyl monomer (i-3) other than the above monomers, and 0.0005-1.0 parts by weight of a unit derived from a polyfunctional maleimide monomer, all based on 100 parts by weight of the total amount of (i-1) to (i-3). The thermoplastic styrenic resin composition manufactured in the present invention is excellent in processability. The rubber modified thermoplastic styrenic resin composition of the present invention gives a good heat stability, impact strength, fluidity and other mechanical properties. In addition, it also gives a uniform wall thickness, and the gloss on the surface of injected products after painting process is excellent.Type: GrantFiled: November 7, 2003Date of Patent: February 15, 2005Assignee: Chi Mei CorporationInventor: Wen-Yi Su
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Publication number: 20040222544Abstract: A process for the preparation of a side-by-side or eccentric sheath-core bicomponent fiber wherein each component comprises a different poly(trimethylene terephthalate) composition.Type: ApplicationFiled: June 26, 2003Publication date: November 11, 2004Inventors: Jing C. Chang, Ray W. Miller
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Publication number: 20040180200Abstract: The invention provides a method for making fibers and yarns having improved dyeability with reactive and disperse dyes, resistance to staining and improved mechanical properties and characteristics. The method includes blending a polyolefin polymer and a fibril forming polymer to provide a mixture of polyolefin and fibril forming polymers. The mixture is conducted to a hot melt extruder to provide a substantially homogenous molten mixture of polyolefin and fibril forming polymers. The molten mixture is forced through a spinneret having a length to diameter (L/D) ratio ranging from about 3 to about 30 to provide a fiber having a polyolefin matrix and elongate, substantially discontinuous fibrils of the fibril forming polymer dispersed into the polyolefin matrix, whereby the exterior surface of the fibers is substantially devoid of fibrils. Fibers made by the process of the invention are useful as carpet face yarn, in textiles, upholstery and other industrial applications, like chemical industry and others.Type: ApplicationFiled: March 25, 2004Publication date: September 16, 2004Inventors: Luca Bertamini, Luigi Marco Pontarin, Mauro Caldara, William C. Mallonee
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Patent number: 6780937Abstract: A rubber composition having improved processability and which provides a vulcanized rubber exhibiting excellent wear resistance and good tensile strength to service temperatures of up to about 150° C. The composition comprises (1) a crosslinked polymer particle having as repeat units (a) up to about 25% of a conjugated diene unit, (b) at least 70% of an aromatic vinyl unit, (c) about 15% to about 30% of a crosslinking monomer, and (d) about 0.Type: GrantFiled: August 29, 2002Date of Patent: August 24, 2004Assignee: The Goodyear Tire & Rubber CompanyInventor: Eric Sean Castner
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Patent number: 6770365Abstract: A polytrimethylene terephthalate (PTT) filament yarn capable of being produced by a high speed spinning method and having a high residual elongation and excellent draw-false twisting processability includes 0.5 to 4.0% by mass of filament elongation enhancing agent particles which are drawn-oriented in the filaments along the longitudinal direction thereof and have a thermal deformation temperature of 40° C. or more but less than 105° C., an average particle size D of 0.03 to 0.35 &mgr;m determined in the cross-sections of the filaments and a ratio L/D of the average particle length L in the filament longitudinal direction to the average cross-sectional particle size D of 2 to 20; and the filament yarn exhibits an increase in the residual elongation of 30% or more due to the presence of the filament elongation enhancing agent, a birefringence &Dgr;n of 0.02 to 0.07, a retaining elongation of 60 to 250% and a thermal stress peak value of 0.18 cN/dtex or less.Type: GrantFiled: June 26, 2003Date of Patent: August 3, 2004Assignee: Teijin LimitedInventors: Mie Yoshimura, Koichi Iohara
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Patent number: 6737009Abstract: A system and process for producing spunbond nonwoven fabric in which two or more polymeric components are separately melted and are separately directed through a distribution plate configured so that the separate molten polymer components combine at a multiplicity of spinnerette orifices to form filaments containing the two or more polymer components. Multicomponent filaments are extruded from the spinnerette orifices into a quench chamber where quench air is directed from a first independently controllable blower and into contact with the filaments to cool and solidify the filaments. The filaments and the quench air are directed into and through a filament attenuator and the filaments are pneumatically attenuated and stretched. The filaments are directed from the attenuator into and through a filament depositing unit and are deposited randomly upon a moving continuous air-permeable belt to form a nonwoven web of substantially continuous filaments.Type: GrantFiled: August 2, 2001Date of Patent: May 18, 2004Assignee: BBA Nonwovens Simpsonville, Inc.Inventors: Thomas B. Taylor, Robert C. Alexander
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Publication number: 20040070101Abstract: A method for producing a ultrafine fiber includes spinning an island polymer and a sea polymer to a ultrafine fiber. The island polymer is an olefin polymer and the sea polymer has a different dissolving property from that of the island polymer. A method for producing a ultrafine fiber substrate, which includes obtaining a substrate from the ultrafine fiber from the above-mentioned method, dissolving and removing the sea polymer in the substrate to obtain the ultrafine fiber substrate.Type: ApplicationFiled: October 8, 2003Publication date: April 15, 2004Inventors: Ching-Tang Wang, Mong-Ching Lin, Chung-Chih Feng, Kuo-Kuang Cheng, Chih-Yi Lin
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Patent number: 6706658Abstract: One aspect of the invention relates to a catalyst composite containing an extruded catalyst support containing an extruded activated carbonaceous material having specifically a defined pore structure. For example, the extruded activated carbonaceous material may have pores wherein at least about 40% of total Hg porosity occurs in pores having a diameter of about 200 Å and larger. Alternatively the extruded activated carbonaceous material may have a first set of pores having a pore diameter of at least about 40 Å and at most about 100 Å with a porosity of at least about 0.15 cc/g, and a second set of pores having a pore diameter of at least about 5,000 Å and at most about 20,000 Å with a porosity of at least about 0.3 cc/g.Type: GrantFiled: December 21, 2001Date of Patent: March 16, 2004Assignee: Engelhard CorporationInventor: James Ferguson White
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Publication number: 20040041298Abstract: Methods for manufacturing super micro fibers to produce fibers having dimensions of between 0.003-0.003 denier per filament. The manufacturing methods include the following steps: blending polyamide and polyester compounds; passing the polyamide-polyester mixture through twin-screw extrusion; spinning the mixture and; melting, dissolving and removing the polyester compounds with alkaline solvents.Type: ApplicationFiled: July 5, 2002Publication date: March 4, 2004Inventor: Zo-Chun Jen
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Patent number: 6544455Abstract: A method for making a biodegradable thermoplastic composition. The thermoplastic composition may be used in methods to produce multi-component fibers and non-woven materials that demonstrate a higher contact angle hysteresis, quicker intake times, and improved skin dryness as compared to prior art materials. In addition, biodisintegratable nonwoven materials made according to the present invention also exhibit high wetting rates, which is unexpected based upon the higher hysteresis values. The nonwoven material may be produced using thermoplastic compositions which comprise an unreacted mixture of an aliphatic polyester polymer as a continuous phase, polyolefin microfibers as a discontinuous phase encased within the aliphatic polyester polymer continuous phase, and a compatibilizer for the aliphatic polyester polymer and the polyolefin microfibers. The multicomponent fiber exhibits substantial biodisintegratable properties and good wettability yet is easily processed.Type: GrantFiled: August 1, 2000Date of Patent: April 8, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Fu-Jya Daniel Tsai
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Patent number: 6506327Abstract: In a method for producing a monofilament with reduced secondary binding forces of at least two commonly extruded polymers for the production of bristles or interdental cleaners which are slittable substantially axially through the action of mechanical forces, the at least two polymers of the monofilament are disposed in a regular geometrical arrangement with substantially axially extending boundary layers in which the reduced secondary binding forces prevail for generation of defined slits of flags.Type: GrantFiled: November 29, 2001Date of Patent: January 14, 2003Assignee: Pedex & Co. GmbHInventor: Georg Weihrauch
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Publication number: 20020063364Abstract: A system and process is provided for producing spunbond nonwoven fabric. Two or more polymeric components are separately melted and are separately directed through a distribution plate configured so that the separate molten polymer components combine at a multiplicity of spinnerette orifices to form filaments containing the two or more polymer components. Multicomponent filaments are extruded from the spinnerette orifices into a quench chamber where quench air is directed from a first independently controllable blower and into contact with the filaments to cool and solidify the filaments. The filaments and the quench air are directed into and through a filament attenuator and the filaments are pneumatically attenuated and stretched. The filaments are directed from the attenuator into and through a filament depositing unit and are deposited randomly upon a moving continuous air-permeable belt to form a nonwoven web of substantially continuous filaments.Type: ApplicationFiled: August 2, 2001Publication date: May 30, 2002Applicant: BBA Nonwovens Simpsonville, Inc.Inventors: Thomas B. Taylor, Robert C. Alexander
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Patent number: 6392007Abstract: At least two different liquid streams are sub-divided into a dense plurality of individually separated parallel pixels oriented in respective misregistered arrays. Therefore, an individual pixel of one of the liquid stream arrays will be surrounded by pixels of the other liquid stream array. These individual pixel arrays are then bought into contact with one another to form a multi-pixel liquid stream comprised of the misregistered pixel arrays of the two different liquid streams. The “pixelated” liquid stream—that is, the liquid stream containing in cross-section the misregistered pixel arrays of the two different liquid streams—may then be further processed. For example, the pixelated liquid stream may be subjected to further mixing by being directed along a tortuous flow path.Type: GrantFiled: December 30, 1999Date of Patent: May 21, 2002Assignee: BASF CorporationInventors: Karl H. Buchanan, Wendel L. Burton, Charles F. Helms, Jr., John A. Hodan, Gary W. Shore
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Patent number: 6267898Abstract: A leukocyte-removing filter medium which comprises a matrix and ultra-fine fibers having a fiber diameter of less than 1.0 &mgr;m and not less than 0.01 &mgr;m which contains ultra-fine fibers in an amount of less than 50 wt % and not less than 0.1 wt %, the degree of curvature of the ultra-fine fibers being 1.2 or more, and/or the ultra-fine fibers form pores having a roundness of 1.7 or less.Type: GrantFiled: December 27, 1999Date of Patent: July 31, 2001Assignee: Asahi Medical Co., Ltd.Inventors: Tatsuya Fukuda, Jun Tanaka
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Patent number: 6258304Abstract: Lyocell fibres contain elongated domains of polyester, polyamide or an olefin copolymer, the domains having an aspect ratio at least 1.5 and being aligned substantially parallel to the axis of the fibre. A process for the preparation of lyocell fibre or film by extruding a solution of cellulose in amine oxide through a spinneret or film die at elevated temperature via an air gap into an aqueous precipitation bath is characterised in that 0.1 to 60 wt % based on cellulose of a thermoplastic low-melting polymer is incorporated into the cellulose solution. A process for the preparation of a bicomponent fibre by extruding two polymers through a spinneret in side-by-side relationship at elevated temperature is characterised in that one of the polymers is a solution of cellulose in amine oxide and the other polymer is a molten thermoplastic polymer having a melting point above 25° C. but below the extrusion temperature.Type: GrantFiled: September 10, 1999Date of Patent: July 10, 2001Assignee: Tencel LimitedInventor: Hardev Singh Bahia
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Patent number: 6245268Abstract: Polymer blend fibers having a phase separation structure are provided. The phase separation structure is a sea-island structure and a diameter D1 on a circle basis of an island phase of the sea-island structure in a transverse cross-section of the fibers is in the range of 0.001 to 0.4 &mgr;m.Type: GrantFiled: October 21, 1998Date of Patent: June 12, 2001Assignee: Toyo Boseki Kabushiki KaishaInventors: Tetsushi Oka, Seiki Nishihara, Hiroshi Yasuda
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Patent number: 6197237Abstract: Disclosed is a thermoplastic composition comprising an unreacted mixture of an aliphatic polyester polymer as a continuous phase, polyolefin microfibers as a discontinuous phase encased within the aliphatic polyester polymer continuous phase, and a compatibilizer for the aliphatic polyester polymer and the polyolefin microfibers. The multicomponent fiber exhibits substantial biodegradable properties and good wettability yet is easily processed. The thermoplastic composition is useful in making nonwoven structures that may be used in a disposable absorbent product intended for the absorption of fluids such as body fluids.Type: GrantFiled: June 8, 1999Date of Patent: March 6, 2001Assignee: Kimberly Clark CorporationInventors: Fu-Jya Daniel Tsai, Brian Thomas Etzel