Into Liquid Bath (e.g., Wet-spinning, Etc.) Patents (Class 264/172.16)
  • Patent number: 11866558
    Abstract: A sheet comprising a plexifilamentary film-fibril network consisting essentially of high density polyethylene in an overlapping multi-directional configuration, the sheet, as-produced from a spin cell, having a normalized Frazier air permeability of between 0.002 and 0.2 m3/m2·minute at 50 gsm, a BET surface area of between 9 and 20 m2/gm, and a normalized hydrohead of between 150 and 250 cm at 50 gsm, wherein the plexifilamentary film-fibril network in an overlapping multi-directional configuration is flash-spun from a spin fluid comprising polymer and spin agent, the spin fluid temperature being 190° C. or greater, the spin agent comprising dichloromethane, the spin fluid having a polymer concentration of 12 to 14 weight percent.
    Type: Grant
    Filed: January 11, 2021
    Date of Patent: January 9, 2024
    Assignee: DUPONT SAFETY & CONSTRUCTION, INC.
    Inventors: Jan Van Meerveld, Corneille Schmitz, Joseph Mathieu, Noel Stephen Brabbs, Orest Skoplyak, Christine Lemoine, Serge Rebouillat
  • Patent number: 11574752
    Abstract: A magnetic fiber comprises a core comprising a spinel ferrite of formula Me1-xMxFeyO4, wherein Me is Mg, Mn, Fe, Co, Ni, Cu, Zn, or a combination thereof, x=0 to 0.25, and y=1.5 to 2.5, wherein the core is solid or at least partially hollow; and a shell at least partially surrounding the core, and comprising a Me1-xMxFey alloy, wherein when the core is solid with Me=Ni and x=0 the magnetic fiber has a diameter of greater than 0.3 micrometer. A magneto-dielectric material having a magnetic loss tangent of less than or equal to 0.03 at 1 GHz comprises a polymer matrix; and a plurality of the magnetic fibers.
    Type: Grant
    Filed: July 16, 2020
    Date of Patent: February 7, 2023
    Assignee: ROGERS CORPORATION
    Inventors: Yajie Chen, Robert C. Daigle, Li Zhang
  • Patent number: 10920028
    Abstract: A sheet having a plexifilamentary structure with a normalized Frazier air permeability of between 0.002 and 0.2 (m3/m2·minute)@50 gsm, and a normalized hydrohead of between 150 and 250 centimeters@50 gsm.
    Type: Grant
    Filed: June 16, 2015
    Date of Patent: February 16, 2021
    Assignee: DUPONT SAFETY & CONSTRUCTION, INC.
    Inventors: Jan Van Meerveld, Corneille Schmitz, Joseph Mathieu, Noel Stephen Brabbs, Orest Skoplyak, Christine Lemoine, Serge Rebouillat
  • Patent number: 9752256
    Abstract: The invention relates to a continuous process for making a yarn comprising filaments of poly (paraphenylene terephthalamide) and the yarn made thereby, the process utilizing a coagulation bath having a temperature of at least 20° C., washing with an aqueous liquid, and drying the filaments under a tension of 0.3 to 1.0 grams per denier wherein the filaments are dried for 0.4 to 0.9 seconds at a temperature of from 250 to 325° C. The yarn has a tenacity of at least 22 gpd, an elongation at break of at least 3.2 percent, and a tensile modulus of from 530 to 700 gpd; the yarn further has a heat-aged strength retention (HASR) of at least 93 percent and the filaments in the yarn have a D110 crystallinity of at least 55 angstroms.
    Type: Grant
    Filed: July 21, 2015
    Date of Patent: September 5, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Mehdi Afshari, Walter Randall Hall, III
  • Patent number: 8834780
    Abstract: A polymer fiber is formed by hydrodynamic spinning. Fluids are forced to flow through a conduit to form a laminar flow comprising three or more layers of generally coaxial fluid flows, at respective flow rates selected to define a cross-section of a tubular middle layer of the fluid flows. The middle layer comprises a cross-linkable polymer precursor. Another layer of the fluid flows comprise a cross-linking agent. The polymer precursor, cross-linking agent and fluids are selected to prevent substantial diffusion of the polymer precursor away from the middle layer, and to allow a portion of the cross-linking agent to diffuse from the another layer into the middle layer to facilitate cross-linking of the polymer precursor in the middle layer to form a tubular polymer layer in a polymer fiber. The polymer layer thus has a cross-section generally corresponding to the cross-section of the middle layer.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: September 16, 2014
    Assignee: Agency for Science, Technology and Research
    Inventors: Jackie Y. Ying, Min Hu, Rensheng Deng, Karl Schumacher, Motoichi Kurisawa
  • Patent number: 8802233
    Abstract: Upon producing a meta-type wholly aromatic polyamide fiber by wet spinning a polymer solution containing a meta-type wholly aromatic polyamide containing a m-phenylenediamine isophthalamide skeleton as a major component, and an amide solvent containing a salt, (1) the polymer solution is ejected into a coagulation bath containing an amide solvent and water and containing a salt at a low concentration to coagulate as a porous thread body (fibrous material), (2) which is subsequently stretched in a plastic stretching bath containing an aqueous solution of an amide solvent, (3) is rinsed with water and then subjected to a heat treatment in a saturated steam atmosphere, and (4) is then subjected to a dry heat treatment, so as to produce a novel meta-type wholly aromatic polyamide fiber that contains an extremely small amount of a solvent remaining in the fibers, contains a small amount of a volatile substance harmful in a heat treatment step at a high temperature, is capable of suppressing coloration of a fiber p
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: August 12, 2014
    Assignee: Teijin Limited
    Inventors: Kotaro Takiue, Hiroshi Fujita
  • Patent number: 8747093
    Abstract: A spinneret for producing nanofibers from a viscous liquid using electrostatic spinning in an electric field is described. The spinneret includes one or more narrow annular bodies radially centered about and axially spaced along a central axis. The annular bodies may be discs, rings, or coils.
    Type: Grant
    Filed: October 14, 2009
    Date of Patent: June 10, 2014
    Assignee: Deakin University
    Inventors: Tong Lin, Xungai Wang, Xin Wang, Haitao Niu
  • Patent number: 8383026
    Abstract: One or more embodiments relates to the production of a fabricated fiber having an asymmetric polymer network and having an immobilized liquid such as an ionic liquid within the pores of the polymer network. The process produces the fabricated fiber in a dry-wet spinning process using a homogenous dope solution, providing significant advantage over current fabrication methods for liquid-supporting polymers. The fabricated fibers may be effectively utilized for the separation of a chemical species from a mixture based on the selection of the polymer, the liquid, and the solvent utilized in the dope.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: February 26, 2013
    Assignee: U.S Department of Energy
    Inventors: David R. Luebke, Shan Wickramanayake
  • Patent number: 8246886
    Abstract: A method and system for aligning nanotubes within an extensible structure such as a yarn or non-woven sheet. The method includes providing an extensible structure having non-aligned nanotubes, adding a chemical mixture to the extensible structure so as to wet the extensible structure, and stretching the extensible structure so as to substantially align the nanotubes within the extensible structure. The system can include opposing rollers around which an extensible structure may be wrapped, mechanisms to rotate the rollers independently or away from one another as they rotate to stretch the extensible structure, and a reservoir from which a chemical mixture may be dispensed to wet the extensible structure to help in the stretching process.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: August 21, 2012
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Robert Braden, Anastasios John Hart, John Welch
  • Patent number: 8080197
    Abstract: The invention pertains to a method for manufacturing filaments from an optically anisotropic spinning solution in which the spinning solution is extruded through a spinneret including a spinning field with a plurality of spinning orifices into a coagulation bath through a slot or diaphragm, the edges thereof being formed by plates with upper and lower sides. The upper sides of the plates are defined as the sides having the shortest distance to the spinning field, wherein the line through the center of the spinning field and perpendicular to the upper sides is located a distance (d) from a parallel line through the center of the slot or diaphragm. The projection of the slot or diaphragm has about the same size and shape as the projection of the spinning field. The plane of the upper side of one plate has a shorter distance to the center of the spinning field than the plane of the upper side of the other plate, and the line has a smaller distance to the edge of plate than to edge of plate.
    Type: Grant
    Filed: January 18, 2003
    Date of Patent: December 20, 2011
    Assignee: Teijin Aramid B.V.
    Inventors: Johannes Jacobus Meerman, Wilhelmus Marie Roelofs
  • Publication number: 20110237539
    Abstract: Disclosed herein are spinning solutions and methods for manufacturing a biomaterial fiber. The spinning solution includes a biologically absorbable material having a haemostatic function, a polysaccharide selected from the group consisting of hyaluronic acid (HA) and gelatin, and a solvent, wherein the polysaccharide and the haemostatic material exist in a weight ratio between about 0.1 to about 3. The method includes steps of wet spinning the spinning solution into the biomaterial fiber.
    Type: Application
    Filed: March 26, 2010
    Publication date: September 29, 2011
    Applicant: TAIWAN TEXTILE RESEARCH INSTITUTE
    Inventors: Chan-Yi Yang, Jui-Sheng Lee, Chih-Kang Peng
  • Patent number: 7938999
    Abstract: An object of the present invention is to provide: a process for conveniently producing a fiber with high strength, regardless of molecular weight polymer composition, or the like of PHAs, which vary depending on origins such as a wild-type PHAs-producing microorganism product, a genetically modified strain product, and a chemical product; and the fiber with high strength produced through the process. The present invention provides: a process for producing a fiber, comprising: melt-extruding polyhydroxyalkanoic acid to form a melt-extruded fiber; rapidly quenching the melt-extruded fiber to the glass transition temperature of polyhydroxyalkanoic acid +15° C. or less, and solidifying the fiber to form an amorphous fiber; forming a crystalline fiber by leaving the amorphous fiber to stand at the glass transition temperature +15° C. or less; drawing the crystalline fiber; and further subjecting the crystalline fiber to stretch heat treatment.
    Type: Grant
    Filed: August 4, 2005
    Date of Patent: May 10, 2011
    Assignee: Riken
    Inventors: Tadahisa Iwata, Toshihisa Tanaka, Yoshiharu Doi
  • Publication number: 20110094526
    Abstract: The present invention concerns a biodegradable cigarette filter tow comprising composite filaments of cellulose and cellulose acetate, and a process for making such a filter tow comprising providing a solution dope comprising a blend of cellulose and cellulose acetate in an ionic liquid or in N-methylmorphilone-N-oxide (NMMO), and spinning casting the blend into a protic solvent to generate fibres or films, and converting the fibres or films into cigarette filter tow. The invention also concerns cigarette filters and cigarettes made from such a filter tow.
    Type: Application
    Filed: September 29, 2010
    Publication date: April 28, 2011
    Applicant: INNOVIA FILMS LIMITED
    Inventors: Colin MARSHALL, Jamie MOFFAT
  • Publication number: 20110089600
    Abstract: Disclosed are multicomponent fibers derived from a blend of a sulfopolyester with a water non-dispersible polymer wherein the as-spun denier is less than about 6 and wherein the water dispersible sulfopolyester exhibits a melt viscosity of less than 12,000 poise measured at 240° C. at a strain rate of 1 rad/sec, and wherein the sulfopolyester comprising less than about 25 mole % of residues of at least one sulfomonomer, based on the total moles of diacid or diol residues. The multicomponent fiber is capable of being drawn at a relatively high fiber speed, particularly at least about 2000 m/min, and may be used to produce microdenier fibers. Fibrous articles may be produced from the multicomponent fibers and microdenier fibers. Also disclosed is a process for multicomponent fibers, nonwoven fabrics, and microdenier webs.
    Type: Application
    Filed: December 22, 2010
    Publication date: April 21, 2011
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Rakesh Kumar Gupta, Scott Ellery George, Daniel William Klosiewicz, Kab Sik Seo, Coralie McKenna Fleenor, Allen Lynn Crain
  • Patent number: 7871946
    Abstract: A nonwoven fabric composed of ultra-fine continuous fibers having a mean fineness of not more than 0.5 dtex is prepared. The nonwoven fabric comprises a water-soluble thermoplastic resin in a proportion of not more than 5% by weight relative to the nonwoven fabric, has an absorbing height of not less than 30 mm as determined at 20° C. after 10 minutes based on Byreck method when the nonwoven fabric immersion-treated for 60 minutes in a water of 80° C. is used, and satisfies the following formula: (B)/(A)?0.25, wherein the symbol (B) represents a tensile strength [N/5 cm] in the longitudinal direction and the lateral direction of the nonwoven fabric and the symbol (A) represents a fabric weight [g/m] of the nonwoven fabric. In the nonwoven fabric, not less than 30% of the surface may be coated with the water-soluble thermoplastic resin. The water-soluble thermoplastic resin may be a water-soluble thermoplastic polyvinyl alcohol, e.g.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: January 18, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Takuya Tsujimoto, Naoki Fujiwara, Midori Okazaki, Nozomu Sugo
  • Publication number: 20100173102
    Abstract: The present invention relates to artificial grass composed of fibres comprising a core and a cladding, which core and which cladding are made of different materials, wherein the material for the cladding has a hydrophilicity which is different from the hydrophilicity of the material used for the core.
    Type: Application
    Filed: June 5, 2008
    Publication date: July 8, 2010
    Inventor: Peter Van Reijen
  • Publication number: 20100025892
    Abstract: A method of making a composite filter media includes, in an exemplary embodiment, forming a nonwoven fabric mat that includes a plurality of synthetic fibers by a spunbond process, and calendering the nonwoven fabric mat with embossing calender rolls to form a bond area pattern comprising a plurality of substantially parallel discontinuous lines of bond area to bond the synthetic fibers together to form a nonwoven fabric, the nonwoven fabric having a filtration efficiency of about 35% to less than 50%, measured in accordance with EN 1822 (1998) test procedure. The method also includes applying a nanofiber layer by electro-blown spinning a polymer solution to form a plurality of nanofibers on at least one side of the nonwoven fabric mat to form the composite filter media, the composite filter media having a minimum filtration efficiency of about 70%, measured in accordance with EN 1822 (1998) test procedure.
    Type: Application
    Filed: August 1, 2008
    Publication date: February 4, 2010
    Inventors: David Charles Jones, Hyun Sung Lim
  • Publication number: 20090206026
    Abstract: Disclosed are external pressure type hollow fiber membrane having a reinforcing supporter for gas separation and water treatment, and method and apparatus for preparing the same. The reinforcing supporter is woven only with mono-filaments or by mixed spinning of mono-filaments and multi-filaments. The hollow fiber membrane of the present invention has excellent pressure resistance and high tension force by using the rigid and tubular supporter, an improved softness by using the mono-filaments, and an increased bonding force between the supporter and the coating layer by increasing the concave-convexo degree of the reinforcing supporter. Additionally, the hollow fiber membrane can prevent detachment of the separating filtration layer, which is the coating layer, through the surface weight deduction treatment of the reinforcing supporter, and control the inner pore size of the membrane by treating the internal coagulating solution, thereby providing an excellent water-permeability.
    Type: Application
    Filed: July 18, 2003
    Publication date: August 20, 2009
    Inventors: Ho Sung Yoon, Sang Woo Park, Jin Hve Jung
  • Publication number: 20080271909
    Abstract: Described is an insulated non-halogenated, heavy metal free vehicular cable comprising an inner core of a copper based metal wire having a cross sectional area of at least about 0.1 mm2, and an outer insulation, covering the length of the inner core, comprised of a thermoplastic polyphenylene ether composition that has no halogen or heavy metal added thereto, the insulated cable capable of meeting the testing standard ISO 6722.
    Type: Application
    Filed: June 24, 2008
    Publication date: November 6, 2008
    Inventors: Raman V. Chiruvella, Leonard A. Weiner, Eugene W. Yeager, Daniel T. Quinlan, Paul J. Pawlikowski, Edward L. Monroe, Bruce D. Lawrence
  • Publication number: 20080227351
    Abstract: The cleansing polyester fabric of the present invention (AAA). The cleansing fabric of the present invention is useful as a makeup cleansing fabric or as a wiping fabric for precision products and optical devices since it exhibits excellent cleansing performance, is soft to the touch and does not damage the surface of a products to be cleansed.
    Type: Application
    Filed: December 22, 2004
    Publication date: September 18, 2008
    Inventors: Yang-Soo Park, Heung-Ryul Oh, Dong-Eun Lee
  • Publication number: 20080139065
    Abstract: A conductive thermoplastic composition capable of forming conductive fibers including monofilaments, methods of making these compositions, and fibers including these compositions. The conductive thermoplastic compositions may be formed using any method capable of forming the compositions into fibers. The fibers are substantially smooth and/or are capable of being woven into fabrics or other articles to provide conductive properties to the fabric or article. These fibers provide effective static charge dissipation that may be imparted into applications such conveying belts or protective clothing for clean room operation.
    Type: Application
    Filed: December 11, 2006
    Publication date: June 12, 2008
    Inventors: Jayantha Amarasekera, Bo Liu, Lowrence D. Lucco
  • Patent number: 7303710
    Abstract: The present invention relates to an apparatus and a method as well as a system for extruding continuously molded bodies for producing filaments or staple fibers from an extrusion solution, such as a cellulose solution containing water, cellulose and tertiary amine oxide such as N-methylmorpholine N-oxide. In comparison with the methods known from the prior art, profitability can be increased in the production of continuously molded bodies (3) if the extrusion rate v is set to a value v=B·T0.33·10,000·(1/r2). In a system, profitability can be enhanced if the number r of rows is r=[(B/v)·10,000·T0.33]1/2. T is here the fiber titer in T dtex, v the extrusion rate in m/min, r the number of the rows of extrusion duct orifices (12), and B an operational parameter which is not more than 4 and at least 0.5.
    Type: Grant
    Filed: April 25, 2001
    Date of Patent: December 4, 2007
    Assignee: Zimmer A.G.
    Inventors: Stefan Zikeli, Friedrich Ecker
  • Publication number: 20040099985
    Abstract: A process for forming flexible noise attenuating cutting line for use in rotary vegetation trimmers formed of at least two monofilament polymer strands bonded together in a twisted disposition or a single strand twisted about its central axis in which the strand or strands are extruded in a molten disposition through a single die that is rotated during the extruding step either to twist the two strands together about a central longitudinal axis or a single strand about its own longitudinal axis such that upon cooling, stretching and heating, a flexible noise attenuating line is created in a continuous online process.
    Type: Application
    Filed: November 14, 2003
    Publication date: May 27, 2004
    Inventors: Richard A. Proulx, William P. Conley, Rodger D. Thomason
  • Patent number: 6716523
    Abstract: A dispersant slurry for making spandex, based on phosphated block poly(alkylsiloxane)-poly(alkyleneether) alcohol or aromatic- or alkylaromatic-terminated phosphated poly(alkyleneether) alcohol dispersants, is provided.
    Type: Grant
    Filed: January 6, 2003
    Date of Patent: April 6, 2004
    Assignee: E. I. du Pont de Nemours and Co.
    Inventors: Thomas Edward Carney, Oliver Gutsche, Kai-Volker Schubert
  • Patent number: 6682677
    Abstract: Coagulation spinning produces structures such as fibers, ribbons, and yarns of carbon nanotubes. Stabilization, orientation, and shaping of spun materials are achieved by post-spinning processes. Advantages include the elimination of core-sheath effects due to carbonaceous contaminants, increasing mechanical properties, and eliminating dimensional instabilities in liquid electrolytes that previously prohibited the application of these spun materials in electrochemical devices. These advances enable the application of coagulation-spun carbon nanotube fibers, ribbons, and yarns in actuators, supercapacitors, and in devices for electrical energy harvesting.
    Type: Grant
    Filed: September 4, 2001
    Date of Patent: January 27, 2004
    Assignee: Honeywell International Inc.
    Inventors: Alex Lobovsky, Jim Matrunich, Mikhail Kozlov, Robert C. Morris, Ray H. Baughman, Anvar A. Zakhidov
  • Publication number: 20020084550
    Abstract: An oral brush is provided that includes an elongated body, a head portion extending from the body, and a plurality of bristles, formed of particular thermoplastic elastomers, extending from the body. In various embodiments, the thermoplastic elastomer has a Shore A hardness of at least 30; the thermoplastic elastomer is selected from the group consisting of polyetheramides, polyesters, styrene-ethylene-butylene-styrene block copolymers, polyurethanes, polyolefin elastomers, and mixtures thereof; and the thermoplastic elastomer has a flexural modulus of at least 5 MPa.
    Type: Application
    Filed: December 26, 2001
    Publication date: July 4, 2002
    Inventors: Michael Roberts, Thomas Craig Masterman, Edward H. Park, Scott Batson, Philip Sweeney, Mingchih M. Tseng, Stephen C. Witkus