Polyamide (e.g., Nylon, Etc.) Or Addition Polymer Of At Least One Monoethylenically Unsaturated Monomer (e.g., Polyethylene, Polypropylene, Polystyrene, Etc.) Containing Layer Patents (Class 264/173.14)
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Publication number: 20100304062Abstract: The present invention provides a uniaxially oriented multilayer film comprising at least (i) a layer (A) and (ii) a layer (B), wherein said layer (A) comprises a linear low density polyethylene (LLDPE) comprising (e.g. selected from):—a multimodal LLDPE produced using a Ziegler Natta catalyst (znLLDPE), or—a LLDPE produced using a single site catalyst (mLLDPE) or—a mixture of a mLLDPE and a multimodal znLLDPE, said layer (B) comprises a multimodal LLDPE, and said multilayer film is in the form of a stretched film which is uniaxially oriented in the machine direction (MD) in a draw ratio of at least 1:3.Type: ApplicationFiled: December 19, 2007Publication date: December 2, 2010Inventors: Hans Georg Daviknes, Ole Jan Myhre
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Publication number: 20100269455Abstract: The invention is directed to a composition suitable for use in a single-sided stretch cling film, the composition having from 0.1 to 20 percent by weight of a propylene-based copolymer having substantially isotactic propylene sequences, and having from 80 to 99 percent by weight of an ethylene-based copolymer having a density of at least 0.905 g/cc, wherein a film made from the composition exhibits cling layer to release layer cling of at least 70 grams force per inch as measured by ASTM D-5458-95, noise levels of less than 87 dB during unwinding operations, and has a modulus of at least 3 MPA as determined by ASTM D-882.Type: ApplicationFiled: May 24, 2010Publication date: October 28, 2010Inventors: Shaun Parkinson, Jesus Nieto, Andreas Mayer, Pascal E.R.E.J. Lakeman
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Patent number: 7678444Abstract: The present invention provides articles comprising a thermoformable composite comprising: a core comprising a renewable polymer having: (a) a Ts value of up to about 90° C.; and (b) a heat distortion index of up to about 90° C.; and a heat-resistant outer layer substantially surrounding the core and comprising a heat-resistant polymer having: (a) a Ts of greater than about 60° C.; and (b) a heat distortion index of greater than about 50° C.; wherein the renewable polymer comprises at least about 60% by weight of the composite, and wherein the heat-resistant polymer has a Ts value and heat distortion index greater than that of the renewable polymer. The present invention also provides methods for coextruding the heat-resistant polymer outer layer and renewable polymer core to provide a thermoformable composite.Type: GrantFiled: December 17, 2007Date of Patent: March 16, 2010Assignee: International Paper CompanyInventors: Richard A. Tedford, Jr., Wei Li
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Patent number: 7674421Abstract: A guide catheter shaft is formed from an inner tube structure and a multilayer sheath around the inner tube structure. The multilayer sheath includes an intermediate sheath and a shrink tube layer. The intermediate sheath is disposed around the inner tube and realized from a melt-processible first polyether-block amide material. The shrink tube layer is disposed around the intermediate sheath and realized from a different second polyether-block amide (e.g. a cross-linked polyether-block amide material) having a shrink temperature range greater than a melt temperature range of the first polyether-block amide material. The resulting structure is heated at a temperature within the shrink temperature range such that the outer shrink tube layer shrinks and the intermediate layer melts to thereby bond the multilayer sheath to the inner tube.Type: GrantFiled: December 11, 2007Date of Patent: March 9, 2010Assignee: Engineering Resources Group, Inc.Inventor: Christopher Daniel Ross
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Publication number: 20100028664Abstract: The invention relates to the self-adhesive material of hydrogenated block copolymers or a mixture thereof, comprising polymer blocks of vinyl aromatics (A-blocks) and such made by polymerization of 1,3 dienes (B-blocks), mixing the self-adhesive material with 10 to 80 parts per weight, preferably with 10 to 40 parts per weight polyisobutylene with an average molecular weight Mw in relation to 100 parts by weight Mw of the blockcopolymeres.Type: ApplicationFiled: August 3, 2007Publication date: February 4, 2010Applicant: TESA AGInventors: Nicolai Böhm, Michael Janning, Andreas Hagemann, Domenico Boccuto
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Patent number: 7588706Abstract: A method of improving hot tack and/or seal strength in a multi-layer film by selecting a first PE comprising at least one of mPE, LDPE or LLDPE to form a first layer and selecting a blend comprising a mPE and a PP to form an outer layer; and coextruding the first PE and the blend to form the multi-layer film comprising the first layer and the outer layer; wherein the inner layer comprises at least one component having a final melting point at least about 15° C. higher than a final melting point of at least one component of the first layer, wherein the multi-layer film has a maximum hot tack at least about 25% greater than a similar multi-layer film with 0-weight % of the PP in the inner layer.Type: GrantFiled: December 16, 2004Date of Patent: September 15, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Achiel Jos Van Loon, Marc D. Tierens, Dirk J. Permentier
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Patent number: 7524447Abstract: One method for making a laminate material comprising a first surface layer comprising resorcinol arylate polyester chain members and a second surface layer suitable for bonding to a substrate, comprises co-extruding a polymeric first surface layer material and a polymeric second surface layer material through a die and into the first nip of a calender roll stack comprising a first surface roll and a second surface roll that define the first nip, to form the laminate material. A nip load in the first nip of greater than or equal to about 400 N/cm can be applied to the laminate, and the laminate material can be collected from the roll stack. The first roll and the second roll can each have a surface smoothness of less than or equal to about 5 micrometers and temperatures of about 40° C. to about 150° C.Type: GrantFiled: July 20, 2004Date of Patent: April 28, 2009Assignee: Sabic Innovative Plastics IP B.V.Inventors: Himanshu Asthana, M. Shoen Davis, Hari K. Harikumar, Martin J. Lindway, Aniruddha Moitra, Chetan J. Parikh, Om Prakash, Michael T. Roland, Robert A. Schiff, Robert W. Walker, Georgios S. Zafiris
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Publication number: 20090084787Abstract: The present invention provides a packaging container in which the innertape can tightly seal an opening section provided on a top wall surface of the container from the under side, and also can easily and sharply be broken at a position near an edge portion of the opening section when the pull-tab is pealed off in association with an operation for unsealing the opening section, a method of producing the innertape for the packaging containers, and an innertape for the containers.Type: ApplicationFiled: July 10, 2006Publication date: April 2, 2009Applicant: TETRA LAVAL HOLDINGS & FINANCE S.A.Inventor: Tadakatsu Ikenoya
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Publication number: 20090045543Abstract: The present invention relates to methods of manufacturing multi-layered polyolefin films that provide excellent adhesion to cold seal cohesive formulations. A surface of the film is discharge-treated. It has been found that when the discharge-treated surface has at least 0.3% nitrogen functional groups, it provides an excellent cold seal receptive surface. A biaxially oriented polypropylene film made according the invention may also have a second skin layer, opposite the first layer, which may be used for metallizing, laminating, or printing.Type: ApplicationFiled: October 13, 2008Publication date: February 19, 2009Applicant: TORAY PLASTICS (AMERICA), INC.Inventors: Mark S. LEE, Keunsuk P. Chang
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Patent number: 7479322Abstract: A radiation-curable composite layered sheet or film comprising at least one substrate layer and one outer layer, said outer layer being composed of a radiation-curable composition having a glass transition temperature of more than 40° C.Type: GrantFiled: March 26, 2007Date of Patent: January 20, 2009Assignees: BASF Aktiengesellschaft, DaimlerChrysler AGInventors: Rainer Koeniger, Erich Beck, Achim Grefenstein, Reinhold Schwalm, Margit Veeh, Claudia Vogel, Walter Aichholzer, Thomas Gruber, Karl Holdik
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Publication number: 20080280117Abstract: Coextruded blown films comprising coextruded layers of polylactic acid bioresin and polyolefins. Also, a method for making the coextruded blown films.Type: ApplicationFiled: March 10, 2008Publication date: November 13, 2008Inventors: Robert Knoll, Brian Muehl, Michael Stecker
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Patent number: 7442333Abstract: The invention relates to a method for the production of polyamide nanocomposites made from base polymers comprising aromatic components and organically-modified phyllosilicates in a double-screw extruder with a front-feeder and a side-feeder. Said method is characterised in that a portion (A) from 8 to 15 wt. % of a granulate of the base polymer is introduced in the front-feeder of the double-screw extruder and the main portion (B) of said granulate of the base polymer is introduced by means of the side feeder of the double-screw extruder and that 2 to 8 wt. % of the modified phyllosilicate is introduced into the melt of the granulate portion (A) of the base polymer, whereby the wt. % proportions relate to the finished polyamide nanocomposite. According to the invention, packaging materials with high UV absorption and improved gas and aroma barrier effect can be produced by said method. Furthermore, the corresponding packagings the use thereof and moulded bodies produced by means of said method are disclosed.Type: GrantFiled: January 30, 2003Date of Patent: October 28, 2008Assignee: EMS-Chemie AGInventors: Ulrich Presenz, André Marcus Sutter
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Patent number: 7413624Abstract: The present invention relates to a method for making a multilayer article, wherein said multilayer article comprises: (i) a first layer comprising an acrylic resin; (ii) at least one translucent second layer comprising (a) an acrylic resin, optionally further comprising an impact modifier; (b) a rubber modified thermoplastic resin composition; (c) optionally a rheology modifier; and (d) a visual effects additive; (iii) a third layer comprising an acrylonitrile-butadiene-styrene (ABS) resin; and (iv) an optional backing layer comprising either a thermosetting polymer substrate, optionally fiber-reinforced, or glass filled ABS resin; and wherein said method comprises the steps of: (I) drying the components of the second layer, either individually or in combination, to a volatiles content of less than 0.06 weight % prior to processing a mixture comprising said components to form said second layer; and (II) coextruding the second and third layers, and optionally the first layer to form the multilayer article.Type: GrantFiled: April 21, 2005Date of Patent: August 19, 2008Assignee: SABIC Innovative Plastics IP B.V.Inventors: Sandeep Dhawan, Douglas W. Howie, Jr.
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Patent number: 7405008Abstract: The present invention includes a laminate and formation of a laminate having at least one layer of an ionomer and at least one layer of an acid polymer or blend of acid polymer and a thermoplastic polyolefin that can be thermoformed to form a shaped laminate. The shaped laminate can then be contacted with a plastic substrate such as a thermoplastic polyolefin to form a composite article by such means as, for example, injection molding. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Impact and scratch resistant articles can be formed from the laminated substrate such as automotive parts, appliance body parts and sporting equipment.Type: GrantFiled: May 31, 2005Date of Patent: July 29, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Joseph D. Domine, Jeffrey Valentage, Prasadarao Meka
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Patent number: 7390445Abstract: A method of producing a composite sheet having a foam layer of a first polyolefin-based resin and a surface layer of a second polyolefin-based resin provided on at least one side of the foam layer and containing a polymeric antistatic agent. The method includes coextruding through die a first melt containing the first polyolefin-based resin and a physical blowing agent and a second melt containing the second polyolefin-based resin, the polymeric antistatic agent and a volatile plasticizer to obtain the composite sheet. The amount of the polymeric antistatic agent is 4 to 100 parts by weight per 100 parts by weight of the second polyolefin-based resin and the amount of the volatile plasticizer is 5 to 50 parts by weight per 100 parts by weight of a total amount of the second polyolefin-based resin and the polymeric antistatic agent. The second polyolefin-based resin has a crystallization temperature of Ta [° C.Type: GrantFiled: June 21, 2004Date of Patent: June 24, 2008Assignee: JSP CorporationInventors: Kazuhiko Morita, Satoshi Iwasaki, Shinpei Arita
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Patent number: 7387837Abstract: The present invention provides a thermoplastic polyurethane composition which comprises an ethylene-vinyl alcohol copolymer and/or a polyamide, and a thermoplastic polyurethane, in which the retention of melt tension thereof, when kept in a molten state at 220° C. for 1 hour, determined by the following equation (1), is not less than 10%. Retention of melt tension (%)=[Melt tension after being kept in a molten state/Melt tension before being kept in a molten state]×100??(1) The thermoplastic polyurethane composition of the present invention is excellent in production stability of a molded article, and can provide a molded article excellent in appearance because the progress of gelation thereof is suppressed even in a molten state.Type: GrantFiled: April 7, 2006Date of Patent: June 17, 2008Assignee: Kuraray Co., Ltd.Inventors: Yoshihiro Yamana, Hiroyuki Ono
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Publication number: 20080113130Abstract: Compositions and packaging films are provided having a blend of an amorphous nylon copolymer, a low temperature polyamide, and a high temperature polyamide. The compositions can be used in making heat shrinkable films and food packages having desirable levels of free shrink.Type: ApplicationFiled: December 9, 2005Publication date: May 15, 2008Inventors: Thomas Andrew Schell, Matt C. Peterka
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Publication number: 20080081183Abstract: An blow-extrudable film that ensures a reclosing ability after a first opening consists of a support layer on which a connecting layer and an overlying cover layer are arranged. The connecting layer essentially consists of a pressure sensitive hot melt adhesive. Both the support layer and the cover layer are essentially composed of polyethylene. The support layer may e.g. be made of low density and/or high density polyethylene (LD-PE respectively HD-PE). The cover layer consists of up to 100% LLD-PE (linear low density polyethylene) or of a blend of LLD-PE and polyethylene. Due to the LLD-PE content, the cover layer has a higher adhesion on the connecting layer than the support layer. In this manner it is ensured that in the first opening process, during which a portion of the support layer is separated, the connecting layer remains on the cover layer.Type: ApplicationFiled: October 3, 2006Publication date: April 3, 2008Inventor: Jurjen DE BOER
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Patent number: 7335424Abstract: A co-extruded laminate of at least one layer of an ionomer and at least one layer of an acid polymer that can be thermoformed with a plastic substrate such as a polyolefin. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Articles can be formed from the laminated substrate such as automotive parts and sporting equipment.Type: GrantFiled: May 31, 2005Date of Patent: February 26, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Joseph D. Domine, Jeffrey Valentage, Prasadarao Meka
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Patent number: 7273653Abstract: A resin film of a two-layer-construction comprising: (a) a resin layer R1 including a non-stretched resin film which contains a thermoplastic polyester resin containing 3 to 30 percent by weight in a weight fraction in the entire resin of a granular resin with a grain diameter of 0.1 to 5 ?m, the granular resin being a modified polyolefin resin containing 2 to 20 percent by weight of a functional group derived from carboxylic acid in terms of carboxylic acid, and (b) a polyester resin layer R0 containing at least one of polyethylene terephthalate and isophthalic acid copolymerized polyethylene terephthalate, as a basic skeleton, wherein the resin layer R1 and the resin layer R2 are laminated to each other.Type: GrantFiled: November 18, 2005Date of Patent: September 25, 2007Assignee: JFE Steel CorporationInventors: Yasuhide Yoshida, Hiroki Iwasa, Hiroshi Kubo, Takeshi Suzuki, Akihiro Furuta, Keiji Sugawara, Masaaki Yamashita
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Patent number: 7264884Abstract: A stretch film presenting controlled permeability to gases, manufactured by process of balloon co-extrusion and consisting of outer layers (S2) of stretchable polmeric material and by one or two inner barrier layers (S3) of a EVOH based polymeric matrix, which is made stretchable by the addition of a suitable plasticizer in such a percentage as to conciliate the stretchablity with the desired barrier effect, said layers of different material being reciprocally secured by means of layers (S4) of adhesive material. The polymeric matrix which forms the barrier material and the plasticizer are intimately mixed inside a double-screw corotating extruder, immediately before the phase of co-extrusion, through a premelting of the polymeric matrix and the subsequent injection of the plasticizer in liquid phase.Type: GrantFiled: December 21, 2001Date of Patent: September 4, 2007Assignee: A.W.A.X. Progettazione e RicercaInventors: Renato Rimondi, Angelo Cappi, Carlo Nicoletti
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Publication number: 20070194482Abstract: A process for preparing a multi-layer roofing or structural membrane is provided including a top sheet including co-extruding a cap and inner layer and bonding the top sheet to a bottom sheet. The use of the co-extrusion process allows for multi-layer sheets that reduce the need for expensive fillers in all but a cap layer of the membrane. A scrim reinforcement layer is optionally embedded in the membrane. When installed on a roof substrate, the membrane can be sealed by heat welding the seams of the membrane sheets or by other means.Type: ApplicationFiled: February 21, 2007Publication date: August 23, 2007Inventors: Bruce Douglas, Greg Sharrun, Richard Peng
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Patent number: 7179521Abstract: A multilayer shrink film and methods of making same comprising high speed polyethylenic outer layers along with one or more cyclic-olefin copolymer (COC) containing inner layers. The multilayer shrink films of the invention are produced using film biaxial orienting means, have haze values of 5 or less and Young's modulus of 50,000 psi or greater and superior hot slip properties. In order to achieve the desired modulus, films of the present invention comprise from 10% to 30% COC and from 2% to 25% softening olefin copolymer. Preferably the film comprises large proportion of linear low density polyethylene (LLDPE). Suitable COCs for use in the invention are limited to single site catalyzed COC.Type: GrantFiled: March 3, 2004Date of Patent: February 20, 2007Assignee: Central Products CompanyInventors: Trevor Arthurs, Shane Taghavi
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Patent number: 7144542Abstract: The invention relates to the use of a biaxially oriented polyolefin film as a label film. The inventive film consists of a base layer and at least one cover layer. Said cover layer contains as the main component a copolymer or terpolymer consisting of one alkene and unsaturated carboxylic acids or the esters thereof and low amounts of an additive. The cover layer is characterized by excellent and divers adhesion to various polymer materials from which containers are formed. It is no longer necessary to apply adhesives, primers, coatings etc. in a separate step after production of the film.Type: GrantFiled: December 5, 2001Date of Patent: December 5, 2006Assignee: Trespaphan GmbHInventors: Susanne Holzer, Gerhard Wieners, Albert Lauer
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Patent number: 7132073Abstract: The present invention is to provide a method of producing multilayer laminates comprising a polyamide and a fluorine-containing ethylenic polymer laminated together and being excellent in interlayer adhesion strength by multilayer coextrusion in an easy and simple manner without need of any additional step or without being limited to some or other particular adhesive material. The present invention is a production method of a multilayer laminate which comprises laminating at least a polyamide (A) and a fluorine-containing ethylenic polymer (B) by simultaneous multilayer coextrusion using a coextrusion apparatus to obtain the laminate comprising said polyamide (A) and said fluorine-containing ethylenic polymer (B), said coextrusion apparatus comprising a die and a plurality of extruders for feeding resins to said die, and the temperature of said die being set within the range exceeding 260° C. but not higher than 310° C.Type: GrantFiled: March 23, 2001Date of Patent: November 7, 2006Assignee: Daikin Industries, Ltd.Inventors: Takeshi Inaba, Masakatsu Kitano
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Patent number: 7063889Abstract: [Problem] The object is to provide a resin film for metal sheet laminate which endures severe forming owing to excellent formability and impact resistance, and also to excellent adhesion after forming and heating, further gives stable performance independent of forming conditions, and also provides a laminated metal sheet, and a method for manufacturing the same. [Means for Resolution] The resin film for metal sheet laminate has a mixed resin in which a granular resin mainly existing in a state of grains having 0.1 to 5 ?m in diameter is dispersed in a polyester resin having a main basic skeleton of polyethylene terephthalate and/or isophthalic acid copolymerized polyethylene terephthalate, in a range from 3 to 30% by weight in entire resin. The granular resin is a modified polyolefin resin containing a functional group derived from carboxylic acid in a range from 2 to 20% by weight as carboxylic acid.Type: GrantFiled: September 18, 2003Date of Patent: June 20, 2006Assignee: JFE Steel CorporationInventors: Yasuhide Yoshida, Hiroki Iwasa, Hiroshi Kubo, Takeshi Suzuki, Akihiko Furuta, Keiji Sugawara, Masaaki Yamashita
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Patent number: 7041243Abstract: The invention discloses a 5-layer co-extruded biaxial-oriented polypropylene synthetic paper which is a 5-layer laminated structure with thickness between 30–300 ?m comprising the uppermost layer (A) of paper sheet or resin, the second layer (B) of paper sheet or resin, the intermediate foamed layer (C), the forth layer (D) of paper sheet or resin and the bottom layer (E) of paper sheet or resin which is to improve the rigidity and stiffness covering power, strength between layers, glossiness of paper surface, paper thickness and the printability of the conventional synthetic paper.Type: GrantFiled: November 28, 2003Date of Patent: May 9, 2006Assignee: Nan Ya Plastics Corp.Inventor: Allen Fong-Chin Lin
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Patent number: 6982106Abstract: Multilayer polymer structures comprising a layer (A) based on at least one halohydrocarbon polymer linked to a layer (C) based on at least one olefin polymer via a layer (B) containing from 100% to 10% by weight of at least one grafted olefin polymer and from 0 to 90% by weight of at least one halohydrocarbon polymer, the grafted olefin polymer being obtained by grafting a polymerizable monomer, a functional oligomer or a functional telomer onto a preactivated olefin polymer; process for obtaining them and use thereof.Type: GrantFiled: December 18, 2001Date of Patent: January 3, 2006Assignee: SOLVAY (Societe Anonyme)Inventors: Vincent Bodart, Jean-Marie Oreins, Guy Laurent, Fredy Declerck, Alexandra Malinova, Nadia Torres, Bernard Boutevin
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Patent number: 6958193Abstract: A laminated polyolefin film with two or more layers is produced by coextrusion. An outer-layer forming material is prepared by with olefin resin containing specified kinds of non-ionic surfactant and salt of organic sulfonic acid in a specified amount and at a specified ratio. In the production of the laminated polyolefin film by coextrusion, this outer-layer forming material is used to form either one or both of the outer layers if the laminated film is to have three or more layers and to form only one of the outer layers if the laminated film is to have only two layers.Type: GrantFiled: May 30, 2003Date of Patent: October 25, 2005Assignee: Takemoto Yushi Kabushiki KaishaInventors: Yukiyasu Itaya, Michiya Hiei, Toshiya Kamei
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Patent number: 6824864Abstract: The present invention relates to bioriented polyethylene films having high water vapor transmission rates (WVTR) and methods for preparing the same. The film comprises a base layer and skin layers. The base layer comprises highly cavitated polyethylene, such as medium density polyethylene (MDPE) or high density polyethylene (HDPE). The cavitating agent in the base layer may be calcium carbonate. At least one skin layer comprises (i) a copolymer of ethylene and at least one other monomer and (ii) a hydrocarbon resin, such as a cyclopentadiene resin. This copolymer (i) may be an ethylene-propylene copolymer or an ethylene-propylene-butene-1 terpolymer. The film may have unidirectional tear properties in the machine direction. This film is particularly useful for packaging food products, such as pieces of candy.Type: GrantFiled: October 23, 2001Date of Patent: November 30, 2004Assignee: ExxonMobil Oil CorporationInventor: Michael John Bader
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Patent number: 6793859Abstract: In one aspect, the invention provides an image receptor medium which comprises an extruded image receptive layer that is receptive to solvent-based inkjet ink. Image receptive layers of the invention comprise a blend of an ink absorptive resin and a carrier resin. The ink absorptive resin is compatible with the carrier resin and had a Hildebrand Solubility Parameter within about 3.1 (MPa)1/2 of that of the solvent of the ink. In another aspect, the invention provides an image receptor medium which comprises a coextruded or extrusion coated image receptive layer and a core layer bonded together. In other aspects, the invention provides methods of printing images and methods of making an extrusion coated or coextruded image receptor medium.Type: GrantFiled: May 20, 2003Date of Patent: September 21, 2004Assignee: 3M Innovative Properties CompanyInventors: Jeffrey O. Emslander, David J. Kinning, Diane L. Regnier, Caroline M. Ylitalo
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Patent number: 6790405Abstract: An embossed, cast polyolefin film or an embossed, oriented polyolefin film includes: (a) a core layer including a propylene polymer; (b) an embossed outer layer on one side of the core layer, the embossed outer layer including an olefin polymer capable of being embossed; and (c) an additional outer layer on a side of the core layer opposite to the embossed outer layer, the additional outer layer including an olefin polymer. The embossed film can then be metallized to produce a shiny, metallic film having a prismatic or holographic appearance.Type: GrantFiled: December 5, 2001Date of Patent: September 14, 2004Assignee: ExxonMobil Oil CorporationInventors: Robert Andrew Migliorini, Christopher Nothnagle, Salvatore James Pellingra, Jr.
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Publication number: 20040173944Abstract: Methods of making multilayer structures useful for packaging bone-in meat or other like products are provided. More specifically, the multilayer structures made by the methods provided have sufficient rigidity and strength to contain bone-in meat or other like products, while also maintaining good oxygen barrier properties. In addition, the multilayer structures made by the methods provided can easily seal to themselves or to other structures to provide the packages for the products. Moreover, the multilayer structures made by the methods provided may be biaxially oriented and heat-shrinkable.Type: ApplicationFiled: December 12, 2003Publication date: September 9, 2004Inventors: Chad D. Mueller, Michael J. Douglas, Duane H. Buelow, Robert J. Blemberg, Roberto P. Castellani
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Publication number: 20040164444Abstract: This invention relates to a process for making an image-recording element, for example a dye-receiving element for thermal dye transfer, that includes a support having on one side thereof a image-receiving layer and, between the image-receiving layer and the support, a tie layer comprising a thermoplastic antistat polymer. In one embodiment, the process comprises (a) forming a first melt of a polymer for the surface layer and a second melt comprising a thermoplastic antistat polymer in a polymeric binder; (b) coextruding the two melts onto a polyolefin support; (c) stretching the coextruded layers to reduce the thickness; (d) applying the coextruded melts to a support while simultaneously reducing the temperature below the Tg of the composition of the surface layer.Type: ApplicationFiled: February 26, 2003Publication date: August 26, 2004Applicant: Eastman Kodak CompanyInventors: Eric E. Arrington, Thomas M. Laney
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Patent number: 6780373Abstract: A film includes a core layer including a polyamide; two intermediate layers, disposed on opposite surfaces of the core layer, including an adhesive; and two outer layers, each disposed on a surface of the respective intermediate layer, comprising an ethylene/alpha olefin copolymer; wherein the two outer layers each constitute at least 27% of the total thickness of the film. The core layer can include either a single polyamide layer, or three layers wherein two layers of polyamide have therebetween a layer comprising a polymeric adhesive. The film is made preferably by a hot blown process at a blow up ratio of between 2.0:1 and 3.0:1. A process and package are also described.Type: GrantFiled: August 15, 1997Date of Patent: August 24, 2004Assignee: Cryovac, Inc.Inventor: Carlo E. Musco
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Patent number: 6773775Abstract: A multilayer sealant film for use in the medical field at least comprises as its innermost layer a first layer comprising at least one resin selected from the group consisting of linear low-density polyethylene, low-density polyethylene, polypropylene and polybutene-1, and a third layer comprising an ethylene-vinyl alcohol copolymer and laminated to the outer side of the first layer with a second layer serving as an adhesive layer and comprising a resin containing, as a main component, at least one of an amorphous polyolefin, adherent polyolefin and ethylene-vinyl acetate copolymer. The ethylene-vinyl alcohol copolymer forming the third layer functions as a barrier for preventing contaminants from migrating from outside of the third layer toward the first layer (innermost layer). Further, it is possible to improve the formability of the multilayer film since the difference in density between the resin for forming the first layer and the resin for forming the second layer is set to be 0.02 g/cm3 or less.Type: GrantFiled: December 30, 2002Date of Patent: August 10, 2004Assignee: Otsuka Pharmaceutical Factory, Inc.Inventors: Fujio Inoue, Masamitsu Izumi, Shigetoshi Kashiyama
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Patent number: 6767618Abstract: A multi-layered stretched resin film comprises a base layer (A) comprising more than 90 wt % of a polyolefinic resin and less than 10 wt % of an inorganic fine powder and/or an organic filler; and an amorphous resin-containing layer (B), comprising 0 to 85 wt % of a second polyolefinic resin, which may be the same or different than the first polyolefinic resin, and 15 to 100 wt % of an amorphous resin. The amorphous resin-containing layer (B) is disposed on at least one side of the base layer (A), and has a porosity of 5% or less. Such multi-layered stretched resin films are resistant to waving or curling caused by exposure to the vehicle component of offset printing inks during offset printing, and therefore have excellent printing properties.Type: GrantFiled: February 4, 2002Date of Patent: July 27, 2004Assignee: Yupo CorporationInventors: Atsushi Ishige, Kazuhisa Kitamura
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Publication number: 20040099986Abstract: An inflatable cushioning article is made by a process of extruding two multilayer films (or extruding one film which is either annular or folded over) each having (a) a seal layer, (b) a tie layer containing an anhydride modified olefin polymer containing anhydride at a level of at least 150 ppm, based on the weight of the modified olefin polymer, and (c) an oxygen barrier layer comprising crystalline polyamide, crystalline polyester, ethylene/vinyl alcohol copolymer, polyacrylonitrile, and/or crystalline polycycloolefin. Selected portions of the films are heat sealed to one another in a selected area providing a heat seal pattern which leaves inflatable chambers between the films, whereby an inflatable cellular cushioning article is produced. At some point after extrusion, at least one of the multilayer films are aged for a time and at a temperature in accordance with at least one member selected from the group consisting of: (i) 141° F. to 250° F. for a period of at least 1 second; (ii) 101° F.Type: ApplicationFiled: August 26, 2003Publication date: May 27, 2004Inventors: Charles Kannankeril, Robert O'Dowd
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Patent number: 6740412Abstract: Polymeric adhesive comprising a homogeneous mixture of at least three constituents: (a) at least one thermoplastic halogenated hydrocarbon polymer, (b) at least one copolymer of monoethylenic monomers which carry an alkyl carboxylate functional group and (c) at least one alpha-olefin polymer modified by the incorporation of at least one functional group chosen from a carboxyl, an acid anhydride, a hydroxyl and an epoxide. Process for the preparation of this polymeric adhesive and use of this polymeric adhesive in the preparation of structures with multiple polymeric layers. Structures with multiple polymeric layers comprising a layer (A) based on thermoplastic halogenated hydrocarbon polymer bonded to a layer (C) based on thermoplastic nonhalogenated polymer incompatible with (A) via a layer (B) based on this polymeric adhesive.Type: GrantFiled: July 9, 2001Date of Patent: May 25, 2004Assignee: Solvay (Societe Anonyme)Inventors: Jean-Marie Oreins, Vincent Thulliez, Guy Laurent, Fredy Declerck
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Publication number: 20040084803Abstract: A three-layer microwavable, plastic wrap having a core layer between a cling layer and a release layer. The cling layer comprises a base resin and an effective amount of a hydrocarbon tackifier to provide sufficient cling to different surfaces such as aluininum, stainless steel, ceramic, plastic and laninated cardboard. The release layer includes an effective amount of an anti-blocking agent to facilitate dispensing of the wrap from a dispensing roll.Type: ApplicationFiled: October 28, 2003Publication date: May 6, 2004Inventor: Douglas D. Bonke
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Patent number: 6713165Abstract: Multilayer structure based on thermoplastic polymers which is substantially devoid of vinyl chloride polymers and of plasticizers of low molecular mass and which comprises at least 3 layers: a first layer (A) comprising at least 60% by weight of at least one polyolefin of controllable crystallinity defined as comprising at least 90% of ethylene, of propylene or of butene and as having a softening temperature of less than 121° C., the thickness of the first layer being at least 20% of the total thickness of the structure and the first layer having a modulus of elasticity of less than 350 MPa; a second layer (B), positioned between the first layer (A) and the third layer (C), comprising at least 40% by weight of at least one polyolefin of controllable crystallinity, the second layer having an overall softening temperature of less than 121° C.Type: GrantFiled: July 16, 2002Date of Patent: March 30, 2004Assignee: Solvay (Societe Anonyme)Inventor: Petrus J. A. Karsten
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Publication number: 20040051198Abstract: A method of manufacturing a lamination product having a barrier property, the method comprising the steps of:Type: ApplicationFiled: June 30, 2003Publication date: March 18, 2004Inventors: Kazuki Yamada, Hirotaka Tsunoda, Hideki Kurokawa, Noriyuki Shiina, Syoji Yamato
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Patent number: 6706413Abstract: The present invention is a non-porous, breathable membrane of at least polyamide-4,6, with an elongation at rupture of about 250 to about 500% in the longitudinal direction and about 200 to about 500% in the transverse direction. The membrane has a higher heat resistance than a non-porous, breathable membrane made from polyether ester and, if it also contains an antioxidant, passes the oven/watertightness test. If the membrane is produced from a mixture of polyamide-4,6 and about 10 to about 30% by weight polyether amide, the membrane exhibits a surprisingly increased water-vapor permeability. The membrane is usable in the manufacture of thermally protective clothing.Type: GrantFiled: April 3, 2002Date of Patent: March 16, 2004Assignee: Sympatex Technologies GmbHInventors: Bertram R. Böhringer, Henricus Joannes Maria Van De Ven, Jozef Christiaan Wilhelmus Spijkers
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Patent number: 6676871Abstract: The invention concerns a method for producing a microporous film with strong isotropic tendency permeable to gases and impermeable to aqueous liquids, consisting of at least one layer, comprising the following successive steps: preparing a mixture consisting of a polyolefin matrix containing at least a polymer and at least a mineral and/or organic filler; extruding at least a ply by hot-casting the mixture; pre-stretching the ply with a drag roll; cooling and solidifying the pre-stretched ply, using the drag roll; drawing the solidified ply at sufficient temperature for forming the microporous film.Type: GrantFiled: January 24, 2001Date of Patent: January 13, 2004Assignee: Ace S.A.Inventors: Guy Benassi, Christian Dubouchet, Michel Gillet, Guy Pinchard
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Patent number: 6638636Abstract: A breathable multilayer film having a breathable core layer and at least one skin layer is disclosed. The core layer prepared by from a mixture containing a thermoplastic polymer and a particulate filler and the skin layer or layers are prepared from a mixture of at least two incompatible polymers and a polymer which compatiblizes the incompatible polymers. The addition of the compatiblizer in the skin layer improves the film forming consistency. In addition, the core layer contains voids around the particulate filler and the skin layer or layer has cracks or voids, which provides breathability to the multilayer film. Stretching of the film after the layers are coextruded together forms the voids and/or cracks.Type: GrantFiled: August 28, 2001Date of Patent: October 28, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventor: John David Tucker
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Patent number: 6620278Abstract: A method of forming tubular irrigation drip tape includes the steps of a) extruding a web of material having a pair of longitudinally extending, substantially parallel marginal edges; b) heating a center area of the web between and substantially parallel to the marginal edges utilizing a first focused infrared heating device; c) applying one or more secondary flow path components to the center area; d) heating the marginal edges, utilizing a second and third focused infrared heating device; e) folding the web such that the marginal edges overlap to form a seam; and f) applying pressure to the seam.Type: GrantFiled: November 9, 2000Date of Patent: September 16, 2003Assignee: Nelson Irrigation CorporationInventors: Charles R. Harrold, Theodore J. Bren
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Patent number: 6602455Abstract: A bi-axially oriented, heat-shrinkable multi-layer film comprising a core layer (A) comprising an ethylene-vinyl alcohol copolymer (EVOH), a first outer layer (B) comprising an ethylene homo- or co-polymer and a second outer layer (C), which may be equal to or different from the first outer layer (B), comprising an ethylene homo- or co-polymer, characterized in that said film has been bi-axially oriented at an orientation ratio in the longitudinal direction higher than 4:1, preferably higher than 4.5:1, more preferably of at least 5:1 and at an orientation ratio in the cross-wise direction higher than 4:1, preferably higher than 4.5:1, more preferably of at least 5:1, is obtained by a process which comprises melt extrusion of the film polymers through a flat die and orientation of the obtained cast sheet simultaneously in the longitudinal and the transversal directions by a simultaneous tenter.Type: GrantFiled: August 16, 2001Date of Patent: August 5, 2003Assignee: Cryovac, Inc.Inventor: Roberto Forloni
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Patent number: 6599453Abstract: A process for fabricating biaxially oriented polypropylene to modify the properties of polypropylene through treatment of flame is disclosed. The surface tension and the planarity of the polypropylene films is improved after adjusting the composition of the polypropylene and treating the polypropylene films with flame. The polypropylene products through the treatment process have good lamination strength for water-based inks and good adherence with aluminum foils. The requirements of the process for fabricating the polypropylene is illustrated following: 1. The surface for future printing and electroplating is heated by flame. 2. The flame comes from the combustion of a liquid natural gas which contains more than 85% of methane. 3. The flame has following properties: (1) polrization voltage: 0.1-0.8 KV, optimal voltage: 0.2 KV. (2) The temperature of cooling cylinders : 20-50° C., optimal temperature 25° C. (3) The temperature of flame : 700-900° C., optimal temperature 760° C.Type: GrantFiled: September 21, 2000Date of Patent: July 29, 2003Assignee: Nan Ya Plastics CorporationInventor: Allen Fong-Chin Lin
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Patent number: 6585920Abstract: Embossed oriented thermoplastic films and a method of making same are described. The embossed oriented thermoplastic films have substantially the same mechanical properties as unembossed oriented thermoplastic films. The method includes providing an oriented thermoplastic film having first and second major surfaces, softening at least one of the first and second major surfaces to produce a softened surface, embossing the softened surface to produce an embossed oriented thermoplastic film, and cooling the embossed oriented thermoplastic film.Type: GrantFiled: April 27, 2001Date of Patent: July 1, 2003Assignee: 3M Innovative Properties CompanyInventors: Joan M. Strobel, Mark A. Strobel, Patrick J. Hager, Ronald S. Kapaun
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Patent number: 6572295Abstract: The method of continuously manufacturing pencils or crayons consists in coextruding a filled first thermoplastic material referred to as “lead” material, and around it both an intermediate “protective” layer of a thermoplastic material having no expanding agent and a second thermoplastic material containing an expanding agent and referred to as “wood” material, and in cooling said coextruded thermoplastic materials. According to the invention, the thermoplastic material constituting the protective layer is determined so that during cooling it remains deformable while the lead material shrinks. The pencil is constituted by superposing a core of a filled first thermoplastic material referred to as “lead” material, a protective layer of a non-expanded thermoplastic material, and a layer of an expanded second thermoplastic material referred to as “wood” material.Type: GrantFiled: March 25, 2002Date of Patent: June 3, 2003Assignee: ConteInventors: Ludovic Chochoy, Hélène Baillieu, Jacques Bachelet, Lucien Foscarin