Including Subsequent Reshaping (e.g., Stretching, Etc.) Patents (Class 264/173.15)
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Patent number: 12036716Abstract: The present disclosure provides oriented multilayer films including a first layer, a second layer disposed on the first layer and a third layer disposed on the second layer, where the first layer and the third layer include a polyethylene independently selected from (i) a polyethylene having a density of about 0.94 g/cc or greater; (ii) a polyethylene copolymer including ethylene and a C4-C12 alpha-olefin and having a density 7 from about 0.927 g/cc to about 0.95 g/cc; or (iii) a mixture thereof, and at least one of the first layer or the third layer includes the polyethylene copolymer, the second layer includes a polyethylene composition having a density of about 0.91 g/cc or greater and the oriented multilayer film has a haze of about 10% or less and a 1% secant modulus in the direction of stretching of about 500 MPa or greater.Type: GrantFiled: January 23, 2020Date of Patent: July 16, 2024Assignee: ExxonMobil Chemical Patents Inc.Inventors: XiRui Wang, Etienne R. H. Lernoux, Arash Sarhangi Fard, Chiao Kiat Pey
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Patent number: 11426917Abstract: In one embodiment, a multilayer article can comprise: a multilayer substrate M, comprising: greater than or equal to 16 polymer A layers, preferably 16 to 512 polymer A layers; and greater than or equal to 16 polymer B layers, preferably 16 to 512 polymer B layers; wherein the polymer A layers and the polymer B layers are present in a ratio of 1:4 to 4:1, preferably the ratio is 1:1; a protective layer P; and an identification layer I between the protective layer P and the multilayer substrate M; wherein the identification layer I comprises information, and wherein the protective layer P prevents alteration thereof.Type: GrantFiled: July 21, 2017Date of Patent: August 30, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.VInventors: Cornelis Johannes Gerardus Maria van Peer, Roy Martinus Adrianus l'Abee, Bart Eduard Kiekens, Jordi Vink, Pieter Jan Antoon Janssen
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Patent number: 11312827Abstract: A uniaxially-oriented ethylene-based polymeric film having at least one layer comprising at least 65 wt. %, based on total amount of materials present in the at least one layer, of a linear low density polyethylene which exhibits each of the following properties: a CDBI of at least 60%; a melt index, I2, measured according to ASTM D 1238 (2.16 kg @190° C.), of 1.8 g/10 min to 10 g/10 min; a density of from 0.910 g/cc to 0.940 g/cc; and a Mw/Mn of less than 3.0.Type: GrantFiled: October 8, 2018Date of Patent: April 26, 2022Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Wu Aik Yee, Yijian Lin, Rajen M. Patel, Fabricio Arteaga Larios, Jacquelyn A. Degroot, Mridula Kapur, Yutaka Maehara
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Patent number: 11137523Abstract: Embodiments relate to a protective film for a polarizer, a polarizing plate, and a display device comprising the same. The protective film for a polarizer according to the embodiments is improved in mechanical strength and minimized in rainbow strains by minimizing the difference in the orientation angle between the center and the edge of the film while generating a difference in the strengths in the longitudinal/transverse directions of the film. Hence, it can be advantageously used as a protective film for a polarizer.Type: GrantFiled: November 25, 2016Date of Patent: October 5, 2021Assignee: SKC CO., LTD.Inventors: Dawoo Jeong, Jang Won Lee, Young Min Heo, Ho Chun Kang, Sechul Lee
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Patent number: 10286585Abstract: Disclosed herein are biomaterials that include a plurality of fibers embedded in a matrix of hydrogel material. The plurality of fibers and hydrogel material are formed during one process step. In one embodiment, the plurality of fibers and hydrogel materials are formed using a multilayer coextrusion process step. Additional process steps can be performed to form a tissue engineering scaffold. Such a scaffold can be used to grow biological matter. In one embodiment, stem cells are applied to the scaffold to grow biological material. Process steps can be controlled to determine certain mechanical properties of the resulting biomaterial. In one embodiment, the process steps are controlled to determine the stiffness of the resulting biomaterial. In such an embodiment, the stiffness of the resulting biological material determines physical properties of the biological material grown on the scaffold.Type: GrantFiled: August 17, 2016Date of Patent: May 14, 2019Assignee: Case Western Reserve UniversityInventors: LaShanda T. J. Korley, Gary E. Wnek, Alexander M. Jordan
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Patent number: 9919467Abstract: The present disclosure generally relates to extrusion die systems. In particular, the present disclosure relates to the cyclical extrusion of materials to generate small sized grain features, generally in the range of nanosized grain features, in a tubular or profile shape, in which the individual nanolayers possess pores and/or polymer crystals oriented parallel to the extrusion flow direction and including products with enhanced permeation properties.Type: GrantFiled: April 3, 2014Date of Patent: March 20, 2018Assignee: Guill Tool & Engineering Co., Inc.Inventors: Richard Guillemette, Robert Peters, Christopher Hummel
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Patent number: 9598212Abstract: A method of forming a confined crystallization multilayer film includes coextruding a plurality of first polymer layers and a plurality of second polymer layer to form a multilayer film wherein each first polymer layer is sandwiched between second polymer layers and axially orienting the multilayer film at a temperature below the melting temperature (Tm) of the second polymer layer and to a thickness such that each first polymer layer forms a high aspect ratio substantially crystalline lamellae.Type: GrantFiled: July 14, 2014Date of Patent: March 21, 2017Assignee: Case Western Reserve UniversityInventors: Anne Hiltner, Eric Baer, Yijian Lin, Joel Carr
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Patent number: 9346209Abstract: Disclosed are a feedblock multiplier with thickness gradient variation, a feedblock system, a method, and multilayer structure made by the method. The feedblock multiplier combines the functionalities of feedblock and multiplier conventionally used for producing the multilayer structure. The feedblock multiplier includes an input section for feeding fluid materials. A feedblock section is included for dividing the fluid delivered into multiple channels correspondingly. The fluids in the channels are segmented into two or more fluid segments by a segmenting section. The each fluid segment is delivered through corresponding channel-conversion section with thickness-gradient variation in the feedblock multiplier. Each channel-conversion section includes multiple channels with configurable positions. The fluids are then combined in a multiplier section for producing the multilayer structure with overlapped layers. The multilayer structure is outputted from an extruding section.Type: GrantFiled: November 30, 2015Date of Patent: May 24, 2016Assignee: EXTEND OPTRONICS CORP.Inventors: Jen-Huai Chang, Wen-Cheng Wu
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Patent number: 9028732Abstract: A single-sided, slip resistant, self-adhesive material is produced using a blown film process which produces a film having an interior layer capable of being treated or coated to accept a pressure sensitive adhesive, a middle layer of flexible polyolefin and an exterior polyolefin elastomer layer in combination with a blowing agent to produce a single-sided slip resistant material. A number of in-line rollers are optionally provided after a pair of nip rollers, which form part of a machine direction orienter (MDO) that is used in line in the manufacturing process to heat, and then cool and condition (anneal and relieve any stresses and/or thickness inconsistencies) the film prior to the film being coated on one side with a pressure sensitive adhesive.Type: GrantFiled: October 15, 2013Date of Patent: May 12, 2015Assignee: Multi Technologies Industrial L.L.C.Inventors: Michael C. Sullivan, Thomas Zickell, II, George M. Orlych
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Patent number: 8999502Abstract: A cover tape having a temperature at which a heat shrinkage rate in at least one of a machine direction and a transverse direction perpendicular to the machine direction is 5% or more between 80° C. to 200° C.Type: GrantFiled: August 25, 2010Date of Patent: April 7, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Masayuki Yoshino, Toshihiro Koyano, Daisuke Masaki, Yutaka Matsuki
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Patent number: 8945703Abstract: The invention relates to a polyester film incorporating at least one UV stabilizer of the formula I, in which R1 is hydrogen, alkyl, alkenyl, cycloalkyl, cycloalkenyl, heterocycloalkyl, aryl, or heteroaryl, and R2 is a moiety which contains at least one ?-electron system, which contains a carbon atom and at least one further atom selected from carbon, oxygen, and nitrogen, where the moiety R2 contains at least one atom different from carbon, where the film includes at least one further UV absorber which does not correspond to the formula I. The invention further relates to a process for producing the film, and also to articles formed from the film.Type: GrantFiled: July 8, 2010Date of Patent: February 3, 2015Assignee: Mitsubishi Polyester Film GmbHInventors: Holger Kliesch, Oliver Klein, Andreas Bork, Ingo Fischer
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Publication number: 20140315067Abstract: A method of producing a microporous membrane includes combining at least a first polyethylene and a first diluent; combining at least a second polyethylene and a second diluent; combining at least a third polyethylene and a third diluent; forming from the combined polyethylenes and diluents a multi-layer extrudate having a first layer containing the first polyethylene, a second layer containing the second polyethylene, and a third layer located between the first and second layers containing the third polyethylene, wherein the extrudate contains polyethylene having a terminal unsaturation ?0.20 per 10,000 carbon atoms in an amount of 4.0 wt. % to 35.0 wt. %; and removing at least a portion of the first, second, and third diluents from the multi-layer extrudate to produce the membrane.Type: ApplicationFiled: May 12, 2014Publication date: October 23, 2014Applicant: Toray Battery Separator Film Co., Ltd.Inventor: Kazuhiro Yamada
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Patent number: 8808595Abstract: The present invention provides a multilayer film for forming medical solution pouches that help prevent or reduce the presence of bubbles or foam in the solution after heat sterilization. In particular, the present invention provides a multilayer film for forming medical solution pouches that are capable of passing the bubble test as set forth in the Chinese State Drug Package Container Material Standard No. YBB00112005. In particular, the present invention provides a multilayer film in which polyamide 612 or calcium stearate component has been incorporated as an anti-foaming agent. The presence of polyamide 612 or calcium stearate in one or more layers of the film helps prevent the formation of foam in the solution after heat sterilization.Type: GrantFiled: April 7, 2009Date of Patent: August 19, 2014Assignee: Cryovac, Inc.Inventors: Robert Babrowicz, Marvin Russell Havens, Jerry Christopher Richardson
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Patent number: 8801984Abstract: The present invention relates to a multi-layered microporous polyolefin film for a battery separator and a method for preparing the same. The microporous multi-layered film of the present invention has a characteristics to have both the low shutdown temperature conferred by the polyethylene and the high melt fracture temperature conferred by the polypropylene and heat-resistant filler. In addition, it has the high strength and stability conferred by the micropores prepared under wet process and the high permeability and high strength conferred by the macropores prepared under dry process. Therefore, this multi-layered film can be used effectively to manufacture a secondary battery with high capacity and high power.Type: GrantFiled: July 15, 2011Date of Patent: August 12, 2014Assignee: SK Innovation Co., Ltd.Inventors: Jang-Weon Rhee, Inhwa Jung, Gwigwon Kang, Youngkeun Lee
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Publication number: 20140208695Abstract: The invention relates to a shrink film having a multilayer structure, wherein the core layer of the film includes polypropylene, hydrocarbon resin and block-copolymer rubber. The invention also relates to a label including said film and to use of films for labelling recyclable or reusable items. Further the invention relates to a method for producing shrink film, to a method for attaching a shrink film to an article, and to a method separating a shrink film from an article.Type: ApplicationFiled: June 29, 2012Publication date: July 31, 2014Applicant: UPM RAFLATAC OYInventor: Noel Mitchell
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Patent number: 8778245Abstract: A method of forming a confined crystallization multilayer film includes coextruding a plurality of first polymer layers and a plurality of second polymer layer to form a multilayer film wherein each first polymer layer is sandwiched between second polymer layers and axially orienting the multilayer film at a temperature below the melting temperature (Tm) of the second polymer layer and to a thickness such that each first polymer layer forms a high aspect ratio substantially crystalline lamellae.Type: GrantFiled: April 15, 2011Date of Patent: July 15, 2014Assignee: Case Western Reserve UniversityInventors: Anne Hiltner, Eric Baer, Yijian Lin, Joel Carr
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Patent number: 8728371Abstract: A method of producing a stretched film comprising melt-coextruding a thermoplastic resin A and a thermoplastic resin B to produce a composite film 1 having both-end films 2 of the thermoplastic resin B arranged in parallel at both end portions of the main film 1a of the thermoplastic resin A in the direction of width thereof, stretching the composite film, and cutting and removing both end portions of the stretched film in the direction of width, wherein a film stretch stress value of the both-end films 2 is larger than a film stretch stress value of the main film 1a at the same stretching ratio. This minimizes an increase in the thickness at both end portions of the film in stretching the film and decreases the widths by which both end portions of the expensive resin film are to be cut and removed for producing a film.Type: GrantFiled: December 7, 2007Date of Patent: May 20, 2014Assignee: Toyo Kohan Co., Ltd.Inventors: Norimasa Maida, Yoshimi Itoh, Toshiyuki Ueda
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Patent number: 8647553Abstract: In a process of producing a stretch sheet, a strip-shaped laminate sheet 10A having an elastically stretchable elastic layer 1 and substantially inelastic, inelastic fiber layers 2 and 3 partially joined to each other at bonds 4 or a strip-shaped fibrous sheet containing an elastic component and a substantially inelastic component and having embossed regions formed by embossing in parts is stretched in directions starting from the bonds 4 or the embossed regions to obtain a stretch sheet 10. The stretch sheet has raised ridges and recessed grooves extending in the direction perpendicular to the stretch direction, and the bonds 4 or the embossed regions are present in the ridges.Type: GrantFiled: April 25, 2006Date of Patent: February 11, 2014Assignee: Kao CorporationInventors: Hideyuki Kobayashi, Koji Kanazawa, Akihiko Gunji, Tetsuya Masuki
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Patent number: 8623250Abstract: The invention relates to a method of manufacturing a multilayer object in synthetic resin (9) by compression molding a dose of molten multilayer resin (1) comprising at least one functional layer (2,20), each layer of the dose being in the molten state at the time of compression; the method consisting at least in co-extruding the resins through a die, in cutting the extrudate periodically in order to obtain a dose (1), then in depositing the dose (1) in the molten state in the cavity of a mold; the method thereby defining, within the dose, an extrusion direction and an arrangement of the functional layer (2,20) parallel to the extrusion direction; the method being characterized in that the dose is compressed along a compression axis (16) which intersects the extrusion direction, so as to introduce, into the flow of the layers, asymmetry with respect to the compression axis (16).Type: GrantFiled: January 29, 2008Date of Patent: January 7, 2014Assignee: Aisapack Holding S.A.Inventor: Jacques Thomasset
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Patent number: 8617445Abstract: The present invention provides a process for producing an oriented thermoplastic polyester resin sheet which is excellent in tensile strength, tencile modulas and heat resistance, and a light laminate-molded body using the same, which has a low linear expansion coefficient and is excellent in impact resistance, durability, easiness of handling, productivity, and others. A process for producing an oriented thermoplastic polyester resin sheet, which includes: pultrusion-drawing a thermoplastic polyester resin sheet in an amorphous state at a temperature from the glass transition temperature of the thermoplastic polyester resin ?20° C. to the glass transition temperature of the thermoplastic polyester resin +20° C.; and then drawing the resultant uniaxially at a temperature higher than the temperature for the pultrusion-drawing. A laminate-molded body, wherein a thermoplastic resin layer is laminated on each of the surfaces of the resultant oriented thermoplastic polyester resin sheet.Type: GrantFiled: February 17, 2006Date of Patent: December 31, 2013Assignee: Sekisui Chemical Co., Ltd.Inventors: Shigeru Ogasawara, Hirotsugu Yoshida, Hisashi Eguchi, Ryuichi Matsuo
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Patent number: 8580174Abstract: Disclosed herein is a method comprising deforming an organic polymer composition at a temperature below a glass transition temperature of an organic polymer in the organic polymer composition; the deforming being conducted by an application of a shear force, an elongational force, a compressive force, or a combination comprising at least one of the foregoing forces; the forces being applied to the organic polymer composition as it is disposed between a first roll that comprises a rubber surface and a second roll that comprises a textured metal surface; the deforming producing a textured film having a ratio of texturing of about 0.5 to about 3; the textured film having a thickness of about 5 to about 75 micrometers and an average roughness of about 0.3 to about 6 micrometers on opposing surfaces of the film.Type: GrantFiled: June 1, 2007Date of Patent: November 12, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventor: Safwat Ebeid Tadros
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Patent number: 8568636Abstract: The present invention relates to a multilayer film coextruded from an aliphatic polycarbonate and polylactic acid-based polymer and a method for producing the same. According to the present invention, a multilayer film having excellent adhesive property can be manufactured even without a separate adhesive layer.Type: GrantFiled: August 25, 2011Date of Patent: October 29, 2013Assignee: SK Innovation Co., Ltd.Inventors: Min Ho Jeon, Ji Eun Yoo, Moon Jung Choi, Kwang Jin Chung, Myung Ahn Ok
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Patent number: 8551587Abstract: Provided is a polypropylene film, and a method of making the film, the film comprising at least one core layer sandwiched between at least two skin layers, the layers comprising a core layer comprising polypropylene and within the range of from 20 wt % to 50 wt %, by weight of the materials in the core layer, of a propylene-?-olefin elastomer having within the range of from 5 wt % to 25 wt % ?-olefin derived units, by weight of the copolymer; and skin layers comprising one or more polymers having a melting point within the range of from 125° C. to 160° C., a Shore D Hardness within the range of from 55 to 70, and a Flexural Modulus of at least 600 MPa; wherein the film has a Haze value of less than 10%, the film being biaxially oriented but shrinkable substantially only in the MD.Type: GrantFiled: September 27, 2012Date of Patent: October 8, 2013Assignee: ExxonMobil Oil CorporationInventors: Pang-Cha Lu, Benoit Ambroise
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Publication number: 20130261736Abstract: A bioabsorbable scaffold composed of a multilayer structure of alternating layers of different polymers is disclosed. The multilayer structure can have 20 to 1000 layers and the individual thickness of the layers can be 0.2 to 5 microns. A method of making the scaffold including a layer multiplying extrusion process is disclosed.Type: ApplicationFiled: April 2, 2013Publication date: October 3, 2013Applicant: Abbott Cardiovascular Systems Inc.Inventor: Lothar W. Kleiner
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Patent number: 8465759Abstract: A process for the preparation of a bioadhesive laminate comprising a hot-melt extruded reservoir layer and a hot-melt extruded backing layer is provided. The reservoir layer comprises a thermoplastic bioadhesive composition containing an active agent. An active agent-containing thermoplastic bioadhesive hydrophilic composition is hot-melt coextruded with a hydrophobic composition to form at least a bi-layered laminate. The hydrophilic composition and the hydrophobic composition have at least one polymer in common. In addition, the melt flow index of the hydrophobic composition is within 50% of the melt flow index of the hydrophilic composition. As a result, the laminate has a uniform transverse cross-section and/or a uniform longitudinal cross-section throughout a major of the length of the laminate. Moreover, when the laminate is divided into unit doses of approximately the same size, they have a high degree of content uniformity with respect to the active agent(s) present therein.Type: GrantFiled: March 22, 2007Date of Patent: June 18, 2013Assignee: Auxilium US Holdings, LLCInventors: Michael M. Crowley, Justin M. Keen, John J. Koleng, Feng Zhang
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Publication number: 20130136906Abstract: A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep A polyamide resin-based heat-shrinkable multilayer film having excellent heat shrinkability and strength, as well as a high degree of deep drawability as represented a shorter side-basis draw ratio (D/L) in excess of 0.6 between a maximum draw depth (D) and a shorter side length (L) of a mold opening is provided. The multilayer film is characterized by including a surface layer (a) comprising a thermoplastic resin, an intermediate layer (b) comprising a polyamide resin, and a surface layer (c) comprising a sealable resin, wherein (A) the intermediate layer (b) comprises a mixture of an aliphatic polyamide having a melting point of at least 180° C., and an amorphous aromatic polyamide comprising a polycondensation product of an aliphatic diamine with is ophthalmic acid and terephthalic acid as main acid components, including 25-45 wt.Type: ApplicationFiled: December 17, 2010Publication date: May 30, 2013Inventors: Takahisa Ueyama, Tadayoshi Itoh, Yuta Sekiya
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Publication number: 20130115398Abstract: Provided is a polypropylene film, and a method of making the film, the film comprising at least one core layer sandwiched between at least two skin layers, the layers comprising a core layer comprising polypropylene and within the range of from 20 wt % to 50 wt %, by weight of the materials in the core layer, of a propylene-?-olefin elastomer having within the range of from 5 wt % to 25 wt % ?-olefin derived units, by weight of the copolymer; and skin layers comprising one or more polymers having a melting point within the range of from 125° C. to 160° C., a Shore D Hardness within the range of from 55 to 70, and a Flexural Modulus of at least 600 MPa; wherein the film has a Haze value of less than 10%, the film being biaxially oriented but shrinkable substantially only in the MD.Type: ApplicationFiled: September 27, 2012Publication date: May 9, 2013Applicant: ExxonMobil Oil CorporationInventor: ExxonMobil Oil Corporation
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Publication number: 20130095338Abstract: Disclosed is a multi-layer heat shrink film and a method of making the film comprising a core layer comprising at least one ?-olefin copolymer selected from propylene-based elastomers, ethylene plastomers, metallocene catalyzed linear low density polyethylenes, and blends thereof, and an equal or lesser amount of a polypropylene having a melting point higher than ?-olefin copolymer; at least one skin layer comprising a cyclic olefin copolymer (COC); and at least one tie layer between at least one skin layer and the core layer, the tie layer comprising a material or blend of soft materials having a Hardness (ISO 7619, Type A) of from 45 to 100; and a Tensile Strength (ISO 37) of from 10 MPa to 30 MPa.Type: ApplicationFiled: September 5, 2012Publication date: April 18, 2013Inventor: Pang-Chia LU
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Patent number: 8409697Abstract: A multilayer, heat-shrinkable film generally includes at least one bulk layer and a microlayer section comprising at least 10 microlayers, each of which has a thickness ranging from about 0.001 to 0.015 mil. The ratio of the thickness of any of the microlayers to the thickness of the bulk layer is at least about 1:2. The film has a total free shrink (ASTM D2732-03) of at least about 10% at 200° F.Type: GrantFiled: June 28, 2012Date of Patent: April 2, 2013Assignee: Cryovac, Inc.Inventors: Rafizi Ramli, Larry Bikle McAllister, Anton L. Timmons, Bradford E. Webster, John R. Wolf, Christopher Brown, George D. Wofford
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Patent number: 8349422Abstract: The invention relates to a Flexible Intermediate Bulk Container (FIBC) having a body made of flexible woven fabric, and integral handling devices, wherein the fabric is woven from opaque oriented polyethylene terephthalate (PET) strips having a density of from 500 to 1300 kg/m3 and a tensile strength of at least 250 MPa. Advantages of said FIBC include directly printability with the usual type of inks, giving excellent contrast and good adhesion, without pre-treatment like a corona- or flame-treatment. The FIBC based on the PET fabric also shows higher gloss; better UV resistance; better mechanical properties, like high tensile strength and creep resistance; favorable abrasion resistance; and higher temperature resistance than a conventional big bag based on polypropylene strips. The invention further relates to such a FIBC based on stress-whitened PET tapes obtained by a special drawing process.Type: GrantFiled: April 20, 2009Date of Patent: January 8, 2013Assignee: Saudi Basic Industries CorporationInventors: Zahir Bashir, Ian Macmillan Ward, Glen Peter Thompson, Anthony Paul Unwin
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Patent number: 8337188Abstract: An apparatus for making a shingle, together with the shingle made thereby, is provided, in which one or more thermoplastic materials are extruded or co-extruded to form an extrudate, with the extrudate being cut into a preliminary shingle shape, which is allowed to dissipate heat, and then is delivered to a compression mold, wherein the preliminary shingle shape is compression molded to substantially its final dimensions and is then discharged from the mold and allowed to cool.Type: GrantFiled: March 5, 2010Date of Patent: December 25, 2012Assignee: CertainTeed CorporationInventors: Thomas Kevin MacKinnon, Robert E. Dodd, Joong Youn Kim, Douglas H. Wylie
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Patent number: 8328968Abstract: Disclosed herein are methods of preparing a composite sheet material having strength and barrier properties suitable for use as a housewrap, the methods comprising extrusion coating a polyolefin film layer onto a surface of an area-bonded, spunbond nonwoven substrate to form a composite sheet material, the composite sheet material having a grab tensile strength of at least 178 Newtons in at least one of the machine direction (MD) or the cross-machine direction (CD), and stretching the composite sheet material to impart to the composite sheet material a hydrostatic head of at least 100 cm, and a moisture vapor transmission rate (MVTR) of at least 35 g/m2/24 hr at 50% relative humidity and 23° C.Type: GrantFiled: April 16, 2012Date of Patent: December 11, 2012Assignee: Fiberweb, Inc.Inventors: Gary W. Anderson, Susannah D. Gelotte
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Patent number: 8298465Abstract: Provided is a microporous film which is made of a thermoplastic resin composition comprising (a) 100 parts by mass of a polypropylene resin and (b) 5 to 90 parts by mass of a polyphenylene ether resin, and which has a sea island structure comprising a sea portion comprising the polypropylene resin as a principal component and an island portion comprising the polyphenylene ether resin as a principal component, wherein pores are formed at an interface between the sea portion and the island portion and within the sea portion.Type: GrantFiled: July 31, 2009Date of Patent: October 30, 2012Assignee: Asahi Kasei E-Materials CorporationInventors: Kentaro Kikuchi, Hidetoshi Masugi
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Publication number: 20120233965Abstract: A coextruded annealed gas-barrier heat-shrinkable packaging film suitable for flowpack or tray-lidding applications comprises a core EVOH layer (A), first and second outer polyolefin layers (B) and (C), and at least one inner layer (D) of a copolymer of propylene with butene and optionally also with ethylene, and is characterized by a maximum shrink force in the transverse direction £ 0.35 N/cm and by a residual shrink force in the range 0.11 to 0.22 N/cm. The film is obtained by coextrusion, optional irradiation, orientation and annealing at a temperature of from 70 to 90° C.Type: ApplicationFiled: September 14, 2010Publication date: September 20, 2012Inventors: Marina Riccio, Roberto Forloni, Felice Ursino
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Patent number: 8187683Abstract: An object of the present invention is to provide a multilayered polyamide-based tube for food packaging that is free from blocking in a Layer (C), and that has an excellent adherence to processed meat or like packaged food. The present invention provides a multilayered polyamide-based tube for food packaging comprising a Layer (A), a Layer (B) and a Layer (C); the multilayered polyamide-based tube having a low-temperature shrinkage ratio of 2 to 10%, and exhibiting heat shrinkage properties and gas barrier properties; the Layer (A) containing a polyamide-based resin; the Layer (B) containing a polyolefin-based resin; and the Layer (C) that comes in contact with the packaged food, the Layer (C) being a Layer (C-1) that contains a polypropylene-based resin having a heat distortion temperature (ISO 75B-1 or ISO 75B-2) of not less than 60° C. and a Vicat softening point of not less than 120° C.Type: GrantFiled: March 26, 2009Date of Patent: May 29, 2012Assignee: Gunze LimitedInventors: Hiroki Kuriu, Hiroyuki Yabuta
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Microporous membranes having a relatively large average pore size and the methods of making the same
Patent number: 8182908Abstract: Microporous membranes having a relatively large average pore size, methods of making microporous membranes having a relatively large average pore size, and methods of using microporous membranes having a relatively large average pore size are disclosed.Type: GrantFiled: September 24, 2008Date of Patent: May 22, 2012Assignee: 3M Innovative Properties CompanyInventor: James S. Mrozinski -
Patent number: 8080310Abstract: A multilayer, heat-shrinkable film generally includes at least one bulk layer and a microlayer section comprising a plurality of microlayers. The ratio of the thickness of any of the microlayers to the thickness of the bulk layer ranges from about 1:2 to about 1:40.Type: GrantFiled: July 1, 2011Date of Patent: December 20, 2011Assignee: Cryovac, Inc.Inventors: Rafizi Ramli, Anton L. Timmons, Bradford E. Webster, John R. Wolf, Larry Bikle McAllister, Christopher Brown, George D Wofford
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Publication number: 20110241245Abstract: A method of forming a confined crystallization multilayer film includes coextruding a plurality of first polymer layers and a plurality of second polymer layer to form a multilayer film wherein each first polymer layer is sandwiched between second polymer layers and axially orienting the multilayer film at a temperature below the melting temperature (Tm) of the second polymer layer and to a thickness such that each first polymer layer forms a high aspect ratio substantially crystalline lamellae.Type: ApplicationFiled: April 15, 2011Publication date: October 6, 2011Inventors: ANNE HILTNER, Eric Baer, Yijian Lian, Joel Carr
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Patent number: 8021759Abstract: The present invention is directed to a heat-shrinkable, thermoplastic film or bag which contains at least one homogeneous ethylene alpha-olefin copolymer having a density of at least 0.90 g/cc. Oriented films made in accordance with the present invention exhibit improved optics and improved impact resistance. A homogeneous ethylene alpha-olefin may be present in a monolayer film either alone or in a blend or may be included in one or more layers of a multilayer film in accordance with the present invention.Type: GrantFiled: December 22, 1997Date of Patent: September 20, 2011Assignee: Cryovac Inc.Inventors: Kelly R. Ahlgren, Robert Babrowicz, Solomon Bekele, Blaine C. Childress, Marvin R. Havens, Vincent W. Herran, Ronald D. Moffitt, Gautam P. Shah, George D. Wofford
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Patent number: 8017052Abstract: A process and apparatus for making a shingle, together with the shingle made thereby, is provided, in which one or more thermoplastic materials are extruded or co-extruded to form an extrudate, with the extrudate being cut into a preliminary shingle shape, which is allowed to dissipate heat, and then is delivered to a compression mold, wherein the preliminary shingle shape is compression molded to substantially its final dimensions and is then discharged from the mold and allowed to cool.Type: GrantFiled: January 7, 2010Date of Patent: September 13, 2011Assignee: CertainTeed CorporationInventors: Thomas Kevin MacKinnon, Robert E. Dodd, Joong Youn Kim, Douglas H. Wylie
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Patent number: 8012572Abstract: A multilayer, heat-shrinkable film generally includes at least one bulk layer and a microlayer section comprising a plurality of microlayers. The ratio of the thickness of any of the microlayers to the thickness of the bulk layer ranges from about 1:2 to about 1:40.Type: GrantFiled: March 6, 2009Date of Patent: September 6, 2011Assignee: Cryovac, Inc.Inventors: Rafizi Ramli, Larry Bikle McAllister, Anton L. Timmons, Bradford E. Webster, John R. Wolf, Christopher Brown, George D. Wofford
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Patent number: 7998385Abstract: A transparent multilayer stretched product is produced through a process including: providing a resin laminate including at least on layer of polyglycolic acid resin, heat-forming and cooling the resin laminate, reheating the resin laminate until the polyglycolic acid resin is crystallized to be opaque and then stretching the reheated resin laminate. The thus-obtained multilayer stretched product is excellent in gas-barrier property in addition to the transparency and is suitable as a packaging material or container.Type: GrantFiled: September 29, 2004Date of Patent: August 16, 2011Assignee: Kureha CorporationInventors: Kazuyuki Yamane, Ryo Kato, Hisanori Tobita
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Publication number: 20110189437Abstract: A thermoplastic film with a three-dimensionally structured outer surface is made by coextruding through a slit nozzle a multilayer molten plastic film having an outer layer formed of a thermoplastic polyurethane elastomer with an isocyanate additive and an inner layer. This multilayer film is compressed in a nip between a roll and a belt to emboss a three-dimensional structure into the outer layer. The roll is cooled to cool the film and set the three-dimensional structure in the outer surface of the outer layer.Type: ApplicationFiled: April 21, 2010Publication date: August 4, 2011Inventors: Gruendken Marcel, Herbert Bader, Andreas Hagemann
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Patent number: 7981492Abstract: Multilayer laminates useful in packaging of respiring food products and packages made therefrom. The laminates have a CO2 permeability rate of at least about 10 cm3/100 in2/24 hours and an O2 permeability rate of less than about 5.3 cm3/100 in2/24 hours.Type: GrantFiled: October 28, 2008Date of Patent: July 19, 2011Assignee: Exopack, LLCInventor: Jay D. Hodson
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Publication number: 20110171464Abstract: The invention relates to a sealable, biaxially oriented polyester film comprising a base layer B, a sealable cover layer A, and a non-sealable cover layer C. The invention further relates to a method for producing the film and to the use thereof.Type: ApplicationFiled: September 3, 2009Publication date: July 14, 2011Inventors: Matthias Konrad, Bodo Kuhmann, Gottfried Hilkert, Herbert Peiffer
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Publication number: 20110135221Abstract: The invention relates to a Flexible Intermediate Bulk Container (FIBC) having a body made of flexible woven fabric, and integral handling devices, wherein the fabric is woven from opaque oriented polyethylene terephthalate (PET) strips having a density of from 500 to 1300 kg/m3 and a tensile strength of at least 250 MPa. Advantages of said FIBC include directly printability with the usual type of inks, giving excellent contrast and good adhesion, without pre-treatment like a corona- or flame-treatment. The FIBC based on the PET fabric also shows higher gloss; better UV resistance; better mechanical properties, like high tensile strength and creep resistance; favourable abrasion resistance; and higher temperature resistance than a conventional big bag based on polypropylene strips. The invention further relates to such a FIBC based on stress-whitened PET tapes obtained by a special drawing process.Type: ApplicationFiled: April 20, 2009Publication date: June 9, 2011Applicant: Saudi Basic Industries CorporationInventors: Zahir Bashir, Ian Macmillian Ward, Glen Peter Thompson, Anthony Paul Unwin
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Patent number: 7910032Abstract: The present invention provides an exemplary process for manufacturing a flexible packaging laminate into a pouch for containing liquids such as edible oil. The process includes taking granules of polypropylene and medium density polyethylene in a proportion of 1-1.5:1.5-2.5, —melting the granules at 200-230 degrees Celsius in a 3 layer blown film extruder to form a co-extruded film, —printing the film by a Rotogravure printing technique at 40-60 degrees Celsius, —laminating the printed film with a conventional 5 layer co-extruded nylon film at 60-80 degrees Celsius, —curing the laminated film at 35-45 degrees Celsius for at least 2 days, —and slitting the cured laminated film to a desired size for using with a Form Fill Seal machine (FFS Machine) at 160-180 degrees Celsius, to make pouches that hold liquids, such as edible oil.Type: GrantFiled: December 14, 2005Date of Patent: March 22, 2011Assignee: Cargill India Private LimitedInventor: Mukul Kumar
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Publication number: 20100327480Abstract: A method of co-extrusion is used to prepare a thermal imaging element such as a thermal dye receiver element. In this method, two or three of an image receiving layer, an antistatic tie layer, and a compliant layer are co-extruded and these co-extruded multiple layers can be disposed on a support to provide a smooth outer surface and reduced delamination among layers especially in a high humidity environment.Type: ApplicationFiled: June 24, 2009Publication date: December 30, 2010Inventors: Narasimharao Dontula, Somsack Chang, Brian Thomas
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Publication number: 20100227136Abstract: A multilayer, heat-shrinkable film generally includes at least one bulk layer and a microlayer section comprising a plurality of microlayers. The ratio of the thickness of any of the microlayers to the thickness of the bulk layer ranges from about 1:2 to about 1:40.Type: ApplicationFiled: March 6, 2009Publication date: September 9, 2010Inventors: Rafizi Ramli, Larry Bikle McAllister, Anton L. Timmons, Bradford E. Webster, John R. Wolf, Christopher Brown, George D. Wofford
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Patent number: 7785510Abstract: A process and apparatus for making a shingle, together with the shingle made thereby, is provided, in which one or more thermoplastic materials are extruded or co-extruded to form an extrudate, with the extrudate being cut into a preliminary shingle shape, which is allowed to dissipate heat, and then is delivered to a compression mold, wherein the preliminary shingle shape is compression molded to substantially its final dimensions and is then discharged from the mold and allowed to cool.Type: GrantFiled: September 15, 2005Date of Patent: August 31, 2010Assignee: CertainTeed CorporationInventors: Thomas Kevin MacKinnon, Robert E. Dodd, Joong Youn Kim, Douglas H. Wylie