Styrene Polymer Containing Patents (Class 264/174.1)
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Patent number: 8871125Abstract: A process to produce a laminate comprising coextruding a dynamically vulcanized alloy (DVA) film with an adhesive layer comprising a vulcanizable elastomeric composition through a die to produce the laminate. The process provides a residence time of the vulcanizable elastomeric composition in the melt to partially scorch the vulcanizable elastomeric composition. A melt of the DVA is in contact with the melt of the vulcanizable elastomeric composition in the die for at least 5 seconds, optionally also with a change in the area of the contact between the DVA film and the adhesive layer as it passes through the die, to increase the adhesion between the adhesive layer and the DVA layer relative to a shorter co-residence time. A laminate and a pneumatic tire comprising the laminate are also disclosed.Type: GrantFiled: December 19, 2011Date of Patent: October 28, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Porter C. Shannon, Michael J. Vinck
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Patent number: 8795816Abstract: Coextruded films provide cross directional zoned multiple components side-by-side to one another. Systems and methods relate to coextruding such films. During coextrusion, a first polymer conjoins with a second polymer while a temperature differential is maintained between the first and second polymers. This temperature differential is selected to reduce a difference between the viscosities of the first and second polymers making the viscosity of the first polymer close enough to the viscosity of the second polymer to avoid separation upon coextrusion. Further, the films may form a layer in subsequent lamination to other material layers.Type: GrantFiled: March 14, 2013Date of Patent: August 5, 2014Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Matthew B. Lake, Bryon Paul Day
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Publication number: 20140037880Abstract: A flexible tube includes a first polymer layer and a second polymer layer adjacent to the first polymer layer. The first polymer layer includes a polyolefin, an ethylene vinyl acetate copolymer, an ethylene/norbornene copolymer, a styrenic block copolymer, a styrene butadiene copolymer, or combination thereof having a total organics content of less than about 12 ?g/L per USP 34, Chapter 643. The second polymer layer includes a polyolefin, a styrenic block copolymer, a blend thereof, or combination thereof, wherein the second polymer layer has a shore A durometer of less than about 65. Further included is a method of forming the flexible tube.Type: ApplicationFiled: July 26, 2013Publication date: February 6, 2014Inventors: Sridhar Krishnamurthi Siddhamalli, Mark W. Simon
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Patent number: 8501064Abstract: Techniques for preparing PNCs are provided. In one embodiment, a polymer extruding device may include a barrel configured to accommodate a composite material, a shaft rotatably disposed in the barrel, and a motor coupled to the shaft and configured to rotate the shaft, thereby moving the composite material. The polymer extruding device may further include a die including one or more injectors configured to inject nano particles into the die to cause shear stress to be exerted to the composite material, thereby forming a layer of the nano particles on a surface of the composite material.Type: GrantFiled: January 9, 2012Date of Patent: August 6, 2013Assignee: SNU R&DB FoundationInventor: Youngtack Shim
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Publication number: 20130157049Abstract: A process to produce a laminate comprising coextruding a dynamically vulcanized alloy (DVA) film with an adhesive layer comprising a vulcanizable elastomeric composition through a die to produce the laminate. The process provides a residence time of the vulcanizable elastomeric composition in the melt to partially scorch the vulcanizable elastomeric composition. A melt of the DVA is in contact with the melt of the vulcanizable elastomeric composition in the die for at least 5 seconds, optionally also with a change in the area of the contact between the DVA film and the adhesive layer as it passes through the die, to increase the adhesion between the adhesive layer and the DVA layer relative to a shorter co-residence time. A laminate and a pneumatic tire comprising the laminate are also disclosed.Type: ApplicationFiled: December 19, 2011Publication date: June 20, 2013Inventors: Porter C. Shannon, Michael J. Vinck
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Patent number: 8460588Abstract: Coextruded films provide cross directional zoned multiple components side-by-side to one another. Systems and methods relate to coextruding such films. During coextrusion, a first polymer conjoins with a second polymer while a temperature differential is maintained between the first and second polymers. This temperature differential is selected to reduce a difference between the viscosities of the first and second polymers making the viscosity of the first polymer close enough to the viscosity of the second polymer to avoid separation upon coextrusion. Further, the films may form a layer in subsequent lamination to other material layers.Type: GrantFiled: July 30, 2007Date of Patent: June 11, 2013Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Matthew B. Lake, Bryon Paul Day
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Patent number: 8361362Abstract: A method for supplying molten polymer and expanding agent flows to a mixing area, by dispersing the expanding agent in a polymer melt by a rapid dividing mixing in a first static mixer, holding and intensively dividingly mixing the thus obtained mixture in a second static mixer, cooling the mixture, during mixing, in a third static mixer to an intermediate temperature, cooling the mixture to a granulation temperature, extruding polymer threads and subsequently quenching and granulating them. During processing, a weight ratio between the polymer melt flow Gp and the expanding agent flow GBA ranges from 13.0 to 19.0, a temperature in the first static mixer for rapid dividing mixing is calculated according to formula (I), in the second and third static mixed according to formulas (II) and (III), respectively, wherein GBA max. is the quantity of a maximum possible expanding agent flow, GBBct.Type: GrantFiled: February 15, 2006Date of Patent: January 29, 2013Assignee: Sulzer Chemtech Ltd.Inventors: Maxim Nikolaevich Rogov, Halyl Halafovich Rahimov, Marat Hafisovich Ishmijarov, Sergei Ivanovich Mjachin, Alexej Vladimirovich Prokopenko, Alexandr Alexeevich Krasheninnikov, Irina Vladimirovna Mjasitsheva, Leonid Isaakovich Ginzburg, Eugenia Michailova Tarkova
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Patent number: 8246878Abstract: A method comprising extrusion compounding a styrenic polymer and a layered compound to produce a composite, and orienting the composite to produce an oriented composite wherein the layered compound comprises natural clay, synthetic clay, natural colloid, synthetic colloid, natural sol, synthetic sol, natural gel, synthetic gel, natural fumes, synthetic fumes, or combinations thereof. A method of preparing an oriented film comprising extrusion compounding a styrenic polymer and a clay to produce a nanocomposite, casting the nanocomposite into a film, and orienting the film in at least one direction.Type: GrantFiled: April 30, 2008Date of Patent: August 21, 2012Assignee: Fina Technology, Inc.Inventors: Luyi Sun, Jose Sosa
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Patent number: 8206629Abstract: A co-extrusion process enhances the durability of the ultimate product over previous systems which use relatively fragile paint coatings to limit heat absorption. By providing near-IR transmissive and reflective pigments within the co-extruded polymers, a highly durable finished product is obtained. The co-extruded layers are disclosed for use in fence and deck applications, but will also find application in a wide variety of building product applications, both exterior and interior.Type: GrantFiled: November 22, 2010Date of Patent: June 26, 2012Assignee: Certainteed CorporationInventors: Ming-Liang Shiao, Joong-Youn Kim
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Publication number: 20110244185Abstract: Described are biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. The films can be used, for example, in packaging applications. The films can be metallized, or combined with barrier coatings or layers, for improved gas barrier properties particularly for moisture vapor transmission barrier desired in packaging applications. The films can also be printing films for packaging applications and may be transparent or matte in appearance. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.Type: ApplicationFiled: December 23, 2010Publication date: October 6, 2011Applicant: TORAY PLASTICS (AMERICA), INC.Inventors: Shichen DOU, Mark S. Lee, Claudio M. Paulino, Nao Yokota, Keunsuk P. Chang
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Publication number: 20110159297Abstract: Multilayer structures having layers of a styrene polymer, polyethylene, propylene polymer, and common tie layers of a styrene-butadiene-styrene triblock copolymer-containing adhesive.Type: ApplicationFiled: December 30, 2009Publication date: June 30, 2011Applicant: Equistar Chemicals, LPInventor: Maged G. Botros
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Patent number: 7524447Abstract: One method for making a laminate material comprising a first surface layer comprising resorcinol arylate polyester chain members and a second surface layer suitable for bonding to a substrate, comprises co-extruding a polymeric first surface layer material and a polymeric second surface layer material through a die and into the first nip of a calender roll stack comprising a first surface roll and a second surface roll that define the first nip, to form the laminate material. A nip load in the first nip of greater than or equal to about 400 N/cm can be applied to the laminate, and the laminate material can be collected from the roll stack. The first roll and the second roll can each have a surface smoothness of less than or equal to about 5 micrometers and temperatures of about 40° C. to about 150° C.Type: GrantFiled: July 20, 2004Date of Patent: April 28, 2009Assignee: Sabic Innovative Plastics IP B.V.Inventors: Himanshu Asthana, M. Shoen Davis, Hari K. Harikumar, Martin J. Lindway, Aniruddha Moitra, Chetan J. Parikh, Om Prakash, Michael T. Roland, Robert A. Schiff, Robert W. Walker, Georgios S. Zafiris
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Publication number: 20090035593Abstract: Coextruded films provide cross directional zoned multiple components side-by-side to one another. Systems and methods relate to coextruding such films. During coextrusion, a first polymer conjoins with a second polymer while a temperature differential is maintained between the first and second polymers. This temperature differential is selected to reduce a difference between the viscosities of the first and second polymers making the viscosity of the first polymer close enough to the viscosity of the second polymer to avoid separation upon coextrusion. Further, the films may form a layer in subsequent lamination to other material layers.Type: ApplicationFiled: July 30, 2007Publication date: February 5, 2009Inventors: Matthew B. Lake, Bryon Paul Day
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Patent number: 7413624Abstract: The present invention relates to a method for making a multilayer article, wherein said multilayer article comprises: (i) a first layer comprising an acrylic resin; (ii) at least one translucent second layer comprising (a) an acrylic resin, optionally further comprising an impact modifier; (b) a rubber modified thermoplastic resin composition; (c) optionally a rheology modifier; and (d) a visual effects additive; (iii) a third layer comprising an acrylonitrile-butadiene-styrene (ABS) resin; and (iv) an optional backing layer comprising either a thermosetting polymer substrate, optionally fiber-reinforced, or glass filled ABS resin; and wherein said method comprises the steps of: (I) drying the components of the second layer, either individually or in combination, to a volatiles content of less than 0.06 weight % prior to processing a mixture comprising said components to form said second layer; and (II) coextruding the second and third layers, and optionally the first layer to form the multilayer article.Type: GrantFiled: April 21, 2005Date of Patent: August 19, 2008Assignee: SABIC Innovative Plastics IP B.V.Inventors: Sandeep Dhawan, Douglas W. Howie, Jr.
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Patent number: 6954983Abstract: A method for continuously producing flat cables with electric conductors embedded in an isolating material which are arranged at a certain distance from each other, parallel to each other. According to this invention, the band shaped conductors are guided separately in a plane forming two sides of a surface. The surface sides have insulating layers based on thermoplastic synthetic materials. According to this invention, at least one of the insulating layers which covers the surface sides is produced by extrusion coating of a thermoplastic melt.Type: GrantFiled: November 14, 2001Date of Patent: October 18, 2005Assignee: Reifenhäuser GmbH & Co MaschinenfabrikInventors: Karl Fröschl, Frank Bennerscheidt, Hartmut Halter
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Patent number: 6852405Abstract: Disclosed is a composite sheeting comprised of polystyrene having a thin protective layer of an acrylic ester polymer and a process for producing the composite sheeting. The process comprises joining a molten stream of each polymeric material in a single extruder discharge conduit such that there is produced a single molten stream having a reasonably well defined interface between the two types of polymeric material, and thereafter, passing the resulting single stream of material through a sheet-form extrusion die having its die lips generally aligned with the foregoing interface.Type: GrantFiled: June 14, 2001Date of Patent: February 8, 2005Assignee: AtofinaInventors: Robert A. Wanat, Leslie A. Cohen
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Publication number: 20040232581Abstract: The present invention relates to a method of producing a plank product and related components having a controllable and realistic wood-grain appearance, the planks and related components having at least one accent color, the method including the steps of: a) introducing into an extruder a powdered or pelletized base material and accent color pellets, the base material containing less than about 75% by weight wood flour, and having a vicat softening temperature, the accent color pellets (i) having a higher vicat softening temperature than said base material, and (ii) including a styrene polymer having a high vicat softening temperature and a melt flow index of greater than or equal to 1.Type: ApplicationFiled: June 21, 2004Publication date: November 25, 2004Applicant: CertainTeed CorporationInventor: Richard Arnold Hills
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Patent number: 6780367Abstract: A method for preparing a concrete article comprised of concrete having therein a reinforcing fiber, where at least about 50 percent of the reinforcing fibers are frayed only at an end or ends of the reinforcing fibers, may be made by mixing concrete, water and a reinforcing fiber for a sufficient time to fray the ends of at least 50 percent of the fibers and curing the mixture to form the concrete article.Type: GrantFiled: June 26, 2001Date of Patent: August 24, 2004Assignee: Dow Global Technologies Inc.Inventors: Aleksander J. Pyzik, Kenneth B. Stewart, Jr., Hari Reddy, Kwanho Yang, Sharon M. Allen, Ted A. Morgan
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Publication number: 20030218266Abstract: The present invention relates to a method of producing a plank product and related components having a controllable and realistic wood-grain appearance, the planks and related components having at least one accent color, the method including the steps of: a) introducing into an extruder a powdered or pelletized base material and accent color pellets, the base material containing less than about 75% by weight wood flour, and having a vicat softening temperature, the accent color pellets (i) having a higher vicat softening temperature than said base material, and (ii) including a styrene polymer having a high vicat softening temperature and a melt flow index of greater than or equal to 1.Type: ApplicationFiled: March 14, 2003Publication date: November 27, 2003Inventor: Richard Arnold Hills
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Patent number: 6572806Abstract: A multilayered biaxially-oriented styrene based resin sheet comprises; a styrene based resin layer (A) as at least two outer layers formed by the polymerization of methacrylic acid in a weight proportion of 1˜3.5% and styrene, and a styrene based resin layer (B) formed from polystyrene which is sandwiched between the outer layers and for which the loss tangent (tan &dgr;) maximum peak value temperature for dynamic viscoelasticity measurement is 6.5˜25° C. lower than that for the resin of the resin layer (A). The sheet has excellent properties of transparency and external appearance, can be reused by recovering and moreover does not suffer from raindrop occurrence by secondary forming.Type: GrantFiled: September 29, 2000Date of Patent: June 3, 2003Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Satoshi Oya, Hidetsugu Sawada, Akio Toyoda, Kosuke Arai, Nobuyuki Konishi, Koji Adachi
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Publication number: 20030015819Abstract: An elastic web of material has a multiplicity of stems extending from at least one side of the web. The web includes a first continuous layer of elastic material having a first side and a second side and a second layer of material. The second layer of material has a first side which faces the first side of the first layer and a second side from which the stems extend. The first and second layers of material are joined together. The second layer of material can be formed of thermoplastic material or melt processable polymeric material. The first and second layers of material are melt formed. They are joined by coextrusion or lamination to form a multiple layer sheet on which a multiplicity of stems are formed on at least the second layer by a process such as embossing the stems into the heated web using a patterned roll or mold.Type: ApplicationFiled: September 9, 2002Publication date: January 23, 2003Applicant: 3M Innovative Properties CompanyInventors: Leon Levitt, Robert D. Kampfer, Michael D. Delmore, Stephen E. Krampe, Brandon T. Berg, Alan J. Sipinen, Mark E. Napierala, Victor P. Thalacker
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Patent number: 6406653Abstract: A multilayer sheet, which is particularly well adapted for use as as a label sleeve on carbonated beverage containers, includes first and second coextruded unfoamed layers of polymer compositions each consisting essentially of polyolefin, polystyrene and a compatibility agent. The polyolefin and polystyrene are in a weight ratio in the range of about 30/70 to 70/30, and the compatibility agent is in the amount of about 5% to 10% by total weight. A pigment in the amount of about 10% to 15% by total weight may be included in one or both of the coextruded layers. The polyolefin preferably is selected from the group consisting of polypropylene, polyethylene and mixtures thereof, and the compatibility agent preferably comprises a styrene-ethylene/butylene-styrene block copolymer. One of the unfoamed layers preferably is thicker and of higher strength than the other layer, while the other layer has a smooth uniform exterior surface.Type: GrantFiled: November 19, 1999Date of Patent: June 18, 2002Assignee: American Fuji Seal, Inc.Inventors: Maurice W. Blackwelder, Louis M. DiBello
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Patent number: 6340530Abstract: Book covers and a substantially transparent, coextruded matte, bilayer nylon film which is contact transparent to a paper stock to form a soft book cover having high scratch, abrasion and mar resistance, a soft feel and good moisture curl properties. A substantially transparent, coextruded film which has a first nylon layer attached adjacent to a second nylon layer, the first nylon layer has from about 20 weight percent to about 70 weight percent of a refractory filler based on the weight of the first nylon layer.Type: GrantFiled: April 28, 2000Date of Patent: January 22, 2002Assignee: Honeywell International Inc.Inventors: Simon J. Porter, Jeffrey D. Moulton, Lance R. Altizer