Biaxial Stretching Of Film Patents (Class 264/235.8)
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Patent number: 11794397Abstract: In one example embodiment, disclosed is a biaxially oriented multilayer film, which may include a first tie layer and a second tie layer, wherein each has an inside surface and an outside surface. The film's core layer may consist of: (i) at least 50 wt. % high-crystalline polypropylene; (ii) both cyclic olefin copolymer and polypropylene homopolymer, or, polypropylene heterophasic copolymer; (iii) and, optionally, additives, wherein the core layer is between the inside surface of the first tie layer and the inside surface of the second tie layer. The film may also include a first skin layer on the outside surface of the first tie layer and a second skin layer on the outside surface of the second tie layer, wherein shrinkage is less than 3.5% in a transverse direction for the biaxially oriented multilayer film after subjecting the biaxially oriented multilayer film to 135° C. for 7 min at 1 atm.Type: GrantFiled: July 15, 2021Date of Patent: October 24, 2023Assignee: Jindal Films Americas LLCInventors: Thierry J. L. Dabadie, Gabriel Domingos, Alain Marchal, François Gastineau
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Patent number: 11594765Abstract: In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.Type: GrantFiled: September 7, 2021Date of Patent: February 28, 2023Assignee: Celgard, LLCInventors: Paul M. Halmo, Xiaomin Zhang, Paul D. Vido, Zhengming Zhang, Lie Shi, Daniel R. Alexander, Jill V. Watson
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Patent number: 11504940Abstract: A laminated assembly extends in a longitudinal direction and a lateral direction orthogonal to the longitudinal direction, the assembly including a non-woven sheet and an elastic film that are laminated together, the non-woven sheet including at least one activated zone extending over the length of the non-woven sheet measured in the longitudinal direction and over a width that is strictly less than the width of the non-woven sheet measured in the lateral direction, the degree of activation of the activated zone of the non-woven sheet in the lateral direction being different from the degree of activation of the elastic film in the lateral direction, the degree of activation of the activated zone of the non-woven sheet in the lateral direction lying in the range 20% to 200%.Type: GrantFiled: July 11, 2017Date of Patent: November 22, 2022Assignee: APLIXInventors: Nathalie Moinard, Thierry Marche
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Patent number: 11434353Abstract: A method, and product thereof, for modifying the surface of recycled sulfur-cured rubber via surface devulcanization that minimizes alteration of the network structure of the recycled sulfur-cured rubber, while generating strong tack between mixed recycled rubber and fresh rubber for optimal adhesion upon subsequent co-curing. In one embodiment, the surface of recycled rubber is devulcanized by treating recycled rubber with a thiol and a base dissolved in a solvent that does not effectively penetrate and only minimally swells vulcanized rubbers.Type: GrantFiled: February 11, 2020Date of Patent: September 6, 2022Assignee: APPIA, LLCInventors: Georg Bohm, Xuesong Yan, Yu Sun, Li Jia
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Patent number: 10557024Abstract: A sustainable thermoplastic composition made by forming a mixture of virgin polypropylene and post-industrial-recycled material (PIR). The PIR may include a thermoplastic, elastomeric-polymer and a spunbond component. The mixture is melt-blended in an extruder. Extruded materials made from the mixture demonstrate little variance in the results of the IZOD Impact Test of materials containing 30 to 70 percent PIR, and a material containing 100 percent virgin polypropylene. In addition, the extruded materials containing 30 to 70 percent PIR demonstrate a substantially constant strain at yield, that strain at yield being substantially equal to that demonstrated by a material containing 100 percent virgin polypropylene.Type: GrantFiled: December 23, 2013Date of Patent: February 11, 2020Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Brent Merrik Thompson, James Hongxue Wang, Gregory James Wideman
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Patent number: 10137625Abstract: A laminate film including at least one bio-based polyester layer. The polyester layer has a radiocarbon (14C) content of at least 21.5 pMC. The laminate film may further have additional layers such as a second bio-based polyester resin-containing layer of at least about 21.5 pMC radiocarbon content, a metal layer, or combinations thereof.Type: GrantFiled: July 8, 2011Date of Patent: November 27, 2018Assignee: TORAY PLASTICS (AMERICA), INC.Inventors: Stefanos L. Sakellarides, Keunsuk P. Chang
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Patent number: 10121724Abstract: A heat diffusion sheet 2 has a configuration in which a composite adhesive film is formed on a surface of a graphite sheet 10 having a thickness of 300 ?m or more and 2,000 ?m or less. This composite adhesive film has a configuration in which (A) an acrylic adhesive layer that has a thickness of 5 ?m or more and 15 ?m or less and does not contain a thermally conductive material, (B) a polyester film having a thickness of 20 ?m or more and 60 ?m or less, and (C) a silicone adhesive layer that has a thickness of 2 ?m or more and 25 ?m or less, does not contain a thermally conductive material, and has a peel strength of 0.005 N/cm or more and 1.0 N/cm or less are sequentially layered on the graphite sheet 10.Type: GrantFiled: February 17, 2015Date of Patent: November 6, 2018Assignee: DEXERIALS CORPORATIONInventors: Minoru Nagashima, Teruo Hiyama
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Patent number: 10086557Abstract: Disclosed is a method for manufacturing a film. 50 wt % to 85 wt % of a first polyester and 50 wt % to 15 wt % of a second polyester are dried and mixed to form a mixture. The first polyester is polyethylene terephthalate (PET), polyethylene naphthalate (PEN), or combinations thereof. The second polyester is copolymerized of 1 part by mole of terephthalic acid, m parts by mole of 1,4-cyclohexanedimethanol (1,4-CHDM), n parts by mole of 1,3-cyclohexanedimethanol (1,3-CHDM), and o parts by mole of ethylene glycol (EG). m+n+o=1, 0?o?0.4, 0.6?m+n?1, and 0.06?n/m?1.31. The mixture is melted and blended to form a polyester composition, which is extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a thermal setting.Type: GrantFiled: December 23, 2013Date of Patent: October 2, 2018Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Cheng-Hsing Fan, Chun-Yen Chen, Ming-Tsong Leu, Chien-Pang Wu
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Patent number: 9453114Abstract: Provided is a polyester film having excellent high-temperature dimensional stability. More particularly, provided is a method for producing a polyester film, including: a) extruding and cooling a polyester resin to provide a non-oriented sheet; b) orienting the sheet in the machine direction (MD); c) orienting the MD oriented sheet in the transverse direction (TD); d) heat treating the sheet; and e) carrying out simultaneous relaxation by subjecting the heat treated sheet to MD relaxation at a ratio of 1% or higher, while subjecting it to TD relaxation in a tenter. Provided also is a polyester film obtained by the method.Type: GrantFiled: September 2, 2009Date of Patent: September 27, 2016Assignee: KOLON INDUSTRIES, INC.Inventors: Yun Jo Kim, Gi Sang Song, Si Min Kim
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Patent number: 8778247Abstract: The invention relates to a polymer film made of a polyamide composition comprising at least 80 weight percentage (wt. %) of a semi-crystalline semi-aromatic polyamide with a melting temperature (Tm) of at least 270° C., wherein the wt. % is relative to the total weight of the polymer composition, wherein the polymer film has an average coefficient of thermal expansion in plane in the temperature range of 20° C.-Tg, measured in plane with the method according to ASTM D969-08, of at most 40 ppm/K. The said film can be made from a polyamide moulding composition comprising said polyamide by film casting followed by biaxial stretching. The film has properties suitable for carrier films in flexible printed circuit boards.Type: GrantFiled: January 15, 2010Date of Patent: July 15, 2014Assignee: DSM IP Assets B.V.Inventors: Alexander Antonius Marie Stroeks, Guido Richard Struijk
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Patent number: 8747713Abstract: Flexible tubular film (10) is helically cut into a flat strip by unwinding the tubular film in flattened form by a tumbling unwinder (1), advancing the flat film tube to a tube expansion zone (17) in which the flat tube is expanded into a circular cylindrical tube and is passed axially over a hollow mandrel (14) slightly lower in external diameter than the diameter of the expanded tube to be cut by knife (18) helically while on the mandrel into a flat strip that is removed at an angle to the mandrel axis. The flat tube is longitudinally stretched by stretching rollers (107-112), which tumble with the tumbling unwinder. The apparatus further comprises stabilization means for stabilizing the orientation applied by the tumbling stretching rollers, applied to the helically cut film strip after it has been drawn from the mandrel.Type: GrantFiled: July 22, 2009Date of Patent: June 10, 2014Inventors: Ole-Bendt Rasmussen, Nikolaj Wettergren Rasmussen
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Patent number: 8728371Abstract: A method of producing a stretched film comprising melt-coextruding a thermoplastic resin A and a thermoplastic resin B to produce a composite film 1 having both-end films 2 of the thermoplastic resin B arranged in parallel at both end portions of the main film 1a of the thermoplastic resin A in the direction of width thereof, stretching the composite film, and cutting and removing both end portions of the stretched film in the direction of width, wherein a film stretch stress value of the both-end films 2 is larger than a film stretch stress value of the main film 1a at the same stretching ratio. This minimizes an increase in the thickness at both end portions of the film in stretching the film and decreases the widths by which both end portions of the expensive resin film are to be cut and removed for producing a film.Type: GrantFiled: December 7, 2007Date of Patent: May 20, 2014Assignee: Toyo Kohan Co., Ltd.Inventors: Norimasa Maida, Yoshimi Itoh, Toshiyuki Ueda
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Patent number: 8722161Abstract: Disclosed is a heat shrinkable polyester film formed from a polyester resin that is mainly composed of ethylene terephthalate and contains 3-12% by mole (inclusive) of one or more monomer components, which can be amorphous components, relative to all the polyester resin components, in which the heat shrinkable polyester film has a main shrinkage direction which is the width direction. The heat shrinkable polyester film is characterized in that the shrinkage in 80° C. glycerin, the shrinkage in 130° C. glycerin and the tensile breaking strength in the longitudinal direction are controlled within specific ranges.Type: GrantFiled: March 16, 2011Date of Patent: May 13, 2014Assignee: Toyo Boseki Kabushiki KaishaInventors: Masayuki Haruta, Yukinobu Mukoyama, Katsuya Ito
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Patent number: 8691132Abstract: Stretch film is treated by passing a web of tackifier-containing, unbloomed thin polymer film through a heater so that the web is heated to a temperature sufficient to cause tackifier bloom prior to the web reaching a next stage in an in-line process. Also, a pattern can be applied to a thin polymer film. An oriented web of thin polymer film is passed across at least one heated roller having the pattern engraved thereon to define face regions and relief regions collectively conforming to the pattern. As the web contacts each roller surface, portions of the web positioned over the relief regions receive less heat than portions of the web positioned over the face regions, thereby causing the respective portions of the web to undergo differential, heat-induced shrinkage which imparts the pattern to the thin polymer film.Type: GrantFiled: August 18, 2009Date of Patent: April 8, 2014Assignee: Macro Engineering & Technology, Inc.Inventor: Miroslav Planeta
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Patent number: 8685305Abstract: The invention aims at providing a heat-shrinkable polyester film which is excellent in tearability along perforations and in break resistance after storage when used as labels of beverage bottles. The invention relates to a heat-shrinkable polyester film which is made of a polyester resin comprising ethylene terephthalate as the main constituent and containing at least 13 mol % of at least one monomer capable of forming an amorphous component in the whole polyester resin component and which has specific heat shrinkage characteristics and exhibits specific mechanical characteristics after heat shrinking treatment. The film can be produced by a sequential biaxial orientation process comprising longitudinal orientation step, intermediate heat treatment step, positive cooling step, transverse orientation step, and final heat treatment step.Type: GrantFiled: September 24, 2008Date of Patent: April 1, 2014Assignee: Toyo Boseki Kabushiki KaishaInventors: Masayuki Haruta, Masatoshi Hashimoto, Masakazu Iwasaki, Katsuhiko Nose
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Patent number: 8617445Abstract: The present invention provides a process for producing an oriented thermoplastic polyester resin sheet which is excellent in tensile strength, tencile modulas and heat resistance, and a light laminate-molded body using the same, which has a low linear expansion coefficient and is excellent in impact resistance, durability, easiness of handling, productivity, and others. A process for producing an oriented thermoplastic polyester resin sheet, which includes: pultrusion-drawing a thermoplastic polyester resin sheet in an amorphous state at a temperature from the glass transition temperature of the thermoplastic polyester resin ?20° C. to the glass transition temperature of the thermoplastic polyester resin +20° C.; and then drawing the resultant uniaxially at a temperature higher than the temperature for the pultrusion-drawing. A laminate-molded body, wherein a thermoplastic resin layer is laminated on each of the surfaces of the resultant oriented thermoplastic polyester resin sheet.Type: GrantFiled: February 17, 2006Date of Patent: December 31, 2013Assignee: Sekisui Chemical Co., Ltd.Inventors: Shigeru Ogasawara, Hirotsugu Yoshida, Hisashi Eguchi, Ryuichi Matsuo
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Patent number: 8592028Abstract: The invention relates to A bi-axially stretched breathable film comprising a polymeric mixture, said polymeric mixture comprising based on the total weight of the polymeric mixture/—at least 50% of at least one polyether block copolymer; and —from 0.5 to less than 50% of at least one polyester. The invention also relates to a method to manufacture said film, and uses of said film. The invention also relates to a method for producing a bi-axially stretched breathable film comprising at least one polyether block copolymer.Type: GrantFiled: August 25, 2006Date of Patent: November 26, 2013Assignee: DuPont Teijin Films U.S. Limited PartnershipInventors: Lucien Schosseler, Alexis Grosrenaud, Duncan Henry MacKerron, Valery Rebizant
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Patent number: 8529817Abstract: The present invention provides a stretched thermoplastic resin foam sheet that has excellent flexibility even compressed to a thickness as thin as about 0.05 mm, and a method for producing the same. The stretched thermoplastic resin foam sheet of the present invention is producible by stretching a thermoplastic resin foam sheet and has a compressive strength of 1 to 500 kPa as measured in accordance with JIS K6767 when compressed in a thickness direction thereof to a thickness of 0.05 mm. Accordingly, the stretched thermoplastic resin foam sheet has excellent flexibility even compressed to a thickness as thin as about 0.05 mm and is suitably used as a sealing material for a small electronic device such as mobile phones.Type: GrantFiled: September 26, 2008Date of Patent: September 10, 2013Assignee: Sekisui Chemical Co., Ltd.Inventors: Takumei Uno, Eiji Tateo, Futoshi Kanazawa
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Patent number: 8518321Abstract: Biaxially-oriented nylon film according to the present invention is biaxially-oriented nylon film made from nylon. In the biaxially-oriented nylon film, an elongation ratio of the film in each of four directions (an MD direction, a TD direction, a 45 degree direction and a 135 degree direction) until a film rupture is 70 percent or more, the elongation ratio being measured in a tensile test (testing conditions: a sample width is 15 mm; a distance between gauge points is 50 mm; and a tensile speed is 100 mm/min), and a stress ratio A (?1/?2) between a tensile stress ?1 and a tensile stress ?2 in a stress-strain curve obtained in the tensile test of the film is 2 or more in each of the four directions, the tensile stress ?1 being a value at a point where the elongation ratio becomes 50 percent while the tensile stress ?2 being a value at an yield point.Type: GrantFiled: August 10, 2007Date of Patent: August 27, 2013Assignee: Idemitsu Unitech Co., Ltd.Inventor: Masao Takashige
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Publication number: 20130213581Abstract: The present invention provides a film of an oriented material which exhibits the property of expansion in at least one of its machine and transverse directions at a first temperature and of shrinkage at a second, higher, shrink onset temperature, the film having been annealed after orientation at a temperature above the first temperature and selected with reference to an intended recycling wash-off process to promote expansion of the film at the selected temperature of the wash-off process.Type: ApplicationFiled: September 7, 2011Publication date: August 22, 2013Applicant: Innovia Films LimitedInventors: Michael Taylor, Richard Waning, Barry Frizell
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Patent number: 8486521Abstract: The present invention relates to a microporous polyethylene film for use as battery separator. The microporous polyethylene film according to the present invention is characterized by having a film thickness of 5-40 ?m, a porosity of 35-55%, a permeability from 2.5×10?5 to 10.0 10?5 Darcy, a puncture strength of at least 0.10 N/?m at 90° C., a puncture angle of at least 30° at 90° C., and a permeability from 2.0 10?5 to 8.0 10?5 Darcy after shrinking freely at 120° C. for 1 hour. The microporous polyethylene film in accordance with the present invention has very superior puncture strength and thermal stability at high temperature and takes place of less decrease of permeability due to low thermal shrinkage at high temperature, as well as superior permeability. Therefore, it can be usefully applied in a high-capacity, high-power battery to improve thermal stability and long-term stability of the battery.Type: GrantFiled: September 11, 2008Date of Patent: July 16, 2013Assignee: SK Innovation Co., Ltd.Inventors: Inhwa Jung, Jang-Weon Rhee, Gwigwon Kang, Youngkeun Lee, Yongkyoung Kim
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Patent number: 8435432Abstract: Retardation expressibility of a transparent polymer film can be easily controlled by heat treatment of the film at a temperature T (unit, ° C.) satisfying a condition of the following formula (1): Tc?T<Tm0??Formula (1) wherein Tc represents the crystallization temperature (unit, ° C.) of the film before the heat treatment; and Tm0 represents the melting point (unit, ° C.) of the film before the heat treatment.Type: GrantFiled: February 21, 2007Date of Patent: May 7, 2013Assignee: FUJIFILM CorporationInventor: Yasuyuki Sasada
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Patent number: 8414803Abstract: A method for producing a transparent polymer film, comprising heat-treating a polymer film containing a polymer and a plasticizer having a number-average molecular weight of from 500 to 10000 and having a repetitive unit, at a temperature T (unit, ° C.) satisfying the following formula (1): Tc?T<Tm0??(1) wherein Tc means the crystallization temperature of the polymer film and Tm0 means the melting point of the polymer film.Type: GrantFiled: July 29, 2008Date of Patent: April 9, 2013Assignee: FUJIFILM CorporationInventors: Yasuo Mukunoki, Yasuyuki Sasada
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Patent number: 8323547Abstract: Disclosed in the present invention are a microporous polyethylene film and a method of manufacture thereof. The polyethylene microporous film manufactured according to the present invention may contribute to an increased productivity of stable products as its extrusion and stretching may be done readily. And thus manufactured product may be used for battery separators and various filters owing to its high gas permeability, superior puncture strength, and small ratio of shrinkage.Type: GrantFiled: May 24, 2007Date of Patent: December 4, 2012Assignee: SK Innovation Co., Ltd.Inventors: Young-Keun Lee, Jang-Weon Rhee, Jung-Moon Sung, Byoung-Cheon Jo, Chol-Ho Lee, Gwi-Gwon Kang, In-Hwa Jung, Je-An Lee
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Patent number: 8273447Abstract: A multilayer oriented film comprising at least one layer (a) comprising one or more polyesters and/or copolyesters characterized by a % of crystallinity higher than 15, an adjacent layer (b) comprising one or more polyolefin-based adhesive resins, and a layer (c) comprising one or more co-polyesters characterized by a % of crystallinity lower than 15, is positioned between said two layers (a) and (b) in such a way that one of the two principal surfaces of layer (c) is directly adhered to layer (a) and the other is directly adhered to layer (b). The presence of a co-polyester layer (c) of relatively low % crystallinity positioned between (co)polyester layer (a) and adhesive layer (b) remarkably increases the bond between the two layers (a) and (b) and prevents delamination problems in the oriented structure.Type: GrantFiled: January 19, 2007Date of Patent: September 25, 2012Assignee: Cryovac, Inc.Inventor: Roberto Forloni
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Patent number: 8268215Abstract: A laminated film for a reflecting plate is provided that comprises a layer A and a layer B, the layer A comprising a polyester that comprises substantially no antimony element and preferably comprises 1 to 25 wt % of inert particles having an average particle diameter of 0.3 to 3.0 ?m and the layer B being in contact with the layer A and comprising a polyester which preferably comprises 31 to 80 wt % of inert particles having an average particle diameter of 0.3 to 3.0 ?m. This laminated film has a practically satisfactory capability of reflecting visible light, can be produced stably even if inert particles are added in high concentration, hardly has streak-like defects, and can be suitably used as a substrate for a reflecting plate for a liquid crystal display or an internally illuminating electrical billboard.Type: GrantFiled: June 16, 2005Date of Patent: September 18, 2012Assignee: Teijin Dupont Films Japan LimitedInventors: Hiroshi Kusume, Atsushi Oyamatsu
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Patent number: 8187683Abstract: An object of the present invention is to provide a multilayered polyamide-based tube for food packaging that is free from blocking in a Layer (C), and that has an excellent adherence to processed meat or like packaged food. The present invention provides a multilayered polyamide-based tube for food packaging comprising a Layer (A), a Layer (B) and a Layer (C); the multilayered polyamide-based tube having a low-temperature shrinkage ratio of 2 to 10%, and exhibiting heat shrinkage properties and gas barrier properties; the Layer (A) containing a polyamide-based resin; the Layer (B) containing a polyolefin-based resin; and the Layer (C) that comes in contact with the packaged food, the Layer (C) being a Layer (C-1) that contains a polypropylene-based resin having a heat distortion temperature (ISO 75B-1 or ISO 75B-2) of not less than 60° C. and a Vicat softening point of not less than 120° C.Type: GrantFiled: March 26, 2009Date of Patent: May 29, 2012Assignee: Gunze LimitedInventors: Hiroki Kuriu, Hiroyuki Yabuta
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Patent number: 8178210Abstract: The invention relates to a high modulus, bi-axially oriented film, heat-shrinkable or non heatshrinkable, comprising a first outer layer comprising a polyester or a copolyester, a second outer layer comprising an ethylene or propylene homo- or co-polymer, a core layer comprising an ethylene-vinyl alcohol copolymer, and no core polyamide or polyester layers. The film according to the present invention is prepared by orienting biaxially a flat extruded tape by means of a tenter frame, preferably simultaneously, and has a modulus higher than 6,000 kg/cm2 in at least one direction. The film of the present invention is particularly useful, in the non heat-shrinkable version, for food and non food packaging applications.Type: GrantFiled: July 21, 2004Date of Patent: May 15, 2012Assignee: Cryovac, Inc.Inventors: Roberto Forloni, Eugenio Longo
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Patent number: 8153044Abstract: A thermoplastic film is transversely stretched, and then transported in a heat-treating zone (46) such that the ratio (G/D) of an inter-roll distance (G) to a roll lap length (D) is 0.01 to 3, and the ratio (V2/V1) of an exit-side transporting speed (V2) to an entry-side transporting speed (V1) is 0.6 to 0.999. The thermoplastic film is heat-treated in the heat-treating zone (46) at (Tg?20)° C. to (Tg+50)° C., in which Tg is the glass transition temperature of the film. The heat-treated thermoplastic film exhibits an Rth/Re ratio of at least 0.5 and less than 1, an Rth/Re ratio range of 0.01 to 0.1 in the width direction, and a thermal dimensional change of 0.001% to 0.3% under conditions of 80° C. and 200 hours.Type: GrantFiled: April 17, 2008Date of Patent: April 10, 2012Assignee: Fujifilm CorporationInventors: Kiyokazu Hashimoto, Tetsuya Yoshida, Masaaki Otoshi
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Patent number: 7887727Abstract: The present invention relates to a process for manufacturing a microporous polyolefin film which can be used for various battery separators, separating filters and membranes for microfiltration. The process for manufacturing a microporous polyolefin film according to the invention comprises mixing/extrusion through efficient and separate injection of 15-55% by weight of polyolefin (Component I), and 85-45% by weight of a diluent (Component II) which forms thermodynamic single phase with the polyolefin and a diluent (Component III) which can undergo thermodynamic liquid-liquid phase separation with the polyolefin, into an extruder.Type: GrantFiled: December 12, 2007Date of Patent: February 15, 2011Assignee: SK Energy Co., Ltd.Inventors: Young-keun Lee, Jang-weon Rhee, Gwi-gwon Kang, In-hwa Jung
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Patent number: 7879272Abstract: An oriented thermoplastic elastomer film having reduced permeability and improved fatigue resistance comprising a dynamically vulcanized polymer blend of (A) a halogenated isobutylene elastomer and (B) polyamide, the film is produced by casting or blowing the above polymer blend under the condition such that a shear rate at a die lip for casting or blowing is regulated to control the molecular arrangement in the film, whereby the planar birefringence (PBR) of the resultant film becomes greater or equal to 0.002 and a production process of the same.Type: GrantFiled: December 28, 2009Date of Patent: February 1, 2011Assignees: ExxonMobil Chemicals Patents, Inc., The Yokohama Rubber Co., Ltd.Inventors: Yoshihiro Soeda, Andy Haishung Tsou, Foshee Joyce Caraway
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Patent number: 7815825Abstract: The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.Type: GrantFiled: December 12, 2008Date of Patent: October 19, 2010Assignee: Tonen Chemical CorporationInventors: Hidehiko Funaoka, Kotaro Takita, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
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Patent number: 7744806Abstract: As a first aspect, the present invention is directed to a process for making a heat-shrinkable annular film, comprising: (A) extruding an annular extrudate downward from an annular die; (B) quenching the annular extrudate by applying a quenching liquid to the annular extrudate; (C) reheating the extrudate to an orientation temperature of from 130° F. to 210° F., resulting in a reheated annular extrudate; and (D) orienting the reheated annular extrudate while the reheated annular extrudate is in the solid state, the orientation being carried out with a total orientation factor of at least 2, so that the resulting oriented, heat-shrinkable film has a total free shrink at 185° F. of at least 10 percent. The extrudate comprises at least one semi-crystalline polyamide selected from the group consisting of: (i) polyamide 6, (ii) polyamide 66, (iii) polyamide 6/66, and (iv) polyamide 6/12. The semi-crystalline polyamide makes up at least 5 volume percent of the annular extrudate.Type: GrantFiled: January 29, 2007Date of Patent: June 29, 2010Assignee: Cryovac, Inc.Inventors: Michael E. Broadus, Richard M. Dayrit, Bryan E. Freeman, Frank M. Hofmeister, Brian P. Rivers, Roger D. Vrooman, Christopher K. Robinson, George D. Bolden, Robert W. Campbell, Nathanael R. Miranda
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Patent number: 7718104Abstract: A process for the production of a polymeric film comprising a copolyester having an acid component and a diol component, said acid component comprising a dicarboxylic acid and a sulfomonomer containing a sulfonate group attached to the aromatic nucleus of an aromatic dicarboxylic acid, said process comprising the steps of: (i) melt-extruding a layer of said copolyester; (ii) stretching the extrudate in at least one direction; (iii) heat-setting the film by raising the temperature of the stretched film to a temperature T1 in a first heating zone such that (TM-T1) is in the range of from 5 to 30° C., and then raising the temperature of the film to a temperature T2 in a second heating zone such that (TM-T2 is in the range of from 0 to 10° C.Type: GrantFiled: December 6, 2002Date of Patent: May 18, 2010Assignee: Dupont Teijin Films US Ltd.Inventors: William Alasdair MacDonald, Pierre Georges Osborne Moussalli, Kenneth Evans, Julian Peter Attard, David Boyce, Christopher Charles Naylor, Brian John Farmer, legal representative, David Edward Robins, legal representative
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Patent number: 7615183Abstract: The invention provides polylactic acid (PLA) films substantially free of plasticizers and methods of manufacturing same by blown film process are provided. PLA films are environmentally degradable and have applications in, at least, packaging and labeling.Type: GrantFiled: November 3, 2006Date of Patent: November 10, 2009Assignee: Plastic Suppliers, Inc.Inventors: Edward Carl Tweed, Henry Mike Stephens, Theodore Emil Riegert
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Publication number: 20080143016Abstract: A film feeding machine includes a drawing device to draw a continuous film out of a film base to a predetermined position. The film is held by a feeding device and cut off by a cutting device to have a film piece. The film piece is fed to external equipment by the feeding device. The film feeding machine of the present invention is incorporated in a molding process having advantages of lower cost, lower defective ratio and high production efficiency.Type: ApplicationFiled: February 12, 2007Publication date: June 19, 2008Applicant: Snyang Yu Enterprise Co., Ltd.Inventor: Tsung-Wen Yu
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Patent number: 7364659Abstract: A porous polyethylene hollow fiber membrane having a pore-size gradient across the inner and outer surfaces thereof is prepared by introducing, during the cooling step of a melt-spun polyethylene hollow fiber, a nitrogen flow and a solvent having a boiling point in the range of 30 to 80° C. to the inner and outer surfaces of the melt-spun hollow fiber, respectively.Type: GrantFiled: August 24, 2005Date of Patent: April 29, 2008Assignee: KMS Co., Ltd.Inventors: Moon-Seog Jang, Sung-Soo Kim, Myung-Nam Han, Jin-Ho Kim, Min-Soo Park
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Publication number: 20070237972Abstract: The invention relates to a multilayer polyester film comprising a hydrolysis stabilizer, wherein the hydrolysis stabilizer is an epoxidized alkyl ester of fatty acid or is a mixture of epoxidized alkyl esters of fatty acid or is an epoxidized fatty acid glyceride or is a mixture of epoxidized fatty acid glycerides, and at least one external layer of the film does not comprise the hydrolysis stabilizer. The form in which the hydrolysis stabilizer is added to the polyester can be that of dry liquid, absorbed by a carrier material.Type: ApplicationFiled: March 30, 2007Publication date: October 11, 2007Inventors: Holger KLIESCH, Martin Jesberger, Bodo Kuhmann, Ingo Fischer, Dagmar Klein
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Patent number: 7229581Abstract: Invention relates to a process for producing a single-layer or multilayer film by extrusion or coextrusion, biaxial orientation, and heat setting based on crystallizable thermoplastics whose principal constituent is a crystallizable thermoplastic having a standard viscosity SV (DCA) of from 600 to 1000. The thermoplastic is mixed prior to extrusion or coextrusion with 50% by weight (based on the total weight of all thermoplastics) of a secondary thermoplastic having a standard viscosity SV (DCA) of more than 900 to 1500, the standard viscosity SV (DCA) of the two thermoplastics differing by at least 100 units. The secondary thermoplastic is a byproduct or waste product from the production of PET plastic bottles or originates from recycled PET bottles.Type: GrantFiled: November 5, 2003Date of Patent: June 12, 2007Assignee: Mitsubishi Polyester Film GmbHInventors: Ulrich Kern, Ursula Murschall, Holger Kliesch
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Patent number: 7214339Abstract: The object of the present invention is to provide a method for producing a polyester film excellent in rigidity, toughness, dimensional stability, electric properties, etc. and less in thickness fluctuation and surface defects, hence very suitable as a film for various industrial materials such as magnetic recording media, capacitors, heat transfer ribbons and thermal mimeographic stencil paper. The first method of the present invention is a method for producing a polyester film, in which a film made of a resin mainly composed of a polyester is simultaneously biaxially stretched by a simultaneously biaxially stretching tenter oven, comprising the step of effecting small-ratio stretching at an area stretching ratio of 1.0005 to 3.Type: GrantFiled: September 23, 2002Date of Patent: May 8, 2007Assignee: Toray Industries, Inc.Inventors: Tetsuya Tsunekawa, Takuji Higashioji, Kenji Tsunashima
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Patent number: 7189347Abstract: A biaxially oriented polyamide laminate film having a layered structure of A/B, A/B/A or A/B/C, layer A having no projections with a height of 0.27 ?m or higher on the surface, or having a density of projections with a height of 0.27 ?m or higher on the surface of 200 projections/mm2, and the film exhibiting a maximum dimensional change of 4% or less during immersion in 95° C. hot water, a maximum dimensional change of 6% or less after withdrawal from the hot water, and a maximum dimensional change of 4% or less after heat treatment in dry hot air at 160° C.; and a process for producing the same. This film reduces the differences in physical properties in the width direction that occurs in a tenter and exhibits excellent adhesive properties, resistance to fatigue from flexing and operability, and can be provided economically.Type: GrantFiled: August 22, 2001Date of Patent: March 13, 2007Assignee: Toyo Boseki Kabushiki KaishaInventors: Shinji Fujita, Yukinobu Mukoyama, Katsuya Ito
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Patent number: 7037461Abstract: A method of stretching films in which all or a portion of the width of the film is cooled during or just after stretching so as to improve the uniformity of the film. The includes stretching a polymeric film in a tenter that grasps the film with a plurality of clips along the opposing edges of the film and propels the clips to thereby stretch the film. The tenter includes driven clips and idler clips, with at least one idler clip between respective pairs of driven clips. The cooling is done so as to improve the uniformity of the clip spacing relative to the spacing obtained at otherwise identical process conditions without such cooling.Type: GrantFiled: December 21, 1999Date of Patent: May 2, 2006Assignee: 3M Innovative Properties CompanyInventors: Martin E. Denker, Joseph T. Bartusiak, Anthony B. Ferguson, Thomas P. Hanschen, Jeffery N. Jackson, William Ward Merrill, Susan J. Newhouse, Fred J. Roska, Richard J. Thompson, Chiu Ping Wong
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Patent number: 7001557Abstract: An object of the present invention is to provide a biaxially oriented high quality polyester film excellent in thermal dimensional stability and clarity and also excellent in productivity, and also to provide a production process thereof. Another object is to provide a biaxially oriented polyester film greatly improved in the practical properties respected in various applications of the polyester film, such as the recording track shift in magnetic recording tape application, curling in magnetic recording card application, dimensional change during process in printing plate application, printing shift in ribbon application, thermostability in capacitor application, and perforation sensitivity and low temperature curling in heat-sensitive mimeograph stencil application.Type: GrantFiled: April 10, 2002Date of Patent: February 21, 2006Assignee: Toray Industries, Inc.Inventors: Tetsuya Tsunekawa, Hirofumi Hosokawa, Takuji Higashioji
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Patent number: 6966999Abstract: Oriented films are prepared. A thermoplastic vulcanizate, prepared by mixing at least 20 wt % of a thermoset rubber by weight of the total composition into a thermoplastic polymer are disclosed. After the mixture is prepared the thermoset rubber is entrained as discrete particles within the continuous thermoplastic polymer phase. The resulting composite is subjected to a stress either by pulling, blow molding, or any other film-forming process as is known in the art. This stress causes the continuous phase polymer molecules to become aligned or oriented in the direction in which the stress was applied, thus creating the oriented thermoplastic vulcanizate of the invention. This material has improved gas permeability and improved flexibility properties.Type: GrantFiled: July 2, 2001Date of Patent: November 22, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: Andy H. Tsou, Ilan Duvdevani, Hsien-Chang Wang
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Patent number: 6942831Abstract: A high-CHDM PET-based support for an imaging element can be annealed relatively rapidly to achieve acceptable core-set and post-process curl properties. The fast annealing response of this material allows effective in-line annealing of the film support, yielding a more efficient manufacturing process with less annealing-induced defects in the imaging support.Type: GrantFiled: August 1, 2003Date of Patent: September 13, 2005Assignee: Eastman Kodak CompanyInventors: Jehuda Greener, Beverly A. Contestable, Jeffrey R. Gillmor, YuanQiao Rao
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Patent number: 6919112Abstract: The invention concerns a biaxially stretched and thermoset tubular seamless single- or multi-layered foodstuff skin wherein the layer, or, a multi-layered skin wherein at least one of the layers, contains a block copolymer with “hard” aliphatic polyamide blocks and “soft” aliphatic polyether blocks, the block copolymer corresponding to one of formulae (I) to (III), Ea—(NH—[CH2]x—CO)m—Xa—(A—O)n—A Xa—(CO—[CH2]x—NH)m—Ea (I), (II), —[X—(CO—[CH2]x—NH)o—Y—X—(A—O)p—A]-(III). The invention is particularly suitable as a skin for a sausage which is to be boiled or heated in water, and does not form folds when the filling is introduced manually, with no or only slight pressure.Type: GrantFiled: October 24, 1997Date of Patent: July 19, 2005Assignee: Kalle Nalo GmbH & Co. KGInventor: Ulrich Delius
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Patent number: 6824878Abstract: A thermoplastic film comprising a core layer comprising a polyolefin wherein the core layer comprises the interior of the film; a first transition layer comprising a polyolefin and a silicone additive, wherein the first transition layer is exterior to the core layer; and a first skin layer comprising a polyolefin wherein the first skin layer is exterior to the first transition layer and the core layer.Type: GrantFiled: June 12, 2001Date of Patent: November 30, 2004Assignee: ExxonMobil Oil CorporationInventors: Robert A. Migliorini, Karen A. Sheppard
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Publication number: 20040173944Abstract: Methods of making multilayer structures useful for packaging bone-in meat or other like products are provided. More specifically, the multilayer structures made by the methods provided have sufficient rigidity and strength to contain bone-in meat or other like products, while also maintaining good oxygen barrier properties. In addition, the multilayer structures made by the methods provided can easily seal to themselves or to other structures to provide the packages for the products. Moreover, the multilayer structures made by the methods provided may be biaxially oriented and heat-shrinkable.Type: ApplicationFiled: December 12, 2003Publication date: September 9, 2004Inventors: Chad D. Mueller, Michael J. Douglas, Duane H. Buelow, Robert J. Blemberg, Roberto P. Castellani
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Patent number: 6780371Abstract: There is disclosed a process for inline producing a biaxially oriented releasing film by consecutively orienting a non oriented film (polyethylene terephthalate or polypropylene) in the machine or transverse direction one by one which comprises coating at least one side of a film in a state prior to biaxial orientation with an addition reaction type silicone based releasing agent (e.g. solvent type), preferably incorporated with a photosensitizer; biaxially orienting the film; thereafter heat annealing the same; and subsequently performing ultraviolet ray irradiation. The process enables easy production of the releasing film which is excellent in releasability, non-migration property of silicone, and productivity, and which is well suited for use in the production of pressure sensitive adhesive labels and tapes, ceramic green sheets, synthetic leather, etc.Type: GrantFiled: July 3, 2001Date of Patent: August 24, 2004Assignee: Lintec CorporationInventors: Tomishi Shibano, Toru Nakamura
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Publication number: 20040142194Abstract: The invention relates to a transparent, biaxially oriented polyester film which comprises at least 80% by weight of thermoplastic polyester and also comprises an amount in the range from 0.05 to 0.5% by weight of a specific pigment system. The invention further relates to a process for producing the film. The film can be used as a packaging film, or for metalizing or ceramic coating, and in applications in the industrial sector, as a substrate for stamping foils.Type: ApplicationFiled: December 18, 2003Publication date: July 22, 2004Inventors: Herbert Peiffer, Martin Mueller-Roosen, Gottfried Hilkert