Biaxial Stretching Of Film Patents (Class 264/235.8)
  • Publication number: 20040135286
    Abstract: A method for producing a nonwoven web material having cross-machine direction extensibility in which a nonwoven web is conveyed through a machine which elongates the nonwoven web in a cross-machine direction (CD). The elongated nonwoven web is then necked, forming a cross-machine direction extensible nonwoven web material. The CD extensible nonwoven web material is highly stretchable and is suitable for use in personal care articles, such as diapers, incontinence garments, and feminine care products, as well as other articles, such as wipes, face masks, tissues, bandages and wound dressings.
    Type: Application
    Filed: December 23, 2003
    Publication date: July 15, 2004
    Inventors: Sandy Chi-Ching Ying, Michael Tod Morman, Susan Elaine Shawver, Paul Windsor Estey, Jay Sheldon Shultz, Duane Girard Uitenbroek
  • Publication number: 20040130059
    Abstract: Invention relates to a process for producing a single-layer or multilayer film by extrusion or coextrusion, biaxial orientation, and heat setting based on crystallizable thermoplastics whose principal constituent is a crystallizable thermoplastic having a standard viscosity SV (DCA) of from 600 to 1000. The thermoplastic is mixed prior to extrusion or coextrusion with 50% by weight (based on the total weight of all thermoplastics) of a secondary thermoplastic having a standard viscosity SV (DCA) of more than 900 to 1500, the standard viscosity SV (DCA) of the two thermoplastics differing by at least 100 units. The secondary thermoplastic is a byproduct or waste product from the production of PET plastic bottles or originates from recycled PET bottles.
    Type: Application
    Filed: November 5, 2003
    Publication date: July 8, 2004
    Inventors: Ulrich Kern, Ursula Murschall, Holger Kliesch
  • Patent number: 6749785
    Abstract: Multilayer shaped articles, including films, preforms and containers, and method for forming the same, having at least one layer of poly(1,3-propylene 2,6-naphthalate) and at least one layer of poly(ethylene terephthalate). Poly(1,3-propylene 2,6-naphthalate) can be co-stretched with poly(ethylene terephthalate) to form oriented multilayer structures which have superior barrier properties. The poly(1,3-propylene 2,6-naphthalate) and poly(ethylene terephthalate) layers have good adhesion and do not require an adhesive tie layer.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: June 15, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Pallatheri M. Subramanian, Howard Chung-Ho Ng, Ross A. Lee
  • Patent number: 6699418
    Abstract: A method for producing a biaxially stretched film is provided, in which the method comprises, stretching a film made mainly of an ethylene-vinyl alcohol copolymer having an ethylene content of 15 to 70 mol % and a saponification degree of 80 mol % or more under heating; cooling the film; and subjecting the cooled film to a heat treatment; wherein a heating temperature during the stretching is 60 to 160° C., a cooling temperature is a temperature 30 to 100° C. lower than the heating temperature during the stretching, and a temperature for the heat treatment is 150 to 190° C. The thus obtained biaxially stretched film of the present invention has a small bowing coefficient.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: March 2, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Kazuhisa Okada, Nariaki Fujii
  • Patent number: 6696146
    Abstract: Mono- or biaxially-stretched polyester resin foamed sheets and films wherein the polyester resin has a melt strength of more than 1 centinewton at 280° C., a melt viscosity of at least 1500 Pa.s at 280° C. for a shear ratio which tends to zero and a crystallization rate such that for a 10-minute heating at 120° C. the crystallinity can reach values as high as 30-35%.
    Type: Grant
    Filed: March 20, 2000
    Date of Patent: February 24, 2004
    Assignee: Sinco Ricerche S.p.A.
    Inventors: Hussein Al Ghatta, Sandro Cobror, Tonino Severini
  • Patent number: 6685871
    Abstract: Toughened biaxially oriented polyamide films prepared by dry blending i) a polyamide homopolymer, copolymer, or blends thereof; and ii) a functionalized polyolefin terpolymer comprising maleic anhydride, ethyl acrylate, and an olefin, to thereby form a dry mixture. The dry mixture is melted to form a polymer blend, which is then formed into a polymer film. The edges of the film are pinned to a casting roll, and the film is plasticized in at least one water bath. The polymer film is subsequently biaxially oriented. The result is a toughened biaxially oriented film which is resistant to pinholes, cracks, and other structural defects. Such films are particularly suited for making packaging materials for various food products.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: February 3, 2004
    Assignee: Honeywell International Inc.
    Inventors: Jeffrey D. Moulton, Delroy G. Blissett, Gary M. Bardzak, Anthony B. Crochunis, Ann M. Majestic, Simon J. Porter, Thomas L. Staskowski
  • Patent number: 6666969
    Abstract: The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: December 23, 2003
    Assignee: Tonen Chemical Corporation
    Inventors: Hidehiko Funaoka, Kotaro Takita, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Publication number: 20030220433
    Abstract: The invention relates to a raw material or masterbatch made from a thermoplastic and comprising silicon compounds, to a process for its production, and also to films produced using the polymer and having a thickness in the range from 0.5 to 1 000 &mgr;m. The polymer or masterbatch also comprises at least one stabilizer/free radical scavenger. The invention further relates to a process for producing the film.
    Type: Application
    Filed: September 12, 2002
    Publication date: November 27, 2003
    Inventors: Holger Kliesch, Bodo Kuhmann, Ursula Murschall, Rainer Kurz, Ulrich Kern
  • Patent number: 6638988
    Abstract: A porous thermoplastic resin film capable of functioning well as a separator of a cell is provided. The porous film is constituted with a thermoplastic resin and a filler, wherein XR defined by the following formula: XR=25×TGUR×d2/Y is smaller than 5, where Y(&mgr;m), TGUR (sec/100 cc), and d (&mgr;m) represent the thickness, the gurley value, and the average pore diameter of said film, respectively. The porous film constructed as shown above can reduce the internal resistance of a cell when used as a separator of the cell.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: October 28, 2003
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Atsuhiro Takata, Takeshi Yamada, Ryuma Kuroda
  • Patent number: 6623679
    Abstract: A method for controlling the width of a polyester film support comprising, in order, the steps of: (a) extruding a polyester resin using one or more extruders; (b) casting the resin on a casting wheel to form a polyester sheet; (c) stretching the polyester sheet along the machine direction by ratios of 3 to 5 times at temperatures ranging from above the glass transition temperature to below the thermal crystallization temperature, wherein the machine contains extended edge rollers (14) in the drafter at the point where stretching occurs; (d) stretching the polyester sheet along the transverse direction by ratios of 3 to 5 times at temperatures ranging from above the glass transition temperature to below the thermal crystallization temperature; and (e) heat setting the polyester sheet at temperatures ranging from 180 to 250° C.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: September 23, 2003
    Assignee: Eastman Kodak Company
    Inventors: Wen-Li A. Chen, Timothy F. Cilano, Larry K. Maier, Jeffrey P. Johnson
  • Publication number: 20030124280
    Abstract: Multilayer shaped articles, including films, preforms and containers, and method for forming the same, having at least one layer of poly(1,3-propylene 2,6-naphthalate) and at least one layer of poly(ethylene terephthalate). Poly(1,3-propylene 2,6-naphthalate) can be co-stretched with poly(ethylene terephthalate) to form oriented multilayer structures which have superior barrier properties. The poly(1,3-propylene 2,6-naphthalate) and poly(ethylene terephthalate) layers have good adhesion and do not require an adhesive tie layer.
    Type: Application
    Filed: November 21, 2002
    Publication date: July 3, 2003
    Inventors: Pallatheri M. Subramanian, Howard Chung-Ho Ng, Ross A. Lee
  • Patent number: 6566012
    Abstract: It is an object of the present invention to provide a microporous polyolefin membrane, high in pin puncture strength, adequate in pore diameter and high in porosity, comprising (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and having a porosity of 30 to 95%, bubble point exceeding 980 KPa and pin puncture strength of 4,900 mN/25 &mgr;m or more. The membrane can be used as a filter or as a separator for a battery.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: May 20, 2003
    Assignee: Tonen Chemical Corporation
    Inventors: Kotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 6562274
    Abstract: A biaxially oriented polyester film that is 7.0 GPa or more in either the Young's modulus in the machine direction (YmMD) or in the transverse direction (YmTD), and in the range of 55° or more and 85° or less in the circumferential half-width of the diffraction line from the crystal plane in the direction of the polyester's backbone chain that is determined through crystal orientation analysis by wide angle X-ray diffractometry performed while rotating the polyester film around its normal. The film is high in rigidity in all directions within the film plane, high in tear resistance, high in dimensional stability, and resistant to deformation under load, and have very great industrial advantages as material for high-density magnetic recording media, with wide applicability as material for electrostatic capacitor, heat transfer ribbon, and base paper for thermosensitive stencil printing.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: May 13, 2003
    Assignee: Toray Industries, Inc.
    Inventors: Masayoshi Asakura, Kenichi Etou, Tetsuya Tsunekawa
  • Publication number: 20030064195
    Abstract: The invention concerns a unilaterally mat, sealable, UV-stabilized and flame-resistant, sealable, co-extruded, biaxially oriented polyester film comprising at least one base layer (B) and a sealable top coating (A) applied to both sides of said base layer, in addition to a mat covering (C). The film also contains at least one UV stabilizer as a light stabilizer. The invention further concerns a method for the production of said film and the use thereof.
    Type: Application
    Filed: July 26, 2002
    Publication date: April 3, 2003
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
  • Publication number: 20030064214
    Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B which is composed of at least 80% by weight of a thermoplastic polyester, and with at least one outer layer A. Another polymeric layer made from a copolymer crosslinked using an acrylic and/or methacrylic compound, has been applied to that side of the film opposite to the outer layer A. The film has low oxygen transmission and exhibits very good adhesion between the respective layers. The coated film moveover has low coefficient of friction, excellent windability, and excellent antistatic performance. It is particularly suitable for packaging purposes, specifically for packaging foodstuffs or other consumable items. The invention further relates to a process for the production of the film.
    Type: Application
    Filed: April 5, 2002
    Publication date: April 3, 2003
    Inventors: Bart Janssens, Herbert Peiffer
  • Publication number: 20030064236
    Abstract: The invention relates to a multi-layered biaxially-oriented film, mainly made of a crystallizeable thermoplastic polyester and economically produceable with a high surface quality, i.e. without pinning bubbles and without electric arcing and film breaks, at production speeds of 340 m/min or higher. According to the invention the multi-layered polyester film has an average specific electrical melt resistance over its total thickness which lies within a range from 1.5×107 to 30×107 &OHgr;×cm. The invention also relates to a method of production of the film.
    Type: Application
    Filed: August 24, 2001
    Publication date: April 3, 2003
    Inventors: Harald Mueller, Ursula Murschall
  • Patent number: 6517762
    Abstract: The object of the present invention is to provide a method for producing a polyester film excellent in rigidity, toughness, dimensional stability, electric properties, etc. and less in thickness fluctuation and surface defects, hence very suitable as a film for various industrial materials such as magnetic recording media, capacitors, heat transfer ribbons and thermal mimeographic stencil paper. The first method of the present invention is a method for producing a polyester film, in which a film made of a resin mainly composed of a polyester is simultaneously biaxially stretched by a simultaneously biaxially stretching tenter oven, comprising the step of effecting small-ratio stretching at an area stretching ratio of 1.0005 to 3.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: February 11, 2003
    Assignee: Toray Industries, Inc.
    Inventors: Tetsuya Tsunekawa, Takuji Higashioji, Kenji Tsunashima
  • Publication number: 20020190436
    Abstract: Toughened biaxially oriented polyamide films prepared by dry blending i) a polyamide homopolymer, copolymer, or blends thereof; and ii) a functionalized polyolefin terpolymer comprising maleic anhydride, ethyl acrylate, and an olefin, to thereby form a dry mixture. The dry mixture is melted to form a polymer blend, which is then formed into a polymer film. The edges of the film are pinned to a casting roll, and the film is plasticized in at least one water bath. The polymer film is subsequently biaxially oriented. The result is a toughened biaxially oriented film which is resistant to pinholes, cracks, and other structural defects. Such films are particularly suited for making packaging materials for various food products.
    Type: Application
    Filed: May 15, 2001
    Publication date: December 19, 2002
    Inventors: Jeffrey D. Moulton, Delroy G. Blissett, Gary M. Bardzak, Anthony B. Crochunis, Ann M. Majestic, Simon J. Porter, Thomas L. Staskowski
  • Publication number: 20020167111
    Abstract: An object of the present invention is to provide a biaxially oriented high quality polyester film excellent in thermal dimensional stability and clarity and also excellent in productivity, and also to provide a production process thereof. Another object is to provide a biaxially oriented polyester film greatly improved in the practical properties respected in various applications of the polyester film, such as the recording track shift in magnetic recording tape application, curling in magnetic recording card application, dimensional change during process in printing plate application, printing shift in ribbon application, thermostability in capacitor application, and perforation sensitivity and low temperature curling in heat-sensitive mimeograph stencil application.
    Type: Application
    Filed: April 10, 2002
    Publication date: November 14, 2002
    Applicant: Toray Industries, Inc.
    Inventors: Tetsuya Tsunekawa, Hirofumi Hosokawa, Takuji Higashioji
  • Patent number: 6478999
    Abstract: A manufacturing method of adhesive tape, by preparing a raw material of a biaxially or non-drawn, film or sheet on the back surface of which a release agent has been applied and to the which an adhesive agent has been applied, and subjecting the raw material to uniaxial drawing under heated conditions without deteriorating releasing and adhesive performance of the raw material, thus producing an adhesive tape having high-strength and low-elongation. The obtained adhesive tape has long and narrow bubbles elongated in the uniaxial drawing direction thereon.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: November 12, 2002
    Inventors: Seiya Ishizawa, Tomoaki Ishizawa, Kinichi Yazawa, Tetsuo Nagai
  • Patent number: 6472445
    Abstract: Provided is a porous film which is excellent in a water vapor transmission rate, a tear strength and a weatherability. This porous film can be produced by melt-extruding, for example, by a T-die method, a composition comprising 100 parts by weight of a resin blend (1) comprising 100 parts by weight of {circle around (1)} an ethylene-propylene copolymer, 3 to 40 parts by weight of {circle around (2)} a low density polyethylene and 3 to 40 parts by weight of {circle around (3)} an ethylene-vinyl acetate copolymer and 100 to 200 parts by weight of calcium carbonate (2), or a composition comprising 100 parts by weight of the above resin blend (1), 100 to 200 parts by weight of calcium carbonate (2), 0.5 to 20 parts by weight of titanium dioxide (3) coated on a surface thereof with silica and/or alumina, 0.2 to 10 parts by weight of a hindered amine light stabilizer (4) having a molecular weight of 1500 to 4500 and 0.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: October 29, 2002
    Assignee: Tokuyama Corporation
    Inventors: Yoshinori Takahashi, Daisuke Osaki
  • Publication number: 20020121727
    Abstract: A method for controlling the width of a polyester film support comprising, in order, the steps of: (a) extruding a polyester resin using one or more extruders; (b) casting the resin on a casting wheel to form a polyester sheet; (c) stretching the polyester sheet along the machine direction by ratios of 3 to 5 times at temperatures ranging from above the glass transition temperature to below the thermal crystallization temperature, wherein the machine contains extended edge rollers (14) in the drafter at the point where stretching occurs; (d) stretching the polyester sheet along the transverse direction by ratios of 3 to 5 times at temperatures ranging from above the glass transition temperature to below the thermal crystallization temperature; and (e) heat setting the polyester sheet at temperatures ranging from 180 to 250° C.
    Type: Application
    Filed: December 29, 2000
    Publication date: September 5, 2002
    Inventors: Wen-Li A. Chen, Timothy F. Cilano, Larry K. Maier, Jeffrey P. Johnson
  • Publication number: 20020081423
    Abstract: A one-step method of imparting breathability and elasticity to a film includes coextruding elastic fibers within a matrix of a filled, semi-rigid film structure. Once the elastic fibers are within the film structure, the film can be stretched to impart breathability, while the elastic fibers provide elasticity. Furthermore, the elastic fibers can include an absorbent material. The resulting breathable, elastic film is particularly useful in diapers and other personal care products.
    Type: Application
    Filed: December 22, 2000
    Publication date: June 27, 2002
    Inventor: Michael T. Heffelfinger
  • Patent number: 6395209
    Abstract: The present invention relates to a deposited plastic film comprising: a deposited plastic film comprising: a plastic film; a coating layer which is formed on at least one surface of said plastic film and comprises a cured resin composition obtained by curing a resin composition comprising 6 to 80% by weight of an oxazoline group-containing water-soluble polymer; and a deposit layer which comprises a metal, metal oxide or mixture thereof and is formed on a surface of said coating layer.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: May 28, 2002
    Assignees: Mitsubishi Chemical Corporation, Mitsubishi Polyester Film Corporation
    Inventors: Shigenobu Yoshida, Yuzou Otani
  • Publication number: 20020058133
    Abstract: The invention relates to a single-layered or multi-layered biaxially-oriented film, which mainly consists of a crystallizeable thermoplastic polyester and which has a total thickness ranging from 4 to 25 &mgr;m. The film which is provided with a magnetic coating has a skew value of ≦1. The invention also relates to a process for the production of this film which comprises the melting of the thermoplastic polyester in an extruder, extruding it through a flat-film die (slot die), and chilling it thereafter in order to obtain a prefilm. The prefilm is then stretched, the stretched film is thermofixed and the thermofixed final film is seamed and wound up. After the winding process the film roll is, submitted to an aging process.
    Type: Application
    Filed: August 24, 2001
    Publication date: May 16, 2002
    Inventors: Harald Mueller, Ursula Murschall, Cynthia Bennett
  • Publication number: 20020051872
    Abstract: The invention describes a biaxially oriented polyester film with at least one base layer B. with at least one metal-adherent outer layer A, and preferably with another outer layer C, the metal-adherent outer layer A having a metal adhesion of at least 4 N/25 mm.
    Type: Application
    Filed: July 18, 2001
    Publication date: May 2, 2002
    Inventors: Stefan Bartsch, Herbert Peiffer
  • Patent number: 6368532
    Abstract: The present invention improves the bowing phenomenon of a biaxially stretched polyester film which comprises stretching the longitudinally stretched cast film laterally at a temperature higher than the glass transition temperature of the polyester film from by 5° C. to by 50° C., staying the laterally stretched film in an intermediate zone for a period from 3 to 30 seconds which has been controlled at a temperature from higher than the lateral stretching temperature by 20° C. or more to lower than a heat setting temperature by 20° C. or less, and then heat-setting at the heat setting temperature which is lower than the melting point of the polyester film from by 30° C. to by 5° C.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: April 9, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaaki Otoshi, Takanori Sato, Yasuyuki Hosono, Fumitaka Terai, Kazuo Ozaki
  • Publication number: 20020027313
    Abstract: There is disclosed a process for inline producing a biaxially oriented releasing film by consecutively orienting a non oriented film (polyethylene terephthalate or polypropylene) in the machine or transverse direction one by one which comprises coating at least one side of a film in a state prior to biaxial orientation with an addition reaction type silicone based releasing agent (e.g. solvent type), preferably incorporated with a photosensitizer; biaxially orienting the film; thereafter heat annealing the same; and subsequently performing ultraviolet ray irradiation. The process enables easy production of the releasing film which is excellent in releasability, non-migration property of silicone, and productivity, and which is well suited for use in the production of pressure sensitive adhesive labels and tapes, ceramic green sheets, synthetic leather, etc.
    Type: Application
    Filed: July 3, 2001
    Publication date: March 7, 2002
    Applicant: LINTEC Corporation
    Inventors: Tomishi Shibano, Toru Nakamura
  • Patent number: 6245272
    Abstract: It is an object of the present invention to provide a microporous polyolefin membrane, high in elongation and porosity, low in shrinkage, and capable of improving battery characteristics, safety and productivity, when used for battery separators. The microporous polyolefin membrane of the present invention comprises (A) an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, or (B) a composition containing an ultra-high-molecular-weight polyolefin having a weight-average molecular weight of 5×105 or more, and having a porosity of 45 to 95%, elongation at break of 300% or more, bubble point exceeding 980 KPa and thermal shrinkage in the TD direction of 3% or less. The present invention also provides a method for producing the above microporous polyolefin membrane.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: June 12, 2001
    Assignee: Tonen Chemical Corporation
    Inventors: Kotaro Takita, Hidehiko Funaoka, Norimitsu Kaimai, Shigeaki Kobayashi, Koichi Kono
  • Patent number: 6245270
    Abstract: A polyolefin porous material is produced by synthesizing silica particles, polysiloxane particles or crosslinked vinyl polymer particles having an average particle diameter of 0.01 to 0.1 &mgr;m in a molten polyolefin to obtain a polyolefin composition. The polyolefin composition is subsequently subjected to molding and stretching to obtain a polyolefin porous material. The obtained polyolefin porous material contains fine particles dispersed therein, substantially without forming agglomerates, and has an average pore diameter of 0.005 to 0.1 &mgr;m. The small pore diameter allows the material to be used as a liquid/liquid separation membrane, a base material for precision filtration, or a separator for batteries.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: June 12, 2001
    Assignee: Tokuyama Corporation
    Inventors: Yukio Mizutani, Satoshi Nagou
  • Patent number: 6221301
    Abstract: Method and apparatus for producing thermoplastic resin film which allows a biaxially oriented polyester film to be formed at a high speed of 400 m/min or more. In the method, a molten thermoplastic resin film is brought into contact with a cooling medium, to be cooled and solidified, for producing a cast film. The method is characterized by keeping the surface temperature of the cooling medium in the region immediately before the melt reaching position at not lower than the glass transition temperature and not higher than the melting point of the thermoplastic resin. The apparatus is characterized by a cooling medium having a heater and a cooler to ensure that the surface temperature of the cooling medium in the region immediately before the melt reaching position is kept at the requisite temperature, and by a surface temperature of the cooling drum in the region immediately before the film leaving position being maintained lower than the glass transition temperature of the thermoplastic resin.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: April 24, 2001
    Assignee: Toray Industries, Inc.
    Inventors: Kenji Tsunashima, Masaharu Toyama, Katsutoshi Miyakawa, Shunichi Osada, Nobutsugu Chigira, Hiroshi Yoshimura