Abstract: A process for forming fibers, films and fibrous webs from thermoset polymers is disclosed. The process includes first forming an energy activatable prepolymer composition. The prepolymer composition is extruded through a die in order to form polymeric articles. Once extruded through the die, the prepolymer composition is then contacted with an energy source which causes the prepolymer composition to irreversibly undergo a chemical transformation to form a thermoset polymer. The cured polymeric articles can then be collected onto a surface and used as desired. The energy source used to activate the prepolymer composition can be, for instance, a heated gas stream, ultra sonic sound waves, or a radiation source.
Abstract: Profiled sections 1, in particular extruded seals made of elastic material, are designed and produced economically such that they have absolute storage stability and low coefficients of friction and are suitable for a wide variety of uses. The profiled sections 1 are made of a non-lacquer-repelling material. After leaving the extruder 12 and before entering the fused salt bath 16 the profiled sections are coated with a lubricating lacquer 7 applied to the uncured surface 5. The lubricating lacquer 7 is then cured in the fused salt bath 16 without there being a need for a separate curing section or similar. This method not only evenly coats the profiled sections with lubricating lacquer 7 but also prevents the formation of air bubbles or the like, thereby yielding a consistently even coating 6.
Abstract: A polyolefin shaped article having high strength and high modulus is efficiently manufactured without a need to accompany a process of removing a flow modifier or the like.
A method is characterized as including the steps of melt forming a composition principally containing 100 parts by weight of high-density polyolefin, such as high-density polyethylene, and 1-30 parts by weight of a polymerizable monomer or oligomer having a preferred affinity for the high-density polyolefin into a sheet or film, calendering and stretching the sheet or film, and then polymerizing the polymerizable monomer or oligomer incorporated in the sheet or film.
Abstract: The present invention relates to materials which are barriers to gases and to liquids, which are resistant to water and which are capable of being shaped into single- or multimaterial thin layers or films which can be processed by drawing and/or thermoforming. These barrier materials are based on copolyamide composed essentially of units derived from hexamethylenediamine, iso- and terephthalic acids and optionally adipic acid.
They can be used for the manufacture of composite materials comprising one or more thin layers, sheets and/or films, pipes or hollow bodies intended in particular for the packaging of chemicals, foodstuffs or pharmaceutical and/or cosmetic products.
Abstract: The invention relates to a process for making a controlled release device suitable for introduction into a human or animal body. The process comprises coextruding a continuous external body comprising a silicone elastomer and one or more elements comprising a synthetic pharmaceutical agent within the continuous external body.
Type:
Grant
Filed:
July 10, 1998
Date of Patent:
September 19, 2000
Assignee:
Dow Corning France S.A.
Inventors:
Louis Michel Jacques Aguadisch, Patrick Robert Peignot, Alain Etienne, Frederic Jean Claude Goutte
Abstract: The present invention relates to a method for the formation of amorphous boron silicon oxycarbide fibers and crystalline boron-doped silicon carbide fibers wherein the method comprises preparing a blend of a siloxane resin and a carborane-siloxane oligomer, forming the blend into green fibers, and then curing and pyrolyzing the fibers.
Abstract: The present invention generally relates to polymeric compositions capable of providing enhanced crosslinking efficiency, to single and multilayer films having the subject composition contained within at least one layer of said film, to a method of treating said film to provide enhanced crosslink within said at least one layer of the film and to the resultant cross-linked film product as well as articles made from said cross-linked film product.
Type:
Grant
Filed:
March 24, 1997
Date of Patent:
November 30, 1999
Assignee:
Cryovac, Inc.
Inventors:
Robert Babrowicz, William John Gauthier, Charles Robert Morgan, William Peyton Roberts, Drew Ve Speer, Andrew W. Van Putte
Abstract: The present invention relates to a method for the formation of amorphous boron silicon oxycarbide fibers and crystalline boron-doped silicon carbide fibers comprising: preparing a blend of a siloxane resin and a boron-containing polymer, forming the blend into green fibers, and then curing and pyrolyzing the fibers.
Abstract: Uncured thermoset composite reactants containing ultraviolet curable reagents may be effectively cured by pultrusion using a unique molding die which uniformly irradiates the uncured composites contained within the die. The die includes strategically positioned passageways communicating through the chamber walls of the die to the die chamber. The passageways are equipped with fiber optic cables connected to an ultraviolet generator at one cable end and ultraviolet discharging end for discharging ultraviolet radiation within the die chamber at an opposite cable end. Ultraviolet light conducted to the die chamber by the fiber optic cables uniformly initiates and catalyzes the uncured reactants to produce a fully cured thermoset composite. Uncured composite reactants may be continuously fed to the die as the cured composites are continuously withdrawn from the die.
Abstract: The present invention relates to a method for preparing a ceramic fiber from alkenyl or alkynyl functional resins and to the ceramic fibers produced therefrom. The method comprises (A) forming a fiber from a siloxane resin comprised of R.sup.1.sub.a R.sup.2.sub.b RSiO.sub.(3-a-b)/2 units wherein R is an unsaturated carbon group; each R.sup.1 is selected from the group consisting essentially of an aryl group having from 6 to 10 carbon atoms and functional derivatives thereof; each R.sup.2 is selected from the group consisting essentially of an alkyl group having from 1 to 4 carbon atoms and functional derivatives thereof; a has a value of 0, 1 or 2; b has a value of 0, 1, or 2 with the proviso that a+b <2; (B) curing the fiber by exposing the fiber to high energy radiation to render it non-fusible; and (C) heating the non-fusible fiber in an inert environment to a temperature above about 800.degree. C. to convert it to a ceramic fiber.
Type:
Grant
Filed:
April 22, 1997
Date of Patent:
November 24, 1998
Assignee:
Dow Corning Corporation
Inventors:
William Henry Atwell, Duane Ray Bujalski, Jonathan Lipowitz, Kai Su, Gregg Alan Zank
Abstract: Conventionally produced edible tubular casing is improved in its mechanical properties by being exposed to ultraviolet spectra in the range of 180 nm to 420 nm. The so treated casing is humidified, collapsed and wound onto a reel. The reel of tubular casing may be transported to a point of use where it is unwound, inflated, shipped and cut into lengths as desired.
Abstract: The present invention relates to a method for preparing a ceramic fiber wherein the method comprises (A) forming a green fiber from an alk-1-enyl ether functional siloxane resin of the general formula (R.sup.1 SiO.sub.3/2).sub.q (R.sup.2 SiO.sub.3/2).sub.r (R.sup.1.sub.w R.sup.2.sub.x RSiO.sub.(3-w-x)/2).sub.s (R.sup.1.sub.w R.sup.2.sub.x R.sup.3 SiO.sub.(3-w-x)/2).sub.t wherein R is an alk-1-enyl ether group; each R.sup.1 is selected from an aryl group having from 6 to 10 carbon atoms; each R.sup.2 is selected from an alkyl group having from 1 to 4 carbon atoms; R.sup.3 is an alkenyl group having from 2 to 10 carbon atoms; w has a value of 0, 1 or 2; x has a value of 0, 1, or 2 with the provisio that w+x.ltoreq.2; q has a value of 0 to 0.98; r has a value of 0 to 0.98; s is greater than zero; t.gtoreq.0; s+t=0.02 to 0.5 and q+r+s+t=1; (B) curing the green fiber to render it non-fusible; and (C) heating the non-fusible fiber in an inert environment to a temperature above 800.degree. C.
Type:
Grant
Filed:
July 31, 1997
Date of Patent:
September 29, 1998
Assignee:
Dow Corning Corporation
Inventors:
Duane Ray Bujalski, Kai Su, Gregg Alan Zank
Abstract: A method for the thermal treatment of an electroconductive polymeric pyrogen in which two parallel conductors are incorporated and electroconductive carbon black is dispersed in an insulating polymer, comprising the step of heating the pyrogen in an oven simultaneously while applying an electric field to the pyrogen through a lid line connected from the two conductors to an external power source, by which a desired final resistance can be obtained in a far shorter time while preventing the polymer from being degraded.
Abstract: To provide an oil supplying means for an oil coating roller, by which oil can be supplied stably for a long time while preventing offset, a cylindrical non-sintered molded body which is a mixture of ceramic fiber and clay is used as an oil holding member in an oil coating roller.
Abstract: The invention relates to a process for preparing a fibre-reinforced composite or a fibre-reinforced coating, which comprises impregnating reinforcing fibres with a radiation-curable composition comprising a polymerisable monomer and a polymer which is dissolved or dispersed in the monomer, and exposing the impregnated fibres to radiation to effect curing of the composition.
Abstract: A process of manufacturing elastomeric fibers in which fibers are obtained by co-extruding an extrudable and curable .tbd.SiO-- containing material and an aqueous organic polymer solution into a coagulation bath. The .tbd.SiO-- containing material is surrounded by the coagulated organic polymer. The .tbd.SiO-- containing material is then cured inside the protective sheath that is formed, and thereafter the organic polymer sheath is dissolved to expose a continuous elastomeric fiber of the .tbd.SiO-- material.
Type:
Grant
Filed:
July 13, 1995
Date of Patent:
February 18, 1997
Assignee:
Dow Corning Corporation
Inventors:
John D. Blizzard, Steven E. Cray, Jenny L. Gilles, Daniel Graiver, Arnold W. Lomas, James McVie
Abstract: A plastic foam material composed of a polyolefin based resin composition, consists essentially of specified amounts of polypropylene based resins and polyethylene based resins, included from about 20 to about 65 weight percent of a cross linked portion. The cross linked portion consists of from about 55 to about 95 weight percent of a cross linked polypropylene and from about 5 to about 45 weight percent of cross linked polyethylene. The amount of cross-linkage can be determined by a xylene extraction technique. The plastic foam material may further include specified amounts of a cross-linking agent and specified amounts of an organic thermodecomposition foaming agent. The thermodecomposition foaming agent decomposes at sufficiently high temperatures to yield a plastic foam material, which exhibits superior adherence properties and fewer deformities of its surface exemplified by swelling, shrinkage and wrinkling of its surface. A method to produce the plastic foam material is also disclosed.
Abstract: A process for preparing thermal bondable fibers including exposing molten fiber grade polymer to electromagnetic radiation at the one or more orifices of the spinneret and the upper portion of the spin line, and the fibers prepared therefrom.
Abstract: High molecular weight polyethylene products of high strength, good thermal resistance and creep resistance process in which the polyethylene is melt drawn in a multiple-stage drawing process in which the polyethylene extrudate is treated sequentially by a first drawing process which uses an elongating draw at an elongation strain rate of from about 0.03 to 0.5 S.sup.-1, a subsequent stage of elongating draw at a lower elongational strain rate, whilst subjecting the extruded polyethylene to UV crosslinking during the subsequent stage of elongating draw at lower elongational strain rate.
Type:
Grant
Filed:
July 11, 1994
Date of Patent:
April 9, 1996
Inventors:
Dedo Suwanda, Stephen T. Balke, Xue L. He