Abstract: A vapor permeation method and apparatus for removing a vapor from a vaporous feed stream, the method and apparatus utilizing highly solvent-resistant composite hollow fiber membranes and a permeate flow countercurrent to the feed flow, wherein the support of the composite membrane is formed by solution casting and has been rendered sufficiently solvent-resistant by a post-casting step to retain at least 20 of its burst pressure when soaked in the solvent used to cast the support.

Abstract: A process for the production of foamed material from waste paper and the like, such as paper, cardboard, waste cardboard or materials with similar properties, are usable in the same way as raw material, either sorted by type of material or as a raw material mixture. First, a liquid-containing pulp is prepared from the raw materials. The foaming and hardening of this pulp takes place under the action of microwave radiation. By using suitable molds permitting an unobstructed access of the radiation to the liquid-containing mass and unhindered expulsion of the resulting vapor, it is possible to manufacture any type of shaped bodies in a continuous or batch-wise process.

Abstract: Completely open-celled rigid polyurethane foams are produced by subjecting closed-celled or partially closed-celled rigid polyurethane foams to applied external pressure. These open-celled foams are useful as filling material in insulating panels or as insulating foams.

Abstract: A structurally rigid biodegradable foam scaffold useful for cell transplantation is provided. The foam can be loaded with nutrients and/or drugs that elute from the foam during transplant to promote growth of the cells. The foam, which features a continuous network of pores, is fabricated using a novel method involving phase separation and consequent expansion upon sublimation of a liquid solvent, preferably naphthalene.

Abstract: To prevent the deterioration of the flux and salt rejection characteristics of polyamide, thin-film, composite reverse osmosis membranes when subjected to relatively high temperature drying conditions, an unsubstituted inorganic ammonium cation salt of an acid is incorporated into the process of manufacture. The ammonium salt can be introduced into the process either before or after the membrane is formed by interfacial polymerization so long as it is added before the membrane is heated.

Abstract: Bowling pins formed by molding a plastic shell about a foamed plastic core have not heretofore come into practical use because of inability to withstand shocks in service, resulting in separation of the shell from the core. According to the present invention, a foamed thermoset (non-melting) copolymer is employed for casting the core. Thereafter, before casting a plastic shell thereabout, the core surface area is substantially increased by simply removing the core surface skin, thereby opening the outermost thermoset core cells for filling by the shell material.

Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.

Abstract: A method of making beaded foam molded products with corrosion inhibitor incorporated therein includes the steps of expanding a foamable synthetic resin into puffed beads, spraying onto the puffed beads a liquid containing a vapor phase corrosion inhibitor to provide a coating thereon, and molding the coated puffed beads into a beaded foam molded product with the corrosion inhibitor dispersed throughout the thickness thereof and migratable to the surface thereof.

Abstract: The present invention provides, in a preferred embodiment, an interior trim component for a motor vehicle including a first membrane with a connected foam backing, an apertured second membrane spread adjacent the foam backing of the first membrane, and a moldable rigid polymeric material providing a backing for the second membrane and supporting the first membrane, the moldable polymeric material penetrating the apertures of the second membrane and adhering to the foam backing of the first membrane.

Abstract: A method of fabricating a controlled and uniform cell size blotter roll for blotting liquid images consisting of toner particles and carrier liquid. The method includes the step of mixing a first grade of salt having first particles of a first uniform size with a polymer material so as to form a first mixture. The method next includes a step of extruding the first mixture to form an extruded sleeve having intimately compacted polymer material and salt particles, an outer surface, and an inner surface defining a hollow interior.

Abstract: There is disclosed a heat-sterilizable spiral-wound filtration module having an outer shell comprising a cord, fabric or laminate consisting of a heat-resistant rigid first polymer encased within a thermoplastic second polymer.

Abstract: A process for the production of hydrophilic membranes using at least one hydrophobic polymer and polyvinyl pyrrolidone as a hydrophilic polymer, membrane-forming shaping of the polymers and immobilization of the polyvinyl pyrrolidone is characterized in that the polyvinyl pyrrolidone is immobilized on and/or in the membrane by treatment with an aqueous solution of peroxodisulphate in a hot condition. The solution of peroxodisulphate is kept substantially free of oxygen during immobilization by degassing the solution. The membranes are used for hemodialysis, hemodiafiltration and hemofiltration of blood.

Abstract: A foamed plastic manufactured by foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in the foams of the foamed plastic is less than atmospheric pressure, is disclosed. Further, a foamed plastic manufactured by hermetically sealing with an airtight film and foaming a mixture of a resin and a volatile polymerizable foaming agent, wherein the pressure in a gap region between the airtight film and the foamed plastic and the pressure in the foams of the foamed plastic are less than atmospheric pressure is disclosed. Further, a method of manufacturing foamed plastic comprising foaming a mixture of a volatile polymerizable foaming agent and a resin, and irradiating the foamed plastic with an energy beam.

Abstract: Foams are prepared under reduced pressure and are subsequently encased in a material which will prevent ambient air from entering the cell voids. In the most preferred embodiment of the invention a polyurethane or polyisocyanurate foam is formed by mixing the polyol and isocyanate components under reduced pressure, allowing the gas within the foam to reach equilibrium at a lesser pressure then in prior systems. The need for blowing agents is substantially reduced and the K-factor of such foams is highly desirable. The foams are particularly well suited for use in refrigeration applications where the foams can be encased to prevent air from entering the cells after curing of the foam.

Abstract: A modified polyvinyl chloride (PVC) separation membrane and a method for its preparation. The membrane has improved water permeability, contamination resistance, and hydrophilic properties. The method comprises contacting a PVC membrane with a treating solution containing a compound having an amino functional group, preferably in the presence of an alkali alcoholate catalyst, and heat-treating the PVC membrane at elevated temperature. The membrane can be dipped in the treating bath at high temperature or dipped in solution at room temperature and heat-treated after removal from the treating bath.

Abstract: The invention relates to membranes for facilitated ion transport in aqueous solutions. The membrane is an adduct of a heteropolysiloxane and a crown-ether, and contains certain ions such as picrate or fluoroborate. This membrane is efficient for the selective transport of potassium ions.

Abstract: A foamed adhesive insulation, consisting of a mixture of a foamed adhesive material and a fibrous insulation material, is provided which adheres to a desired surface without the need for a retaining means to hold the mixture in place. While in the flowable state, the foamed fiber insulation can be molded to a desired shape and texture. The foamed fiber insulation adheres and can be applied to substantially any surface, such as wood, metal, masonry, concrete, or urethane, with virtually any orientation. The compression and tensile strengths of the layer of foamed fiber insulation can be selected by adjusting the mixture of foamed adhesive material and insulation particles. The foamed fiber insulation can include additives such as a dye to produce a substantially rigid insulation layer of a desired color, or a fire retardant material to produce a fire retardant insulation layer.

Abstract: A method for applying a closing tape to an extruded foam article is disclosed. The tape is applied immediately after the article is extruded and while the article is still subject to shrinkage, which is common with extruded foamed products. The tape is prestressed and is of a material to alleviate the problems associated with shrinkage. This method is particularly appropriate for applying a closing tape to an extruded polyethylene pipe insulation product which has been longitudinally slit to allow the pipe to be located interior to the insulation. The tape has one side attached to one side of the slit with the other portion of the tape being positioned for closing the slit by engaging the opposite side of the slit. A pressure sensitive adhesive is provided on the tape and a release liner protects the adhesive on the other portion of the tape.

Abstract: Membranes composed of sulphonated polyaryl ether sulphones are disclosed in which the repetitive polymer units have the formula ##STR1## in which the aryl radicals are substituted by SO.sub.3 X where X is hydrogen or an alkali metal and the polymer includes from about 0.3 to 0.6 SO.sub.3 X radicals per unit. Processes for producing these membranes are also disclosed.

Abstract: A method of forming a thermoplastic polyester series foamed material having a thickness of at least 3 mm and an apparent density of from 0.05 to 0.7 g/cm.sup.3, wherein the crystallinity of the resin in the surface portion within 0.5 mm from the surface of the foamed material is not more than 30% and at least 1% lower than the crystallinity of the resin in the central portion of the foamed material.

Abstract: The present invention provides a method for fabricating an asymmetric fluoropolymer membrane comprised of a fluoropolymer material, the membrane having a first surface comprised of a dense layer of the fluoropolymer material, and an opposite second surface comprised of a porous layer of the fluoropolymer material, comprising the steps of:(a) dissolving a fluoropolymer material in a solvent to form a solution;(b) depositing the solution on a casting surface; and(c) removing the solvent from the solution, thereby precipitating the membrane therefrom.The present invention also provides asymmetric fluoropolymer membranes comprised of a fluoropolymer material, wherein the membrane has a first surface comprised of a dense layer of the fluoropolymer material, and an opposite second surface comprised of a porous layer of the fluoropolymer material, and provides compositions for making the same.

Abstract: A method for drying porous ultrafiltration membranes by the use of heat and possibly also at reduced pressure is characterized in that prior to the application of heat the pores of the membranes are at least partially filled with a solution of a water-soluble organic solid which swells the membranes and which has a melting point above 35.degree. C. in an organic solvent which is completely miscible with water and which does not change the membrane structure.

Abstract: A permanently hydrophilic membrane on an aromatic polysulphone basis and a method for its production. Due to their chemical and thermal resistivity and also because they are unobjectionable with respect to their contacting foodstuffs, membranes on an aromatic polysulphone basis represent a preferred filtration material. But since they are hydrophobic, they would have to be hydrophilated before they are used. Known hydrophilation methods were insufficient to maintain the hydrophilic properties of the membranes, especially after repeated sterilization. The new method aims at making the membranes permanently hydrophilic under sterilization conditions. In an aftertreatment step, the membranes on an aromatic polysulphone basis are conducted, before or after drying, through an impregnating bath of polyvinylpyrrolidone, a copolymer of vinylpyrrolidone and one or more hydrophobic monomers and peroxodisulphate, then heated to 70 to 150.degree. C. and cooled down again.

Abstract: A passive insulating system can provide highly effective protection in the presence of transient high temperatures. The system comprises, for example, a porous body forming a multiplicity of fine cells with a material having low thermal conductivity, a thermally absorptive liquid, providing an endothermic reaction in the presence of a catalyst, and a finely divided catalyst for the reaction uniformly distributed in the porous body. In preferred systems, the thermally absorptive liquid is para-hydrogen, the catalyst is granulated ferric oxide, and the liquid para-hydrogen changes to gaseous para-hydrogen, and from para-hydrogen to ortho-hydrogen in the presence of the ferric oxide catalyst, absorbing heat by its heat of vaporization and endothermic catalytic reaction and reducing heat transfer through the porous body.

Abstract: A method for forming a plastic composite bowling pin includes removing the surface skin of a foam core, mounting a plastic base ring on such core, and molding a relatively thick elastomer shell around the prepared core and the base ring so that the hardening of the shell interlocks the shell, core and base ring. A pin made by this method is easily refurbished by removing the base ring and part of the shell and re-molding the surface of the shell.

Abstract: A method for the preparation of a cross-linked, rigid, polyethylene, foam sheet product, which method comprises heating at least one surface of a cross-linked, polyethylene, foam sheet material, to a temperature sufficient to cause a slight surface post-expansion of the foam sheet material, contacting the heated, post-expanded, foam surface with a cold metal element, to form a cross-linked, polyethylene, foam sheet product of the desired, accurate thickness, or having a desired three-dimensional design on the cross-linked, foam sheet material.

Abstract: A sound insulating structure is provided which is made by foam-backing a carpet in a single operation and which includes a consolidated layer with few or no cells followed by a cellular soft elastic layer. To this end structured materials such as fleece and/or cut foam into which foaming takes place in order to form the consolidated layer, are provided on the back of the carpet or of a foam-proof covering thereon.

Abstract: A PVDF membrane exposed to a quarternary ammonium hydroxide solution retains it hydrophobicity and resistance to corrosive environments, yet spontaneously and completely wets with concentrated sulfuric and nitric acids. The modified membrane is incorporated into filtration devices that are in situ integrity testable in concentrated inorganic mineral acids.

Abstract: A method of coating chromatographic particulate supports to provide a biocompatible outer layer of synthetic membrane-type film which prevents the release of fines but permits the adsorption of components to an affinity ligand is described. The matrix is provided with a membrane-type coating, which prevents leaching of fines, with a pore size of at least 20 angstroms. The coating is applied to a solid particulate under conditions where an integral membrane coat will be formed. It may also be necessary to control the size and number of pores of the membranes by treating a suspension of the solid support in a solvent which contains 0.1-1% of the support weight of a biocompatible polymer along with 0.5-5% of the weight of said polymer of a dissolved compatible pore-controlling component. The solvent is then removed from the suspension and the membrane-coated material used in extracorporeal treatment of body fluids or in other chromatographic techniques.

Abstract: A method for preparing a microporous polyolefin shaped article which includes the steps of (1) melt blending a polyolefin with an additive which is miscible with the polymer at the melt temperature of the blend but which phase separates on cooling to form a solution; (2) forming a shaped article from the solution; (3) cooling the shaped article by use of a patterned chill roll to provide areas on the surface of the article where the polymer mixture does not contact the chill roll; and (4) (a) removing at least a substantial portion of the compatible liquid; or (b) stretching the article in at least one direction sufficient to permanently attenuate the article and effect orientation of the polymer; or (c) a combination of (a) and (b) to form a microporous polyolefin shaped article. The article is of substantially uniform thickness and has a patterned surface. The patterned surface provides substantially skinless areas having high microporosity and skinned areas or reduced porosity.

Abstract: Halogen-substitutable hydrogen atoms are linked to nitrogen atoms of a polymer, with ethylenically-unsaturated monomers. By using inorganic or organic hypohalogenites and/or organic N-halogen derivatives as halogenation means, hydrogen atoms on the nitrogen atoms of the polymer membranes or polymer formed materials are replaced by halogen atoms and part of these are removed by reducing agents in the presence of ethylenically unsaturated monomers, with radical grafting of these on to the nitrogen atoms, after which the remaining halogen atoms are removed by reducing agents in the absence of monomers.

Abstract: A method of forming complex polyimide foam shapes by impregnating a low density, open cell, reticulated foam with polyimide foam precursor, placing the combination in a mold, closing the mold, then heating the assembly to the foaming and curing temperatures of the precursor. As the powdered precursor expands, it spreads throughout the reticulated foam producing a product having substantially uniform density and polyimide foam characteristics. If desired, the reticulated foam can be removed from the product by using a material that outgasses and boils away at polyimide processing temperatures. Radar absorbing materials may be incorporated in the reticulated foam so that the final product will have uniformly distributed radar absorbing components with the desirable high temperature resistance and other properties of polyimide foams.

Abstract: A post treatment for cellular foam blocks such as polyurethane which includes recirculating reactant laden air through a foam block which has been slit along opposing side faces following formation. The faces are slit to a depth of one-eighth to three-eights inches with adjustably fixed knives. The slit foam block is then covered and positioned against a blower assembly in an air infiltration chamber and one side of the block is urged against air inlets whereby air is directed into the opposite face where it passes through the foam and is recirculated thereby removing the heat and finalizing the cure of the foam in a complete and consistent manner with better compression-set properties.

Abstract: Method of producing a paint or other plastic resinous material or product which on application to a surface imparts the surface with a tanned skin or leather-like appearance. The method includes incorporating into a paint or a plastic resin fluid a granular non-flocculating resin-plastic-compatible leather powder having a specific gravity of about 0.38 to about 0.5 g/cc. The leather powder is produced from tanned skin and/or leather chips and/or strips which have been steam heated a period of time sufficient to permit the chips and/or strips to swell and simultaneously cause the naturally occurring twisted and tangled collagen fibers therein to shrinkk and to automatically loosen and become less twisted and less tangled which upon pulverization produces a powder including relatively smooth granules having lubricity and relatively non-fibrous.

Abstract: Oil and water repellency is conferred upon porous substrates (10) by treatment with a solution of a monomer (16) of the formula: (C.sub.n E.sub.2n+1)(CH.sub.2).sub.x (CHR)OCOCH.dbd.CH.sub.2 where n is an integer; X is 0,1,2 or 3 and R is H or CH.sub.2 --OCOCH.dbd.CH.sub.2. The monomer is polymerized in situ upon the substrate to provide a conformal coating (16') which preserves the porous structure.

Abstract: A polytetrafluoroethylene porous film obtainable by applying an aqueous dispersion of emulsion polymerized polytetrafluoroethylene particles having an average minor particle size of 1 to 500 nm and an average aspect ratio of at least 10 on a substrate, drying the applied dispersion and optionally sintering the dried polytetrafluoroethylene particles on the substrate to obtain the polytetrafluoroethylene porous film, which has a uniform thin thickness.

Abstract: Foam molding is carried out with a melt blend of polyethylene terephthalate (PET), ethylene copolymer elastomer, and glass fibers in the presence of blowing agent and with a cold mold, so that the resultant foamed article has an amorphous-rich PET surface and a crystalline PET core.

Abstract: A method of producing self-supporting ceramic bodies having a modified metal-containing component includes first providing a self-supporting ceramic body comprising (i) a polycrystalline oxidation reaction product formed upon oxidation of a molten parent metal precursor with an oxidant, and (ii) an interconnected metal-containing component at least partially accessible from one or more surfaces of said ceramic body. The surface or surfaces of the ceramic body is contacted with a quantity of foreign metal different from said interconnected metal-containing component at a temperature and for a time sufficient to allow for interdiffusion, whereby at least a portion of said metal-containing component is displaced by said foreign metal. The resulting ceramic body, having an altered metal-containing component, exhibits modified or improved properties.

Abstract: A microporous polyolefin shaped article is provided. The article comprises a polyolefin substrate of substantially uniform thickness having a patterned surface, the patterned surface providing substantially skinless areas having high microporosity and skinned areas of reduced microporosity. A method for preparing the article is also provided.

Abstract: A ceramic filter having good permeability and a superior durability, and a process for manufacturing the same. This filter comprises a porous support made of a ceramic, a fine intermediate layer formed on one surface of said support and comprised of at least one kind of particles selected from particles of SnO.sub.2, TiO.sub.2, ZrO.sub.2 or CeO.sub.2 and having a particle diameter of not more than 500 .ANG., and a thin film formed on the surface of said fine intermediate layer and comprised of at least one particles selected from particles of SnO.sub.2, TiO.sub.2, ZrO.sub.2 or CeO.sub.2 and having a particle diameter of not more than 300 .ANG. and smaller than the particle diameter of the particles that constitute said fine intermediate layer.

Abstract: A method for designing and making composite membranes having a microporous support membrane coated with a permselective layer. The method involves calculating the minimum thickness of the permselective layer such that the selectivity of the composite membrane is close to the intrinsic selectivity of the perselective layer. The invention also provides high performance membranes with optimized properties.

Abstract: The method of making polystyrene foam for foam products which includes utilizing atmospheric gases as the blowing agents or preferably mixing one or more of these gases and a blending agent which is non-volatile at the extrusion temperatures, introducing the mixture to a molten thermoplastic polystyrene resin containing nucleating agents such as sodium bicarbonate and citric acid and extruding the thermoplastic in the form of a foam. The resultant foam has substantially no residual blowing agent, is dimensionally stable at ambient temperatures and when used with a non-volatile blending agent can be made with small amounts of blowing agent permitting cooling of the melt without high loading on the extruder. The foam may be coextruded with one or more layers of thermoplastic films so that the resultant product is adpated for use for plates, cups, food containers or packaging and for labells for containers such as glass and plastic containers and for labels that are shrunk in place on a container.

Abstract: There is disclosed a porous inorganic material, suitable for use as a support material for biological macromolecules, comprising substantially spherical particles of an aluminosilicate ceramic material, any internal cavities present in a particle occupying no more than 10% of the volume of the particle, each particle having a diameter in the range of from 5 micrometers to 5 millimeters and consisting predominantly of an open three-dimensional matrix of needles of the ceramic material each of which needles has a length in the range of from 2 to 20 micrometers and a width in the range of from about 0.2 to 2 micrometers, the ceramic needles defining between them interconnecting pores of width of from 0.1 to 5 micrometers. Also disclosed is a method of preparing such a porous inorganic material.

Abstract: A pore modified microporous membrane is disclosed which is made by the process of incorporating a polymerizable vinyl monomer within the pores of a microporous membrane followed by polymerization to secure the resulting polymer within the pores. The process is particularly suitable for modifying a hydrophobic microporous membrane with a hydrophilic polymer, as occurs for example when polyacrylic acid is secured into the pores of a polypropylene microporous membrane. In further applications of the present invention, the inventive method may be used to produce liquid membrane supports for use with or without active carriers.

Abstract: A process for producing tubular film from a thermoplastic molten material, including supplying an annular stream of thermoplastic material through a passageway substantially free of flow interurptions having a plurality of axially aligned-annularly spaced feed ports, funneling and recombining the annular stream of thermoplastic material after being supplied through the feed ports to evenly recombine the thermoplastic material, and forming a tubular stream of thermoplastic film having a substantially uniform thickness throughout.

Abstract: A hydrophilic, semipermeable membrane comprises a microporous PTFE membrane having the internal and external surfaces of the membrane structure coated by a complex formed by the combination of a hydrophilic polymer which adheres to the membrane structure and a complexing agent, the complex rendering the microporous PTFE membrane substantially hydrophilic and protein affinitive. The preferred hydrophilic polymariz/polyvinyl alcohol, and the complexing agent is preferably a dibasic inorganic acid, such as boric acid, or a salt thereof. Such hydrophilic, semipermeable membranes are particularly suitable for protecting the target area of a body fluid diagnostic test strip, and a cell culture support members. Methods of forming the membranes are also described.

Abstract: The process includes molding a plurality of recesses on a layer of foam material which is laid on a laying surface and moved forward. These recesses include a base open on the laying surface and are subsequently cross-linked by introducing steam under pressure through the bases of the recesses into cavities of the recesses formed during the molding step. The plant includes a conveyor element in which a plurality of plates disposed side-by-side are provided with protuberances corresponding to the recesses to be formed in the foam layer. The protuberances are open at their bases to enable introduction of steam into an inner space within each of the protuberances.

Abstract: A method for the production of a hydrophilic porous membrane of polyvinylidene fluoride excelling in perviousness to water and other various properties and enjoying high commercial value, having uniform hydrohilicity imparted to the surface of pores therein, which porous membrane is characterized by the fact that the reflection spectrum thereof in the visible zone is substantially unchanged from that which existed before the treatment for impartation of hydrophilcity. The method for the production of the hydrophilic porous membrane is characterized by chemically treating the porous membrane is a strong alkali solution containing an oxidizing agent.

Abstract: A process for preparing an asymmetrical macroporous membrane from a polymer solution comprised as the dissolved portion fraction a polymeric mixture comprised of about 5-70% by weight of polyvinylpyrrolidone having a molecular weight of .gtoreq.100,000 Dalton and about 95-30% by weight of a polymer selected from the group consisting of polysulfone, a polyether sulfone, and an aromatic or araliphatic polyamide, said weight being relative to the total weight of the dissolved polymeric fraction, by action of a coagulating liquid, wherein the coagulation is effected under conditions such that skin formation, asymmetrical port formation and retention of the polyvinylpyrrolidone are achieved, recovering the asymmetrical macroporous membrane comprising the polymeric mixture.

Abstract: A method for designing and making composite membranes having a microporous support membrane coated with a permselective layer. The method involves calculating the minimum thickness of the permselective layer such that the selectivity of the composite membrane is close to the intrinsic selectivity of the permselective layer. The invention also provides high performance membranes with optimized properties.