Liquid To Gas Phase Change Patents (Class 264/53)
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Patent number: 8962707Abstract: Various uses of monochlorotrifluoropropenes, in combination with one or more other components, including other fluoroalkenes, hydrocarbons; hydrofluorocarbons (HFCs), ethers, alcohols, aldehydes, ketones, methyl formate, formic acid, water, trans-1,2-dichloroethylene, carbon dioxide and combinations of any two or more of these, in a variety of applications, including as blowing agents, are disclosed.Type: GrantFiled: September 8, 2010Date of Patent: February 24, 2015Assignee: Honeywell International Inc.Inventor: Rajiv R. Singh
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Publication number: 20150045464Abstract: A method for producing resin foam including: melting a resin composition including a polyolefin resin and a thermoplastic elastomer; impregnating the molten resin composition with a material that is a gas at normal temperature and normal pressure, in a supercritical state, under a condition in which the supercritical state of the material is maintained; foaming the resin composition impregnated with the material by arranging the resin composition under a condition in which the supercritical state of the material is not maintained; and hot-pressing the foamed resin composition.Type: ApplicationFiled: October 24, 2014Publication date: February 12, 2015Applicant: INOAC CORPORATIONInventors: Naoya Okumura, Yasuhiro Usami, Shigeyasu Shimura
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Publication number: 20150038606Abstract: Foamed thermoplastic elastomeric polyurethane and ethylene-vinyl acetate copolymer articles are made with from about 0.1 to about 4 weight percent of supercritical fluid nitrogen based on polymer weight and from about 0.1 to about 5 weight percent of a supercritical fluid carbon dioxide based on polymer weight, with the supercritical fluid nitrogen and the supercritical fluid carbon dioxide being separately added to the molten polymer.Type: ApplicationFiled: August 2, 2013Publication date: February 5, 2015Applicant: NIKE, Inc.Inventor: Hossein A. Baghdadi
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Publication number: 20150038605Abstract: Foamed thermoplastic elastomeric polyurethane and ethylene-vinyl acetate copolymer articles are made with a combination of a supercritical fluid and a non-supercritical fluid blowing agent.Type: ApplicationFiled: August 2, 2013Publication date: February 5, 2015Applicant: Nike, Inc.Inventor: Hossein A. Baghdadi
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Publication number: 20150038607Abstract: A method for making a low density foamed article includes placing a desired amount of thermoplastic polyurethane foam beads in a cavity of an injection mold and closing the mold; combining in an extruder connected to the mold a molten polymer selected from the group consisting of thermoplastic polyurethane elastomers and thermoplastic ethylene-vinyl acetate copolymers with both a physical or chemical blowing agent other than a supercritical fluid present in an amount up to about 15 wt % based on molten polymer weight and a supercritical fluid that is at least one of about 0.1 to about 5 weight percent of supercritical CO2 based on molten polymer weight or about 0.1 to about 4 weight percent of supercritical N2 based on molten polymer weight, to form a mixture and injecting the mixture into the mold and foaming the mixture to form the low density foamed article.Type: ApplicationFiled: August 2, 2013Publication date: February 5, 2015Applicant: NIKE, Inc.Inventor: Hossein A. Baghdadi
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Patent number: 8946312Abstract: An azeotrope-like mixture consisting essentially of chlorotrifluoropropene and at least one component selected from the group consisting of a C1-C3 alcohol, a C5-C6 hydrocarbon, a halogenated hydrocarbon, methylal, methyl acetone, water, nitromethane, and combinations thereof.Type: GrantFiled: November 17, 2011Date of Patent: February 3, 2015Assignee: Honeywell International Inc.Inventors: Rajat Basu, Leslie Bement, Kane Cook, Ryan Hulse, Gary Knopeck, Hang T. Pham, Rajiv R. Singh, David J. Williams
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Patent number: 8921434Abstract: A polylactic acid composition is produced with an MI value of 0.05 or more and 5 or less, the MI value being measured at 190° C. under a load of 21.6 kg in accordance with JIS K7210 (ISO 1133). A polylactic acid is crosslinked with a polyisocyanate to generate a cross-linked polylactic acid, including a large cross-linked polylactic acid molecule which inhibits foaming. The cross-linked polylactic acid is mechanically grinded-by applying a shear force to decrease a molecular weight of the large cross-linked polylactic acid molecule. The amount of the polyisocyanate combined is 0.4 to 5% by weight based on the polylactic acid. The grinding is conducted in supercritical condition of an inert gas. A foam molded article is made from the polylactic acid composition.Type: GrantFiled: March 29, 2011Date of Patent: December 30, 2014Inventors: Kosuke Uchiyama, Kazunori Tsuda, Tenya Suzuki
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Patent number: 8889046Abstract: A method comprising injection molding a plastic part from a polymer formulation comprising an injection moldable thermoplastic and an additive, wherein the additive has a decomposition temperature that establishes a maximum processing temperature for the polymer formulation. The additive will thermally decompose to generate gaseous products causing visible bubble formation in the surface of the plastic part in response to exposure to a processing temperature that exceeds the decomposition temperature of the additive. A suitable additive may be, for example, selected from oxalates, carbamic acids, carbonic acids, diazocarbonyl compounds, and combinations thereof.Type: GrantFiled: December 6, 2011Date of Patent: November 18, 2014Assignee: International Business Machines CorporationInventors: Joseph Kuczynski, Melissa K. Miller, Heidi D. Williams, Jing Zhang
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Patent number: 8865037Abstract: A method of manufacturing foamed thermoplastic films and trash bags wherein a foaming agent is added to a base thermoplastic resin. The resultant foaming agent/base resin mixture is extruded to form a single-ply foamed thermoplastic film. The film may be formed into bag, such as a trash bag.Type: GrantFiled: March 10, 2008Date of Patent: October 21, 2014Assignee: VINXI, L.L.C.Inventor: John Charles Marrelli
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Publication number: 20140264994Abstract: Provided is a process for forming a personal care article comprising producing a personal care article from a twin screw extruder employing blowing agents, the personal care article including (i) from about 10% to about 60% of one or more anionic surfactants, wherein the one or more anionic surfactants have a Krafft point of less than about 30° C.; (ii) from about 10% to about 50% of one or more water soluble polymers; (iii) from about 1% to about 30% of one or more plasticizers; and (iv) from about 0.01% to about 40% water. The personal care article has a density of from about 0.05 g/cm3 to about 0.95 g/cm3.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: The Procter & Gamble CompanyInventors: Robert Wayne GLENN, JR., Todd Ryan THOMPSON, Ungyeong JUNG, Chul B. PARK, Changwei ZHU
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Patent number: 8829062Abstract: The object of the present invention is concerned with a stimuli-responsive polymer membrane and method of making the same. The method and making the membrane is a new one The entire body of the responsive membrane is a gel. Gels are used as membranes because they are permeable-swollen network. This disclosure discusses a new combination of cylindrical pores in a swollen network. When the network swells or shrinks the cylindrical pores open or close. Thus, inside the network, one can introduce ligands, function groups which due to specific interaction with some signaling molecules in the surrounding environment can cause swelling or shrinking the membrane and this way they open or close pores. With cylindrical pores in a gel there is the ability to regulate pore size in a broad range and an ability to arrange response by adding some functional groups inside the gel body.Type: GrantFiled: April 9, 2007Date of Patent: September 9, 2014Assignee: Clarkson UniversityInventors: Serigy Minko, Maxim Orlov, Ihor Tokarev, Evengy Katz
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Patent number: 8821772Abstract: A method comprising injection molding a plastic part from a polymer formulation comprising an injection moldable thermoplastic and a fluorescent compound, wherein the fluorescent compound has a decomposition temperature that establishes a maximum processing temperature for the polymer formulation. The fluorescent compound will thermally decompose to generate gaseous products causing visible bubble formation in the surface of the plastic part in response to exposure to a processing temperature that exceeds the decomposition temperature of the fluorescent compound. If the plastic part was processed without exposure to a processing temperature that exceeds the decomposition temperature of the fluorescent compound, then any fluorescent compound within the plastic part will cause the plastic part to fluoresce in response to exposure to black light. A suitable fluorescent compound may be, for example, selected from oxalates, carbamic acids, carbonic acids, diazocarbonyl compounds, and combinations thereof.Type: GrantFiled: June 19, 2012Date of Patent: September 2, 2014Assignee: International Business Machines CorporationInventors: Joseph Kuczynski, Jr., Melissa K. Miller, Heidi D. Williams, Jing Zhang
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Publication number: 20140227505Abstract: Disclosed is a method for molding a foamed article, such as a midsole or outsole for footwear, in which first water, then a desired amount of thermoplastic polyurethane foam beads are placed in a compression mold in the shape of the article and the mold is brought to a peak temperature of from about 130° C. to about 180° C. over a period of from about 300 to about 1500 seconds, then cooled to from about 5° C. to about 80° C. over a period of from about 300 to about 1500 seconds within about 30 seconds after the peak temperature is reached. The foamed article made by the method has a density of from about 0.1 to about 0.45 g/cm3.Type: ApplicationFiled: February 12, 2013Publication date: August 14, 2014Inventors: Denis Schiller, Sui-Chieh J. Yu, Hossein A. Baghdadi
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Publication number: 20140213676Abstract: A foam molding method, a foamed plastic formed by the method, and a foaming agent used in the foam molding method are provided. The foam molding method may include rotating a screw provided in a barrel, feeding a granular or powdered raw material and a foaming agent into the barrel, the foaming agent producing foam through a chemical reaction, melting the fed raw material and producing a gas from the foaming agent, and phase-changing the produced gas to a supercritical state and mixing the gas with the melted raw material.Type: ApplicationFiled: November 15, 2013Publication date: July 31, 2014Inventors: Changhoon JEONG, Daejin Jeong, Gangyoun Kim
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Patent number: 8765035Abstract: A process for manufacturing a self-extinguishing cable including at least one transmissive element and at least one flame-retardant coating in a position radially external to the at least one transmissive element, wherein the at least one coating includes an expanded flame-retardant polymeric material having (a) at least one expandable polymer; (b) at least one expanding agent; (c) at least one flame-retardant inorganic filler, in an amount of 100 parts by weight of 250 parts by weight with respect to 100 parts by weight of the at least one expandable polymer. The process includes the following steps: (i) feeding the flame-retardant polymeric material to an extruding apparatus, therein melting and mixing it; (ii) passing the flame-retardant polymeric material obtained in step (i) through at least one static mixer; and (iii) depositing by extrusion the flame-retardant polymeric material obtained in step (ii) onto the at least one transmissive element conveyed to the extruding apparatus.Type: GrantFiled: December 24, 2003Date of Patent: July 1, 2014Assignee: Prysmian Cavi E Sistemi Energia S.R.L.Inventors: Gianbattista Grasselli, Alberto Bareggi, Cristiana Scelza, Marco Frigerio, Paolo Veggetti, Sergio Belli
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Publication number: 20140145364Abstract: A noncrosslinked polyethylene resin expanded particle is provided having a bulk density BD in a range of 10 g/L to 100 g/L, the particle being obtained by expanding a polyethylene resin particle whose density is in a range of 0.920 g/cm3 to 0.940 g/cm3, the noncrosslinked polyethylene resin expanded particle having a shrinkage factor in a range of 2% to 30%, the shrinkage factor being obtained by the following formula (1): Shrinkage Factor=(BD?VBD)×100/VBD??(1), wherein: the BD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at 0.1 MPa (at a normal atmospheric pressure); and the VBD of the noncrosslinked polyethylene expanded particle is a bulk density at 23° C. and at a reduced pressure of 0.002 MPa or less.Type: ApplicationFiled: January 30, 2014Publication date: May 29, 2014Applicant: KANEKA CORPORATIONInventor: Kiyotaka NAKAYAMA
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Patent number: 8734671Abstract: An azeotrope-like mixture consisting essentially of a binary azeotrope-like mixture consisting essentially of trans-1-chloro-3,3,3-trifluoropropene (trans-HFO-1233zd) and a second component selected from the group consisting of 2,3,3,3-tetrafluoropropene (HFO-1234yf) and trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze), and combinations of these and various uses thereof.Type: GrantFiled: November 15, 2011Date of Patent: May 27, 2014Assignee: Honeywell International Inc.Inventors: Ryan Hulse, Rajiv R. Singh, Hang T. Pham
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Publication number: 20140138868Abstract: Provided are non-crosslinked foamed polyethylene resin particles that have a bulk density BD of 10 g/L or more and 100 g/L or less and are obtained by foaming polyethylene resin particles containing an antistatic agent in an amount of 0.1 part by weight or more and 3 parts by weight or less with respect to 100 parts by weight of a polyethylene resin and having a density of 0.920 g/cm3 or more and less than 0.940 g/cm3, and the non-crosslinked foamed polyethylene resin particles have a shrinkage ratio of 3% or more and 30% or less determined in accordance with Formula (1). The non-crosslinked foamed polyethylene resin particles can simply afford an antistatic molded non-crosslinked foamed polyethylene resin body that has a small shrinkage ratio with respect to mold dimension, is deformed in a small degree, and has good surface stretch.Type: ApplicationFiled: July 13, 2012Publication date: May 22, 2014Applicant: KANEKA CORPORATIONInventor: Kiyotaka Nakayama
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Patent number: 8696957Abstract: In a method of microcellular injection molding, a polymer and a supercritical fluid are processed. A condition of processing the polymer and/or the supercritical fluid is adjusted to control a weight of a plastic part and/or a surface characteristic of a plastic part produced. In another method of producing a plastic part using microcellular injection molding, a polymer is heated and melted and a supercritical fluid is added thereto. The resulting mix is a single-phase polymer-gas solution comprising the polymer and the supercritical fluid. The polymer and/or the supercritical fluid are adjusted to control the weight of the plastic part and/or a surface characteristic of the plastic part. Once adjusted, the melted polymer with the supercritical fluid is injected into a mold. Upon injecting the melted polymer and supercritical fluid, a pressure drop causes the supercritical fluid to nucleate in the melted polymer, thereby causing nucleation of bubbles.Type: GrantFiled: September 10, 2010Date of Patent: April 15, 2014Assignee: Eveready Battery Company, IncInventors: Eugene P. Dougherty, Jr., Keith Edgett, Lih-Sheng Turng, Chris Lacey, Jungjoo Lee, Patrick J. Gorton, Xiaofei Sun
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Publication number: 20130313749Abstract: An object of the invention is to provide a blow-molded foam which has homogeneous foamed cells in size, is light in weight, and is excellent in surface smoothness, and a process for producing the same. The invention is directed to a blow-molded foam 1 having a wall portion formed in such a manner that a thermoplastic resin containing a foaming agent mixed therewith is subjected to blow molding. Herein, the wall portion has a closed cell structure in which a plurality of foamed cells are contained. The wall portion has an expansion ratio of not less than 2.0 times. The wall portion has an outer face having a center-line average surface roughness Ra of less than 9.0 ?m. The foamed cell has a cell diameter having a standard deviation of less than 40 ?m in a thickness direction of the wall portion.Type: ApplicationFiled: July 24, 2013Publication date: November 28, 2013Applicant: KYORAKU CO., LTD.Inventors: Masaaki ONODERA, Takehiko SUMI, Teruo TAMADA, Yu IGARASHI, Yoshinori OHNO
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Publication number: 20130285274Abstract: A method and apparatus for controlling processing temperatures and the activation of polymer by way of machine to control, and control to machine signalling, that allows heat energy compensation for polymer heat energy loss. This is useful when a lower temperature substance, like water is added to expand natural or man made polymers within short distances like that of a nozzle.Type: ApplicationFiled: October 21, 2011Publication date: October 31, 2013Inventor: Peter Woodworth
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Patent number: 8568632Abstract: A process for making closed-cell, alkenyl aromatic polymer foams using nano-particle nucleation agents to control the cell morphology of the resulting foam includes forming a polymer melt at a temperature above the polymer glass transition temperature (for crystal polymers) or the polymer melt point (for amorphous polymers); incorporating selected nano-particles into the polymer melt; incorporating blowing agents into the polymer melt at an elevated pressure; optionally incorporating other additives, such as flame retardants, into the polymer melt; and extruding the polymer melt under conditions sufficient to produce a foam product having a desired cell morphology, characterized by parameters such as reduced average cell size range and/or increased asymmetry of the cells.Type: GrantFiled: November 26, 2003Date of Patent: October 29, 2013Assignee: Owens Corning Intellectual Capital, LLCInventors: Joseph P. Rynd, Roland R. Loh, Raymond M. Briendel
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Publication number: 20130260133Abstract: The invention relates to a process for generating a porous material having homogeneous, gas-containing inclusions in the micrometer and sub-micrometer range, and also to the material produced by such process.Type: ApplicationFiled: December 1, 2011Publication date: October 3, 2013Applicant: UNIVERSITAT ZU KOLNInventors: Reinhard Strey, Alexander Müller
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Publication number: 20130256935Abstract: A method for continuous High Internal Phase Emulsion (HIPE) foam production. A HIPE is produced then extruded onto a belt. After polymerization, a portion of the saturated aqueous phase is removed using a vacuum box. A nip insert is inserted under the vacuum box to raise the vacuum box leading to improved uniformity of the HIPE in the cross direction along the belt.Type: ApplicationFiled: March 25, 2013Publication date: October 3, 2013Applicant: The Procter & Gamble CompanyInventors: Wei-ling Siew, Jiajie Zhang, Aditya Garg
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Patent number: 8524110Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.Type: GrantFiled: April 28, 2011Date of Patent: September 3, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao
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Publication number: 20130203877Abstract: An object of the present invention is to inexpensively provide a method and device of producing a high viscosity polylactic acid composition, which composition is appropriate for foam molding having a high expansion ratio and is stable, and a foam molded article having a high expansion ratio formed of said high viscosity polylactic acid composition. A method of producing a polylactic acid foam molded article of the present invention which can achieve the above-described object is characterized by comprising a step of mechanically grinding a polylactic acid composition by applying a shear force, using a device equipped with an injection molding machine (B) or an extrusion molding machine (G), an orifice portion (S) and a foaming mold (P), in a foaming gas atmosphere in the orifice portion (S).Type: ApplicationFiled: March 29, 2011Publication date: August 8, 2013Inventors: Kosuke Uchiyama, Kazunori Tsuda, Tenya Suzuki
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Patent number: 8486294Abstract: The present invention relates to compositions containing hydrofluoroolefins and to the uses thereof as heat transfer fluids, blowing agents, solvents and aerosols. More particularly, the invention relates to compositions having: 10 to 90% by weight, of 2,3,3,3-tetrafluoropropene, 5 to 85% by weight of HFC-134a and 2 to 20% by weight of HFC-152a.Type: GrantFiled: May 14, 2009Date of Patent: July 16, 2013Assignee: Arkema FranceInventor: Wissam Rached
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Patent number: 8476327Abstract: Prepare an extruded polymeric foam by extruding a foamable polymer composition through a foaming die and allowing the foamable polymer composition to expand into a polymer foam as it travels through and is constrained in its thickness dimension by at least two constraining sections, the first having opposing essentially parallel forming plates and the second constraining section having forming plates spaced further apart than the first constraining section.Type: GrantFiled: February 24, 2010Date of Patent: July 2, 2013Assignee: Dow Global Technologies LLCInventors: Bertrand Wurtz, Van-Chau Vo
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Patent number: 8465669Abstract: To obtain a non-particle-aggregation-type organic polymer monolith separation medium, there is provided a monolith separation medium comprising a skeletal phase and pores being continuous in the form of three-dimensional network, which skeletal phase on its surface has a functional group permitting introduction of a new functional group. The skeletal phase has a non-particle-aggregation-type co-continuous structure having an average diameter of submicron to micrometer size, and is constituted of an addition polymer from an epoxy compound of bi- or higher functionality and an amine compound of bi- or higher functionality. Further, the skeletal phase is enriched in organic matter and does not contain any carbon atoms derived from aromatic series.Type: GrantFiled: August 3, 2011Date of Patent: June 18, 2013Assignee: Shimadzu CorporationInventor: Ken Hosoya
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Publication number: 20130072588Abstract: Impact resistant, medium density molded polyurethane foams are produced by the process of the present invention. These foams include from 5 to 35% by weight of glass fibers having an average fiber length of from 12.5 to 50 mm and from 25 to 60% by weight of one or more particulate fillers having an average particle size of from 0.3 to 40 microns.Type: ApplicationFiled: September 21, 2011Publication date: March 21, 2013Applicant: Bayer MaterialScience LLCInventors: James W. Rosthauser, James P. Kotar, Usama E. Younes
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Patent number: 8361363Abstract: To provide a foam board of a polyolefin resin which has an excellent heat insulating property and sound absorption property, of which a product can be material-recycled and which can continuously be produced at a low cost; a method for producing a foam board, which comprises extrusion-foaming by ejecting a mixture of a polyolefin resin composition containing a linear polypropylene resin having a melt tension of from 5 to 30 g at 230° C. and a foaming agent containing at least carbon dioxide in the supercritical state, by means of an extruder which has a multi-hole type die having an opening diameter of from 0.1 to 1.0 mm and the number of openings of from 50 to 5,000 at an ejection amount (V) of from 0.05 to 0.45 kg/hr per one opening in the die at a melt-extrusion temperature of from 160 to 250° C., under atmosphere at a proximal resin pressure of from 7 to 20 MPa at the openings of the die.Type: GrantFiled: June 27, 2008Date of Patent: January 29, 2013Assignee: Asahi Fiber Glass Company, LimitedInventors: Toru Itadani, Masaaki Ono, Kengo Ozaki
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Publication number: 20120308804Abstract: The invention relates to a molded foam body having anisotropic shape memory properties, to a method for manufacturing such a molded foam body and to an article, which contains or is composed of such a molded foam body. The molded foam body according to the invention comprises at least one shape memory polymer, which forms a foam structure having asymmetric pores oriented substantially in a common, first spatial direction (L). Said molded foam body is manufactured by foaming the polymer by means of the release of a gaseous propellant under conditions that promote the release and the escape of the propellant from the polymer substantially in a main flow direction. Following thermomechanical programming, such a shape memory foam exhibits a direction-dependent level of recovery and recovery forces when reheated.Type: ApplicationFiled: November 23, 2010Publication date: December 6, 2012Applicant: Helmholtz-Zentrum Geesthacht Zentrum fur Material-Und Kustenforschung GmbHInventors: Andreas Lendlein, Samy Madbouly, Andreas Klein, Karl Kratz, Karola Lützow
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Patent number: 8324287Abstract: Prepare a polymeric foam from a foamable polymer composition containing a thermoplastic polymer composition and a blowing agent wherein 75 percent or more by weight of all non-halogenated polymers in the foamable polymer composition is a styrene-acrylonitrile copolymer composition having a polymerized acrylonitrile content distribution with a positive skew in a copolymerized AN content distribution and a positive percent difference between the mean and the median copolymerized AN content distribution.Type: GrantFiled: March 30, 2009Date of Patent: December 4, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Stephane Costeux, William A. Heeschen
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Publication number: 20120301649Abstract: A process for producing a foamed blow-molded article, including melting and mixing a branched polycarbonate resin having a specific polystyrene equivalent weight average molecular weight, a specific weight average absolute molecular weight and a relatively high terminal hydroxyl group content, a linear polycarbonate resin having specific polystyrene equivalent weight average molecular weight, a specific weight average absolute molecular weight and a relatively low terminal hydroxyl group content and a branching agent to obtain a polycarbonate resin “A”, mixing the polycarbonate resin “A” with a blowing agent to obtain a foamable molten resin composition, extruding the foamable molten resin composition to obtain a foamed parison, and blow-molding the foamed parison.Type: ApplicationFiled: August 3, 2012Publication date: November 29, 2012Inventors: Tomoo TOKIWA, Masahiro Gomibuchi
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Publication number: 20120235781Abstract: A method of forming a film is described. The method begins by forming a mixture including a polymer and a plurality of unordered nanomaterial. The film is dried and a plurality of pores is formed within the film. A sensitive film transducer capable of detecting changes in pressure and applied force can be made using this method.Type: ApplicationFiled: November 30, 2009Publication date: September 20, 2012Inventor: Zuruzi Bin Abu Samah
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Patent number: 8268904Abstract: Prepare an extruded polymeric foam using a thermoplastic polymer composition of styrene-acrylonitrile copolymer having a copolymerized acrylonitrile comonomer content of 20 weight-percent or less, a mean acrylonitrile comonomer content that exceeds its median acrylonitrile comonomer content and an average copolymerized acrylonitrile comonomer distribution having a breadth at half-height that is greater than 2.5 weight-percent as measured at half peak height of a copolymerized acrylonitrile comonomer distribution curve for the styrene-acrylonitrile copolymer.Type: GrantFiled: September 8, 2010Date of Patent: September 18, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Brian H. Deshano
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Publication number: 20120183760Abstract: Disclosed are: a low dielectric sheet which is used for 2-D communication, can be used in a sheet structure for 2-D communication, and has the lowest dielectric constant and dielectric loss tangent to date; a production method therefor; and a 2-D communication structure using the dielectric sheet for 2-D communication. Specifically disclosed is a low dielectric sheet which is used for 2-D communication and is characterized by having a density of 0.01 to 0.2 g/cm3 and a dielectric constant of no more than 1.6. In particular, a foam that comprises cells and has a dielectric loss tangent of no more than 0.01 is preferred.Type: ApplicationFiled: September 29, 2010Publication date: July 19, 2012Applicant: NITTO DENKO CORPORATIONInventors: Kiyoaki Kodama, Makoto Saitou, Hiroichi Ukei, Toshihiko Tomita
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Publication number: 20120168976Abstract: A microporous film comprises a first component comprising a super high molecular weight polyolefin resin, wherein the weight-average molecular weight of the super high molecular weight polyolefin is about 1×106 to about 6×106. The microporous film also comprises a second component comprising a polyolefin resin, wherein the weight-average molecular weight of the polyolefin resin is less than about 5×105. A method of producing a microporous film comprises melting a first polyolefin resin which is a super high molecular weight polyolefin resin in a solvent to form a first mixture, and adding to the first mixture a second polyolefin resin having a weight-average molecular weight of the less than about 5×105 to form a second mixture.Type: ApplicationFiled: March 12, 2012Publication date: July 5, 2012Applicant: BYD Co. Ltd.Inventors: Mingjun Luo, Zhen You, Huiquan Liu
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Patent number: 8206626Abstract: Process for the production of moldings from nanoporous polymer materials, comprising the stages of a) preparation of a multiphase polymer mixture with domains in the range from 5 to 200 nm, b) impregnation of the polymer mixture with a blowing agent, where the solubility of the blowing agent in the phase forming the domains is at least twice as high as in the adjacent phases, c) expansion of the multiphase polymer mixture comprising blowing agent, by introducing the polymer mixture into a cavity and expanding it therein, thus obtaining the molding.Type: GrantFiled: June 27, 2007Date of Patent: June 26, 2012Assignee: BASF SEInventors: Andre Guerin Moreira, Marc Bothe, Volker Schädler, Markus Allmendinger, Pedro Manuel Sampaio Lopes, Bernd Sowart, Timothy Francis, Erik Waβner, Christian Schade, Daniela Longo, Siljana Lietz, Volker Alstädt, Jan Sandler
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Publication number: 20120107602Abstract: A method of treating an article made of a fluoropolymer such as PTFE and, in particular, expanded PTFE (ePTFE), to provide a hydrophilic surface characteristic to the article. A filler is dispersed in a solvent and combined with PTFE to form a paste, which is extruded to form a shaped article and then expanded to form a porous ePTFE article, such as a tubular filter, for example, that includes filler particles dispersed and embedded within the bulk ePTFE. Functional groups of at least some of the filler particles are exposed at the surfaces or within the pores of the ePTFE article, which serve as reaction sites for a hydrophilic treatment by which hydrophilic molecules are chemically bound to the filler particles to thereby provide the surface and/or pores of the ePTFE article with a hydrophilic characteristic.Type: ApplicationFiled: October 24, 2011Publication date: May 3, 2012Applicant: WHITFORD CORPORATIONInventor: Daniel C. Chung
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Patent number: 8168096Abstract: A process for producing polystyrene foam particles having a bulk density in the range from 40 to 400 g/l by extrusion of a polystyrene melt comprising carbon dioxide and/or water as blowing agent through a nozzle and underwater pelletization, wherein the underwater pelletization is carried out at a pressure in the range 1-30 bar.Type: GrantFiled: April 5, 2006Date of Patent: May 1, 2012Assignee: BASF SEInventors: Markus Allmendinger, Klaus Hahn, Joachim Ruch
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Publication number: 20120061870Abstract: In a method of microcellular injection molding, a polymer and a supercritical fluid are processed. A condition of processing the polymer and/or the supercritical fluid is adjusted to control a weight of a plastic part and/or a surface characteristic of a plastic part produced. In another method of producing a plastic part using microcellular injection molding, a polymer is heated and melted and a supercritical fluid is added thereto. The resulting mix is a single-phase polymer-gas solution comprising the polymer and the supercritical fluid. The polymer and/or the supercritical fluid are adjusted to control the weight of the plastic part and/or a surface characteristic of the plastic part. Once adjusted, the melted polymer with the supercritical fluid is injected into a mold. Upon injecting the melted polymer and supercritical fluid, a pressure drop causes the supercritical fluid to nucleate in the melted polymer, thereby causing nucleation of bubbles.Type: ApplicationFiled: September 10, 2010Publication date: March 15, 2012Applicant: PLAYTEX PRODUCTS LLCInventors: Eugene P. Dougherty, JR., Keith Edgett, Lih-Sheng Turng, Chris Lacey, Jungjoo Lee, Patrick J. Gorton, Xiaofei Sun
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Patent number: 8084510Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided.Type: GrantFiled: October 25, 2007Date of Patent: December 27, 2011Assignee: Sekisui Plastics Co., Ltd.Inventors: Ikuo Morioka, Yasutaka Tsutsui, Hideyasu Matsumura
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Publication number: 20110313069Abstract: In a flame-retarded foamable styrene-based resin composition comprising a bromine-containing flame retardant, the flame retardant is a mixture of (a) an organic bromine-containing compound having a 2,3-dibromopropyl group or an organic bromine-containing compound having a bromine content of greater than 60 wt % in which all bromine atoms are attached to a benzene ring, and (b) an organic bromine compound having a 2,3-dibromo-2-alkylpropyl group. The composition comprises this mixture in amount from 0.5 to 10 parts by weight per 100 parts by weight of the styrene-based resin. The composition exhibits high flame retardant and heat stabilizing effects yet allowing recycling.Type: ApplicationFiled: April 2, 2011Publication date: December 22, 2011Inventors: Hideaki Onishi, HIsanori Semori, Masashi Asaoka
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Patent number: 8043539Abstract: Using a metal mold (20a) consisting of a convex mold part (21a) and a concave mold part (22a), a molding material (14) is placed between a pair of coating films (12), and after clamping, the molding material (14) and the coating film (12) are heated and molded to make a biodegradable expanded molded article, and at the same time, the coating film (12) is softened and pressure-bonded to a surface of the biodegradable expanded molded article. An exhaust hole (31a) and (32a) are provided on the convex mold part (21a) and the concave mold part (22a), respectively. At the time of heating and molding, gaseous matter existing between the coating film (12) and a surface of the metal mold (20a) is discharged out of the metal mold (20a) through the exhaust holes (31a) and (32a).Type: GrantFiled: March 12, 2003Date of Patent: October 25, 2011Assignee: Nissei Company, Ltd.Inventors: Akio Ozasa, Akihisa Hashimoto, Rumi Shinohara, Shinji Tanaka, Takeshi Shingu
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Patent number: 8034266Abstract: A process for the production of an open-cell carbon foam from a metallic salt of a lignosulfonate is described. The process includes heating the metallic salt of a lignosulfonate from ambient temperature to a maximum temperature, greater than about 250° C., at a rate sufficiently slow as to provide for essentially uniform heating of the lignin derived material. Heating of the lignin derived material is performed in a non-oxidizing atmosphere having a pressure greater than about 100 psig. The resultant carbon foam can subsequently be optionally subjected to carbonization or graphitization temperatures as desired. The resultant carbon foam has a regular open-cell structure. Densities of the carbon foam products are commonly in the range of about 0.1 g/cm3 to 0.2 g/cm3. The carbon foams may also exhibit compressive strengths of up to about 200 psi. The carbon foam materials potentially have utility as lightweight thermal barriers and in many other of the applications associated with carbon foams.Type: GrantFiled: August 3, 2004Date of Patent: October 11, 2011Assignee: Touchstone Research Laboratory, Ltd.Inventors: Drew M. Spradling, Doug R. Amie
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Material and sheet for packaging bacon and/or other meats, and methods for making and using the same
Publication number: 20110195165Abstract: A packaging sheet, which can also be used for packaging other meats, includes a polymer having a microstructure that includes a plurality of closed cells, each cell containing a void and each cell having a maximum dimension extending across the void within the cell that ranges between 1 micrometer and 200 micrometers long. When used to package bacon, the packaging sheet may also include a main portion, a flap pivotable relative to the main portion, a first surface that extends across the main portion and the flap, and that contacts the bacon, a second surface that extends across the main portion and the flap, and that does not contact the bacon, and a thickness that extends from the first surface to the second surface in a direction perpendicular to the first surface.Type: ApplicationFiled: February 8, 2010Publication date: August 11, 2011Inventor: John E. Cahill -
Patent number: 7959825Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.Type: GrantFiled: June 17, 2009Date of Patent: June 14, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao, Donald Bernard Bivens, Deepak Perti, Mark Steven Baunchalk
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Patent number: 7956094Abstract: A method is provided for sterilizing a collagen preparation and for production of self-sterilized, antiseptic collagen preparations. The preparations may be used for producing collagen products, such as sponges, films or gels, especially for medical and/or cosmetic purposes.Type: GrantFiled: April 18, 2006Date of Patent: June 7, 2011Assignee: Lohmann & Rauscher GmbH & Co. KGInventors: Corneliu Iulian Alupei, Marius-Thomas Gorka, Peter Ruth, Christian Rohrer, Helmut Leuprecht
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Patent number: RE42424Abstract: In the extrusion of feed-stuff pellets and relevant consumer products, the extruded products are subject to expansion as a result of the boiling of their water content when the products, after being exposed to high extrusion pressure and a correspondingly high temperature, are discharged to the atmosphere through the extrusion nozzles. Such an expansion is directly aimed at, but it is desirable to be able to control it, which is difficult by adjustment of the ordinary process parameters. With the invention it has been found that the expansion which arises can be controlled in a highly constant manner, i.e. by carrying out the extrusion into a closed chamber in which an over-pressure of a few bar is established in relation to the atmospheric pressure, and which can be regulated. The extrusion products can be continuously discharged from this chamber, or they can be discharged intermittently in portions.Type: GrantFiled: May 27, 1999Date of Patent: June 7, 2011Assignee: Andritz Feed & Biofuel A/SInventor: Anders Flarup-Knudsen