Plural Or Incremental Expansion Steps Patents (Class 264/55)
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Patent number: 12053913Abstract: A foam molding apparatus and a foam molding method thereby are proposed. The foam molding apparatus includes a foaming agent supply unit configured to supply a foaming agent, a molten resin supply unit configured to supply molten resin, a fixed mixing unit configured to produce a foaming resin-critical solution by mixing a foaming agent supplied from the foaming agent supply unit and molten resin supplied from the molten resin supply unit through a rod-shaped body, and a molding unit configured to mold a foam molding product using the foaming resin-critical solution supplied from the fixed mixing unit. Accordingly, it is possible to produce a foaming resin-critical solution by uniformly mixing a large amount of high-viscosity gel-state molten resin and a high-pressure compressed and low-viscosity foaming agent, using high-strength multiple channels.Type: GrantFiled: August 5, 2020Date of Patent: August 6, 2024Assignee: etat'H solideInventor: Myung Ho Kang
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Patent number: 12049031Abstract: The invention relates to a process for the production of a composite component (33) which comprises a molding (1) made of a thermoplastic polymer foam and which comprises a functional layer (37) made of an unfoamed thermoplastic, comprising the following steps: (e) insertion of the molding (1) made of thermoplastic polymer foam into a mold (3), (f) application of a thermoplastic polymer by an injection process, where the pressure during the application of the thermoplastic polymer is smaller than 100 bar.Type: GrantFiled: February 13, 2015Date of Patent: July 30, 2024Assignee: BASF SEInventors: Jürgen Lambert, Christian Obermann, Jürgen Bartl, Andreas Medert
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Patent number: 11851583Abstract: The invention relates to a process for producing a porous polyurethane coatings, using a polyol ester as additives in an aqueous polymer dispersion, the process comprising the steps of a) providing a mixture comprising an aqueous polymer dispersion, a polyol ester, and an additive, b) foaming the mixture to give a homogeneous, fine-cell foam, c) adding at least one thickener to establish the desired viscosity of the wet foam, d) applying a coating of the foamed polymer dispersion to a suitable carrier, e) drying the coating. The invention further relates to a phosphorylated polyol ester.Type: GrantFiled: July 13, 2017Date of Patent: December 26, 2023Assignee: Evonik Operations GmbHInventors: Michael Klostermann, Martin Glos, Jan Marian Von Hof, Verena Dahl, Christian Eilbracht, Oliver Springer, Hans Henning Wenk
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Patent number: 11623375Abstract: The process for forming closed cell expanded low density polyethylene foam includes the steps of: providing a mixture including low density polyethylene pellets and an effective amount of hydrocarbon scavenger additives or degassing agents, such as glycerides; adding a primary blowing agent comprising one of liquid propane, liquid butane, and combinations thereof, to the mixture and gasifying the blowing agent to expand the low density polyethylene; forming the expanded low density polyethylene into sheets, curing the expanded low density polyethylene until 80%, generally at least 99%, of the primary blowing agent is dissipated from cells within the expanded low density polyethylene forming evacuated closed cell low density polyethylene sheets.Type: GrantFiled: July 31, 2020Date of Patent: April 11, 2023Inventor: Joseph Riccelli
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Patent number: 11571843Abstract: According to the present invention, a side part cavity (23) in which a side part is molded, a body part cavity (24) in which a body part is molded, and an attachment part cavity (25) in which an attachment part is molded are formed between a plurality of molding molds (21, 22), and a guiding part (26) that is configured to guide a foam to the body part cavity when an undiluted foam solution of the second synthetic resin material supplied to the side part cavity foams is arranged at a part of the side part cavity adjacent to, in a left-right direction X, a rear end part of the body part cavity in which a non-contact part is molded.Type: GrantFiled: January 24, 2018Date of Patent: February 7, 2023Assignee: Archem Inc.Inventors: Yoshiyuki Takahashi, Taisuke Yonezawa, Yukiko Tsugawa
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Patent number: 11351707Abstract: An additive injection system for use in injection molding machines to inject additive materials, such as fluids or powders, downstream of a nozzle of the injection molding machine. The additive injection unit has an additive tank to store or contain additive material and additive injectors that inject an additive material into an injection molding machine. A pump pumps the additive material from the tank through a common manifold connected to the additive injectors to be injected into the injection molding machine. A controller controls operation of the additive injection device and one or more sensors coupled to the additive injection device can provide feedback to the controller.Type: GrantFiled: April 21, 2020Date of Patent: June 7, 2022Assignee: IMFLUX INC.Inventors: Milko Gergov, Gene Michael Altonen, Herbert Kenneth Hanson, III, William Francis Lawless, III
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Publication number: 20150094391Abstract: A method of forming an element to float at least partially on a surface of an at least partially liquid hydrocarbon mixture. The method includes mixing a polymer resin and a foaming agent together in preselected proportions to provide a material mixture, and heating the material mixture, to at least partially liquefy it. The material mixture is injected into a mold cavity configured to define the element's exterior surface in a series of at least three steps, commencing with an initial step. In each step, the material mixture is injected over a predetermined time period at a predetermined velocity and under a predetermined pressure. Each predetermined velocity in the steps following the initial step is less than the predetermined velocity in an immediately preceding step thereof. Each predetermined pressure in the steps following the initial step is less than the predetermined pressure in the immediately preceding step thereof.Type: ApplicationFiled: October 2, 2013Publication date: April 2, 2015Applicant: Greatario Industries Storage Systems Ltd.Inventors: J. Scott Burn, Terrance J. Frank, Steven A. Coppa
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Patent number: 8926874Abstract: The present invention relates to a porous manganese oxide-based lithium absorbent and a method for preparing the same. The method includes the steps of preparing a mixture by mixing a reactant for the synthesis of a lithium-manganese oxide precursor powder with an inorganic binder, molding the mixture, preparing a porous lithium-manganese oxide precursor molded body by heat-treating the molded mixture, and acid-treating the porous lithium-manganese oxide precursor molded body such that lithium ions of the porous lithium-manganese oxide precursor are exchanged with hydrogen ions, wherein pores are formed in the lithium-manganese oxide precursor molded body by gas generated in the heat treatment. The porous manganese oxide-based lithium adsorbent according to the present invention is easy to handle and has many more adsorption reaction sites compared to existing molded adsorbents, thus providing high lithium adsorption efficiency.Type: GrantFiled: June 26, 2012Date of Patent: January 6, 2015Assignee: Korea Institute of Geoscience and Mineral Resources (KIGAM)Inventors: Kang-Sup Chung, Tae Gong Ryu, Byoung Gyu Kim, Jung Ho Ryu
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Patent number: 8889046Abstract: A method comprising injection molding a plastic part from a polymer formulation comprising an injection moldable thermoplastic and an additive, wherein the additive has a decomposition temperature that establishes a maximum processing temperature for the polymer formulation. The additive will thermally decompose to generate gaseous products causing visible bubble formation in the surface of the plastic part in response to exposure to a processing temperature that exceeds the decomposition temperature of the additive. A suitable additive may be, for example, selected from oxalates, carbamic acids, carbonic acids, diazocarbonyl compounds, and combinations thereof.Type: GrantFiled: December 6, 2011Date of Patent: November 18, 2014Assignee: International Business Machines CorporationInventors: Joseph Kuczynski, Melissa K. Miller, Heidi D. Williams, Jing Zhang
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Patent number: 8871122Abstract: A method facilitates fabricating a cellular cushion. The method comprises injecting material into a mold in an injection molding process to form a cushion first layer that includes a plurality of hollow cells that extend outward from the base and are each coupled together in flow communication, coupling a second layer to the first layer, and coupling an injection stem in flow communication to the plurality of hollow cells to enable an operating pressure within the cells to be changed.Type: GrantFiled: July 23, 2003Date of Patent: October 28, 2014Assignee: Star Cushion Products, Inc.Inventor: Kevin Gerard Fraser
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Patent number: 8765035Abstract: A process for manufacturing a self-extinguishing cable including at least one transmissive element and at least one flame-retardant coating in a position radially external to the at least one transmissive element, wherein the at least one coating includes an expanded flame-retardant polymeric material having (a) at least one expandable polymer; (b) at least one expanding agent; (c) at least one flame-retardant inorganic filler, in an amount of 100 parts by weight of 250 parts by weight with respect to 100 parts by weight of the at least one expandable polymer. The process includes the following steps: (i) feeding the flame-retardant polymeric material to an extruding apparatus, therein melting and mixing it; (ii) passing the flame-retardant polymeric material obtained in step (i) through at least one static mixer; and (iii) depositing by extrusion the flame-retardant polymeric material obtained in step (ii) onto the at least one transmissive element conveyed to the extruding apparatus.Type: GrantFiled: December 24, 2003Date of Patent: July 1, 2014Assignee: Prysmian Cavi E Sistemi Energia S.R.L.Inventors: Gianbattista Grasselli, Alberto Bareggi, Cristiana Scelza, Marco Frigerio, Paolo Veggetti, Sergio Belli
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Patent number: 8715437Abstract: A composite foam product comprising a foam core surrounded by a gas-impermeable film. The gas-impermeable film retains the gas formed from the blowing agent so that the pressure inside the foam core is above ambient pressures.Type: GrantFiled: February 22, 2010Date of Patent: May 6, 2014Assignee: Novation IQ LLCInventor: Michel Marc
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Patent number: 8536240Abstract: An expandable polystyrene composition in the form of expandable beads, comprising by weight (1) 100 parts of a styrene polymer, (2) from 2.2 to less than 4.0 parts of at least one blowing agent, and (3) from 0.01 to 0.4 part of at least one plasticizing. The composition is particularly useful for manufacturing medium density expanded moulded polystyrene objects, particularly with a density from 40 to 190 g/l. A process for manufacturing such objects,is provided, together with pre-expanded beads with a buld density of 40 to 190 g/l, containing by weight (a) 100 parts of a styrene polymer, (b) from 0.5 to less than 3.0 parts of at least one blowing agent, and (c) from 0 to 0.4 part of at least one plasticizing agent.Type: GrantFiled: July 14, 2004Date of Patent: September 17, 2013Assignee: Ineos Commercial Services UK LimitedInventors: Philippe-Luc Bres, Christophe Carlier, Alexandre Gallice, Uwe Waeckerle
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Patent number: 8476327Abstract: Prepare an extruded polymeric foam by extruding a foamable polymer composition through a foaming die and allowing the foamable polymer composition to expand into a polymer foam as it travels through and is constrained in its thickness dimension by at least two constraining sections, the first having opposing essentially parallel forming plates and the second constraining section having forming plates spaced further apart than the first constraining section.Type: GrantFiled: February 24, 2010Date of Patent: July 2, 2013Assignee: Dow Global Technologies LLCInventors: Bertrand Wurtz, Van-Chau Vo
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Publication number: 20120321873Abstract: A polymeric foam has a thermoplastic polymer matrix defining multiple cells, the foam characterized by: (a) the polymer matrix having greater than 50 weight-percent copolymer containing at least two different monomers at least one of which is a methacrylate monomer, each monomer having a solubility parameter lower than 20 (megaPascals)0.5 and a chemical composition where twice the mass fraction of oxygen plus the mass fraction of nitrogen, fluorine and silicon is greater than 0.2; wherein the monomers comprise at least 90 weight-percent of all monomers in the copolymer; (b) at least one of the following: (i) a nucleation site density of at least 3×1014 effective nucleation sites per cubic centimeter of foamable polymer composition; (ii) an average cell size of 300 nanometer or less; (c) a porosity percentage greater than 30%; (d) an absence of nano-sized nucleating additive; and (e) a thickness of at least one millimeter.Type: ApplicationFiled: February 23, 2011Publication date: December 20, 2012Inventors: Stephane Costeux, Lingbo Zhu, Hyun Jeon, Shana P. Bunker, Thomas H. Kalantar
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Patent number: 8324287Abstract: Prepare a polymeric foam from a foamable polymer composition containing a thermoplastic polymer composition and a blowing agent wherein 75 percent or more by weight of all non-halogenated polymers in the foamable polymer composition is a styrene-acrylonitrile copolymer composition having a polymerized acrylonitrile content distribution with a positive skew in a copolymerized AN content distribution and a positive percent difference between the mean and the median copolymerized AN content distribution.Type: GrantFiled: March 30, 2009Date of Patent: December 4, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Stephane Costeux, William A. Heeschen
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Patent number: 8268904Abstract: Prepare an extruded polymeric foam using a thermoplastic polymer composition of styrene-acrylonitrile copolymer having a copolymerized acrylonitrile comonomer content of 20 weight-percent or less, a mean acrylonitrile comonomer content that exceeds its median acrylonitrile comonomer content and an average copolymerized acrylonitrile comonomer distribution having a breadth at half-height that is greater than 2.5 weight-percent as measured at half peak height of a copolymerized acrylonitrile comonomer distribution curve for the styrene-acrylonitrile copolymer.Type: GrantFiled: September 8, 2010Date of Patent: September 18, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Brian H. Deshano
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Patent number: 8168293Abstract: Formulation for cellular, foamed-polymer product based on polyvinyl chloride, comprising: a polyvinyl chloride homopolymer having a K-value of from 60 to 85 and a pH value of the aqueous extract ranging of from 8 to 12; at least one isocyanate selected from isomers and homologues of diphenylmethane-4,4?-diisocyanate and modified diphenylmethane-4,4-diisocyanate s and mixtures thereof; at least one anhydride selected from the group of succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, cyclohexane-1,2-dicarboxylic anhydride, methyl-endomethylene tetrahydrophthalic anhydride, dodecenyl succinic anhydride, trimellitic anhydride and mixtures thereof; at least a surfactant; at least a foaming agent.Type: GrantFiled: June 5, 2007Date of Patent: May 1, 2012Assignee: Diab International ABInventors: Leone Lauri, Sam Shehyee Ang, Jan Jerry Christian Stigsson, Raffaela Bressan
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Publication number: 20120065286Abstract: The present invention enables the secondary expansion of lightweight foamed beads. The foamed beads are produced using a compound comprising a compostable or biobased polyester and a physical blowing agent as well as a chemical blowing agent. Secondary expansion can be used either to lower the density of the foamed bead further or to enable expansion of the beads during molding to promote fusion. The foam beads can be produced using conventional melt processing techniques, such as single and twin-screw extrusion processes.Type: ApplicationFiled: September 12, 2011Publication date: March 15, 2012Applicant: Lifoam IndustriesInventors: Adam R. Pawloski, Jeffrey J. Cernohous, Kent Kaske, Garrett Van Gorden
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Patent number: 8133420Abstract: Expandable polymer compositions are used to reinforce or provide various types of insulation to cavities in structural elements. The polymer compositions include at least two different segments, which may or may not be joined. At least one of the segments will expand before another segment when heated. The first-to-expand segment forms a physical barrier to the expansion of later-expanding segments, thereby restricting the expansion of the later-expanding segment in at least one direction. In this manner, the location of the expanded polymer within the cavity can be easily and inexpensively controlled.Type: GrantFiled: August 9, 2007Date of Patent: March 13, 2012Assignee: Dow Global Technologies LLCInventors: Frank V. Billotto, Mark P. Allen, Frank J. Flavin
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Publication number: 20120007267Abstract: The present invention describes compostable or biobased foams that are useful for fabricating foamed articles. The foams are produced using a compound comprising a compostable or biobased polyester and a blowing agent. Additives including plasticizers and chain extenders are optionally included in the compostable or biobased composition. These foams can be produced using conventional melt processing techniques, such as single and twin-screw extrusion processes. In one embodiment, foamed strand profiles are cooled and cut using conventional strand pelletizing equipment. In another embodiment, foamed beads are produced by cutting the foamed strand at the face of the extrusion die and the foamed bead or strand is subsequently cooled. The resulting compostable or biobased foamed bead has a specific gravity less than 0.15 g/cm3 and the foam is compostable, as determined by ASTM D6400.Type: ApplicationFiled: July 7, 2011Publication date: January 12, 2012Applicant: Lifoam IndustriesInventors: Adam R. Pawloski, Jeffrey J. Cernohous, Kent Kaske
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Patent number: 8048349Abstract: The method of the present invention is adapted to foam and crosslink a raw material including a rubber, a crosslinking agent and a foaming agent. The method includes the following steps: (1) a first crosslinking and foaming step, placing the raw material into a first mold, crosslinking and foaming the raw material to form a pre-molded body; (2) a second crosslinking and foaming step, withdrawing the pre-molded body from the first mold, placing the pre-molded body into a second mold after the pre-molded body being cooled down, crosslinking and foaming the pre-molded body to form a molded body; and (3) a third crosslinking and foaming step, withdrawing the molded body from the second mold, placing the molded body into a heating device after the molded body being cooled down, crosslinking and foaming the molded body to form a product.Type: GrantFiled: February 11, 2010Date of Patent: November 1, 2011Inventor: Chun-Fu Kuo
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Patent number: 7998313Abstract: Inflated fibers of regenerated cellulose and other regenerated structures are formed from ionic liquid/cellulose dope. Fibers so produced may be incorporated into absorbent sheet with other papermaking fibers to provide softness, bulk and absorbency.Type: GrantFiled: November 8, 2007Date of Patent: August 16, 2011Assignee: Georgia-Pacific Consumer Products LPInventor: Bruce J. Kokko
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Publication number: 20110193254Abstract: The method of the present invention is adapted to foam and crosslink a raw material including a rubber, a crosslinking agent and a foaming agent. The method includes the following steps: (1) a first crosslinking and foaming step, placing the raw material into a first mold, crosslinking and foaming the raw material to form a pre-molded body; (2) a second crosslinking and foaming step, withdrawing the pre-molded body from the first mold, placing the pre-molded body into a second mold after the pre-molded body being cooled down, crosslinking and foaming the pre-molded body to form a molded body; and (3) a third crosslinking and foaming step, withdrawing the molded body from the second mold, placing the molded body into a heating device after the molded body being cooled down, crosslinking and foaming the molded body to form a product.Type: ApplicationFiled: February 11, 2010Publication date: August 11, 2011Inventor: Chun-Fu KUO
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Patent number: 7968023Abstract: The invention relates to a process and a device for the production of polyurethane clock foam, in which the reaction mixture, after flowing through a mixer, flows freely from an outflow opening and then flows through an accumulation chamber, in which a static pressure is built up, a gap and finally an expansion chamber.Type: GrantFiled: October 19, 2007Date of Patent: June 28, 2011Assignee: Hennecke GmbHInventors: Juergen Wirth, Martin Schamberg, Horst Klahre
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Patent number: 7919538Abstract: Polymer foam containing styrene-acrylonitrile and containing one or more infrared attenuating agents achieves surprisingly high dimensional integrity at elevated temperatures.Type: GrantFiled: October 15, 2007Date of Patent: April 5, 2011Assignee: Dow Global Technologies LLCInventors: Chau V. Vo, Lawrence S. Hood
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Patent number: 7901602Abstract: According to the present invention, there is provided a method for producing expandable styrene-modified olefin-based resin particles comprising steps of: impregnating styrene-modified olefin-based resin particles with an easily volatile blowing agent to obtain expandable resin particles, and impregnating 100 parts by weight of the expandable resin particles with 0.1 to 2.0 parts by weight of a surfactant at a temperature of 10 to 30° C. and at a pressure of 0.05 to 0.30 MPa, to obtain expandable styrene-modified olefin-based resin particles.Type: GrantFiled: March 22, 2004Date of Patent: March 8, 2011Assignee: Sekisui Plastics Co., Ltd.Inventors: Narihiko Togou, Masaya Satou
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Patent number: 7858002Abstract: An injection-foaming method for a thermoplastic resin comprising using an injection unit 30 provided with a hopper 35, a plasticizing cylinder 31 and a screw 32, and a mold 10 having a mold cavity 10a of changeable capacity; filling the mold cavity 10a with a foaming-agent-containing melted resin injected from the injection unit 30; and then enlarging the mold cavity 10a for allowing the foaming-agent-containing melted resin to expand, wherein inclusion of a foaming agent into a thermoplastic resin is done by using a mixture of a foam nucleating agent and a foaming gas as foaming agent, feeding the mixture to hopper 35 or plasticizing cylinder 31 and screw 32 of injection unit 30 at a pressure of 0.1 MPa or more and less than 1.0 MPa, and contacting the mixture with a pre- or post-plasticized thermoplastic resin present in hopper 35 or plasticizing cylinder 31 and screw 32.Type: GrantFiled: July 21, 2005Date of Patent: December 28, 2010Assignee: Ube Machinery Corporation, Ltd.Inventors: Akio Okamoto, Kazuaki Miyamoto
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Publication number: 20100261000Abstract: Composite laminated article having: a first layer of a fibre-reinforced resin, a second layer of a closed cell foam of a thermoplastic material, and a third layer of a fibre-reinforced resin, the resin of the first and third layers respectively adhering a surface of the first and third layers to a respective surface of the second layer to form a sandwich construction of the first, second and third layers, wherein the closed cell foam comprises a plurality of expanded beads mutually welded together, each bead comprising a plurality of closed cells, wherein in each bead the closed cell foam has an average cell size of from 15 to 75 microns, at least 50% of the beads comprise first beads having a uniform cell size in which the maximum cell size is 100 microns and at most 50% of the beads comprise second beads having a non-uniform cell size in which the majority of cells have a maximum cell size of 100 microns and a minority of cells have a maximum cell size from more than 100 microns to up to 660 microns.Type: ApplicationFiled: October 6, 2008Publication date: October 14, 2010Applicant: Gurit (UK) Ltd.Inventor: Daniel Thomas Jones
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Publication number: 20100213631Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: ApplicationFiled: April 29, 2010Publication date: August 26, 2010Applicant: NOVA Chemicals Inc..Inventors: Jiansheng Tang, David Allen Cowan, Dennis H. Piispanen, Michael T. Williams
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Patent number: 7740776Abstract: A method for injection foaming molding of a thermoplastic resin includes the steps of (1) injecting the foaming-agent-containing plasticized resin from an injection apparatus 30 to fill a mold cavity 10a, (2) releasing a clamping force of a mold 10 immediately after the foaming-agent-containing plasticized resin is injected and filled into the mold cavity 10a, so as to release the pressure of the foaming-agent-containing plasticized resin in the mold cavity 10a, (3) maintaining the pressure-released state of the foaming-agent-containing plasticized resin in the mold cavity 10a for a predetermined period of time, (4) expanding the mold cavity 10a to foam the foaming-agent-containing plasticized resin, and (5) cooling and maintaining the foaming-agent-containing plasticized resin while the mold cavity 10a is in the expanded state.Type: GrantFiled: August 23, 2006Date of Patent: June 22, 2010Assignee: Ube Machinery Corporation, Ltd.Inventors: Akio Okamoto, Kazuaki Miyamoto
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Publication number: 20100068487Abstract: Formulation for cellular, foamed-polymer product based on polyvinyl chloride, comprising: a polyvinyl chloride homopolymer having a K-value of from 60 to 85 and a pH value of the aqueous extract ranging of from 8 to 12; at least one isocyanate selected from isomers and homologues of diphenylmethane-4,4?-diisocyanate and modified diphenylmethane-4,4-diisocyanate s and mixtures thereof; at least one anhydride selected from the group of succinic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, 4-methyl-hexahydrophthalic anhydride, cyclohexane-1,2-dicarboxylic anhydride, methyl-endomethylene tetrahydrophthalic anhydride, dodecenyl succinic anhydride, trimellitic anhydride and mixtures thereof; at least a surfactant; at least a foaming agent.Type: ApplicationFiled: June 5, 2007Publication date: March 18, 2010Inventors: Leone Lauri, Sam Shehyee Ang, Jan Jerry Christian Stigsson, Raffaela Bressan
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Publication number: 20090155537Abstract: A process for producing a thermoplastic elastomer composition foam body is provided that includes, in sequence, a step of injecting by an injection molding machine into a cavity of a mold for injection molding a foaming agent and a thermoplastic elastomer composition comprising component (A), component (B), and component (C) below, component (B) having a content of 5 to 150 parts by weight relative to 100 parts by weight of component (A) and component (C) having a content of 5 to 300 parts by weight relative to 100 parts by weight of component (A), a step of holding for not less than 4 seconds after completion of the injection, and a step of enlarging the volume of the cavity by moving a wall face of the cavity to a predetermined position. (A): A hydrogenated product of a block copolymer comprising a block composed of an aromatic vinyl compound-based monomer unit and a block composed of a conjugated diene compound-based monomer unit, (B): a propylene resin, and (C): a mineral oil.Type: ApplicationFiled: December 10, 2008Publication date: June 18, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kazuyoshi Fuse, Yuya Yamamoto
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Publication number: 20090108485Abstract: The thermoplastic elastomer composition of the present invention comprises a thermoplastic elastomer which includes an ethylene.?-olefin copolymer and a crystalline polyethylene resin, wherein the crystalline polyethylene resin constitutes a three-dimensional network structure in a matrix formed by the ethylene.?-olefin copolymer, an organic or inorganic blowing agent and a nucleating agent, wherein the thermoplastic elastomer has a melt flow rate of 5 g/10 min or more at a temperature of 230° C. and a load of 10 kg, and a melt tension of 3.0 gf or more at a temperature of 210° C. and a pulling rate of 2 m/min. Also the foam injection molding method of the present invention is a method including injecting the above-mentioned composition into a cavity space of a metal mold and then expanding the cavity space to foam by opening the metal mold at a mold opening rate of 0.05 to 0.4 mm/sec.Type: ApplicationFiled: December 29, 2008Publication date: April 30, 2009Applicants: Honda Motor Co., Ltd., JSR CORPORATIONInventors: Tomokazu Abe, Katumasa Idea, Akihiko Morikawa, Kentarou Kanae
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Publication number: 20080290543Abstract: An injection-foaming method for a thermoplastic resin comprising using an injection unit 30 provided with a hopper 35, a plasticizing cylinder 31 and a screw 32, and a mold 10 having a mold cavity 10a of changeable capacity; filling the mold cavity 10a with a foaming-agent-containing melted resin injected from the injection unit 30; and then enlarging the mold cavity 10a for allowing the foaming-agent-containing melted resin to expand, wherein inclusion of a foaming agent into a thermoplastic resin is done by using a mixture of a foam nucleating agent and a foaming gas as foaming agent, feeding the mixture to hopper 35 or plasticizing cylinder 31 and screw 32 of injection unit 30 at a pressure of 0.1 MPa or more and less than 1.0 MPa, and contacting the mixture with a pre- or post-plasticized thermoplastic resin present in hopper 35 or plasticizing cylinder 31 and screw 32.Type: ApplicationFiled: July 21, 2005Publication date: November 27, 2008Applicant: Ube Machinery Corporation, Ltd.Inventors: Akio Okamoto, Kazuaki Miyamoto
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Patent number: 7052634Abstract: A method for making a foam sheet having ventilation holes includes the steps of: (a) preparing first and second molds, each including lower and upper mold parts separably closed to each other so as to define first and second mold cavities for the first and second molds, respectively, and providing the second mold with a plurality of pins extending into the second mold cavity, the second mold cavity being larger than the first mold cavity; (b) placing a foamable blank into the first mold cavity; (c) foaming the blank in the first mold cavity; (d) placing the blank foamed in step (c) into the second mold cavity, and piercing the blank through the use of the pins; and (e) foaming the blank to form a foam product within the second mold cavity while being pierced by the pins.Type: GrantFiled: January 5, 2004Date of Patent: May 30, 2006Inventor: Kun-Chung Liu
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Publication number: 20040235973Abstract: The invention relates to an improved method for producing foamed material, especially poly(meth)acrylimide foams, which are foamed from polymer plates produced according to the casting method. The two-step method consists of a pre-heating step and at least one foaming step. The product obtained has a significantly smaller compressive strain, measured according to DIN 53425(ASMD 621), than prior art products.Type: ApplicationFiled: March 1, 2004Publication date: November 25, 2004Inventors: Peter Stein, Hermann Seibert, Leonard Maier, Rainer Zimmermann, Wilfried Heberer, Werner Geyer
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Publication number: 20040132848Abstract: Disclosed is a closed-cell polyisocyanurate foam composition capable of high compressive strength at temperatures up to 200° C. The new composition further exhibits no loss or degradation in conventional mechanical properties—less than that which impacts the intended use. The formulation of the present invention is based on the reaction product of a isocyanate and an epoxide resin catalyzed by a mixture of a tertiary amine and a cyclic amine. Compressive strength is augmented by incorporating a large fraction of a non-reactive bulk filler into the precursor polymer gel.Type: ApplicationFiled: August 28, 2003Publication date: July 8, 2004Inventors: LeRoy L. Whinnery, Steven H. Goods, Craig C. Henderson, Thomas E. Bennett
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Patent number: 6634624Abstract: A device for multifoaming expandable plastics, such as, for instance, EPS, EPE, EPP or polymer mixtures, includes at least one storage or supply assembly and a foaming vessel for the discontinuous or batchwise afterfoaming of the prefoamed expandable plastics, whereby precisely adjustable bulk densities are attainable in an afterfoaming procedure while observing tight environmental conditions.Type: GrantFiled: January 15, 2002Date of Patent: October 21, 2003Assignee: Hirsch Maschinenbau GmbH & Co. KG.Inventor: Hans Reiner Stampfer
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Publication number: 20030042644Abstract: An extruded, polystyrene-based resin foam plate produced by extruding a foamable molten composition containing a polystyrene-based resin and a blowing agent consisting of (a) isobutane and (b) a blowing agent component other than isobutane, chlorofluorocarbons and fluorocarbons from a high pressure zone into a lower pressure zone. The extruded foam plate has a thickness of at least 10 mm and an apparent density of 25-60 kg/m3 contains residual isobutane in an amount of 0.45-0.80 mol per 1 kg thereof, has cells having an average diameter in the thickness direction thereof of 0.05-0.18 mm and a cell strain rate of 0.7-1.2, wherein the cell strain rate is obtained by dividing the average diameter in the thickness direction of the extruded foam plate by the average diameter in the horizontal direction of the extruded foam plate, meets the flammability standard on extruded polystyrene foam insulation plates as defined in JIS A9511-1995, and has a thermal conductivity of not greater than 0.028 W/m·K.Type: ApplicationFiled: June 14, 2002Publication date: March 6, 2003Applicant: JSP CORPORATIONInventors: Hiroyuki Gokuraku, Naochika Kogure, Seiji Takahashi, Daisuke Imanari, Masato Naito
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Patent number: 6527993Abstract: The present invention provides a process for producing a molded foam article of a crystalline aromatic polyester resin. The process is characterized by heating the surface temperature of a mold for cavity-molding to the temperature within a range of from (td+35) to (Tg+57)°C. (Tg is a glass transition temperature of the crystalline aromatic polyester resin prepuffs), thereby to mold prepuffs, and cooling the surface of the mold to a temperature not lowered than Tg for at least 20 seconds.Type: GrantFiled: June 7, 2001Date of Patent: March 4, 2003Assignee: Sekisui Plastics Co., Ltd.Inventors: Takaaki Hirai, Minoru Fujishima, Hiroyuki Ueno, Hideyasu Matsumura, Ikuo Morioka, Yukio Aramomi, Hiroyuki Yamagata
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Patent number: 6524519Abstract: A molding method and a mold therefor capable of forming a doll head of a shape exactly conforming to a mold by blow molding using a safe molding material. A split mold (2, 3) which has an inner surface formed to have a configuration conforming to a shape of a doll head (17) is so arranged that a parting line (18) formed by mold members (2, 3) of the split mold may be formed on a hairline of the hair of the doll head (17) or in proximity thereto. A molding material is constituted by a thermoplastic synthetic resin elastomer as a main ingredient thereof and has a plasticizer and a coloring agent added thereto. The molding material is heated and then dropped in as a parison (15) between the mold members (2, 3) of the split mold spaced from each other. Then, the mold members (2, 3) of the split mold are joined together and air is blown into the split mold. Air is removed through at least one projection such as a nose (5) or the like from a cavity during blowing of air into the split mold (2, 3).Type: GrantFiled: July 20, 2000Date of Patent: February 25, 2003Assignee: Takara Co., Ltd.Inventors: Kazuo Ohba, Takahiro Ueno
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Publication number: 20030017325Abstract: A process for producing a foamed article of a thermoplastic resin composition having a relatively thicker solid skin layer exhibiting better appearance without occurrence of swirl mark and having a foam structure of relatively uniform foam cell size with better foam cell configuration, which is light-weighing and superior in the stiffness, in an easy and efficient manner, by causing the said resin composition to foam up in a cavity of a mold, which process comprisesType: ApplicationFiled: November 20, 2001Publication date: January 23, 2003Applicant: GRAND POLYMER CO., LTD.Inventors: Hideo Akimoto, Mitsuru Watari, Takashi Miyazaki, Tatsuji Kawamura
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Publication number: 20020070472Abstract: The present invention relates to a method of injection moulding an ornamental product of thermoplastic material the improvement comprising adding a foaming agent to the thermoplastic material, differentially cooling the product inside the mould whereby the parts to be expanded are cooled sufficiently to form a skin, but where said parts have a temperature remaining high enough to permit foaming expansion outside the mould while the balance of the product is cooled below the solidification temperature of the polymer.Type: ApplicationFiled: December 13, 2000Publication date: June 13, 2002Inventor: Donald Shaw
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Patent number: 6369120Abstract: An acoustical insulation foam having, either with or without elastification, an Asker C hardness of less than about 65, a density of about 5 to about 150 kg/m3, a cell size of about 0.05 to about 15 mm, an open cell content of 0 to about 100 volume percent, a thickness of about 1 to about 200 mm, and a width of about 100 to about 3000 mm; comprising; (A) one or more alkenyl aromatic polymers, (B) one or more substantially random interpolymers and (C) optionally, one or more nucleating agents and (D) optionally, one or more other additives; and (E) one or more blowing agents.Type: GrantFiled: October 12, 2000Date of Patent: April 9, 2002Assignee: The Dow Chemical CompanyInventors: Bharat I. Chaudhary, Russell P. Barry, Chung P. Park, Martin Reimers
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Patent number: 6348167Abstract: A method for making a surfboard includes six steps of processes. The first step is to prepare and cut plastic plate material into a panel. The second step is to place it in a mold to hotly press to let the panel foam half. The third step is to take the half-foamed prototype out of the mold to let it continue to foam to expand. The fourth step is to place the fully foamed prototype in a baking device to heat it into an almost completed surfboard. The fifth step is to place it in a cooling mold to cool and harden to become a finished surfboard. The sixth step is to take the finished surfboard out of the cooling mold. Thus the method can shorten the time for making a surfboard and save material waste.Type: GrantFiled: June 12, 2000Date of Patent: February 19, 2002Assignee: Sun Own Industrial Co., Ltd.Inventor: Ching-Hsi Chen
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Patent number: 6348511Abstract: A process for multifoaming expendable plastics, such as, for instance, EPS, EPE, EPP or polymer mixtures, wherein prefoaming is effected in a first step and after foaming of already prefoamed material is effected in at least one further step. The process also provides that discontinuous or batchwise foaming is carried out as final afterfoaming.Type: GrantFiled: September 8, 1999Date of Patent: February 19, 2002Assignee: Hirach Maschinenbau GmbH & Co. KG.Inventor: Hans Reiner Stampfer
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Patent number: 6346207Abstract: A process for preparing EVA foam includes the steps of placing an amount of a kneaded composition in a mold such that the volume ratio of the kneaded composition to the mold cavity is about 0.15 to 0.5 and such that the kneaded composition is laid on the lower mold half, heating upper and lower mold halves of the mold in a manner that the temperatures of the upper and lower mold halves are not less than a reaction temperature, at which foaming and curing of the kneaded composition take place, and raising the temperature of the upper mold half to be higher than that of the lower mold half when the kneaded composition expands to a volume such that the volume ratio of the kneaded composition to the mold cavity is about 0.9 to 0.95.Type: GrantFiled: July 23, 2001Date of Patent: February 12, 2002Inventor: Tao-Shan Liu
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Patent number: 6274069Abstract: A seat, which is covered with a surface material and has a multilayer with different hardness, the air permeability, a good feeling on the surface and such a hardness that a weight of a person can be supported, is provided. The seat (1) is covered with a surface material (2) having the air permeability and comprises a foamed body having an outline generally corresponding to an outline of the seat. The foamed body comprises a first foamed body (10) as a base of the foamed body and a second foamed body (6).Type: GrantFiled: December 16, 1998Date of Patent: August 14, 2001Assignee: Namba Press Works Co., Ltd.Inventors: Taro Ogawa, Yasumasa Senoo, Takeshi Watadani, Yasuyuki Toda
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Publication number: 20010003756Abstract: A flexible, low density thermoplastic foam and a method for lowering the density and increasing the flexibility of a thermoplastic foam having a melting temperature and being either amorphous with a softening temperature or semicrystalline with a glass transition temperature.Type: ApplicationFiled: January 12, 2001Publication date: June 14, 2001Applicant: Armacell Enterprice GMBHInventors: David W. Kreiser, Allan L. Dinkel, Juerg Patrik Weibel