Varistor Patents (Class 264/617)
  • Patent number: 8609017
    Abstract: Electronically tunable dielectric materials having favorable properties are disclosed. The electronically tunable materials include an electronically tunable dielectric phase such as barium strontium titanate in combination with at least two additional metal oxide phases. The additional metal oxide phases may include, for example, oxides of Mg, Si, Ca, Zr, Ti and Al. The electronically tunable materials may be provided in bulk, thin film and thick film forms for use in devices such as phased array antennas, tunable filters and the like. The materials are useful in many applications, including the area of radio frequency engineering and design.
    Type: Grant
    Filed: February 17, 2007
    Date of Patent: December 17, 2013
    Assignee: BlackBerry Limited
    Inventors: Louise C. Sengupta, Xubai Zhang, Luna H. Chiu
  • Patent number: 8562899
    Abstract: Electronically tunable dielectric materials having favorable properties are disclosed. The electronically tunable materials include an electronically tunable dielectric phase such as barium strontium titanate in combination with at least two additional metal oxide phases. The additional metal oxide phases may include, for example, oxides of Mg, Si, Ca, Zr, Ti and Al. The electronically tunable materials may be provided in bulk, thin film and thick film forms for use in devices such as phased array antennas, tunable filters and the like. The materials are useful in many applications, including the area of radio frequency engineering and design.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: October 22, 2013
    Assignee: Blackberry Limited
    Inventors: Louise C. Sengupta, Xubai Zhang, Luna H. Chiu
  • Patent number: 8535575
    Abstract: A current-voltage non-linear resistor (10) comprises a sintered body (20) of a mixture whose chief constituent is zinc oxide and including as auxiliary constituents at least bismuth (Bi), antimony (Sb), manganese (Mn), cobalt (Co) and nickel (Ni). Also, the average grain size of the mixture is no more than 0.4 ?m; and the average grain size of the zinc oxide grains in the sintered body (20) is no more than 7.5 ?m and the standard deviation based on the grain size distribution of zinc oxide grains in the sintered body (20) is no more than 15% of the average grain size of the zinc oxide grains.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: September 17, 2013
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yasunori Kasuga, Hideyasu Ando
  • Publication number: 20110319255
    Abstract: A varistor ceramic includes the following materials: Zn as the main component, Pr in a proportion of 0.1 to 3 atom %, and a metal M selected from Y, Ho, Er, Yb and Lu in a proportion of 0.1 to 5 atom %.
    Type: Application
    Filed: February 1, 2010
    Publication date: December 29, 2011
    Applicant: EPCOS AG
    Inventor: Monika Piber
  • Publication number: 20110299213
    Abstract: A varistor ceramic includes Zn as the main component and Pr in a proportion of 0.1 to 3 atom %.
    Type: Application
    Filed: February 1, 2010
    Publication date: December 8, 2011
    Applicant: EPCOS AG
    Inventors: Monika Piber, Hermann Grünbichler
  • Publication number: 20100140563
    Abstract: A current-voltage non-linear resistor (10) comprises a sintered body (20) of a mixture whose chief constituent is zinc oxide and including as auxiliary constituents at least bismuth (Bi), antimony (Sb), manganese (Mn), cobalt (Co) and nickel (Ni). Also, the average grain size of the mixture is no more than 0.4 ?m, and the average grain size of the zinc oxide grains in the sintered body (20) is no more than 7.5 ?m and the standard deviation based on the grain size distribution of zinc oxide grains in the sintered body (20) is no more than 15% of the average grain size of the zinc oxide grains.
    Type: Application
    Filed: December 3, 2009
    Publication date: June 10, 2010
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Yasunori KASUGA, Hideyasu Ando
  • Patent number: 7341639
    Abstract: A method produces a component having a ceramic base body and contact surfaces on opposite sides of the ceramic base body. The method includes forming first protective layers on the opposite sides of the ceramic base body in regions not to be covered by the contact surfaces, forming second protective layers on opposite surfaces of the ceramic base body, sintering the ceramic base body with the first and second protective layers at a first temperature, forming the contact surfaces on the ceramic base body, and sintering the contact surfaces at a temperature that is lower than the first temperature.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: March 11, 2008
    Assignee: EPCOS AG
    Inventors: Günther Greier, Günter Engel, Renate Kofler, Axel Pecina, Robert Krumphals
  • Publication number: 20070273468
    Abstract: The present invention relates to a method for manufacturing a SrTiO3 series varistor using grain boundary segregation, and more particularly, to a method for manufacturing a SrTiO3 series varistor by sintering a powdered composition in which acceptors such as Al and Fe are added in powdered form and then sintered under a reducing atmosphere and heat-treated them in the air to selectively form electrical conduction barriers at grain boundaries in a process for manufacturing SrTiO3 series varistor having an excellent non-linear coefficient and a breakdown voltage suitable for use.
    Type: Application
    Filed: February 22, 2007
    Publication date: November 29, 2007
    Inventors: Suk-Joong Kang, Seong-Min Wang, Sung-Yoon Chung
  • Patent number: 7300620
    Abstract: The raw material for a ZnO—Pr-based varistor is mixed with cobalt and potassium to prepare a ceramic raw material powder. Potassium, which is an alkali metal, is added in the form of KClO4, KHC4H4O6, PtCl6, or K3[Co(NO2)6]. The ceramic raw material powder is pulverized by a wet process while 0.1 to 5.0 wt % of polycarboxylate dispersant is added to the powder. Such a method can produce a reliable, high-quality varistor having excellent varistor characteristics, such as varistor voltage V1mA and insulation resistance IR, and less variation in these characteristics.
    Type: Grant
    Filed: July 4, 2003
    Date of Patent: November 27, 2007
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Ryo Teraura
  • Patent number: 7189297
    Abstract: A method of manufacturing an Electro Static Discharge (ESD) protection componentin which slurry including varistor particles and a resin binder is produced, and a varistor green sheet is formed from this slurry. A conductor layer is formed on a surface of the varistor green sheet. A adhesive layer is formed on a baked ceramic substrate, the varistor green sheet is adhered to the adhesive layer and then baked. The method produces a high-performance and uniform ESD protection component.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: March 13, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Hidenori Katsumura, Tatsuya Inoue, Hiroshi Kagata
  • Patent number: 6878304
    Abstract: A highly accurate reduction resistant thermistor exhibiting stable resistance characteristics even under conditions where the inside of a metal case of a temperature sensor becomes a reducing atmosphere, wherein when producing the thermistor comprised of a mixed sintered body (M1 M2)O3.AOx, the mean particle size of the thermistor material containing the metal oxide, obtained by heat treating, mixing, and pulverizing the starting materials, is made smaller than 1.0 ?m and the sintered particle size of the mixed sintered body, obtained by shaping and firing this thermistor material, is made 3 ?m to 20 ?m so as to reduce the grain boundaries where migration of oxygen occurs, suppress migration of oxygen, and improve the reduction resistance.
    Type: Grant
    Filed: August 9, 2001
    Date of Patent: April 12, 2005
    Assignees: Nippon Soken Inc., Denso Corporation
    Inventors: Itsuhei Ogata, Daisuke Makino, Kaoru Kuzuoka, Atsushi Kurano
  • Publication number: 20040195734
    Abstract: The raw material for a ZnO—Pr-based varistor is mixed with cobalt and potassium to prepare a ceramic raw material powder. Potassium, which is an alkali metal, is added in the form of KClO4, KHC4H4O6, PtCl6, or K2[Co(NO2)4]. The ceramic raw material powder is pulverized by a wet process while 0.1 to 5.0 wt % of polycarboxylate dispersant is added to the powder. Such a method can produce a reliable, high-quality varistor having excellent varistor characteristics, such as varistor voltage V1 ma and insulation resistance IR, and less variation in these characteristics.
    Type: Application
    Filed: March 2, 2004
    Publication date: October 7, 2004
    Inventor: Ryo Teraura
  • Patent number: 6743381
    Abstract: A process for forming a thixotropic ink for use in manufacturing the ceramic of a zinc oxide varistor where the ceramic includes zinc, oxygen and a plurality of additive elements. The process includes the steps of calcining a mixture of powders of zinc oxide and the additive elements to form a calcined product having a particle size larger than the particle size of the zinc ozide powders, mixing said calcined product with an organic liquid, mechanically working the mixture to produce a calcined particulate material in the organic liquid having a particle size less than the particle size of said calcined product, adding an organic binder to the mixture and mixing the composition to produce said ink.
    Type: Grant
    Filed: September 4, 2001
    Date of Patent: June 1, 2004
    Assignee: Littlefuse, Inc.
    Inventors: Stephen P. Cowman, Derek A. Nicker, John M. Shreeve
  • Patent number: 6620346
    Abstract: The invention concerns novel varistors based on zinc oxide and a method for making same, which consists in using as base products nanocrystalline powders obtained by high-intensity mechanical grinding and in subjecting the mixture resulting from said nanocrystalline powders a consolidating treatment such as sintering, in suitably selected temperature and time conditions so as to retain the smallest possible grain size of ZnO. The resulting varistors have a very fine homogeneous microstructure and an average grain size characteristically not more than 3 mu m, i.e. five times smaller than standard materials. Said novel varistors have a larger number of grain boundaries per length unit and therefore a much higher breakdown voltage. Said voltage is characteristically higher than 10 kV/cm and can reach 17 kV/cm which is almost one order of magnitude above the breakdown voltage of standard varistors.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: September 16, 2003
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Sabin Boily, Alain Joly, André Van Neste, Houshang Alamdari
  • Patent number: 6599463
    Abstract: A process for producing a monolithic ceramic electronic component, which includes: providing a ceramic slurry, a conductive paste, and a ceramic paste; forming a plurality of composite structures each comprising a ceramic green sheet produced by shaping the ceramic slurry, internal circuit element films formed by applying the conductive paste partially onto a main surface of the ceramic green sheet so as to provide step-like sections, and a ceramic green layer which compensates for spaces defined by the step-like sections, the ceramic green layer being formed by applying the ceramic paste onto the region on the main surface of the sheet on which the element films are not formed, so as to substantially compensate for the spaces; forming a green laminate by laminating the composite structures; and firing the green laminate, wherein the ceramic paste contains ceramic powder, an organic solvent, and an organic binder.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: July 29, 2003
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Makoto Miyazaki, Satoru Tanaka, Koji Kimura, Koji Kato, Koji Suzuki
  • Patent number: 6183685
    Abstract: Apparatus for producing multilayer varistors using ceramic ink and electrode ink consists of a succession of stations, in which alternating layers of ceramic ink and electrode ink are laid down on a substrate. The stations may be printing stations in which either a ceramic ink screen or an electrode ink screen is used to apply the appropriate ink to the substrate. In a first printing step, a layer of ceramic ink is laid down, within a region determined by a mask area of a ceramic ink screen. In the following step, electrode ink is laid down in regions determined by mask areas of the electrode ink screen. The apparatus includes transfer mechanisms for advancing substrates from station to station for successive printing operations, and control mechanisms for regulating and coordinating the successive printing operations and substrate travel.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 6, 2001
    Assignee: LittleFuse Inc.
    Inventors: Stephen P. Cowman, Alan J. Ratcliffe, Derek A. Nicker, John M. Shreeve, Anthony L. Oliver
  • Patent number: 6146581
    Abstract: A method of manufacturing a ceramic component including at least one cermet body, especially a cermet electrode, in which the costs are reduced and the ceramic component can be produced in accordance with requirements with an integrated cermet body in a reproducible manner. The cermet body initially is produced as a green compact; the cermet body then is inserted into the ceramic composition; the ceramic composition subsequently is consolidated together with the green compact cermet body, e.g. by pressing, and the resulting assembly is finally sintered.
    Type: Grant
    Filed: August 23, 1999
    Date of Patent: November 14, 2000
    Assignees: Friatec Aktiengesellschaft, Krohne Messtechnik GmbH & Co. KG
    Inventors: Guenther Bitz, Helmut Mayer, Hans-Joachim Graf
  • Patent number: 6143207
    Abstract: Provided are wide-range thermistor materials with high responsibility, which have linear resistance temperature characteristics and a large rate of temperature-dependent resistance change in wide temperature range of from lower than room temperature to higher than 1000.degree. C. The thermistor material comprises an electrically-insulating ceramic matrix and second phase grains as discontinuously dispersed in the matrix, in which the second phase grains are of a semiconductive or conductive substance having a large rate of temperature-dependent resistance chance. The material may optionally contain a resistance-controlling additive of one or more of nitrides, borides, silicides, sulfides, oxides and carbide of elements, third phase grains with internal stress-relaxing ability having a lower modulus of elasticity than the matrix and the second phase grains, and a resistance stabilizer of TiO.sub.2 and/or Ti.sub.n O.sub.2n-1 (n=4 to 9).
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: November 7, 2000
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Katsunori Yamada, Mitsuru Asai, Nobuo Kamiya, Yuko Matsubara
  • Patent number: 5807510
    Abstract: A composition for electric material containing as a primary component zinc oxide. The composition further contains at least one of rare-earth elements in a range of 0.01 mol % to 3.0 mol % in terms of oxide thereof given by R.sub.2 O.sub.3 where R represents generally the rare-earth elements, and aluminum in a range of 0.0005 mol % to 0.005 mol % in terms of aluminum oxide given by Al.sub.2 O.sub.3. The composition is suited for manufacturing a resistance element whose varistor voltage can be increased over a whole current range without being accompanied with any appreciable degradation in flatness ratio of a voltage-versus-current characteristic.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: September 15, 1998
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Naomi Furuse, Masahiro Kobayashi, Toshihiro Suzuki, Junichi Shimizu, Yoshio Takada, Hiroshi Nakajoh, Kei-Ichiro Kobayashi, Tomoaki Kato
  • Patent number: 5759480
    Abstract: Components whose palladium metal-containing constituent is not subject to delamination and which exhibit very good dielectric properties are obtained by means of a method of manufacturing a ceramic electronic component. The ceramic electronic component is essentially composed of a dielectric oxide ceramic and at least one palladium-containing component, and is obtained by firing and sintering of a green body containing an organic binder with the firing process including a first step in which the binder is removed from the binder-containing green body by means of a water-gas reaction in a water vapor-containing, essentially oxygen-free, atmosphere at temperatures between 20.degree. and 880 .degree. C., and a second step in which the dielectric oxide ceramic is re-oxidized in an atmosphere having an oxygen content of 10 to 100% by volume at a temperature in the range from 880 .degree. C. to 900 .degree. C.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: June 2, 1998
    Assignee: U.S. Philips Corporation
    Inventors: Detlev Hennings, Herbert Schreinemacher
  • Patent number: 5753176
    Abstract: A process for producing a voltage-dependent nonlinear resistor that contains zinc oxide as a major component and that also contains a minor oxide component, is improved by the steps of adding an organometallic compound as the minor oxide component to the powder of zinc oxide, mixing the two components, forming the mixture into a shape and sintering the shape. The organometallic compound as the minor oxide component is either a compound in which a hydrocarbon group is bound to a metal atom or a compound in which the hydrogen atom in a carboxyl, hydroxyl, imino group, etc., is replaced by a metal. The method is capable of reducing the scattering of the electrical characteristics of the voltage-dependent nonlinear resistor, which contributes to an improvement of the change of varistor voltage by surge current.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: May 19, 1998
    Assignee: Murata Manufacturing Co. Ltd.
    Inventors: Tomoaki Ushiro, Hiroshi Komatsu, Tooru Tominaga, Hiroyuki Kubota, Kazutaka Nakamura, Masahiro Yuruki
  • Patent number: 5739742
    Abstract: A zinc oxide ceramic and a method for producing the zinc oxide ceramics are provided wherein a zinc oxide varistor for a high voltage which has excellent electric characteristics and great reliability for DC loading and surge can be produced in high yield by performing sintering at a temperature of 750.degree. to 1050.degree. C. At least one of B.sub.2 O.sub.3, Cr.sub.2 O.sub.3, GeO.sub.2, LaO.sub.3, MgO, Nb.sub.2 O.sub.5, Nd.sub.2 O.sub.3, PbO, PrO, Sb.sub.2 O.sub.3, SiO.sub.2, SnO.sub.2, Ta.sub.2 O.sub.5, WO.sub.3 and Y.sub.2 O.sub.3 powders and a Bi.sub.2 O.sub.3 powder are mixed. A mixture thus obtained is heat treated at a temperature of 400.degree. to 700.degree. C. and ground to prepare a synthetic powder. 0.5 to 20 parts by weight of the synthetic powder and 0.1 to 5.0 parts by weight of at least one of CoO, MnO.sub.2 and NiO powders are added and ground for 100 parts by weight of a zinc oxide powder. A binder is added to the ground powder to form a sheet.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: April 14, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Atsushi Iga, Masahiro Ito, Masakazu Tanahashi
  • Patent number: 5707583
    Abstract: In preparing a zinc oxide base varistor in the form of a sintered body which itself has a voltage-dependent nonlinear resistance, firing is done in an atmosphere containing at least 60% of oxygen at or above the temperature at which additives form a liquid phase, and thereafter the sintered body is heat treated in an atmosphere containing at least 10% of oxygen at a temperature of 600.degree. to 1,000.degree. C. There is obtained a zinc oxide base varistor having a high energy handling capability, a high nonlinearity index .alpha., and satisfactory load life characteristics such as a humid load life.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: January 13, 1998
    Assignee: TDK Corporation
    Inventor: Masatada Yodogawa
  • Patent number: 5640136
    Abstract: The invention provides a voltage-dependent nonlinear resistor porcelain in the form of a ZnO system sintered body comprising zinc oxide as a major component and at least one of rare earth element oxides, cobalt oxide, chromium oxide, at least one of Group IIIb element oxides, at least one of Group Ia element oxides, 0.01 to 2 atom % calculated as Ca of calcium oxide, and 0.001 to 0.5 atom % calculated as Si of silicon oxide as subordinate components, the atomic ratio of calcium to silicon (Ca/Si) ranging from 0.2 to 20. With the atomic ratio of calcium to silicon (Ca/Si) set between 0.2 and 20, preferably between 2 and 6, the element has a significantly increased load life at high temperature and humidity. The element experiences less deterioration of the asymmetry of its volt-ampere characteristic between different directions of DC conduction. If magnesium oxide is added to the composition in an amount of 0.
    Type: Grant
    Filed: June 9, 1994
    Date of Patent: June 17, 1997
    Assignee: TDK Corporation
    Inventors: Masatada Yodogawa, Toshiyuki Yamazaki, Hitomi Naitou, Masahito Furukawa, Dai Matsuoka