Abstract: A process for producing fibers of refractory material. In one embodiment, a dispersion of particles of refractory material is prepared first. The dispersion then is mixed with a carrier solution of a salt of cellulose xanthate to form a spin mix. Using general wet spinning techniques, a filament of regenerated cellulose is formed from the spin mix. The filament has the particles dispersed therein. At this point, the filament can be utilized as a mixture of cellulose and refractory material, or it can be heat treated. If heated, the filament is raised to sufficient temperatures and over sufficient durations to remove substantially all of the regenerated cellulose and to sinter the particles of refractory material to form a filament.
Type:
Grant
Filed:
August 30, 1996
Date of Patent:
October 27, 1998
Inventors:
Richard B. Cass, Roland R. Loh, Thomas C. Allen
Abstract: To provide an oil supplying means for an oil coating roller, by which oil can be supplied stably for a long time while preventing offset, a cylindrical non-sintered molded body which is a mixture of ceramic fiber and clay is used as an oil holding member in an oil coating roller.
Abstract: A method of preparing polymer derived silicon fibers comprising the steps of providing a spin dope solution comprising a silicon carbide forming organosilicon polymer, preferably polycarbosilane, a solvent, a soluble boron precursor, preferably solid boron hydride, and a nitrogen containing precursor, preferably polyvinylsilazane; spinning the solution to form high strength green fibers; and heat treating the green fibers to produce high strength, homogeneously doped, boron containing fibers. The fibers produced are high strength, homogeneously boron doped silicon carbide fibers with average tensile strength in the range of from about 2.0 to 4.0 GPa at room temperature.
Type:
Grant
Filed:
July 18, 1996
Date of Patent:
August 11, 1998
Assignee:
University of Florida
Inventors:
Michael D. Sacks, William Toreki, Christopher D. Batich, Guang J. Choi
Abstract: A ceramic fiber is made by spinning a plurality of polymeric materials each including at least one ceramic precursor into a composite fiber, and then pyrolysing the composite fiber to form a composite ceramic fiber of non-homogeneous composition. A preferred ceramic material for use in this method is made by pyrolysing an organo-metallic compound dispersed in an organic polymer carrier. The principal products are tailored matrix-compatible ceramic fibers for reinforcements, and have a core-sheath structure made by coaxial spinning methods. A core of desired mechanical properties, such as silicon carbide, is given a chemically appropriate surface layer. Transition metals compounds are preferred, in a range of organo-metallic ceramic precursors that include carborane derivatives. Allowed additives include metal-silicon compounds, other ceramics, corresponding metal oxides and elementary metals.
Abstract: A method for forming parts from inorganic particulate materials is diclosed. The method utilizes a two-component binder composition which is removable at a faster rate than conventional binder compositions, thereby reducing the formation of voids and cracks that occur during binder removal. No toxic materials are required and the method does not rely on solvents. The method may be used with ceramics, metals, and cermets.
Type:
Grant
Filed:
September 9, 1996
Date of Patent:
March 3, 1998
Assignee:
Rohm and Haas Company
Inventors:
Leonard Edward Bogan, Jr., Richard Anthony Einhorn
Abstract: A method for the preparation of a fibrous monolithic ceramic which exhibits non-brittle fracture characteristics from green monofilament ceramic fibers having a controlled texture. This method includes the steps of: (a) forming a first ceramic-laden composition includes a thermoplastic polymer and at least about 40 vol. % of a ceramic particulate into a substantially cylindrical core, (b) applying a layer of a second ceramic-laden composition includes a thermoplastic polymer and at least about 40 vol.
Type:
Grant
Filed:
September 21, 1994
Date of Patent:
July 8, 1997
Assignee:
The Regents of the University of Michigan
Inventors:
Dragan Popovic', John W. Halloran, Gregory E. Hilmas, Guy Allen Brady, Scott Somers, Andrew Barda, Gregory Zywicki