Abstract: A method for determining skin factor of a subsurface rock formation from within a wellbore drilled therethrough includes measuring a nuclear magnetic resonance property of the formation at a plurality of lateral depths therein. The measured nuclear magnetic resonance property is used to estimate the skin factor.

Abstract: Methods and related systems are described for extracting information about a system of nuclear spins including: performing a plurality of Nuclear Magnetic Resonance (NMR) measurements on the system of nuclear spins; acquiring NMR data from each of the plurality of NMR measurements; performing data inversion using an random-sampler to generate an ensemble of spectra so as to extract information about the system of nuclear spins; and analyzing the performed random-sampler inversion results to extract information about the system of nuclear spins.

Abstract: A method for measuring the conducting fluid saturation and the resistivity of a porous medium have application to development of underground geological formations. A solid sample is extracted from the medium and placed in a centrifugation cell, beside a second sample for limiting the capillary end effect in the first sample. The two samples are partly desaturated by subjecting them to centrifugation. The resistivity of the sample is measured by placing it in a radial-electrode resistivity measurement cell. The saturation of the sample is then determined by measuring its nuclear magnetization by means of an NMR device. Repeating this procedure for different centrifugation velocities provides resistivity and saturation pairs allowing a relationship between saturation and resistivity to be estimated.

Abstract: A displaced electrode amplifier (“DEA”) for measuring signals from high impedance sources. The amplifier may include an operational amplifier (“op-amp”) configured as a unity gain buffer, with a feedback path to the non-inverting input to at least partly compensate for a parasitic input shunt impedance. In cases where the device is to measure AC signals in high ambient temperatures, the non-inverting input may be coupled via a large resistance to a ground reference that is driven with a second feedback signal to magnify the effective value of the large resistance. Where a differential configuration is desired, one or more tuning resistors may be provided to match responses of different input buffer stages, thereby maximizing the common mode rejection. The disclosed amplifier is suitable for use in oil-based mud resistivity imaging tools but is also suitable for other applications.

Abstract: A method of measuring a parameter characteristic of a rock formation is provided, the method including the steps of deploying in a section of a well penetrating the rock formation a toolstring combining a tool for generating and measuring responses to a sensing field at different radial depth shells in the rock formation relative to the well and a tool to cause a flow of fluid through the different radial depth shells such that responses to the sensing field are obtained for at least two different radial depth shells and for at least two different flow conditions in said at least two different radial depth shells to determine a radial depth dependent profile of said parameter.

Abstract: NMR spin echo signals are acquired downhole. Principal Component Analysis is used to represent the signals by a weighted combination of the principal components and these weights are telemetered to the surface. At the surface, the NMR spin echo signals are recovered and inverted to give formation properties.

Abstract: A method for determining oil viscosity and continuous gas-oil-ratio (GOR) from nuclear magnetic resonance logs (NMR). The method includes obtaining a set of NMR data of a portion of the subterranean formation from inside the wellbore without acquiring formation fluid sample; isolating a quantitative reservoir fluid information associated with oil from oil based mud (OBM) using radial profiling of the set of NMR data, wherein the OBM is used for extracting fluid from the underground reservoir; determining GOR related information associated with the portion of the subterranean formation from the quantitative reservoir fluid information associated with oil, wherein the GOR related information is determined based on a predetermined model; and performing operations for the oilfield based on the GOR related information.

Abstract: A method for estimating a distribution of pore sizes of a fluid filled rock formation penetrated by a borehole, the method including: processing nuclear magnetic resonance (NMR) data to determine a distribution of diffusion coefficients and a distribution of relaxation time constants for at least one depth in the borehole; plotting the distribution of diffusion coefficients and the distribution of relaxation time constants as a cross-plot for the at least one depth; identifying a water line on the cross-plot, each point on the water line having substantially the same value for the diffusion coefficient; and estimating the distribution of pore sizes from the distribution of relaxation time constants plotted along the water line.

Abstract: In general, in one aspect, the invention relates to a method for evaluating a volcanic reservoir formation having volcanic rock forming elements and a borehole penetrating the volcanic reservoir formation. The method includes controlling chlorine concentration in an environment of the borehole and a tool operation to enable neutron capture spectroscopy measurements of the volcanic rock forming elements, obtaining neutron capture spectroscopy data relating to the volcanic rock forming elements from borehole logging tools, determining a lithology of the volcanic reservoir formation based on at least the neutron capture spectroscopy data, and generating an evaluation of the volcanic reservoir formation based on at least the lithology.

Abstract: A downhole micro MR analyzer for use in a wellbore, having a micro sample tube, a micro RF coil in close proximity to the micro sample tube, and one or more magnets disposed about the micro sample tube is disclosed. The micro MR analyzer can be used for nuclear magnetic resonance or electron spin resonance experiments to ascertain formation properties and chemical compositions.

Abstract: A method for selecting a location of a wellbore includes: using a nuclear magnetic resonance (NMR) instrument deployed on a surface of a production area, determining a location of ground water in the production area; and locating the wellbore according to the location of the ground water. A system and a computer program product are disclosed as well as a method for performing steam assisted gravity recovery.

Abstract: A first NMR echo train is acquired with a single TE. A second NMR echo train is acquired with a first portion having the same TE and the second portion having a longer TE. When measurements are made with a low magnetic field gradient, processing the two echo trains can be used to determine gas in the formation.

Abstract: A method for estimating fluid saturation in a formation penetrated by a wellbore from nuclear magnetic resonance measurements made at a plurality of lateral depths into the formation from the wellbore includes estimating a bound water volume, a total porosity and a free water volume at each of the lateral depths from the nuclear magnetic resonance measurements. A minimum water saturation is estimated at each lateral depth from the total porosity, the free water volume and the bound water volume at each lateral depth. A value of water saturation is estimated at each lateral depth from the minimum water saturation at each lateral depth. A relationship between lateral depth and water saturation is determined. Water saturation is estimated at a selected lateral depth greater than the greatest lateral depth of the nuclear magnetic resonance measurements.

Abstract: A method for estimating a property of a material, the method including: acquiring data using nuclear magnetic resonance (NMR) measurements, the measurements performed by varying at least one of a magnetic field gradient (G) and an inter-echo time (TE); organizing the data according to at least one of magnetic field gradients (G) and inter-echo times (TE) used in the NMR measurements; calculating a shift of apparent transverse relaxation time (T2,app) and (longitudinal relaxation time T1)/(apparent transverse relaxation time T2,app) due to a variation of the product of G and TE; constructing a mathematical model of the NMR measurements from the shifts; and inverting the mathematical model to estimate the property.

Abstract: A method for estimating a viscosity of a fluid in a rock formation, the method including: performing a first nuclear magnetic resonance (NMR) measurement with zero magnetic field gradient on at least a portion of a sample of the rock formation to obtain a first distribution of transverse relaxation time constants; estimating a first diffusive couple factor from the first distribution; replacing the fluid of the at least a portion of the sample with another fluid; performing a second NMR measurement with zero magnetic field gradient on the at least a portion of the sample containing the another fluid to obtain a second distribution of transverse relaxation time constants; estimating a second diffusive couple factor from the second distribution; and estimating the viscosity of the fluid using the first diffusive couple factor and the second diffusive couple factor.

Abstract: Pulse sequences are applied to a fluid in an earth formation in a static magnetic field and NMR spin echo signals are obtained. The signals are inverted to give T2 distributions at a plurality of depths. Similarities between logs of the T2 bins with resistivity and/or gamma ray logs are used to identify and subtract contributions to the NMR signal from oil. having internal gradients. From the received signals, relaxation and diffusion characteristics of the fluid are determined. The determination takes into account the internal field gradients. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

Abstract: Single-shot methods suitable for determining capillary pressure and relative permeability curves in petroleum reservoir core plugs are proposed. Three classes of measurement are outlined. (i) Measurements undertaken with steady state gas flow and stationary water or oil phases in the rock. SPRITE (Single-Point Ramped Imaging with T1 Enhancement) MRI (Magnetic Resonance Imaging) spin density images map spatially varying fluid content. (ii) Similar measurements are proposed with a stationary gas phase and flowing water or oil phases. (iii) Measurements are also possible with either water or oil as the stationary phase, with the other phase undergoing steady state flow. In all cases the outflow boundary condition is maintained, capillary pressure zero, by washing the outlet face of the sample with the stationary fluid phase.

Abstract: A method to obtain a free induction decay signal using includes inducing a static magnetic field in a sample volume. A radio frequency (RF) magnetic field is then induced in the sample volume. The RF magnetic field has parameters selected to minimize the contribution of inhomogeneity in the static magnetic field to a free induction decay time. The free induction decay signal is then detected from the sample volume. In one example, prior to inducing the RF magnetic field, a reorienting radio frequency magnetic field is induced in the sample volume to reorient magnetic spins by a first selected angle. The inducing the RF magnetic field in this example has parameters selected to reorient spins by a second angle. The inducing the RF magnetic field and detecting the free induction decay signal are repeated until nuclear magnetic equilibrium is substantially attained.

Abstract: A method for analytically separating properties of hydrocarbon materials from other materials in a downhole environment, the method including: performing nuclear magnetic resonance (NMR) measurements downhole; determining a signal for sodium-23 (23Na) from the NMR measurements; and associating the 23Na signal with the other materials. A computer program product, an apparatus and additional methods are provided.

Abstract: NMR spin echo signals are acquired downhole. Principal Component Analysis is used to represent the signals by a weighted combination of the principal components and these weights are telemetered to the surface. At the surface, the NMR spin echo signals are recovered and inverted to give formation properties.

Abstract: The use of time-lapsed NMR diffusivity measurements in an observation well is disclosed. The observation well is cased in the zone of interest with non-magnetic and non-conductive casing that is invisible to the NMR tool. Second, because NMR measurements have a dead zone in front of the antenna depending on the spatial variation of the fixed magnet strength, for example about 2.7 inches, a distance between the casing and the formation is reduced to less than the dead zone length by drilling the observation well at small deviation of about 5° and running the casing without centralizers. Both the casing and the pad-type NMR tool will follow the low side of the borehole, ensuring the measurement volume of the NMR tool is inside the formation and beyond the annulus.

Abstract: An apparatus and method for estimating a property of a species of the hydrocarbon in a downhole fluid are provided. In one aspect, the method may include: imparting a magnetic field on the fluid to align nuclei of the fluid with a direction of the primary magnetic field; imparting a perturbing radio frequency signal on the fluid to excite the nuclei of the fluid; detecting a radio frequency signal emitted by the excited nuclei of the fluid; estimating a frequency shift between the perturbing radio frequency and the detected radio frequency; and estimating using the frequency shift a property of one or more species of the hydrocarbons in the fluid.

Abstract: The invention relates to a method and a device for examining molecules by means of NMR spectroscopy. It is the object of the invention to be able to characterize a sample with a high resolution and comprehensively. The object is solved by a method and an associated device for examining a sample by means of nuclear magnetic spectroscopy by measuring heteronuclear and homonuclear J-couplings in a small magnetic field and by using the measured heteronuclear and homonuclear J-couplings for characterizing the sample.

Abstract: A method to determine one or more properties of a substance in a downhole region of investigation is disclosed. The method includes obtaining NMR measurements from the region of investigation, obtaining at least one additional well log measurement from the region of investigation, expressing the NMR measurements in terms of NMR subcomponents, expressing the additional well log measurement in terms of well log subcomponents, and simultaneously inverting the expressed NMR measurements and the expressed additional well log measurement for the NMR subcomponents to yield one or more properties of a substance.

Abstract: The present invention pertains to an apparatus and method for conducting magnetic resonance measurements on fluids at high pressures and/or high temperatures. The apparatus can be used in conjunction with or as part of a downhole fluid sampling tool to perform NMR measurements on fluids withdrawn from petroleum reservoirs, or can also be used for laboratory measurements on live reservoir fluids. The apparatus can perform all of the measurements made by modern NMR logging tools, including multi-dimensional distribution functions of spin-spin (T2) and spin-lattice relaxation (T1) times and molecular diffusion coefficients. The spin densities of hydrogen and other NMR sensitive species can be computed from the distribution functions. The apparatus can also be used to predict the apparent conductivity of the fluids in the flowline from measurements of the quality factor (“Q”) of the NMR circuit. The apparent conductivity can be used to predict water cut or water salinity.

Abstract: A logging instrument for estimating a property of a formation penetrated by a borehole, the instrument having a magnet disposed at least one of at and in the instrument wherein the magnet exhibits a magnetic field of “substantially” constant magnitude over a range of temperatures in the borehole.

Abstract: Measurements of fluorescence spectra of fluid samples recovered downhole are processed to give the fluid composition. The processing may include a principal component analysis followed by a clustering method or a neutral network. Alternatively the processing may include a partial least squares regression. The latter can give the analysis of a mixture of three or more fluids.

Abstract: An apparatus and methods that can be used to determine various qualitative parameters of an earth formation from nuclear magnetic resonance (NMR) measurements. One embodiment provides a method of NMR-based remote sensing in which a nuclear spins in fluid of interest are encoded while inside an earth formation and then withdrawn into a tool module and analyzed by a sensor located in the tool module. Separate encoding and detection systems may be used, allowing each system to be independently optimized. In particular, because detection of the encoded spins may occur while the spins are inside the detector system, rather than within the earth formation (where they are encoded), the detector system may be constructed to employ a highly uniform magnetic field. This may facilitate various NMR measurements.

Abstract: A system and method for measuring fluid flow in a wellbore in an earth formation using time-of-flight (TOF) sensing and remote detection nuclear magnetic resonance (NMR) techniques, by applying a magnetic field to the formation to polarize spins present in a portion of the formation, providing an encoding shell in the formation, selecting an encoding volume from the encoding shell, applying an encoding signal to excite the spins in the encoding volume, introducing a time delay to the encoding signal, providing a detection shell in the formation, applying a detection signal to the detection shell, detecting an NMR signal generated by the migration of spins from the encoding shell to the detection shell, and collecting TOF data corresponding to time elapsed from when a spin is encoded to when the spin reaches the detection shell.

Abstract: A method for estimating a property downhole is provided, which, in one aspect, may include receiving a core at a receiving end of a downhole tool while removing a portion of the received core distal from the receiving end of the tool, obtaining measurements by a sensor downhole, and processing the measurements to estimate the property of interest.

Abstract: A magnet assembly for measuring properties of a formation from a borehole, the magnet assembly including a first device and a second device, each device adapted for insertion into the borehole, the first device producing a first magnetic field, the second device producing a second magnetic field; wherein the second magnetic field is configurable for one of reinforcing and reducing the first magnetic field; and wherein the first device comprises a permanent magnet and the second device comprises at least one of one of a switchable magnet and switching windings.

Abstract: Methods and apparatus for the characterization of formation fluids are disclosed. A downhole tool disposed in a borehole penetrating a subterranean formation obtains a NMR measurement, effects a change in a characteristic of the formation fluid, and obtains another NMR measurement subsequent to the change. Alternatively, the downhole tool effects a radial gradient of a characteristic of the formation and obtains NMR measurements at two or more selected radial distances from the wellbore wall. A parameter representative of the subterranean formation or the formation fluid is further determined from the NMR measurements.

Abstract: A method for determining viscosity, ?, of a fluid downhole, calls for performing a nuclear magnetic resonance (NMR) survey of the fluid; determining a longitudinal relaxation time, T1, and an apparent transverse relaxation time, T2app, for the fluid; forming a ratio R of T1/T2app for the fluid; and determining the viscosity, ?, according to the ratio, R. A computer program product for implementing the method is provided.

Abstract: For use in logging downhole in an earth borehole, a method for determining a characteristic of oil, includes: providing and determining the viscosity of a plurality of crude oil samples; performing test measurements, using a predetermined operating mode, on media including the crude oil samples to obtain test data; applying a test processing procedure to the test data to obtain an output test parameter relating to the test data and the predetermined operating mode; deriving, for the plurality of crude oil samples, a correlation relating the output test parameter to the viscosities of the crude oil samples; performing downhole measurements in the measurement region with a logging device, operated with substantially the predetermined operating mode, to obtain logging data, and applying a measurement processing procedure to the logging data to obtain an output logging parameter; and determining the oil characteristic using the output logging parameter and the correlation.

Abstract: Disclosed is a non-lineal statistical independent component (ICA) analysis methodology for calculating T2 or T1 distributions of nuclear magnetic resonance logs. In one aspect, the invention employs a classical blind source separation (BSS) approach with the input data (T2 or T1 distributions) being considered not only horizontally (in relaxation time units), but also vertically (in depth). The statistical variations are used for separating the principal independent components and their corresponding weighting matrix. The result of such ICA based BSS is an efficient separation of T2 components correlative to the presence of particular conditions (e.g., clay bound water, heavy oil, capillary bound water, free water, mud filtrate (water and oil), and noise). Individual saturation of estimated fluids can be calculated from the weighting matrix generated in accordance with the invention.

Abstract: An NMR logging tool for conducting NMR measurements in a plurality of sensitive volumes ranging up to a meter from the tool. The tool comprises a magnetic assembly using one or more permanent magnets and at least one pole piece for extending a magnet pole and shaping the magnetic field to simulate a magnetic monopole in a sensitive volume within the formation. Different embodiments of a segmented antenna enable directional NMR logging. The tool embodiments and methods of their use are suitable for wireline or LWD logging, and can be used for directional drilling.

Abstract: A method and a computer program product for estimating the true intrinsic relaxation time T2 and the internal gradient Gint for a multi-frequency nuclear magnetic resonance imaging tool for well logging includes providing at least two frequencies in a plurality of echo trains, evaluating the signal decay in each echo train, quantifying the signal decay and correlating the signal decay to the internal gradient.

Abstract: System and methods for using nuclear magnetic resonance (NMR) T1 measurements for wireline, LWD and MWD applications and down-hole NMR fluid analyzers. The T1 measurements are characterized by insensitivity to motion, as the detrimental effects arising from tool motion or fluid flow are effectively reduced or eliminated. T1 measurements alone or in combination with other standard oil field measurements are shown to provide efficient data acquisition resulting in compact and robust data sets, the potential for substantially increased logging speeds, and simple methods for fluid typing, including direct and robust identification of gas.

Abstract: The present invention is directed to a nuclear magnetic resonance apparatus and method for generating an axisymmetric magnetic field having long, straight contour lines in the resonance region. A magnetically permeable member is used to shape the static magnetic field generated by an array of permanent magnets. The magnetically permeable member minimizes variations of the static magnetic field in the formation due to vertical motion of the apparatus while obtaining a nuclear magnetic resonance measurement. Further, the magnetically permeable member may minimize variations of the static magnetic field in the formation due to lateral motion of the apparatus while obtaining a nuclear magnetic resonance measurement.

Abstract: When a static magnetic field and a crossed oscillating field are applied, the deformation rate at a boundary between a fluid and a porous medium depends on the amplitudes of the applied magnetic fields (to be exact, on their product), electric conductivity, porosity, and permeability. Knowing two of the three enables determination of the third. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.72(b).

Abstract: Saturation pulse sequences are designed to ensure complete saturation of nuclear spins for dual wait time measurements and saturation recovery measurements in the case of axial motion of a downhole NMR logging tool. Frequency and/ or phase modulation may be used. An auxiliary saturation coil may be used.

Abstract: A system for measuring at least one of a temperature and a pressure of an earth formation is disclosed. The system includes: a downhole tool disposed in a borehole and configured to be movable within the borehole; at least one nuclear quadrupole resonance (NQR) measurement device including a transmitter configured to emit a radiofrequency magnetic field having at least one selected frequency band into the earth formation to cause a component thereof to produce a NQR signal, and a detector configured to detect the NQR resonance signal; and a processor in operable communication with the measurement device and configured to generate NQR data from the NQR signal and calculate at least one of the temperature and the pressure of the earth formation therefrom. A method of measuring at least one of a temperature and a pressure of an earth formation is also enclosed.

Abstract: A partial least squares (PLS) regression relates spin echo signals with samples having a known parameter such as bound water (BW), clay bound water (CBW), bound volume irreducible (BVI), porosity (PHI) and effective porosity (PHE). The regression defines a predictive model that is validated and can then be applied to spin echo signals of unknown samples to directly give an estimate of the parameter of interest. The unknown samples may include earth formations in which a NMR sensor assembly is conveyed in a borehole.

Abstract: A fluid monitoring arrangement 1 for an engine is operated in accordance with a method whereby nuclear magnetic resonance (NMR) interrogation of the fluid flow 3 it is possible to determine whether appropriate fluids and additives are being utilised as well as whether potential detrimental actions occur such as engine wear and carbonisation through particulate components within the flow 3. Generally, an expected signal response from the fluid flow 3 is determined and the actual signal response compared in a comparator 8 with that expected signal response. Divergence in the actual signal response and in particular with regard to its profile is identified and an indication provided in a display 10 with regard to the potential coolant of such divergence. Normally, a reference library 11 is provided of expected signal responses for comparison in the comparator with the actual signal responses.

Abstract: Certain embodiments are directed to devices, systems and methods for determining a penetration depth of an induced oscillation in a porous medium. In certain examples, the devices, systems and methods are designed to detect a magnetic resonance signal in the presence of an induced oscillatory fluid flow in a porous medium to determine penetration depth of the induced oscillation in the porous medium. In some examples, the mobility of a fluid in the porous medium may be determined from the determined penetration depth.

Abstract: An apparatus and method is disclosed for measuring a parameter of an earth formation surrounding a wellbore. A Nuclear Magnetic Resonance (NMR) tool and at least one second tool are conveyed in the wellbore on a wireline, the NMR tool having a magnetic influence on a region of the wellbore. The magnetic influence of the NMR tool is removed from the region of the wellbore using a demagnetizing device. The parameter of the earth formation is measured using the at least one second tool. A second demagnetizing device may be used to remove the magnetic influence of the at least one second tool from the region of the wellbore.

Abstract: Embodiments of conductive polymers and instruments using the conductive polymers in geophysical exploration are provided. Methods for fabrication are included.

Abstract: A method to obtain a free induction decay signal using includes inducing a static magnetic field in a sample volume. A radio frequency (RF) magnetic field is then induced in the sample volume. The RF magnetic field has parameters selected to minimize the contribution of inhomogeneity to the static magnetic field to a free induction decay time. The free induction decay signal is then detected from the sample volume. In one example, prior to inducing the RF magnetic field, a reorienting radio frequency magnetic field is induced in the sample volume to reorient magnetic spins by a first selected angle. The inducing the RF magnetic field in this example has parameters selected to reorient spins by a second angle. The inducing the RF magnetic field and detecting the free induction decay signal are repeated until nuclear magnetic equilibrium is substantially attained.

Abstract: An NMR logging tool for conducting NMR measurements in a plurality of sensitive volumes ranging up to a meter from the tool. The tool comprises a magnetic assembly using one or more permanent magnets and at least one pole piece for extending a magnet pole and shaping the magnetic field to simulate a magnetic monopole in a sensitive volume within the formation. Different embodiments of a segmented antenna enable directional NMR logging. The tool embodiments and methods of their use are suitable for wireline or LWD logging, and can be used for directional drilling.

Abstract: A nuclear magnetic resonance (NMR) method is used to determine a velocity distribution or velocity image of a flowing fluid in a downhole environment. The method comprises applying a radio frequency pulse sequence; applying a magnetic field gradient magnetic field and a gradient pulse duration; measuring a NMR signal; determining a phase characteristic of the NMR signal; and determining the velocity distribution or image of the fluid using the determined phase characteristic, the magnetic field gradient pulse parameters, and a time delay between gradient pulses.