Abstract: A method for determining fluids in a formation. The method includes obtaining open hole measurements for a borehole in the formation; identifying points in the borehole from which to obtain pressure measurements using the open hole measurements; obtaining pressure measurements at the identified points in the borehole; applying an excess pressure technique to the pressure measurements to identify a plurality of pressure compartments in the borehole; characterizing fluid in each of the plurality of compartments; and developing a drilling plan based on characterization of fluids in each of the plurality of compartments.

Abstract: A method for analytically separating properties of hydrocarbon materials from other materials in a downhole environment, the method including: performing nuclear magnetic resonance (NMR) measurements downhole; determining a signal for sodium-23 (23Na) from the NMR measurements; and associating the 23Na signal with the other materials. A computer program product, an apparatus and additional methods are provided.

Abstract: Pulse sequences are applied to a fluid in an earth formation in a static magnetic field and NMR spin echo signals are obtained. The signals are processed to give a distribution of relaxation time at each of the plurality of depths. A quasi-DNA is obtained by autoscaling and a nonlinear mapping of T2 component logs and non-NMR logs. Similarities between the quasi-DNA of the two types of logs are used to estimate formation lithology and fluids.

Abstract: A method and system for performing speed correction on nuclear magnetic resonance logging data is provided. The speed correction performed can be done on a representation of echo data received by a logging tool, and then additively applied to the echo data. Such a process can reduce or remove the amplification of noise in the echo data that is common in conventional methods of speed correction.

Abstract: The present invention provides a method of determining a physiochemical property of a drilling fluid at a drilling site during a drilling phase, said method comprising detecting a nuclear magnetic resonance signal from out-of-hole drilling fluid at said site and calculating therefrom a value indicative of said property.

Abstract: Measurements of fluorescence spectra of fluid samples recovered downhole are processed to give the fluid composition. The processing may include a principal component analysis followed by a clustering method or a neutral network. Alternatively the processing may include a partial least squares regression. The latter can give the analysis of a mixture of three or more fluids.

Abstract: A method and apparatus to determine the fractional amount of at least one constituent of a hydrocarbon mixture, comprising dissolving the hydrocarbon mixture in a substantially hydrogen free solvent to produce a diluted solution, the diluted solution having sufficient solvent to render a NMR property of the diluted solution to be predictably related to the constituent concentrations of the hydrocarbon mixture; making NMR measurements on the diluted solution; and determining the fractional amount of at least one constituent of the hydrocarbon mixture from the NMR measurements.

Abstract: Methods and systems are provided for tools having non-resonant circuits for analyzing a formation and/or a sample. For example, nuclear magnetic resonance and resistivity tools can make use of a non-resonant excitation coil and/or a detection coil. These coils can achieve desired frequencies by the use of switches, thereby removing the requirement of tuning circuits that are typical in conventional tools.

Abstract: Embodiments of conductive polymers and instruments using the conductive polymers in geophysical exploration are provided. Methods for fabrication are included.

Abstract: A method for determining wettability of an earth formation zone surrounding a borehole, including the following steps: introducing paramagnetic ions into the water component of the zone; performing NMR measurements on the zone, and determining an NMR relaxation time parameter for the zone; extracting a fluid sample from the zone; performing NMR measurements on the sample, and determining the NMR relaxation time parameter for the sample; and determining wettability of the earth formation zone using the determined relaxation time parameter for the zone and the determined relaxation time parameter for the sample.

Abstract: Downhole orientation sensing with a nuclear spin gyroscope. A downhole orientation sensing system for use in conjunction with a subterranean well can include a downhole instrument assembly positioned in the well, the instrument assembly including an atomic comagnetometer, and at least one optical waveguide which transmits light between the atomic comagnetometer and a remote location. A method of sensing orientation of an instrument assembly in a subterranean well can include incorporating an atomic comagnetometer into the instrument assembly, and installing the instrument assembly in the well.

Abstract: To characterize an electrical cable that is deployed in a well, a voltage input is applied to the electrical cable at an earth surface location, where the well extends from the earth surface location. A current response resulting from the voltage input is measured at the earth surface location. At least one parameter of the electrical cable is computed according to the measured current response.

Abstract: In some embodiments, apparatus and systems, as well as methods, may operate to acquire data representing a plurality of nuclear magnetic resonance (NMR) echo trains associated with a material, such as a geological formation. Additional operations may include inverting a model of at least one of the plurality of NMR echo trains to provide an estimated distribution of transverse relaxation time constants, inverting models of selected ones of the plurality of NMR echo trains using the estimated distribution of transverse relaxation time constants to provide an estimated diffusion distribution, and inverting a model of selected ones of the plurality of NMR echo trains, using the estimated distributions of transverse relaxation time constants and diffusion, to provide an apparent and an intrinsic probability density function to identify fluid types in the material.

Abstract: A tool disposable within a well pipe, such as for detecting a freepoint of a well pipe, includes an electromagnet capable of inducing a magnetic field within a wall of a well pipe. The tool includes a Barkhausen noise sensing device capable of sensing magnetic Barkhausen noise in response to the electromagnet inducing the magnetic field within the wall of the well pipe. The tool may be moved along the well pipe so as make two passes of the tool along the well pipe, with one pass being performed while the well pipe is less stressed and the other pass being performed while the well pipe is more stressed, with the output of the tool during a first pass being compared to the output of the tool during a second pass to determine the location of the freepoint of the well pipe.

Abstract: A method for performing magnetic resonance measurements on a sample includes applying a first predetermined number of pulse trains for excitation, each pulse train having a constant amplitude and including a second predetermined number of pulses spaced by a predetermined time interval. The pulse trains are modulated by a bent function. After each pulse, data is sampled. Preferably a square number of pulses is generated being constant in power, and the Walsh transform of the sequence of their phases is constant in power, so that the power of the excitation in time and frequency domain is constant. The method can reduce power requirements and may permit undercutting specific absorption rate (SAR) limits due to the small excitation power necessary to create time signals with reasonable signal to noise ratio.

Abstract: A laboratory NMR methodology (and corresponding laboratory apparatus) defines a sample volume. The method stores downhole tool data corresponding to a hydrocarbon-bearing sample collected from a given subsurface formation. The downhole tool data includes parameters pertaining to magnetic fields used by a downhole tool during a suite of NMR measurements of the given subsurface formation. The sample is positioned in the sample volume of the laboratory apparatus, which applies a static magnetic field in the sample volume. Furthermore, the laboratory apparatus applies a suite of NMR measurements to the sample volume to thereby determine a property of the sample. The NMR measurements of the suite each include a pulse sequence of oscillating magnetic field in conjunction with a pulsed-mode gradient field. The pulsed-mode gradient field is based on the stored downhole tool data corresponding to the sample. A laboratory NMR methodology for optimizing downhole NMR measurements is also described.

Abstract: The Larmor frequency for an in situ nuclear magnetic resonance (NMR) tool is determined and used to acquire NMR data. An NMR tool is provided and placed in situ, for example, in a wellbore. An initial estimate of the Larmor frequency for the in situ NMR tool is made and NMR data are acquired using the in situ NMR tool. A spectral analysis is performed on the NMR data, or optionally, the NMR data are digitized and a discrete Fourier transform (DFT) is performed on the digitized NMR data. The modal frequency of the spectral analysis or DFT is determined, and the Larmor frequency for the in situ NMR tool is determined using the modal frequency. The NMR tool is modified to transmit at the determined Larmor frequency and then used to acquire further NMR data.

Abstract: NMR spin echo signals are acquired downhole. Principal Component Analysis is used to represent the signals by a weighted combination of the principal components and these weights are telemetered to the surface. At the surface, the NMR spin echo signals are recovered and inverted to give formation properties.

Abstract: Methods and related systems are described for estimating fluid or rock properties from NMR measurements. A modified pulse sequence is provided that can directly provide moments of relaxation-time or diffusion distributions. This pulse sequence can be adapted to the desired moment of relaxation-time or diffusion coefficient. The data from this pulse sequence provides direct estimates of fluid properties such as average chain length and viscosity of a hydrocarbon. In comparison to the uniformly-spaced pulse sequence, these pulse sequences are faster and have a lower error bar in computing the fluid properties.

Abstract: The viscosity ? (in centipoise) of a heavy oil sample is determined according to an equation of the form ln ? ? g = - C ? ? 1 * ( T - c ? ? 246 ) c ? ? 47.10 + ( T - c ? ? 246 ) , where T is the temperature of the heavy oil, T2LM is the logarithmic mean of the T2 distribution of the sample obtainable from nuclear magnetic resonance (NMR) measurements, c?=1.0±0.05, c?=1.0±0.04, ?g is the glass transition temperature viscosity of the heavy oil and a function of T2LM, and C1 is a variable which is a constant for the heavy oil and is a function of T2LM. Both C1 and ?g are considered functions of certain NMR values associated with the heavy oil sample, with ?g and C1 preferably estimated by empirically fitting data to the equations ln T2LM=a?+b? ln ?g and ln T2LM=a?+b?C1, where a?, b?, a? and b? are constants.

Abstract: A method of determining the effect of formation porosity on formation resistivity and parameters derived from the formation resistivity is described, including the step of determining for a depth interval a heterogeneity measure; and using a pre-defined relation to transform the heterogeneity measure into an algebraic term determining the effect of the formation porosity on the formation resistivity, based for example on Archie's law or similar relations.

Abstract: NMR spin echo signals are acquired downhole. Principal Component Analysis is used to represent the signals by a weighted combination of the principal components and these weights are telemetered to the surface. At the surface, the NMR spin echo signals are recovered and inverted to give formation properties. Real-time displays may be used for determining formation properties and for altering the acquisition parameters.

Abstract: A method of measuring a parameter characteristic of a rock formation in an oil well is provided for evaluating a reservoir treatment applied to a subterranean formation including the steps of injecting from a tool body suspended into a well at an injection location a known volume of fluid into the formation, performing a logging operation sensitive to a change of fluid content at several measuring points below and above the injection location; and using results of the logging operation to determine a depth profile along said well of a parameter related to fluid content.

Abstract: An integral microfluidic device includes an alkali vapor cell and microfluidic channel, which can be used to detect magnetism for nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI). Small magnetic fields in the vicinity of the vapor cell can be measured by optically polarizing and probing the spin precession in the small magnetic field. This can then be used to detect the magnetic field of in encoded analyte in the adjacent microfluidic channel. The magnetism in the microfluidic channel can be modulated by applying an appropriate series of radio or audio frequency pulses upstream from the microfluidic chip (the remote detection modality) to yield a sensitive means of detecting NMR and MRI.

Abstract: A nuclear magnetic resonance relaxation dispersion method to determine the wettability and other parameters of a fluid in a porous medium such as in an earth formation is provided. The method includes the steps of measuring the spin-lattice relaxation time T1 of the fluid in the porous medium at varying polarizing magnetic field strengths or nuclear Larmor frequencies; and determining whether the values of T1 at varying Larmor frequencies follow a dispersion curve that is characteristic of the parameter of the fluid in the porous medium to be determined.

Abstract: An apparatus for estimating a property of an earth formation penetrated by a borehole, the apparatus includes: a carrier configured to be conveyed through the borehole; a nuclear magnetic resonance (NMR) instrument disposed at the carrier and configured to perform an NMR measurement on a volume sensitive to the NMR measurement; and a contrast agent disposed in the volume and comprising particles that form a suspension in a liquid, the suspension of particles being configured increase a magnetic field gradient of at least one earth formation material in the volume to change an NMR relaxation time constant of the at least one earth formation material; wherein the NMR measurement on the volume containing the at least one earth formation material and the contrast agent is used to estimate the property.

Abstract: Multimodal geosteering systems and methods are disclosed. Some disclosed tool embodiments include first and second transmitter-receiver arrangements that make geosteering measurements using different forms of energy (such as acoustic and electromagnetic energy) to provide geosteering measurements that at least indicate a boundary direction but may also indicate a boundary distance. Some disclosed method embodiments include: determining a direction to a bed boundary using measurements with different energy types; and adjusting a drilling direction based at least in part on said determination. Combinations of (or selections between) the different measurements may be made based on, inter alia, measurement range, resolution, and contrast. Some disclosed system embodiments include a memory and a processor. The memory stores geosteering display software that configures the processor to generate an image with different regions based on the different types of geosteering measurements.

Abstract: NMR logging in a wellbore is used to monitor an oil reservoir during oil recovery by miscible displacement. Diffusivity distributions found by NMR logging indicate whether one or two phases are present and composition of residual oil. Operation of the oil recovery procedure may be maintained or modified in response to monitoring of the reservoir.

Abstract: An apparatus and method is disclosed for measuring a parameter of an earth formation surrounding a wellbore. A Nuclear Magnetic Resonance (NMR) tool and at least one second tool are conveyed in the wellbore on a wireline, the NMR tool having a magnetic influence on a region of the wellbore. The magnetic influence of the NMR tool is removed from the region of the wellbore using a demagnetizing device. The parameter of the earth formation is measured using the at least one second tool. A second demagnetizing device may be used to remove the magnetic influence of the at least one second tool from the region of the wellbore.

Abstract: Viscosity of heavy oil is determined in situ in a formation by making nuclear magnetic resonance (NMR) measurements in the formation, and then calculating viscosity according to an equation of the form T 2 ? LM = a + b ? ( ? T ) c , where T is the temperature of the heavy oil sample, ? is the viscosity, T2LM is the logarithmic mean of the T2 distribution spectrum of the sample, and a, b, and c are non-zero constants. Typically, constant b has a value between 5 and 7 and constant c has a value between ?0.7 and ?0.5.

Abstract: A method for detecting the presence of precipitants in a hydrocarbon stream, the method comprising introducing at least a portion of the hydrocarbon stream into a measurement chamber of an NMR measuring device, assaying the fluids in the chamber with proton nuclear magnetic resonance to obtain NMR signals, and processing the NMR signals to detect the formation of precipitants in the hydrocarbon stream. The method may be carried out at first and second locations, and NMR signals obtained at the two locations compared to detect precipitation of precipitant between the two locations. A method of monitoring the water content of a hydrocarbon stream in a flowline comprising introducing at least a portion of the hydrocarbon stream into an NMR measuring device, measuring a baseline NMR water signal of the hydrocarbon stream and comparing subsequent NMR water signals with the baseline NMR water signal to detect changes in the water content of the hydrocarbon stream.

Abstract: A method is disclosed for the non-destructive determination of the pore size distribution and the distribution of fluid flow velocities using NMR spin echo signal measurements. In one embodiment, the invention involves simultaneously injecting acoustic energy (208), generating a magnetic field having a gradient, and injecting radio-frequency electromagnetic energy (206) into a subsurface region, using for example an NMR tool and a well logging tool having an acoustic transmitter placed in a wellbore (202). The spin echo signal generated in the subsurface region is measured (210) by the NMR tool for at least two values (212) of the magnetic field gradient. A relationship is provided by which the pore fluid velocity distribution may be calculated (214) from the inverse Fourier transform of the spin echo data. The pore size distribution may then be calculated from the pore fluid velocity distribution.

Abstract: The disclosed innovation is a method for acquiring spatial frequency spectra from specific locations in a 3D sample using modifications of the current MRI techniques for localized NMR spectroscopy. The innovation in its simplest abstraction is to add the use of a read out gradient to the current NMR spectroscopy pulse sequences and record the resultant echo. These techniques generate spectra from a selected region or generate an image of the results over a region of the sample. These methods can be applied to analyzing the structure of trabecular bone as well as for analyzing or diagnosing disease in cases where there is a difference in the spatial frequency power spectrum due to physiologic or disease processes. Various embodiments are disclosed.

Abstract: A method for determining oil viscosity and continuous gas-oil-ratio (GOR) from nuclear magnetic resonance logs (NMR). The method includes obtaining a set of NMR data of a portion of the subterranean formation from inside the wellbore without acquiring formation fluid sample; isolating a quantitative reservoir fluid information associated with oil from oil based mud (OBM) using radial profiling of the set of NMR data, wherein the OBM is used for extracting fluid from the underground reservoir; determining GOR related information associated with the portion of the subterranean formation from the quantitative reservoir fluid information associated with oil, wherein the GOR related information is determined based on a predetermined model; and performing operations for the oilfield based on the GOR related information.

Abstract: A method for estimating a distribution of pore sizes of a fluid filled rock formation penetrated by a borehole, the method including: processing nuclear magnetic resonance (NMR) data to determine a distribution of diffusion coefficients and a distribution of relaxation time constants for at least one depth in the borehole; plotting the distribution of diffusion coefficients and the distribution of relaxation time constants as a cross-plot for the at least one depth; identifying a water line on the cross-plot, each point on the water line having substantially the same value for the diffusion coefficient; and estimating the distribution of pore sizes from the distribution of relaxation time constants plotted along the water line.

Abstract: The present disclosure relates to a method to estimate a subsurface formation property. A downhole logging tool is provided and disposed in a wellbore. Multiple measurements of various measurement types are obtained at various depths of investigation using the downhole logging tool. The multiple measurements may include natural gamma ray measurements, density measurements, resistivity measurements, nuclear measurements, and nuclear magnetic resonance measurements. The signal-to-noise ratio of the measured signals is increased using, for example, lateral stacking and multi-shell inversion. The subsurface formation property is estimated using the increased signal-to-noise ratio signals. The subsurface formation property may include porosity, adsorbed gas volume, free gas volume, bound water volume, free water volume, oil volume, and kerogen volume. A fluid analysis may be performed using a multi-dimensional nuclear magnetic resonance technique.

Abstract: The present invention relates to making one or more measurements in a virgin formation using a downhole tool that includes a miniature logging tool. The downhole tool is disposed in a wellbore penetrating the formation, adjacent to the formation, and a sidetrack borehole is made into the formation. All or a portion of the miniature logging tool is deployed into the sidetrack borehole and measurements are made in the virgin formation using the miniature logging tool. The downhole tool may include a drilling/coring module, a pump module, and packers. The drilling/coring module is used to make the sidetrack borehole, and the packers and pump module can be used to create an underbalanced drilling condition in an isolated section of the wellbore.

Abstract: In some embodiments, apparatus and systems, as well as methods, may operate to acquire signature data representing a plurality of nuclear magnetic resonance (NMR) echo trains associated with a material comprising a first fluid and a second fluid, force a subset of the signature data associated with the first fluid or the second fluid to correspond to single-peak signatures in the T1 and/or T2 domains, and solve for the first fluid and second fluid saturation. The first fluid may include oil, gas, or water and the second fluid may include oil-based mud filtrate or water-based mud filtrate, among others.

Abstract: A method for estimating fluid productivity of a subsurface rock formation from within a wellbore drilled therethrough includes measuring a nuclear magnetic resonance property of the formation at a plurality of lateral depths therein. The measured nuclear magnetic resonance property is used to estimate the fluid productivity.

Abstract: A method for estimating fluid saturation in a formation penetrated by a wellbore from nuclear magnetic resonance measurements made at a plurality of lateral depths into the formation from the wellbore includes estimating a bound water volume, a total porosity and a free water volume at each of the lateral depths from the nuclear magnetic resonance measurements. A minimum water saturation is estimated at each lateral depth from the total porosity, the free water volume and the bound water volume at each lateral depth. A value of water saturation is estimated at each lateral depth from the minimum water saturation at each lateral depth. A relationship between lateral depth and water saturation is determined. Water saturation is estimated at a selected lateral depth greater than the greatest lateral depth of the nuclear magnetic resonance measurements.

Abstract: Disclosed is a non-lineal statistical independent component (ICA) analysis methodology for calculating T2 or T1 distributions of nuclear magnetic resonance logs. In one aspect, the invention employs a classical blind source separation (BSS) approach with the input data (T2 or T1 distributions) being considered not only horizontally (in relaxation time units), but also vertically (in depth). The statistical variations are used for separating the principal independent components and their corresponding weighting matrix. The result of such ICA based BSS is an efficient separation of T2 components correlative to the presence of particular conditions (e.g., clay bound water, heavy oil, capillary bound water, free water, mud filtrate (water and oil), and noise). Individual saturation of estimated fluids can be calculated from the weighting matrix generated in accordance with the invention.

Abstract: A method for mineral analysis of a sample based on detection of NQR and/or NMR signals from a particular substance within a sample includes: setting a frequency of RF pulses to be approximately equal to one of the NQR or NMR frequencies of the substance; setting a set of parameters of the RF pulses to be optimal for the substance; setting a set of receiving parameters to be optimal for the substance; tuning the probe to maximum sensitivity for the signals detected at predetermined frequency and/or to maximum power transfer efficiency for RF pulses transmitted with the probe; transmitting the RF pulses with the probe at said optimal level during a transmitting period to irradiate the sample and excite an NQR or NMR signal in the substance, if present; detecting and processing NQR or NMR signals emitted by the substance; and calculating the concentration of the substance in the sample.

Abstract: Computer based CAE FSI models for simulating the physical behavior of diapers, and/or diaper materials, and/or diaper machines during diaper manufacturing processes.

Abstract: An apparatus and a method is provided based on the Magnetic Resonance techniques to analyze and measure a uni- and/or a bi-directional flow regime of multiphase fluids in a transport and production conduct, in real time and flow-rates, based on a magnetic resonance analytical module, two magnetic prepolarization modules of variable effective length and a control computer of data acquisition and transfer, all associated to each other.

Abstract: A nuclear magnetic resonance sensing apparatus and method for operating in an earth borehole comprises a source of switchable magnetic field to polarize nuclei in the region of interest, said source comprising a coil wound on a magnetic core having controllable residual magnetization. Maintaining the magnetization of the core during a polarization interval does not require steady current in the coil. Switching intensity and polarity of magnetization of the core causes precession of spin magnetic moments of the nuclei; the precession induces a signal indicative of nuclear magnetic resonance properties of earth formations.

Abstract: A method for determining effective permeabilities of earth formations. The method includes receiving a database having one or more measurements made on a collection of fluid filled rocks and dividing the measurements into input measurements and output measurements. The input measurements include one or more measured properties of the fluid filled rocks and the output measurements include the corresponding effective permeabilities of the fluid filled rocks. The method then includes constructing a mapping function using the input measurements and the output measurements. The mapping function may then be used to predict the effective permeabilities of one or more rocks that are not part of the collection of fluid filled rocks.

Abstract: A method for determining particle size distribution of a subsurface rock formation using measurements of at least one nuclear magnetic resonance property made from within a wellbore penetrating the rock formation includes determining a distribution of nuclear magnetic relaxation times from the measurements of the at least one nuclear magnetic resonance property. A surface relaxivity of the formation is determined from measurements of a formation parameter. The relaxation time distribution and surface relaxivity are used to determine the particle size distribution.

Abstract: A method and apparatus useful to determine characteristics of fluid flow, such as fluid holdup and flow velocity. The apparatus comprises a flow tube, a permanent magnet, a first set of coils, and a second set of coils. The first set of coils creates a radio frequency magnetic field within the flow tube with a series of refocusing pulses. The second set of coils encodes velocity information onto the fluid molecules using rotating frame zeugmatography that is later decoded and used to estimate the fluid flow velocity.

Abstract: Methods and related systems are described for real-time wellsite production allocation analysis. Spectroscopic in-situ measurements are made in the vicinity of a wellsite of a produced fluid from one or more boreholes. The produced fluid includes in a co-mingled state, at least a first fluid component from a first production zone and a second fluid component from a second production zone. An allocation is estimated in real-time for at least the first fluid component in the produced fluid based at least in part on the spectroscopic in-situ measurements. The in-situ measurements can be several types, for example: (1) absorption of electromagnetic radiation having wavelengths in the range of ultraviolet, visible and/or infrared light, (2) X-ray fluorescence spectroscopy measurements, (3) electromagnetic scattering spectroscopic measurements such as Raman spectroscopy measurements, (4) NMR spectroscopy measurements, and (5) terahertz time-domain spectroscopy measurements.

Abstract: A system for measuring at least one of a temperature and a pressure of an earth formation is disclosed. The system includes: a downhole tool disposed in a borehole and configured to be movable within the borehole; at least one nuclear quadrupole resonance (NQR) measurement device including a transmitter configured to emit a radiofrequency magnetic field having at least one selected frequency band into the earth formation to cause a component thereof to produce a NQR signal, and a detector configured to detect the NQR resonance signal; and a processor in operable communication with the measurement device and configured to generate NQR data from the NQR signal and calculate at least one of the temperature and the pressure of the earth formation therefrom. A method of measuring at least one of a temperature and a pressure of an earth formation is also enclosed.