With Significant Electrolyte Patents (Class 361/504)
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Patent number: 7292431Abstract: The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from ?3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.Type: GrantFiled: April 4, 2005Date of Patent: November 6, 2007Assignee: Gen 3 Partners, Inc.Inventors: Alexander Mikhailovich Timonov, Sergey Anatolijevich Logvinov, Dmitriy Ivanovich Pivunov, Svetlana Viktorovna Vasiljeva, Nik Shkolnik, Sam Kogan
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Patent number: 7289312Abstract: The present invention relates generally to an electrical charge storage device (ECSD) with enhanced power characteristics. More particularly, the present invention relates to enhancing the current density, voltage rating, power transfer characteristics, frequency response and charge storage density of various devices, such as capacitors, batteries, fuel cells and other electrical charge storage devices. For example, one aspect of the present invention is solid state and electrolytic capacitors where the conductor surface area is increased with smooth structures, thereby reducing the distance separating the conductors, and improving the effective dielectric characteristics by employing construction techniques on atomic, molecular, and macroscopic levels.Type: GrantFiled: March 4, 2004Date of Patent: October 30, 2007Inventor: William B. Duff, Jr.
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Patent number: 7286335Abstract: An electric double layer capacitor capable of preventing leakage of an electrolytic solution from the inside and interfusion of unnecessary material from the outside, and capable of forming insulation between a terminal and an outer casing, is provided. A lower-insulation ring 131 is fit into a terminal 112 until the lower-insulation ring comes in the upper side of a flange portion 113. Then, the terminal 112 in this state is inserted into a center of the through hole 111a of a sealing plate 111 from the inside of an outer casing 121. Then, an O-ring 133 is press fit into a spacing 135 formed by a cylindrical portion 112a and the through hole 111a. Further, an upper-side insulation ring 137 is fit to the upper side of this press fit O-ring 133. Then, a setting spring 139 is attached to the terminal 112 so as to press down the upper-side insulation ring 137.Type: GrantFiled: April 20, 2006Date of Patent: October 23, 2007Assignee: Asahi Glass Company, LimitedInventors: Yoshihiro Hozumi, Katsuji Ikeda
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Patent number: 7283349Abstract: An electric double layer capacitor has a pair of current collectors, a positive polarizable electrode which is provided on one of the pair of current collectors, includes activated carbon of a weight W+ and has a capacitance C+, a negative polarizable electrode which is provided on the other of the pair of current collectors, includes activated carbon of a weight W? and has a capacitance C?, a separator interposed between the positive and negative polarizable electrodes, and an organic electrolytic solution which impregnates at least the positive and negative polarizable electrodes and the separator, wherein C?/C+=0.6 to 1.0 and W?/W+=1.1 to 2.0. Even when continuously charged at a high applied voltage, the electric double layer capacitor has a high retention of capacitance and a low rise in internal resistance, and thus has an excellent durability.Type: GrantFiled: September 25, 2006Date of Patent: October 16, 2007Assignee: Nisshinbo Industries, Inc.Inventors: Hiroshi Yoshida, Hidenori Nakata
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Patent number: 7268995Abstract: An electric double layer capacitor is composed of a pair of current collectors, a positive polarizable electrode provided on one of the pair of current collectors, a negative polarizable electrode provided on the other of the pair of current collectors, a separator between the positive and negative polarizable electrodes, and an organic electrolytic solution which impregnates at least the positive and negative polarizable electrodes and the separator. The capacitor has a theoretical amount of ions Qt defined as Qt (moles)=C×V÷96,500, wherein C is the rated capacitance (farads) of the capacitor and V is the rated voltage (volts), and an amount of ions Qe in the organic electrolytic solution, such that Qe/Qt=1.7 to 3.5. The capacitor has a high voltage rating, excellent cycle characteristics during high-current charging and discharging, and a low internal resistance in low-temperature environments.Type: GrantFiled: September 25, 2006Date of Patent: September 11, 2007Assignee: Nisshinbo Industries, Inc.Inventors: Hiroshi Yoshida, Kanako Yuyama
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Patent number: 7268205Abstract: Devices formed of or including biocompatible polyhydroxyalkanoates are provided with controlled degradation rates, preferably less than one year under physiological conditions. Preferred devices include sutures, suture fasteners, meniscus repair devices, rivets, tacks, staples, screws (including interference screws), bone plates and bone plating systems, surgical mesh, repair patches, slings, cardiovascular patches, orthopedic pins (including bone filling augmentation material), adhesion barriers, stents, guided tissue repair/regeneration devices, articular cartilage repair devices, nerve guides, tendon repair devices, atrial septal defect repair devices, pericardial patches, bulking and filling agents, vein valves, bone marrow scaffolds, meniscus regeneration devices, ligament and tendon grafts, ocular cell implants, spinal fusion cages, skin substitutes, dural substitutes, bone graft substitutes, bone dowels, wound dressings, and hemostats.Type: GrantFiled: January 16, 2007Date of Patent: September 11, 2007Assignee: Metabolix, Inc.Inventors: Simon F. Williams, David P. Martin, Frank A. Skraly
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Patent number: 7256981Abstract: An electric double layer capacitor comprising a pair of electrodes and an electrolytic solution in contact with said pair of electrodes, wherein: the electrolytic solution contains a compound having the formula (1) and an organic solvent. Here, R1 is a group selected from among dimethylene, trimethylene, tetramethylene and pentamethylene, and R2 is tetramethylene or pentamethylene.Type: GrantFiled: May 26, 2006Date of Patent: August 14, 2007Assignee: TDK CorporationInventors: Atsuko Kosuda, Yoshihiko Ohashi
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Patent number: 7251122Abstract: An electric chemical capacitor includes first and second electrodes each including a collector 111, 121, a polarized electrode layer 112, 122 and an undercoat layer 113, 123 for bonding the collector and the polarized electrode layer with each other, and a separator put between the first and second electrodes so that the polarized electrode layers 112 and 122 face each other, wherein an end portion of each undercoat layer 113, 123 is located in the same position as or on the outer side of an end portion of the corresponding polarized electrode layer 112, 122, and located on the inner side of an end portion of the separator 130. Thus, the polarized electrode layers can be prevented from peeling from the collector. Further, the undercoat layers can be prevented from abutting against each other, and the undercoat layer of one electrode and the collector of the other electrode can be prevented from abutting against each other.Type: GrantFiled: December 21, 2004Date of Patent: July 31, 2007Assignee: TDK CorporationInventors: Kiyonori Hinoki, Yousuke Miyaki, Kazuo Katai, Hideki Tanaka, Tsuyoshi Ichiki
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Patent number: 7242572Abstract: A sealed electrode enclosed in separator material is provided for use in a capacitor cell. The separator may either be adhered to the electrode in sheets, or may be formed into a pouch, which is used to enclose the electrode. A method of preparing the electrode sealed with separator is described in which an adhesive is used to secure the pouch to the electrode before sealing it. The prefabricated electrode and separator combination may be used in both coiled capacitor cells and flat capacitor cells that are often used in implantable medical devices. Electrodes prepared in this fashion can be efficiently and reliably aligned within the case of a capacitor cell, and have no exposed electrode surfaces that could lead to short-circuiting within the cell.Type: GrantFiled: July 11, 2003Date of Patent: July 10, 2007Assignee: Medtronic, Inc.Inventors: John D. Norton, Anthony W. Rorvick, Mark D. Breyen, Paul A. Pignato, Thomas P. Miltich
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Patent number: 7236348Abstract: A reinforcing material-having functional sheet of a sheet-like functional material including a functional powder and a binder resin and, laminated thereon, a reinforcing sheet comprising a woven fabric or a non-woven fabric, which are bonded, wherein the basis weight of the reinforcing sheet, the fiber diameter of the fiber constituting the reinforcing sheet and the functional sheet thickness are in specific ranges. A sheet-like electrode for electric double layer capacitors, which electrode comprises a sheet-like electrode of carbon fine powder and a fluorine-containing polymer resin and, laminated thereon, the reinforcing sheet, and an electric double layer capacitor having this electrode. The functional sheet has strength and no elimination of the functional material powder, and also efficiently exhibits high functional properties.Type: GrantFiled: August 19, 2003Date of Patent: June 26, 2007Assignee: Nippon Valqua Industries, Ltd.Inventors: Yoshitaka Asano, Toru Sugitani, Michinao Hayashi, Daijirou Akiyama
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Patent number: 7233481Abstract: An electric double layer capacitor has a pair of activated carbon electrodes and an organic solution in which an electrolyte is dissolved in an organic solvent. An electrolyte solution is also provided. In the electric double layer capacitor, at least one of cycloalkane, cycloalkene, or derivatives thereof is contained in at least one of the activated carbon and the organic electrolyte solution. The organic solvent contains a main solvent and an additive solvent. The main solvent contains propylenecarbonate in a range of from 99.9 to 70 wt %, and at least one of ethylenecarbonate and dimethylcarbonate in a range of from 0.1 to 30 wt %, and the additive solvent contains cycloalkane in a range of from 5 to 30 wt % to the total amount of the organic solvent.Type: GrantFiled: January 27, 2005Date of Patent: June 19, 2007Assignee: Honda Motor Co., Ltd.Inventor: Takeshi Fujino
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Patent number: 7233482Abstract: A surface mount energy storage device in the form of a supercapacitor (1) includes a generally rectangular folded prismatic housing (2) and two energy storage elements (not shown) that are sealingly contained within the housing (2) and which are connected in series. A mount, in the form of an integrally formed tinned metal frame (3), extends about and captively retains housing (2) in the folded configuration shown. Two terminals, in the form of elongate contacts (4, 5) extend from the energy storage elements and terminate outside housing (2) for allowing external electrical connection to the elements.Type: GrantFiled: April 6, 2006Date of Patent: June 19, 2007Assignee: CAP-XX LimitedInventors: David Albert James, Stephen Robert Wilson, Alina Kay Sloan, Richard Michael Stephens
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Patent number: 7224574Abstract: An electric double layer capacitor in which gas generation due to decomposition of a solvent of an electrolyte solution in the capacitor is reduced and performance maintaining ratio is superior, is provided by a method which is different from a method of adding additives to the electrolyte solution. The electric double layer capacitor has activated carbon polarizing electrodes and a non-water-based solvent, and a positive electrode of the activated carbon polarizing electrodes contains an antacid agent.Type: GrantFiled: March 13, 2006Date of Patent: May 29, 2007Assignee: Honda Motor Co., Ltd.Inventors: Takeshi Fujino, Byoungju Lee
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Patent number: 7215532Abstract: A method for manufacturing electrical components of the energy-accumulating electrostatic or electrochemical type, consisting in winding at least two layers of a film on a support made of an electrically nonconducting material that has a substantially polygonal cross-section, by providing a preset number of film turns until a predefined thickness is reached, and forming a first layer; arranging respective spacers at the corners of the polygon in which the contour of the wound film is inscribed; and winding more turns of film around the first layer and around the spacers inserted at the corners, to form a second layer. A machine by means of which the method is performed comprises a rotatingly mounted frame on which the support is fixed for winding of the layer of film.Type: GrantFiled: February 17, 2005Date of Patent: May 8, 2007Assignee: Arcotronics Industries S.p.AInventors: Sauro Righi, Mirko Mazza
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Patent number: 7214328Abstract: An electrolytic solution for operating electrolytic capacitors which deteriorates extremely little in electrical properties even when used in a high-tension capacitor. The electrolytic solution comprises a compound expressed by general formula (1) below and a compound expressed by general formula (2) below or their salts: where each R is a same or different alkyl group, and R? is hydrogen, a methyl group or an ethyl group, and n is an integer of 0 to 14.Type: GrantFiled: December 9, 2002Date of Patent: May 8, 2007Assignee: Okamura Oil Mill, Ltd.Inventors: Noritaka Miyoshi, Masashi Nakagawa, Yasuyuki Yamagawa, Kazuhisa Takii
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Patent number: 7212397Abstract: The invention relates to an electrochemical cell including: at least a pair of current collector plates that are placed in parallel to each other, flat electrodes containing aqueous electrolyte printed on opposing faces of said current collectors, such that a peripheral region is defined on each of said faces of said current collectors, which region is not covered by said electrode, and a separating medium interposed between said electrodes, the geometric form and size of said separating medium being identical to the form and size of said current collector plates, said separating medium having a central region permeable to said electrolyte, surrounded by a peripheral masked region which is non-permeable to said electrolyte, such that the permeable region of said separating medium coincide with the electrodes printed on the opposing faces of said current collectors, with respect to position, geometric form and size; wherein the pores in the peripheral region of the separating medium are impregnated with a suitType: GrantFiled: August 30, 2004Date of Patent: May 1, 2007Assignee: Cellergy Ltd.Inventor: Joel Lang
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Patent number: 7206190Abstract: In an electrode for an electric double layer capacitor of the present invention, the peak value of particle size distribution of graphite particles added to a conductive adhesive is in a range of 2.6 to 3.2 ?m, not less than 100,000 dimples having a largest outer diameter in a range of 4 to 10 ?m and a depth in a range of 4 to 15 ?m are formed on the surface of the collector sheet per 1 cm2, and the occupied area of the dimples to the entire surface area of the collector sheet is not more than 50%. By determining the saponification value of polyvinylalcohol which is used as a binder component of the conductive adhesive in a range of 90.0 to 98.5, adhesiveness of the collector sheet and the electrode forming sheet is improved. Furthermore, by substituting H atoms contained in the polyvinylalcohol with Si atoms, adhesiveness of the collector sheet and the electrode forming sheet can be further improved.Type: GrantFiled: June 21, 2005Date of Patent: April 17, 2007Assignees: Honda Motor Co., Ltd., No-Tape Industrial Co., Ltd., Daido Metal Company Ltd.Inventors: Kenichi Murakami, Manabu Iwaida, Shigeki Oyama, Toshiaki Fukushima, Tomohiko Kawaguchi, Kouki Ozaki, Masanori Tsutsui
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Patent number: 7206189Abstract: Composite electrode/current collectors for capacitors, e.g., a flow-through capacitor or electric double layer capacitor are disclosed. Also disclosed are methods for making a composite electrode/current collectors and capacitors having at least one composite electrode/current collector.Type: GrantFiled: August 27, 2004Date of Patent: April 17, 2007Assignee: Advanced Energy Technology Inc.Inventor: Robert A. Reynolds, III
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Patent number: 7203056Abstract: Thermal protection is provided in systems utilizing high-current double-layer capacitors. For example, in one implementation, an interconnection coupled to at least one double-layer capacitor that carries capacitor current to or from the at least one double-layer capacitor is functionally coupled to the at least one double-layer capacitor to reduce a temperature of the capacitor is provided.Type: GrantFiled: October 7, 2004Date of Patent: April 10, 2007Assignee: Maxwell Technologies, Inc.Inventor: Guy Thrap
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Patent number: 7198712Abstract: For desulfurization and, if necessary, for denitrification of hydrocarbon fractions the hydrocarbon mixture is brought into contact with a non-aqueous ionic liquid of general formula Q+A?, wherein Q+ is a ammonium, phosphonium or sulfonium cation, that contains at least one alkylating agent of the formula RX?, making it possible to form ionic sulfur-containing derivatives (and, if necessary, nitrogen-containing derivatives) that have a preferred solubility in the ionic liquid; and the ionic liquid is separated from the hydrocarbon mixture that is low in sulfur and nitrogen by decanting.Type: GrantFiled: June 17, 2003Date of Patent: April 3, 2007Assignee: Institut Francais du PetroleInventors: Helene Olivier-Bourbigou, Denis Uzio, Lionel Magna, Fabrice Diehl
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Patent number: 7199997Abstract: An asymmetric supercapacitor has a positive electrode having a current collector an active material selected from the group consisting of manganese dioxide, silver oxide, iron sulfide and mixtures thereof, a negative electrode having a carbonaceous active material carbon and optional current collector, an electrolyte, and a separator plate. In a preferred embodiment at least one of the electrodes has nanostructured/nanofibrous material and in a more preferred embodiment, both electrodes have nanostructured/nanfibrous material. The electrolyte can be liquid or solid although liquid electrolytes are preferred. The asymmetric supercapacitor has improved energy density by electrically coupling an electrode of high faradaic capacity such as one having manganese oxide (MnO2) with an electrode such as carbon that stores charge through charge separation at the electric double-layer. The asymmetric supercapacitor also improves power density by using high surface area nanostructured/nanofibrous electrode materials.Type: GrantFiled: June 9, 2000Date of Patent: April 3, 2007Assignee: U.S. Nanocorp, Inc.Inventors: Stephen M. Lipka, John R. Miller, Tongsan D. Xiao, David E. Reisner
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Patent number: 7198654Abstract: A separator sheet for manufacturing an electric double layer capacitor, and a method for manufacturing the electric double layer capacitor using the same, are provided. According to an embodiment, the separator sheet for manufacturing the electric double layer capacitor comprises: a plurality of separators; and a resin film holding the plurality of separators, wherein the separators are disposed in the resin film at a predetermined interval.Type: GrantFiled: December 21, 2005Date of Patent: April 3, 2007Assignee: LG Electronics Inc.Inventors: Kang Yoon Kim, Sang Gon Lee, Young Kee Seo, Jung Hoon Lee
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Patent number: 7179883Abstract: Devices formed of or including biocompatible polyhydroxyalkanoates are provided with controlled degradation rates, preferably less than one year under physiological conditions. Preferred devices include sutures, suture fasteners, meniscus repair devices, rivets, tacks, staples, screws (including interference screws), bone plates and bone plating systems, surgical mesh, repair patches, slings, cardiovascular patches, orthopedic pins (including bone filling augmentation material), adhesion barriers, stents, guided tissue repair/regeneration devices, articular cartilage repair devices, nerve guides, tendon repair devices, atrial septal defect repair devices, pericardial patches, bulking and filling agents, vein valves, bone marrow scaffolds, meniscus regeneration devices, ligament and tendon grafts, ocular cell implants, spinal fusion cages, skin substitutes, dural substitutes, bone graft substitutes, bone dowels, wound dressings, and hemostats.Type: GrantFiled: December 22, 2004Date of Patent: February 20, 2007Assignee: Metabolix, Inc.Inventors: Simon F. Williams, David P. Martin, Frank A. Skraly
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Patent number: 7177139Abstract: An electrical double layer capacitor is provided which is capable of ensuring its reliability and providing increased energy density per unit volume of a capacitor. A negative electrode is so configured as to cover all surfaces of a positive electrode and, therefore, there is no portion in which the positive electrode does not face the negative electrode, which enables generation of gas within the capacitor to be suppressed and ensures reliability of the capacitor. Portions in which the negative electrode do not face the positive electrode serve as non-covered portions and, therefore, electrostatic capacitance per unit volume of electrodes is made to increase, and energy density is improved.Type: GrantFiled: August 17, 2005Date of Patent: February 13, 2007Assignee: NEC Tokin CorporationInventor: Wataru Oizumi
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Patent number: 7170739Abstract: Electrochemical double layer capacitors are disclosed that advantageously include separators having at least one porous layer of nanofibers having average diameters of between about 50 nm and about 1000 nm that provide improved combinations of reduced thickness, barrier against the development of soft short-circuits and low ionic resistance as compared with known capacitor separators.Type: GrantFiled: September 30, 2005Date of Patent: January 30, 2007Assignee: E.I. du Pont de Nemours and CompanyInventors: Pankaj Arora, Simon Frisk, Lu Zhang
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Patent number: 7167353Abstract: The water present within an ionic liquid that is in a liquid state at 25° C. or an organic solution containing at least one ionic compound is decomposed by bringing electrodes into contact with the ionic liquid or organic solution within an atmosphere having a dew-point temperature not higher than ?40° C. or under a reduced pressure of not more than 75 torr, thereby reducing the water content. This process makes it possible to obtain highly dehydrated ionic liquids.Type: GrantFiled: April 24, 2003Date of Patent: January 23, 2007Assignee: Nisshinbo Industries, Inc.Inventors: Kanako Yuyama, Ryutaro Nozu, Gen Masuda, Takaya Sato
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Patent number: 7167354Abstract: A mesoporous polymer and method of preparing a mesoporous polymer whose polymerization kinetics are dependent upon pH and whose pore size is controlled by pH and solvent concentration are disclosed. The polymer is optionally pyrolyzed to form a primarily carbonaceous solid. The material has an average pore size in the mesopore range and is suitable for use in liquid-phase surface limited applications including chromatographic, sorbent, catalytic, and electrical applications.Type: GrantFiled: February 12, 2002Date of Patent: January 23, 2007Assignee: TDA Research, Inc.Inventors: Steven Dietz, Vinh The Nguyen
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Patent number: 7163643Abstract: A driving electrolyte containing a solvent, a solute containing the following compounds represented by General Formulae (1) and (2) prepared by synthesis, and a nitro compound, (wherein, each of R1 and R2 is independently an alkyl group; each of M1 and M2 is a functional group selected from the group consisting of a hydrogen atom, an ammonium group and an amine group; and n is an integer of 0 to 14), (wherein, R3 is an alkyl group; R4 is a functional group selected from the group consisting of a hydrogen atom, a methyl group and an ethyl group; M3 is a functional group selected from the group consisting of a hydrogen atom, an ammonium group and an amine group; and m is an integer of 0 to 14).Type: GrantFiled: June 24, 2004Date of Patent: January 16, 2007Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Ryoko Takaoka, Kazumitsu Honda, Yuuichiro Tsubaki, Yukiyasu Sugihara
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Patent number: 7160615Abstract: An electrode sheet of an electric double layer capacitor is produced by using granules for formation of an electrode of an electric double layer capacitor which are obtained by kneading and then crushing materials including an activated material, a conductive filler, and a binder at 50 to 97 mass-%, 1 to 30 mass-%, and 2 to 20 mass-%, respectively, and which are essentially granules whose diameter is in a range of 47 to 840 ?m. A method for manufacturing a sheet-like electrode by mixing and kneading materials including an activated carbon, carbon black, and PTFE into a kneaded material, producing a forming material by converting the kneaded material into granules, and forming and rolling the forming material.Type: GrantFiled: November 26, 2003Date of Patent: January 9, 2007Assignees: Honda Motor Co., Ltd., Daido Metal Company Ltd.Inventors: Manabu Iwaida, Shigeki Oyama, Kenichi Murakami, Kouki Ozaki, Masanori Tsutsui
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Patent number: 7154738Abstract: A polarizing electrode for an electric double layer capacitor has good moldability and is capable of achieving higher density of electrode and higher capacity. An electric double layer capacitor employs the same. The polarizing electrode for an electric double layer capacitor is made of an activated carbon obtained by activating a hard-to-graphitize material (for example, phenol resin) with water vapor, and the activated carbon has a median particle size within a range from 4 ?m to 8 ?m in the particle size distribution as measured by a laser diffraction method and a benzene adsorption ratio of not less than 47.0% and not more than 60% by weight of activated carbon.Type: GrantFiled: November 26, 2003Date of Patent: December 26, 2006Assignees: Honda Motor Co., Ltd., Kuraray Chemical Co., Ltd.Inventors: Shigeki Oyama, Manabu Iwaida, Kenichi Murakami
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Patent number: 7120009Abstract: The capacitor element includes a chip body 2 prepared by compacting valve metal powder into a porous body and sintering the body, and an anode bar 3 fixed to the chip body so as to project from an end surface 2a of the chip body. A solid electrolyte layer 5 of conductive polymer is formed on the chip body via a dielectric film 4. A cathode film 6 is formed on the solid electrolyte layer. The solid electrolyte layer 5 formed at the end surface 2a of the chip body 2 includes carbide 5a formed by pyrolysis of the solid electrolyte layer to surround the entire circumference of the anode bar 3, so that damage is prevented from occurring at the root portion of the anode bar.Type: GrantFiled: September 15, 2005Date of Patent: October 10, 2006Assignee: Rohm Co., Ltd.Inventor: Kentarou Naka
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Patent number: 7116545Abstract: A long life double layer capacitor and method of making the same including a case and a first terminal with an electrically insulating hermitic seal interposed between the first terminal and the case. A first current collector foil is electrically coupled to an interior portion of the first terminal and a first electrode comprising carbon which is juxtaposed against the first current collector foil. A porous separator is then juxtaposed against the first electrode comprising carbon and separating the first electrode from a second electrode comprising carbon. A second current collector foil is juxtaposed against a side of the second electrode and is electrically coupled to the second terminal.Type: GrantFiled: March 9, 2005Date of Patent: October 3, 2006Assignee: Maxwell Technologies, Inc.Inventors: C. Joseph Farahmandi, John M. Dispennette, Edward Blank, Robert W. Crawford, Chenniah Nanjundiah
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Patent number: 7116546Abstract: This invention provides novel capacitors comprising nanofiber enhanced surface area substrates and structures comprising such capacitors, as well as methods and uses for such capacitors.Type: GrantFiled: January 12, 2006Date of Patent: October 3, 2006Assignee: Nanosys, Inc.Inventors: Calvin Y. H. Chow, Robert S. Dubrow
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Patent number: 7112389Abstract: Alkaline and lithium batteries are disclosed that advantageously include separators comprising at least one porous layer of fine fibers having a diameter of between about 50 nm and about 3000 nm that provide improved combinations of reduced thickness, dendritic barrier against short-circuiting and low ionic resistance as compared with known battery separators.Type: GrantFiled: September 30, 2005Date of Patent: September 26, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Pankaj Arora, Simon Frisk, Lu Zhang
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Patent number: 7110243Abstract: An electric double layer capacitor comprises a pair of polarizable electrodes impregnated with an electrolytic solution comprising an organic solvent and a supporting electrolyte dissolved in the organic solvent, and a gasket comprising a fluororesin. The organic solvent comprises propylene carbonate (PC), and the fluororesin for the gasket comprises a tetrafluoroethylene-perfluoroalkylvinylether copolymer (PFA).Type: GrantFiled: August 13, 2004Date of Patent: September 19, 2006Assignee: Sanyo Electric Co., Ltd.Inventors: Yohei Kawata, Hiroshi Nakajima
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Patent number: 7099142Abstract: The present invention provides additives for a non-aqueous electrolytic solution secondary cell and a non-aqueous electrolytic solution electric double layer capacitor comprising a phosphazene derivative represented by formula (1): (PNF2)n??formula (1) wherein n represents 3 to 14, and provides the non-aqueous electrolytic solution secondary cell and the non-aqueous electrolytic solution electric double layer capacitor each containing a non-aqueous electrolytic solution which has the additive for the non-aqueous electrolytic solution secondary cell or the additive for the non-aqueous electrolytic solution electric double layer capacitor and a supporting salt, an anode, and a cathode.Type: GrantFiled: September 5, 2001Date of Patent: August 29, 2006Assignee: Bridgestone CorporationInventors: Masashi Otsuki, Shigeki Endo, Takao Ogino
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Patent number: 7095603Abstract: An electrode for an energy storage device, including a substrate of at least one metal that forms a native oxide layer; and a treated layer formed on the substrate from the native oxide layer, the treated layer having a resistance that is less than the resistance of a native oxide layer. In some embodiments, the treated layer possesses at least one of the following properties: includes one or more dopants, is thinner than the native oxide layer, has a carbon coating that is applied to the treated layer which improved adhesion characteristics, and others. Further, there is an energy storage device having two or more of such electrodes, wherein the device has a low initial ESR and/or a low ESR at various intervals. Moreover, disclosed is a low resistance metal including a substrate of at least one metal that forms a native oxide layer; and a treated layer formed on the substrate from the native oxide layer, the treated layer having a resistance that is less than the resistance of a native oxide layer.Type: GrantFiled: December 30, 2002Date of Patent: August 22, 2006Assignee: Energy Storage Systems PTY LTDInventors: Peter John Mahon, Clodoveo Simone Sacchetta, Calum John Drummond, Phillip Brett Aitchison
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Patent number: 7088572Abstract: A polymer gel electrolyte includes an electrolyte solution composed of a plasticizer with at least two carbonate structures on the molecule and an electrolyte salt, in combination with a matrix polymer. Secondary batteries made with the polymer gel electrolyte can operate at a high capacitance and a high current, have a broad service temperature range and a high level of safety, and are thus particularly well-suited for use in such applications as lithium secondary cells and lithium ion secondary cells. Electrical double-layer capacitors made with the polymer gel electrolyte have a high output voltage, a large output current, a broad service temperature range and excellent safety.Type: GrantFiled: May 12, 2005Date of Patent: August 8, 2006Assignee: Nisshinbo Industries, Inc.Inventors: Hiroshi Yoshida, Kimiyo Hata, Tatsuya Maruo, Takaya Sato
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Patent number: 7085125Abstract: Electrical devices which incorporate electrodes coated with carbon nanotubes. An anode is placed in conductive relationship with the coated electrode. A gas or liquid medium is placed between the electrode and anode which medium also participates in the transfer of electrons. Using specific gas media in combination with nanotube coated electrodes allows for the production of electromagnetic radiation sources which have extended life, reduced power requirements, and significantly decreased operating temperatures. Likewise carbon nanotube coated electrodes can be advantageously utilized in fuel cells, electrodeposition, and similar applications greatly extending the life of electrodes and improving the electron emission properties.Type: GrantFiled: March 21, 2003Date of Patent: August 1, 2006Inventor: Chien-Min Sung
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Patent number: 7082027Abstract: A proton-conducting electric double layer capacitor comprising a electrolytic solution containing an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added.Type: GrantFiled: February 4, 2005Date of Patent: July 25, 2006Assignee: NEC Tokin CorporationInventors: Tomoki Nobuta, Toshihiko Nishiyama, Hiroyuki Kamisuki, Gaku Harada, Masato Kurosaki, Yuji Nakagawa, Shinako Kaneko, Masaya Mitani
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Patent number: 7057881Abstract: This invention provides novel capacitors comprising nanofiber enhanced surface area substrates and structures comprising such capacitors, as well as methods and uses for such capacitors.Type: GrantFiled: March 8, 2005Date of Patent: June 6, 2006Assignee: Nanosys, IncInventors: Calvin Y. H. Chow, Robert S. Dubrow
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Patent number: 7054139Abstract: A surface mount energy storage device in the form of a supercapacitor (1) includes a generally rectangular folded prismatic housing (2) and two energy storage elements (not shown) that are sealingly contained within the housing (2) and which are connected in series. A mount, in the form of an integrally formed tinned metal frame (3), extends about and captively retains housing (2) in the folded configuration shown. Two terminals, in the form of elongate contacts (4, 5) extend from the energy storage elements and terminate outside housing (2) for allowing external electrical connection to the elements.Type: GrantFiled: December 6, 2001Date of Patent: May 30, 2006Assignee: Energy Storage Systems PTY LTDInventors: David Albert James, Stephen Robert Wilson, Alina Kay Sloan, Richard Michael Stephens
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Patent number: 7046503Abstract: The present invention provides an electrode for an electric double layer capacitor which enhances an adhesive property between an electrode layer and an etched aluminum foil current collector. An electrode for a capacitor, includes a current collector, an undercoat layer on the current collector, and an electrode layer on the undercoat layer, wherein the current collector is made of an aluminum foil; the undercoat layer includes at least electrically conductive particles (P) and a binder (B) in a weight ratio P/B of 0.25 to 2.33, and the binder (B) includes a fluorine-containing polymer as a main component; and the electrode layer includes at least a carbon material and a binder.Type: GrantFiled: December 21, 2004Date of Patent: May 16, 2006Assignee: TDK CorporationInventors: Kiyonori Hinoki, Yousuke Miyaki, Kazuo Katai, Katsuo Naoi, Eiji Horigome, Yuukichi Morita
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Patent number: 7002790Abstract: A capacitor in an implantable medical device is provided. The capacitor having an anode, a cathode including a conductive coating, and an electrolyte disposed and in contact between the anode and the cathode. The conductive coating is composed of a chemisorbed conductive layer that is interposed between a metal substrate and a layer including a mix of activated carbon with a metal-oxide and electrolyte disposed and in contact between the anode and the cathode.Type: GrantFiled: September 30, 2002Date of Patent: February 21, 2006Assignee: Medtronic, Inc.Inventors: Joachim Hossick-Schott, John D. Norton, Craig L. Schmidt
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Patent number: 6980415Abstract: An electrolyte for an electrical double layer capacitor and an electrical double layer capacitor using the electrolyte are disclosed. The electrolyte has a low coefficient of viscosity, high conductivity, and high withstand voltage, and excels in long term reliability. The electrolyte for an electrical double-layer capacitor comprises a dimethyl carbonate and a compound of the following formula (1), wherein, m and n individually represent a natural number of 3-7, and X is a counter anion.Type: GrantFiled: March 29, 2005Date of Patent: December 27, 2005Assignees: Honda Motor Co., Ltd., Japan Carlit Co., Ltd.Inventors: Takashi Higono, Kenji Sato, Noriko Suga, Kazumi Chiba, Teruaki Kamei
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Patent number: 6970343Abstract: An aluminum electrolytic capacitor produced by winding an anode foil 11 and a cathode foil 12 via a separator 13 impregnated with a driving electrolyte solution 14, wherein the driving electrolyte solution 14 comprises a polar solvent, at least one electrolyte selected from inorganic acids, organic acids, inorganic acid salts, and organic acid salts, and a random copolymer of polyoxyethylene and polyoxypropylene having a hydroxy group at one end and a hydrogen group at the other end and the separator 13 is formed by overlaying a cellulosic fiber-mixed paper, a cellulosic fiber paper, and a cotton linter. The present invention provides a long-lasting driving electrolyte solution higher in electric conductivity and superior in the chemical self-restoring ability and heat resistance at high temperature, and an aluminum electrolytic capacitor using the same.Type: GrantFiled: March 3, 2005Date of Patent: November 29, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kazunari Hayashi, Ryoko Takaoka, Hisao Nagara, Kazumitsu Honda, Yoshihiro Watanabe
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Patent number: 6942819Abstract: An electrolyte for use with an aluminum electrolyte capacitor includes a glycol/boric acid/borate compound, traces of water, and an inhibitor to suppress corrosion of an aluminum oxide coating of the capacitor. The inhibitor contains a weak organic acid and at least one acid group selected from among carboxylic acid, sulfonic acid, phosphonic acid, and an acidic derivative of carboxylic acid, sulfonic acid, and phosphonic acid.Type: GrantFiled: March 23, 2001Date of Patent: September 13, 2005Assignee: Epcos AGInventors: Thomas Ebel, Frank Stippich, Jürgen Behm, Olaf Magnussen, Stefan Lauterborn
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Patent number: 6939774Abstract: An electrolytic capacitor comprising an anode, cathode and an electrolyte. The electrolyte comprises: about 35-60%, by weight water; about 10-55%, by weight organic solvent; about 0.05 to 10%, by weight, sulphuric acid; about 0.05 to 10%, by weight, boric acid; and about 0.05 to 10%, by weight, phosphorus oxy acid.Type: GrantFiled: April 16, 2004Date of Patent: September 6, 2005Assignees: Kemet Electronics, Medtronics, Inc.Inventors: Mark Edward Viste, Joachim Hossick-Schott, Zhi Fang, Brian John Melody, John Tony Kinard
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Patent number: 6937460Abstract: The invention relates to a double layer capacitor comprising: at least a pair of current collector plates that are placed in parallel to each other, flat electrodes containing aqueous electrolyte printed on opposing faces of said current collectors, such that a peripheral region is defined on each of said faces of said current collectors, which region is not covered by said electrode, and a separator interposed between said electrodes, the geometric form and size of said separator being identical to the form and size of said current collector plates, said separator having a central region permeable to said electrolyte, surrounded by a peripheral masked region which is non-permeable to said electrolyte, such that the permeable region of said separator coincide with the electrodes printed on the opposing faces of said current collectors, with respect to position, geometric form and size; wherein the pores in the peripheral region of the separator are impregnated with a suitable sealant, and wherein one or moreType: GrantFiled: August 9, 2004Date of Patent: August 30, 2005Assignee: Cellergy Ltd.Inventor: Joel Lang
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Patent number: 6927967Abstract: Electrolytic capacitor powder substrates are provided of refractory metal nitrides to reduce instability at a substrate-oxide (as formed) interface whereby the resultant capacitor sensitivity to hear, bias and frequency is reduced.Type: GrantFiled: December 17, 2002Date of Patent: August 9, 2005Assignee: H. C. Starck Inc.Inventor: Terrance B. Tripp