Chemical Fluids Patents (Class 365/107)
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Patent number: 11565465Abstract: A method for manufacturing a three-dimensional shaped object includes an nth layer forming step, an n+1th layer forming step, and a curing step. In the nth layer forming step, a cured portion of an nth layer, a first and second portions each of which is an uncured portion of the material are formed. In the n+1th layer forming step, a cured portion of an n+1th layer, and a third portion formed at a region adjacent to the cured portion of the n+1th layer and communicated with the first portion are formed. In the curing step, the second portion is cured prior to the n+1th layer forming step and the first and third portions are cured after the n+1th layer forming step, or the first, second and third portions are cured after the n+1th layer forming step.Type: GrantFiled: November 27, 2018Date of Patent: January 31, 2023Assignee: CANON KABUSHIKI KAISHAInventor: Naoari Shibata
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Patent number: 11484969Abstract: A method of making a three-dimensional structure including substructures is provided. The method includes directing laser light from a microscope objective through a photopolymerizable material to form a plurality of substructures each having at least one vertical wall directly attached to a vertical wall of an adjacent substructure. The substructures are individually formed in a sequence such that any second substructure that is formed in a location vertically disposed between the microscope objective and a first substructure has a wall that extends horizontally a shorter distance than a wall of the first substructure if a third substructure will subsequently be formed directly attached to the wall of the first substructure. The method is useful for minimizing passing laser light through a portion of an already formed substructure during formation of the three-dimensional structure.Type: GrantFiled: August 11, 2020Date of Patent: November 1, 2022Assignee: 3M Innovative Properties CompanyInventor: Jeremy K. Larsen
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Patent number: 11485080Abstract: A system and method for providing centrifuge-based additive object manufacturing includes a rotating drum containing a photopolymer material that solidifies when irradiated by a light source, the photopolymer material spreads evenly over an item being manufactured when the rotating drum is in motion, a light source module emitting a light capable of solidifying the photopolymer material, a set of platform actuator elements coupled to a plurality of perforated platforms for controlling a position of the plurality of perforated platforms within the rotating drum while in operation, and a photopolymer material delivery system for adding a controlled amount of the photopolymer material into the rotating drum. The light source module moves inside the rotating drum and selectively emits its light solidifying the part of the layer above the plurality of perforated platforms in the areas crossing the object currently being manufactured.Type: GrantFiled: November 16, 2020Date of Patent: November 1, 2022Inventor: Anton Zavoyskikh
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Patent number: 10896722Abstract: Some embodiments include an integrated assembly having first memory cells in a first array and second memory cells in a second array. First and second digit lines extend along columns of the first and second arrays, respectively. The first digit lines are comparatively coupled with the second digit lines through sense-amplifier-circuitry. The sense-amplifier-circuitry is distributed amongst at least two patch locations. A first of the patch locations has a first portion of the sense-amplifier-circuitry and has a first local column-select-structure. A second of the patch locations has a second portion of the sense-amplifier-circuitry and has a second local column-select-structure. A column-select-bus extends from decoder-circuitry to the first and second local column-select-structures. The column-select-bus is selectively coupled to the first and second local column-select-structures through first and second switches, respectively.Type: GrantFiled: November 15, 2019Date of Patent: January 19, 2021Assignee: Micron Technology, Inc.Inventors: Jiyun Li, Charles L. Ingalls
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Patent number: 9934855Abstract: A retainer node circuit is provided that can retain state information of a volatile circuit element (e.g., a flip-flop, latch, switch, register, etc.) of an electronic device for planned or unplanned power-down events. The retainer node circuit can include a resistive-switching memory cell that is nonvolatile, having very fast read and write performance. Coupled with power management circuitry, the retainer node circuit can be activated to receive and store a signal (e.g., bit) output by the volatile circuit element, and activated to output the stored signal. Various embodiments disclose non-volatile retention of state information for planned shut-down events as well as unplanned shut-down events. With read and write speeds in the tens of nanoseconds, sleep mode can be provided for volatile circuit elements between clock cycles of longer time-frame applications, enabling intermittent power-down events between active periods. This enables reduction in power without loss of activity for an electronic device.Type: GrantFiled: February 2, 2016Date of Patent: April 3, 2018Assignee: CROSSBAR, INC.Inventors: Mehdi Asnaashari, Hagop Nazarian
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Patent number: 8743599Abstract: A memory chip and methods of fabricating a memory device with different programming performance and retention characteristics on a single wafer. One method includes depositing a first bounded area of phase change material on the wafer and depositing a second bounded area of phase change material on the wafer. The method includes modifying the chemical composition of a switching volume of the first bounded area of phase change material. The method includes forming a first memory cell in the first bounded area of phase change material with a modified switching volume of phase change material and a second memory cell in the second bounded area of phase change material with an unmodified switching volume of phase change material such that the first memory cell has a first retention property and the second memory cell has a second retention property. The first retention property is different from the second retention property.Type: GrantFiled: March 15, 2012Date of Patent: June 3, 2014Assignee: International Business Machines CorporationInventors: Matthew J. BrightSky, Roger W. Cheek, Ming-Hsiu Lee
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Patent number: 8022384Abstract: A microelectronic programmable structure suitable for storing information and array including the structure and methods of forming and programming the structure are disclosed. The programmable structure generally includes an ion conductor and a plurality of electrodes. Electrical properties of the structure may be altered by applying energy to the structure, and thus information may be stored using the structure.Type: GrantFiled: May 29, 2009Date of Patent: September 20, 2011Assignee: Axon Technologies CorporationInventor: Michael N Kozicki
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Patent number: 7652907Abstract: A memory device including a stack of layers. At least one first active layer is based on a crystalline ionic and electronic conducting material capable of releasing and/or accepting at least one ionic species. At least one second active layer is based on a crystalline ionic and electronic conducting material capable of releasing and/or accepting the ionic species. The first active layer and the second active layer are based on a material that has a high potential variation for a low variation in the concentration of the ionic species. At least one layer forms an electrolyte between the first active layer and the second active layer, and is based on at least one ionic conducting and electronic insulating material. A measurement instrument is provided for measuring the electrochemical potential difference between the first active layer and the second active layer.Type: GrantFiled: August 21, 2007Date of Patent: January 26, 2010Assignee: Commissariat A l'Energie AtomiqueInventors: Didier Bloch, Frederic Le Cras
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Patent number: 7471581Abstract: A high speed voltage mode sensing is provided for a digital multibit non-volatile memory integrated system. An embodiment has a local source follower stage followed by a high speed common source stage. Another embodiment has a local source follower stage followed by a high speed source follower stage. Another embodiment has a common source stage followed by a source follower. An auto zeroing scheme is used. A capacitor sensing scheme is used. Multilevel parallel operation is described.Type: GrantFiled: March 22, 2007Date of Patent: December 30, 2008Assignee: Silicon Storage Technology, Inc.Inventors: Hieu Van Tran, Sakhawat M. Khan
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Patent number: 7317628Abstract: A sense amplifier circuit with faster sensing speed and improved insensitivities to fabrication process variations (i.e., eliminated functional failures) is provided herein. According to one embodiment, the sense amplifier circuit associated with a row of memory cells within a memory device may include a charging portion, which is coupled for receiving a reference voltage that is supplied to at least one additional sense amplifier circuit within the memory device. The reference voltage is provided by a current reference generator, which is coupled to the sense amplifier circuit(s) for detecting: (i) a maximum amount of current that can pass through one compare stack within the memory cell array, or (ii) a difference between the maximum amount of current and the current contribution of an n-channel current source within the sense amplifier circuit. A memory device and method of operating one embodiment of the improved sense amplifier circuit are also provided herein.Type: GrantFiled: October 24, 2005Date of Patent: January 8, 2008Assignee: NetLogic Microsystems, Inc.Inventor: Anita X. Meng
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Patent number: 7236388Abstract: A variable resistance element is configured to be provided with a perovskite-type oxide between a first electrode and a second electrode, of which electric resistance between the first electrode and the second electrode is changed by applying a voltage pulse of a predetermined polarity between the first electrode and the second electrode, and the variable resistance element has a resistance hysteresis characteristic, in which a changing rate of a resistance value is changed from positive to negative with respect to increase of a cumulative pulse applying time in the application of the voltage pulse. The voltage pulse is applied to the variable resistance element so that the cumulative pulse applying time is not longer than a specific cumulative pulse applying time, in which the changing rate of the, resistance value is changed from positive to negative with respect to increase of the cumulative pulse applying time in the resistance hysteresis characteristic.Type: GrantFiled: June 28, 2005Date of Patent: June 26, 2007Assignee: Sharp Kabushiki KaishaInventors: Yasunari Hosoi, Yukio Tamai, Kazuya Ishihara, Shinji Kobayashi, Nobuyoshi Awaya
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Patent number: 7233537Abstract: Normal memory cells and dummy cells are arranged continuously in a memory array. In a data read operation, first and second data lines are connected to the selected memory cell and the dummy cell, respectively, and are supplied with operation currents of a differential amplifier. An offset corresponding to a voltage difference between first and second offset control voltages applied from voltage generating circuits are provided between passing currents of the first and second data lines, and a reference current passing through the dummy cell is set to a level intermediate between two kinds of levels corresponding to storage data of a data read current passing through the selected memory cell.Type: GrantFiled: October 1, 2002Date of Patent: June 19, 2007Assignees: Renesas Technology Corp., Mitsubishi Electric Engineering Company LimitedInventors: Hiroaki Tanizaki, Hideto Hidaka, Takaharu Tsuji, Tsukasa Ooishi
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Patent number: 7227169Abstract: Programmable surface control devices whose physical features, such as surface characteristics and mass distribution, are controlled by the presence or absence of an electrodeposition of metal and/or metal ions from a solid solution upon application of a suitable electric field.Type: GrantFiled: October 28, 2002Date of Patent: June 5, 2007Assignee: Arizona Board of RegentsInventor: Michael N. Kozicki
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Patent number: 6994947Abstract: A photochemical hole burning medium is composed of a material in which a rare earth complex and a reducing agent is dispersed in a solid matrix. The rare earth complex may be at least one complex selected from the group consisting of a europium (III) crown ether complex, a europium (III) polyether complex, and a europium (III) cryptand complex.Type: GrantFiled: February 28, 2002Date of Patent: February 7, 2006Assignee: Osaka UniversityInventor: Kenichi Machida
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Patent number: 6867408Abstract: A method of erasable/rewritable optical data storage is provided in which a laser beam from a laser (10) operated in either a pulsed or continuous wave mode is focussed by an optical system (11-18) onto a photorefractive polymeric material (32) to cause two photon excitation of the material to record data which may subsequently be erased by illuminating the material with radiation having a wavelength in the ultraviolet or visible spectrum to erase the recorded data. New photorefractive polymeric materials having a relatively narrow absorption band for use in the method are also disclosed.Type: GrantFiled: February 16, 2000Date of Patent: March 15, 2005Assignee: Victoria University of TechnologyInventors: Min Gu, Daniel J Day, Andrew J. Smallridge
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Patent number: 6865117Abstract: A circuit for programming a microelectronic device is disclosed. The circuit is configured to provide a reversible bias across the microelectronic device to perform erase and write functions. One configuration of the programming circuit includes one or more inputs coupled to the programmable device and a complimentary metal-oxide semiconductor circuit coupled to the programmable device. This design allows for writing and erasing of the programmable cell using a low and high voltage input.Type: GrantFiled: January 2, 2003Date of Patent: March 8, 2005Assignee: Axon Technologies CorporationInventor: Michael N. Kozicki
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Patent number: 6280904Abstract: The present invention relates to the field of optical recording materials, in particular, fluorescent compounds and matrices suitable for use in optical memory systems, including three dimensional optical memory systems for READ ONLY MEMORY (ROM). In particular, nonfluorescent Rhodamine B lactams are photochemically transformed into fluorescent Rhodamine B derivatives.Type: GrantFiled: February 17, 2000Date of Patent: August 28, 2001Assignee: Tridstore IP, LLCInventors: Natalia T. Sokoluk, Vladimir V. Shubin, Eugene B. Levich, Jacob N. Malkin
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Patent number: 6027855Abstract: The present invention relates to the field of optical recording materials, in particular, fluorescent compounds and matrices suitable for use in optical memory systems, including three dimensional optical memory systems for READ ONLY MEMORY (ROM). In particular, nonfluorescent Rhodamine B lactams are photochemically transformed into fluorescent Rhodamine B derivatives.Type: GrantFiled: December 12, 1997Date of Patent: February 22, 2000Assignee: OMD Devices LLCInventors: Natalia T. Sokoluk, Vladimir V. Shubin, Eugene B. Levich, Jacob N. Malkin
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Patent number: 5914893Abstract: A programmable metallization cell ("PMC") comprises a fast ion conductor such as a chalcogenide-metal ion and a plurality of electrodes (e.g., an anode and a cathode) disposed at the surface of the fast ion conductor and spaced a set distance apart from each other. Preferably, the fast ion conductor comprises a chalcogenide with Group IB or Group IIB metals, the anode comprises silver, and the cathode comprises aluminum or other conductor. When a voltage is applied to the anode and the cathode, a non-volatile metal dendrite grows from the cathode along the surface of the fast ion conductor towards the anode. The growth rate of the dendrite is a function of the applied voltage and time. The growth of the dendrite may be stopped by removing the voltage and the dendrite may be retracted by reversing the voltage polarity at the anode and cathode. Changes in the length of the dendrite affect the resistance and capacitance of the PMC.Type: GrantFiled: January 7, 1998Date of Patent: June 22, 1999Assignees: Axon Technologies Corporation, Arizona Board of RegentsInventors: Michael N. Kozicki, William C. West
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Patent number: 5814265Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 6, 1995Date of Patent: September 29, 1998Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5761115Abstract: A programmable metallization cell ("PMC") comprises a fast ion conductor such as a chalcogenide-metal ion and a plurality of electrodes (e.g., an anode and a cathode) disposed at the surface of the fast ion conductor and spaced a set distance apart from each other. Preferably, the fast ion conductor comprises a chalcogenide with Group IB or Group IIB metals, the anode comprises silver, and the cathode comprises aluminum or other conductor. When a voltage is applied to the anode and the cathode, a non-volatile metal dendrite grows from the cathode along the surface of the fast ion conductor towards the anode. The growth rate of the dendrite is a function of the applied voltage and time. The growth of the dendrite may be stopped by removing the voltage and the dendrite may be retracted by reversing the voltage polarity at the anode and cathode. Changes in the length of the dendrite affect the resistance and capacitance of the PMC.Type: GrantFiled: May 30, 1996Date of Patent: June 2, 1998Assignees: Axon Technologies Corporation, Arizona Board of RegentsInventors: Michael N. Kozicki, William C. West
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Patent number: 5609813Abstract: An improved method for stereolithographically making an object by alternating the order in which similar sets of vectors are exposed over two or more layers. In another method, a pattern of tightly packed hexagonal tiles are drawn. Each tile is isolated from its neighboring tiles by specifying breaks of unexposed material between the tiles. Using an interrupted scan method, vectors are drawn with periodic breaks along their lengths. In another method, modulator and scanning techniques are used to reduce exposure problems associated with the acceleration and deceleration of the scanning system when jumping between vectors or changing scanning directions.Type: GrantFiled: June 7, 1995Date of Patent: March 11, 1997Assignee: 3D Systems, Inc.Inventors: Joseph W. Allison, Dennis R. Smalley, Charles W. Hull, Paul F. Jacobs
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Patent number: 5609812Abstract: An improved method for stereolithographically making an object by alternating the order in which similar sets of vectors are exposed over two or more layers. In another method, a pattern of tightly packed hexagonal tiles are drawn. Each tile is isolated from its neighboring tiles by specifying breaks of unexposed material between the tiles. Using an interrupted scan method, vectors are drawn with periodic breaks along their lengths. In another method, modulator and scanning techniques are used to reduce exposure problems associated with the acceleration and deceleration of the scanning system when jumping between vectors or changing scanning directions.Type: GrantFiled: September 14, 1993Date of Patent: March 11, 1997Assignee: 3D Systems, Inc.Inventors: Craig M. Childers, Charles W. Hull
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Patent number: 5597520Abstract: A method and apparatus for making high resolution objects by stereolithography utilizing low resolution materials which are limited by their inability to form unsupported structures of desired thinness and/or their inability to form coatings of desired thinness. Data manipulation techniques, based on layer comparisons, are used to control exposure in order to delay solidification of the material on at least portions of at least some cross-sections until higher layers of material are deposited so as to allow down-facing features of the object to be located at a depth in the building material which is equal to or exceeds a minimum cure depth that can effectively be used for solidifying these features. Similar data manipulations are used to ensure minimum reliable coating thicknesses exist, above previously solidified material, before attempting solidification of a next layer. In addition, horizontal comparison techniques are used to provide enhanced cross-sectional data for use in forming the object.Type: GrantFiled: April 25, 1994Date of Patent: January 28, 1997Inventors: Dennis R. Smalley, Thomas J. Vorgitch, Chris R. Manners, Charles W. Hull, Stacie L. VanDorin
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Patent number: 5573722Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 7, 1995Date of Patent: November 12, 1996Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5573721Abstract: A system is provided for producing a three dimensional object from a reactive liquid medium capable of being solidified. The object is constructed from many successive layers of the solidified reactive liquid medium when subjected to appropriate synergistic stimulation. A reservoir contains both the reactive liquid medium and an underlying supporting, substantially immiscible, non-reactive liquid medium. To begin forming the object, a platform within the reservoir is initially positioned at a depth equal to the thickness of a first layer to be solidified, and continues to support the object being constructed. The synergistic source radiates toward the reactive liquid medium and imaging apparatus defining a three dimensional object of required configuration selectively controls the size and shape of that part of a new two dimensional layer to be solidified. At least part of the new layer is solidified, after which a further layer is applied.Type: GrantFiled: February 16, 1995Date of Patent: November 12, 1996Assignee: Hercules IncorporatedInventor: Paul C. Gillette
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Patent number: 5571471Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 5, 1995Date of Patent: November 5, 1996Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5569431Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 7, 1995Date of Patent: October 29, 1996Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5556590Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminas, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 7, 1995Date of Patent: September 17, 1996Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5554336Abstract: A system for generating three-dimensional objects by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: June 5, 1995Date of Patent: September 10, 1996Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5500069Abstract: A three-dimensional object-forming method for forming an object of a three-dimensional shape with photosetting resin, includes the following steps. The desired three-dimensional shape is represented by a set of data related to sectional shapes of the three-dimensional shape cut at predetermined intervals distance of. The laser light is scanned, from above a tank containing liquid of photosetting resin not yet hardened, outward around a predetermined point of each sectional shape in a manner to trace similar figures to an arbitrary shape, to thereby to set a surface of a resin layer in a shape corresponding to one sectional shape. The set resin layer is sunk into the liquid of the photosetting resin not yet hardened by a distance of a cross section. A plurality of the set resin layers of the photosetting resin is laminated by repeating the scanning and sinking steps on the basis of the set of data.Type: GrantFiled: April 14, 1994Date of Patent: March 19, 1996Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Yousuke Ogue, Takahiro Kuyama, Kazuyuki Kaino
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Patent number: 5386310Abstract: A parallel optical switching apparatus wherein at least one m-channel light emission element array and one n-channel light receiving element array are optically connected via an m.times.n optical conversion element array and the optical conversion element array has an optical amplification function by inductive discharge of input light for each element and performs optical arithmetic or optical conversion in parallel for input light from the light emission element array by the amplification and modulation function.Type: GrantFiled: December 3, 1992Date of Patent: January 31, 1995Assignee: Hitachi, Ltd.Inventors: Makoto Haneda, Yuuichi Ono, Katuaki Chiba
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Patent number: 5273691Abstract: An improved stereolithography system for generating a three-dimensional object by creating a cross-sectional pattern of the object to formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, information defining the object being structurally specified to reduce curl, stress and distortion in the ultimately formed object, the successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: April 14, 1992Date of Patent: December 28, 1993Assignee: 3D Systems, Inc.Inventors: Charles W. Hull, Stuart T. Spence, Charles W. Lewis, Wayne Vinson, Raymond S. Freed, Dennis R. Smalley
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Patent number: 5270965Abstract: A method of driving a device having a pair of electrodes and organic insulating layer sandwiched therebetween. The device exhibits at least three states of different electroconductivities in response to an applied voltage. A transition from the first state to the second state is achieved by applying a voltage within a first predetermined range to the device in the first state, and a transition from the second state to the third state is achieved by applying a voltage within a second predetermined range to the device in the second state.Type: GrantFiled: May 10, 1993Date of Patent: December 14, 1993Assignee: Canon Kabushiki KaishaInventors: Yoshihiro Yanagisawa, Hisaaki Kawade, Kunihiro Sakai, Hiroshi Matsuda, Haruki Kawada, Kiyoshi Takimoto, Yuko Morikawa, Ken Eguchi
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Patent number: 5258146Abstract: Improved apparatus and methods for forming a layer of material over a surface of a previously-formed cross-section of a three-dimensional object in anticipation of forming a next cross-section of the object out of the layer. A volume of material, including at least some excess material, is placed over the surface, and the excess material is swept off by placing the excess material in the predetermined path of a sweeping member, the path being substantially in a plane spaced from a working surface of material. The member may be directed to sweep the excess material away through a successive number of sweeps, which may vary for each cross-section, at least a velocity which may vary for each sweep. Additionally, the clearance between the member and the surface of the previous cross-section may vary for each sweep. A "winged" member is also provided, comprising two legs extending from a base, and a "Trident" embodiment is also provided, comprising three legs extending from a base.Type: GrantFiled: May 6, 1992Date of Patent: November 2, 1993Assignee: 3D Systems, Inc.Inventors: Thomas A. Almquist, Borzo Modrek, Paul F. Jacobs, Charles W. Lewis, Mark A. Lewis, Abraham Liran, Adam L. Cohen, Dennis R. Smalley
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Patent number: 5256340Abstract: An improved method for stereolithographically forming a three-dimensional object wherein ordinarily solidified internal walls of the object remain at least partially unsolidified. Any unsolidified medium within the object can be drained from the internal walls of the object prior to post-curing so that a hollow three-dimensional object is formed. The object is formed on a layer by layer basis with the internal portion of each layer of the object formed as a grid of solidified portions and unsolidified portions wherein the solidified and unsolidified portions are different on each layer. Objects formed in this manner can be used as patterns in investment casting.Type: GrantFiled: June 25, 1992Date of Patent: October 26, 1993Assignee: 3D Systems, Inc.Inventors: Joseph W. Allison, Jan Richter, Craig M. Childers, Dennis R. Smalley, Charles W. Hull, Paul F. Jacobs
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Patent number: 5238639Abstract: A method and apparatus for eliminating or substantially reducing curling effects in stereolithographically formed objects. Synergistic stimulation is applied to a curable material to form a three dimensional object through the build up of successive layers. Curling between successive layers is eliminated or substantially reduced by curing a balancing layer in relation to a balanced layer such that reverse curl of the balanced layer caused by the balancing layer offsets or negates normal curl of the balanced layer caused by the balancing layer.Type: GrantFiled: August 31, 1992Date of Patent: August 24, 1993Assignee: 3D Systems, Inc.Inventors: Wayne A. Vinson, Joseph W. Allison, Paul F. Jacobs, Dennis R. Smalley
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Patent number: 5236637Abstract: A stereolithographic system for automatically generating three-dimensional objects on a layer by layer basis by alternately forming layers of medium over previously formed layers of the object and selectively solidifying successive layers of medium at a surface of a body of the medium whereby the object is formed from a plurality of solidified and adhered layers. The surface of the body of medium is maintained at a desired working surface, for example by detecting its level and relatively adjusting it and the working surface so that they coincide.Type: GrantFiled: February 21, 1992Date of Patent: August 17, 1993Assignee: 3D Systems, Inc.Inventor: Charles W. Hull
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Patent number: 5209878Abstract: Methods and apparatus for reducing surface discontinuities, resulting from the formation of a three-dimensional object out of a plurality of stacked layers, during layer by layer stereolithographic formation of the three-dimensional object. The discontinuities between layers are reduced by utilizing formation and solidification of thin fill layers near the edges of thicker structural layers or by utilizing surface tension effects to smooth discontinuities between the structural layers by formation of meniscuses of building material and solidifying the meniscuses.Type: GrantFiled: October 30, 1990Date of Patent: May 11, 1993Assignee: 3D Systems, Inc.Inventors: Dennis R. Smalley, Hop D. Nguyen, Kris A. Schmidt, Herbert E. Evans, Ray S. Freed, Paul J. Jacobs
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Patent number: 5198159Abstract: A process of fabricating a three-dimensional object from a light curable liquid resin includes irradiating a light to a surface of the light curable liquid resin so as to form successive cross-sectional layers of the cured resin at that surface and to superimpose the successive layers on each other. An improvement resides in that one or more of the successive layers is made to have different portions made through different curing conditions. By providing such cross-sectional layers having different curing conditions, the resulting three-dimensional object can be made into accurate outer configuration without leaving any critical residual stress therein.Type: GrantFiled: October 9, 1990Date of Patent: March 30, 1993Assignee: Matsushita Electric Works, Ltd.Inventors: Yoshimitsu Nakamura, Teruyoshi Kuribayashi, Yoshiyuki Utinono, Yoshikazu Higashi, Syungo Ozawa, Shinobu Ikeno
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Patent number: 5192469Abstract: A method and apparatus for making an object by stereolithography from layers of a medium solidifiable upon exposure to synergistic stimulation by selecting an area element of a first layer of medium. The depth of the medium within the object underlying the area element is determined and compared to the depth to the minimum solidification depth of the medium. The area element is exposed to solidifying synergistic stimulation only if the depth of the medium equals or exceeds the minimum solidification depth. A next layer is created over the first layer without exposing the first layer to solidifying synergistic stimulation, if the depth is less than the minimum solidification depth. The layers may have a thickness selected such that the minimum solidification depth is a integer multiple of the layer thickness.Type: GrantFiled: October 30, 1990Date of Patent: March 9, 1993Assignee: 3D Systems, Inc.Inventors: Dennis R. Smalley, Thomas J. Vorgitch
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Patent number: 5182055Abstract: An improved method for stereolithographically making an object by alternating the order in which similar sets of vectors are exposed over two or more layers. In another method, a pattern of tightly packed hexagonal tiles are drawn. Each tile is isolated from its neighboring tiles by specifying breaks of unexposed material between the tiles. Using an interrupted scan method, vectors are drawn with periodic breaks along their lengths. In another method, modulator and scanning techniques are used to reduce exposure problems associated with the acceleration and deceleration of the scanning system when jumping between vectors or changing scanning directions.Type: GrantFiled: May 17, 1991Date of Patent: January 26, 1993Assignee: 3D Systems, Inc.Inventors: Joseph W. Allison, Jan Richter, Craig M. Childers, Dennis R. Smalley, Charles W. Hull, Paul F. Jacobs
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Patent number: 5182056Abstract: An improved stereolithographic apparatus (SLA) and an improved method for generating a part from curable material. The invention utilizes control and/or knowledge of depths of penetration of actinic radiation into a vat of photopolymer to determine and/or control and/or produce desirable characteristics associated with the creation of parts. From a predictive point of view, these desirable characteristics may include determination of cure depth from a given exposure, determination cure width, determination of required minimum surface angle (MSA), determination of optimum skin fill spacing, the strength of cross sections of partially polymerized material, amount of curl type distortion, and necessary overcure to attain adhesion between layers, etc. These determinations can lead to the use of particular building techniques to insure adequate part formation.Type: GrantFiled: October 27, 1989Date of Patent: January 26, 1993Assignee: 3D Systems, Inc.Inventors: Stuart T. Spence, Dennis R. Smalley
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Patent number: 5174931Abstract: Apparatus and methods for stereolithographically forming a three-dimensional object includes a vessel for holding a building material and a smoothing member for forming a uniform coating over a previously formed layer of the object. The smoothing member has a plurality of blades. The smoothing member is swept over a previously formed layer of the object, in at least two directions. Different clearances between the lower surface of the smoothing member and the upper surface of the previously formed layer are used to provide a uniform coating for a subsequent layer over the previously formed layer. The sweeping velocity of the smoothing member can be varied. Retractable needles are attached to the smoothing member for adjusting a blade gap between the lower surface of the smoothing member and the surface of the building material.Type: GrantFiled: April 27, 1990Date of Patent: December 29, 1992Assignee: 3D Systems, Inc.Inventors: Thomas A. Almquist, Borzo Modrek, Paul F. Jacobs, Charles W. Lewis, Mark A. Lewis, Abraham Liran
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Patent number: 5137662Abstract: An improved stereolithography system for generating a three-dimensional object by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, information defining the object being specially processed to reduce curl and distortion, and increase resolution, strength, accuracy, speed and economy of reproduction even for rather difficult object shapes, the successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: May 2, 1991Date of Patent: August 11, 1992Assignee: 3-D Systems, Inc.Inventors: Charles W. Hull, Borzo Modrek, Brent Parker, Raymond S. Freed, Thomas Almquist, Stuart T. Spence, David J. Albert, Dennis R. Smalley, Richard A. Harlow, Phil Stinebaugh, Harry L. Tarnoff, Hop D. Nguyen, Charles W. Lewis, Tom J. Vorgitch, David Z. Remba, Wayne B. Vinson
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Patent number: 5130064Abstract: A stereolithographic method for constructing an object from a medium capable of solidification upon exposure to synergistic stimulation (e.g. a laser beam). Stacked layers of solidified medium are constructed by exposing the medium to synergistic stimulation in magnitude and pre-selected pattern, such that each layer is formed with external boundaries and up and down facing surfaces as necessary. At least a portion of a layer which is neither upfacing nor downfacing is also skinned, e.g., provided with a continuous skin formed by overlapping skin vectors or traces of the laser beam. Alternatively, all intermediate or internal cross-sectional layers are provided with skin and cross-hatch. Upfacing and downfacing features, and intermediate layers may be provided with a skin created by scanning in a first pass using non-consecutive skin vectors followed by scanning in at least one additional pass that completes the exposing process by filling in between the originally drawn vectors.Type: GrantFiled: October 30, 1989Date of Patent: July 14, 1992Assignee: 3D Systems, Inc.Inventors: Dennis R. Smalley, Charles W. Hull
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Patent number: 5104592Abstract: An improved sterolithography system for generating a three-dimensional object from object defining information, the information defining the object being structurally specified to reduce curl, stress and distortion in the ultimately formed object is described. A stereolithographic distortion known as curl is reduced by the system, and several techniques to eliminate or reduce curl are utilized by the system, including dashed line, bent line, secondary structure, rivets, and multi-pass techniques.Type: GrantFiled: April 17, 1989Date of Patent: April 14, 1992Assignee: 3D Systems, Inc.Inventors: Charles W. Hull, Stuart T. Spence, Charles W. Lewis, Wayne A. Vinson, Raymond S. Freed, Dennis R. Smalley
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Patent number: 5059359Abstract: An improved sterolithography system for generating a three-dimensional object by creating a cross-sectional pattern of the object to be formed at a selected surface of a fluid medium capable of altering its physical state in response to appropriate synergistic stimulation by impinging radiation, particle bombardment or chemical reaction, information defining the object being specially processed to reduce curl and distortion, and increase resolution, strength, accuracy, speed and economy of reproduction even for rather difficult object shapes, and successive adjacent laminae, representing corresponding successive adjacent cross-sections of the object, being automatically formed and integrated together to provide a step-wise laminar buildup of the desired object, whereby a three-dimensional object is formed and drawn from a substantially planar surface of the fluid medium during the forming process.Type: GrantFiled: April 18, 1988Date of Patent: October 22, 1991Assignee: 3 D Systems, Inc.Inventors: Charles W. Hull, Stuart T. Spence, David J. Albert, Dennis R. Smalley, Richard A. Harlow, Phil Steinbaugh, Harry L. Tarnoff, Hop D. Nguyen, Charles W. Lewis, Tom J. Vorgitch, David Z. Remba
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Patent number: 4972370Abstract: A three-dimensional memory element comprises a multilayer tunnel switch portion formed by alternately stacking conductive films and insulating films, both the ends of the switch portion consisting of insulating films, a write electrode formed on the insulating film as one end of the multilayer tunnel switch portion, a read electrode formed on the insulating film as the other end of the multilayer tunnel switch portion, and charge accumulating capacitors respectively connected to the conductive films of the multilayer tunnel switch portion.Type: GrantFiled: August 24, 1989Date of Patent: November 20, 1990Assignee: Olympus Optical Co., Ltd.Inventors: Masamichi Morimoto, Yoshiyuki Mimura, Yasuo Isono
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Patent number: 4896292Abstract: The invention relates to an apparatus for reversible optical data storage using polymeric liquid crystals with mesogenic side groups as a storage medium, arranged to store information by means of selective variation of the order of the polymeric liquid crystals be means of a heat source. The macroscopically oriented film made from the liquid crystal polymer is held in the solid form retaining condition of the liquid crystal polymer in the temperature range below the glass temperature T.sub.g >T.sub.a (room remperature) for the purpose of storing the information. The polymer is then selectively and locally heated by means of the heat source into the isotropic liquid condition and the local information is fixed in the glass condition of the polymer after the heat source is turned off.Type: GrantFiled: October 26, 1988Date of Patent: January 23, 1990Assignee: Rohm GMBH Chemische FabrikInventors: Manfred Eich, Joachim Wendorff