Abstract: The present invention describes a process utilized for the remediation of soils and petroleum drilling wastes contaminated with hydrocarbons, which consists in stabilization by application and mixing in specific proportions of calcium oxides and organic conditioners. It is possible to treat materials with concentrations of at least seven percent (dry weight) of hydrocarbons petroleum hydrocarbons (TPH) and reduce the concentration to 1-1.5% TPH. Furthermore, residual toxicity is completely eliminated in the treated material, vegetative growth is stimulated, the treated material does not present significant concentrations of hydrocarbons leachates and it passes all criteria to be considered not a dangerous waste (CRETI or TCLP).

Abstract: A soil remediation apparatus comprises: a trommel screen having an inlet and an outlet; a trommel screen housing, and air extraction means operable to extract contaminant vapors volatilized by the trommel screen during soil aeration from the housing and to contaminant remediation means, such as a biofilter. The trommel screen housing comprises: a trough in which the trommel screen is mounted with its inlet inclined upwards; a front cover mounted at the front of the trough and having an impacted soil inlet in communication with the trommel screen inlet; a rear cover mounted at the rear of the trough and having a vapor discharge outlet above the trommel screen and a treated soil outlet in communication with the trommel screen outlet, and a vapor cover frame at least partially removably mounted to the trough and a flexible vapor cover removably mounted over the frame.

Abstract: Methods of treating hazardous materials, such as, for example, contaminated soils, are disclosed. In one aspect, a method may include treating a contaminated soil with a hazardous material treatment composition to form a resulting material. In one aspect, the hazardous material treatment composition may include mostly salt, and from 0.5 to 15 wt % sorbent. The method may further include treating the resulting material with one or more inorganic binding agents. Other methods of treating hazardous materials are also disclosed, as well as compositions for treating hazardous materials.

Abstract: The present invention includes methods for investigating a site for possible selective removal of sediment containing a contaminant. The methods include calculating an adjusted contaminant concentration for sediment zones on the site. The site preferably contains a water course. The methods may also include determining whether sediment zone need remediation by comparing the adjusted contaminant concentration to a standard. The invention also includes a system for carrying out the described methods, at least partially implemented in a computer.

Abstract: A method and apparatus for converting spent water-based drilling mud into fertile indigenous top soil at a well site or location. The fertile indigenous top soil is produced by the steps of: admixing, at a well site, effective amounts of spent water-based drilling mud, mature compost, organic fertilizer, and top soil from the well site to provide a mixture containing spent water-based drilling mud, from about 30 to about 150 volume percent mature compost, from about 5 to 20 volume percent organic fertilizer, and from about 5 to 20 volume percent top soil from the well site wherein each of the volume percents is based on the volume of the spent water-based drilling mud present in the mixture; stirring the mixture for a period of time effective to form a substantially homogenous mixture; and drying the substantially homogenous mixture so as to provide fertile indigenous top soil possessing similar microbial and enzyme characteristics as the top soil at the well site.

Abstract: The invention disclosed relates to a method and apparatus for recovering non-aqueous phase liquids (NAPL) from regions below ground where NAPL spills are sources of aquifer contamination. The apparatus includes a system to supply gas-supersaturated liquid, a system of ground wells in fluid communication with the contaminated ground water region (source of contamination) and with an above-ground NAPL recovery system, said system of wells including an injection well in fluid communication with the system to supply gas-supersaturated liquid and with the contaminated region below ground, an extraction well in fluid communication with the contaminated region below ground and with the NAPL recovery system, wherein the NAPL is in the gaseous phase or gas-mobilized non-volatile liquid phase or both, and a pump for delivering the gas-supersaturated liquid to the vicinity of the contaminated region below ground.

Abstract: A method and apparatus for converting spent water-based drilling mud into fertile indigenous top soil at a well site or location. The fertile indigenous top soil is produced by the steps of: admixing, at a well site, effective amounts of spent water-based drilling mud, mature compost, organic fertilizer, and top soil from the well site to provide a mixture containing spent water-based drilling mud, from about 30 to about 150 volume percent mature compost, from about 5 to 20 volume percent organic fertilizer, and from about 5 to 20 volume percent top soil from the well site wherein each of the volume percents is based on the volume of the spent water-based drilling mud present in the mixture; stirring the mixture for a period of time effective to form a substantially homogenous mixture; and drying the substantially homogenous mixture so as to provide fertile indigenous top soil possessing similar microbial and enzyme characteristics as the top soil at the well site.

Abstract: Bioremediatory fungi, such as Trichoderma harzianum, which have been found to catabolise cyanide, are capable of detoxifying contaminated environmental areas in association with a suitable rhizosphere.

Abstract: An apparatus, system and method for removing and treating contaminated materials on a bottom of a body of water and introducing growth packets to revitalize the treated bottom of the body of water. The structure may comprise a vessel with an open face. The vessel may be lowered down to the bottom of the body of water with the face facing down. As a result, the vessel and the bottom form an isolated space. The structure may comprise at least one agitating device(s) for stirring up the materials inside the vessel so as to form a mixture containing the sediment materials which in turn contain the contaminants. Multiple at least one pipe(s) may be coupled to the vessel for transporting the mixture out of the vessel for processing (filtering, treating with chemicals, etc.) so as to neutralize or eliminate the contaminants in the mixture. Then, the treated mixture can be returned to the inside of the vessel via the at least one pipe(s).

Abstract: A method and system for improved environmental remediation. A method comprising establishing an initial remediation protocol; applying at least one initial motive force according to the initial remediation protocol; monitoring the effect on the site resulting from the application of the at least one initial motive force; modifying the remediation protocol to improve the performance of the remediation using information gleaned from the monitoring of the site; applying at least one motive force according to the modified remediation protocol; and repeating monitoring, modifying, and applying in a more or less continuous fashion until the remediation is complete.

Abstract: Stable dispersions of zero-valent iron particles are produced by milling of micro- and nano-scale iron particles (colloids) in the presence of a dispersant or dispersants.

Abstract: To overcome obstacles faced by current remediation technologies for contaminated sediments, the present invention provides a new strategy based on in situ control of hydrophobic organic contaminants (HOC) bioavailability. The strategy employs the addition of activated carbon sorbents to sediments. These activated carbon materials sorb HOC contaminants strongly, reduce release of HOCs into water, and reduce HOC uptake by benthic biota, thereby reducing environmental exposure and human health risk to such contaminants. By in situ sorbing the contaminants, the inventive approach reduces environmental exposure and avoids massive material removal while controlling food web transfer of HOCs including polychlorinated biphenyls (PCBs).

Abstract: A method of treatment of a contaminated material contaminated with an organic compound. The method includes treating the contaminate with a bioremediation step followed by a chemical oxidation step. The bioremediation step includes contacting the contaminate with a microbial consortium under conditions suitable for the consortium to mediate solubilization or biodegradation of the organic compound or chemical oxidation products thereof. The subsequent chemical oxidation step includes treating the bioremediated contaminate with: a transition metal in soluble form; a chelator of the transition metal, to form a transition metal:chelator complex; an oxidizing agent that provides a reactive free radical in the presence of the transition metal complex; and a buffering compound to maintain the pH in a neutral range. The reactive free radical initiates a chemical reaction with the organic compound to produce reaction products of the organic compound.

Abstract: An apparatus and method for treating contaminated groundwater in low permeability ground formations is provided having a groundwater intake region at the bottom of the well and a groundwater expulsion region above the bottom of the well and a means for moving the water therebetween.

Abstract: The present invention is a mobile, in situ applicator system and method for remediating contaminated soils at a site without the removal of those soils. The applicator system comprises a vehicle, preferably a chemical treatment vehicle used in the oil and gas industry, and fluid dispensing components comprising a tank, hose, and pump for the application to contaminated sites.

Abstract: An in situ method of reducing concentrations of contaminates in contaminated soil, where contaminated soil positioned in a first horizontal location is in situ mixed with clean soil in vertical proximity to the contaminated soil. The mixed soil is blended under conditions and for a time sufficient to substantially homogenize the contaminants in the blended soil. The mixing and blending is then repeated for a second horizontal location.

Abstract: In this invention, after the grade at a construction site has been excavated and/or graded to its preliminary rough grade, re-enforcing material, typically synthetic in nature, such as nylon or polypropylene mesh or rods, fiber-glass rods or mesh, or other specified re-enforcing material is laid across soil at the construction site and a reinforced base is formed by covering the reinforcing material with a polymeric resin, whereby upon curing, the polymeric resin and reinforcing material forms a contiguous thermo-structural base. Re-enforcement material comprising synthetic and/or non-synthetic components in the form of rods, rope, strapping, mesh, netting, geotextile fabrics or other dimensional forms laid longitudinally, or in a grid pattern, in single or multiple layers, tied or not tied all in situ sprayed with a high density closed cell, water resistant expanding two component polyurethane foam system.

Abstract: A soil aerating machine includes in combination a skid-steer and a basket resembling a loader bucket adapted for attachment to the skid-steer boom. An air pressure tank, an elongate air nozzle pipe, an air hammer, and air control valves for the air nozzle pipe and air hammer are carried within the basket. The elongate air nozzle is attached to the basket using a pivotal bearing surface, which permits controlled motion therebetween. The air hammer is used to assist with the driving of the elongate air nozzle pipe into an earthen medium. A blast of air is then released through the air nozzle pipe into the earth, to loosen and aerate packed or clogged soil. A method of restoring a septic system using the preferred apparatus is also described, as are various alternative apparatus and method steps.

Abstract: The invention relates to a method, composition and apparatus for stabilizing mercury and other heavy metals present in a particulate material such that the metals will not leach from the particulate material. The method generally involves the application of a metal reagent, a sulfur-containing compound, and the addition of oxygen to the particulate material, either through agitation, sparging or the addition of an oxygen-containing compound.

Abstract: A process for treating a solid-liquid mixture by cavitation to decompose at least some contaminant associated with the solid particles, the contaminant either being absorbed into the pores of the solid or onto the surface of the solid particles. The process includes the step of subjecting the mixture to cavitation such that a portion of the contaminant is chemically decomposed. Typically the chemical decomposition occurs at the surface of the solid particle. Typically the cavitation process is an ultrasonic treatment step, although other cavitation processes are applicable, for example high shear mixing. The cavitation effect is capable of achieving physico-chemical changes at the particle surfaces. The localized high temperatures on bubble collapse (as high as 5000K) can decompose contaminant substances such as PCB and other hazardous materials including polybrominated biphenyl PBB), organochloride and organophosphate compounds, pesticides and the like.

Abstract: The present invention relates to a method of preparing adsorbent particles formed from expanded plastics materials, said particles comprising cellular structures that are open at their surface, characterized in that a material constituted by agglomerated beads of said expanded material and having smooth surfaces is rasped into fine chips. The present invention also relates to adsorbent particles formed from an expanded plastics material comprising cellular structures that are open at their surface, characterized in that they are in the form of fine chips, preferably with a dimension of 0.8 mm to 4 mm, said open cellular structures represent more than 80% of the visible surface area of said chips. In a method of treating soil polluted with hydrocarbons, the following steps are carried out, in which: 1) said polluted soil is mixed with adsorbent particles according to the invention; and 2) said adsorbent particles charged with hydrocarbons are separated from the depolluted soil.

Abstract: A method and system for improved environmental remediation. A method comprising establishing an initial remediation protocol; applying at least one initial motive force according to the initial remediation protocol; monitoring the effect on the site resulting from the application of the at least one initial motive force; modifying the remediation protocol to improve the performance of the remediation using information gleaned from the monitoring of the site; applying at least one motive force according to the modified remediation protocol; and repeating monitoring, modifying, and applying in a more or less continuous fashion until the remediation is complete.

Abstract: Methods are provided for remediating contaminated soil. The methods may include collecting contaminated soil at a plurality of treatment sites. The contaminated soil at one or more of the plurality of treatment sites may be at least partially contained. Contaminated soil at the plurality of treatment sites may be treated with equipment in a central treatment facility. Treatment of the plurality of sites may be coordinated such that equipment in the central treatment facility operates substantially continuously as soil is delivered to, treated at, and removed from various treatment sites. The plurality of sites may be treated in a sequential manner, in which soil is delivered to one site, treated at a second site, and removed from a third site substantially simultaneously.

Abstract: A method for recombining and then solidifying groups of soil particles by utilizing changes in the status and properties of soil particles which comprises a combination (in an adhering state) between soil particles and groups polymers (humin) in an aqueous solution (solvent). By using specified solvents, the preliminary treatment of separating soil particles and polymers is initiated. Secondarily, each structure of groups of soil particles is observed microscopically as a metal complex, and the combining method is accomplished by utilizing substitution based on various reactions (i.e. SN, SE, and SEAr type reactions) along with electron transfer in a solvent made of specified solutes. The substitution includes the rock forming function through the substitution of the hydrogen atom within the hydroxyl group of clay minerals as molecular components and the dehydration and dissociation function resulted from the binding structure of oxygen molecule O−2 and Al+3 as components of aluminum oxide.

Abstract: A method of treatment of a contaminated material contaminated with an organic compound. The method includes treating the contaminate with a chemical oxidation step and a bioremediation step. The chemical oxidation step includes treating the contaminate with the following: a transition metal in soluble form in combination with an isolated chelator of the transition metal, to form a transition metal:chelator complex; an oxidizing agent that provides a reactive free radical in the presence of the transition metal complex; and a buffering compound; the pH being maintained in a neutral range. The method of treatment further includes treating the contaminate with a microbial consortium including at least two species prior to or after the chemical oxidation step to enhance the remediation process.

Abstract: A method for performing exploration of the vadose soil zone first obtains samples of the surface vegetation from a region, next the samples are analyzed to determine if a contaminant is present in any of the analyzed samples, and, finally, a determination is made if a vadose soil zone at that region is contaminated based on the analyzed samples. As a result of the contamination determination, further, more-detailed site characterization can be performed at only those regions that are contaminated.

Abstract: Apparatus suitable for venting and dispensing gas from an area of ground. The apparatus comprising a passage arrangement locatable in the ground extending generally horizontally and formed from a plurality of self-supporting open units. One or more columns extends downwardly from the passage, the columns being formed of a core material having an open permeable structure. The or each column has a fluid permeable exterior, and is in communication with the passage.

Abstract: A method of treatment of a contaminated material contaminated with an organic compound is provided. The method includes treating the contaminate with a chemical oxidation step. The chemical oxidation step includes treating the contaminate with a transition metal in soluble form in combination with a chelator of the transition metal, to form a transition metal:chelator complex; an oxidizing agent that provides a reactive free radical in the presence of the transition metal complex; and a buffering compound; the pH being maintained in a neutral range. The method of treatment may further include treating the contaminate with biodegradation step prior to or after the chemical oxidation step.

Abstract: An apparatus for high volume in-situ treatment of contaminated soil is a mobile vehicle with a chain trenching tool an excavator drums attached to the idler wheel to extend the width of soil cutting and increase the volume of soil being churned and treated in-situ. The drums may be arranged both for clock-wise and counter clock-wise rotation, and oriented to provide vertical lifting and swirling of the soil. The apparatus may include a hood disposed over the cutting drums to define a remediation chamber with ports for injecting high temperature air or chemical or biological remediation fluid into the soil. In a preferred embodiment, the hood has internal partitions that create a vapor recovery chamber outboard of the drums.

Abstract: A soil remediation system, such as an in situ thermal desorption system, may be used to treat contaminated soil in a treatment area with an arcuate obstruction in the treatment area. A pattern of wells may be positioned to avoid placing a well in a wall of the obstruction. The well pattern may be oriented based upon the center of the obstruction. A well of the well pattern may be placed at the center of the obstruction. Alternatively, the center of the obstruction may be positioned at a centroid of a unit of the well pattern, or at the midpoint of a side of a unit of the well pattern. The well pattern may be a regular pattern that is positioned so that the arcuate obstruction is placed within a large gap between adjacent orbitals (or rings) of the regular well pattern.

Abstract: A method is providing for treating waters, such as standing and flowing waters and waste waters, soils, sediments and/or silts. At least one alkaline earth metal peroxide is brought into contact with such waters or the like, especially to effect immobilization of phosphates and heavy metals except manganese and iron therein.

Abstract: A plurality of rows of wells are drilled in the soil of the area to be stabilized, and then pairs of electrodes, i.e., an aluminum anode and a copper-graphite cathode connected to a source of a bipolar pulse current, are inserted into each well in such a manner that during operation all anodes of odd wells are connected to a positive terminal (for odd pulses) of the source, while all cathodes of even wells are connected to a negative terminal (for odd pulses) of the source. After a certain period of treatment the anodes and cathodes are reversed so that all anode of even wells are connected to the positive terminals (for even pulses) of the source, whereas the cathodes of the odd wells are connected to the negative terminal of the source. Controlled directional structuring of the soil mass is carried out by adjusting the duration of current pulses, intervals between two sequential bipolar pulses of pulse current, and current density in the pulses.

Abstract: A laboratory technique for rapidly predicting the long-term hydrophobic organic contaminant (HOC) desorption behavior in a contaminated soil or sediment useful for planning remediation schemes and/or assessing alternative remediation endpoint decisions employs a superheated water extraction technique for rapid prediction of long-term HOC desorption. The proposed method has great practical significance because desorption at ambient temperatures requires months or years, while high temperature experiments are accomplished in hours or days.

Abstract: A method comprises conducting a permeable-reactive barrier (PRB) treatment of a contaminated aqueous medium and in-well monitoring effectiveness of the permeable-barrier treatment. A system comprises a PRB zone to treat a contaminated groundwater and an in-well sensor located within a gradient of the contaminated groundwater or within the PRB zone to sense a characteristic of the groundwater.

Abstract: A method of removing contaminated sediment material from a contaminated area on the ocean floor using a reactor vessel wherein seawater is from within the interior of the reactor vessel so that the vessel penetrates the ocean floor. A pressurized fluid is introduced into the reactor vessel to create a slurry vortex of the contaminated sediment material and then a remediation fluid injected into the slurry vortex of the contaminated sediment material using a sufficient amount of the remediation fluid to remediate the contaminated sediment material and provide a noncontaminated sediment material. Pressurized seawater is injected into the interior of the reactor vessel to create a positive pressure within the reactor vessel to lift the reactor vessel above the ocean floor allowing for a transfer of the reactor vessel to another area of sediment contamination on the ocean floor.

Abstract: A process for treating earth materials such as rock heaps to prevent acid rock drainage therefrom is disclosed. First, the oxygen concentration in the gas-phase of the rock heap is decreased, that is, displaced and/or depleted. This first step may be accomplished physically, chemically or biologically. Then, the gas-phase oxygen concentration in the heap is maintained at a low level. This second step may be provided for in a self-sustaining manner, like, for example, by covering the rock heap with soil and vegetation so that acid rock drainage is prevented indefinitely. Alternatively, the density of the gas-phase of the rock heap may be increased, and maintained at an elevated level indefinitely. The process is applicable to waste heaps from mining and industrial operations such as power generation and minerals processing, and to rubble collections in open and closed mines.

Abstract: A mixture of hydrocarbons with particulate rock and/or soil that is incapable of sustaining growth of erosion retarding plants can be converted to soil that is capable of sustaining such plant growth by blending the mixture with particulate biomass, and/or with particulate carbonates, hydroxides, and/or oxides of calcium and/or magnesium to produce a compostable aggregate and then exposing suitable piles of the compostable aggregate to the natural atmosphere for a sufficient time to cause the conversion of the aggregate to fertile soil.

Abstract: The present invention provides a novel ecological method of phyto-remediation of alkaline ad chemically degraded soils, said method comprising the steps of dispersing biomass obtained from Pelargonium sp. in alkaline or chemically degraded soil.

Abstract: A method of treating a contaminated material in which a low-permeability barrier is formed over the contaminated material, thereby creating a substantially hydraulically closed system. The material beneath the barrier is treated by at least one of delivering a substance to treat the contamination and removing flowable material from beneath the barrier. The invention also relates to compositions and properties of composite particles suitable for the treatment method, additional methods of implementing the composite particles, and methods of applying the composite particles.

Abstract: A method of removing contaminated sediment material from a contaminated area on the ocean floor using a reactor vessel wherein seawater is from within the interior of the reactor vessel so that the vessel penetrates the ocean floor. A pressurized fluid is introduced into the reactor vessel to create a slurry vortex of the contaminated sediment material and then a remediation fluid injected into the slurry vortex of the contaminated sediment material using a sufficient amount of the remediation fluid to remediate the contaminated sediment material and provide a noncontaminated sediment material. Pressurized seawater is injected into the interior of the reactor vessel to create a positive pressure within the reactor vessel to lift the reactor vessel above the ocean floor allowing for a transfer of the reactor vessel to another area of sediment contamination on the ocean floor.

Abstract: The invention provides a method of treatment of a contaminated material contaminated with an organic compound. The method includes the steps of treating the contaminate with a chemical oxidation step. The chemical oxidation step includes treating the contaminate with a transition metal in soluble form in combination with a chelator of the transition metal, to form a transition metal:chelator complex; and an oxidizing agent that provides a reactive free radical in the presence of the transition metal complex. The pH is maintained in a neutral range by a buffering compound. In particular embodiments, the method of treatment may further include pre-treating the contaminate with a biodegradation step prior to or after the chemical oxidation step. The biodegradation step includes a step of contacting the contaminate with a microbial consortium under conditions suitable for the consortium to mediate solubilization or biodegradion of the organic compound.

Abstract: A method and apparatus for constructing a underground barrier wall structure using a jet grout injector subassembly comprising a pair of primary nozzles and a plurality of secondary nozzles, the secondary nozzles having a smaller diameter than the primary nozzles, for injecting grout in directions other than the primary direction, which creates a barrier wall panel having a substantially uniform wall thickess. This invention addresses the problem of the weak “bow-tie” shape that is formed during conventional jet injection when using only a pair of primary nozzles. The improvement is accomplished by using at least four secondary nozzles, of smaller diameter, located on both sides of the primary nozzles. These additional secondary nozzles spray grout or permeable reactive materials in other directions optimized to fill in the thin regions of the bow-tie shape. The result is a panel with increased strength and substantially uniform wall thickness.

Abstract: An apparatus for high volume in-situ treatment of contaminated soil is a mobile vehicle with a chain trenching tool an excavator drums attached to the idler wheel to extend the width of soil cutting and increase the volume of soil being churned and treated in-situ. The drums may be arranged both for clock-wise and counter clock-wise rotation, and oriented to provide vertical lifting and swirling of the soil. The apparatus may include a hood disposed over the cutting drums to define a remediation chamber with ports for injecting high temperature air or chemical or biological remediation fluid into the soil. In a preferred embodiment, the hood has internal partitions that create a vapor recovery chamber outboard of the drums.

Abstract: A method and system for removing contaminants from the phreatic zone, also known as the saturation zone, or groundwater. The technique preferably involves gas sparging while slowing down the sparging process by placing packing balls into an eductor tube. A preferred embodiment of the system is comprised of a means for supplying gas to the lower extent of a well which induces a flow of groundwater and gas bubbles up the well. The system may also contain a conduit within the well which extends below the water table. The conduit has a lower fluid-permeable section which is located below the water table and an upper fluid-permeable section which is adjacent to the water table. The system may further comprise an eductor tube contained in the conduit which extends from the top extent of the conduit to the saturation zone. Packing balls may be located between the eductor tube and the means for supplying gas to the lower extent of the well.

Abstract: An apparatus for soil remediation to remedy a soil contaminated with a pollutant less affecting the environment, which includes a soil borer having a rotatable drilling form or portion capable of agitating the soil, introducing into the soil at least one agent selected from the group consisting of a microorganism capable of degrading the pollutant, a nutrient for the microorganism and an inducer to make the microorganism express the pollutant-degrading activity, and measuring pollutant concentration in the soil.