Copper Oxide Patents (Class 419/22)
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Patent number: 9631669Abstract: The oil-impregnated sintered bearing made of iron-copper sintered alloy consisting of 10-59% of Cu, 0.5-3% of Sn, and balance of Fe and impurities, includes pores in the iron-copper sintered alloy matrix of not less than 800 per mm2, has pores exposed at 20-50% by area ratio at the inner circumferential surface with diameters greater than 100 ?m, not more than 0.5%, respectable to the total pores number. The pores number with diameters greater than 80 ?m and not greater than 100 ?m, not more than 0.1%, respectable to the total pores number with diameters greater than 60 ?m and not greater than 80 ?m is 0.5-1.5%, respectable to the total pores number, with diameters greater than 40 ?m and not greater than 60 ?m is 0.8-3% respectable to the total pores number, and the remainder pores are with diameters less than 40 ?m.Type: GrantFiled: April 22, 2014Date of Patent: April 25, 2017Assignee: HITACHI CHEMICAL COMPANY, LTD.Inventors: Naoki Nishizawa, Hideaki Kawata, Hidekazu Tokushima
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Publication number: 20150060741Abstract: The present application relates to a new contact material, methods for the production of said contact material, and the use of said contact material.Type: ApplicationFiled: March 26, 2013Publication date: March 5, 2015Inventor: Michael Bender
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Publication number: 20140322063Abstract: A process for producing an FePt-based sputtering target includes adding metal oxide powder containing unavoidable impurities to FePt-based alloy powder containing Pt in an amount of 40 at % or more and less than 60 at % and one or more kinds of metal elements other than Fe and Pt in an amount of more than 0 at % and 20 at % or less with the balance being Fe and unavoidable impurities and with a total amount of Pt and the one or more kinds of metal elements being 60 at % or less so that the metal oxide powder accounts for 20 vol % or more and 40 vol % or less of a total amount of the FePt-based alloy powder and the metal oxide powder, followed by mixing the FePt-based alloy powder and the metal oxide powder to produce a powder mixture.Type: ApplicationFiled: July 14, 2014Publication date: October 30, 2014Inventors: Takanobu MIYASHITA, Yasuyuki GOTO, Takamichi YAMAMOTO, Ryousuke KUSHIBIKI, Masahiro AONO, Masahiro NISHIURA
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Patent number: 8758476Abstract: Provided are a method of producing mixed powder comprising noble metal powder and oxide powder, wherein powder of ammonium chloride salt of noble metal and oxide powder are mixed, the mixed powder is subsequently roasted, and ammonium chloride is desorbed by the roasting process in order to obtain mixed powder comprising noble metal powder and oxide powder, and mixed powder comprising noble metal powder and oxide powder, wherein chlorine is less than 1000 ppm, nitrogen is less than 1000 ppm, 90% or more of the grain size of the noble metal powder is 20 ?m or less, and 90% or more of the grain size of the oxide powder is 12 ?m or less. Redundant processes in the production of noble metal powder are eliminated, and processes are omitted so that the inclusion of chlorine contained in the royal water and nitrogen responsible for hydrazine reduction reaction is eliminated as much as possible.Type: GrantFiled: August 18, 2009Date of Patent: June 24, 2014Assignee: JX Nippon Mining & Metals CorporationInventors: Atsutoshi Arakawa, Kazuyuki Satoh, Atsushi Sato
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Patent number: 8524013Abstract: There are provided a permanent magnet and a manufacturing method thereof capable of manufacturing metal alkoxide in better work environment, simpler production facilities and easier manufacturing process and also reducing the manufacturing costs. An electrolytic solution is obtained through dissolving chloride or injecting hydrogen chloride gas into alcohol which is same alcohol as is a constituent element of metal alkoxide to be manufactured. Then, electrolysis is performed on the electrolytic solution while using, for an anode, a ferroalloy that contains iron and metal which is a constituent element of the metal alkoxide to be manufactured in a predetermined weight ratio (such as 1:1), and, for a cathode, the same ferroalloy, carbon, platinum or stainless steel, so as to obtain an alcohol solution of the metal alkoxide. Then, a permanent magnet is manufactured using the alcohol solution of the metal alkoxide thus obtained.Type: GrantFiled: April 28, 2011Date of Patent: September 3, 2013Assignee: Nitto Denko CorporationInventors: Keisuke Taihaku, Katsuya Kume, Izumi Ozeki, Tomohiro Omure
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Patent number: 8491728Abstract: There are provided a permanent magnet and a manufacturing method thereof that enables concentration of V, Mo, Zr, Ta, Ti, W or Nb contained in an organometallic compound in grain boundaries of the permanent magnet. To fine powder of milled neodymium magnet is added an organometallic compound solution containing an organometallic compound expressed with a structural formula of M-(OR)x (M represents V, Mo, Zr, Ta, Ti, W or Nb, R represents a substituent group consisting of a straight-chain or branched-chain hydrocarbon, x represents an arbitrary integer) so as to uniformly adhere the organometallic compound to particle surfaces of the neodymium magnet powder. Thereafter, a compact body obtained by compacting the magnet powder is held for several hours in hydrogen atmosphere at 200 through 900 degrees Celsius so as to perform a calcination process in hydrogen. Thereafter, through sintering, a permanent magnet is manufactured.Type: GrantFiled: March 28, 2011Date of Patent: July 23, 2013Assignee: Nitto Denko CorporationInventors: Izumi Ozeki, Katsuya Kume, Keisuke Hirano, Tomohiro Omure, Keisuke Taihaku, Takashi Ozaki
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Patent number: 8025710Abstract: Provided are an ancillary material, used for shape processing, which is capable of shortening a processing time, avoiding a reduction in quality of a shape provided to a workpiece material, and allowing a relatively low manufacturing cost; a processing method using the ancillary material; and a method of manufacturing the ancillary material. The tungsten alloy grains (1) comprise: tungsten of greater than or equal to 80% by mass and less than or equal to 98% by mass; nickel; at least one kind of metal selected from the group consisting of iron, copper, and cobalt; and an inevitable impurity, a maximum diameter thereof is greater than or equal to 0.1 mm and less than or equal to 5.00 mm, and a specific surface area thereof is less than or equal to 0.02 m2/g. The tungsten alloy grains (1, 10), the workpiece material (30), an abrasive (20) are blended in a container (100) and the container is rotated, thereby processing the shape of the workpiece material (30).Type: GrantFiled: November 20, 2006Date of Patent: September 27, 2011Assignee: A.L.M.T. Corp.Inventors: Shinji Kikuhara, Hitoshi Inoue, Noboru Uenishi, Satoshi Umemoto
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Publication number: 20090053089Abstract: A method of making a homogeneous granulated metal-based powder, comprises steps of: providing preselected amounts of at least one metal element or metal alloy, at least one ceramic compound, and/or at least one non-metallic element; forming a homogeneous slurry/suspension or wet mixture comprising the preselected amounts of metal element(s) and/or metal alloys, ceramic compound(s), and/or non-metallic element(s), a liquid phase comprising at least one liquid, and at least one binder material; drying the slurry/suspension or mixture to remove at least a portion of the liquid phase and form a powder mixture comprising partially or completely dried granules; and subjecting the granules to a thermal de-binder process for effecting: additional removal of any remaining liquid phase, if necessary; removal of the at least one binder material; reduction of carbon content; reduction of oxygen on the surfaces or interior of the metal or metal alloy phases in the granules; and optional partial sintering for strengtheningType: ApplicationFiled: August 20, 2007Publication date: February 26, 2009Applicant: HERAEUS INC.Inventors: Fenglin YANG, Carl Derrington, Bernd Kunkel
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Publication number: 20080280166Abstract: Solid oxide fuel cell wherein the anode has a cermet, including a metallic portion and an electrolyte ceramic material portion substantially uniformly interdispersed.Type: ApplicationFiled: December 30, 2003Publication date: November 13, 2008Applicant: PERELLI & C.S.P.A.Inventors: Boris L. Kuzin, Sergey M. Beresnev, Nina M. Bogdanovich, Edhem Kh. Kurumchine, Ana Berta Lopes Correia Tavares, Antonio Zaopo, Yuri A. Dubitsky
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Publication number: 20010051103Abstract: A method for recycling copper oxide includes: a first step in which a sodium hydroxide aqueous solution is added to acidic copper chloride waste etchant produced in the PCB industry, to obtain copper hydroxide slurry; and a second step in which the slurry obtained in the first step is heated and sintered to thereby prepare a needle-form copper oxide. Since copper oxide has a purity of more than 99.0 wt % and the needle-form crystal morphology, so that it has an excellent filtering ability and homogeneous particle size distribution.Type: ApplicationFiled: January 24, 2001Publication date: December 13, 2001Inventors: Kyu Bum Seo, Young Sun Uh, Young Hee Kim, Jung Yoon Han, Sun Jin Kim, Myung Hun Kim
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Patent number: 6103354Abstract: A ceramic circuit substrate includes an insulating layer fabricated of a ceramic, a first surface conductor layer fabricated on a surface of the insulating layer and embedded in the insulating layer except at least its surface, and a second surface conductor layer fabricated to be stacked on the first surface conductor layer.Type: GrantFiled: September 22, 1997Date of Patent: August 15, 2000Assignee: Sumitomo Metal (SMI) Electronic Devices Inc.Inventors: Hideaki Araki, Kunihiko Mori
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Patent number: 5993731Abstract: The process for producing net shape or near net shape metal parts is improved by sintering a compact in a reducing atmosphere where the compact contains a metal and chemically-bound oxygen in the form of a metal oxide, for example, and the chemically-bound oxygen is in an amount sufficient to improve the sintering of the compact. Improved sintering is facilitated when the metal oxide forms a metal/metal oxide eutectic during reduction of the chemically-bound oxygen in a reducing atmosphere during the sintering process. The compact can contain a metal oxide and a solution compound to produce an alloy part, provided the chemically-bound oxygen is present in an amount sufficient to improve sintering. In a preferred embodiment, the compact also contains a reinforcement compound and is sintered to make a metal matrix composite. The resultant density of the near net shape metal parts made by the improved sintering process is preferably about 97% or more of the theoretical density.Type: GrantFiled: November 7, 1997Date of Patent: November 30, 1999Assignee: Brush Wellman, Inc.Inventors: David E. Jech, Juan L. Sepulveda, Anthony B. Traversone
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Patent number: 5846288Abstract: Electrical contact material made from intimate mixtures of silver powder and a powder of a second phase material is shown in which the powder of the second phase material is milled to produce a selected grain distribution of approximately 90% less than 7-10 microns, approximately 50% between 2 and 5 microns and approximately 10% less than 0.8 to 1.0 microns. The powder of the second phase material is added to a silver salt solution, ammonium hydroxide and hydrazine hydrate to form a precipitate of second phase material particles covered with silver. For applications in which the particles need to be free flowing the particles are compacted together without any binder, broken into chunks and milled to provide granules. In one embodiment homogeneously doped tin oxide particles are disclosed in which tin oxide and the oxide of the dopant are dissolved in nitric acid to produce finely dispersed tin oxide and dopant oxide. The oxides are calcined and ground to the selected grain size distribution.Type: GrantFiled: November 26, 1996Date of Patent: December 8, 1998Assignee: Chemet CorporationInventors: Ernest M. Jost, Kirk McNeilly
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Patent number: 5826159Abstract: The sinterability of a copper/tungsten green compact is improved by using copper oxide, tungsten oxide or both as the copper and/or tungsten source. Sinterability is further enhanced by including steam in the sintering atmosphere. Spontaneous combustion of the source powders used to form the sintering compacts can be reduced or eliminated by including corrosion inhibitor in the powders.Type: GrantFiled: April 29, 1997Date of Patent: October 20, 1998Assignee: Brush Wellman, Inc.Inventors: David E. Jech, Juan L. Sepulveda, Anthony B. Traversone
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Patent number: 5812925Abstract: A method for joining a first metal surface to a second metal surface that includes providing powder metal particles substantially all of which have hardnesses lower than the hardnesses of the first and second metal surfaces, at normal temperatures; locating the particles in a layer between the first and second metallic surfaces, to form an assembly; heating the assembly to an elevated temperature or temperatures below the softening temperature of the first and second metallic surfaces; and effecting compression of the layer by and between the first and second surfaces at a pressure level or levels below the compressive yield strengths of the first and second surfaces, and above the compressive yield strengths of the particles, and for a time duration to effect a bond between the first and second metallic surfaces.Type: GrantFiled: October 23, 1996Date of Patent: September 22, 1998Inventor: Gunes M. Ecer
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Patent number: 5594932Abstract: In a method for the manufacture of an encased high critical temperature superconducting wire by the "powder in tube" method, prior to the introduction of a compressed rod of superconducting material into a silver tube, the rod is heat treated so that grains of unwanted phase are reabsorbed. The tube can be drawn more easily, and strands can be produced with a regular geometry and no defects. The wire is constituted by 15 .mu.m to 20 .mu.m thick filaments (30) with a form factor of more than 60.Type: GrantFiled: June 9, 1994Date of Patent: January 14, 1997Assignee: Alcatel Alsthom Compagnie General d'ElectriciteInventors: Gerard Duperray, Denis Legat
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Patent number: 5480728Abstract: A conductive contact for use with metal oxide superconductors is described. The conductive contact comprises a metal contact which is attached by a diffusion bonding means to a superconductive metal oxide substrate. In a preferred embodiment, diffusion bonding means comprises a metal paint which includes metal particles and an organic binder which is heated to pyrolized the organic binder and form metallic diffusion bonds to the metal contact and metal oxide substrate. The invention also comprises a method for forming the conductive contact which includes selecting the superconducting metal oxide substrate, coating the substrate with a metal paint, placing the metal contact in touching contact with the metal paint and heating the combination of materials described above to pyrolized the organic binder and coalesce the metal particles.Type: GrantFiled: January 3, 1994Date of Patent: January 2, 1996Assignee: General Electric CompanyInventor: John E. Tkaczyk
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Patent number: 5433917Abstract: Process for producing novel fluxed PZT dielectric ceramic compositions having sintering temperatures below about 1000.degree., so as to be non-reactive with electrode layers when co-fired therewith. The PZT is sintered with an effective amount of an eutectic mixture of CuO and an oxide of an alkaline earth metal, preferably barium oxide and/or strontium oxide, to reduce the sintering temperature of the PZT composition below about 1000.degree. C. Dopant such as manganese oxide may be added to reduce the dielectric losses.Type: GrantFiled: September 16, 1993Date of Patent: July 18, 1995Assignee: The Penn State Research FoundationInventors: Ashvin Srivastava, Amar Bhalla, L. Eric Cross
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Patent number: 5429791Abstract: An article and method of manufacture of a (Bi,Pb)--Sr--Ca--Cu--O superconductor comprisingcalcinating powders of superconductor precursors of PbO, Bi.sub.2 O.sub.3, SrCO.sub.3 or SrO, CaCO.sub.3 or CaO in air to obtain a 2223 superconductor lump and second phases;crushing the lump into powder;molding the powder into a superconductor body;disposing the body within silver powder to form a composite;molding the composite;heat treating the composite to increase the bond strength of the silver powder; andworking the composite into a useable shape by rolling and drawing while applying intermediate and final heat treatments to obtain a final product.Type: GrantFiled: June 23, 1994Date of Patent: July 4, 1995Assignees: Korea Atomic Energy Research Institute, Korea Electric Power CorporationInventors: Hee-Gyun Lee, Seon-Chil Kweon, Dong-Yeon Won, Gye-Won Hong
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Patent number: 5413753Abstract: Methods of forming composite articles of superconducting materials and metal at ambient temperature by applying a mixture of metal and binder to a ceramic oxide preform to yield a coated preform which is then heat treated to provide composite articles of superconducting ceramic and metal.Type: GrantFiled: September 17, 1993Date of Patent: May 9, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: George E. Zahr
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Patent number: 5399312Abstract: A process for fabricating Thallium-based superconducting tapes comprising the steps of: (1) preparing a powder mixture having a nominal composition of (Tl.sub.1-x-y Bi.sub.y Pb.sub.z)(Ba.sub.2-z Sr.sub.z)Ca.sub.2 Cu.sub.3 O.sub.9 ; (2) placing the powder mixture into a silver tube and drawing and/or swaging the silver tube containing the powder mixture into a wire having a pre-determined diameter, wherein x and y are real numbers between 0.2 and 0.4, and z is a real number between 0 and 2; (3) rolling the wire into a tape having a pre-determined thickness; and (4) subjecting the tape to a two-stage single-sintering process at two respective sintering temperatures. The two-stage single-sintering process of the present invention allows Thallium-based superconducting tapes to be fabricated which exhibit substantially increased critical current density, without causing a substantially increased cost and complexity, as do other prior art processes, such as the double-sintering process.Type: GrantFiled: October 4, 1993Date of Patent: March 21, 1995Assignee: Industrial Technology Research InstituteInventors: Ru-Shi Liu, Sheng-Feng Wu, Chung-Ho Tai, Der-Shiuh Shy
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Patent number: 5374391Abstract: A method of producing a molded ceramic article comprises the first step mixing powdery raw materials and a liquid additive, thereby obtaining a mixed raw material, the second step press-molding the mixed raw material obtained in the first step in a hydrostatically applied condition of pressure, thereby removing an excess of the liquid additive to obtain a preform, and the third step calcining the preform obtained in the second step to obtain a molded ceramic article. The molded ceramic article comprises, as a principal component, copper and, as essential components, Cr and Ni within composition ranges of 0.1.ltoreq. Cr< 2 wt. % and 0.1.ltoreq. Ni< 10 wt. % and further at least one additive component selected from the group consisting of the following composition ratios: the following composition ratios: O<Fe< 5 wt. %, O.ltoreq.Co< 5 wt. %, O.ltoreq.Al< 10 wt. %, O.ltoreq.Ti< 20 wt. %, O.ltoreq.Mo< 3 wt. %, O.ltoreq.Si< 3 wt. %, O.ltoreq.V< 3 wt. %, O.ltoreq.Mg< 1 wt. % and O.Type: GrantFiled: June 9, 1993Date of Patent: December 20, 1994Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Mitsuo Kuwabara, Kiyoshi Ikegami, Teruaki Yoshida, Koji Takahashi, Tamotsu Harada, Takeshi Komiyama, Fumio Hirai, Masamichi Hayashi
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Patent number: 5354535Abstract: An article and method of manufacture of (Bi,Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi,Pb)-Sr-Ca-Cu-O superconductor.Type: GrantFiled: April 6, 1993Date of Patent: October 11, 1994Assignee: University of ChicagoInventors: Stephen E. Dorris, Roger B. Poeppel, Barton C. Prorok, Michael T. Lanagan, Victor A. Maroni
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Patent number: 5338714Abstract: The invention relates to nano-composite powders of alumina and metal constituted of grains of micronic size. Each grain comprises a compact matrix of alumina of a specific surface area less than 5 m.sup.2 /g, in which are dispersed crystallites of transition metals of alloys of these metals, of sizes less than 50 nm. The powder according to the invention may be produced starting with a precursor comprised of a mixed carboxylic salt of aluminum and one or more transition metals. The powders according to the invention permit producing by sintering cermets of alumina/metal benefitting from greatly improved mechanical and thermo-mechanical properties.Type: GrantFiled: March 24, 1992Date of Patent: August 16, 1994Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)Inventors: Abel Rousset, Xavier DeVaux
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Patent number: 5326525Abstract: A process is disclosed for fabricating a metal aluminide composite which comprises providing a metal aluminide, such as titanium aluminide, or a titanium aluminide alloy, and a reinforcing fiber material, such as silicon carbide fiber, and placing an interlayer or diffusion barrier layer in the form of a metal selected from the group consisting of silver, copper and gold, and alloys thereof, between the metal aluminide and the reinforcing fiber material. The interlayer metal can be a foil of the metal or in the form of a coating, such as a silver coating, on the reinforcing fiber material. The metal aluminide, the reinforcing fiber material, and the metal interlayer, e.g., in the form of a packet of a plurality of alternate layers of metal aluminide alloy and reinforcing fiber material, each layer being separated by the metal interlayer, is pressed and heated at an elevated temperature, e.g., ranging from about 900.degree. to about 1200.degree. C., at which diffusion bonding occurs.Type: GrantFiled: July 11, 1988Date of Patent: July 5, 1994Assignee: Rockwell International CorporationInventor: Amit K. Ghosh
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Patent number: 5312582Abstract: A process for producing porous structures for use in molten carbonate fuel cells in which a powder comprising at least one of a non-alloyed metal powder and a metal oxide powder, and a ceramic oxide powder is mixed, formed into a desired shape and sintered in an oxidizing atmosphere at a temperature between 900.degree. C. and about 1400.degree. C. via reactive oxidation to form a sintered oxide structure, which is then cooled to 700.degree. C. to 1100.degree. C. and treated in a reducing atmosphere to form a metallic structure with the non-reducible oxide dispersed within the metal.Type: GrantFiled: February 4, 1993Date of Patent: May 17, 1994Assignee: Institute of Gas TechnologyInventor: Rafael A. Donado
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Patent number: 5262398Abstract: A ceramic oxide superconductive composite material comprising a ceramic oxide superconductor and a non-superconductive material comprising at least one element which does not react with any of the elements of the ceramic oxide superconductor has improved superconductive properties such as a higher critical temperature and a larger critical current density.Type: GrantFiled: December 16, 1992Date of Patent: November 16, 1993Assignee: Sumitomo Electric Industries, Ltd.Inventors: Masayuki Nagata, Minoru Yokota, Ken-ichi Sato
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Patent number: 5258052Abstract: A powder metallurgy material for use in the manufacture of electrical contacts and having enhanced cold workability consists essentially, by weight percent, of 5 to 20% tin oxide, 2000 to 5000 ppm, preferably 2000 to less than 4000 ppm copper, 20 to 200 ppm, preferably 20 to 100 ppm, lithium, balance silver. Such materials are produced by compacting the powdered components and heating to sinter the material to at least 93% of theoretical density. Such materials subsequently can be hot or cold worked to a form useful for the manufacture of electrical contacts.Type: GrantFiled: June 18, 1992Date of Patent: November 2, 1993Assignee: Advanced Metallurgy IncorporatedInventor: Richard C. Bevington
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Patent number: 5223480Abstract: A novel method for forming homogeneous silver high temperature superconductor (HTS) composites. The novel method comprises a chemical coprecipitation of silver, barium, yttrium, and copper salts solutions, followed by calcination and milling processes. The novel method has an advantage of retaining all the virtues immanent in a composite HTS, for example, increased critical current density (Jc), and improved mechanical properties, while bypassing extant and deficient methodologies for forming a composite, the deficient composites characterized by heterogeneity.Type: GrantFiled: April 22, 1991Date of Patent: June 29, 1993Assignee: Eastman Kodak CompanyInventors: Ashok K. Agarwala, Paul A. Christian, Kenneth B. Quinn
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Patent number: 5202308Abstract: The present invention relates to a sintered ceramic superconducting wire which is made by placing powders of metal oxides or a mixture of powders of metal oxides and metal carbonates, said oxides and said carbonates each having an oxidation potential higher than or equal to that of copper, in a metallic cylinder formed from a high temperature oxidation-resistant material, and drawing the packed cylinder to a final size and sintering said drawn packed cylinder in air, wherein said cylinder is removed prior or subsequent to the final step of sintering.Type: GrantFiled: December 13, 1991Date of Patent: April 13, 1993Assignee: Sumitomo Electric Industries, Ltd.Inventors: Susumu Yamamoto, Nozomu Kawabe, Teruyuki Murai
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Patent number: 5179075Abstract: A method of making at least one low electrical resistance connection between a metal and a high T.sub.c superconducting ceramic part, said part being made from a ceramic powder which is placed in a mold, compressed, and sintered, wherein at least one volume of silver or gold powder corresponding to the shape of said connection and situated at the desired location is placed inside said mold in juxtaposition with said ceramic powder but without being mixed therewith, after which the compression and the sintering are performed under an atmosphere containing oxygen and at a temperature that is lower than the melting temperature of silver or gold.Type: GrantFiled: October 29, 1990Date of Patent: January 12, 1993Assignee: GEC Alsthom SAInventors: Albert Leriche, Gerard Duperray, Fernand Grivon
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Patent number: 5152959Abstract: The present invention relates to a process for forming a composite strip material without any sintering step. The process includes blending a powdered high conductivity material such as powdered copper with a powdered low thermal expansion phase material such as a nickel-iron alloy, compacting the powders to form a green composite strip, heating the green strip to a hot rolling temperature and hot rolling the heated strip to a desired gauge. The heated strip is reduced less than about 45% to minimize the deformation of the low thermal expansion phase particles.Type: GrantFiled: June 24, 1991Date of Patent: October 6, 1992Assignee: AMETEK Speciality Metal Products DivisionInventor: Clive R. Scorey
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Patent number: 5087413Abstract: Vias each having no pore are formed in a multilayer ceramic substrate by filling through holes of green sheets with conducting material obtained by: kneading mixed powder particles, the powder particles produced by adding copper oxide powder particles in the amount of 50% (in weight) or less to copper powder particles, with a solution including methyl ethyl ketone and 0.5% (in weight) of isosulfonyltridecylbenzene titanate; drying and cracking the kneaded mixed powder particles, producing cracked mixed powder particles; classifying the cracked mixed powder particles with a 100 mesh filter, producing classified mixed powder particles; spheroidizing the classified mixed powder particles with a collision method performed in gases flowing at high speed; and firing the green sheets at a temperature of about 800.degree. C.Type: GrantFiled: January 9, 1991Date of Patent: February 11, 1992Assignee: Fujitsu LimitedInventor: Kenichiro Abe
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Patent number: 5071826Abstract: A method for making metal/ceramic superconductor thick film structures including the steps of preparing a silver/superconductor ink, applying the ink to a substrate, evaporating the ink's binder, decomposing a silver compound in the residue to coat the superconductor grains, sintering the coated superconductor grains, and oxygenating the superconductor grains through the silver coating. The resultant inter-granular silver increases the critical current and mechanical strength of the superconductor.Type: GrantFiled: October 13, 1989Date of Patent: December 10, 1991Assignee: Hewlett-Packard CompanyInventors: John T. Anderson, V. K. Nagesh, Richard C. Ruby
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Patent number: 5049332Abstract: A conductive-metal-filled substrate is formed by intermingling oxide coated, non-conductive copper or nickel particles into a substrate having a softening point of at least 200.degree. C. followed by compression molding at a temperature of at least 200.degree. C. The filled substrates are electrically conductive and are useful for a variety of uses such as EMI shielding.Type: GrantFiled: July 3, 1990Date of Patent: September 17, 1991Assignee: Akzo NVInventors: Karolyn E. Ziemer, William J. E. Parr
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Patent number: 5041416Abstract: A superconductor metal matrix composite formable into an electrical current carrying material. A superconductive particulate is intermixed with a normal metal matrix, pressed into form and heated to form the composite. The metal matrix surrounds the superconductive particulate to prevent loss of oxygen from the superconductive particulate so the particulate retains its superconductive properties. The metal matrix also becomes superconductive due to proximity effect.Type: GrantFiled: October 16, 1990Date of Patent: August 20, 1991Assignee: FMC CorporationInventor: Charles N. Wilson
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Patent number: 4980125Abstract: Sinter materials having the constitution AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO produced from an intraoxidized alloy powder have added thereto bismuth zirconate and/or bismuth titanate in parts by weight of preferably between 0.1 and 5%. For the production of these materials, bismuth zirconate and/or bismuth titanate is added as a separate powder to the intraoxidized alloy powder of AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO. With such a contact material, the excess temperature behavior in motor contactors is significantly improved.Type: GrantFiled: November 17, 1989Date of Patent: December 25, 1990Assignee: Siemens AktiengesellschaftInventors: Wolfgang Haufe, Ralf-Dieter Krause, Bernhard Rothkegel, deceased
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Patent number: 4975414Abstract: The method of producing a superconducting product includes: providing a pressed-powder preform consisting essentially of REBa.sub.2 Cu.sub.3 O.sub.x where 6.0<x<7.0; preheating the preform to elevated temperature for a time period between 0 and 10 minutes, within a medium consisting of a mixture of refractory ceramic particles, carbonaceous particles and ultra fine graphitic particles; providing a preheated grain bed and embedding the heated preform in that bed, the bed having the same composition as the medium; and consolidating the preform to at least about 95% of theoretical density by application of pressure to the grain bed, thereby to form the product.Type: GrantFiled: November 13, 1989Date of Patent: December 4, 1990Assignee: Ceracon, Inc.Inventors: Henry S. Meeks, Sundeep V. Rele
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Patent number: 4975411Abstract: A ceramic superconductor is made by consolidating a plurality of metals and a chalcogen and applying a magnetic field during the consolidation operation.Type: GrantFiled: May 19, 1987Date of Patent: December 4, 1990Assignee: Fonar CorporationInventors: Gordon T. Danby, Charles E. Brukl, Lawrence A. Minkoff
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Patent number: 4971754Abstract: The method concerns preparing a contact material constituted by silver and tin oxide.According to the invention the method comprises the following steps:preparing an aqueous solution containing dissolved silver nitrate and tin oxide particles in suspension, with the size of said particles measured in terms of specific surface area using the BET method lying between about 2 m.sup.2 /g and 6 m.sup.2 /g;causing silver nitrate to precipitate in silver hydroxide by rapidly adding a strong base and stirring, with silver hydroxide being unstable and transforming progressively into silver oxide;eliminating the ions from the solution and then the water in order to obtain a dry product; andheating the dry product to a temperature of about 200.degree. C. to 500.degree. C. in order to reduce the silver oxide to metallic silver.The invention is applicable to manufacturing electrical contacts for opening and closing in electromechanical apparatuses.Type: GrantFiled: November 22, 1989Date of Patent: November 20, 1990Assignee: TelemecaniqueInventors: Gerard Fontet, Michel Leclercq, Jacques Muniesa, Thierry Pagnier, Tretarre Rene
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Patent number: 4962084Abstract: A process for producing an oxidic superconductor precursor alloy which comprises mechanicallly allowing metallic elemental constituents of the oxidic superconductor in stoichiometric proportions and in the presence of a process control agent non-detrimental to the superconductor to provide a uniform mechanically alloyed product which is compacted and worked to provide a product form such as wire, tape or thin strip. This product form can then be given the configuration required for use (e.g. open coil) and then oxidized to provide the superconductor.Type: GrantFiled: April 12, 1988Date of Patent: October 9, 1990Assignee: INCO Alloys International, Inc.Inventors: John J. deBarbadillo, II, Gaylord D. Smith
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Patent number: 4959348Abstract: A superconductor essentially comprises a three-component metallic oxide including yttrium, barium, and copper (Y-Ba-Cu three-component metallic oxide) and an oxide of an element having a melting point lower than that of the three-component metallic oxide and having 0.1 to 5.0 wt % in form of the oxide thereof. The element is preferably of bismuth, antimony, boron, lead, and praseodymium.Type: GrantFiled: November 9, 1988Date of Patent: September 25, 1990Assignee: Kabushiki Kaisha ToshibaInventors: Kouji Higashibata, Hironori Suzuki
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Patent number: 4948424Abstract: Sinter contact materials produced from an intraoxidized alloy powder having the constitution AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO have added thereto at least zirconium oxide and optionally additionally bismuth oxide in parts by weight of preferably between 0.1 and 5%. For the production of these materials, zirconium oxide power and optionally additionally bismuth oxide powder is added to the intraoxidized alloy powder AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO. With such a contact material, the excess temperature behavior in motor contactors is improved.Type: GrantFiled: November 17, 1989Date of Patent: August 14, 1990Assignee: Siemens AktiengesellschaftInventors: Wolfgang Haufe, Bernard Rothkegel, deceased
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Patent number: 4948676Abstract: The present invention provides a ceramic/metal composite material comprising cerium/aluminum mixed oxides as the ceramic phase and an alloy or intermetallic compond of cerium and at least one of aluminum, nickel, iron and cobalt as the metal phase. The ceramic phase may comprise interengaged crystal lattices of ceria and alumina. The material may be a self-sustaining body which may be used as substrate for a dimensionally stable anode in molten sale aluminum electrowinning cells, coated with a protective layer of cerium oxyfluoride in situ during electrolysis in molten cryolite containing cerium ions.Type: GrantFiled: February 15, 1989Date of Patent: August 14, 1990Assignee: Moltech Invent S.A.Inventors: Dominique Darracq, Jean-Jacques Duruz
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Patent number: 4915899Abstract: The invention comprises a process for co-sintering of conductors of copper or copper-based alloy and a ceramic substrate, the substrate being produced from a ceramic powder of cordierite type, having a sintering temperature of lower than 950.degree. C.The process comprises the following steps:(a) shaping of the ceramic substrate from a powder of cordierite type,(b) deposit of copper on the ceramic substrate, and(c) co-sintering heat treatment, during which the organic compounds are removed, the copper is regenerated in a reducing atmosphere, and co-sintering of the conductors and the substrate is carried out in a flow of moist inert gas with a plateau at a temperature of between 1065.degree. and 1080.degree. C.The process according to the invention makes it possible to produce substrates of cordierite with internal and external conductors.Type: GrantFiled: January 23, 1989Date of Patent: April 10, 1990Assignee: Pechiney Recherche Groupement d'Interet EconomiqueInventors: Veronique Oliver, Jean-Louis Guille, Jean-Claude Bernier, Claude Drapier
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Patent number: 4914080Abstract: A method for fabricating a superconductive film composed of a RE.sub.1 Ba.sub.2 Cu.sub.3 O.sub.x compound, or a (Bi.Sr.Ca.Cu.O) compound. In a first embodiment, oxides or carbonates of the component materials, namely Y.sub.2 O.sub.3, BaCO.sub.3, and CuO are mixed in atomic ratios of 1:2:3, according to the chemical formula of RE.sub.1 Ba.sub.2 Cu.sub.3 O.sub.x, and sintered to create a rhombic perovskite structure. The sintered mixture is powdered again, with added powdered amounts of Y.sub.2 O.sub.3 and powdered metallic Cu, and sintered. The sintered product is used as the source for an electron beam evaporator. In a second embodiment the (Bi.Sr.Ca.Cu.O) compound is formed into a sintered pellet which is composed of a mixture of one part of BiO, 3-15 parts of SrCO.sub.3, 4-30 parts of CaCO.sub.3, and 2-5 parts of CuO, in atomic ratios of Bi, Sr, Ca and Cu.Type: GrantFiled: January 24, 1989Date of Patent: April 3, 1990Assignee: Fujitsu LimitedInventors: Kohta Yoshikawa, Naoki Awaji, Kyung-ho Park, Nagisa Ohsako, Seigen Ri
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Patent number: 4892581Abstract: A composition of matter comprised of copper and particles which are dispersed throughout the copper, where the particles are comprised of copper oxide and copper having a coating of copper oxide, and a method for making this composition of matter.Type: GrantFiled: April 4, 1989Date of Patent: January 9, 1990Assignee: The United States of America as represented by the United States Department of EnergyInventors: Haskell Sheinberg, Thomas T. Meek, Rodger D. Blake
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Patent number: 4892861Abstract: Disclosed is a cermet exhibiting superconducting properties with improved mechanical properties comprising a mixture of a superconducting ceramic and one or more metals, the cermet resulting from liquid phase sintering at a temperature at which one of the metals is molten and below the melting temperature of the superconducting ceramic.Type: GrantFiled: August 14, 1987Date of Patent: January 9, 1990Assignee: Aluminum Company of AmericaInventor: Siba P. Ray
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Patent number: 4857266Abstract: A composition of matter comprised of copper and particles which are dispersed throughout the copper, where the particles are comprised of copper oxide and copper having a coating of copper oxide, and a method for making this composition of matter.Type: GrantFiled: December 5, 1988Date of Patent: August 15, 1989Assignee: The United States of America as represented by the United States Department of EnergyInventors: Haskell Sheinberg, Thomas T. Meek, Rodger D. Blake
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Patent number: 4855104Abstract: Contact materials based on AgSnO.sub.2 and having Bi.sub.2 O.sub.3 and CuO as further metal oxide additives were previously disclosed. In these materials the total content of all metal oxides was supposed to be between 10 and 25% by volume with the SnO.sub.2 share equal to or greater than 70% by volume of the total amount of oxide.According to this invention the quantity of SnO.sub.2 is kept smaller than 70% by volume; specifically at about 65%, but in any case equal to or greater than 50%. The SnO.sub.2 weight content is to be in the 4% to 8% range and the weight percentage ratio of SnO.sub.2 to CuO is to be between 8:1 and 12:1.In the associated production process, either Bi.sub.2 O.sub.3 powder is purposely admixed to an internally oxidized alloy powder (IOAP) in an additional operation, a grain restructuring with locally different Bi.sub.2 O.sub.3 concentrations occurring in the structure after sintering and compacting.Type: GrantFiled: May 6, 1988Date of Patent: August 8, 1989Assignee: Siemens AktiengesellschaftInventors: Bernhard Rothkegel, Wolfgang Haufe