Tungsten Containing Patents (Class 420/114)
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Patent number: 11186901Abstract: A steel constituting a chisel according to the present invention includes: 0.40-0.45% by mass of carbon, 0.50-0.80% by mass of silicon, 1.00-1.30% by mass of manganese, 0.001-0.005% by mass of sulfur, 2.90-3.80% by mass of chromium, and 0.20-0.40% by mass of molybdenum, with a balance consisting of iron and an unavoidable impurity, the steel has an ideal critical diameter DI defined by Equation (1) of 600 or more: DI=7·(% C)1/2·(1+0.64·% Si)·(1+4.1·% Mn)·(1+2.83·% P)·(1?0.62·% S)·(1+2.33·% Cr)·(1+3.14·% Mo)??(1).Type: GrantFiled: March 9, 2016Date of Patent: November 30, 2021Assignee: KOMATSU LTD.Inventors: Eiji Amada, Akihiro Ochiai, Norimasa Tsunekage, Yuko Nagaki
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Patent number: 10465269Abstract: Disclosed herein are embodiments of alloys which can be used for hardfacing applications, and hardfacing layers themselves. In particular, embodiments of the alloys can have high hardness as well as impact resistance. These advantageous properties can occur due to the inclusion of hardfacing particles, as well as other compositional, microstructural, thermodynamic, and performance criteria.Type: GrantFiled: July 22, 2015Date of Patent: November 5, 2019Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, Adolfo Castells, Jonathon Bracci
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Patent number: 9212411Abstract: A high-strength steel sheet includes a composition containing, in mass percent, 0.08% to 0.20% of carbon, 0.2% to 1.0% of silicon, 0.5% to 2.5% of manganese, 0.04% or less of phosphorus, 0.005% or less of sulfur, 0.05% or less of aluminum, 0.07% to 0.20% of titanium, and 0.20% to 0.80% of vanadium, the balance being iron and incidental impurities.Type: GrantFiled: June 29, 2010Date of Patent: December 15, 2015Assignee: JFE Steel CorporationInventors: Koichi Nakagawa, Takeshi Yokota, Kazuhiro Seto, Satoshi Kinoshiro, Yuji Tanaka, Katsumi Yamada, Tetsuya Mega, Katsumi Nakajima
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Patent number: 9068238Abstract: Described is a high tensile strength hot rolled steel sheet having high strength and formability, and a manufacturing method. It has tensile strength ?980 MPa and excellent formability, and specifically identified ranges by mass % of C, Si, Mn, P, S, N, Al, Ti, V, Solute V, and Solute Ti; (ii) microstructure with fine carbides dispersion precipitated therein, the fine carbides containing Ti and V and having the average particle diameter <10 nm, as well as volume ratio with respect to the entire microstructure ?0.007; and matrix as ferrite phase having area ratio with respect to the entire microstructure ?97%. C, Ti, V, S and N satisfy (1) Ti?0.08 +(N/14×48+S/32×48) and (2) 0.8?(Ti/48+V/51)/(C/12)?1.2, where “C”, “Ti”, “V”, “S” and “N” represent contents (mass %) of corresponding elements, respectively.Type: GrantFiled: March 30, 2011Date of Patent: June 30, 2015Assignee: JFE STEEL CORPORATIONInventors: Tamako Ariga, Katsumi Nakajima, Tetsuya Mega
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Patent number: 9005520Abstract: The invention concerns steels having excellent resistance over time, in a corrosive atmosphere due to oxidizing environments such as, for example, fumes or water vapor, under high pressure and/or temperature. The invention concerns a steel composition for special applications, said composition containing, by weight, about 1.8 to 11% of chromium (and preferably between about 2.3 and 10% of chromium), less than 1% of silicon, and between 0.20 and 0.45% of manganese. It has been found that it is possible to adjust the contents of the composition based on a predetermined model, selected to obtain substantially optimal properties with respect to corrosion in specific conditions of high temperature performances. Said model can involve as additive of as residue at least one element selected among molybdenum, tungsten, cobalt, and nickel.Type: GrantFiled: June 7, 2007Date of Patent: April 14, 2015Assignees: V & M FranceInventors: Jean Leyer, Bruno Vandenberghe, Viviane Lepingle, Ghislain Louis, Annie Fouquet, Catheline Petelot, Emilie Petelot, Adeline Petelot
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Publication number: 20150044086Abstract: A steel wire rod or steel bar as hot-rolled, including: by mass %: C: 0.1 to 0.6%, Si: 0.01 to 1.5%, Mn: 0.05 to 2.5%, Al: 0.015 to 0.3%, and N: 0.0040 to 0.0150%, and P: limited to 0.035% or less and S: limited to 0.025% or less, and the balance substantially consisting of iron and unavoidable impurities, wherein a depth of d (mm) from the surface of the surface layer region with 20 HV 0.2 or more higher, relative to HV 0.2 that is the average hardness in the region where the depth from the surface is from sectional radius R×0.5 (mm) to the center satisfies the formula (1); the steel structure of the surface layer region has a ferrite fraction of 10% or less by area ratio, with the balance being one or two or more of martensite, bainite and pearlite; the steel structure where the depth from the surface is from the sectional radius R×0.Type: ApplicationFiled: April 1, 2013Publication date: February 12, 2015Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Kei Miyanishi, Atsushi Monden, Shingo Yamasaki, Shunta Homma
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Patent number: 8865061Abstract: The invention relates to a steel alloy for a low alloy steel for producing high-tensile, weldable, hot-rolled seamless steel tubing, in particular construction tubing. The chemical composition (in % by mass) is: 0.15-0.18% C; 0.20-0.40% Si; 1.40-1.60% Mn; max. 0.05% P; max. 0.01% S; >0.50-0.90% Cr; >0.50-0.80% Mo; >0.10-0.15% V; 0.60-1.00% W; 0.0130-0.0220% N; the remainder is made up of iron with production-related impurities; with the optional addition of one or more elements selected from Al, Ni, Nb, Ti, with the proviso that the relationship V/N has a value of between 4 and 12 and the Ni content of the steel is not more than 0.40%.Type: GrantFiled: January 23, 2009Date of Patent: October 21, 2014Assignee: Vallourec Deutschland GmbHInventors: Christoph Kaucke, Guido Kubla, Heinz Sanders, Charles Stallybrass, André Schneider, Markus Schütz
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Patent number: 8801872Abstract: A case hardened gear steel having enhanced core fracture toughness includes by weight percent about 16.3Co, 7.5Ni, 3.5Cr, 1.75Mo, 0.2W, 0.11C, 0.03Ti, and 0.02V and the balance Fe, characterized as a predominantly lath martensitic microstructure essentially free of topologically close-packed (TCP) phases and carburized to include fine M2C carbides to provide a case hardness of at least about 62 HRC and a core toughness of at least about 50 ksi?in.Type: GrantFiled: August 20, 2008Date of Patent: August 12, 2014Assignee: QuesTek Innovations, LLCInventors: James A. Wright, Jason Sebastian
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Patent number: 8709336Abstract: The invention concerns a method for making an abrasion resistant steel plate having a chemical composition comprising: 0.35%?C?0.8%, 0%?Si?2%, 0%?Al?2%, 0.35%?Si+Al?2%, 0%?Mn?2.5%, 0%?Ni?5%, 0%?Cr?5%, 0%?Mo?0.50%, 0%?W?1.00%, 0.1%?Mo+W/2?0.50%, 0%?B?0.02%, 0%?Ti?2%, 0%?Zr?4%, 0.05%?Ti+Zr/2?2%, 0%?S?0.15%, N<0.03%; optionally from 0% to 1.5% of Cu; optionally Nb, Ta or V with Nb/2+Ta/4+V?0.5%; optionally less than 0.1% of Se, Te, Ca, Bi or Pb; the rest being iron and impurities; the composition satisfying: 0.1%?C*=C?Ti/4?Zr/8+7×N/8?0.55% and 1.05×Mn+0.54×Ni+0.50×Cr+0.3×(Mo+W/2)1/2+K>1.8, with K=0.5 if B?0.0005% and K=0 if B<0.0005% and Ti+Zr/2?7×N/2?0.05%; hardening after austenitization while cooling at a speed>0.5° C./s between a temperature>AC3 and ranging between T=800?270×C*?90×Mn?37×Ni?70×Cr?83×(Mo+W/2) and T?50° C.; then at a core speed Vr<115×ep?1.7 between T and 100° C., (ep=plate thickness in mm); cooling down to room temperature. The invention also concerns the resulting plate.Type: GrantFiled: June 17, 2008Date of Patent: April 29, 2014Assignee: Industeel CreusotInventors: Jean Beguinot, Jean-Georges Brisson
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Publication number: 20140065316Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <20 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: ApplicationFiled: August 22, 2013Publication date: March 6, 2014Applicant: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Patent number: 8647449Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are families of alloys capable of forming crack-free weld overlays after multiple welding passes.Type: GrantFiled: March 6, 2012Date of Patent: February 11, 2014Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Patent number: 8562760Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: GrantFiled: November 3, 2010Date of Patent: October 22, 2013Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Patent number: 8562759Abstract: Disclosed herein are iron-based alloys having a structure comprising fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the step determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: GrantFiled: September 17, 2010Date of Patent: October 22, 2013Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Publication number: 20130266820Abstract: A work piece for use in abrasive environments with hardbanding is provided. The work piece has at least a protective layer deposited onto at least a portion to be protected. The deposited layer exhibits a hardness of at least 50 Rc, a wear rate of less than 0.5 grams of mass loss as measured according to ASTM G65-04, Procedure A, a wear rate on a contacting secondary body comprising carbon steel of less than 0.005 grams as measured according to modified ASTM G77 wear test. The deposited alloy forms an iron matrix comprising embedded hard particles in an amount of less than 15 vol. %. The embedded hard particles have an average particle size of ranging from 100 nm to 5 ?m. In one embodiment, the deposition is via welding.Type: ApplicationFiled: April 5, 2012Publication date: October 10, 2013Applicant: c/o Chevron CorporationInventors: Grzegorz Jan Kusinski, Justin Lee Cheney, John Hamilton Madok
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Publication number: 20130017117Abstract: A bearing steel contains C: 0.56% by mass or more and 0.70% by mass or less, Si: 0.15% by mass or more and less than 0.50% by mass, Mn: 0.60% by mass or more and 1.50% by mass or less, Cr: 0.50% by mass or more and 1.10% by mass or less, P: 0.025% by mass or less, S: 0.025% by mass or less, Al: 0.005% by mass or more and 0.500% by mass or less, O: 0.0015% by mass or less, N: 0.0030% by mass or more and 0.015% by mass or less, and a remainder of Fe and incidental impurities. The bearing steel has a composition such that the eutectic carbide formation index Ec satisfies 0<Ec?0.25.Type: ApplicationFiled: November 30, 2010Publication date: January 17, 2013Applicant: JFE Steel CorporationInventors: Minoru Honjo, Kazukuni Hase, Hideto Kimura
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Publication number: 20120321503Abstract: An ingot steel for bearings has a composition containing C: 0.56% by mass or more and 0.70% by mass or less, Si: 0.15% by mass or more and less than 0.50% by mass, Mn: 0.60% by mass or more and 1.50% by mass or less, Cr: 0.50% by mass or more and 1.10% by mass or less, P: 0.025% by mass or less, S: 0.025% by mass or less, Al: 0.005% by mass or more and 0.500% by mass or less, O: 0.0015% by mass or less, N: 0.0030% by mass or more and 0.015% by mass or less, and a remainder of Fe and incidental impurities, wherein eutectic carbide formation index Ec satisfies 0<Ec?0.25.Type: ApplicationFiled: November 30, 2010Publication date: December 20, 2012Inventors: Minoru Honjo, Kazukuni Hase, Hideto Kimura
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Publication number: 20120224992Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are families of alloys capable of forming crack-free weld overlays after multiple welding passes.Type: ApplicationFiled: March 6, 2012Publication date: September 6, 2012Inventors: JUSTIN LEE CHENEY, John Hamilton Madok
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Publication number: 20120014831Abstract: The present invention provides a wire rod with a composition at least including: C: 0.95-1.30 mass %; Si: 0.1-1.5 mass %; Mn: 0.1-1.0 mass %; Al: 0-0.1 mass %; Ti: 0-0.1 mass %; P: 0-0.02 mass %; S: 0-0.02 mass %; N: 10-50 ppm; O: 10-40 ppm; and a balance including Fe and inevitable impurities, wherein 97% or more of an area in a cross-section perpendicular to the longitudinal direction of the wire rod is occupied by a pearlite, and 0.5% or less of an area in a central area in the cross-section and 0.5% or less of an area in a first surface layer area in the cross-section are occupied by a pro-eutectoid cementite.Type: ApplicationFiled: October 19, 2010Publication date: January 19, 2012Inventors: Shingo Yamasaki, Toshiyuki Manabe, Daisuke Hirakami, Nariyasu Muroga
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Publication number: 20110274578Abstract: The present invention is steel for surface hardening for machine structural use which contains, by mass %, C: 0.3 to 0.6%, Si: 0.02 to 2.0%, Mn: 0.35 to less than 1.5%, and Al: 0.01 to 0.5%, is restricted to B: less than 0.0003%, S: 0.0001 to 0.021%, N: 0.003 to 0.0055%, P: 0.0001 to 0.03%, and O: 0.0001 to 0.0050%, has a ratio Mn/S of Mn and S satisfying 70 to 30,000, has a balance of Fe and unavoidable impurities, and, when nitrided, then induction hardened, has a surface hardenability of a Vicker's hardness when tempered at 300° C. of 650 or more.Type: ApplicationFiled: January 15, 2010Publication date: November 10, 2011Inventors: Atsushi Mizuno, Masayuki Hashimura, Kei Miyanishi, Shuji Kozawa
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Publication number: 20110129381Abstract: The present invention provides a high-tensile steel material having a tensile strength of the 550 MPa class or more which can simultaneously raise the strength and toughness of the heat affected zone of weld to equal those of the matrix and a method of production of the same, that is, a high-tensile steel material with excellent weldability and toughness and with tensile strength of the 550 MPa class or more containing, by mass %, C: 0.005 to 0.10%, W: 0.10 to 3.0%, Nb: 0.010 to 0.080%, and V: 0.010 to 0.50%, limiting the Ti to less than 0.005%, satisfying equation; EC=2[C]?[Nb]/9?[V]/12>0.020, having an amount of precipitation of W contained in the steel material, in terms of analytical value obtained by quantitative analysis of potential electrolysis extraction residue by fluorescent X-ray analysis, of 0.0050% or less, and having 60% or more of its structural composition in a cross-section of the steel as a bainite structure.Type: ApplicationFiled: May 2, 2005Publication date: June 2, 2011Applicant: NIPON STEEL CORPORATIONInventors: Yasushi Hasegawa, Naoki Saitoh, Youichi Tanaka
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Publication number: 20110121056Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: ApplicationFiled: November 3, 2010Publication date: May 26, 2011Inventors: Justin Lee Cheney, John Hamilton Madok
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Publication number: 20110068152Abstract: Disclosed herein are iron-based alloys having a structure comprising fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferrific matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the step determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: ApplicationFiled: September 17, 2010Publication date: March 24, 2011Inventors: Justin Lee Cheney, John Hamilton Madok
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Publication number: 20110008647Abstract: This cold-rolled steel sheet includes, in terms of mass %, C: not less than 0.05% and not more than 0.095%, Cr: not less than 0.15% and not more than 2.0%, B: not less than 0.0003% and not more than 0.01%, Si: not less than 0.3% and not more than 2.0%, Mn: not less than 1.7% and not more than 2.6%, Ti: not less than 0.005% and not more than 0.14%, P: not more than 0.03%, S: not more than 0.01%, Al: not more than 0.1%, N: less than 0.005%, O: not less than 0.0005% and not more than 0.005%, and contains as the remainder, iron and unavoidable impurities, wherein the microstructure of the steel sheet includes mainly polygonal ferrite having a crystal grain size of not more than 4 ?m, and hard microstructures of bainite and martensite, the block size of the martensite is not more than 0.9 ?m, the Cr content within the martensite is 1.1 to 1.5 times the Cr content within the polygonal ferrite, and the tensile strength is at least 880 MPa.Type: ApplicationFiled: March 26, 2009Publication date: January 13, 2011Inventors: Masafumi Azuma, Naoki Yoshinaga, Naoki Maruyama, Noriyuki Suzuki, Yasuharu Sakuma
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Patent number: 7820098Abstract: In the thermal power system, the electricity production efficiency may be improved by providing turbine members having the improved high temperature characteristic over the corresponding prior art turbine members. Turbine members may be provided by using high resistant steels composed of any one or ones selected from the group consisting of the components, including 0.08 to 0.13% of carbon (C), 8.5 to 9.8% of chromium (Cr), 0 to 1.5% of molybdenum (Mo), 0.10 to 0.25% of vanadium (V), 0.03 to 0.08% of niobium (Nb), 0.2 to 5.0% of tungsten (W), 1.5 to 6.0% of cobalt (Co), 0.002 to 0.015% of boron (B), 0.015 to 0.025% of nitrogen (N), and optionally, 0.01 to 3.0% of rhenium (Re), 0.1 to 0.50% of silicon (Si), 0.1 to 1.0% of manganese (Mo), 0.05 to 0.8% of nickel (Ni) and 0.1 to 1.3% of cupper.Type: GrantFiled: August 16, 2001Date of Patent: October 26, 2010Assignees: The Japan Steel Works, Ltd., The Kansai Electric Power Co., Inc.Inventors: Masahiko Morinaga, Yoshinori Murata, Tsukasa Azuma, Kazuhiro Miki, Tohru Ishiguro, Ryokichi Hashizume
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Publication number: 20100196189Abstract: A high-strength steel sheet has high stretch flangeability after working and corrosion resistance after painting. The steel sheet contains, on the basis of mass percent, C: 0.02% to 0.20%, Si: 0.3% or less, Mn: 0.5% to 2.5%, P: 0.06% or less, S: 0.01% or less, Al: 0.1% or less, Ti: 0.05% to 0.25%, and V: 0.05% to 0.25%, the remainder being Fe and incidental impurities. The steel sheet has a substantially ferritic single phase, the ferritic single phase containing precipitates having a size of less than 20 nm, the precipitates containing 200 to 1750 mass ppm Ti and 150 to 1750 mass ppm V, V dissolved in solid solution being 200 or more but less than 1750 mass ppm.Type: ApplicationFiled: July 31, 2008Publication date: August 5, 2010Applicant: JFE STEEL CORPORATIONInventors: Koichi Nakagawa, Takeshi Yokota, Nobuyuki Nakamura, Kazuhiro Seto, Satoshi Kinoshiro, Katsumi Yamada
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Publication number: 20100047617Abstract: Steel sheet having a composition of ingredients containing substantially, by mass %, C: 0.005 to 0.200%, Si: 2.50% or less, Mn: 0.10 to 3.00%, N: 0.0100% or less, Nb: 0.005 to 0.100%, and Ti: 0.002 to 0.150% and satisfying the relationship of Ti-48/14×N?0.0005, having a sum of the X-ray random intensity ratios of the {100}<001> orientation and the {110}<001> orientation of a ? sheet thickness part of 5 or less, having a sum of the maximum value of the X-ray random intensity ratios of the {110}<111> to {110}<112> orientation group and the X-ray random intensity ratios of the {211}<111> orientation of 5 or more, and having a high rolling direction Young's modulus measured by the static tension method and a method of production of the same are provided.Type: ApplicationFiled: November 7, 2007Publication date: February 25, 2010Inventors: Natsuko Sugiura, Naoki Maruyama, Manabu Takahashi, Yohji Nakamura, Koji Hanya
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Publication number: 20100028196Abstract: The present invention provides a high strength heat treated steel wire for spring having a tensile strength of 2000 MPa or more which is coiled in the cold state and can achieve both sufficient atmospheric strength and coilability and spring steel used for that steel wire, that is, a high strength heat treated steel wire for a spring characterized by comprising, by mass %, C: 0.5 to 0.9%, Si: 1.0 to 3.0%, Mn: 0.1 to 1.5%, Cr: 1.0 to 2.5%, V: over 0.15 to 1.0%, and Al: 0.005% or less, controlling N to 0.007% or less, further containing one or two of Nb: 0.001 to less than 0.01% and Ti: 0.001 to less 0.005%, and having a tensile strength of 2000 MPa or more, having cementite-based spheroidal carbides and alloy-based spheroidal carbides in a microscopic visual field satisfying an area percentage of carbides with a circle equivalent diameter of 0.Type: ApplicationFiled: November 9, 2006Publication date: February 4, 2010Inventors: Masayuki Hashimura, Hiroshi Hagiwara, Takayuki Kisu, Kouichi Yamazaki, Tatsuroi Ochi, Takashi Fujita
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Publication number: 20090274572Abstract: The invention provides a high-strength pearlitic steel rail, which is inexpensive, and has a tensile strength of 1200 MPa or more, and is excellent in delayed fracture properties. Specifically, the rail contains, in mass percent, C of 0.6 to 1.0%, Si of 0.1 to 1.5%, Mn of 0.4 to 2.0%, P of 0.035% or less, S of 0.0005 to 0.010%, and the remainder is Fe and inevitable impurities, wherein tensile strength is 1200 MPa or more, and size of a long side of an A type inclusion is 250 mm or less in at least a cross-section in a longitudinal direction of a rail head, and the number of A type inclusions, each having a size of a long side of 1 mm to 250 mm, is less than 25 per observed area of 1 mm2 in the cross-section in the longitudinal direction of the rail head.Type: ApplicationFiled: March 16, 2007Publication date: November 5, 2009Applicant: JFE Steel CorporationInventors: Minoru Honjo, Tatsumi Kimura, Shinichi Suzuki, Nobuo Shikanai
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Publication number: 20090238713Abstract: The invention relates to an ultrahigh-strength thin steel sheet excellent in the hydrogen embrittlement resistance, the steel sheet including, by weight %, 0.10 to 0.60% of C, 1.0 to 3.0% of Si, 1.0 to 3.5% of Mn, 0.15% or less of P, 0.02% or less of S, 1.5% or less of Al, 0.003 to 2.0% of Cr, and a balance including iron and inevitable impurities; in which grains of residual austenite have an average axis ratio (major axis/minor axis) of 5 or more, the grains of the residual austenite have an average minor axis length of 1 ?m or less, and the grains of the residual austenite have a nearest-neighbor distance between the grains of 1 ?m or less.Type: ApplicationFiled: December 28, 2006Publication date: September 24, 2009Applicants: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.), Shinshu TLO Co., Ltd.Inventors: Junichiro Kinugasa, Fumio Yuse, Yoichi Mukai, Shinji Kozuma, Hiroshi Akamizu, Kouji Kasuya, Muneaki Ikeda, Koichi Sugimoto
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Patent number: 7575646Abstract: The present invention provides a steel wire, for springs excellent in coiling property while having a high strength, as a heat treated steel wire for high strength springs, characterized by: comprising, in mass, C: 0.75 to 0.85%, Si: 1.5 to 2.5%, Mn: 0.5 to 1.0%, Cr: 0.3 to 1.0%, P: not more than 0.015%, S: not more than 0.015%, N: 0.001 to 0.007%, W: 0.05 to 0.3%, and the balance consisting of Fe and unavoidable impurities; having a tensile strength of not less than 2,000 MPa; spheroidal carbides, composed of mainly cementite, observed in a microscopic visual field satisfying the area percentage of the spheroidal carbides not less than 0.2 ?m in circle equivalent diameter being not more than 7%, the density of the spheroidal carbides 0.2 to 3 ?m in circle equivalent diameter being not more than 1 piece/?m2, and the density of the spheroidal carbides over 3 ?m in circle equivalent diameter being not more than 0.Type: GrantFiled: February 7, 2002Date of Patent: August 18, 2009Assignee: Nippon Steel CorporationInventors: Masayuki Hashimura, Takanari Miyaki, Hiroshi Hagiwara, Hiroaki Hayashi, Shouich Suzuki, Katsuaki Shiiki, Noriyuki Yamada, Seiichi Koike
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Patent number: 7537727Abstract: The present invention relates to a low alloy, low to medium carbon content, high strength, and high ductility steel composition. The present invention contains relatively low nickel content, yet exhibits high performance characteristics and is manufactured at a substantially lower cost than alloy compositions containing high levels of nickel.Type: GrantFiled: January 21, 2004Date of Patent: May 26, 2009Assignee: Ellwood National Forge CompanyInventors: Morris Dilmore, James D. Ruhlman
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Publication number: 20090092516Abstract: The present invention provides spring use heat treated steel which is cold coiled, can achieve both sufficient atmospheric strength and coilability, has a tensile strength of 2000 MPa or more, and can improve the performance as a spring by heat treatment after spring fabrication, that is, high strength spring-use heat treated steel characterized by containing, by mass %, C: 0.45 to 0.9%, Si: 1.7 to 3.0%, and Mn: 0.1 to 2.0%, restricting N: to 0.007% or less, having a balance of Fe and unavoidable impurities, and satisfying, in terms of the analyzed value of the extracted residue after heat treatment, [amount of Fe in residue on 0.2 ?m filter/[steel electrolysis amount]×100?1.1.Type: ApplicationFiled: March 29, 2007Publication date: April 9, 2009Inventors: Masayuki Hashimura, Tatsuro Ochi, Takayuki Kisu, Hiroshi Hagiwara
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Patent number: 7494618Abstract: To provide an alloy tool steel having high-temperature strength at an operating temperature of the order of 700° C., while maintaining room-temperature strength as high as that of a conventional matrix high-speed tool steel. The steel contains from 0.45 wt % to 0.65 wt % C, from 0.10 wt % to 1.00 wt % Si, from 0.20 wt % to 2.00 wt % Mn, not more than 0.020 wt % P, not more than 0.015 wt % S, not more than 1.00 wt % Cu, not more than 1.00 wt % Ni, from 3.50 wt % to 5.00 wt % Cr, from 0.00 wt % to 3.00 wt % Mo, from 0.00 wt % to 10.00 wt % W, from 1.00 wt % to 2.00 wt % V, from 0.00 wt % to 8.00 wt % Co, not more than 0.10 wt % Al, not more than 0.01 wt % O, not more than 0.02 wt % N, and the balance substantially constituted of Fe and unavoidable impurities, in which Weq is from 2.0 to 10.0, 2Mo/Weq is not more than 0.60, and ?C is from ?0.3 to 0.0.Type: GrantFiled: December 7, 2004Date of Patent: February 24, 2009Assignee: Daido Tokushuko Kabushiki KaishaInventor: Kozo Ozaki
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Patent number: 7074286Abstract: A high-strength, high-toughness steel alloy includes, generally, about 2.5% to about 4% chromium, about 1.5% to about 3.5% tungsten, about 0.1% to about 0.5% vanadium, and about 0.05% to 0.25% carbon with the balance iron, wherein the percentages are by total weight of the composition, wherein the alloy is heated to an austenitizing temperature and then cooled to produce an austenite transformation product.Type: GrantFiled: December 18, 2002Date of Patent: July 11, 2006Assignee: UT-Battelle, LLCInventors: Ronald L. Klueh, Philip J. Maziasz, Vinod Kumar Sikka, Michael L. Santella, Sudarsanam Suresh Babu, Maan H. Jawad
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Patent number: 6942741Abstract: An iron alloy strip having a gage of 0.1 to 5 mm and a magnetic field strength variation within the strip of 0 to 10 Hz, made of an iron alloy consisting essentially of, in % by weight, 0.0001-0.02% of C, 0.0001-5% of Si, 0.001-0.2% of Mn, 0.0001-0.05% of P, 0.0001-0.05% of S, 0.0001-5% of Al, 0.001-0.1% of O, 0.0001-0.03% of N, 0-10% of Co, 0-10% of Cr, 0.01-5% in total of Ti, Zr, Nb, Mo, V, Ni, W, Ta and/or B, and the balance of Fe, and having a saturation magnetic flux density of 1.7-2.3 Tesla, a maximum relative permeability of 1,200-22,000 and a coercive force of 20-380 A/m is suited for use as yokes in voice coil motor magnetic circuits. The iron alloy strip is highly resistant to corrosion and eliminates a need for a corrosion resistant coating.Type: GrantFiled: August 7, 2002Date of Patent: September 13, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masanobu Shimao, Masaaki Nishino, Takehisa Minowa
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Patent number: 6841122Abstract: A hot working die steel contains 0.05-0.25% C, 0.30% or less Si, 0.03% or less Mn, 1.0% or less Ni, 5.0-13.0 % Cr, 2.0% or less Mo, 1.0-8.0% W, 1.0-10.0% Co, 0.003-0.020% B, 0.005-0.050% N, and the balance consisting essentially of Fe and unavoidable impurities. If desired, the hot working die steel may further contain 0.01-1.0% V and 0.01-1.0% of at least one kind selected from Nb and Ta.Type: GrantFiled: April 29, 2002Date of Patent: January 11, 2005Assignee: The Japan Steel Works, Ltd.Inventors: Rinzo Kayano, Eiji Maeda
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Patent number: 6821360Abstract: A heat-resisting steel comprising 0.15-0.30 wt. % C, 0.05-0.3 wt. % Si, 0.01-0.7 wt. % Mn, 1.8-2.5 wt. % Cr, 0.15-0.23 wt. % V, 1.5-2.5 wt. % W, 0.01-0.02 wt. % Ti, 0.01-0.08 wt. % Nb, 0.005-0.03 wt. % N, 0.001-0.015 wt. % B, and Fe and unavoidable impurities as the remainder; a heat-resisting steel comprising 0.15-0.30 wt. % C, 0.05-0.3 wt. % Si, 0.01-0.7 wt. % Mn, 1.8-2.5 wt. % Cr, 0.15-0.23 wt. % V, 1.5-2.5 wt. % W, 0.3-0.8 wt. % Mo, 0.01-0.02 wt. % Ti, 0.01-0.08 wt. % Nb, 0.005-0.03 wt. % N, 0.001-0.015 wt. % B, and Fe and unavoidable impurities as the remainder; and a heat-resisting steel that is obtained by subjecting one of the above heat-resisting steels to a heat treatment comprising the step of oil-cooling the heat-resisting steel to a temperature of 300° C. or lower. These heat-resisting steels are excellent in both high-temperature strength and impact properties.Type: GrantFiled: November 29, 2000Date of Patent: November 23, 2004Assignee: Kabushiki Kaisha ToshibaInventors: Ryuichi Ishii, Yoichi Tsuda, Masayuki Yamada
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Publication number: 20040118490Abstract: A high-strength, high-toughness steel alloy includes, generally, about 2.5% to about 4% chromium, about 1.5% to about 3.5% tungsten, about 0.1% to about 0.5% vanadium, and about 0.05% to 0.25% carbon with the balance iron, wherein the percentages are by total weight of the composition, wherein the alloy is heated to an austenitizing temperature and then cooled to produce an austenite transformation product.Type: ApplicationFiled: December 18, 2002Publication date: June 24, 2004Inventors: Ronald L. Klueh, Philip J. Maziasz, Vinod Kumar Sikka, Michael L. Santella, Sudarsanam Suresh Babu, Maan H. Jawad
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Patent number: 6482354Abstract: A tool steel alloy having a unique combination of hardness and toughness is disclosed. The alloy contains, in weight percent, about: wt. % C 1.85-2.30, Mn 0.15-1.0, Si 0.15-1.0, P 0.030 max., S 0-0.30, Cr 3.7-5.0, Ni+Cu 0.75 max., Mo 1.0 max., Co 6-12, W 12.0-13.5, V 4.5-7.5. The balance is essentially iron and usual impurities. The elements C, Cr, Mo, W, and V are balanced in this alloy such that −0.05≦&Dgr;C≦−0.42 where &Dgr;C=((0.033W)+(0.063Mo)+(0.06Cr)+(0.2V))−C. A powder metallurgy tool steel article made from consolidated alloy powder having the aforesaid weight percent composition provides a Rockwell C hardness of at least about 69.5 when heat treated.Type: GrantFiled: July 26, 2001Date of Patent: November 19, 2002Assignee: CRS Holdings, Inc.Inventors: David E. Wert, Gregory J. Del Corso, Harrison A. Garner, Jr.
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Patent number: 6096262Abstract: A martensitic heat resisting steel having improved heat resistance, which consists by weight percentage of 0.35%.ltoreq.C.ltoreq.0.60%, 1.0%.ltoreq.Si.ltoreq.2.5%, 0.1%.ltoreq.Mn<1.5%, 7.5%.ltoreq.Cr.ltoreq.13.0%, one or both of 1.0%.ltoreq.Mo.ltoreq.3.0% and 1.0%.ltoreq.W.ltoreq.3.0% so that 1.5%.ltoreq.(Mo+0.5W).ltoreq.3.0%, optionally 0.1%.ltoreq.Nb+Ta.ltoreq.1.0%, 0.1%.ltoreq.V.ltoreq.1.0% and S.ltoreq.0.1%, and the remainder is substantially Fe.Type: GrantFiled: May 4, 1999Date of Patent: August 1, 2000Assignee: Daido Tokushuko Kabushiki KaishaInventors: Shigeki Ueta, Toshiharu Noda, Michio Okabe
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Patent number: 6057045Abstract: A powder-metallurgy produced high-speed steel article having a combination of high hardness and wear resistance, particularly at elevated temperatures. This combination of properties is achieved by the combination of W, Mo, V, and Co. The article is particularly suitable for use in the manufacture of gear cutting tools, such as hobs, and surface coatings.Type: GrantFiled: October 14, 1997Date of Patent: May 2, 2000Assignee: Crucible Materials CorporationInventors: Andrzej L. Wojcieszynski, William Stasko
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Patent number: 5830287Abstract: A hot-worked, fully dense, wear resistant, vanadium-rich, powder metallurgy cold work tool steel article having improved impact toughness. This is achieved by controlling the amount, composition and size of the primary carbides and by insuring that substantially all the primary carbides remaining after hardening and tempering are MC-type vanadium-rich carbides. The article is produced by hot isostatic compacting of nitrogen atomized powder particles.Type: GrantFiled: April 9, 1997Date of Patent: November 3, 1998Assignee: Crucible Materials CorporationInventors: Kenneth E. Pinnow, William Stasko
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Patent number: 5817191Abstract: An iron-based, cobalt-containing soft magnetic alloy suitable for use as a core in a magnetic switch or other exciting circuits has a cobalt content of 6 through 30 weight percent, at least one of the elements chromium, molybdenum, vanadium and tungsten in range of 3 through 8 weight percent, and a remainder iron, possibly including inconsequential contaminants. The alloy has a coercive field strength of lower than or equal to 3.2 A/cm, and a saturation flux density of greater than 1.9 Tesla.Type: GrantFiled: August 26, 1997Date of Patent: October 6, 1998Assignee: Vacuumschmelze GmbHInventors: Kurt Emmerich, Hartwin Weber, Hermann Wegerle
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Patent number: 5753005Abstract: A source powder for a wear-resistant sintered material, consisting essentially of, in weight percentages, Cr: 3.0 to 6.0%, 2 Mo+W: 10.0 to 20.0%, V: 1.0 to 8.0%, Co: 10.0% or below, C: 0.20% to {0.01(2 Mo+W)+0.24 V}%, Si: 0.1 to 1.0%, Mn: 0.1 to 1.0% and the balance being Fe and unavoidable impurities, or one prepared by adding 0.10 to 0.8% of S to the above composition. This powder can be compacted into a green compact having a high green density, which can further give a wear-resistant sintered material having a high sintered density, hardness and strength.Type: GrantFiled: January 10, 1997Date of Patent: May 19, 1998Assignees: Hitachi Powdered Metals Co., Ltd., Mitsubishi Steel Mfg. Co., Ltd.Inventors: Yoshimasa Aoki, Kei Ishii, Yukio Tokuyama, Yuji Soda
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Patent number: 5746843Abstract: A low Mn-low Cr ferritic heat resistant steel consisting essentially of, in weight %: 0.02-0.20% C, up to 0.7% Si, less than 0.1% Mn, up to 0.8% Ni, 0.8-3.5% Cr, 0.01-3.0% W, 0.1-0.5% V, 0.01-0.20% Nb, 0.001-0.05% Al, 0.0005-0.05% Mg, 0.0005-0.01% B, less than 0.05% N, up to 0.03% P, up to 0.015% S, 0.001-0.05% Ti and the balance Fe and incidental impurities, wherein the B content is defined so as to satisfy the following formula (14/11)B>N-N(V/51)/{(C/12)+(N/14)}-N(Nb/93)/{(C/12)+(N/14)}-N(Ti/48)/{C/12 )+(N/14)}. The steel can further contain optionally 0.01-1.5% Mo, and/or one or more elements selected from the group consisting of 0.01-0.2% La, 0.01-0.2% Ce, 0.01-0.2% Y, 0.01-0.2% Ca, 0.01-0.2% Ta and 0.01-0.2% Zr. The steel can be used in place of the austenitic steels or high Cr ferritic steels, since it has remarkably improved toughness, workability and weldability, and excellent creep properties at elevated temperatures.Type: GrantFiled: February 10, 1997Date of Patent: May 5, 1998Assignees: Sumitomo Metal Industries, Ltd., Mitsubishi Jukogyo Kabushiki KaishaInventors: Kaori Miyata, Masaaki Igarashi, Fujimitsu Masuyama, Nobuyoshi Komai, Tomomitsu Yokoyama
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Patent number: 5201965Abstract: A heat-resistant cast steel having a metal matrix substantially consisting of a ferrite phase and a pearlitic-colony phase has a composition consisting essentially, by weight, of C: 0.05-0.25%, Si:2.5-3.5%, Mn:2% or less, Cr:4-8%, N:0.05% or less, and Fe and inevitable impurities: balance, as well as at least one selected from the group consisting of (i) W and/or Co:0.1-2%, (ii) a rare earth element and/or Y:0.1% or less, (iii) Mg and/or Ca:0.005-0.03%, and (iv) B:0.001-0.01%.Type: GrantFiled: April 14, 1992Date of Patent: April 13, 1993Assignee: Hitachi Metals, Ltd.Inventors: Koki Ohtsuka, Norio Takahashi
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Patent number: 5032356Abstract: A high fatigue strength metal band saw backing material of the present invention comprises 0.27 to 0.40% of C, not more than 0.35% of Si, 0.3 to 1.2% of Mn, 0.45 to 0.75% of Ni, more than 3.0% to 4.5% of Cr, 1.5 to 2.3% of one or two of Mo and W in terms of "Mo+W/2", 0.03 to 0.2% of one or two of V and Nb in terms of "V+Nb/2", in terms of percent by weight, the balance Fe and inevitable impurities. The metal band saw can maintain its high fatigue strength even if it is subjected to heat treatment under the same conditions as those for high speed steel used as an edge material and thus exhibits excellent properties as a metal band saw backing material.Type: GrantFiled: April 17, 1990Date of Patent: July 16, 1991Assignee: Hitachi Metals, Ltd.Inventors: Atushi Kumagai, Toshio Okuno, Yoshihiro Minagi, Katuaki Fukushima
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Patent number: 4729872Abstract: Isotropic tool steel consisting essentially of necessary elements as tool steel, less than 0.005 weight % of S and less than 30 ppm of O, the balance being substantially Fe. The necessary elements are, by weight, 0.10-0.70% of C, 2.00% or less of Si, 2.00% or less of Mn, 7.00% or less of Cr, 0.20-12.00% of W and/or Mo alone or in combination (1/2W+Mo), 3.00% or less of V. They may further include at least one of 4.00% or less of Ni, 6.50% or less of Co and 0.20% or less of N. The isotropic tool steel has cleanliness with respect to non-metallic inclusions defined by JIS G 0555 of dA60.times.400.ltoreq.0.010% and d(B+C)60.times.400.ltoreq.0.020%, and a ratio of transverse direction toughness to longitudinal direction toughness of more than 0.70. Since it is highly resistant to the generation and propagation of cracks and fracture, dies for hot working made therefrom can enjoy a long life.Type: GrantFiled: September 10, 1986Date of Patent: March 8, 1988Assignee: Hitachi Metals, Ltd.Inventors: Tamiya Kishida, Mitsuru Suzuki, Toshio Okuno, Atsusuke Nakao
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Patent number: H326Abstract: Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.Type: GrantFiled: June 23, 1986Date of Patent: September 1, 1987Assignee: The United States of America as represented by the United States Department of EnergyInventors: Howard R. Brager, Francis A. Garner