Vanadium, Tantalum Or Niobium Containing Patents (Class 420/127)
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Patent number: 11462344Abstract: A method of heat-treating an additively-manufactured ferromagnetic component is presented. The additively-manufactured ferromagnetic component includes a metal alloy having iron and cobalt. The method of heat-treating is performed such that a saturation flux density of a heat-treated ferromagnetic component is greater than a saturation flux density of an as-formed ferromagnetic component. The heat-treated ferromagnetic component has a microstructure having an average grain size of substantially all grains in a range of about 0.1 micron to about 25 microns. A ferromagnetic component is also presented.Type: GrantFiled: July 30, 2019Date of Patent: October 4, 2022Assignee: General Electric CompanyInventors: Raghavendra Rao Adharapurapu, Sudeep Pradhan Sadananda Rao, Reshma Saira Mathew, Min Zou
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Patent number: 10513762Abstract: A cold-rolled flat steel product for deep drawing applications including in addition to Fe and unavoidable impurities (in % by weight) C: 0.008%-0.1%, Al: 6.5%-12%, Nb: 0.1%-0.2%, Ti: 0.15-0.5%, P: <0.1%, S: <0.03%, N: <0.1% and optionally one or more elements from the group of Mn, Si, REM, Mo, Cr, Zr, V, W, Co, Ni, B, Cu, Ca, N, where 2.5?% Ti/% Nb?1.5. Also a method of producing such a flat steel product including casting a pre-product, which is then hot-rolled into a hot strip with a hot rolling end temperature of 820-1000° C. and wound at a winding temperature of up to 750° C. After winding, the hot strip is annealed at an annealing temperature of >650-1200° C. for 1-50 h, then cold-rolled in one or more stages with a total cold rolling level of ?65% and finally annealed at 650-850° C.Type: GrantFiled: February 13, 2014Date of Patent: December 24, 2019Assignee: THYSSENKRUPP STEEL EUROPE AGInventors: Evgeny Balichev, Harald Hofmann, Jose Jimenez
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Patent number: 9340860Abstract: A high strength cold-rolled steel sheet and a high strength plated steel sheet which have an excellent surface appearance required for outer panels of automobiles and which have an extremely high r value in a direction at 45° with respect to the rolling direction and which have excellent press formability and a tensile strength of at least 340 MPa and a process for their manufacture are provided. The steel sheets have a chemical composition consisting essentially of, in mass %, C: 0.0005-0.025%, Si: at most 0.2%, Mn: 0.3-2.5%, P: at most 0.15%, S: at most 0.02%, N: at most 0.006%, sol. Al: less than 0.005%, Ti: 0.005-0.05%, and Nb: 0.020-0.200% with the mass ratio (Nb/Ti) of the contents of Nb and Ti being at least 2, and a remainder of Fe and impurities, and they have an r value in a direction at 45° with respect to the rolling direction (r45) of at least 1.80 and/or a mean r value (rm) of at least 1.60, and a tensile strength of at least 340 MPa.Type: GrantFiled: September 4, 2009Date of Patent: May 17, 2016Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Seiji Furuhashi, Jun Haga, Takayuki Nishi
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Patent number: 9227847Abstract: A method for preparing vanadium-nitrogen alloy, the method including: 1) mixing and pressing a vanadium-containing compound, an agglutinant, and a carbon-premixed reducing agent to yield a spherical raw material, and air drying the spherical raw material; and 2) mixing the spherical raw material with a granular carbonaceous reducing agent to yield a mixture, and continually feeding the mixture into a shaft kiln of a medium frequency induction furnace, purging the shaft kiln with pure nitrogen and maintaining a furnace pressure at between 0.01 and 0.03 mPa, drying the mixture at a temperature of between 100 and 600° C., carbonizing and nitriding at a temperature of between 900 and 1350° C., cooling the resulting product to less than 100° C., and discharging the product.Type: GrantFiled: October 9, 2013Date of Patent: January 5, 2016Inventor: Jianwei Zheng
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Patent number: 9180553Abstract: A welding electrode hybrid laser arc welding is provided which is either a solid or metal core electrode. The electrode contains at least carbon, manganese, silicon, sulfur and phosphorus. The electrode has is no more than 0.02% carbon, manganese in the range of 0.6 to 1.2%, silicon in the range of 0.3 to 0.6%, no more than 0.01% sulfur, and no more than 0.01% phosphorus in % by weight of the electrode.Type: GrantFiled: September 29, 2011Date of Patent: November 10, 2015Assignee: Lincoln Global, Inc.Inventors: Marie Annette Quintana, Vaidyanath Bharata Rajan
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Patent number: 9115415Abstract: A case hardened steel with excellent cold forgeability and excellent impact properties after case hardening processing contains C, Si, Mn, S, Cr, Al, Ti, Nb, B, and N, with the balance being iron and unavoidable impurities. Of precipitates containing Ti and/or Nb, precipitates having a size of not less than 20 ?m2 are at a number density of not more than 1.0/mm2. Of precipitates containing Ti and/or Nb, precipitates having a size of more than 5 ?m2 and less than 20 ?m2 and containing Mn and S are at a number density of more than 0.7/mm2 and not more than 3.0/mm2. The ferrite fraction is more than 77% by area.Type: GrantFiled: August 10, 2011Date of Patent: August 25, 2015Assignee: Kobe Steel, Ltd.Inventors: Nariaki Okamoto, Mutsuhisa Nagahama
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Publication number: 20150079420Abstract: The steel for hot forming has the following composition in weight %: C: 0.10-0.25, Mn: 1.4-2.8, Si: ?1.0, Cr: ?1.0, Ti: ?0.05, Nb: ?0.05, V: ?0.1, Mo: ?0.1, Al: ?0.05, P: ?0.02, S: ?0.005, Ca: ?0.005, O: ?0.01, N: ?0.02, B: ?0.0004, the remainder being iron and unavoidable impurities. Also disclosed is a strip, sheet or blank produced with such a steel, a method for producing a hot formed product, such a product and the use thereof.Type: ApplicationFiled: September 17, 2014Publication date: March 19, 2015Inventors: David Neal HANLON, Stefanus Matheus Cornelis VAN BOHEMEN
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Patent number: 8961816Abstract: Getter devices based on powders of alloys particularly suitable for hydrogen and nitrogen sorption are described. Such alloys have a composition including zirconium, vanadium, titanium and, optionally, one or more elements selected from iron, chromium, manganese, cobalt, nickel and aluminum.Type: GrantFiled: May 13, 2013Date of Patent: February 24, 2015Assignee: Saes Getters S.p.A.Inventors: Alberto Coda, Alessandro Gallitognotta, Antonio Bonucci, Andrea Conte
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Publication number: 20150044086Abstract: A steel wire rod or steel bar as hot-rolled, including: by mass %: C: 0.1 to 0.6%, Si: 0.01 to 1.5%, Mn: 0.05 to 2.5%, Al: 0.015 to 0.3%, and N: 0.0040 to 0.0150%, and P: limited to 0.035% or less and S: limited to 0.025% or less, and the balance substantially consisting of iron and unavoidable impurities, wherein a depth of d (mm) from the surface of the surface layer region with 20 HV 0.2 or more higher, relative to HV 0.2 that is the average hardness in the region where the depth from the surface is from sectional radius R×0.5 (mm) to the center satisfies the formula (1); the steel structure of the surface layer region has a ferrite fraction of 10% or less by area ratio, with the balance being one or two or more of martensite, bainite and pearlite; the steel structure where the depth from the surface is from the sectional radius R×0.Type: ApplicationFiled: April 1, 2013Publication date: February 12, 2015Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Kei Miyanishi, Atsushi Monden, Shingo Yamasaki, Shunta Homma
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Publication number: 20150038317Abstract: A molten bath-based direct smilting process comprises controlling the process conditions in a direct smelting vessel so that molten slag in a molten bath of metal and slag in the vessel has a viscosity in a range of 0.5-5 poise when the slag temperature is in the range of 1400-1550° C. in the molten bath in the vessel.Type: ApplicationFiled: October 20, 2014Publication date: February 5, 2015Inventors: Rodney James Dry, Jacques Pilote
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Publication number: 20150034049Abstract: A rolled steel bar for hot forging consisting, by mass percent, of C: 0.25-0.50%, Si: 0.40-1.0%, Mn: 1.0-1.6%, S: 0.005-0.035%, Al: 0.005-0.050%, V: 0.10-0.30%, and N: 0.005-0.030%, and the balance of Fe and impurities, i.e., P: 0.035% or less and O: 0.0030% or less, wherein Fn1=C+Si/10+Mn/5+5Cr/22+1.65V?5S/7 is 0.90 to 1.20. The predicted maximum width of nonmetallic inclusions at the time when a cumulative distribution function obtained by extreme value statistical processing by taking the width of nonmetallic inclusion in an R1/2 part of a longitudinal cross section of the steel bar as W (mm) is 99.99% is 100 mm or narrower. The number density of sulfides each having a circle-equivalent diameter of 0.3 to 1.0 mm observed per unit area of the R1/2 part of a transverse cross section of the steel bar is 500 pieces/mm2 or higher.Type: ApplicationFiled: February 5, 2013Publication date: February 5, 2015Inventors: Naoki Matsui, Masashi Higashida, Hitoshi Matsumoto, Yutaka Neishi, Talzo Makino, Kouji Morita, Yoshihiro Tanimura, Naoyuki Sashima, Toshimasa Itou
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Publication number: 20150028724Abstract: A product, such as one or more thin sheets, each containing a single or near-single crystalline inclusion-containing magnetic microstructure, is provided. In one embodiment, the inclusion-containing magnetic microstructure is a Galfenol-carbide microstructure. Various methods and devices, as well as compositions, are also described.Type: ApplicationFiled: January 31, 2013Publication date: January 29, 2015Inventors: Eric Summers, Rob Meloy
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Publication number: 20150024237Abstract: A hot stamping steel material, which secures good hydrogen embrittlement resistance even when the steel sheet after hot stamping is subjected to processing leading to remaining of stress, such as piercing and which is easily practicable, wherein the steel sheet has the chemical composition of: C: 0.18 to 0.26%; Si: more than 0.02% and not more than 0.05%; Mn: 1.0 to 1.5%; P: 0.03% or less; S: 0.02% or less; Al: 0.001 to 0.5%; N: 0.1% or less; O: 0.001 to 0.02%; Cr: 0 to 2.0%; Mo: 0 to 1.0%; V: 0 to 0.5%; W: 0 to 0.5%; Ni: 0 to 5.0%; B: 0 to 0.01%; Ti: 0 to 0.5%; Nb: 0 to 0.5%; Cu: 0 to 1.0%; and balance: Fe and impurities, in terms of % by mass, the concentration of a Mn-containing inclusion is not less than 0.010% by mass and less than 0.25% by mass, and the number ratio of a Mn oxide to the inclusion having a maximum length of 1.0 to 4.0 ?m is 10.0% or more.Type: ApplicationFiled: March 5, 2013Publication date: January 22, 2015Inventors: Hiroyuki Tanahashi, Toshimasa Tomokiyo
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Publication number: 20150023835Abstract: Martensitic steel compositions and methods of production thereof are provided. More specifically, a martensitic steel having tensile strengths ranging from 1700 to 2200 MPa are provided. Most specifically, the present invention provides thin gage (thickness of ?1 mm) ultra high strength steel with an ultimate tensile strength of 1700 to 2200 MPa and methods of production thereof.Type: ApplicationFiled: November 28, 2012Publication date: January 22, 2015Inventors: Rongjie Song, Narayan S. Pottore
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Publication number: 20140314616Abstract: Provided is a hot-rolled steel sheet having a composition containing 0.04 mass percent to 0.20 mass percent C, 0.7 mass percent to 2.3 mass percent Si, 0.8 mass percent to 2.8 mass percent Mn, 0.1 mass percent or less P, 0.01 mass percent or less S, 0.1 mass percent or less Al, and 0.008 mass percent or less N, the remainder being Fe and inevitable impurities. Internal oxides containing one or more selected from the group consisting of Si, Mn, and Fe are present at grain boundaries and in grains in a base metal. The internal oxides present at the grain boundaries in the base metal are located within 5 ?m from the surface of the base metal. The difference between the depths at which the internal oxides are formed in the cross direction of the steel sheet is 2 ?m or less.Type: ApplicationFiled: November 2, 2012Publication date: October 23, 2014Applicant: JFE STEEL CORPORATIONInventors: Mai Miyata, Yoshitsugu Suzuki, Yasunobu Nagataki, Yoshiyasu Kawasaki, Hirokazu Sugihara
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Publication number: 20140271768Abstract: The invention provides medical devices comprising high-strength alloys which degrade over time in the body of a human or animal, at controlled degradation rates, without generating emboli and which have enhanced degradation due to the presence of a halogen component. In one embodiment the alloy is formed into a bone fixation device such as an anchor, screw, plate, support or rod. In another embodiment the alloy is formed into a tissue fastening device such as staple. In yet another embodiment, the alloy is formed into a dental implant or a stent.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: Bio DG, Inc.Inventors: Herbert RADISCH, Paul JABLONSKI
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Patent number: 8828154Abstract: A steel sheet contains, in terms of percent by mass, C: 0.01 to 0.2%, Si: 2.0% or less, and Mn: 3.0% or less and has a martensite phase as dominant phase and ferrite with a grain size of 20 ?m or less as a second phase. The ferrite is contained in area ratio of 1% to 30% and the amount of solute carbon being 0.01 percent by mass of more. The steel sheet can provide a hot-rolled steel sheet suitable for automobile steel sheet, i.e., has excellent press workability and excellent strain aging property whereby the tensile strength significantly increases by heat treatment at about the same temperature as typical baking process after the press-working. Moreover, hardening of the ferrite phase improves the fatigue strength after the strain aging.Type: GrantFiled: March 29, 2006Date of Patent: September 9, 2014Assignee: JFE Steel CorporationInventors: Toru Hoshi, Saiji Matsuoka
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Patent number: 8821652Abstract: Steel for induction hardening wherein coarsening of austenite crystal grains can be prevented even at a high temperature of over 1100° C. such as which occurs at projecting parts of steel parts at the time of induction hardening, the steel for induction hardening characterized by containing, by mass %, C: 0.35 to 0.6%, Si: 0.01 to 1%, Mn: 0.2 to 1.8%, S: 0.001 to 0.15%, Al: 0.001 to 1%, Ti: 0.05 to 0.2%, and Nb: 0.001 to 0.04%, restricting N: 0.0060% or less, P: 0.025% or less, and O: 0.0025% or less, satisfying Nb/Ti?0.015, and having a balance of iron and unavoidable impurities.Type: GrantFiled: October 7, 2010Date of Patent: September 2, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Shuji Kozawa, Manabu Kubota
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Patent number: 8801872Abstract: A case hardened gear steel having enhanced core fracture toughness includes by weight percent about 16.3Co, 7.5Ni, 3.5Cr, 1.75Mo, 0.2W, 0.11C, 0.03Ti, and 0.02V and the balance Fe, characterized as a predominantly lath martensitic microstructure essentially free of topologically close-packed (TCP) phases and carburized to include fine M2C carbides to provide a case hardness of at least about 62 HRC and a core toughness of at least about 50 ksi?in.Type: GrantFiled: August 20, 2008Date of Patent: August 12, 2014Assignee: QuesTek Innovations, LLCInventors: James A. Wright, Jason Sebastian
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Patent number: 8801874Abstract: A steel plate for line pipes containing, in terms of % by weight, C: 0.02 to 0.06%, Si: 0.5% or less, Mn: 0.8 to 1.6%, P: 0.008% or less, S: 0.0008% or less, Al: 0.08% or less, Nb: 0.005 to 0.035%, Ti: 0.005 to 0.025%, and Ca: 0.0005 to 0.0035%, and optionally contains one or more of Cu: 0.5% or less, Ni: 1% or less, Cr: 0.5% or less, Mo: 0.5% or less and V: 0.1% or less, and has a CP value of 0.95 or less represented by CP=4.46C(%)+2.37Mn(%)/6+{1.18Cr(%)+1.95Mo(%)+1.74V(%)}/5+{1.74Cu(%)+1.7Ni(%)}/15+22.36P(%), and a Ceq value of 0.30 or more represented by Ceq=C(%)+Mn(%)/6+{Cr(%)+Mo(%)+V(%)}/5 +{Cu(%)+Ni(%)}/15.Type: GrantFiled: November 7, 2008Date of Patent: August 12, 2014Assignee: JFE Steel CorporationInventors: Nobuyuki Ishikawa, Makoto Suzuki, Tomohiro Matsushima, Akiyoshi Tsuji, Shinichi Kakihara, Nobuo Shikanai, Yutaka Awajiya
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Patent number: 8795443Abstract: A steel sheet undergone precipitation strengthening and refinement in crystal grain size by containing at least one element of 0.005% to 0.05% of Nb, 0.005% to 0.05% of Ti, and 0.0005% to 0.005% of B as a chemical composition is produced through continuous annealing. A steel containing at least one element of Nb, Ti, and B is hot rolled, cooled at a cooling rate of 40° C./s or less, and coiled at 550° C. or higher to facilitate precipitation of cementite after recrystallization annealing. As a result, a steel sheet for a can having a tensile strength of 450 to 550 MPa, a total elongation of 20% or more, and a yield elongation of 5% or less is produced.Type: GrantFiled: April 14, 2008Date of Patent: August 5, 2014Assignee: JFE Steel CorporationInventors: Yuka Nishihara, Katsumi Kojima, Hiroki Iwasa, Yoshun Yamashita
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Patent number: 8778261Abstract: The present invention provides a steel material for automobile chassis parts, having high fatigue characteristics, without a heat treatment, and superior shapeability, and a method of production of such automobile chassis parts. The surface of the steel has a high hardness and the center has a low hardness, providing the superior characteristics. With an annealing step of the invention, it is possible to relieve internal stress and further improve fatigue characteristics.Type: GrantFiled: November 21, 2011Date of Patent: July 15, 2014Assignees: Nippon Steel & Sumitomo Metal Corporation, Toyota Jidosha Kabushiki KaishaInventors: Hideyuki Nakamura, Isao Anai, Yasushi Yamamoto, Takaaki Fukushi, Izuru Yamamoto, Masaaki Kondo, Satoru Shimazu
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Patent number: 8764918Abstract: The present invention provides high strength steel pipe for line pipe superior in low temperature toughness suppressed in drop of toughness of the HAZ and a method of production of the same, more particularly high strength steel plate for line pipe used as a material for high strength steel pipe for line pipe and a method of production of the same, in particular high strength steel pipe for line pipe superior in low temperature toughness characterized in that the chemical compositions of the base metal is, by mass %, C: 0.020 to 0.080%, Si: 0.01 to 0.50%, Mo: 0.01 to 0.15%, Al: 0.0005 to 0.030%, and Nb: 0.0001 to 0.030% contained in a range of C+0.25Si+0.1Mo+Al+Nb: 0.100% or less and the mixture of austenite and martensite present along prior austenite grain boundaries of the reheated part of the heat affected zone has a width of 10 ?m or less and a length of 50 ?m or less.Type: GrantFiled: July 2, 2007Date of Patent: July 1, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Takuya Hara, Hitoshi Asahi, Yoshio Terada
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Patent number: 8765269Abstract: An APIX100-grade high strength steel pipe includes a base material containing, in mass percentage, C: more than 0.03% and 0.08% or less, Si: 0.01% to 0.5%, Mn: 1.5% to 3.0%, P: 0.015% or less, S: 0.005% or less, Al: 0.01% to 0.08%, Nb: 0.005% to 0.025%, Ti: 0.005% to 0.025%, N: 0.001% to 0.010%, O: 0.005% or less, and B: 0.0003% to 0.0020%, further contains one or more of Cu, Ni, Cr, Mo, and V, satisfies 0.19?Pcm?0.25, the balance being Fe and unavoidable impurities, and has a TS of 760 to 930 MPa, a uniform elongation of 5% or more, and a YR of 85% or less; the seam weld metal has a specific composition.Type: GrantFiled: February 5, 2010Date of Patent: July 1, 2014Assignee: JFE Steel CorporationInventors: Junji Shimamura, Nobuyuki Ishikawa, Mitsuhiro Okatsu, Nobuo Shikanai
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Publication number: 20140161659Abstract: This high-strength hot-rolled steel plate contains specific amounts of C, Si, Mn, Al, V and also Ti and/or Nb so as to fulfill C?12(V/51+Ti/48+Nb/93)>0.03, and the rest consists of iron and unavoidable impurities. Ferrite is the main microstructure, the remaining microstructure is one or more selected from the group consisting of bainite, martensite and retained austenite, wherein the average particle diameter of precipitated carbides (the total content of V, Ti and Nb is 0.02% or greater) in the ferrite is less than 6 nm.Type: ApplicationFiled: August 15, 2012Publication date: June 12, 2014Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Toshio Murakami, Masao Kinefuchi, Hideo Hata
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Patent number: 8747576Abstract: This high-carbon pearlitic steel rail having excellent ductility, includes: in terms of percent by mass, C: more than 0.85% to 1.40%; Si: 0.10% to 2.00%; Mn: 0.10% to 2.00%; Ti: 0.001% to 0.01%; V: 0.005% to 0.20%; and N: less than 0.0040%, with the balance being Fe and inevitable impurities, wherein contents of Ti and V fulfill the following formula (1), and a rail head portion has a pearlite structure.Type: GrantFiled: April 14, 2010Date of Patent: June 10, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Teruhisa Miyazaki, Masaharu Ueda, Suguru Yoshida
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Patent number: 8747577Abstract: High yield ratio high-strength hot rolled thin steel sheet superior in weldability and ductility comprising, by mass %, C: over 0.030 to less than 0.10%, Si: 0.30 to 0.80%, Mn: 1.7 to 3.2%, P: 0.001 to 0.02%, S: 0.0001 to 0.006%, Al: 0.060% or less, N: 0.0001 to 0.0070%, containing further Ti: 0.01 to 0.055%, Nb: 0.012 to 0.055%, Mo: 0.07 to 0.55%, B: 0.0005 to 0.0040%, and simultaneously satisfying 1.1?14×Ti(%)+20×Nb(%)+3×Mo(%)+300×B(%)?3.7, the balance comprised of iron and unavoidable impurities, and having a yield ratio of 0.64 to less than 0.92, a TS×El1/2 of 3320 or more, an YR×TS×El1/2 of 2320 or more, and a maximum tensile strength (TS) of 780 MPa or more.Type: GrantFiled: June 3, 2011Date of Patent: June 10, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Naoki Yoshinaga, Shunji Hiwatashi, Yasuharu Sakuma, Atsushi Itami
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Publication number: 20140150930Abstract: The present invention relates to a hot press forming steel plate made of a composition comprising: 0.3-1.0 wt % of C; 0.0-4.0 wt % of Mn; 1.0-2.0 wt % of Si; 0.01-2.0 wt % of Al; 0.015 wt % or less of S; 0.01 wt % or less of N; and the remainder being Fe and unavoidable impurities. Further, the present. invention relates to a method for manufacturing the hot press forming steel plate, characterized by comprising the steps of: heating, to between 1100 and 1300° C., a steel slab having the composition; performing hot rolling finishing between. an Ar3 transformation point and 950° C.; and performing winding between MS and 720° C. Further, the present invention. relates to a hot press formed member characterized by having the composition, and having a dual phase microstructure made of bainite and residual austenite.Type: ApplicationFiled: July 15, 2011Publication date: June 5, 2014Inventors: Kyoo-Young Lee, Jin-Keun Oh, Jong-Sang Kim, Tae-Kyo Han
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Patent number: 8709174Abstract: A seamless steel pipe for line pipe having high strength and high toughness contains, by mass percent, C: 0.02 to 0.10%, Si: at most 0.5%, Mn: 0.5 to 2.0%, Al: 0.01 to 0.1%, P: at most 0.03%, S: at most 0.005%, Ca: at most 0.005%, and N: at most 0.007%, and further contains at least one selected from a group consisting of Ti: at most 0.008%, V: less than 0.06%, and Nb: at most 0.05%, the balance being Fe and impurities. A carbon equivalent Ceq defined by Formula (1) is at least 0.38, a content of Ti, V and Nb satisfies Formula (2), and the size of carbo-nitride containing at least one of Ti, V, Nb and Al is at most 200 nm, Ceq=C+Mn/6+(Cr+Mo+V)/5+(Ni+Cu)/15??(1) Ti+V+Nb<0.06??(2).Type: GrantFiled: September 11, 2012Date of Patent: April 29, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Yuji Arai, Keisuke Hitoshio
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Patent number: 8691030Abstract: The present application describes a steel composition that provides enhanced corrosion resistance. This steel composition includes one of vanadium in an amount of 1 wt % to 9 wt %, titanium in an amount of about 1 wt % to 9 wt %, and a combination of vanadium and titanium in an amount of 1 wt % to about 9 wt %. In addition, the steel composition includes carbon in an amount of 0.03 wt % to about 0.45 wt %, manganese in an amount up to 2 wt % and silicon in an amount up to 0.45 wt %. In one embodiment, the steel composition includes a microstructure of one of the following: ferrite, martensite, tempered martensite, dual phase ferrite and martensite, and dual phase ferrite and tempered martensite. Further, the present application describes a method for processing the steel composition and use of equipment such as oil country tubular goods, fabricated with the steel composition.Type: GrantFiled: May 2, 2008Date of Patent: April 8, 2014Assignee: ExxonMobil Upstream Research CompanyInventors: Dylan V. Pugh, Joseph C. Bondos, Shiun Ling, Raghavan Ayer, Shalawn K. Jackson, Jayoung Koo, Swarupa S. Bangaru
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Patent number: 8679373Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.Type: GrantFiled: March 20, 2012Date of Patent: March 25, 2014Assignee: Electromagnetics CorporationInventor: Christopher J. Nagel
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Patent number: 8673402Abstract: The present disclosure relates to a method of spray cladding a wear plate. The method may include melting an alloy including glass forming chemistry, pouring the alloy through a nozzle to form an alloy stream, forming droplets of the alloy stream, and forming a coating of the alloy on a base metal. The base plate may exhibit a first hardness H1 of Rc 55 or less and the alloy coated base plate may exhibit a hardness H2, wherein H2>H1. In addition, the coating may exhibit nanscale or near-nanscale microstructural features in the range of 0.1 nm to 1,000 nm. Furthermore, the alloy coated base plate may exhibit a toughness of greater than 60 ft-lbs.Type: GrantFiled: November 10, 2008Date of Patent: March 18, 2014Assignee: The NanoSteel Company, Inc.Inventor: Daniel James Branagan
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Patent number: 8663400Abstract: Provided is a low alloy steel for high-pressure hydrogen gas environments, which contains, by mass percent, C: 0.15 to 0.60%, Si: 0.05 to 0.5%, Mn: 0.05 to 3.0%, P: not more than 0.025%, S: not more than 0.010%, Al: 0.005 to 0.10%, Mo: 0.5 to 3.0%, V: 0.05 to 0.30%, O (oxygen): not more than 0.01%, N: not more than 0.03%, and the balance Fe and impurities, and has tensile strength of not less than 900 MPa. This low alloy steel desirably contains B of 0.0003 to 0.003%, but in this case, N is limited to not more than 0.010%. It is desirable to contain at least one among Cr, Nb, Ti, Zr, and Ca. The contents of Mo and V desirably satisfy the following formula (1): [Mo(%)]·[V(%)]0.2?0.32??(1).Type: GrantFiled: June 12, 2009Date of Patent: March 4, 2014Assignee: Sumitomo Metal Industries, Ltd.Inventors: Tomohiko Omura, Mitsuo Miyahara, Hiroyuki Semba, Masaaki Igarashi
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Publication number: 20140044987Abstract: A steel sheet for a hot stamping member contains, as a chemical composition, 0.10 mass % to 0.35 mass % of C; 0.01 mass % to 1.0 mass % of Si; 0.3 mass % to 2.3 mass % of Mn; 0.01 mass % to 0.5 mass % of Al; limited to 0.03 mass % or less of P; limited to 0.02 mass % or less of S; limited to 0.1 mass % or less of N; and a balance consisting of Fe and unavoidable impurities, in which a standard deviation of diameters of iron carbides which are contained in a region from a surface to a ¼ thickness position of the steel sheet is less than or equal to 0.8 ?m.Type: ApplicationFiled: April 26, 2012Publication date: February 13, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Hiroyuki Tanahashi, Jun Maki
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Patent number: 8647449Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are families of alloys capable of forming crack-free weld overlays after multiple welding passes.Type: GrantFiled: March 6, 2012Date of Patent: February 11, 2014Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Patent number: 8641836Abstract: The present invention provides steel plate for line pipe excellent in strength and ductility and a method of production of the same. The steel plate has a steel composition containing, by mass %, C: 0.04 to 0.15%, Si: 0.05 to 0.60%, Mn: 0.80 to 1.80%, P: 0.020% or less, S: 0.010% or less, Nb: 0.01 to 0.08%, and Al: 0.003 to 0.08%, having a balance of iron and unavoidable impurities, and having a value of Ceq shown by the following formula <1> of 0.48 or less, comprised of a mixed structure of ferrite and pearlite or ferrite and pearlite partially containing bainite in which a ferrite percentage is 60 to 95%, having a yield strength of 450 MPa or more, and having an amount of hydrogen contained in the steel of 0.1 ppm or less: Ceq=C+Mn/6+(Cu+Ni)/15+(Cr+Mo+Nb+V+Ti)/5+5B??<1>.Type: GrantFiled: October 28, 2009Date of Patent: February 4, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hajime Ishikawa, Ryuji Uemori, Yoshiyuki Watanabe, Nobuhiko Mamada
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Patent number: 8623108Abstract: A wear-resistant material which comprises certain concentrations of carbon, nitrogen, oxygen, niobium/tantalum as well as other metallic elements. The material comprises a metal matrix and hard phases embedded therein. The hard phases comprise one or more of carbides, nitrides, carbonitrides, and oxide carbonitrides and have a diameter of from about 0.2 ?m to about 50 ?m. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.Type: GrantFiled: January 13, 2010Date of Patent: January 7, 2014Assignee: Boehler Edelstahl GmbH & Co KGInventors: Werner Theisen, Stephan Huth, Jochen Perko, Herbert Schweiger
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Publication number: 20130323112Abstract: In a hot-rolled sheet, an average value of pole densities of an orientation group {100}<011> to {223}<110>, which is represented by an arithmetic mean of pole densities of orientations {100}<011>, {116}<110>, {114}<110>, {112}<110>, and {223}<110> in a thickness center portion of a thickness range of ? to ? from a surface of the steel sheet, is 1.0 to 6.5 and a pole density of a crystal orientation {332}<113> is 1.0 to 5.0; and a Lankford value rC in a direction perpendicular to a rolling direction is 0.70 to 1.10 and a Lankford value r30 in a direction that forms 30° with respect to the rolling direction is 0.70 to 1.10.Type: ApplicationFiled: March 5, 2012Publication date: December 5, 2013Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Riki Okamoto, Nobuhiro Fujita, Manabu Takahashi, Kunio Hayashi, Tetsuo Kishimoto, Kazuaki Nakano, Takeshi Yamamoto
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Patent number: 8562759Abstract: Disclosed herein are iron-based alloys having a structure comprising fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the step determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: GrantFiled: September 17, 2010Date of Patent: October 22, 2013Assignee: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Publication number: 20130272914Abstract: The steel wire material of the present invention contains 0.05 to 1.2% of C (mass %; same for the chemical components hereafter), 0.01 to 0.5% of Si, 0.1 to 1.5% of Mn, 0.02% or less (but not 0%) of P, 0.02% or less (but not 0%) of S, and 0.005% or less (but not 0%) of N, with the balance being iron and inevitable impurities. The wire material has a scale layer that is no thicker than 7.0 ?m or less. The scale layer has an FeO percentage of 30 to 80 vol % and an Fe2SiO4 percentage of less than 0.1 vol %. The scale layer that is formed will not peel when cooled after hot rolling or during storage and transport, but will easily peel during mechanical descaling.Type: ApplicationFiled: January 6, 2012Publication date: October 17, 2013Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel. Ltd.)Inventors: Mikako Takeda, Shohei Nakakubo, Kazuhiko Kirihara, Masayuki Endo
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Publication number: 20130272913Abstract: This steel wire material contains 0.05%-1.2% C (“%” means “% by mass,” same hereinafter for chemical components.), 0.01%-0.7% Si, 0.1%-1.5% Mn, 0.02% max. P (not including 0%), 0.02% max. S (not including 0%), and 0.005% max. N (not including 0%), with the remainder being iron and unavoidable impurities. The steel wire material has a scale 6.0-20 ?m thick and holes of an equivalent circle diameter of 1 ?m max. in said scale that occupy 10% by area max. Said scale does not detach in the cooling process after hot rolling or during storage or transportation but can readily detach during mechanical descaling.Type: ApplicationFiled: December 9, 2011Publication date: October 17, 2013Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Mikako Takeda, Shohei Nakakubo, Kazuhiko Kirihara, Masayuki Endo
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Publication number: 20130266820Abstract: A work piece for use in abrasive environments with hardbanding is provided. The work piece has at least a protective layer deposited onto at least a portion to be protected. The deposited layer exhibits a hardness of at least 50 Rc, a wear rate of less than 0.5 grams of mass loss as measured according to ASTM G65-04, Procedure A, a wear rate on a contacting secondary body comprising carbon steel of less than 0.005 grams as measured according to modified ASTM G77 wear test. The deposited alloy forms an iron matrix comprising embedded hard particles in an amount of less than 15 vol. %. The embedded hard particles have an average particle size of ranging from 100 nm to 5 ?m. In one embodiment, the deposition is via welding.Type: ApplicationFiled: April 5, 2012Publication date: October 10, 2013Applicant: c/o Chevron CorporationInventors: Grzegorz Jan Kusinski, Justin Lee Cheney, John Hamilton Madok
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Patent number: 8500924Abstract: A high-strength steel plate includes the following composition: 0.18 to 0.23 mass % of C; 0.1 to 0.5 mass % of Si; 1.0 to 2.0 mass % of Mn; 0.020 mass % or less of P; 0.010 mass % or less of S; greater than 0.5 mass % and equal to or less than 3.0 mass % of Cu, 0.25 to 2.0 mass % of Ni; 0.003 to 0.10 mass % of Nb; 0.05 to 0.15 mass % of Al; 0.0003 to 0.0030 mass % of B; 0.006 mass % or less of N; and a balance composed of Fe and inevitable impurities. A weld crack sensitivity index Pcm of the high-strength steel plate is calculated by Pcm=[C]+[Si]/30+[Mn]/20+[Cu]/20+[Ni]/60+[Cr]/20+[Mo]/15+[V]/10+5[B], and is 0.39 mass % or less. The Ac3 transformation point is equal to or less than 850° C., the percentage value of a martensite structure is equal to or greater than 90%, the yield strength is equal to or greater than 1300 MPa, and the tensile strength is equal to or greater than 1400 MPa and equal to or less than 1650 MPa.Type: GrantFiled: October 13, 2009Date of Patent: August 6, 2013Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Tatsuya Kumagai, Akira Usami, Masaharu Oka
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Publication number: 20130177469Abstract: Methods comprising providing a composition comprising iron and a high melting point element; heating the composition to an elevated temperature up to about 3,500° F.; holding the composition at the elevated temperature for a time sufficient for the heat's temperature to stabilize; and allowing the composition to cool or solidify. Methods comprising providing a master alloy comprising iron and up to about 30% by weight of a high melting point element; and adding the master alloy to a heat of steel. Compositions comprising an alloy of iron and high melting point element in which the alloy is up to about 30% by weight of the high melting point element. Compositions comprising an alloy of iron and high melting point element having a substantially uniform microstructure.Type: ApplicationFiled: December 21, 2012Publication date: July 11, 2013Inventors: James D. Ruhlman, Charles Scherrer, Randall W. Schudalla
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Publication number: 20130153091Abstract: A hot-rolled steel sheet has an average value of the X-ray random intensity ratio of a {100} <011> to {223} <110> orientation group at least in a sheet thickness central portion that is in a sheet thickness range of ? to ? from a steel sheet surface of 1.0 to 6.0, an X-ray random intensity ratio of a {332} <113> crystal orientation of 1.0 to 5.0, rC which is an r value in a direction perpendicular to a rolling direction of 0.70 to 1.10, and r30 which is an r value in a direction that forms an angle of 30° with respect to the rolling direction of 0.70 to 1.10.Type: ApplicationFiled: July 27, 2011Publication date: June 20, 2013Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Nobuhiro Fujita, Kunio Hayashi, Riki Okamoto, Manabu Takahashi, Tetsuo Kishimoto, Hiroshi Yoshida
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Patent number: 8430976Abstract: A high-strength pearlitic steel rail with an excellent combination of wear properties and rolling contact fatigue resistance wherein the steel has 0.88% to 0.95% carbon, 0.75% to 0.92% silicon, 0.80% to 0.95% manganese, 0.05% to 0.14% vanadium, up to 0.008% nitrogen, up to 0.030% phosphorus, 0.008 to 0.030% sulphur, at most 2.5 ppm hydrogen, at most 0.10% chromium, at most 0.010% aluminium, at most 20 ppm oxygen, the remainder being iron and unavoidable impurities.Type: GrantFiled: February 23, 2009Date of Patent: April 30, 2013Assignee: Tata Steel UK LimitedInventors: Robert Carroll, Howard Martin Smith, Shreekant Jaiswal
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Publication number: 20130076477Abstract: The present invention provides a Fe-group-based soft magnetic powder that is used for the pressed powder magnetic cores for a choke coil, reactor coil, etc., and that has a higher magnetic permeability. At least one selected from Fe, Co, or Ni that is generally used is used as the main component of the Fe-group-based alloy (iron-based alloy) soft magnetic powder. The soft magnetic powder is produced by adding a small amount of Nb (0.05-4 wt %) or V, Ta, Ti, Mo, or W, to the molten metal and by means of an inexpensive method such as the water-atomizing method.Type: ApplicationFiled: June 7, 2011Publication date: March 28, 2013Inventor: Yasushi Kino
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Publication number: 20130076017Abstract: Hot-rolled high-strength steel elongated structural members and method of making same are disclosed by hot-rolling high-strength steel having a specific chemical composition to provide the members of desired geometrical configuration including a thin web with opposed thicker flanges extending therefrom to increase the load bearing capacity of the members.Type: ApplicationFiled: September 23, 2011Publication date: March 28, 2013Applicant: CONSOLIDATED METAL PRODUCTS, INC.Inventor: Hugh M. Gallagher, JR.
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Patent number: 8398786Abstract: Disclosed herein is a precipitation hardening cold-rolled steel sheet and method for manufacturing the same, which can be used for structural components such as seat rails and the like of a vehicle body. The steel sheet comprises, by weight %, C: 0.07˜0.1%, Mn: 1.4˜1.7%, P: 0.05˜0.07%, S: 0.005% or less, acid-soluble Al: 0.1˜0.15%, Nb: 0.06˜0.09%, B: 0.0008˜0.0012%, Sb: 0.02˜0.06%, and the balance of Fe and other unavoidable impurities. The steel sheet has a yield strength of 750 MPa or more and a yield ratio of 85% or more, and is free from surface defects due to a very low degree of oxide enrichment on the surface thereof.Type: GrantFiled: September 28, 2006Date of Patent: March 19, 2013Assignee: POSCOInventor: Sang-Ho Han
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Patent number: 8388770Abstract: A cold-rolled steel sheet has a composition containing, by mass percent, 0.0040% or less of C, 0.02% or less of Si, 0.14% to 0.25% of Mn, 0.020% or less of P, 0.015% or less of S, 0.0040% or less of N, 0.020% to 0.070% of Al, 0.005% to 0.030% of Nb, 0.005% to 0.030% of Ti, (0.0003% to 0.0010% of the equivalent amount of solid solution B (from which the amount of B forming BN has been subtracted)), and the balance composed of Fe and inevitable impurities, wherein even when the rolling reduction of cold rolling is 85% or less, the average grain size of a ferrite structure is reliably 12.0 ?m or less, and the relationship ?0.20??r?0.20 can be reliably satisfied and which has an excellent earing property.Type: GrantFiled: March 13, 2007Date of Patent: March 5, 2013Assignee: JFE Steel CorporationInventors: Nobuko Mineji, Eiko Yasuhara, Reiko Sugihara, Tadashi Inoue