Chromium Or Molybdenum Containing Patents (Class 420/421)
-
Patent number: 5549797Abstract: Amorphous alloy comprising 30 to 75 atomic % Cr, the remainder being substantially at least one element selected from the group consisting of Ti and Zr and alloys represented by the general formula: X.sub.a Cr.sub.b M.sub.c wherein X is at least one element selected from the group consisting of Ti and Zr; M is at least one element selected from the group consisting of Mg, Al, Fe, Co, Ni, Cu, Mo and W; and a, b, and c are, in atomic percentage, a>20, 20 .ltoreq.b.ltoreq.75, 0<c .ltoreq.20 and a+b+c=100. The alloys are excellent in corrosion resistance and wear resistance, form a stable protective film and are spontaneously passive, even in corrosive environment such as a poorly oxidizing, highly corrosive HCl solution containing chlorine ions.Type: GrantFiled: March 7, 1994Date of Patent: August 27, 1996Assignees: Koji Hashimoto, YKK CorporationInventors: Koji Hashimoto, Hideaki Yoshioka, Asahi Kawashima
-
Patent number: 5545265Abstract: A gamma titanium aluminide alloy is provided, based on the intermetallic compound TiAl, in which the resulting alloy is characterized by high creep strength and environmental resistance at elevated temperatures in excess of about 650.degree. C., and as high as about 850.degree. C. The alloy achieves these desirable properties through limited and interrelated additions of chromium, niobium and tantalum, whose combined amount is established by a minimum amount necessary to achieve a desired level of oxidation resistance.Type: GrantFiled: March 16, 1995Date of Patent: August 13, 1996Assignee: General Electric CompanyInventors: Curtiss M. Austin, Thomas J. Kelly, Shyh-Chin Huang
-
Patent number: 5518690Abstract: TiAl-besed intermetallic compound alloys contain chromium and consist essentially of a dual-phase microstructure of .gamma. and .beta. phases, with the .beta. phase precipitating at .gamma. grain boundaries. The .beta. phase precipitating at .gamma. grain boundaries is 2% to 25% by volume fraction. A process for preparing TiAl-based intermetallic compound alloys comprises the steps of preparing a molten TiAl-based intermetallic compound alloy of a desired composition, solidifying the molten alloy, homogenizing the solidified alloy by heat treatment, and thermomechanically working the homogenized alloy.Type: GrantFiled: August 12, 1994Date of Patent: May 21, 1996Assignee: Nippon Steel CorporationInventors: Naoya Masahashi, Youji Mizuhara, Munetsugu Matsuo
-
Patent number: 5492574Abstract: The present invention comprises a plurality of single phase gamma TiAl alloys modified by Ta. These alloys comprise Ti.sub.(45-46) Al.sub.(50-51) Ta.sub.4 in atomic percent, and exhibit significant room temperature ductility, in the range of 1.3-2.1% tensile elongation. The alloys may be made by the use of cast and forging techniques.Type: GrantFiled: September 21, 1994Date of Patent: February 20, 1996Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5458701Abstract: An article comprises a Cr-bearing, predominantly gamma titanium aluminide matrix including second phase dispersoids, such as TiB.sub.2, in an amount effective to increase both the strength and the ductility of the matrix.Type: GrantFiled: December 2, 1993Date of Patent: October 17, 1995Assignees: Howmet Corporation, Martin Marietta CorporationInventors: Stephen L. Kampe, Leontios Christodoulou, Donald E. Larsen, Jr.
-
Patent number: 5451366Abstract: A Ti--Al system intermetallic compound comprised of 25 at. % to 75 at. % of aluminum and the remainder of titanium. The compound includes 0.004 at. % to 1.0 at. % each of at least one halogen element selected from the group consisting of fluorine, chlorine, bromine and iodine. Alternatively, to provide a Ti--Al system intermetallic compound with oxidation resistance, the surface of the Ti--Al system intermetallic compound is heated to 800.degree. C. to 1125.degree. C. in a mixture of gas including 2 ppm to 1% by volume of at least one halogen element selected from the group consisting of fluorine, chlorine, bromine and iodine, and also including 0.1% by volume or more of oxygen. Thus, a dense aluminum oxide film is formed on the surface of the intermetallic compound. Alternatively, to form the dense aluminum oxide film, at least one halogen element is first disposed on the part providing the oxidation resistance of the intermetallic compound, and heated for 0.2 hour or longer at 800.degree. C. to 1125.degree.Type: GrantFiled: July 13, 1993Date of Patent: September 19, 1995Assignee: Sumitomo Light Metal Industries, Ltd.Inventors: Masaki Kumagai, Kazuhisa Shibue, Mok-soon Kim, Tsutomu Furuyama
-
Patent number: 5437835Abstract: A corrosion resistant Ti based alloy comprising:Cr: 0.005-2.0 wt %, and further comprising one or more of elements selected from:Ni: 0.005-2.0 wt %, Pd: 0.005-2.0 wt %, Ru: 0.005-2.0 wt %, Pt: 0.005-2.0 wt %, Os: 0.005-2.0 wt %, Ir: 0.005-2.0 wt %, Rh: 0.005-2.0 wt %, andthe balance of Ti and inevitable impurities.Cr may be replaced with one or more of 0.005-1.5 wt % of Cu and 0.005-1.5 wt % of Si, or 0.005-2.0 wt % of Al. The corrosion resistant Ti based alloy has excellent corrosion resistance also in a non-oxidative atmosphere and also has an excellent crevice corrosion resistance.Type: GrantFiled: January 26, 1994Date of Patent: August 1, 1995Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Yasuaki Sugizaki, Keiji Ueda, Hiroshi Satoh, Hidetoshi Nishimoto, Tatsuya Yasunaga, Takashi Yashiki
-
Patent number: 5433799Abstract: An article comprises a Cr-bearing, predominantly gamma titanium aluminide matrix including second phase dispersoids, such as TiB.sub.2, in an amount effective to increase both the strength and the ductility of the matrix.Type: GrantFiled: December 2, 1993Date of Patent: July 18, 1995Assignees: Howmet Corporation, Martin Marietta CorporationInventors: Stephen L. Kampe, Leontios Christodoulou, Donald E. Larsen, Jr.
-
Patent number: 5431754Abstract: A TiAl-based intermetallic compound has a metallographic structure which includes a region A having fine .beta.-phases dispersed in a .gamma.-phase. The volume fraction Vf of the .beta.-phases in the region A is set equal to or more than 0.1% (Vf.gtoreq.0.1%). Thus, the .beta.-phases can exhibit a pinning effect to prevent a transgranular pseudo cleavage fracture in the .gamma.-phase, thereby providing an enhanced high-temperature strength of the TiAl-based intermetallic compound.Type: GrantFiled: October 5, 1993Date of Patent: July 11, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Yoshiya Fujiwara, Toshio Tokune
-
Patent number: 5429796Abstract: A TiAl alloy base melt including at least one of Cr, C, Ga, Mo, Mn, Nb, Ni Si, Ta, V and W and at least about 0.5 volume % boride dispersoids is investment cast to form a crack-free, net or near-net shape article having a gamma TiAl intermetallic-containing matrix with a grain size of about 10 to about 250 microns as a result of the presence of the boride dispersoids in the melt. As hot isostatically pressed and heat treated to provide an equiaxed grain structure, the article exhibits improved strength.Type: GrantFiled: October 26, 1993Date of Patent: July 4, 1995Assignee: Howmet CorporationInventor: Donald E. Larsen, Jr.
-
Patent number: 5393356Abstract: A multi-phase, high temperature-resistant material with an intermetallic base alloy of the .gamma.-TiAl type, is intended in particular for use in heat engines, such as internal combustion engines, gas turbines and aircraft engines. The material has a content of aluminum of from 30 to 40 atom %, silicon of from 0.1 to 20 atom %, niobium of from 0.1 to 15 atom %, and a remainder of titanium.Type: GrantFiled: July 28, 1993Date of Patent: February 28, 1995Assignee: ABB Patent GmbHInventor: Lorenz Singheiser
-
Patent number: 5376193Abstract: Novel Ti-Al-Nb-Cr alloys incorporating in their microstructure the hexagonal DO.sub.19 phase, the omega-type B8.sub.2 phase, the cubic B2 phase, and, optionally, the orthorhombic O phase. The intermetallic alloys consist essentially of, in atomic percent, about 48-62% Ti, about 28-32% Al, and about 10-20% Nb with Cr, wherein Cr is preferably present at about 4-16% of the total concentration.Type: GrantFiled: June 23, 1993Date of Patent: December 27, 1994Assignee: The United States of America as represented by the Secretary of CommerceInventor: Leonid A. Bendersky
-
Patent number: 5370839Abstract: TiAl-besed intermetallic compound alloys contain chromium and consist essentially of a dual-phase microstructure of .gamma. and .beta. phases, with the .beta. phase precipitating at .gamma. grain boundaries. The .beta. phase precipitating at .gamma. grain boundaries is 2% to 25% by volume fraction. A process for preparing TiAl-based intermetallic compound alloys comprises the steps of preparing a molten TiAl-based intermetallic compound alloy of a desired composition, solidifying the molten alloy, homogenizing the solidified alloy by heat treatment, and thermomechanically working the homogenized alloy.Type: GrantFiled: July 1, 1992Date of Patent: December 6, 1994Assignee: Nippon Steel CorporationInventors: Naoya Masahashi, Youji Mizuhara, Munetsugu Matsuo
-
Patent number: 5368659Abstract: Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 10.sup.6 K/s comprise beryllium in the range of from 2 to 47 atomic percent and at least one early transition metal in the range of from 30 to 75% and at least one late transition metal in the range of from 5 to 62%. A preferred group of metallic glass alloys has the formula (Zr.sub.1-x Ti.sub.x).sub.a (Cu.sub.1-y Ni.sub.y).sub.b Be.sub.c. Generally, a is in the range from 30 to 75% and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 62%, and c is in the range of from 6 to 47%. When x is in the range of from 0.15 to 0.4, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.4 to 0.6, b is in the range of from 5 to 62%, and c is in the range of from 2 to 47%. When x is in the range of from 0.6 to 0.Type: GrantFiled: February 18, 1994Date of Patent: November 29, 1994Assignee: California Institute of TechnologyInventors: Atakan Peker, William L. Johnson
-
Patent number: 5368660Abstract: Two phase, TiAl.sub.2 -based, ternary aluminides of iron, nickel and other transitional metals are disclosed. A transformation from the tetragonal crystal configurations of the TI--Al system to the face-centered cubic configurations of the TI--Al--Fe and TI--Al--Ni systems is attributed to the transitional elements substituting for titanium in the face-centered cubic crystal lattice of the titanium aluminides. The resulting alloys of the composition Ti.sub.30 M.sub.4 Al.sub.66 or Ti.sub.25 M.sub.9 Al.sub.66, including Ti.sub.30 Fe.sub.4 Al.sub.66 and Ti.sub.30 Ni.sub.4 Al.sub.66, are low density, high temperature, aluminum-rich alloys possessing desirable properties, including ductility.Type: GrantFiled: October 30, 1992Date of Patent: November 29, 1994Assignee: New Mexico Tech Research FoundationInventors: Nuri Durlu, Osman T. Inal
-
Patent number: 5362441Abstract: A method of making a titanium base alloy comprising the steps of: heating a titanium base alloy to a temperature ranging from .beta.-transus minus 250.degree. C. to 5-transus; the titanium base alloy consisting essentially of about 3.42 to 5 wt. % Al, 2.1 to 3.7 wt. % V, 0.85 to 3.15 wt. % Mo, at least 0.01 wt. % 0, at least one element selected from the group consisting of Fe, Ni, Co and Cr, and the balance being titanium, and satisfying the following equations: 0.85 wt. %.ltoreq.X wt %.ltoreq.3.15 wt %, 7 wt %.ltoreq.Y wt %.ltoreq.13 wt. %, X wt. %=Fe wt. %+Ni wt. %+Co wt. %+0.9.times.Cr wt. %, Y wt. %=2.times.Fe wt. %+2.times.Ni wt. %+2.times.Co wt. %+1.8.times.Cr wt. %+1.5.times.V wt. %+Mo wt. %, and hot working the heated alloy with a reduction ratio percent of at least 50%.Type: GrantFiled: December 20, 1993Date of Patent: November 8, 1994Assignee: NKK CorporationInventors: Atsushi Ogawa, Kuninori Minakawa, Kazuhide Takahashi
-
Patent number: 5360677Abstract: A magnetic disk substrate having a composition wherein (V/13)+(Fe/20)+(Cr/17)+(Ni/31)+(Co/23) are no greater than 0.010%, Rem+Si+B+W are no greater than 0.015% (where Rem denotes rare earth metals), 0+2N+0.75C are no less than 0.03% and no greater than 0.5%, and the remainder consists substantially of Ti, all % being weight %.Type: GrantFiled: January 13, 1993Date of Patent: November 1, 1994Assignee: NKK CorporationInventors: Hideaki Fukai, Hiroyoshi Suenaga, Kuninori Minakawa, Shinichiro Otaka, Masahiko Naoe
-
Patent number: 5358584Abstract: A Ti--Al--V--Cr intermetallic alloy having an atomic percent composition of 5-35 Al, 10-15 (V+Cr), the balance being Ti. The alloy is partially of DO.sub.19 type and partially of B2 type and has high temperature strength and excellent room temperature ductility. The alloy is produced by arc melting the metallic components Ti, Al and at least one of V and Cr; followed by homogenizing the melted components; solidifying the melted components to form an alloy; hot working the solidified alloy by isothermal forming to form a beta-phase polycrystalline microstructure; transforming the metastable .beta.-phase into a two-phase microstructure; and equilibrating the two-phase microstructure by prolonged annealing.Type: GrantFiled: July 20, 1993Date of Patent: October 25, 1994Assignee: The United States of America as represented by the Secretary of CommerceInventor: Leonid A. Bendersky
-
Patent number: 5358586Abstract: The invention relates to a process for improving the aging response and uniformity in a beta titanium alloy comprising the steps of:(a) cold working said beta titanium alloy to at least about 5% so that a reasonable degree of recrystallization can be obtained during subsequent solution treatment;(b) pre-aging said cold worked alloy at about 900.degree. to about 1300.degree. F. for a time in excess of about 5 minutes to obtain a pre-aged alloy;(c) solution treating said pre-aged alloy at a time and temperature to achieve a reasonable degree of recrystallization of said pre-aged alloy above the beta transus; and(d) aging said solution treated alloy at temperature and times to achieve a pre-aged, solution treated and aged beta titanium alloy substantially in a state of metallurgical equilibrium.Type: GrantFiled: December 17, 1992Date of Patent: October 25, 1994Assignee: RMI Titanium CompanyInventors: Ronald W. Schutz, Stanley R. Seagle
-
Patent number: 5354351Abstract: An article comprises a Cr-bearing, predominantly gamma titanium aluminide matrix including second phase dispersoids, such as TiB.sub.2, in an amount effective to increase both the strength and the ductility of the matrix.Type: GrantFiled: June 18, 1991Date of Patent: October 11, 1994Assignees: Howmet Corporation, Martin Marietta CorporationInventors: Stephen L. Kampe, Leontios Christodoulou, Donald E. Larsen, Jr.
-
Patent number: 5350466Abstract: Creep resistant titanium aluminide alloy article consisting essentially of, in atomic %, about 45 to about 48 Al, about 1.0 to about 3.0 Nb, about 0.5 to about 1.5 Mn, about 0.25 to about 0.75 Mo, about 0.25 to about 0.75 W, about 0.15 to about 0.3 Si and the balance titanium. The article has a heat treated microstructure including gamma phase, alpha-two phase and at least one additional particulate phase including, one or more or W, Mo, and Si dispersed as distinct regions in the microstructure.Type: GrantFiled: July 19, 1993Date of Patent: September 27, 1994Assignees: Howmet Corporation, Avco CorporationInventors: Donald E. Larsen, Jr., Prabir R. Bhowal, Howard F. Merrick
-
Patent number: 5348702Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.Type: GrantFiled: March 5, 1993Date of Patent: September 20, 1994Assignee: Nippon Steel CorporationInventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
-
Patent number: 5348594Abstract: A Ti--Al intermetallic compound has a compressibility of at least 25% at room temperature and a superior high temperature oxidation resistance and consists essentially of about 40 to 52 atomic percent of Ti, about 48 to 60 atomic percent of Al, and 10 to 1000 atomic ppm of at least one of P, As, Se, or Te.Type: GrantFiled: May 6, 1993Date of Patent: September 20, 1994Assignee: Nippon Steel CorporationInventors: Toshihiro Hanamura, Ryuji Uemori, Mitsuru Tanino, Jin-ichi Takamura
-
Patent number: 5342577Abstract: The high temperature alloy is intended for machine components subjected to high mechanical and thermal stress. It is essentially based on doped TiAl and has the following composition:______________________________________ Ti.sub.x El.sub.y Me.sub.z Al.sub.1 -(x + y + z), in which El = B, Ge or Si and Me = Co, Cr, Ge, Hf, Mn, Mo, Nb, Pd, Ta, V, W, Y, and/or Zr and: 0.46 .ltoreq.x .ltoreq.0.54, 0.001 .ltoreq.y .ltoreq.0.015 for El = Ge and Me = Cr, Hf, Mn, Mo, Nb, Ta, V and/or W, 0.001 .ltoreq.y .ltoreq.0.015 for El = Si and Me = Hf, Mn, Mo, Ta, V and/or W, 0 .ltoreq.y .ltoreq.0.01 for El = B and Me = Co, Ge, Pd, Y and/or Zr, 0 .ltoreq.y .ltoreq.0.02 for El = Ge and Me = Co, Ge, Pd, Y and/or Zr, 0.0001 .ltoreq.y .ltoreq.0.01 for El = B and Me = Cr, Mn, Nb and/or W, 0.01 .ltoreq.z .ltoreq.0.04 if Me = an individual element, 0.01 .ltoreq.z .ltoreq.0.08 if Me = two or more individual elements and 0.46 .ltoreq.(x + y +z) .ltoreq.0.54.Type: GrantFiled: November 3, 1993Date of Patent: August 30, 1994Assignee: Asea Brown Boveri Ltd.Inventors: Mohamed Nazmy, Markus Staubli
-
Patent number: 5324367Abstract: A TiAl composition is prepared to have high strength, high oxidation resistance and to have acceptable ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a highly desirable effective aluminum concentration and by addition of chromium and tantalum and boron ingredients according to the approximate formula Ti-Al.sub.46-50 Cr.sub.2 Ta.sub.2-4 B.sub.0.05-0.2. Homogenization of the composition above the alpha transus temperature is used in combination with the boron doping to achieve higher ductility without sacrifice of strength.Type: GrantFiled: April 6, 1993Date of Patent: June 28, 1994Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5316722Abstract: A corrosion resistant Ti based alloy comprising:Cr: 0.005-2.0 wt %, and furthercomprising one or more of elements selected from:______________________________________ Ni: 0.005-2.0 wt %, Pd: 0.005-2.0 wt %, Ru: 0.005-2.0 wt %, Pt: 0.005-2.0 wt %, Os: 0.005-2.0 wt %, Ir: 0.005-2.0 wt %, Rh: 0.005-2.0 wt %, and ______________________________________the balance of Ti and inevitable impurities.Cr may be replaced with one or more of 0.005-1.5 wt % of Cu and 0.005-1.5 wt % of Si, or 0.005-2.0 wt % of Al. The corrosion resistant Ti based alloy has excellent corrosion resistance also in a non-oxidative atmosphere and also has an excellent crevice corrosion resistance.Type: GrantFiled: July 9, 1992Date of Patent: May 31, 1994Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Yasuaki Sugizaki, Keiji Ueda, Hiroshi Satoh, Hidetoshi Nishimoto, Tatsuya Yasunaga, Takashi Yashiki
-
Patent number: 5304344Abstract: A TiAl composition is prepared to have high strength, high oxidation resistance and to have acceptable ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a highly desirable effective aluminum concentration by addition of chromium and tungsten according to the approximate formula Ti.sub.48 Al.sub.48 Cr.sub.2 W.sub.2.Type: GrantFiled: June 2, 1989Date of Patent: April 19, 1994Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5304263Abstract: A titanium alloy part having a structure comprising ex-beta acicular grains and with equi-axial alpha phases gathered in a plurality of rows at boundaries of the grains. The alloy comprises, by weight, 2 to 5% Mo, 3.5 to 6.5% Al, 1.5 to 2.5% Sn, 1.5 to 4.8% Zr, Fe.ltoreq.1.5%, 4 to 12% Mo+V+Cr, and the balance, titanium and impurities.Type: GrantFiled: June 30, 1993Date of Patent: April 19, 1994Assignee: Compagnie Europeenne Du Zirconium CezusInventors: Bernard Champin, Bernard Prandi
-
Patent number: 5296055Abstract: A titanium aluminide is composed of 31 to 34 mass % of Al, 1.5 to 3.0 mass % of Fe, 0.5 to 2.0 mass % of V, 0.18 to 0.35 mass % of B with remainder being Ti and inevitable impurities. The 0.5 to 2.0 mass % of V may be replaced with a 1.0 to 3.0 mass % of Mo or a 0.3 to 1.5 mass % of Cr. By precision casting this alloy, a novel titanium aluminide alloy is obtained in which numerous whisker-like Ti--B compound are uniformly dispersed. The titanium aluminide alloy does not possess a coarse lamellar structure which would cause cracking.Type: GrantFiled: July 30, 1991Date of Patent: March 22, 1994Assignee: Ishikawajima-Harima Heavy Industries Co., Ltd.Inventor: Kenji Matsuda
-
Patent number: 5296056Abstract: A family of gamma titanium aluminide alloys is provided which is based on the intermetallic compound TiAl and includes alloying additions which enable the alloys to exhibit both sufficient mechanical properties and environmental capabilities for use in high temperature applications associated with gas turbine and automotive engines. The preferred alloys have a nominal aluminum content of about 46 atomic percent and further include niobium at about three to about five atomic percent and tungsten at about one atomic percent nominally, so as to selectively enhance the oxidation resistance of the alloy. As species of the preferred alloy, alloying additions of vanadium, chromium and manganese can be included at levels of up to about two atomic percent to enhance the toughness and ductility of the preferred alloy at lower temperatures, such as those encountered during fabrication and during low temperature operations.Type: GrantFiled: October 26, 1992Date of Patent: March 22, 1994Assignee: General Motors CorporationInventors: Sushil K. Jain, James R. Roessler
-
Patent number: 5286443Abstract: The high temperature alloy is intended for machine components subjected to high mechanical and thermal stress. It is essentially based on doped TiAl and has the following composition:Ti.sub.x El.sub.y Me.sub.z Al.sub.1-(x+y+z),in which El=B, Ge or Si and Me=Co, Cr, Ge, Hf, Mn, Mo, Nb, Pd, Ta, V, W, Y, and/or Zr and:______________________________________ 0.46 .ltoreq.x .ltoreq.0.54, 0.001 .ltoreq.y .ltoreq.0.015 for El = Ge and Me = Cr, Hf, Mn, Mo, Nb, Ta, V and/or W, 0.001 .ltoreq.y .ltoreq.0.015 for El = Si and Me = Hf, Mn, Mo, Ta, V and/or W, 0 .ltoreq.y .ltoreq.0.01 for El = B and Me = Co, Ge, Pd, Y and/or Zr, 0 .ltoreq.y .ltoreq.0.02 for El = Ge and Me = Co, Ge, Pd, Y and/or Zr, 0.0001 .ltoreq.y .ltoreq.0.01 for El = B and Me = Cr, Mn, Nb and/or W, 0.01 .ltoreq.z .ltoreq.0.04 if Me = an individual element, 0.01 .ltoreq.z .ltoreq.0.08 if Me = two or more individual elements and 0.46 .ltoreq.(x + y + z) .ltoreq.0.54.Type: GrantFiled: November 25, 1992Date of Patent: February 15, 1994Assignee: Asea Brown Boveri Ltd.Inventors: Mohamed Nazmy, Markus Staubli
-
Patent number: 5284618Abstract: A niobium and titanium based alloy having a density less than 6.5 and possessing a high resistance to oxidation at high temperatures in the region of 900.degree. C. has a chemical composition comprising, in atomic percentages:more than 24% Nbfrom 30 to 48% Tifrom 21 to 38% Aland possibly up to 8% of at least one of Cr, Mo, V and Zr.Type: GrantFiled: March 20, 1992Date of Patent: February 8, 1994Assignees: Association pour la Recherche et le Developpement des Methodes et Processus Industriels "A.R.M.I.N.E.S.", Societe Nationale d'Etude et de Construction de Moteurs d'Aviation "S.N.E.C.M.A."Inventors: Michel L. Allouard, Yves C. Bienvenu, Christophe Delaunay, Christian A. B. Ducrocq, Gerard Lemaitre, Michel Marty, Andre Walder
-
Patent number: 5284620Abstract: A TiAl alloy base melt including at least one of Cr, C, Ga, Mo, Mn, Nb, Ni Si, Ta, V and W and at least about 0.5 volume % boride dispersoids is investment cast to form a crack-free, net or near-net shape article having a gamma TiAl intermetallic-containing matrix with a grain size of about 10 to about 250 microns as a result of the presence of the boride dispersoids in the melt. As hot isostatically pressed and heat treated to provide an equiaxed grain structure, the article exhibits improved strength.Type: GrantFiled: December 11, 1990Date of Patent: February 8, 1994Assignee: Howmet CorporationInventor: Donald E. Larsen, Jr.
-
Patent number: 5271884Abstract: A TiAl composition is prepared to have high strength and to have improved ductility by altering the atomic ratio of the titanium and niobium to have what has been found to be a highly desirable effective aluminum concentration by addition of a combination of manganese and tantalum according to the approximate formula:Ti.sub.52-43 Al.sub.46-50 Ta.sub.1-4 Mn.sub.1-3.Type: GrantFiled: September 8, 1989Date of Patent: December 21, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5264051Abstract: A TiAl composition is prepared to have high strength, high oxidation resistance and to have acceptable ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a highly desirable effective aluminum concentration by addition of chromium, niobium, and silicon according to the approximate formula Ti-Al.sub.45 Cr.sub.2 Si.sub.2 Nb.sub.4.Type: GrantFiled: December 2, 1991Date of Patent: November 23, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5264054Abstract: A method for providing improved ductility in a gamma titanium aluminide is taught. The method involves adding inclusions of boron to the titanium aluminide containing chromium, carbon, and niobium and thermomechanically working the casting. Boron additions are made in concentrations between 0.5 and 2 atomic percent. Fine grain equiaxed microstructure is found from solidified melt. Property improvements are achieved by the thermomechanical processing.Type: GrantFiled: May 18, 1992Date of Patent: November 23, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5261940Abstract: Composite materials comprising beta titanium alloy matrices containing high strength, high stiffness filaments are described. The matrix materials are true beta titanium alloys having very limited solid solubility for the filament materials. This low reactivity permits high fabrication temperatures and high use temperatures without formation of deleterious brittle phases. Also described is a method for fabricating such composites.Type: GrantFiled: May 8, 1989Date of Patent: November 16, 1993Assignee: United Technologies CorporationInventor: Douglas M. Berczik
-
Patent number: 5256202Abstract: The present invention provides a Ti--Al intermetallic compound sheet of a thickness in the range of 0.25 to 2.5 mm formed of a Ti--Al intermetallic compound of 40 to 53 atomic percent of Ti, 0.1 to 3 atomic percent of at least one of material selected from the group consisting of Cr, Mn, V and Fe, and the balance of Al, and a Ti--Al intermetallic compound sheet producing method comprising the steps of pouring a molten Ti--Al intermetallic compound of the foregoing composition into the mold of a twin drum continuous casting machine, casting and rapidly solidifying the molten Ti--Al intermetallic compound to produce a thin cast plate of a thickness in the range of 0.25 to 2.5 mm and, when necessary, subjecting the thin cast plate to annealing and HIP treating. The Ti--Al intermetallic compound sheet has excellent mechanical and surface properties.Type: GrantFiled: August 23, 1991Date of Patent: October 26, 1993Assignee: Nippon Steel CorporationInventors: Toshihiro Hanamura, Munetsugu Matsuo, Toshiaki Mizoguchi, Kenichi Miyazawa, Masao Kimura, Naoya Masahashi
-
Patent number: 5238647Abstract: The invention provides (1) a titanium alloy with excellent corrosion resistance consisting essentially of 10-40 wt % of Mo, 0.1-15 wt % of Cr, and the balance of Ti and unavoidable impurities and (2) a titanium alloy according to (1) which further contains 0.01-2.0 wt % (in total) of Ru, Ir, Os, Pd, Pt, or/and Rh. The addition of Mo allows Ti-based alloys to form on the surface a protective film with a high concentration of Mo, whereby their corrosion resistance in non-oxidizing acids, such as hydrochloric and sulfuric acids, is markedly improved. In environments where oxidants are present, even but a few ppm in amount, Mo comes out in solution, seriously affecting the corrosion resistance of the alloys. To avoid this, Cr must also be added. The addition of Cr helps keep Mo from dissolving out and thereby prevent the deterioration of corrosion resistance by the action of oxidants in the environments. The platinum group elements, singly or in combination, further improve the corrosion resistance.Type: GrantFiled: November 25, 1991Date of Patent: August 24, 1993Assignee: Nippon Mining and Metals Company LimitedInventors: Yasuhiro Mitsuyoshi, Kazuhiro Taki
-
Patent number: 5232661Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+ 2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.Type: GrantFiled: August 8, 1991Date of Patent: August 3, 1993Assignee: Nippon Steel CorporationInventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
-
Patent number: 5228931Abstract: A TiAl composition is prepared to have high strength, high oxidation resistance and to have acceptable ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a highly desirable effective aluminum concentration and by addition of chromium, boron, and tantalum according to the approximate formulaTi-Al.sub.46-48 Cr.sub.1-3 Ta.sub.2-4 B.sub.0.1-0.3.The alloy is cast to form a body and the body is HIPped to impart a desirable combination of properties thereto.Type: GrantFiled: December 20, 1991Date of Patent: July 20, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5215600Abstract: A sheet of Ti 6-2-2-2-2 alloy having a starting thickness of between approximately 0.040 inches and 0.187 inches is thermomechanically treated at a temperature of between approximately 1500 degrees F. and 1750 degrees F. at a mechanical strain rate in the range of between approximately 1.times.10.sup.-4 and 1.times.10.sup.-2 inch per inch per second to produce a formed part having a tensile strength which is approximately 33% greater than untreated rolled Ti 6-2-2-2-2 alloy sheet or plate.Type: GrantFiled: July 22, 1991Date of Patent: June 1, 1993Assignee: Rohr, Inc.Inventors: Mark S. Bertolini, Brian Norris, Michael J. Waring
-
Patent number: 5213635Abstract: A method for providing improved castability in a gamma titanium aluminide is taught. The method involves adding inclusions to the near stoichiometric titanium aluminide and specifically low chromium and high niobium inclusions. Niobium additions are made in concentrations between 6 and 14 atomic percent. Chromium additions are between 1 and 3 atom percent. Property improvements are also achieved.A preferred composition is according to the following expression:Ti--i Al.sub.46--48 Cr.sub.1--3 Nb.sub.Type: GrantFiled: December 23, 1991Date of Patent: May 25, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5209790Abstract: A method of making a Titanium, Vanadium and Chromium alloy substantially free of Titanium-Chromium phases and inclusions of undissolved Vanadium including the steps of alloying preselected amounts of Vanadium and Chromium to produce a stable phase alloy substantially free of unalloyed Chromium or Vanadium and then mixing and melting the stable phase alloy together with a preselected amount of Titanium to produce the final alloy composition.Type: GrantFiled: February 11, 1992Date of Patent: May 11, 1993Assignee: Teledyne Industries, Inc.Inventor: Chester C. Wojcik
-
Patent number: 5207982Abstract: The high temperature alloy is intended for machine components subjected to high mechanical and thermal stress. It is essentially based on doped TiAl and has the following composition:Ti.sub.x El.sub.y Me.sub.z Al.sub.1 -(x+y+z),in whichEl=B, Ge or Si and Me=Co, Cr, Ge, Hf, Mn, Mo, Nb, Pd, Ta, V, W, Y, and/or Zr and:______________________________________ 0.46 .ltoreq.x .ltoreq.0.54, 0.001 .ltoreq.y .ltoreq.0.015 for El = Ge and Me = Cr, Hf, Mn, Mo, Nb, Ta, V and/or W, 0.001 .ltoreq.y .ltoreq.0.015 for El = Si and Me = Hf, Mn, Mo, Ta, V and/or W, 0 .ltoreq.y .ltoreq.0.01 for El = B and Me = Co, Ge, Pd, Y and/or Zr, 0 .ltoreq.y .ltoreq.0.02 for El = Ge and Me = Co, Ge, Pd, Y and/or Zr, 0.0001 .ltoreq.y .ltoreq.0.01 for El = B and Me = Cr, Mn, Nb and/or W, 0.01 .ltoreq.z .ltoreq.0.04 if Me = an individual element, 0.01 .ltoreq.z .ltoreq.0.08 if Me = two or more individual elements and 0.46 .ltoreq.(x + y + z) .ltoreq.0.54.Type: GrantFiled: May 3, 1991Date of Patent: May 4, 1993Assignee: Asea Brown Boveri Ltd.Inventors: Mohamed Nazmy, Markus Staubli
-
Patent number: 5207845Abstract: A process for manufacturing rolled articles of titanium material comprising steps of contacting heated titanium material with fluorine- or fluoride-containing gas to form a fluoride layer on the surface of the titanium material, removing the fluoride layer formed thereon just before rolling and then rolling the titanium material to give a rolled article. With this structure, passive coat layers, such as the oxide layer on the surface of the titanium material is changed to a fluoride layer. The fluoride layer protects the surface of the titanium material. Therefore even if there is space of time between formation and removal of the fluoride layer, the fluoride layer formed on the surface of the titanium material protects the same surface in a favorable condition, which results in preventing re-formation of an oxide layer on the titanium material surface.Type: GrantFiled: May 28, 1992Date of Patent: May 4, 1993Assignee: Daidousanso Co., Ltd.Inventors: Akira Yoshino, Haruo Senbokuya, Masaaki Tahara
-
Patent number: 5205875Abstract: A TiAl composition is prepared to have high strength and to have improved ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be an effective aluminum concentration and by addition of chromium, boron, and niobium according to the approximate formula Ti-Al.sub.46-48 Cr.sub.2 Nb.sub.2 B.sub.0.1-0.2. The composition is preferably prepared by casting, homogenization at a high temperature, and forging the homogenized casting.Type: GrantFiled: December 2, 1991Date of Patent: April 27, 1993Assignee: General Electric CompanyInventor: Shyh-Chin Huang
-
Patent number: 5205876Abstract: A titanium/aluminum alloy having a lamellar structure, comprising 0.01 to 0.05 wt. % of carbon, 31 to 35 wt. % of aluminum, 0.5 to 2.5 wt. % of manganese, 0.01 to 0.3 wt. % of nickel, 0.01 to 0.03 wt. % of cobalt, 0.05 to 0.2 wt. % of tungsten, 0 to 0.02 wt. % of magnesium, 0.01 to 0.05 wt. % of gold, 0.03 to 0.06 wt. % of boron, 0.04 to 0.08 wt. % of iron, and the balance of titanium.Type: GrantFiled: April 20, 1992Date of Patent: April 27, 1993Assignee: Taiyo Kogyo Co., Ltd.Inventor: Kuniyasu Sakai
-
Patent number: RE34588Abstract: Four groups of advanced hydrogen hydride storage and hydride electrode materials, consisting of two common elements, titanium and nickel. In the first group of materials, zirconium and chromium are added with the common elements. The second group of materials contain three additional elements in addition to the common elements, namely, chromium, zirconium and vanadium. The third group of materials contain also, in addition to the common elements, zirconium and vanadium. The fourth group of materials adds manganese and vanadium with the common elements. The preparation methods of the materials, as well as their hydride electrode are disclosed. Electrochemical studies indicate that these materials have high capacity, long cycle life and high rate capability.Type: GrantFiled: May 8, 1992Date of Patent: April 19, 1994Inventor: Kuochih Hong
-
Patent number: RE34598Abstract: Disclosed is a highly pure titanium which comprises containing not more than 200 ppm of oxygen; not more than 30 ppm each of elements consisting of iron, nickel and chromium, and not more than 0.1 ppm each of elements consisting of sodium and potassium.Disclosed is also a process for preparing the above highly pure titanium which comprises melting a crude titanium obtained by molten salt electrolysis, in a high vacuum of 5.times.10.sup.-5 mbar or less.Type: GrantFiled: January 2, 1992Date of Patent: May 3, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Kazumi Shimotori, Yoshiharu Ochi, Hideo Ishihara, Takenori Umeki, Takashi Ishigami