Molybdenum Or Tungsten Containing Patents (Class 420/450)
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Patent number: 11401582Abstract: An objective of the invention is to provide a Ni-based forged alloy article based on a superhigh precipitation-strengthening Ni-based alloy material that has mechanical properties balanced at higher level than before, and a turbine high-temperature member formed of the forged alloy article. There is provided a Ni-based forged alloy article comprising crystal grains of the ? phase and precipitation particles of the ?? phase, and having a chemical composition enabling to precipitate a ?? phase in an amount of 50-70 volume % at 700° C. within a matrix of a ? phase. The ?? phase comprises: aging precipitation ?? phase particles precipitating within the ? phase grains; and eutectic reaction ?? phase particles precipitating between/among the ? phase grains. The eutectic reaction ?? phase particles comprise a higher content of Ni and Al than the aging precipitation ?? phase particles and have an average particle size of 2 to 40 ?m.Type: GrantFiled: November 17, 2017Date of Patent: August 2, 2022Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Takashi Shibayama, Shinya Imano
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Publication number: 20150129644Abstract: A metal chemistry includes an amount of chromium weight of between about 9.0% and about 16% by weight, an amount of cobalt of between about 7.0% and about 14% by weight, an amount of molybdenum of between about 10% and about 20% by weight, an amount of iron of between about 1.0% and about 5.0% by weight, an amount of aluminum of between about 0.05% and about 0.75% by weight, an amount of titanium of between about 0.5% and about 2.0% by weight, an amount of manganese not to exceed about 0.8% by weight, an amount of carbon of between about 0.02% and about 0.10% by weight, an amount of a titanium+aluminum alloy of between about 0.55% and about 2.75% by weight, and an amount of nickel.Type: ApplicationFiled: January 22, 2015Publication date: May 14, 2015Inventors: Yan Cui, Srikanth Chandrudu Kottilingam, Dechao Lin, Brian Lee Tollison
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Publication number: 20150010427Abstract: In a Ni-base alloy, an area-equivalent diameter D is calculated. D is defined by D=A1/2 from an area A of a largest nitride in a field of view when an observation area S0 is observed. This process is repeated in n fields of view for measurement, where n is the number of the fields of view for measurement, so as to acquire n pieces of data on D, and the pieces are arranged in ascending order D1, D2, . . . , Dn to obtain a reduced variate yj. The obtained values are plotted on X-Y axis coordinates, where an X axis corresponds to D and a Y axis corresponds to yj. In a regression line yj=a×D+b, yj is obtained when a target cross-sectional area S is set to 100 mm2. When the obtained yj is substituted into the regression line, the estimated nitride maximum size is ?25 ?m in diameter.Type: ApplicationFiled: February 6, 2013Publication date: January 8, 2015Applicants: HITACHI METALS MMC SUPERALLOY, LTD., MITSUBISHI MATERIALS CORPORATIONInventors: Masato Itoh, Kenichi Yaguchi, Tadashi Fukuda, Takanori Matsui
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Patent number: 8828313Abstract: An Ni-base alloy for a turbine rotor of a steam turbine contains in percent by weight C: 0.01 to 0.15, Cr: 15 to 28, Co: 10 to 15, Mo: 8 to 12, Al: 1.5 to 2, Ti: 0.1 to 0.6, B: 0.001 to 0.006, Re: 0.5 to 3, and the balance of Ni and unavoidable impurities.Type: GrantFiled: March 13, 2009Date of Patent: September 9, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Kuniyoshi Nemoto, Kiyoshi Imai, Yomei Yoshioka, Masayuki Yamada, Reki Takaku, Shigekazu Miyashita, Takeo Suga, Takeo Takahashi, Kenichi Okuno, Akihiro Takakuwa
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Publication number: 20140248509Abstract: Compositions are provided that exhibit an austenitic nickel microstructure. The compositions comprise Ni, Cr, Mo and at least one element selected from the group consisting of Al, Si, and Ti. Feedstock having the composition may be in the form of a cored wire or wires, a solid wire or wires, or a powder.Type: ApplicationFiled: May 15, 2014Publication date: September 4, 2014Applicant: Scoperta, Inc.Inventors: Justin Lee Cheney, Grzegorz Jan Kusinski
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Patent number: 8808473Abstract: An austenitic heat resistant alloy includes, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 10.14 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 0.05%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 1.36% or less, Ti: 3% or less, and Nb: 3% or less, and the balance being Fe and impurities. The contents of P and S in the impurities are P: 0.03% or less and S: 0.01% or less. The alloy satisfies 1?4×Al+2×Ti+Nb?12 and P+0.2×Cr×B?0.035, where an element in the Formulas represents the content by mass percent.Type: GrantFiled: May 16, 2012Date of Patent: August 19, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroyuki Hirata, Hirokazu Okada, Hiroyuki Semba, Kazuhiro Ogawa, Atsuro Iseda, Mitsuru Yoshizawa
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Publication number: 20140193291Abstract: A foundry method of casting monocrystalline metal parts, the method including at least casting a molten alloy into a cavity of a mold through at least one casting channel in the mold, subjecting the alloy to heat treatment, and removing the mold, and wherein the heat treatment is performed before an end of mold removal.Type: ApplicationFiled: August 6, 2012Publication date: July 10, 2014Applicant: SNECMAInventors: Celine Yanxi Chan, Benoit Georges Jocelyn Marie, David Locatelli
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Patent number: 8734716Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.Type: GrantFiled: March 11, 2011Date of Patent: May 27, 2014Assignee: National Institute for Materials ScienceInventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
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Patent number: 8524149Abstract: A nickel base alloy includes: by mass, 0.001 to 0.1% of carbon; 12 to 23% of chromium; 15 to 25% of cobalt; 3.5 to 5.0% of aluminum; 4 to 12% of molybdenum; 0.1 to 7.0% of tungsten; and a total amount of Ti, Ta and Nb being not more than 0.5%. A parameter Ps represented by a formula (1) shown below is 0.6 to 1.6, Ps=?7×[C]?0.1×[Mo]+0.5×[Al]??(1) where [C] indicates an amount of carbon; [Mo] indicates an amount of molybdenum; and [Al] indicates an amount of aluminum, by mass percent.Type: GrantFiled: March 22, 2010Date of Patent: September 3, 2013Assignee: Hitachi, Ltd.Inventors: Jun Sato, Shinya Imano, Hiroyuki Doi
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Publication number: 20130224068Abstract: A metallic coating or alloy is provided. The metallic coating includes iron, cobalt, chromium, and aluminum. Tantalum may also be included. A new addition in nickel based coating with stabilized gamma/gamma? phases at high temperatures lead to a reduction of local stresses. A component including the metallic coating or alloy is also provided.Type: ApplicationFiled: March 23, 2010Publication date: August 29, 2013Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Anand A. Kulkarni, Jonathon E. Shipper, JR., Werner Stamm
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Patent number: 8480952Abstract: A method of manufacturing liposome-containing preparations which contain liposomes exhibiting superior stability in vivo and high enclosure rate of a drug is disclosed, comprising mixing a supercritical or subcritical carbon dioxide, one or more liposome membrane constituents including a phospholipid exhibiting a phase transition temperature and a water-soluble chemical.Type: GrantFiled: July 22, 2005Date of Patent: July 9, 2013Assignee: Konica Minolta Medical & Graphic, Inc.Inventors: Chiaki Nagaike, Yasuyuki Motokui
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Patent number: 8460482Abstract: A heat-resistant alloy spring is made of a Ni-based alloy material comprising in weight %: not more than 0.1% C; not more than 1.0% Si; not more than 1.50% Mn; 13.0 to 25.0% Cr; 1.5 to 7.0% Mo; 0.5 to 4.0% Ti; 0.1 to 3.0% Al; {at least one optional element selected from the group consisting of 0.15 to 2.50% W, 0.001 to 0.020% B, 0.01 to 0.3% Zr, 0.30 to 6.00% Nb, 5.0 to 18.0% Co, and 0.03 to 2.00% Cu}; the balance being essentially Ni; and incidental impurities. The Ni-based alloy material is provided in its crystal structure with gamma prime phase [Ni3(Al, Ti)] or gamma prime phase [Ni3(Al, Ti, Nb)].Type: GrantFiled: September 24, 2007Date of Patent: June 11, 2013Assignees: Nippon Seisen Co., Ltd., Chuo Spring Co., Ltd.Inventors: Yoshinori Tanimoto, Naoyuki Kawahata, Shoji Ichikawa, Hiroyuki Shiga
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Patent number: 8449262Abstract: Nickel-based superalloys, turbine blades, and methods of improving or repairing turbine engine components are included. A nickel-based superalloy includes, by weight, about 5% to about 12% cobalt, about 3% to about 10% chromium, about 5.5% to about 6.3% aluminum, about 5% to about 10% tantalum, about 3% to about 10% rhenium, about 2% to about 5% of one or more of elements selected from a group consisting of platinum, ruthenium, palladium, and iridium, about 0.1% to about 1.0% hafnium, about 0.01% to about 0.4% yttrium, about 0.01% to about 0.15% silicon, and a balance of nickel.Type: GrantFiled: December 8, 2009Date of Patent: May 28, 2013Assignee: Honeywell International Inc.Inventor: Tom Strangman
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Patent number: 8444778Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.Type: GrantFiled: August 29, 2008Date of Patent: May 21, 2013Assignees: Hitachi Metals, Ltd., Babcock-Hitachi Kabushiki Kaisha, Hitachi, Ltd.Inventors: Toshihiro Uehara, Takehiro Ohno, Akihiro Toji, Takashi Sato, Gang Bao, Shinya Imano, Hiroyuki Doi
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Publication number: 20130048700Abstract: A filler metal chemistry includes an amount of chromium weight of between about 9.0% and about 16% by weight, an amount of cobalt of between about 7.0% and about 14% by weight, an amount of molybdenum of between about 10% and about 20% by weight, an amount of iron of between about 1.0% and about 5.0% by weight, an amount of aluminum of between about 0.05% and about 0.75% by weight, an amount of titanium of between about 0.5% and about 2.0% by weight, an amount of manganese not to exceed 0.8% by weight, an amount of carbon of between 0.02% and about 0.10% by weight, an amount of titanium+aluminum of between about 0.55% and 2.75% by weight, and an amount of nickel.Type: ApplicationFiled: August 29, 2011Publication date: February 28, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Yan Cui, Srikanth Chandrudu Kottilingam, Dechao Lin, Brian Lee Tollison
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Publication number: 20130045129Abstract: A solder alloy including a base material, a solder, and an additive is provided. The solder alloy has the following formula: (1?x?y)*base material+x*solder+y*additive, where 0.2?x?0.8 and 0?y<0.8 and also (y<1?x)<(1?x). The base material includes chromium, cobalt, aluminum, and tungsten. The solder includes chromium, cobalt, aluminum, tungsten, germanium and/or gallium and nickel. The additive may include boron, zirconium, hafnium, niobium, and carbon.Type: ApplicationFiled: April 12, 2010Publication date: February 21, 2013Inventors: Michael Ott, Sebastian Piegert
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Publication number: 20130029179Abstract: A germanium containing nickel-based solder having a similar composition to a nickel-based superalloy is provided. As a result of which the proportion of ?? formed in the solder is reduced. The solder also includes chromium, cobalt, molybdenum, tungsten, aluminum, and titanium. A component including the solder is also provided.Type: ApplicationFiled: April 6, 2011Publication date: January 31, 2013Inventors: Michael Ott, Sebastian Piegert, Peter Randelzhofer, Robert Singer
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Patent number: 8354176Abstract: A metallic coating for protecting a substrate from high temperature oxidation and hot corrosion environments comprising about 2.5 to about 13.5 wt. % cobalt, about 12 to about 27 wt. % chromium, about 5 to about 7 wt. % aluminum, about 0.0 to about 1.0 wt. % yttrium, about 0.0 to about 1.0 wt. % hafnium, about 1.0 to about 3.0 wt. % silicon, about 0.0 to about 4.5 wt. % tantalum, about 0.0 to about 6.5 wt. % tungsten, about 0.0 to about 2.0 wt. % rhenium, about 0.0 to about 1.0 wt. % molybdenum and the balance nickel.Type: GrantFiled: May 22, 2009Date of Patent: January 15, 2013Assignee: United Technologies CorporationInventors: Michael Minor, Paul M. Pellet, Michael L. Miller, Brian S. Tryon
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Patent number: 8349250Abstract: A cobalt-nickel alloy composition is described, containing about 20% to about 28% cobalt; about 37% to about 46% nickel; at least about 6% chromium; aluminum; and at least one refractory metal. The total weight of cobalt, aluminum, and refractory metal in the composition is less than about 50% of the total weight of the composition. Moreover, the alloy composition comprises both a (Co, Ni)-gamma phase and an L12-structured (gamma prime) phase. Various components made from the cobalt-nickel alloy composition are also described. Examples include high-temperature machinery and devices, e.g., components of gas turbine engines.Type: GrantFiled: May 14, 2009Date of Patent: January 8, 2013Assignee: General Electric CompanyInventors: Akane Suzuki, Michael Francis Xavier Gigliotti, Jr.
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Publication number: 20120282086Abstract: The invention is a class of nickel-base alloys for gas turbine applications, comprising, by weight, about 13.7 to about 14.3 percent chromium, about 5.0 to about 10.0 percent cobalt, about 3.5 to about 5.2 percent tungsten, about 2.8 to about 5.2 percent titanium, about 2.8 to about 4.6 percent aluminum, about 0.0 to about 3.5 percent tantalum, about 1.0 to about 1.7 percent molybdenum, about 0.08 to about 0.13 percent carbon, about 0.005 to about 0.02 percent boron, about 0.0 to about 1.5 percent niobium, about 0.0 to about 2.5 percent hafnium, about 0.0 to about 0.04 percent zirconium, and the balance substantially nickel. The nickel-base alloys may be provided in the form of useful articles of manufacture, and which possess a unique combination of mechanical properties, microstructural stability, resistance to localized pitting and hot corrosion in high temperature corrosive environments, and high yields during the initial forming process as well as post-forming manufacturing and repair processes.Type: ApplicationFiled: May 4, 2011Publication date: November 8, 2012Inventors: Ganjiang Feng, Jon Conrad Schaeffer, Stephen Joseph Balsone, Hariharan Sundaram, Sundar Amancherla, Gitahi Charles Mukira
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Patent number: 8293169Abstract: A high strength, ductile, and tough Ni-base heat resistant alloy comprises by mass percent, C: 0.1% or less, Si: 1% or less, Mn: 1% or less, Cr: not less than 15% to less than 28%, Fe: 15% or less, W: more than 5% to not more than 20%, Al: more than 0.5% to not more than 2%, Ti: more than 0.5% to not more than 2%, Nd: 0.001 to 0.1% and B: 0.0005 to 0.01%, with the balance being Ni and impurities. Impurity contents of P, S, Sn, Pb, Sb, Zn and As are P: 0.03% or less, S: 0.01% or less, Sn: 0.020% or less, Pb: 0.010% or less, Sb: 0.005% or less, Zn: 0.005% or less and As: 0.005% or less, and formulas of [0.015?Nd+13.4×B?0.13], [Sn+Pb?0.025] and [Sb+Zn +As?0.010] are met.Type: GrantFiled: March 24, 2011Date of Patent: October 23, 2012Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hiroyuki Semba, Atsuro Iseda, Hiroyuki Hirata, Kaori Kawano, Masaaki Igarashi, Osamu Miyahara
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Patent number: 8187725Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron; less than about 1.0% manganese; about 2.1 to 4.0% niobium plus tantalum; 1.0 to 6.5% molybdenum; less than 0.50% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities. The method includes the steps of forming a welding electrode from the above alloy composition and melting the electrode to form a weld deposit. A preferred weldment may be in the form of a tubesheet of a nuclear reactor.Type: GrantFiled: July 19, 2007Date of Patent: May 29, 2012Assignees: Huntington Alloys Corporation, Areva NP Inc.Inventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
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Publication number: 20110223055Abstract: A Ni-base heat resistant alloy, which comprises by mass percent, C: 0.1% or less, Si: 1% or less, Mn: 1% or less, Cr: not less than 15% to less than 28%, Fe: 15% or less, W: more than 5% to not more than 20%, Al: more than 0.5% to not more than 2%, Ti: more than 0.5% to not more than 2%, Nd: 0.001 to 0.1% and B: 0.0005 to 0.01%, with the balance being Ni and impurities, in which the contents of P, S, Sn, Pb, Sb, Zn and As among the impurities are P: 0.03% or less, S: 0.01% or less, Sn: 0.020% or less, Pb: 0.010% or less, Sb: 0.005% or less, Zn: 0.005% or less and As: 0.005% or less, and further satisfies the formulas of [0.015?Nd+13.4×B?0.13], [Sn+Pb?0.025] and [Sb+Zn+As?0.010] is an alloy in which much higher strength than the conventional Ni-base heat resistant alloy can be achieved, the ductility and toughness after a long period of use at a high temperature are remarkably improved, and moreover the zero ductility temperature and the hot workability are also further improved.Type: ApplicationFiled: March 24, 2011Publication date: September 15, 2011Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Hiroyuki SEMBA, Atsuro ISEDA, Hiroyuki HIRATA, Kaori KAWANO, Masaaki IGARASHI, Osamu MIYAHARA
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Publication number: 20110192501Abstract: It is an object of the present invention to provide an Ni based alloy for forging having high forging-related characteristics with a wide temperature range for high-temperature forging and high upper forging temperature limit. An Ni based alloy for forging, containing Cr at 12 to 20%, Al at 3.5 to 5%, Co at 15 to 23%, W at 5 to 12%, C at 0.001 to 0.05%, and Nb, Ti and Ta at a total content of 0.5 to 1.0%, all percentages by mass, and a steam turbine plant component using the same.Type: ApplicationFiled: February 2, 2011Publication date: August 11, 2011Inventors: Shinya IMANO, Hiroyuki Doi, Jun Sato
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Publication number: 20110194971Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.Type: ApplicationFiled: March 11, 2011Publication date: August 11, 2011Inventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
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Publication number: 20110058978Abstract: A nickel base alloy includes: by mass, 0.001 to 0.1% of carbon; 12 to 23% of chromium; 15 to 25% of cobalt; 3.5 to 5.0% of aluminum; 4 to 12% of molybdenum; 0.1 to 7.0% of tungsten; and a total amount of Ti, Ta and Nb being not more than 0.5%. A parameter Ps represented by a formula (1) shown below is 0.6 to 1.6, Ps=?7×[C]?0.1×[Mo]+0.5×[Al]??(1) where [C] indicates an amount of carbon; [Mo] indicates an amount of molybdenum; and [Al] indicates an amount of aluminum, by mass percent.Type: ApplicationFiled: March 22, 2010Publication date: March 10, 2011Inventors: Jun SATO, Shinya Imano, Hiroyuki Doi
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Publication number: 20110058977Abstract: A Ni based cast alloy consisting essentially of C: 0.01 to 0.2% by weight, Si: 0.5 to 4.0% by weight, Cr: 14 to 22% by weight, Mo+W: 4.0 to 10% by weight, B: 0.001 to 0.02% by weight, Co: up to 10% by weight, Al: up to 0.5% by weight, Ti: up to 0.5% by weight, Nb: up to 5.0% by weight, Fe: up to 10% by weight, the balance being Ni and incidental impurities, wherein a ?? phase precipitates in a matrix phase thereof.Type: ApplicationFiled: August 27, 2010Publication date: March 10, 2011Inventors: Jun Sato, Shinya Imano, Hiroyuki Doi
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Publication number: 20100266442Abstract: Burn-resistant metal alloys that also have a high tensile strength are described. The alloys generally include about 55 to about 75 weight percent nickel, about 12 to about 17 weight percent cobalt, about 4 to about 16 weight percent chromium, about 1 to about 4 weight percent aluminum, and about 1 to about 4 weight percent titanium.Type: ApplicationFiled: November 25, 2009Publication date: October 21, 2010Inventors: Monica A. Jacinto, Dallis Ann Hardwick
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Publication number: 20100226814Abstract: Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.Type: ApplicationFiled: August 29, 2008Publication date: September 9, 2010Applicants: HITACHI METALS, LTD., BABCOCK-HITACHI KABUSHIKI KAISHA, HITACHI, LTD.Inventors: Toshihiro Uehara, Takehiro Ohno, Akihiro Toji, Takashi Sato, Gang Bao, Shinya Imano, Hiroyuki Doi
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Publication number: 20100155236Abstract: Disclosed is a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel. More particularly, the present invention relates to a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel wherein Cr, Si, Al, Nb and Ti are added to a Ni-based substrate so as to form an oxide coating film which is stable in a LiCl—Li2O molten salt and, in addition, a process thereof and use of the same.Type: ApplicationFiled: December 18, 2008Publication date: June 24, 2010Applicant: KOREA ATOMIC ENERGY RESEARCH INSTITUTEInventors: Jong-Hyeon LEE, Soo-Haeng CHO, Eung-Ho KIM, Seong-Won PARK
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Publication number: 20100135847Abstract: A nickel-containing alloy is disclosed. The alloy contains about 1.5 to about 4.5 weight percent aluminum; about 1.5 to about 4.5 weight percent titanium; about 0.8 to about 3 weight percent niobium; about 14 to about 28 weight percent chromium; up to about 0.2 weight percent zirconium; about 10 to about 23 weight percent cobalt; about 1 to about 3 weight percent tungsten; about 0.05 to about 0.2 weight percent carbon, about 0.002 to about 0.012 weight percent boron; and about 40 to about 70 weight percent nickel. The atomic ratio of aluminum to titanium is at least about 0.5. The alloy is also substantially free of tantalum. Related processes and articles are also disclosed.Type: ApplicationFiled: October 21, 2009Publication date: June 3, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Liang Jiang, Ji-Cheng Zhao, Ganjiang Feng
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Patent number: 7708846Abstract: For a group of nickel-based superalloys, improved properties have been obtained by stabilizing at increased temperature for a reduced time relative to prior art specifications. In particular, improved creep properties have been obtained with a one-hour 1800° F. stabilization relative to a prior art four-hour 1500° F. stabilization.Type: GrantFiled: November 28, 2005Date of Patent: May 4, 2010Assignee: United Technologies CorporationInventor: David R. Malley
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Publication number: 20100092301Abstract: A component for a high-temperature steam turbine which operates at temperatures above 600° C., especially above 700° C., is formed of a nickel-based alloy. The negative influence of oxidation of the component which is induced by the superheated steam is prevented by the alloy which is used, having the following composition (in % by weight): C: ?0.2 Si: ?1.0 Mn: ?1.0 Cr: 22.0-25.0 Co: 15.0-25.0 Mo: ?3.0 Nb: ?2.0 Al: 1.0-3.0 Ti: 2.0-4.0 Fe: ?2.0 Zr: ?0.2 B: ??0.05 Ni: remainder.Type: ApplicationFiled: October 27, 2008Publication date: April 15, 2010Inventor: Richard Brendon Scarlin
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Patent number: 7662740Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.Type: GrantFiled: June 3, 2004Date of Patent: February 16, 2010Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
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Publication number: 20090285715Abstract: The invention relates to a welding additive material, a use of a welding additive material, welding methods and a component which significantly improves the weldability of some nickel-based superalloys by means of a welding additive material and comprises the following constituents (in wt %): 18.0%-20.0% of chromium, 9.0%-11.0% of cobalt, 7.0%-10.0% of molybdenum, 2.0%-2.5% of titanium, 1.0%-1.7% of aluminum, 0.04%-0.08% of carbon, balance nickel.Type: ApplicationFiled: February 16, 2007Publication date: November 19, 2009Inventors: Nikolai Arjakine, Uwe Paul, Rolf Wilkenhöner
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Patent number: 7597843Abstract: Nickel based superalloys with excellent mechanical strength, corrosion resistance and oxidation resistance, which consist essentially of chromium in an amount of 3 to 7% by weight, cobalt in an amount of 3 to 15% by weight, tungsten in an amount of 4.5 to 8% by weight, rhenium in an amount of 3.3 to 6% by weight, tantalum in an amount of 4 to 8% by weight, titanium in an amount of 0.8 to 2% by weight, aluminum in an amount of 4.5 to 6.5% by weight, ruthenium in an amount of 0.1 to 6%, hafnium in an amount of 0.01 to 0.2% by weight, molybdenum in an amount of less than 0.5% by weight, carbon in an amount 0.06% by weight or less, boron in an amount of 0.01% by weight or less, zirconium in an amount of 0.01% by weight or less, oxygen in an amount of 0.005% by weight or less, nitrogen in an amount of 0.005% by weight or less and inevitable impurities and the balance being nickel.Type: GrantFiled: August 29, 2005Date of Patent: October 6, 2009Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc.Inventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
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Patent number: 7547188Abstract: A Ni-based alloy member has resistance against grain boundary fracture, fatigue strength, and oxidation resistance at temperatures near 1000° C. or higher. The Ni-based alloy member includes a non-repaired region made of a Ni-based alloy base and a region repaired by welding, which is formed on the non-repaired region and which is made of a buildup-welded layer, the buildup-welded layer being made of a Ni-based alloy containing, by weight, 15% or less of Co, 18-22% of Cr, 0.8-2.0% of Al, 5.0% or less of Ta, 0.5% or less of Mo, 0.5% or less of Ti, 13-18% of W, 0.05-0.13% of C, 0.06% or less of Zr, 0.015% or less of B, 0.4-1.2% of Mn, and 0.1-0.3% of Si, the balance of the alloy being preferably essentially made of Ni.Type: GrantFiled: February 17, 2006Date of Patent: June 16, 2009Assignee: Hitachi, Ltd.Inventors: Shinya Imano, Hiroyuki Doi, Kunihiro Ichikawa, Katsumi Tanaka
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Patent number: 7531054Abstract: Embodiments of the present disclosure relate to nickel-base alloys and methods of direct aging nickel-base alloys. More specifically, certain embodiments of the present disclosure relate to methods of direct aging 718Plus® nickel-base alloy to impart improved mechanical properties, such as, but not limited to, tensile strength, yield strength, low cycle fatigue, fatigue crack growth, and creep and rupture life to the alloys. Other embodiments of the present disclosure relate to direct aged 718Plus® nickel-base alloy, and articles of manufacture made therefrom, having improved mechanical properties, such as, but not limited to, tensile strength, yield strength, low cycle fatigue, fatigue crack growth, and creep and rupture life.Type: GrantFiled: September 6, 2005Date of Patent: May 12, 2009Assignee: ATI Properties, Inc.Inventors: Richard L. Kennedy, Wei-Di Cao
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Patent number: 7484926Abstract: A steam turbine power plant which is provided with an extra-high-pressure turbine 100, a high-pressure turbine 200, an intermediate-pressure turbine 300 and a low-pressure turbine 400, and has high-temperature steam of 650° C. or more introduced into the extra-high-pressure turbine 100, wherein the extra-high-pressure turbine 100 has an outer casing cooling unit which cools an outer casing 111, and a turbine rotor 112, an inner casing 110 and a nozzle box 115 of the extra-high-pressure turbine 100 are formed of an Ni base heat-resisting alloy, and the outer casing 111 is formed of a ferrite-based alloy.Type: GrantFiled: March 15, 2006Date of Patent: February 3, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Takeo Suga, Ryuichi Ishii, Takeo Takahashi, Masafumi Fukuda
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Publication number: 20080260570Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.Type: ApplicationFiled: December 2, 2005Publication date: October 23, 2008Inventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
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Publication number: 20080253923Abstract: A nickel-based superalloy that forms a chromia scale in an oxidizing environment is disclosed. The alloy provides good oxidation resistance at temperatures below 900° C. in a dry or moist atmosphere. The superalloy is suited for components of gas or steam turbine engines including blades and vanes.Type: ApplicationFiled: April 10, 2007Publication date: October 16, 2008Inventors: Douglas J. Arrell, Allister W. James
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Publication number: 20080166258Abstract: A heat-resistant alloy spring is made of a Ni-based alloy material comprising in weight %: not more than 0.1% C; not more than 1.0% Si; not more than 1.50% Mn; 13.0 to 25.0% Cr; 1.5 to 7.0% Mo; 0.5 to 4.0% Ti; 0.1 to 3.0 % Al; {at least one optional element selected from the group consisting of 0.15 to 2.50% w, 0.001 to 0.020% B, 0.01 to 0.3% Zr, 0.30 to 6.00% Nb, 5.0 to 18.0% Co, and 0.03 to 2.00% Cu}; the balance being essentially Ni; and incidental impurities. The Ni-based alloy material is provided in its crystal structure with gamma prime phase [Ni3(Al, Ti)] or gamma prime phase [Ni3(Al, Ti, Nb)]. The gamma prime phase has an average grain diameter (d) of not less than 25 nanometers, and a hardness-diameter ratio (Hv/d) of a Vickers hardness Hv of a position at a depth of one-fourth of the entire thickness or the wire diameter from a surface of the Ni-based alloy material toward its center and the average grain diameter d(nanometer) is 5 to 25.Type: ApplicationFiled: September 24, 2007Publication date: July 10, 2008Applicants: Nippon Seisen Co., Ltd., Chuo Spring Co., Ltd.Inventors: Yoshinori Tanimoto, Naoyuki Kawahata, Shoji Ichikawa, Hiroyuki Shiga
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Patent number: 7208116Abstract: A nickel base superalloy comprising 14.0 to 20.0 wt % cobalt, 13.5 to 17.0 wt % chromium, 2.5 to 4.0 wt % aluminium, 3.4 to 5.0 wt % titanium, 0 to 3.0 wt % tantalum, 3.8 to 5.5 wt % molybdenum, 0.035 to 0.07 wt % carbon, 0.01 to 0.04 wt % boron, 0.055 to 0.075 wt % zirconium, 0 to 0.4 wt % hafnium and the balance nickel plus incidental impurities. The nickel base superalloy is suitable for use as gas turbine engine high pressure compressor rotor discs or turbine discs. It is capable of operation at temperatures above 700° C. and has good fatigue crack propagation resistance, creep resistance and tensile strength.Type: GrantFiled: September 26, 2001Date of Patent: April 24, 2007Assignee: Rolls-Royce plcInventors: Andrew J Manning, David Knowles, Colin J Small
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Patent number: 7165325Abstract: A welding material composition, which is a nickel based super alloy having ?? phase and chromium carbides precipitated. The composition comprising 18 to 25% by weight of Co, 15 to 20% by weight of Cr, 1.5 to 5.5% by weight of Al, 5 to 14% by weight of W, 0.05 to 0.15% by weight of C, 0 to 0.02% by weight of B, 0 to 1% by weight of at least one of Ta, Nb, Ti, Mo, Re and Fe, 0 to 0.5% by weight of at least one of V, Zr, rare earth elements and Y, 0 to 1% by weight of Mn, 0 to 0.5% by weight of Si, and the balance being Ni.Type: GrantFiled: August 7, 2003Date of Patent: January 23, 2007Assignee: Hitachi, Ltd.Inventors: Shinya Imano, Hiroyuki Doi, Kunihiro Ichikawa, Hideaki Ishii
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Patent number: 7160400Abstract: A low thermal expansion Ni-base superalloy contains, by weight % (hereinafter the same as long as not particularly defined) C: 0.15% or less; Si: 1% or less; Mn: 1% or less; Cr: 5 to 20%; at least one of Mo, W and Re of Mo+½(W+Re) of 17 (exclusive) to 25%; Al: 0.2 to 2%; Ti: 0.5 to 4.5%; Fe of 10% or less; at least one of B: 0.02% and Zr: 0.2% or less; a remainder of Ni and inevitable impurities; wherein the atomic % of Al+Ti is 2.5 to 7.0.Type: GrantFiled: September 27, 2002Date of Patent: January 9, 2007Assignees: Daido Tokushuko Kabushiki Kaisha, Mitsubishi Heavy Industries, Ltd.Inventors: Ryotaro Magoshi, Hisataka Kawai, Yoshikuni Kadoya, Ryuichi Yamamoto, Toshiharu Noda, Susumu Isobe, Michio Okabe
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Patent number: 7005015Abstract: A high-temperature component made of a nickel super-alloy has the following composition in wt %: 11–13% of Cr, 3–5% of W, 0.5–2.5% of Mo, 3–5% of Al, 3–5% of Ti, 3–7% of Ta, 1–5% of Re and a remainder formed of nickel. A corresponding component which is also provided is formed of an alloy having a composition essentially similar to that mentioned above, but with the rhenium proportion replaced with 0.1–5 wt % of ruthenium.Type: GrantFiled: January 29, 2002Date of Patent: February 28, 2006Assignee: Seimens AktiengesellschaftInventors: Ralf Bürgel, Winfried Esser, Jörn Grossmann, Wolfgang Hermann, Hael Mughrabi, Jürgen Preuhs, Florian Pyczak, Alfred Scholz, Robert Singer, Andreas Volek
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Patent number: 6974508Abstract: A low solvus, high refractory alloy having unusually versatile processing mechanical property capabilities for advanced disks and rotors in gas turbine engines. The nickel base superalloy has a composition consisting essentially of, in weight percent, 3.0–4.0 Al, 0.02–0.04 B, 0.02–0.05 C, 12.0–14.0 Cr, 19.0–22.0 Co, 2.0–3.5 Mo, greater than 1.0 to 2.1 Nb, 1.3 to 2.1 Ta, 3.0–4.0 Ti, 4.1 to 5.0 W, 0.03–0.06 Zr, and balance essentially Ni aid incidental impurities. The superalloy combines ease of processing with high temperature capabilities to be suitable for use in various turbine engine disk, impeller, and shaft applications. The Co and Cr levels of the superalloy can provide low solvus temperature for high processing versatility. The W, Mo, Ta, and Nb refractory element levels of the superalloy can provide sustained strength, creep, and dwell crack growth resistance at high temperatures.Type: GrantFiled: October 29, 2002Date of Patent: December 13, 2005Assignee: The United States of America as represented by the United States National Aeronautics and Space AdministrationInventors: Timothy P. Gabb, John Gayda, Ignacy Telesman, Pete T. Kantzos
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Patent number: 6969431Abstract: A nickel based superalloy composition comprising 16.0 to 20.0 weight % Co, 9.5 to 11.5 weight % Cr, 1.8 to 3.0 weight % Mo, 4.3 to 6.0 weight % W, 3.0 to 4.2 weight % Al, 3.0 to 4.4 weight % Ti, 1.0 to 2.0 weight % Ta, 0.5 to 1.5 weight % Nb, 0.01 to 0.05 weight % C, 0.01 to 0.04 weight % B, and 0.04 to 0.15 weight % Zr, balance Ni.Type: GrantFiled: August 29, 2003Date of Patent: November 29, 2005Assignee: Honeywell International, Inc.Inventors: Andrew F. Hieber, Howard F. Merrick
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Patent number: 6921442Abstract: The present invention relates to a Ni base alloy having sufficient strength at high temperatures and high corrosion resistance at high temperatures in a high-temperature composite corrosive environment in which chlorination or sulfidation occurs simultaneously with high-temperature oxidation, without excessive cooling or surface protection. According to the present invention, a Ni base alloy having high-temperature strength and corrosion resistance includes Cr in a range of from 25 to 40 weight %, Al in a range of from 1.5 to 2.5 weight %, C in a range of from 0.1 to 0.5 weight %, W of 15 weight % or less, Mn of 2.0 weight % or less, Si in a range of from 0.3 to 6 weight %, Fe of 5% or less, and Ni of rest except inevitable impurities. When strength at high temperatures is allowed to be small, W is in a range of from 0 to 8%, and Si is in a range of from 0.3 to 1% or from 1 to 6%. In order to enhance strength at high temperatures, W is in a range of from 8 to 15, and Si is in a range of from 0.Type: GrantFiled: October 24, 2001Date of Patent: July 26, 2005Assignees: Ebara Corporation, Daido Tokushuko Kabushiki KaishaInventors: Manabu Noguchi, Kei Matsuoka, Hiroshi Yakuwa, Akira Uchino, Hideyuki Sakamoto, Michio Okabe, Yoshiyuki Sawada, Shigeki Ueta
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Patent number: 6918972Abstract: A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.Type: GrantFiled: February 20, 2003Date of Patent: July 19, 2005Assignee: Daido Tokushuko Kabushiki KaishaInventors: Shigeki Ueta, Toshiharu Noda