Titanium Containing Patents (Class 420/446)
  • Patent number: 12098446
    Abstract: A corrosion-resistant nickel alloy is provided. The alloy includes the following components in percentage by mass: 4.68-5.35% of B, 5.69-6.41% of W, 27.68-28.39% of Cr, 12.65-13.42% of Al, and the balance of Ni and inevitable impurities. The corrosion-resistant nickel alloy is a Ni—W—B ternary alloy with main components of Ni, W and B, wherein the three elements have strong high-temperature corrosion resistance at a temperature of about 600° C., and have the potential of solid solution hardening and precipitate formation because all belong to solid solution forming elements, so that a creep strength of a nickel alloy matrix is improved. Meanwhile, Al and Cr are further added in the alloy formula, so that Al2O3 and Cr2O3 oxide layers can be formed, which play a role as a physical diffusion barrier against chlorine gas and other corrosive gases.
    Type: Grant
    Filed: November 9, 2023
    Date of Patent: September 24, 2024
    Assignee: Hainan University
    Inventors: Wenchao Ma, Terrence Wenga, Sixuan Zeng, Xingcai Chen, Lingyu Tai
  • Patent number: 11866806
    Abstract: A corrosion-resistant nickel alloy, a preparation method thereof and, and a use thereof are provided. The alloy includes the following components in percentage by mass: 4.68-5.35% of B, 5.69-6.41% of W, 27.68-28.39% of Cr, 12.65-13.42% of Al, and the balance of Ni and inevitable impurities. The alloy disclosed by the present invention is a Ni—W—B ternary alloy with main components of Ni, W and B, wherein the three elements have strong high-temperature corrosion resistance at a temperature of about 600° C., and have the potential of solid solution hardening and precipitate formation because all belong to solid solution forming elements, so that a creep strength of a nickel alloy matrix is improved. Meanwhile, Al and Cr are further added in the alloy formula, so that Al2O3 and Cr2O3 oxide layers can be formed, which play a role as a physical diffusion barrier against chlorine gas and other corrosive gases.
    Type: Grant
    Filed: December 8, 2022
    Date of Patent: January 9, 2024
    Assignee: TIANJIN UNIVERSITY
    Inventors: Wenchao Ma, Sixuan Zeng, Terrence Wenga
  • Patent number: 10626488
    Abstract: This document describes a process/strategy for age hardening nickel based alloys to create desirable properties with reduced energy expenditure. The inventive process introduces isolated atom nucleation sites to accelerate the nucleation rate by approximately 36 times, thereby permitting age hardening to occur in significantly less time and with significantly less energy expenditure.
    Type: Grant
    Filed: October 12, 2016
    Date of Patent: April 21, 2020
    Assignee: The Florida State University Research Foundation, Inc.
    Inventors: Ke Han, Pingli Mao, Yan Xin
  • Patent number: 10335644
    Abstract: Some embodiments include a reinforced face of a club head. Other embodiments for related reinforced faces of club heads and related methods are also disclosed.
    Type: Grant
    Filed: May 26, 2017
    Date of Patent: July 2, 2019
    Assignee: Karsten Manufacturing Corporation
    Inventors: Eric V. Cole, Eric J. Morales
  • Patent number: 9962748
    Abstract: A roll for winding equipment in a hot rolling factory is obtained by forming a base build-up layer on the surface of the body of the roll and forming on the base build-up layer a self-fluxing alloy thermal spraying layer, in which carbide particles are dispersed. The base build-up layer has a Shore hardness of 60 or higher and includes an iron-based build-up layer that contains, in terms of mass %, 0.4-1.0% of C, 2.0% or less of Si, 3.0% or less of Mn, 1.0-15.0% of Cr and 0.5-5.0% of Nb.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: May 8, 2018
    Assignee: NIPPON STEEL & SUMIKIN HARDFACING CO., LTD.
    Inventor: Koichi Shijo
  • Patent number: 8992700
    Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 18.0 to 30.0% cobalt, 11.4 to 16.0% chromium, up to 6.0% tantalum, 2.5 to 3.5% aluminum, 2.5 to 4.0% titanium, 5.5 to 7.5% molybdenum, up to 2.0% niobium, up to 2.0% hafnium, 0.04 to 0.20% carbon, 0.01 to 0.05% boron, 0.03 to 0.09% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.71 to 1.60.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: March 31, 2015
    Assignee: General Electric Company
    Inventors: Kenneth Rees Bain, David Paul Mourer, Richard DiDomizio, Timothy Hanlon, Laurent Cretegny, Andrew Ezekiel Wessman
  • Patent number: 8877378
    Abstract: The performance of an ABx type metal hydride alloy is improved by adding an element to the alloy which element is operative to enhance the surface area morphology of the alloy. The alloy may include surface regions of differing morphologies.
    Type: Grant
    Filed: January 7, 2013
    Date of Patent: November 4, 2014
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Kwo Young, Benjamin Reichman, Michael A. Fetcenko
  • Patent number: 8734716
    Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.
    Type: Grant
    Filed: March 11, 2011
    Date of Patent: May 27, 2014
    Assignee: National Institute for Materials Science
    Inventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
  • Publication number: 20130224068
    Abstract: A metallic coating or alloy is provided. The metallic coating includes iron, cobalt, chromium, and aluminum. Tantalum may also be included. A new addition in nickel based coating with stabilized gamma/gamma? phases at high temperatures lead to a reduction of local stresses. A component including the metallic coating or alloy is also provided.
    Type: Application
    Filed: March 23, 2010
    Publication date: August 29, 2013
    Applicant: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Anand A. Kulkarni, Jonathon E. Shipper, JR., Werner Stamm
  • Patent number: 8426033
    Abstract: Provided are precipitation hardened high strength nickel based alloy welds that yield improved properties and performance in joining high strength metals. The advantageous weldments include two or more segments of ferrous or non-ferrous components, and fusion welds, friction stir welds, electron beam welds, laser beam welds, or a combination thereof bonding adjacent segments of the components together, wherein the welds comprise a precipitation hardened nickel based alloy weld metal composition including greater than or equal to 1.4 wt % of combined aluminum and titanium based on the total weight of the nickel based alloy weld metal composition. Also provided are methods for forming the welds from the nickel based alloy weld compositions, wherein the precipitation hardening occurs in the as-welded condition. The nickel based welds do not require a separate heat treatment step after welding to produce advantageous strength properties.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: April 23, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Raghavan Ayer, Neeraj Srinivas Thirumalai, Hyun-Woo Jin, Daniel B. Lillig, Douglas Paul Fairchild, Steven Jeffrey Ford
  • Publication number: 20120288400
    Abstract: An austenitic heat resistant alloy consisting of, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 0.03 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 4%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 3% or less, Ti: 3% or less, and Nb: 3% or less, the balance being Fe and impurities. The contents of P and S in the impurities being P: 0.03% or less and S: 0.01% or less. The alloy satisfies 1?4×Al+2×Ti+Nb?12 and P+0.2×Cr×B?0.035, is excellent in weld crack resistance and toughness of HAZ, and is further excellent in creep strength at high temperatures.
    Type: Application
    Filed: May 16, 2012
    Publication date: November 15, 2012
    Applicant: SUMITOMO METAL INDUSTRIES., LTD.
    Inventors: Hiroyuki Hirata, Hirokazu Okada, Hiroyuki Semba, Kazuhiro Ogawa, Atsuro Iseda, Mitsuru Yoshizawa
  • Patent number: 8137293
    Abstract: Medical devices and methods for making and using the same are disclosed. An example medical device may include a guidewire. The guidewire may include an elongate shaft. The shaft may include a porous metal alloy. The porous metal alloy may be arranged so that the porous metal alloy has a first pore distribution along a first portion of the shaft and a second pore distribution different from the first pore distribution along a second portion of the shaft.
    Type: Grant
    Filed: November 17, 2009
    Date of Patent: March 20, 2012
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Pu Zhou, Horng-Ban Lin, Hancun Chen, James Feng
  • Publication number: 20110194971
    Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.
    Type: Application
    Filed: March 11, 2011
    Publication date: August 11, 2011
    Inventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
  • Publication number: 20100303666
    Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 18.0 to 30.0% cobalt, 11.4 to 16.0% chromium, up to 6.0% tantalum, 2.5 to 3.5% aluminum, 2.5 to 4.0% titanium, 5.5 to 7.5% molybdenum, up to 2.0% niobium, up to 2.0% hafnium, 0.04 to 0.20% carbon, 0.01 to 0.05% boron, 0.03 to 0.09% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.71 to 1.60.
    Type: Application
    Filed: May 29, 2009
    Publication date: December 2, 2010
    Applicant: General Electric Company
    Inventors: Kenneth Rees Bain, David Paul Mourer, Richard DiDomizio, Timothy Hanlon, Laurent Cretegny, Andrew Ezekiel Wessman
  • Publication number: 20100266442
    Abstract: Burn-resistant metal alloys that also have a high tensile strength are described. The alloys generally include about 55 to about 75 weight percent nickel, about 12 to about 17 weight percent cobalt, about 4 to about 16 weight percent chromium, about 1 to about 4 weight percent aluminum, and about 1 to about 4 weight percent titanium.
    Type: Application
    Filed: November 25, 2009
    Publication date: October 21, 2010
    Inventors: Monica A. Jacinto, Dallis Ann Hardwick
  • Publication number: 20100266865
    Abstract: An article of manufacture for reducing susceptibility of a metal pipe to metal dusting degradation. The article includes a multi-layer tubing having an alloy layer and a copper layer. The alloy layer can include a Ni based, an Al based and an Fe based alloy layer. In addition, layers of chrome oxide, spinel and aluminum oxide can be used.
    Type: Application
    Filed: November 20, 2007
    Publication date: October 21, 2010
    Inventors: Krishnamurti Natesan, Zuotao Zeng
  • Publication number: 20100155236
    Abstract: Disclosed is a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel. More particularly, the present invention relates to a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel wherein Cr, Si, Al, Nb and Ti are added to a Ni-based substrate so as to form an oxide coating film which is stable in a LiCl—Li2O molten salt and, in addition, a process thereof and use of the same.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Applicant: KOREA ATOMIC ENERGY RESEARCH INSTITUTE
    Inventors: Jong-Hyeon LEE, Soo-Haeng CHO, Eung-Ho KIM, Seong-Won PARK
  • Publication number: 20100092301
    Abstract: A component for a high-temperature steam turbine which operates at temperatures above 600° C., especially above 700° C., is formed of a nickel-based alloy. The negative influence of oxidation of the component which is induced by the superheated steam is prevented by the alloy which is used, having the following composition (in % by weight): C: ?0.2 Si: ?1.0 Mn: ?1.0 Cr: 22.0-25.0 Co: 15.0-25.0 Mo: ?3.0 Nb: ?2.0 Al: 1.0-3.0 Ti: 2.0-4.0 Fe: ?2.0 Zr: ?0.2 B: ??0.05 Ni: remainder.
    Type: Application
    Filed: October 27, 2008
    Publication date: April 15, 2010
    Inventor: Richard Brendon Scarlin
  • Patent number: 7662740
    Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: February 16, 2010
    Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
  • Publication number: 20090211094
    Abstract: A memory metal or Nitinol plug is inserted into a tube and heated to cause the plug to expand as it transforms from a martensitic state to an austenitic state. The plug is held by a tool connected to an electric conductor. The tube is then grounded and current is run through the holder, the plug, and, in turn, the tube. Electrical resistance causes the plug to heat up and revert to the austenitic state. The holder is preferably a tube with an internal collet, spring urged into a closed position adapted to grasp a post of the Nitinol plug. To separate the holder from the plug, the collet is pulled to an expanded position by pulling the holder from the tube. This allows the collet to open and separate from the plug.
    Type: Application
    Filed: February 26, 2008
    Publication date: August 27, 2009
    Inventor: Roger Adelman
  • Patent number: 7484926
    Abstract: A steam turbine power plant which is provided with an extra-high-pressure turbine 100, a high-pressure turbine 200, an intermediate-pressure turbine 300 and a low-pressure turbine 400, and has high-temperature steam of 650° C. or more introduced into the extra-high-pressure turbine 100, wherein the extra-high-pressure turbine 100 has an outer casing cooling unit which cools an outer casing 111, and a turbine rotor 112, an inner casing 110 and a nozzle box 115 of the extra-high-pressure turbine 100 are formed of an Ni base heat-resisting alloy, and the outer casing 111 is formed of a ferrite-based alloy.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: February 3, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takeo Suga, Ryuichi Ishii, Takeo Takahashi, Masafumi Fukuda
  • Publication number: 20080260570
    Abstract: Disclosed is a novel heat-resistant superalloy for turbine disks having a chemical composition consisting of, in mass %, 19.5-55% of cobalt, 2-25% of chromium, 0.2-7% of aluminum, 3-15% of titanium and the balance of nickel and inevitable impurities.
    Type: Application
    Filed: December 2, 2005
    Publication date: October 23, 2008
    Inventors: Hiroshi Harada, Yuefeng Gu, Chuanyong Cui, Makoto Osawa, Akihiro Sato, Toshiharu Kobayashi
  • Patent number: 7165325
    Abstract: A welding material composition, which is a nickel based super alloy having ?? phase and chromium carbides precipitated. The composition comprising 18 to 25% by weight of Co, 15 to 20% by weight of Cr, 1.5 to 5.5% by weight of Al, 5 to 14% by weight of W, 0.05 to 0.15% by weight of C, 0 to 0.02% by weight of B, 0 to 1% by weight of at least one of Ta, Nb, Ti, Mo, Re and Fe, 0 to 0.5% by weight of at least one of V, Zr, rare earth elements and Y, 0 to 1% by weight of Mn, 0 to 0.5% by weight of Si, and the balance being Ni.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: January 23, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Shinya Imano, Hiroyuki Doi, Kunihiro Ichikawa, Hideaki Ishii
  • Patent number: 7052782
    Abstract: A high-temperature protection layer contains (% by weight) 23 to 27% Cr, 4 to 7% Al, 0.1 to 3% Si, 0.1 to 3% Ta, 0.2 to 2% Y, 0.001 to 0.01% B, 0.001 to 0.01% Mg and 0.001 to 0.01% Ca, remainder Ni and inevitable impurities. Optionally, the Al content is in a range from over 5 up to 6% by weight.
    Type: Grant
    Filed: July 19, 2004
    Date of Patent: May 30, 2006
    Assignee: ALSTOM Technology Ltd.
    Inventors: Hans-Peter Bossmann, Dietrich Eckardt, Klaus Erich Schneider, Christoph Toennes
  • Patent number: 6918972
    Abstract: A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: July 19, 2005
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventors: Shigeki Ueta, Toshiharu Noda
  • Patent number: 6860948
    Abstract: A nickel-chromium-molybdenum alloy capable of being age hardened for improved strength while maintaining high corrosion resistance contains in weight percent 19.5 to 22 chromium, 15 to 17.5 molybdenum, up to 3 iron, up to 1.5 manganese, up to 0.5 aluminum, up to 0.02 carbon, up to 0.015 boron, up to 0.5 silicon, up to 1.5 tungsten and up to 0.5 of each of hafnium, tantalum and zirconium, with a balance of nickel and impurities. Certain alloying elements must be present in amounts according to an equation here disclosed.
    Type: Grant
    Filed: September 5, 2003
    Date of Patent: March 1, 2005
    Assignee: Haynes International, Inc.
    Inventor: Lee M. Pike, Jr.
  • Patent number: 6818077
    Abstract: A nickel-based superalloy containing 12.0 to 16.0% by weight of Cr, 4.0 to 9.0% by weight of Co, 3.4 to 4.6% by weight of Al, 0.5 to 1.6% by weight of Nb, 0.05 to 0.16% by weight of C, 0.005 to 0.025% by weight of B, and at least one of Ti, Ta and Mo. Amounts of Ti, Ta and Mo are ones calculated by the equations (1) and (2), wherein TiEq is 4.0 to 6.0 and MoEq is 5.0 to 8.0. TiEq=Ti % by weight+0.5153×Nb % by weight+0.2647×Ta % by weight  (1) MoEq−Mo % by weight+0.5217×W % by weight+0.5303×Ta % by weight+1.
    Type: Grant
    Filed: May 6, 2003
    Date of Patent: November 16, 2004
    Assignee: Hitachi, Ltd.
    Inventors: Akira Yoshinari, Hideki Tamaki, Hiroyuki Doi
  • Publication number: 20040208777
    Abstract: Burn-resistant metal alloys that also have a high tensile strength are described. The alloys generally include about 55 to about 75 weight percent nickel, about 12 to about 17 weight percent cobalt, about 4 to about 16 weight percent chromium, about 1 to about 4 weight percent aluminum, and about 1 to about 4 weight percent titanium.
    Type: Application
    Filed: January 30, 2004
    Publication date: October 21, 2004
    Inventors: Monica A. Jacinto, Dallis Ann Hardwick
  • Patent number: 6797232
    Abstract: Creep-proof and corrosion-resistant nickel-based alloy for the use in high-temperature technology, comprising in wt-%: 0.0015 to 0.60 carbon (C); 0.20 to 0.90 nitrogen (N); 22.0 to 32.0 chromium (Cr); 5.0 to 20.0 elements of group 4, 5, and 6 of the periodic table, except Cr; 0.03 to 3.0 aluminum (Al); 0.4 to 3.0 silicon (Si); up to 0.15 elements of group 3 of the periodic table, except actinoids; up to 0.60 manganese (Ma); up to 14.8 iron (Fe); up to 0.01 boron (B); a maximum of 0.014 phosphorus (P); a maximum of 0.004 sulfur (S); a minimum of 51 nickel (Ni) or a combination of nickel (Ni) and cobalt (Co); and melting-related impurities.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: September 28, 2004
    Assignee: Bohler Edelstahl GmbH
    Inventors: Markus Speidel, Josef Bernauer
  • Publication number: 20040170521
    Abstract: Protective coatings known in the state of art can reveal either good corrosion resistance or good mechanical properties.
    Type: Application
    Filed: January 9, 2004
    Publication date: September 2, 2004
    Inventor: Werner Stamm
  • Patent number: 6752883
    Abstract: A free-cutting Ni-base heat-resistant alloy excellent in the high-temperature strength and corrosion resistance was proposed. The alloy contains Ni as a major component, 0.01 to 0.3 wt % of C and 14 to 35 wt % of Cr, and further contains at least one element selected from Ti, Zr and Hf in a total amount of 0.1 to 6 wt %, and S in an amount of 0.015 to 0.5 wt %. The alloy has dispersed in the matrix thereof a machinability improving compound phase, where such phase contains any one of Ti, Zr and Hf as a major constituent of the metal elements, essentially contains C and either S or Se as a binding component for such metal elements. The alloy also satisfies the relations of WTi+0.53WZr+0.27WHf>2WC+0.75WS and WC>0.37WS, where WTi represents Ti content (wt %), WZr represents Zr content (wt %), WHf represents Hf content (wt %), WC represents C content (wt %) and WS represents S content (wt %).
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: June 22, 2004
    Assignees: Dokuritsu Gyousei Houjin Sangyo Gijutsu Sougo Kenkyusho, Daido Tokushuko Kabushiki Kaisha, Tohoku Tokushuko Kabushiki Kaisha
    Inventors: Kiyohito Ishida, Katsunari Oikawa, Shigeki Ueta, Toshiharu Noda, Takashi Ebata
  • Patent number: 6702906
    Abstract: A Ni-base heat resistant alloy excellent in weldability and strength at elevated temperatures and suited for use in manufacturing cracking furnace tubes and reformer furnace tubes to be used in ethylene plants as well as a welded joint therefor is provided. The alloy of the invention is a Ni-base heat-resistant alloy, which comprises C: not more than 0.1%, Si: not more than 2%, Mn: not more than 2%, P: not more than 0.025%, S: not more than 0.005%, N: not more than 0.04%, Cr: 10 to 30%, Al: 2.1 to less than 4.5%, and Mo: 2.5 to 15% or W: 2.5 to 9% or Mo and W: 2.5 to 15% in total, and satisfies the relation (1) given below: (104Si+1980P+1980S+9Al+15Ti+11Nb+1.8W+11600B)≦{1.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: March 9, 2004
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kazuhiro Ogawa, Kazuyuki Kitamura, Hirokazu Okada, Yoshitaka Nishiyama
  • Patent number: 6696176
    Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: February 24, 2004
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: David B. Allen, Gregg P. Wagner, Brij B. Seth
  • Publication number: 20030164213
    Abstract: A Ni-base alloy which has excellent resistance to permanent set at high temperature and which can be produced at low cost, a heat-resistant spring made of the Ni-base alloy, and a process for producing the spring. The Ni-base alloy of the present invention consists of 0.01 to 0.15 mass % of C, 2.0 mass % or less of Si, 2.5 mass % or less of Mn, 12 to 25 mass % of Cr, 5.0 mass % or less of Mo and/or 5.0 mass % or less of W on condition that Mo+W/2 does not exceed 5.0 mass % or less, 1.5 to 3.5 mass % of Ti, 0.7 to 2.5 mass % of Al, 20 mass % or less of Fe, and the balance of Ni and unavoidable impurities. The ratio of Ti/Al in terms of atomic percentage ranges from 0.6 to 1.5 and the total content of Ti and Al ranges from 4.0 to 8.5 atomic %.
    Type: Application
    Filed: February 20, 2003
    Publication date: September 4, 2003
    Applicant: DAIDO TOKUSHUKO KABUSHIKI KAISHA
    Inventors: Shigeki Ueta, Toshiharu Noda
  • Publication number: 20030155047
    Abstract: A low thermal expansion Ni-base superalloy contains, by weight % (hereinafter the same as long as not particularly defined) C: 0.15% or less; Si: 1% or less; Mn: 1% or less; Cr: 5 to 20%; at least one of Mo, W and Re of Mo+½ (W+Re) of 17 (exclusive) to 25%; Al: 0.2 to 2%; Ti: 0.5 to 4.5%; Fe of 10% or less; at least one of B: 0.02% and Zr: 0.2% or less; a remainder of Ni and inevitable impurities; wherein the atomic % of Al+Ti is 2.5 to 7.0.
    Type: Application
    Filed: September 27, 2002
    Publication date: August 21, 2003
    Applicants: Daido Tokushuko Kabushiki Kaisha, Mitsubishi Heavy Industries, Ltd.
    Inventors: Ryotaro Magoshi, Hisataka Kawai, Yoshikuni Kadoya, Ryuichi Yamamoto, Toshiharu Noda, Susumu Isobe, Michio Okabe
  • Publication number: 20030053926
    Abstract: Burn-resistant metal alloys that also have a high tensile strength are described. The alloys generally include about 55 to about 75 weight percent nickel, about 12 to about 17 weight percent cobalt, about 4 to about 16 weight percent chromium, about 1 to about 4 weight percent aluminum, and about 1 to about 4 weight percent titanium.
    Type: Application
    Filed: September 18, 2001
    Publication date: March 20, 2003
    Inventors: Monica A. Jacinto, Dallis Ann Hardwick
  • Publication number: 20030051777
    Abstract: A solution treatment is firstly performed for a non-heat-treated Ni based alloy having a composition equivalent to that of Inconel 718 (registered trademark). Subsequently, a primary aging treatment is applied by holding the Ni based alloy at 610 to 660° C. for 5 to 10 hours. After that, a secondary aging treatment is performed by holding the Ni based alloy at 710 to 760° C. for 5 to 10 hours. There are 700 or more precipitates per &mgr;m2, in which each precipitate has a longer diameter of not less than 0.5 nm, in a metal microstructure of the Ni based alloy. Some of the precipitates are large precipitates having average diameters of 25 nm to 1 &mgr;m. There are 10 or more large precipitates per &mgr;m2. A forging die is produced with the Ni based alloy.
    Type: Application
    Filed: September 17, 2002
    Publication date: March 20, 2003
    Inventor: Koji Sudo
  • Publication number: 20020041821
    Abstract: A nickel base superalloy comprising 14.0 to 20.0 wt % cobalt, 13.5 to 17.0 wt % chromium, 2.5 to 4.0 wt % aluminium, 3.4 to 5.0 wt % titanium, 0 to 3.0 wt % tantalum, 3.8 to 5.5 wt % molybdenum, 0.035 to 0.07 wt % carbon, 0.01 to 0.04 wt % boron, 0.055 to 0.075 wt % zirconium, 0 to 0.4 wt % hafnium and the balance nickel plus incidental impurities. The nickel base superalloy is suitable for use as gas turbine engine high pressure compressor rotor discs or turbine discs. It is capable of operation at temperatures above 700° C. and has good fatigue crack propagation resistance, creep resistance and tensile strength.
    Type: Application
    Filed: September 26, 2001
    Publication date: April 11, 2002
    Inventors: Andrew J. Manning, David Knowles, Colin J. Small
  • Publication number: 20020015656
    Abstract: A low thermal expansion Ni-base superalloy contains, by weight % (hereinafter the same as long as not particularly defined), C: 0.15% or less; Si: 1% or less; Mn: 1% or less; Cr: 5 to 20%; at least one of Mo, W and Re of Mo+½ (W+Re) of 10 to 25%; Al: 0.2 to 2%; Ti: 0.5 to 4.5%; Fe of 10% or less; at least one of B: 0.02% and Zr: 0.2% or less; a remainder of Ni and inevitable impurities; wherein the atomic % of Al+Ti is 2.5 to 7.0.
    Type: Application
    Filed: March 2, 2000
    Publication date: February 7, 2002
    Inventors: Ryotaro Magoshi, Yoshikuni Kadoya, Ryuichi Yamamoto, Toshiharu Noda, Susumu Isobe, Michio Okabe
  • Patent number: 6242113
    Abstract: A nickel, chromium, iron alloy for use in producing weld deposits. The alloy comprises, in weight percent, about 27 to 31.5 chromium; about 7 to 11 iron; about 0.005 to 0.05 carbon; less than about 1.0 manganese, preferably 0.30 to 0.95 manganese; about 0.60 to 0.95 niobium; less than 0.50 silicon, preferably 0.10 to 0.30 silicon; 0.01 to 0.35 titanium; 0.01 to 0.25 aluminum; less than 0.20 copper; less than 1.0 tungsten; less than 1.0 molybdenum; less than 0.12 cobalt; less than 0.10 tantalum; less than about 0.10 zirconium, preferably 0.002 to 0.10 zirconium; less than about 0.01 sulfur; less than about 0.01 boron, preferably 0.001 to 0.01 boron; less than about 0.02 phosphorous; and balance nickel and incidental impurities.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: June 5, 2001
    Assignee: Inco Alloys International, Inc.
    Inventor: Samuel D. Kiser
  • Patent number: 6231692
    Abstract: Machineable nickel base alloy casting, consisting essentially of, in weight %, about 12.5% to 15% Cr, about 9.00% to 10.00% Co, about 3.70% to 4.30% Mo, about 3.70% to 4.30% W, about 2.80% to 3.20% Al, about 4.80% to 5.20% Ti, about 0.005% to 0.02% B, up to about 0.10% Zr, and balance essentially Ni and carbon below about 0.08 weight % to improve machinability while retaining alloy strength properties after appropriate heat treatment.
    Type: Grant
    Filed: January 28, 1999
    Date of Patent: May 15, 2001
    Assignees: Howmet Research Corporation, Siemens Aktiengesellschaft
    Inventors: Russell G. Vogt, John Corrigan, John R. Mihalisin, Ursula Pickert, Winfried Esser
  • Patent number: 6210635
    Abstract: A composition comprises cobalt; chromium; carbon; boron; zirconium; aluminum; at least one refractory material; and nickel. The composition is used as a repair material for repairing superalloy articles in a repair process.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: April 3, 2001
    Assignee: General Electric Company
    Inventors: Melvin Robert Jackson, Aaron Todd Frost, Charles Gitahi Mukira, Ann Melinda Ritter, Paul Vincent Crimi, Raymond Alan White
  • Patent number: 6190465
    Abstract: Soft magnetic alloy of the iron-nickel type, the chemical composition of which comprises, by weight: 40%≦Ni+Co≦65%; 0%≦Co≦7%; 2%≦Cr≦5%; 1%≦Ti≦3%; 0%≦Al≦0.5%; 0%≦Mn+Si≦2%; optionally, up to 3% Mo, 2% W, 2% V, 1.5% Nb, 1% Ta and 3% Cu, the sum of the Cr, Mo, W, V, Nb, Ta and Cu contents being less than 7% and the sum of the Mo, W, V, Nb, Ta and Cu contents being less than 4%; the balance being iron and impurities, such as carbon, sulfur and phosphorus, resulting from the smelting process, the chemical composition furthermore satisfying the relationships: Cr<5−0.015×(Ni+Co−52.5)2, if: Ni+Co≦52.5; Cr<5−0.040×(Ni+Co−52.5)2, if: Ni+Co≧52.5; the alloy having a saturation induction Bs of greater than 0.9 tesla, a coercive field of less than 10 A/m, an electrical resistivity p of greater than 60 &mgr;&OHgr;.cm and a hardness of greater than 200 HV. Process for manufacturing the alloy and uses.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: February 20, 2001
    Assignee: Imphy Ugine Precision
    Inventors: Lucien Coutu, Laurent Chaput, Thierry Waeckerle
  • Patent number: 6054096
    Abstract: Improved compositions for fabricating nickel superalloy single crystal articles are described. The compositions are characterized by the substantial absence of carbon, boron, zirconium and vanadium and intentional additions of cobalt. The cobalt additions increase the stability of the compositions and provide enhanced heat treatability. Single crystal articles of these compositions have utility as gas turbine engine components.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: April 25, 2000
    Assignee: United Technologies Corporation
    Inventors: David N. Duhl, Alan D. Cetel
  • Patent number: 6039919
    Abstract: A high corrosion resisting alloy for use in inlet and exhaust valves of diesel engines which is low in cost and excellent in corrosion resistance and strength, which consists by weight percentage of C.ltoreq.0.1%, Si.ltoreq.1.0%, Mn.ltoreq.1.0%, 25%<Cr.ltoreq.32%, 2.0%<Ti.ltoreq.3.0%, 1.0%.ltoreq.Al.ltoreq.2.0% and the balance being Ni and incidental impurities. The valves for the diesel engines are manufactured through the steps of forging the above-mentioned alloy into near net shapes of the valves, performing aging treatment (after solid solution treatment according to demand), and further enhancing hardness of the valves at their valve faces locally through partial cold forging.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: March 21, 2000
    Assignees: Daido Tokushuko Kabushiki Kaisha, Nittan Valve Co., Ltd.
    Inventors: Tomotaka Nagashima, Michio Okabe, Toshiharu Noda, Kiyoshi Okawachi
  • Patent number: 5900078
    Abstract: A high-temperature sulfidation-corrosion resistant nickel-base alloy includes 12.about.15 weight % of cobalt, 18.about.21 weight % of chromium, 3.5.about.5 weight % of molybdenum, 0.02.about.0.1 weight % of carbon, at most 2.75 weight % of titanium, and at least 1.6 weight % of aluminum. The remainder is essentially of nickel except for impurities. The high-temperature sulfidation-corrosion resistant nickel-base alloy has sufficient high-temperature strength and is highly resistant to a high-temperature sulfidation corrosion.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: May 4, 1999
    Assignee: Ebara Corporation
    Inventors: Hiroshi Yakuwa, Matsuho Miyasaka, Toshio Narita, Shuhei Nakahama, Masamichi Kawasaki
  • Patent number: 5652005
    Abstract: A method of producing filled sandwich cookies to be fed by an auger into an ice cream stream to produce ice cream with filled cookies comprising baking dough in units of multiple cookie elements, of substantially round shape, applying filling to each cookie element of a portion of the units which have been produced, sandwiching other units onto the filling, and then separating the multiple sandwich cookie units into individual sandwich cookies; the units comprise multiple cookie elements of approximately round shape, and each of which is between one-half inch and seven eighths inch diameter, the units containing two rows with three cookies in each row, with juncture lines between adjacent cookies.
    Type: Grant
    Filed: May 29, 1996
    Date of Patent: July 29, 1997
    Assignee: Interbake Foods Inc.
    Inventor: Dennis J. Loalbo
  • Patent number: 5599385
    Abstract: A protective coating resistant to corrosion at medium and high temperatures is applied on a nickel-based or cobalt-based superalloy component. The protective coating essentially consists of the following elements (in percent by weight): 25 to 40% nickel, 28 to 32% chromium, 7 to 9% aluminum, 1 to 2% silicon, 0.3 to 1% of at least one reactive element of the rare earths, at least 5% cobalt; and impurities, as well as selectively from 0 to 15% of at least one of the elements of the group consisting of rhenium, platinum, palladium, zirconium, manganese, tungsten, titanium, molybdenum, niobium, iron, hafnium, and tantalum. The total share of the elements of the group is from 0 to a maximum of 15% and a remainder of at least 5% cobalt. The component and the coating applied thereon have a ductile brittle transition temperature below 500.degree. C.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: February 4, 1997
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5582635
    Abstract: A protective coating resistant to corrosion at medium and high temperatures is applied on a nickel-based or cobalt-based superalloy component. The protective coating essentially consists of the following elements (in percent by weight): 25 to 40% nickel, 28 to 32% chromium, 7 to 9% aluminum, 1 to 2% silicon, 0.3 to 1% of at least one reactive element of the rare earths, at least 5% cobalt; and impurities, as well as selectively from 0 to 15% of at least one of the elements of the group consisting of rhenium, platinum, palladium, zirconium, manganese, tungsten, titanium, molybdenum, niobium, iron, hafnium, and tantalum. The total share of the elements of the group is from 0 to a maximum of 15% and a remainder of at least 5% cobalt. The component and the coating applied thereon have a ductile brittle transition temperature below 500.degree. C.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: December 10, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5543109
    Abstract: A high Cr austenitic heat resistant alloy excellent in high temperature strength which essentially consists of, in weight percent, from more than 0.02% to 0.10% C, not more than 1.0% Si, not more than 2.0% Mn, 28 to 38% Cr, 35 to 60% Ni, from more than 0.5% to 1.5% Ti, not more than 0.05% N, 0.01 to 0.3% Al, 0.001 to 0.01% B, 0 to 0.1% Zr, 0 to 1.0% Nb, one or both of 0.5 to 3.0% Mo and 1.0 to 6.0% W, and the balance being Fe and incidental impurities. The alloy may further contain one or both of 0.001 to 0.05% Mg and 0.001 to 0.05% Ca. This alloy is suitable for producing a single layered tube which is less expensive and more reliable than the conventional double layered tube.
    Type: Grant
    Filed: January 31, 1995
    Date of Patent: August 6, 1996
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Hiroyuki Senba, Yoshiatsu Sawaragi