Aluminum Containing Patents (Class 420/460)
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Patent number: 9169540Abstract: The present invention provides an Ni-based intermetallic compound alloy having excellent hardness. The present invention provides an Ni-based dual multi-phase intermetallic compound alloy comprising Ni as a main component, and 5 to 12 atomic % of Al, 11 to 17 atomic % of V and 1 to 5 atomic % of Re, and having a dual multi-phase microstructure including a primary precipitate L12 phase and a (L12+D022) eutectoid microstructure.Type: GrantFiled: July 20, 2011Date of Patent: October 27, 2015Assignee: OSAKA PREFECTURE UNIVERSITY PUBLIC CORPORATIONInventors: Takayuki Takasugi, Yasuyuki Kaneno
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Patent number: 8999231Abstract: A nickel base repair alloy comprises a blend of about 40 to 60 wt % of a first nickel based braze alloy containing boron, about 15 to 35 wt % of a first nickel based filler material, and the remainder consisting of a blend of a second nickel based filler material and a low melting eutectic braze nickel based alloy.Type: GrantFiled: May 24, 2006Date of Patent: April 7, 2015Assignee: United Technologies CorporationInventors: Beth Kwiatkowski Abriles, Norman Pietruska, John H. Hyde
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Publication number: 20140326849Abstract: A mechanical structure is provided with a crystalline superelastic alloy that is characterized by an average grain size and that exhibits a martensitic phase transformation resulting from a mechanical stress input greater than a characteristic first critical stress. A configuration of the superelastic alloy is provided with a geometric structural feature of the alloy that has an extent that is no greater than about 200 micrometers and that is no larger than the average grain size of the alloy. This geometric feature undergoes the martensitic transformation without intergranular fracture of the geometric feature.Type: ApplicationFiled: September 13, 2012Publication date: November 6, 2014Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGYInventors: Christopher A. Schuh, Jose M. San Juan, Ying Chen
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Patent number: 8858873Abstract: A nickel-based super alloy includes, by weight, about 1.5% to about 5.5% chromium, about 8% to about 12% aluminum, about 4% to about 8% tantalum, about 1.5% to about 5.5% tungsten, less than about 1% of one or more of elements selected from a group consisting of carbon, boron, zirconium, yttrium, hafnium, and silicon, and a balance of nickel.Type: GrantFiled: November 13, 2012Date of Patent: October 14, 2014Assignee: Honeywell International Inc.Inventor: Don Mittendorf
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Patent number: 8771398Abstract: An alloy composition includes a blend of a first alloy and a second, different alloy. The blend has a combined composition including about 17.2 wt %-24.25 wt % of chromium, about 6 wt %-10.51 wt % of aluminum, about 3 wt %-23 wt % of cobalt, about 1.5 wt %-3.6 wt % of silicon, about 0.1 wt %-0.175 wt % of boron, up to about 0.163 wt % of hafnium, about 0.075 wt %-0.7 wt % of yttrium, and a balance of nickel.Type: GrantFiled: August 21, 2012Date of Patent: July 8, 2014Assignee: United Technologies CorporationInventor: Michael Minor
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Publication number: 20140154094Abstract: Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers.Type: ApplicationFiled: December 13, 2013Publication date: June 5, 2014Applicant: General Electric CopmpanyInventors: Richard DiDomizio, Judson Sloan Marte, Pazhayannur Ramanathan Subramanian
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Patent number: 8696833Abstract: An intermetallic compound having excellent mechanical properties at high temperatures is provided. An intermetallic compound of the present invention contains greater than 5 at % and not greater than 13 at % of Al, not less than 9.5 at % and less than 17.5 at % of V, not less than 0 at % and not greater than 3.5 at % of Ti, not less than 0 weight ppm and not greater than 1000 weight ppm of B, and the remaining portion consisting of Ni and inevitable impurities, and having a dual multi-phase microstructure comprising a primary L12 phase and an (L12+D022) eutectoid microstructure.Type: GrantFiled: March 24, 2006Date of Patent: April 15, 2014Assignee: Osaka Prefecture University Public CorporationInventors: Takayuki Takasugi, Yasuyuki Kaneno
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Patent number: 8652650Abstract: Platinum-modified nickel-based superalloys and turbine engine components are provided. The platinum-modified nickel-based superalloy includes, by weight, aluminum, in a range of about 7.8 percent to about 8.2 percent, tantalum, in a range of about 5.0 percent to about 6.0 percent, rhenium, in a range of about 1.6 percent to about 2.0 percent, platinum, in a range of about 0.8 percent to about 1.4 percent, hafnium, in a range of about 0.20 percent to about 0.40 percent, silicon, in a range of about 0.30 percent to about 0.60 percent, about 0.02 percent carbon, about 0.01 percent boron, and a balance of nickel. The platinum-modified a nickel-based superalloy may also include, by weight, chromium in a range of about 4.0 percent to about 5.0 percent.Type: GrantFiled: October 22, 2009Date of Patent: February 18, 2014Assignee: Honeywell International Inc.Inventor: Yiping Hu
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Patent number: 8608877Abstract: Articles that include a material that has L12-structured gamma-prime phase precipitates within a matrix phase at a concentration of at least 20% by volume are disclosed. The gamma-prime phase precipitates are less than 1 micrometer in size. The material also has A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The articles may be formed by mechanically working a workpiece that has at least about 40% nickel, about 1.5% to about 8% titanium, and about 1.5% to about 4.5% aluminum. The workpiece may be worked at a temperature below a solvus temperature of the eta phase; and then heat treated at a temperature sufficient to dissolve any gamma prime phase present in the workpiece but below the solvus temperature of the eta phase.Type: GrantFiled: July 27, 2010Date of Patent: December 17, 2013Assignee: General Electric CompanyInventors: Richard DiDomizio, Judson Sloan Marte, Pazhayannur Ramanathan Subramanian
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Publication number: 20130319580Abstract: Ni base superalloy components containing relatively large amounts of Al and Ti are known to be difficult to build up by a weld build up process without cracking. As the Al and Ti content of the superalloy is increased to improve the strength, the susceptibility to cracking is increased. It is shown herein that reducing the ?? phase in the additive built up material improves robustness against cracking. A stepwise, controlled heating and cooling process is described to be used in cooperation with an additive build up process to reduce the ?? present and thereby reduce cracking.Type: ApplicationFiled: May 10, 2013Publication date: December 5, 2013Inventor: KAZIM OZBAYSAL
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Publication number: 20130272917Abstract: A metallic bondcoat with phases of ? and ?? is provided. The metallic coating or alloy is nickel based. The metallic coating or alloy has ? and ?? phases and optionally has ?-phase. The new addition in nickel based coating stabilizes the phases ? and ?? at high temperatures leading to a reduction of local stresses.Type: ApplicationFiled: November 7, 2011Publication date: October 17, 2013Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Anand A. Kulkarni, Jonathan E. Shipper, JR., Werner Stamm
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Publication number: 20130243642Abstract: A metallic coating or alloy is provided, which is nickel based, and includes at least ? and ?? phases. The metallic coating or the alloy further includes tantalum (Ta) in the range of between 4 wt % to 7.5 wt %. The metallic coating or the alloy also includes cobalt (Co) in the range between 11 wt %-14.5 wt %.Type: ApplicationFiled: November 7, 2011Publication date: September 19, 2013Inventors: Anand A. Kulkarni, Jonathan E. Shipper, JR., Werner Stamm
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Publication number: 20130189149Abstract: The present invention provides an Ni-based intermetallic compound alloy having excellent hardness. The present invention provides an Ni-based dual multi-phase intermetallic compound alloy comprising Ni as a main component, and 5 to 12 atomic % of Al, 11 to 17 atomic % of V and 1 to 5 atomic % of Re, and having a dual multi-phase microstructure including a primary precipitate L12 phase and a (L12+D022) eutectoid microstructure.Type: ApplicationFiled: July 20, 2011Publication date: July 25, 2013Applicant: OSAKA PREFECTURE UNIVERSITY PUBLIC CORPORATIONInventors: Takayuki Takasugi, Yasuyuki Kaneno
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Patent number: 8491837Abstract: A Ni-based brazing composition at least containing, in mass %, 1.0% or more and 1.3% or less of B, 4.0% or more and 6.0% or less of Si, and the balance consisting of Ni and unavoidable impurities, wherein the brazing composition forms wherein the brazing composition forms dispersed phase containing B or Si in a metal texture after the brazing, and a maximum length of the dispersed phase is 30 ?m or less.Type: GrantFiled: September 2, 2008Date of Patent: July 23, 2013Assignee: IHI CorporationInventors: Naoki Oiwa, Sadao Nishikiori, Tsukasa Wakabayashi, Junji Tsuji
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Patent number: 8430981Abstract: Ni-Ti (nickel-titanium) based alloys. and related semi-finished products and methods are described, where the nickel content is comprised between 50.7 and 52.0 atomic % .Type: GrantFiled: July 30, 2012Date of Patent: April 30, 2013Assignee: Saes Smart MaterialsInventors: Francis E. Sczerzenie, Alberto Coda
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Patent number: 8426033Abstract: Provided are precipitation hardened high strength nickel based alloy welds that yield improved properties and performance in joining high strength metals. The advantageous weldments include two or more segments of ferrous or non-ferrous components, and fusion welds, friction stir welds, electron beam welds, laser beam welds, or a combination thereof bonding adjacent segments of the components together, wherein the welds comprise a precipitation hardened nickel based alloy weld metal composition including greater than or equal to 1.4 wt % of combined aluminum and titanium based on the total weight of the nickel based alloy weld metal composition. Also provided are methods for forming the welds from the nickel based alloy weld compositions, wherein the precipitation hardening occurs in the as-welded condition. The nickel based welds do not require a separate heat treatment step after welding to produce advantageous strength properties.Type: GrantFiled: December 16, 2008Date of Patent: April 23, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Raghavan Ayer, Neeraj Srinivas Thirumalai, Hyun-Woo Jin, Daniel B. Lillig, Douglas Paul Fairchild, Steven Jeffrey Ford
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Patent number: 8377374Abstract: A hydrogen-absorbing alloy, which is used as a negative electrode material of nickel-metal hydride secondary batteries for hybrid electric vehicles, and particularly for batteries to drive electric motors of hybrid electric vehicles, is an AB5-type alloy having a CaCu5-type crystal structure and the general formula RNiaCobAlcMnd (R: mixture of rare earth metals), wherein 4.15?a?4.4, 0.15?b?0.35, 1?c/d?1.7, 5.25?a+b+c+d?5.45.Type: GrantFiled: June 7, 2007Date of Patent: February 19, 2013Assignee: Chuo Denki Kogyo Co., Ltd.Inventors: Yasushi Kojima, Hiroyuki Ikeda, Satoru Furukawa, Kazutaka Sugiyama, Nobuo Kobayashi
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Patent number: 8334056Abstract: An alloy including: about 10 at % to about 30 at % of a Pt-group metal; less than about 23 at % Al; about 0.5 at % to about 2 at % of at least one reactive element selected from Hf, Y, La, Ce and Zr, and combinations thereof; a superalloy substrate constituent selected from the group consisting of Cr, Co, Mo, Ta, Re and combinations thereof; and Ni; wherein the Pt-group metal, Al, the reactive element and the superalloy substrate constituent are present in the alloy in a concentration to the extent that the alloy has a solely ??-Ni3Al phase constitution.Type: GrantFiled: September 2, 2011Date of Patent: December 18, 2012Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian M. Gleeson, Daniel J. Sordelet, Wen Wang
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Publication number: 20120189486Abstract: Semi-finished products for the production of devices containing thermoelastic materials with improved reliability and reproducibility are described. The semi-finished products are based on an alloy of Ni—Ti plus elements X and/or Y. The nickel amount is comprised between 40 and 52 atom %, X is comprised between 0.1 and 1 atom %, Y is comprised between 1 and 10 atom % and the balance is titanium. The one or more additional elements X are chosen from Al, Ta, Hf, Si, Ca, Ce, La, Re, Nb, V, W, Y, Zr, Mo, and B. The one or more additional elements Y are chosen from Al, Ag, Au, Co, Cr, Fe, Mn, Mo, Nb, Pd, Pt, Ta and W.Type: ApplicationFiled: March 30, 2012Publication date: July 26, 2012Applicant: SAES SMART MATERIALSInventors: Francis E. SCZERZENIE, Graeme William PAUL
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Publication number: 20120128525Abstract: A nickel-based coating or alloy is provided. The coating includes tantalum preferably without rhenium. The coating or alloy has stabilized the formation of phases ?/?? at high temperatures leading to a reduction of local stresses. A component is also provided. The substrate of the component includes a nickel-based or cobalt-based superalloy.Type: ApplicationFiled: November 24, 2010Publication date: May 24, 2012Inventors: Anand A. Kulkarni, Jonathan E. Shipper, Werner Stamm
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Patent number: 8147749Abstract: A composition of matter comprises, in combination, in weight percent: a largest content of nickel; at least 16.0 percent cobalt; and at least 3.0 percent tantalum. The composition may be used in power metallurgical processes to form turbine engine turbine disks.Type: GrantFiled: November 23, 2009Date of Patent: April 3, 2012Assignee: United Technologies CorporationInventor: Paul L. Reynolds
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Publication number: 20110277568Abstract: Semi-finished products for the production of devices containing thermoelastic materials with improved reliability and reproducibility are described. The semi-finished products are based on an alloy of Ni—Ti plus elements X and/or Y. The nickel amount is comprised between 40 and 52 atom %, X is comprised between 0.1 and 1 atom %, Y is comprised between 1 and 10 atom % and the balance is titanium. The one or more additional elements X are chosen from Al, Ta, Hf, Si, Ca, Ce, La, Re, Nb, V, W, Y, Zr, Mo, and B. The one or more additional elements Y are chosen from Al, Ag, Au, Co, Cr, Fe, Mn, Mo, Nb, Pd, Pt, Ta and W.Type: ApplicationFiled: October 28, 2010Publication date: November 17, 2011Applicant: SAES SMART MATERIALSInventors: Francis E. Sczerzenie, Graeme William Paul
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Publication number: 20110154947Abstract: A brazing composition for the brazing of superalloys including a base material with at least one initial phase is provided. The initial phase has a solidus temperature that is below the solidus temperature of the base material and, above a certain temperature, forms with the base material and/or with at least one further initial phase at least one resultant phase, the solidus temperature of which is higher that the solidus temperature of the initial phases. Heat treatment takes place in two stages, wherein the temperature of the second heat treatment is preferably 800-1200° C. The brazing composition may likewise be of the type MCrAlX, and the power particles of the initial phase may be in the form of nanoparticles.Type: ApplicationFiled: March 9, 2011Publication date: June 30, 2011Inventors: Brigitte Heinecke, Volker Vosberg
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Publication number: 20110097599Abstract: Platinum-modified nickel-based superalloys and turbine engine components are provided. The platinum-modified nickel-based superalloy includes, by weight, aluminum, in a range of about 7.8 percent to about 8.2 percent, tantalum, in a range of about 5.0 percent to about 6.0 percent, rhenium, in a range of about 1.6 percent to about 2.0 percent, platinum, in a range of about 0.8 percent to about 1.4 percent, hafnium, in a range of about 0.20 percent to about 0.40 percent, silicon, in a range of about 0.30 percent to about 0.60 percent, about 0.02 percent carbon, about 0.01 percent boron, and a balance of nickel. The platinum-modified a nickel-based superalloy may also include, by weight, chromium in a range of about 4.0 percent to about 5.0 percent.Type: ApplicationFiled: October 22, 2009Publication date: April 28, 2011Applicant: HONEYWELL INTERNATIONAL INC.Inventor: Yiping Hu
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Patent number: 7824606Abstract: The invention provides nickel-based alloys that are useful in the preparation of articles for applications requiring high mechanical and physical properties, such as high strength and high heat stability, while simultaneously reducing the cost of preparation of the alloys. The invention further provides articles, such as turbine wheels, prepared using the inventive alloys.Type: GrantFiled: September 21, 2006Date of Patent: November 2, 2010Assignee: Honeywell International Inc.Inventor: Mark Heazle
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Publication number: 20100158695Abstract: A composition of matter comprises, in combination, in weight percent: a largest content of nickel; at least 16.0 percent cobalt; and at least 3.0 percent tantalum. The composition may be used in power metallurgical processes to form turbine engine turbine disks.Type: ApplicationFiled: November 23, 2009Publication date: June 24, 2010Applicant: UNITED TECHNOLOGIES CORPORATIONInventor: Paul L. Reynolds
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Patent number: 7740719Abstract: A cutter is composed of a Ni—Cr alloy containing from 32 to 44 mass percent of Cr, from 2.3 to 6.0 mass percent of Al, the balance being Ni, impurities, and additional trace elements and having a Rockwell C hardness of 52 or more. This Ni—Cr alloy provides a cutter produced with a superior workability and by a significantly simplified process, having a low deterioration in the hardness even when heated in use, having excellent corrosion resistance and low-temperature embrittlement resistance, and satisfactorily maintaining the cutting performance for a long time.Type: GrantFiled: May 14, 2003Date of Patent: June 22, 2010Assignee: Kabushiki Kaisha ToshibaInventors: Tomohisa Arai, Takashi Rokutanda, Tadaharu Kido
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Publication number: 20100140439Abstract: A mechanical structure is provided with a crystalline superelastic alloy that is characterized by an average grain size and that is characterized by a martensitic phase transformation resulting from a mechanical stress input greater than a characteristic first critical stress. A configuration of the superelastic alloy is provided with a geometric structural feature of the alloy that has an extent that is no greater than about 200 micrometers and that is no larger than the average grain size of the alloy. This geometric feature is configured to accept a mechanical stress input.Type: ApplicationFiled: July 8, 2009Publication date: June 10, 2010Applicant: Massachusetts Institute of TechnologyInventors: Christopher A. Schuh, Jose M. San Juan, Ying Chen
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Patent number: 7662740Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.Type: GrantFiled: June 3, 2004Date of Patent: February 16, 2010Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
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Patent number: 7659224Abstract: Although nanoparticles capable of providing an extremely large active surface area have highly marked advantages, when a PEFC electrode utilizing nanoparticles is used for a prolonged period of time, the catalyst nanoparticles on carrier of the PEFC electrode because of the nano-size thereof migrate and aggregate together to result in a rapid loss of activity. Thus, there is a demand for inhibition of the above aggregation so as to prevent any drop of catalytic activity. According to the present invention the aggregation of nanoparticles can be inhibited by catalyst nanoparticles containing Pt wherein a porous matter containing an inorganic oxide is disposed on the surface of the catalyst nanoparticles. When use is made of nanoparticles whose surface has undergone specific modification, excellent activity can be realized. Therefore, there are provided surface-modified nanoparticles and catalyst and further a PEFC electrode utilizing these nanoparticles.Type: GrantFiled: September 13, 2006Date of Patent: February 9, 2010Assignee: Hitachi, Ltd.Inventors: Yuzuru Shimazaki, Yoshio Kobayashi, Mikio Konno
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Publication number: 20100008790Abstract: A composition of matter comprises, in combination, in weight percent: a largest content of nickel; at least 16.0 percent cobalt; and at least 3.0 percent tantalum. The composition may be used in power metallurgical processes to form turbine engine turbine disks.Type: ApplicationFiled: March 30, 2005Publication date: January 14, 2010Inventor: Paul L. Reynolds
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Patent number: 7645348Abstract: In accordance with the present invention, a process for repairing metal workpieces, such as turbine engine components, is provided. The process comprises the steps of forming a braze paste containing a first nickel base alloy material containing boron and chromium and a second nickel base alloy material containing chromium and cobalt, applying the brazing paste to an area of the metal workpiece containing at least one crack, and subjecting the workpiece and the brazing paste to a brazing cycle by heating the brazing paste and the workpiece, preferably to a temperature in the range of from 2000 to 2200 degrees Fahrenheit. During the brazing cycle, the brazing paste flows into and fills the at least one crack and thus repairs the metal workpiece.Type: GrantFiled: May 12, 2008Date of Patent: January 12, 2010Assignee: United Technologies CorporationInventor: Monika D. Kinstler
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Patent number: 7622012Abstract: A flat soft magnetic metal powder is provided that includes: Ni in the range of 60 to 90 mass %, one or more kinds of Nb, V, and Ta in the range of 0.05 to 20 mass % in total (0.05 to 19.95 mass % when Mo is added thereto), Mo in the range of 0.05 to 10 mass % if necessary, one or two kinds of Al and Mn in the range of 0.01 to 1 mass % in total if necessary, and the balance including Fe; an average grain size of 30 to 150 ?m and an aspect ratio (average grain size/average thickness) of 5 to 500; and a flat face. Here, with a peak intensity of a face index (220) in an X-ray diffraction pattern I220 and a peak intensity of a face index (111) I111, a peak intensity ratio I220/I111 is in the range of 0.1 to 10.Type: GrantFiled: February 9, 2006Date of Patent: November 24, 2009Assignee: Mitsubishi Materials CorporationInventors: Gakuji Uozumi, Ryoji Nakayama, Yasushi Nayuki
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Patent number: 7597843Abstract: Nickel based superalloys with excellent mechanical strength, corrosion resistance and oxidation resistance, which consist essentially of chromium in an amount of 3 to 7% by weight, cobalt in an amount of 3 to 15% by weight, tungsten in an amount of 4.5 to 8% by weight, rhenium in an amount of 3.3 to 6% by weight, tantalum in an amount of 4 to 8% by weight, titanium in an amount of 0.8 to 2% by weight, aluminum in an amount of 4.5 to 6.5% by weight, ruthenium in an amount of 0.1 to 6%, hafnium in an amount of 0.01 to 0.2% by weight, molybdenum in an amount of less than 0.5% by weight, carbon in an amount 0.06% by weight or less, boron in an amount of 0.01% by weight or less, zirconium in an amount of 0.01% by weight or less, oxygen in an amount of 0.005% by weight or less, nitrogen in an amount of 0.005% by weight or less and inevitable impurities and the balance being nickel.Type: GrantFiled: August 29, 2005Date of Patent: October 6, 2009Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc.Inventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
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Patent number: 7514178Abstract: An alkaline storage battery including a positive electrode (1), a negative electrode (2) using a hydrogen-absorbing alloy, and an alkaline electrolyte solution employs, as the hydrogen-absorbing alloy in the negative electrode, a hydrogen-absorbing alloy for alkaline storage batteries including at least a rare-earth element, magnesium, nickel, and aluminum, and having an intensity ratio IA/IB of 1.00 or greater, wherein IA is the strongest peak intensity appearing in the range 2?=32°-33° and IB is the strongest peak intensity appearing in the range 2?=35°-36° in an X-ray diffraction analysis using Cu- K? radiation as the X-ray source.Type: GrantFiled: January 25, 2005Date of Patent: April 7, 2009Assignee: SANYO Electric Co., Ltd.Inventors: Shigekazu Yasuoka, Tetsuyuki Murata, Jun Ishida
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Publication number: 20080308057Abstract: An electrode for an ignition device is made from a dilute nickel alloy which has improved resistance to high temperature oxidation, sulfidation, corrosive wear, deformation and fracture and includes at least 90% by weight of nickel; zirconium; boron and at least one element from the group consisting of aluminum, magnesium, silicon, chromium, titanium and manganese. The weight ratio of Zr/B may range from about 0.5 to 150, and may include amounts of, by weight of the alloy, 0.05-0.5% zirconium and 0.001-0.01% boron. The oxidation resistance of the alloy may also be improved by the addition of hafnium to the alloy in an amount that is comparable to the amount of zirconium, which may include an amount of, by weight of the alloy, 0.005-0.2% hafnium. Electrodes of dilute nickel alloys which include aluminum and silicon, as well as those which include chromium, silicon, manganese and titanium, are particularly useful as spark plug electrodes.Type: ApplicationFiled: June 18, 2007Publication date: December 18, 2008Inventors: James D. Lykowski, Iryna Levina
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Publication number: 20080175745Abstract: An intermetallic compound having excellent mechanical properties at high temperatures is provided. An intermetallic compound of the present invention contains greater than 5 at % and not greater than 13 at % of Al, not less than 9.5 at % and less than 17.5 at % of V, not less than 0 at % and not greater than 3.5 at % of Ti, not less than 0 weight ppm and not greater than 1000 weight ppm of B, and the remaining portion consisting of Ni and inevitable impurities, and having a dual multi-phase microstructure comprising a primary L12 phase and an (L12+D022) eutectoid microstructure.Type: ApplicationFiled: March 24, 2006Publication date: July 24, 2008Inventors: Takayuki Takasugi, Yasuyuki Kaneno
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Patent number: 7393499Abstract: The invention relates to a Ni alloy anode material for Ni electroplating, which exhibits high plating yield. The Ni alloy anode material comprises a Ni alloy consisting essentially of high-purity Ni having purity of 99.99 mass % or higher and, as an alloy component, Si and Al in the following contents: Si: 30 to 300 ppm, and Al: 30 to 300 ppm.Type: GrantFiled: February 21, 2003Date of Patent: July 1, 2008Assignee: Mitsubishi Materials CorporationInventor: Katsuo Sugahara
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Patent number: 7361302Abstract: The present invention relates to a metallic coating to be deposited on gas turbine engine components. The metallic coating comprises up to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.1 to 1.0 wt % yttrium, up to 0.6 wt % hafnium, up to 0.3 wt % silicon, 3.0 to 10 wt % tantalum, up to 9.0 wt % tungsten, 1.0 to 6.0 wt % rhenium, up to 10 wt % molybdenum, and the balance nickel.Type: GrantFiled: September 13, 2004Date of Patent: April 22, 2008Assignee: United Technologies CorporationInventors: Russell Albert Beers, Allan A. Noetzel, Abdus Khan
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Publication number: 20080091267Abstract: Medical devices, such as endoprostheses, and methods of making the devices are disclosed. The endoprostheses comprise a tubular member capable of maintaining patency of a bodily vessel. The tubular member includes a mixture of at least two compositions, where the presence of the second composition gives the mixture a greater hardness than that of the first composition alone. The first composition includes less than about 25 weight percent chromium, less than about 7 weight percent molybdenum, from about 10 to about 35 weight percent nickel, and iron. The second composition is different from the first and is present from about 0.1 weight percent to about 5 weight percent of the mixture.Type: ApplicationFiled: March 29, 2007Publication date: April 17, 2008Inventors: Jonathan S. Stinson, Matthew Cambronne, Richard B. Frank, Richard A. Gleixner, James E. Heilmann
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Patent number: 7316850Abstract: There is provided a method for depositing a modified MCrAlY coating on a turbine blade tip. The method utilizes laser deposition techniques to provide a metallurgical bond between a turbine blade substrate, such as a superalloy substrate, and the modified MCrAlY composition. Further the modified MCrAlY coating has sufficient thickness such that a post-welding grinding operation to size the turbine blade to a desired dimension will not remove the modified MCrAlY coating entirely. The modified MCrAlY coating thus remains on the finished turbine blade tip after grinding.Type: GrantFiled: March 2, 2004Date of Patent: January 8, 2008Assignee: Honeywell International Inc.Inventors: Yiping Hu, William F. Hehmann
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Patent number: 7273662Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution, and a coating including the alloy.Type: GrantFiled: May 16, 2003Date of Patent: September 25, 2007Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
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Publication number: 20070184346Abstract: A hydrogen-absorbing alloy for alkaline storage battery which is produced by a rapid cool using a rapid quenching method and whose component is represented by a general formula Ln1-xMgxNia-b-cAlbZc is used for a negative electrode of an alkaline storage battery.Type: ApplicationFiled: February 7, 2007Publication date: August 9, 2007Applicant: SANYO ELECTRIC CO., LTD.Inventors: Yoshifumi Magari, Jun Ishida, Shigekazu Yasuoka
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Patent number: 7169478Abstract: Multinary alloys, in particular for use as coatings, if appropriate in combination with other types of layers, for components which are exposed to high temperatures and corrosive gases. The alloys are of the general form: Al—Ni—Ru-M, where at least one B2 phase is present, the aluminum content being in the range from 26–60 atomic percent and where M may be one or more metals and/or semimetals selected from the group consisting of: precious metal, transition metal, rare earths, semimetal. Multinary alloys of this type are very stable with respect to oxidation, have a low thermal conductivity and in particular have similar coefficients of thermal expansion to superalloys, which are usually used as substrates for protective coatings of this type in gas turbine components.Type: GrantFiled: July 16, 2004Date of Patent: January 30, 2007Assignee: Alstom Technology Ltd.Inventors: Anton Kaiser, Valery Shklover, Walter Steurer, Ivan Victor Vjunitsky
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Patent number: 7052782Abstract: A high-temperature protection layer contains (% by weight) 23 to 27% Cr, 4 to 7% Al, 0.1 to 3% Si, 0.1 to 3% Ta, 0.2 to 2% Y, 0.001 to 0.01% B, 0.001 to 0.01% Mg and 0.001 to 0.01% Ca, remainder Ni and inevitable impurities. Optionally, the Al content is in a range from over 5 up to 6% by weight.Type: GrantFiled: July 19, 2004Date of Patent: May 30, 2006Assignee: ALSTOM Technology Ltd.Inventors: Hans-Peter Bossmann, Dietrich Eckardt, Klaus Erich Schneider, Christoph Toennes
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Patent number: 6902633Abstract: A nickel-base alloy consists of, by weight, about 15.0 to about 17.0% chromium, about 7.0 to about 10.0% cobalt, about 1.0 to about 2.5% molybdenum, about 2.0 to about 3.2% tungsten, about 0.6 to about 2.5% columbium, less than 1.5% tantalum, about 3.0 to about 3.9% aluminum, about 3.0 to about 3.9% titanium, about 0.005 to about 0.060% zirconium, about 0.005 to about 0.030% boron, about 0.07 to about 0.15% carbon, the balance nickel and impurities. Preferably, columbium is present in an amount greater than tantalum. Tantalum can be essentially absent from the alloy, i.e., only at impurity levels.Type: GrantFiled: May 9, 2003Date of Patent: June 7, 2005Assignee: General Electric CompanyInventors: Warren Tan King, John Herbert Wood, Gangjigang Feng
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Publication number: 20040221684Abstract: In a method for manufacturing Ni—Al alloy powders for electrode materials of fuel cells, in which, using aluminum chloride (AlCl3) as a catalyst, powders of Ni and Al, that have been used as electrode materials, are chemically reacted with each other to diffuse the Al into the Ni powders, so that Ni—Al alloy powders can be manufactured at a low temperature below fusion points of Ni and Al while maintaining a shape and a size of the existing Ni powders as they are, thus providing a manufacturing process of Ni—Al alloy powders that is simple, economical, compatible in working, and ready for scale-up, and in which a conventional manufacturing process of electrode based on Ni is used as it is, so that large sized electrode is manufactured.Type: ApplicationFiled: October 29, 2003Publication date: November 11, 2004Applicant: Korea Institute of Science and TechnologyInventors: Suk Woo Nam, Anatoli Maganiouk, Seong-Ahn Hong, In-Hwan Oh, Tae Hoon Lim, Heung Yong Ha, Sung Pil Yoon, Jonghee Han, Eun Ae Cho
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Patent number: 6808570Abstract: A fin and a tube for a high-temperature heat exchanger are made of a nickel-based alloy which contains 2.0 to 5.0% of Al and further contains, as required, at least one selected from the group consisting of 0.1 to 2.5% of Si, 0.8 to 4.0% of Cr, and 0.1 to 1.5% of Mn, the balance being Ni and unavoidable impurities.Type: GrantFiled: March 7, 2003Date of Patent: October 26, 2004Assignee: Mitsubishi Materials CorporationInventor: Akira Mitsuhashi
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Patent number: 6756131Abstract: A high temperature corrosion resistant alloy composition comprising, in addition to Ni, 0.1 to 12% by weight of Co, 10 to 30% by weight of Cr, 4 to 15% by weight of Al, 0.1 to 5% by weight of Y, and 0.5 to 10% by weight of Re. The high temperature corrosion resistant alloy composition has an excellent oxidation resistance and ductility and is suitable for use in a bonding layer of a thermal barrier coating material.Type: GrantFiled: December 11, 2002Date of Patent: June 29, 2004Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hidetaka Oguma, Ikuo Okada, Taiji Torigoe, Kouji Takahashi
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Patent number: 6740292Abstract: The invention relates to a nickel-base superalloy. The alloy according to the invention is characterized by the following chemical composition (details in % by weight): 7.7-8.3 Cr, 5.0-5.25 Co, 2.0-2.1 Mo, 7.8-8.3 W, 5.8-6.1 Ta, 4.9-5.1 Al, 1.3-1.4 Ti, 0.11-0.15 Si, 0.11-0.15 Hf, 200-750, preferably 200-300 ppm of C, 50-400, preferably 50-100 ppm of B, remainder Ni and production-related impurities. It is distinguished by very good castability and a high resistance to oxidation.Type: GrantFiled: March 28, 2003Date of Patent: May 25, 2004Assignee: Alstom Technology LtdInventors: Douglas Arrell, Mohamed Nazmy