Aluminum Containing Patents (Class 420/460)
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Patent number: 6720088Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.Type: GrantFiled: February 5, 2002Date of Patent: April 13, 2004Assignee: General Electric CompanyInventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
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Patent number: 6652991Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.Type: GrantFiled: October 9, 2002Date of Patent: November 25, 2003Assignee: The Governors of the University of AlbertaInventors: You Wang, Weixing Chen
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Patent number: 6635362Abstract: Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.Type: GrantFiled: June 4, 2001Date of Patent: October 21, 2003Inventor: Xiaoci Maggie Zheng
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Publication number: 20030170139Abstract: A fin and a tube for a high-temperature heat exchanger are made of a nickel-based alloy which contains 2.0 to 5.0% of Al and further contains, as required, at least one selected from the group consisting of 0.1 to 2.5% of Si, 0.8 to 4.0% of Cr, and 0.1 to 1.5% of Mn, the balance being Ni and unavoidable impurities.Type: ApplicationFiled: March 7, 2003Publication date: September 11, 2003Applicant: MITSUBISHI MATERIALS CORPORATIONInventor: Akira Mitsuhashi
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Patent number: 6475642Abstract: An oxidation-resistant coating is described, formed of an alloy containing: about 40 to about 50 atom % aluminum and about 0.5 atom % to about 3 atom % tantalum; with a balance of nickel; cobalt, iron, or combinations thereof. The coating may also include chromium and a precious metal, as well as other components, such as zirconium or molybdenum. A method for applying the oxidation-resistant coating to a substrate is also described. The substrate can be formed of superalloy material, e.g., a turbine engine component. Related articles are also disclosed.Type: GrantFiled: August 31, 2000Date of Patent: November 5, 2002Assignee: General Electric CompanyInventors: Ji-Cheng Zhao, Melvin Robert Jackson, Ramgopal Darolia
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Patent number: 6471791Abstract: The invention relates to a coating which contains large volumetric fractions, preferably from 20 to 90% by volume, of NiAl-&bgr; phase in a &ggr; matrix. It contains the following microalloying elements which increase the ductility of the coating (data in % by weight): 0.1-8 Fe and/or 0.1-8 Mo and/or 0.1-8 Ga, where the total Fe, Mo and Ga content is at most 10%. In addition, small amounts of Zr, C and/or B may be added to the alloy, strengthening the &bgr;/&ggr; phase boundaries.Type: GrantFiled: May 18, 2000Date of Patent: October 29, 2002Assignee: Alstom (Switzerland) LtdInventors: Mohamed Nazmy, Hans Joachim Schmutzler
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Patent number: 6410153Abstract: A nickel based single crystal superalloy comprising 6-11 wt % cobalt, 4.7-5.7 wt % chromium, 2.4-3.0 wt % molybdenum, 3.0-3.8 wt % tungsten, 3.0-3.8 wt % rhenium, 5.5-7.0 wt % aluminium, 5.0-6.0 wt % tantalum, 0.5-1.0 wt % niobium, 0-0.2 wt % hafnium, 0-150 ppm carbon, 0-100 ppm yttrium, 0-100 ppm lanthanum, 0-5 ppm sulphur and the balance nickel plus incidental impurities. The nickel based single crystal superalloy is suitable for use as a gas turbine engine turbine blade or turbine vane. It is of particular use on cooled turbine blades and turbine vanes which have ceramic thermal barrier coatings, because the superalloy is compatible with the ceramic thermal barrier coating to minimize spalling. The superalloy has lower density than other second generation single crystal superalloys but similar creep strength and oxidation resistance.Type: GrantFiled: February 14, 2000Date of Patent: June 25, 2002Assignee: Rolls-Royce plcInventors: Robert W Broomfield, Colin N Jones
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Patent number: 6355212Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.Type: GrantFiled: January 5, 2000Date of Patent: March 12, 2002Assignee: Turbocoating SpAInventor: Nelso Antolotti
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Patent number: 6280857Abstract: A coating composition for superalloy structural parts, especially, for gas turbine vanes and blades, which has high resistance to oxidation and corrosion and has excellent mechanical behavior. The coating preferably comprises: 18 to 28 wt % of Co; 11 to 15 wt % of Cr; 11.5 to 14 wt % of Al; 1 to 8 wt % of Re; 1 to 2.3 wt % of Si; 0.2 to 1.5 wt % of Ta; 0.2 to 1.5 wt % of Nb; 0.3 to 1.3 wt % of Y; 0 to 1.5 wt % of Mg; 0 to 0.5 wt % of a total of La and La-series; 0 to 0.1 wt % of B; less than 0.1 wt % of Hf; and less than 0.1 wt % of C. The balance of the coating is Ni. A total of Y, La, and La-series is from 0.3 to 2.0 wt %, and a total of Si and Ta is equal to or less than 2.5 wt %.Type: GrantFiled: June 30, 1999Date of Patent: August 28, 2001Assignee: AlstomInventors: Marianne Sommer, Hans-Peter Bossmann, Maxim Konter, Peter Holmes, Christoph Toennes, Hans Joachim Schmutzler
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Patent number: 6242113Abstract: A nickel, chromium, iron alloy for use in producing weld deposits. The alloy comprises, in weight percent, about 27 to 31.5 chromium; about 7 to 11 iron; about 0.005 to 0.05 carbon; less than about 1.0 manganese, preferably 0.30 to 0.95 manganese; about 0.60 to 0.95 niobium; less than 0.50 silicon, preferably 0.10 to 0.30 silicon; 0.01 to 0.35 titanium; 0.01 to 0.25 aluminum; less than 0.20 copper; less than 1.0 tungsten; less than 1.0 molybdenum; less than 0.12 cobalt; less than 0.10 tantalum; less than about 0.10 zirconium, preferably 0.002 to 0.10 zirconium; less than about 0.01 sulfur; less than about 0.01 boron, preferably 0.001 to 0.01 boron; less than about 0.02 phosphorous; and balance nickel and incidental impurities.Type: GrantFiled: June 10, 1999Date of Patent: June 5, 2001Assignee: Inco Alloys International, Inc.Inventor: Samuel D. Kiser
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Patent number: 6238620Abstract: A novel Ni3Al-based alloy exhibits strengths and hardness in excess of the standard base alloy IC-221M at temperatures of up to about 1000° C. The alloy is useful in tool and die applications requiring such temperatures, and for structural elements in engineering systems exposed to such temperatures.Type: GrantFiled: September 15, 1999Date of Patent: May 29, 2001Assignee: U.T.Battelle, LLCInventors: Chain T. Liu, Everett E. Bloom
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Patent number: 6096141Abstract: Carbide-forming elements are added to nickel-based superalloys so as to minimize grain defects, such as freckle and stray grain defects. More specifically, carbide-forming elements that form from the liquid in the mushy zone of the solidification front of single crystal (SC) and directionally solidified (DS) nickel-based superalloys are added so as to reduce the formation of freckle and stray grain defects in such alloys. A preferred nickel-based superalloy includes, by weight, between about 6.00%-9.25% tantalum, 4.75%-6.50% tungsten, at least about 2.75% rhenium, between about 5.00% to about 7.00% aluminum, at least about 0.10% hafnium and carbon in an amount sufficient (typically between about 0.10-0.15% by weight) to form carbides with other constituents to reduce significantly freckle formation in the mushy zone of the superalloy during casting.Type: GrantFiled: August 3, 1998Date of Patent: August 1, 2000Assignee: General Electric Co.Inventors: Warren Tan King, Tresa M. Pollock, Christine Louise Zemsky, Wendy Howard Murphy
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Patent number: 6093262Abstract: A ferromagnetic, high strength, corrosion resistant material for use in electromagnetic equipment. The material comprises Cobalt or Nickel or a combination of these elements in an amount equal to or greater than 60% by weight, with the balance comprising one of a group consisting of Beryllium, Lithium, Aluminum, or Titanium. In different embodiments of the invention, 3% or less of the material comprises Beryllium, with the balance comprising Nickel or Cobalt. The material provides adequate yield strength for use downhole in wellbores, is highly resistant to corrosion induced by downhole well fluids and sea water, and has high ferromagnetic characteristics suitable for use in solenoid valves and other downhole well equipment.Type: GrantFiled: June 23, 1998Date of Patent: July 25, 2000Assignee: PES, Inc.Inventor: Brett Bouldin
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Patent number: 6083327Abstract: A Ni based hydrogen occluding alloy having the composition, comprising: by weight:(i) 32-38% of at least one of La or Ce,(ii) 0.1-17% Co,(iii) 0.1-3.5% Al,(iv) 0.5-10% Mn,(v) 0.005-0.1% of hydrogen, withthe balance being Ni and unavoidable impurities, wherein said alloy has a microstructure of a phase having a Ce.sub.2 Ni.sub.7 -type crystal structure and rare earth element hydride dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure and, wherein the amount of said phase having a Ce.sub.2 Ni.sub.7 -type crystal structure is 1-40% by area and the amount of said rare earth element hydride is 0.5-20% by area.Type: GrantFiled: June 16, 1999Date of Patent: July 4, 2000Assignee: Mitsubishi Materials CorporationInventors: Kouichi Kita, Katsuo Sugahara, Masahiro Wada, Takuya Murai, Takeshi Isobe
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Patent number: 6066291Abstract: Castings based on the nickel aluminide intermetallic alloy IC-221M were melted and poured with an addition of enough molybdenum to bring its concentration to 5 weight %. This resulted in a minimization or elimination of the nickel-zirconium eutectic phase in the dies machined and prepared from these castings. The benefit of eliminating or minimizing the nickel zirconium eutectic phase with the addition of measurable amounts of molybdenum (Mo) to the nickel aluminide (Ni.sub.3 Al) alloy is the increase in the useful service life of the tooling made from it; thus providing the advantages of increased productivity, enhanced quality and reduced costs in a manufacturing setting. Heat treatment of the dies machined and prepared from these castings was also undertaken. The heat treatment regimen includes solution treatment at 2100.degree. F. for 24 hours and aging from between 1150.degree. F. and 1300.degree. F. for between 12 to 24 hours.Type: GrantFiled: August 29, 1997Date of Patent: May 23, 2000Assignee: United Defense, L.P.Inventors: Chien-Hua Chen, Guy Monroe Maddox, Jr., John Edward Orth, Elliott Lee Turbeville
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Patent number: 5964966Abstract: Specific alloys, in particular Ni-based alloys, that can be biaxially textured, with a well-developed, single component texture are disclosed. These alloys have a significantly reduced Curie point, which is very desirable from the point of view of superconductivity applications. The biaxially textured alloy substrates also possess greatly enhanced mechanical properties (yield strength, ultimate tensile strength) which are essential for most applications, in particular, superconductors. A method is disclosed for producing complex multicomponent alloys which have the ideal physical properties for specific applications, such as lattice parameter, degree of magnetism and mechanical strength, and which cannot be fabricated in textured form. In addition, a method for making ultra thin biaxially textured substrates with complex compositions is disclosed.Type: GrantFiled: September 19, 1997Date of Patent: October 12, 1999Assignee: Lockheed Martin Energy Research CorporationInventors: Amit Goyal, Eliot D. Specht, Donald M. Kroeger, Mariappan Paranthaman
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Patent number: 5908487Abstract: A hydrogen absorbing alloy-packed container packed with a mixture of powders classified respectively into at least two particle-size distribution groups, each of which is different in mean particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of a hydrogen absorbing alloy and a substance not absorbing hydrogen, the mixture having a ratio r.sub.N+1 /r.sub.N, wherein r.sub.N is the mean particle size of the powder having a particle-size distribution of the Nth largest mean particle size, N being an integer of not smaller than 1, and r.sub.N+1 is the mean particle size of the powder having a particle-size distribution of the (N+1)th largest mean particle size, of at least 0.03 to not greater than 0.50. The alloy powders can be selected from the group consisting of lanthanum-nickel, mischmetal-nickel, iron titanium and titanium manganese.Type: GrantFiled: March 21, 1997Date of Patent: June 1, 1999Assignee: Sanyo Electric Co., Ltd.Inventors: Koichi Nishimura, Takahiro Yonesaki, Shin Fujitani, Hiroshi Nakamura, Yumiko Nakamura, Ikuo Yonezu, Hiroshi Watanabe
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Patent number: 5902700Abstract: A hydrogen storage alloy electrode for use in electrochemical hydrogen storage cells, the electrode being in the form of a negative electrode fabricated by sintering a mixture of a hydrogen storage alloy containing manganese and an alloy containing a measured amount of manganese.Type: GrantFiled: January 21, 1998Date of Patent: May 11, 1999Assignee: Sanyo Electric Co., Ltd.Inventors: Takamichi Hirosawa, Takaaki Ikemachi
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Patent number: 5900334Abstract: The present invention provides a hydrogen occluding alloy exhibiting high hydrogen absorption and desorption rates, and excellent initial activation in practical use, and a method of making it. There is provided a hydrogen occluding alloy having a composition comprising, by wt %, 32 to 38% of rare earth elements essentially consisting of La and/or Ce, 0.5 to 3.5% of Al, 0.5 to 10% of Mn, 0.005 to 0.5% of hydrogen, optionally 0.1 to 17% of Co, and the balance being Ni and unavoidable impurities; wherein the alloy has a microstructure characterized in that fine rare earth element hydride is dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure in a ratio of 0.5 to 20% by area. There are also provided electrodes and batteries containing such alloys, and methods of making and using such electrodes and batteries.Type: GrantFiled: May 7, 1997Date of Patent: May 4, 1999Assignee: Mitsubishi Materials CorporationInventors: Masahiro Wada, Yoshio Takizawa
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Patent number: 5830415Abstract: The present invention provides a car exhaust purifying filter member which is high in the capacity to collect solid and liquid contents in exhausts and which has such high heat resistance as to be capable of withstanding heat when burned for cleaning and a method of manufacturing the same. A three-dimensional mesh-like metallic porous member made from Ni--Cr--Al and having a three-dimensional framework is heated at 800-1000 .degree. C. in the atmosphere to form on its surface a densely grown fibrous alumina crystal. This member is used as a filter member. Such a filter member shows excellent collecting capacity and corrosion resistance and can withstand high temperatures. Also, it is possible to firmly carry a catalyst on the fibrous alumina crystal formed on the surface. Because of its increased surface area, it has an increased catalyst carrying capacity.Type: GrantFiled: February 21, 1995Date of Patent: November 3, 1998Assignee: Sumitomo Electric Industries, Ltd.Inventors: Takao Maeda, Masayuki Ishii, Hiroshi Yoshino, Shunsuke Ban
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Patent number: 5824166Abstract: Described is a material handling apparatus for processing heated formed ferrous metal products and/or glass products comprising a face centered cubic crystal intermetallic alloy of a metal aluminide having the property of withstanding repeated thermal cycling from ambient temperature to about 1600.degree. F. wherein the metal is selected from the group consisting of a group VIII metal of the Periodic Table. Also described is an aluminide roll that also is characterized as retaining its ultimate tensile strength at 1600.degree. F. of at least 75% of the tensile strength the roll had at ambient room temperature.Type: GrantFiled: May 20, 1994Date of Patent: October 20, 1998Assignee: MetallamicsInventor: Robert R. McDonald
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Patent number: 5725691Abstract: Alloys for use in structural applications based upon NiAl to which are added selected elements to enhance room temperature ductility and high temperature strength. Specifically, small additions of molybdenum produce a beneficial alloy, while further additions of boron, carbon, iron, niobium, tantalum, zirconium and hafnium further improve performance of alloys at both room temperature and high temperatures. A preferred alloy system composition is Ni--(49.1.+-.0.8%)Al--(1.0.+-.0.8%)Mo--(0.7.+-.0.5%)Nb/Ta/Zr/Hf--(nearly zero to 0.03%)B/C, where the % is at. % in each of the concentrations. All alloys demonstrated good oxidation resistance at the elevated temperatures. The alloys can be fabricated into components using conventional techniques.Type: GrantFiled: February 29, 1996Date of Patent: March 10, 1998Assignee: Lockheed Martin Energy Systems, Inc.Inventor: Chain T. Liu
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Patent number: 5725687Abstract: The present invention relates to a wear-resistant high permeability alloy nsisting of Ni, Nb, C and Fe, a wear-resistant high permeability alloy consisting of Ni, Nb, C and Fe as main components and at least one element selected from the group consisting of Cr, Mo, Ge, Au, Co, V, W, Cu, Ta, Mn, Al, Si, Ti, Zr, Hf, Sn, Sb, Ga, In, Tl, Zn, Cd, rare earth element, platinum element, Be, Ag, Sr, B, P, N, O, S as a secondary component and a method of manufacturing the same and a magnetic recording and reproducing head, and an object of the invention is to obtain an excellent wear-resistant magnetic alloy having easy forging processability, a large effective permeability, a saturated flux density of more than 4000G, and a recrystallization texture of {110}<112>+{311}<112>+{111}<112>, and a wear-resistant high permeability alloy consisting by weight of Ni 60-90%, Nb 0.5-14%, C 0.0003-0.Type: GrantFiled: October 30, 1995Date of Patent: March 10, 1998Assignee: The Foundation: The Research Institute of Electric and Magnetic AlloysInventors: Yuetsu Murakami, Katashi Masumoto
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Patent number: 5669989Abstract: A Ni--Fe magnetic alloy consists essentially of: 77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.?Ni!-11.13.times.?Mo!-1.25.times.?Cu!-5.03.times.?M n!)/(2.13.times.?Fe!).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%. A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.Type: GrantFiled: October 19, 1995Date of Patent: September 23, 1997Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
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Patent number: 5628814Abstract: A nickel-base superalloy article has a coating having a composition, in weight percent, of from about 10 to about 20 percent cobalt, from about 14 to about 25 percent chromium, from about 2 to about 12 percent aluminum, from 0 to about 0.2 percent yttrium, from about 0.001 to about 3 percent boron, from about 1 to about 10 percent silicon, balance nickel and incidental impurities. The coating is preferably applied by mixing together two powders, one with a higher solidus temperature and one with a lower solidus temperature, whose net composition is that of the coating. The powder mixture is compacted with a binder, applied to a surface of the article, and heated to a temperature above the lower solidus temperature.Type: GrantFiled: November 22, 1995Date of Patent: May 13, 1997Assignee: General Electric CompanyInventors: Jim D. Reeves, David E. Budinger, Robert A. Anderson
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Patent number: 5500057Abstract: A Ni-Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[M n])/ (2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/ (Mo average content).vertline..times.100%.A method for producing a magnetic Ni-Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.Type: GrantFiled: October 1, 1993Date of Patent: March 19, 1996Assignee: NKK CorporationInventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
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Patent number: 5472663Abstract: To improve high-temperature strength, as well as increased resistance to wear due to sparking, a Ni-based alloy sparking plug electrode material for use in an internal combustion engine is provided. Such a Ni-based alloy sparking plug electrode material contain, by weight, from 3.1 to 4.3 of Al, from 0.5 to 1.5% of Si, from 0.45 to 0.65% of Mn, from 0.002 to 0.01% of C, from 0.005 to 0.05% of at least one of Mg and Ca, and, as necessitated, from to 2% of Cr, with the balance substantially Ni and inevitable impurities.Type: GrantFiled: July 1, 1993Date of Patent: December 5, 1995Assignee: Mitsubishi Materials CorporationInventors: Hideo Kitamura, Kensho Sahira, Akira Mimura
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Patent number: 5374319Abstract: A process is provided for welding a gamma-prime precipitation-strengthened nickel base superalloy by heating the weld area and adjacent region to a ductile temperature, welding while maintaining the entire weld area and adjacent region at the ductile temperature and holding the weldment, weld area and adjacent region at the ductile temperature until the entire weld has solidified. The ductile temperature is above the aging temperature but below the incipient melting temperature of the superalloy.Type: GrantFiled: November 4, 1991Date of Patent: December 20, 1994Assignee: Chromalloy Gas Turbine CorporationInventors: Richard J. Stueber, Thomas Milidantri, Moshen Tadayon
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Patent number: 5167732Abstract: Nickel aluminide single crystal alloys having improved strength and ductility at elevated temperatures, produced by major elemental additions to strengthen the Ni.sub.3 Al phase by solid solutioning and/or secondary phase formation. The major elemental additions comprise (by weight) 7-20% Al, 0.5-9% molybedenum, 0.5-10% tungsten and 2-15% titanium. Optional minor elemental additions of boron, manganese, silcon and/or hafnium are preferred.Type: GrantFiled: October 3, 1991Date of Patent: December 1, 1992Assignee: Textron, Inc.Inventor: Subhash K. Naik
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Patent number: 5116438Abstract: A beta phase nickel aluminide microalloyed with gallium having improved ductility. Nickel aluminide intermetallics alloyed with up to about 0.25 atomic percent gallium have significantly improved room temperature ductility over conventional unalloyed beta phase nickel aluminides or beta phase nickel aluminides alloyed with higher percentages of gallium.Type: GrantFiled: March 4, 1991Date of Patent: May 26, 1992Assignee: General Electric CompanyInventors: Ramgopal Darolia, David F. Lahrman
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Patent number: 5116691Abstract: A NiAl nickel aluminide alloyed with yttrium, optionally gallium, and an element selected from the group consisting of chromium, molybdenum and combinations thereof, having improved room temperature ductility and plastic strain. NiAl nickel aluminide intermetallics alloyed with no more than about 5 atomic percent of additional elements have significantly improved room temperature ductility over conventional unalloyed beta phase nickel aluminides or beta phase nickel aluminides alloyed with higher percentages of additional elements. The NiAl nickel aluminide comprises, in atomic percent, at least 50% nickel, about 0.01% to about 0.25% yttrium, about 0 to about 0.15% gallium, about 0.05% to about 4% of an element selected from the group consisting of chromium, molybdenum and combinations thereof, and balance from about 40% to about 49.85% aluminum and trace impurities.Type: GrantFiled: March 4, 1991Date of Patent: May 26, 1992Assignee: General Electric CompanyInventors: Ramgopal Darolia, David F. Lahrman
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Patent number: 5069179Abstract: An internal combustion engine is described which comprises a main combustion chamber and a secondary combustion chamber which is arranged in the cylinder head of the internal combustion engine and is connected via a shot channel to the main combustion chamber. To increase the high-temperature stability, the parts of the secondary combustion chamber which are acted upon by the hot gas jet are made of a material of intermetallic phase.Type: GrantFiled: October 25, 1999Date of Patent: December 3, 1991Assignee: Mercedes-Benz AGInventors: Johann Kramer, Rainer Renz
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Patent number: 5059259Abstract: An oxidation- and corrosion-resistant high-temperature alloy of high toughness at room temperature for directional solidification, based on an intermetallic compound of the nickel aluminide type and having the following composition:Al=10-20 atom %Si=0.5-8 atom %Nb=2-10 atom %B=0.1-2 atom %Ni=remainder,the total of Al, Si, Nb and B amounting at most to a value of 25 atom %. The alloy contains at least 90% by volume of the intermetallic phases Ni.sub.3 Al, Ni.sub.3 Si and Ni.sub.3 Nb.Type: GrantFiled: July 20, 1990Date of Patent: October 22, 1991Assignee: Asea Brown Boveri Ltd.Inventors: Mohamed Nazmy, Markus Staubli
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Patent number: 4990199Abstract: An oxidation-resistant and corrosion-resistant high-temperature alloy for directional solidification on the basis of an intermetallic compound of the nickel aluminide type having the following composition:Al=10-16 atomic %Si=0.5-8 atomic %Ta=0.5-9 atomic %Hf=0.1-2 atomic %B=0.1-2 atomic %Ni=the remainderThe alloy has at least 90% by volume of the intermetallic phases Ni.sub.3 Al, Ni.sub.3 Si and Ni.sub.3 Ta.Type: GrantFiled: November 13, 1989Date of Patent: February 5, 1991Assignee: Asea Brown Boveri Ltd.Inventors: Maohamed Nazmy, Markus Staubli
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Patent number: 4988488Abstract: The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.Type: GrantFiled: October 19, 1989Date of Patent: January 29, 1991Assignee: Air Products and Chemicals, Inc.Inventor: Doohee Kang
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Patent number: 4983474Abstract: A hydrogen absorbing Ni-based alloy comprising 5 to 25% by weight of titanium (Ti), 10 to 37% by weight of zirconium (Zr), 4 to 20% by weight of manganese (Mn), 0.1 to 12% by weight of vanadium (V), 0.01 to 5% by weight of iron (Fe), 0.01 to 4.5% by weight of aluminum (Al), and balance nickel (Ni) and unavoidable impurities, and a sealed Ni-hydrogen rechargeable battery comprising a negative electrode provided with such a hydrogen absorbing alloy as an active material, an Ni positive electrode, a separator and an alkaline electrolyte solution.Type: GrantFiled: May 17, 1989Date of Patent: January 8, 1991Assignee: Mitsubishi Metal CorporationInventors: Hidekazu Doi, Ritsue Yabuki
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Patent number: 4961905Abstract: A modified class of nickel aluminide (NiAl) type material is disclosed having useful amounts of toughness and ductility at low temperatures, e.g. room temperature. The basic NiAl material is modified with an additional of the material such as cobalt which produces a structure which is susceptible to undergoing a martensitic transformation. The martensitic structure when produced results in a significant increase in toughness and ductility at low temperatures.Type: GrantFiled: December 13, 1988Date of Patent: October 9, 1990Assignee: United Technologies CorporationInventors: Chi C. Law, Scott M. Russell
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Patent number: 4898794Abstract: A hydrogen absorbing Ni,Zr-based alloy comprising 5 to 20% by weight of titanium (Ti), 10 to 37% by weight of zirconium (Zr), 5 to 30% by weight of manganese (Mn), 0.01 to 15% by weight of tungsten (W), 6 to 30% by weight of iron (Fe), and optionally at least one of 0.1 to 7% by weight of Cu, 0.05 to 6% by weight of Cr and 0.01 to 5% by weight of Al, and balance nickel (Ni) and unavoidable impurities; and a sealed Ni-hydrogen rechargeable battery comprising a negative electrode provided with a hydrogen absorbing alloy as an active material, an Ni positive electrode, a separator and an alkaline electrolytic solution, wherein the hydrogen absorbing alloy is composed of such hydrogen absorbing Ni,Zr-based alloy.Type: GrantFiled: July 17, 1989Date of Patent: February 6, 1990Assignee: Mitsubishi Metal CorporationInventors: Hidekazu Doi, Ritsue Yabuki
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Patent number: 4861550Abstract: The invention relates to a Ni-base alloy which contains Mo, Al and Fe, and further, as required, one or more of the following: a group consisting of one or more of V, W, Cr and Cu; one or both of B and Ca; and Co. The alloy of the invention has excellent resistance to stress corrosion cracking even after being subjected to thermal processing such as welding without need for solution treatment thereafter.Type: GrantFiled: March 14, 1988Date of Patent: August 29, 1989Assignee: Mitsubishi Metal Corporation of TokyoInventors: Takeshi Yoshida, Yoshio Takizawa, Ichiro Sekine
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Patent number: 4828613Abstract: A powdery raw material for manufacturing an anode of a fuel cell comprises a powder of a nickel-base alloy consisting essentially of 0.5-10 percent by weight aluminum, and the balance of nickel and inevitable impurities, and having a mean grain size of 3-20 microns. The nickel-base alloy powder may contain 0.01-1.0 percent by weight oxygen, and/or may have an apparent density of 0.5-3.5 g/cm.sup.3, and a specific surface area of at least 0.12 m.sup.2 /g. Advantageously, the nickel-base alloy powder is formed by means of water-atomization under a condition that the water injection pressure is 400 Kg/cm.sup.2, and the specific water quantity is 0.02-0.2 m.sup.3 /Kg, the thus manufactured anodes exhibit initial anode characteristics as excellent as those of conventional anodes, and possess such excellent high-temperature creep strength and sintering resistance, thereby exhibiting excellent anode characteristics over a long period of time.Type: GrantFiled: August 17, 1987Date of Patent: May 9, 1989Assignees: Mitsubishi Kinzoku Kabushiki Kaisha, Mitsubishi Electric CorporationInventors: Koji Hoshino, Fumio Nouda, Seiro Yahata
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Patent number: 4816216Abstract: The present invention relates to an iron-nickel alloy containing from about 30% to about 60% nickel, from about 0.001% to about 0.15% nitrogen, at least one element selected from the group consisting of from about 1% to about 10% molybdenum and from about 0.001% to about 2% aluminum and the balance essentially iron. The alloys demonstrate improved resistance to intermetallic compound formation, improved glass to metal sealing properties, and improved wirebonding performance. The alloys of the present invention have particular utility as a lead frame material for semiconductor packages.Type: GrantFiled: November 29, 1985Date of Patent: March 28, 1989Assignee: Olin CorporationInventors: Chung-Yao Chao, John F. Breedis
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Patent number: 4762558Abstract: Reactive sintering process for producing a shaped body containing the nickel aluminide compound Ni.sub.3 Al, which comprises sintering a compacted shaped mass containing an intimate mixture of substances, e.g. including elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni.sub.3 Al, by heating the mass, e.g. in a vacuum, to an elevated sintering temperature, e.g. 500-750.degree. C., sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering sufficiently to form a densified shaped body containing the nickel aluminide compound Ni.sub.Type: GrantFiled: May 15, 1987Date of Patent: August 9, 1988Assignee: Rensselaer Polytechnic InstituteInventors: Randall M. German, Animesh Bose, David Sims
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Patent number: 4740354Abstract: A nickel-base cast alloy for use in high-temperature forging dies operable in the atmosphere, consisting essentially of 4-10 weight % of Al, 13-23 weight % of Mo and the balance of Ni and impurities. The nickel-base cast alloy may further contain up to 0.1 weight % of at least one of rare earth metals and Y. It may also contain up to 15 weight % of W and/or Ta substituting for a part of Mo. Ni may be replaced by up to 20 weight % of Co. The cast alloy of the present invention has high resistance to compression deformation and oxidation.Type: GrantFiled: September 19, 1986Date of Patent: April 26, 1988Assignee: Hitachi, Metals Ltd.Inventors: Rikizo Watanabe, Takehiro Ohno, Toshiaki Nonomura
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Patent number: 4731221Abstract: Nickel aluminides and nickel-iron aluminides treated with hafnium or zirconium, boron and cerium to which have been added chromium to significantly improve high temperature ductility, creep resistance and oxidation properties in oxidizing environments.Type: GrantFiled: October 11, 1985Date of Patent: March 15, 1988Assignee: The United States of America as represented by the United States Department of EnergyInventor: Chain T. Liu
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Patent number: 4725322Abstract: A tri-nickel aluminide base alloy composition is provided with a desirable combination of tensile strength and ductility. The composition is prepared to include boron dopant in combination with relatively low percentages of carbon for the high increase in strength achieved. The composition has an Ll.sub.2 of crystalline structure. It is prepared by rapid solidification at a cooling rate of at least 10.sup.3 .degree. C. per second.Type: GrantFiled: October 3, 1985Date of Patent: February 16, 1988Assignee: General Electric CompanyInventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
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Patent number: 4710247Abstract: A method for achieving both improved strength and improved ductility in intermediate phases is provided. The method, briefly stated, comprises the steps of providing a melt whose composition substantially corresponds to that of a preselected intermetallic phase having a crystal structure of the Ll.sub.2 type, such as nickel alumininde, modified with from about 0.01 to 2.5 atomic percent boron, and modified further with cobalt substituent metal and rapidly solidifying the melt at a cooling rate of at least about 10.sup.3 .degree. C./second to form a solid body, the principal phase of which is of the Ll.sub.2 type crystal structure in either its ordered or disordered state.Type: GrantFiled: March 14, 1986Date of Patent: December 1, 1987Assignee: General Electric CompanyInventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
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Patent number: 4710243Abstract: A wear-resistant alloy of high permeability having an effective permeabil of at least about 3,000 at 1 KHz, a saturation magnetic flux density of at least about 4,000 G, and a recrystallization texture of {110}<112>+{311}<112> is provided. The alloy is produced by cold working a forged or hot worked ingot of an alloy of a desired composition at a cold working ratio of at least about 50%, heating the cold worked alloy at a temperature which is below the m.p. of the alloy and not less than about 900.degree. C., and cooling the heated alloy from a temperature which is not less than an order-disorder transformation point (about 600.degree. C.) of the alloy. Alternatively, the alloy is produced by reheating the cooled alloy to a temperature which is not over than the order-disorder transformation point, and cooling the reheated alloy.Type: GrantFiled: July 29, 1985Date of Patent: December 1, 1987Assignee: The Foundation: The Research Institute of Electric and Magnetic AlloysInventors: Hakaru Masumoto, Yuetsu Murakami
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Patent number: 4676829Abstract: Improvements in the positive temperature dependence of yield strength and in the work hardening rate of tri-nickel aluminide base alloys are achieved. The novel alloy composition has seven alloying ingredients as follows:______________________________________ Concentration Ingredient in Atomic % ______________________________________ Ni balance Co 8-12 Al 16-20 Si 4-6 Nb 0.26-0.30 Zr 0.02-0.04 B 0.2-0.7 ______________________________________The novel composition may be prepared by forming a melt of the composition and atomizing the melt with an inert gas to form fine particles with Ll.sub.2 type crystal structure. The powder is densified by heat and pressure to a novel alloy composition having the improvements in positive temperature dependence of yield strength and work hardening rate as noted above.Type: GrantFiled: October 3, 1985Date of Patent: June 30, 1987Assignee: General Electric CompanyInventors: Keh-Minn Chang, Alan I. Taub, Shyh-Chin Huang
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Patent number: 4668311Abstract: A substantial increase in strength of a boron doped nickel aluminide is achieved by employing a substituent metal in the Ni.sub.3 Al composition to replace a part of the aluminum. Vanadium and silicon are successfully substituted for a portion of the aluminum to provide a composition:(Ni.sub.0.75 Al.sub.0.20 X.sub.0.05).sub.99 B.sub.1where X is selected from the group consisting of vanadium or silicon.Type: GrantFiled: June 5, 1986Date of Patent: May 26, 1987Assignee: General Electric CompanyInventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
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Patent number: 4661156Abstract: A metal body having high tensile strength and ductility at temperatures over 1000.degree. F. is provided. The body is prepared by hot isostatic pressing of powder formed by atomization of a melt of an alloy. The alloy composition base is according to the formula:(Ni.sub.1-x Al.sub.x).sub.100-y B.sub.ywhere x is between 0.23 and 0.25, and where y is 0.1 to 2.0.The consolidated body is suitable for machining and may be annealed for a couple of hours at temperatures between 800.degree. C. and 1200.degree. C. following such machining.Type: GrantFiled: October 3, 1985Date of Patent: April 28, 1987Assignee: General Electric CompanyInventors: Keh-Minn Chang, Alan I. Taub, Shyh-Chin Huang