Platinum Base Patents (Class 420/466)
  • Patent number: 11774910
    Abstract: A resonant member for a striking mechanism of a watch or of a music box includes at least one resonant part, such as one or more gongs, arranged to vibrate and resonate once activated, and an attachment part. The resonant part and/or the attachment part is made from an alloy of palladium or platinum with more than 51% of palladium or platinum in the alloy.
    Type: Grant
    Filed: November 4, 2019
    Date of Patent: October 3, 2023
    Assignee: Blancpain SA
    Inventors: Laurane Chevallier, Julien Peter
  • Patent number: 11433386
    Abstract: Methods are provided for activation of catalysts comprising low amounts of a hydrogenation metal, such as low amounts of a Group 8-10 noble metal. The amount of hydrogenation metal on the catalyst can correspond to 0.5 wt % or less (with respect to the weight of the catalyst), or 0.1 wt % or less, or 0.05 wt % or less. Prior to loading a catalyst into a reactor, the corresponding catalyst precursor can be first activated in a hydrogen-containing atmosphere containing 1.0 vppm of CO or less. The thus first-activated catalyst can be transferred to a reactor with optional exposure to oxygen during the transfer, where it can be further activated using a hydrogen-containing atmosphere containing 3.0 vppm of CO or higher, to yield a twice-activated catalyst with high performance. The catalyst can be advantageously a transalkylation catalyst or an isomerization catalyst useful for converting aromatic hydrocarbons.
    Type: Grant
    Filed: January 14, 2020
    Date of Patent: September 6, 2022
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mayank Shekhar, Paul Podsiadlo, Michel Molinier, Scott J. Weigel, Travis D. Sparks, Jocelyn A. Gilcrest, Joseph E. Gatt
  • Patent number: 10675586
    Abstract: The present disclosure describes hybrid binary catalysts (HBCs) that can be used as engine aftertreatment catalyst compositions. The HBCs provide solutions to the challenges facing emissions control. In general, the HBCs include a porous primary catalyst and a secondary catalyst. The secondary catalyst partial coats the surfaces (e.g., the internal porous surface and/or the external surface) of the primary catalyst resulting in a hybridized composition. The synthesis of the HBCs can provide a primary catalyst whose entire surface, or portions thereof, can be coated with the secondary catalyst.
    Type: Grant
    Filed: June 2, 2017
    Date of Patent: June 9, 2020
    Assignee: PACCAR INC
    Inventor: Randal A. Goffe
  • Patent number: 10280530
    Abstract: To provide a single crystal production apparatus that is capable of prolonging the lifetime of a heater, and capable of reducing the cost. A single crystal production apparatus of the present invention is the single crystal production apparatus which produces a single crystal of a metal oxide in an oxidative atmosphere, containing: a base body; a cylindrical furnace body having heat resistance disposed above the base body; a lid member occluding the furnace body; a heater disposed inside the furnace body; a high frequency coil heating the heater through high frequency induction heating; and a crucible heated with the heater, the heater containing a Pt-based alloy and having a zirconia coating on an overall surface of the heater.
    Type: Grant
    Filed: January 10, 2018
    Date of Patent: May 7, 2019
    Assignees: FUJIKOSHI MACHINERY CORP., SHINSHU UNIVERSITY
    Inventors: Keigo Hoshikawa, Yasuyuki Fujiwara, Keiichi Kohama, Shinji Nakanishi, Takumi Kobayashi, Etsuko Ohba
  • Patent number: 10113217
    Abstract: A platinum wire in which crystal grain growth is slowed in order to prevent damage caused by creep without dispersing a metal oxide, and occurrence of slip at crystal grain boundaries is slowed. A platinum thermocouple wire that is used in a negative electrode of a platinum-based thermocouple and has a nitrogen mass concentration of 10 to 100 ppm, and when structure observation of the cross section of the wire in a longitudinal direction is performed, a structure is observed in which there is a plurality of crystal grains, which have an aspect ratio {(length of major axis)/(length of minor axis perpendicular to major axis)} of 5 or more and elongate in the longitudinal direction of the wire, in a wire thickness direction.
    Type: Grant
    Filed: February 6, 2015
    Date of Patent: October 30, 2018
    Assignee: FURUYA METAL CO., LTD.
    Inventors: Tomohiro Maruko, Tomoaki Miyazawa, Shoji Saito, Kensuke Morita
  • Patent number: 9903738
    Abstract: A conductive material includes metal nanowires and an extensible copolymer having an N—C?O structure and combined with the metal nanowires. The conductive material has excellent elongation properties and has an electrical resistance that is unlikely to increase even when the conductive material is extended. A method for producing a conductive material includes: a copolymer production step of polymerizing a plurality of monomers including a growth direction control monomer that has an N—C?O structure and controls a growth direction of metal nanowires to produce an extensible copolymer; a reaction step of reacting a metal compound in a solvent containing the copolymer to grow metal nanowires in a longitudinal direction; and an extraction step of extracting a product from the solution after the reaction.
    Type: Grant
    Filed: March 30, 2015
    Date of Patent: February 27, 2018
    Assignees: SUMITOMO RIKO COMPANY LIMITED, KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION
    Inventors: Yutaro Taguchi, Hitoshi Yoshikawa, Hidetsugu Torihara, Ryosuke Matsuno, Masaharu Tsuji, Atsushi Takahara
  • Publication number: 20150125338
    Abstract: Identifying a stable phase of a binary alloy comprising a solute element and a solvent element. In one example, at least two thermodynamic parameters associated with grain growth and phase separation of the binary alloy are determined, and the stable phase of the binary alloy is identified based on the first thermodynamic parameter and the second thermodynamic parameter, wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.
    Type: Application
    Filed: March 12, 2012
    Publication date: May 7, 2015
    Inventors: Heather Murdoch, Christopher A. Schuh
  • Publication number: 20140348203
    Abstract: Provided in one embodiment is a method of identifying a stable phase of an ordering binary alloy system comprising a solute element and a solvent element, the method comprising: determining at least three thermodynamic parameters associated with grain boundary segregation, phase separation, and intermetallic compound formation of the ordering binary alloy system; and identifying the stable phase of the ordering binary alloy system based on the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter by comparing the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter with a predetermined set of respective thermodynamic parameters to identify the stable phase; wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.
    Type: Application
    Filed: May 20, 2014
    Publication date: November 27, 2014
    Applicant: Massachusetts Institute of Technology
    Inventors: Heather A. Murdoch, Christopher A. Schuh
  • Publication number: 20140326849
    Abstract: A mechanical structure is provided with a crystalline superelastic alloy that is characterized by an average grain size and that exhibits a martensitic phase transformation resulting from a mechanical stress input greater than a characteristic first critical stress. A configuration of the superelastic alloy is provided with a geometric structural feature of the alloy that has an extent that is no greater than about 200 micrometers and that is no larger than the average grain size of the alloy. This geometric feature undergoes the martensitic transformation without intergranular fracture of the geometric feature.
    Type: Application
    Filed: September 13, 2012
    Publication date: November 6, 2014
    Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
    Inventors: Christopher A. Schuh, Jose M. San Juan, Ying Chen
  • Publication number: 20140314617
    Abstract: A dental alloy contains palladium (Pd) and indium (In) for CAD/CAM machining. The dental alloy can further include one component selected from the group consisting of gold (Au), silver (Ag), nickel (Ni), cobalt (Co), and platinum (Pt). The dental alloy has a yield strength of 250 MPa to 450 MPa, breaking elongation of 2% to 8%, metal-ceramic adhesion of 20 MPa to 70 MPa, coefficient of linear thermal expansion of 14.0×10?6/K to 17.0×10?6/K, or density of 8 g/cm3 to 15 g/cm3.
    Type: Application
    Filed: April 13, 2012
    Publication date: October 23, 2014
    Applicant: CERAGEM BIOSYS CO., LTD.
    Inventors: Kyeong Jun Park, Jeong Jong Park, Sun Wook Cho
  • Publication number: 20140294676
    Abstract: Hydrogen sensor including a substrate (S) on which there is deposited an active layer of material comprising a first element selected from the rare earth family, a second element selected from the platinum group metals (PGMs) and a third element selected from the alkaline earth metal family.
    Type: Application
    Filed: June 6, 2012
    Publication date: October 2, 2014
    Applicant: THE SWATCH GROUP RESEARCH AND DEVELOPMENT LTD
    Inventors: Klaus Yvon, Edmond Koller, Jean-Philippe Rapin, Michael Stalder
  • Publication number: 20140271220
    Abstract: A platinum plus chromium coating applied to the roots and firtrees of turbine blades where the inclusion of chromium creates a single phase outer zone which minimises diffusion paths for sulphur which can preferentially diffuse down phase boundaries and enables a chromium rich outer oxide scale to form on top of the coating.
    Type: Application
    Filed: February 18, 2014
    Publication date: September 18, 2014
    Applicant: ROLLS-ROYCE PLC
    Inventor: Andrew Jonathan LEGGETT
  • Publication number: 20140255247
    Abstract: A method for producing highly pure platinum on an industrial scale, as well as the use of said highly pure platinum. According to the method, a hexahalogenoplatinate is reduced to platinum in acidic conditions.
    Type: Application
    Filed: March 4, 2014
    Publication date: September 11, 2014
    Applicant: HERAEUS PRECIOUS METALS GMBH & CO. KG
    Inventors: Joachim KRALIK, Martin STETTNER, Hermann VON EIFF, Jan SCHAPP
  • Patent number: 8802151
    Abstract: The instant invention relates to shaped transition metal particles, in particular in the form of a dispersion in an aqueous and/or organic medium, the manufacture thereof and their use as an infrared (IR) absorbing agent, an IR curing agent for coatings, an additive in conductive formulations, an antimicrobial agent or for sensoring organic and/or inorganic compounds. Further, the invention relates to dispersions comprising said shaped particles and an aqueous and/or organic medium, such as a thermoplastic or crosslinkable polymer, as well as to antimicrobial compositions and products.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: August 12, 2014
    Assignee: BASF SE
    Inventors: Nikolay A. Grigorenko, Michael Muehlebach, Florian Muehlebach
  • Publication number: 20140212324
    Abstract: Provided by the present invention are a fine crystallite high-function metal alloy member, a method for manufacturing the same, and a business development method thereof, in which a crystallite of a metal alloy including a high-purity metal alloy whose crystal lattice is a face-centered cubic lattice, a body-centered cubic lattice, or a close-packed hexagonal lattice is made fine with the size in the level of nanometers (10?9 m to 10?6 m) and micrometers (10?6 m to 10?3 m), and the form thereof is adjusted, thereby remedying drawbacks thereof and enhancing various characteristics without losing superior characteristics owned by the alloy.
    Type: Application
    Filed: April 10, 2012
    Publication date: July 31, 2014
    Applicant: THREE-O CO., LTD.
    Inventor: Kazuo Ogasa
  • Publication number: 20140212664
    Abstract: Provided in one embodiment is a method of forming an inorganic nanowire, comprising: providing an elongated organic scaffold; providing a plurality of inorganic nanoparticles attached to the organic scaffold along a length of the organic scaffold; and fusing the nanoparticles attached to the organic scaffold to form an inorganic nanowire.
    Type: Application
    Filed: August 27, 2013
    Publication date: July 31, 2014
    Applicants: Massachusetts Institute of Technology, Board of Regents, The University of Texas System
    Inventors: Angela M. BELCHER, Chuanbin MAO, Daniel J. SOLIS
  • Publication number: 20140158950
    Abstract: Nanocrystals comprising organic ligands at surfaces of the plurality of nanocrystals are provided. The organic ligands are removed from the surfaces of the nanocrystals using a solution comprising a trialkyloxonium salt in a polar aprotic solvent. The removal of the organic ligands causes the nanocrystals to become naked nanocrystals with cationic surfaces.
    Type: Application
    Filed: November 12, 2013
    Publication date: June 12, 2014
    Applicant: The Regents of The University of California
    Inventors: Brett Anthony Helms, Delia Jane Milliron, Evelyn Louise Rosen, Raffaella Buonsanti, Anna Llordes
  • Publication number: 20140134447
    Abstract: A Pt—Al—Hf/Zr aluminide coating that can be used as a bond coat for TBC and improve TBC spallation life in service at elevated temperatures is provided. The aluminide coating can include a metastable ternary or higher X—Pt/Pd—Ni phase where the phase and other elements in the alloy system are present in a NiAl ? phase of the coating. The metastable phase can be present and observable in the as-deposited condition of the bond coating; e.g. in an as-CVD deposited condition of the bond coating.
    Type: Application
    Filed: October 31, 2012
    Publication date: May 15, 2014
    Inventor: Kenneth S. Murphy
  • Publication number: 20140096874
    Abstract: An article made of an alloy of the general formula Pt1-a-bMa(B1-xMdx)b in which i) M stands for one or a mixture of metallic element(s) of the group Zr, Ti, Fe, Ni, Co, Cu, Pd, Ag, Al; ii) Md stands for one or a mixture of several metalloids of the group Si, P, C, S, As, Ge; iii) a is smaller than 0.2; iv) b is comprised between 0.2 and 0.5; v) x is comprised between 0 and 0.8; vi) the overall P content, if present, is less than 10 atomic percent the proportions of the elements forming the alloy having been selected to confer a hardness of at least 400 HV, a melting point below 1000° C. and improved processibility to the alloy.
    Type: Application
    Filed: May 2, 2012
    Publication date: April 10, 2014
    Applicant: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
    Inventor: Ludger WEBER
  • Patent number: 8685878
    Abstract: A multimetallic nanoscale catalyst having a core portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.
    Type: Grant
    Filed: April 23, 2012
    Date of Patent: April 1, 2014
    Assignee: UChicago Argonne, LLC
    Inventors: Vojislav Stamenkovic, Nenad M. Markovic, Chao Wang, Hideo Daimon, Shouheng Sun
  • Patent number: 8530371
    Abstract: A catalyst for diesel particle filter includes a platinum (Pt)-neodymium (Nd) alloy that is carried in silica, a preparation method thereof and a soot reduction device for diesel engine including the same, wherein the catalyst for diesel particle filter can maintain high catalyst activity and implement high nitrogen monoxide (NO) conversion efficiency even though it is used under the high temperature or vulcanization condition for a long time.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: September 10, 2013
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Ho-In Lee, Yeon-Su Kim, Yong-Kwon Chung, Jin Ha Lee, Jie Won Park
  • Publication number: 20130213107
    Abstract: The present invention is a metallic wire rod comprising iridium or an iridium-containing alloy and, the wire rod has in the cross section thereof biaxial crystal orientation of 50% or more of abundance proportion of textures in which crystallographic orientation has preferred orientation to <100> direction. In the present invention, crystal orientation in the outer periphery from semicircle of the cross section which is the periphery of the wire rod is important, and in this zone, abundance proportion of textures in which crystallographic orientation has preferred orientation to <100> direction is preferably not less than 50%.
    Type: Application
    Filed: December 15, 2011
    Publication date: August 22, 2013
    Applicant: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Koichi Sakairi, Kunihiro Tanaka, Muneki Nakamura, Fumie Seki
  • Publication number: 20130199673
    Abstract: The invention is directed to a process to prepare metal nanoparticles or metal oxide nanoparticles by applying a cathodic potential as an alternating current (ac) voltage to a solid starting metal object which solid metal object is in contact with a liquid electrolyte comprising a stabilising cation. The invention is also directed to the use of the nanoparticles as a catalyst.
    Type: Application
    Filed: July 14, 2011
    Publication date: August 8, 2013
    Applicants: STICHTING VOOR FUNDAMENTEEL ONDERZOEK DER MATERIE, UNIVERSITEIT LEIDEN
    Inventors: Alexei Yanson, Marcus Koper, Paramaconi Rodriguez, Nuria Garcia-Araez
  • Patent number: 8491730
    Abstract: A magnetic material includes a main alloy having a rhombohedral crystal structure and a composition represented by CoyCuxPtz, wherein x ranges from 3 to 32, y ranges from 18 to 47, and z ranges from 40 to 60, with the proviso that x+y+z=100. The rhombohedral crystal structure of the main alloy includes a magnetic Co—Pt alloy region and a nonmagnetic Cu—Pt alloy region.
    Type: Grant
    Filed: June 15, 2011
    Date of Patent: July 23, 2013
    Assignee: National Taiwan University
    Inventors: Fu-Te Yuan, An-Cheng Sun, Jen-Hwa Hsu, Chih-Shan Tan, Po-Cheng Kuo
  • Patent number: 8486852
    Abstract: A catalyst for diesel particle filter includes a platinum (Pt)-neodymium (Nd) alloy that is carried in silica, a preparation method thereof and a soot reduction device for diesel engine including the same, wherein the catalyst for diesel particle filter can maintain high catalyst activity and implement high nitrogen monoxide (NO) conversion efficiency even though it is used under the high temperature or vulcanization condition for a long time.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: July 16, 2013
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Ho-In Lee, Yeon-Su Kim, Yong-Kwon Chung, Jin Ha Lee, Jie Won Park
  • Publication number: 20130055625
    Abstract: Provided is a method for producing biodiesel fuel having an excellent oxidative stability and fluidity at low temperature, wherein the method provides selective hydrogenation of a poly-unsaturated fatty acid alkyl ester to the mono-unsaturated fatty acid alkyl ester while inhibiting the formation of the trans-isomer, and a biodiesel fuel composition. In the method for producing biodiesel fuel, a fatty acid alkyl ester prepared from fat and/or waste edible oil by transesterification reaction, and/or (2) a fatty acid alkyl ester treated by esterification reaction of a fatty acid is hydrogenated in the presence of a hydrogenation catalyst containing at least one of noble metals selected from those of Groups 8-10 in the periodic table under low hydrogen pressure.
    Type: Application
    Filed: February 18, 2011
    Publication date: March 7, 2013
    Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Makoto Toba, Yuji Yoshimura, Yoko Abe
  • Patent number: 8367266
    Abstract: A porous catalyst layer formed from discrete particles of unsupported metal, wherein at least 80%, suitably at least 90%, of the discrete particles have a mass of from 1 to 1000 zeptograms, and wherein the catalyst layer has a metal volume fraction of less than 30% and a metal loading of less than 0.09 mg/cm2 is disclosed. The catalyst layer is suitable for use in fuel cells and other electrochemical applications.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: February 5, 2013
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Ian Roy Harkness, Jonathan David Brereton Sharman, Edward Anthony Wright
  • Patent number: 8361250
    Abstract: According to embodiments of the present invention, an amorphous alloy includes at least Pt, P, Si and B as alloying elements, and has a Pt weight fraction of about 0.925 or greater. In some embodiments, the Pt weight fraction is about 0.950 or greater.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: January 29, 2013
    Assignee: California Institute of Technology
    Inventors: Marios D. Demetriou, William L. Johnson
  • Publication number: 20130020539
    Abstract: A novel multiband absorption based solar cell is disclosed by using the europium chalcogenides (EuX, X?O, S, Se, Te) and related magnetic semiconductor materials, in which an intermediate band is formed by the localized Eu 4f electrons between p-states of chalcogen ions and Eu s-d states. The energy gaps among the multibands can be in the spectral range of the sunlight, thus they can serve as better sunlight absorbers in solar cells than the conventional single band-gap semiconductors such as Si and GaAs. With these multiband semiconductors, the bottleneck in current power conversion efficiency can be potentially overcome in single junction photovoltaics.
    Type: Application
    Filed: July 21, 2011
    Publication date: January 24, 2013
    Inventor: Zhixun Ma
  • Publication number: 20120282132
    Abstract: Methods of the invention allow rapid production of high-porous, large-surface-area nanostructured metal and/or metal oxide at attractive low cost applicable to a wide variety of commercial applications such as sensors, catalysts and photovoltaics.
    Type: Application
    Filed: July 13, 2010
    Publication date: November 8, 2012
    Inventors: James J. Watkins, Christos Fotios Karanikas, David Reisner, Xinqing Ma, Jeff Roth, T. Danny Xiao, Stephen Paul Murphy
  • Publication number: 20120283336
    Abstract: The instant invention relates to shaped transition metal particles, in particular in the form of a dispersion in an aqueous and/or organic medium, the manufacture thereof and their use as an infrared (IR) absorbing agent, an IR curing agent for coatings, an additive in conductive formulations, an antimicrobial agent or for sensoring organic and/or inorganic compounds. Further, the invention relates to dispersions comprising said shaped particles and an aqueous and/or organic medium, such as a thermoplastic or crosslinkable polymer, as well as to antimicrobial compositions and products.
    Type: Application
    Filed: March 17, 2010
    Publication date: November 8, 2012
    Applicant: BASF SE
    Inventors: Nikolay A. Grigorenko, Andreas Muehlebach, Michael Muehlebach, Florian Muehlebach
  • Patent number: 8298354
    Abstract: It is found that alloys including amorphous phase comprising at least a first element selected from the group consisting of Pt and Ru, at least a second element selected from the group consisting of Zr, Hf, Si, Ir, Ru, Pd and Ni, and at least a third element selected from the group consisting of Si, Cu, Cr, Fe, Mo, Co, Al, Zr, Hf, Ni and Ru have excellent machining characteristics, heat-resistant characteristics, corrosion resistance and adhesion resistance. Using the alloys as the molding surface of a die, a heat resistant molding die for forming glass optical device having fine structure for performing high definite functions became possible to manufacture with excellent machining characteristics.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: October 30, 2012
    Assignee: Tokyo Institute of Technology
    Inventors: Seiichi Hata, Jyunpei Sakurai, Akira Shimokohbe, Shigeru Hosoe, Hiroyuki Nabeta
  • Publication number: 20120269675
    Abstract: A material for a plug electrode having not only excellent oxidation wear resistance but also excellent spark wear, and also having adequately-considered discharge properties in use is provided. The present invention relates to a material for a plug electrode, comprising 5% by mass or more and 30% by mass or less of Cu, 0.1% by mass or more and 15% by mass or less of Ir, with the balance being Pt. Alloying by combining two metals of Cu and Ir can reduce discharge voltages and improve durability against spark wear. With addition of only one of them, the effect of improving spark wear properties is poor and the effect of reducing discharge voltages cannot be expected.
    Type: Application
    Filed: February 16, 2011
    Publication date: October 25, 2012
    Inventors: Kunihiro Tanaka, Muneki Nakamura
  • Publication number: 20120237392
    Abstract: A magnetic material includes a main alloy having a rhombohedral crystal structure and a composition represented by CoyCuxPtz, wherein x ranges from 3 to 32, y ranges from 18 to 47, and z ranges from 40 to 60, with the proviso that x+y+z=100. The rhombohedral crystal structure of the main alloy includes a magnetic Co—Pt alloy region and a nonmagnetic Cu—Pt alloy region.
    Type: Application
    Filed: June 15, 2011
    Publication date: September 20, 2012
    Applicant: National Taiwan University
    Inventors: Fu-Te Yuan, An-Cheng Sun, Jen-Hwa Hsu, Chih-Shan Tan, Po-Cheng Kuo
  • Publication number: 20120156088
    Abstract: The invention provides a method for the preparation of FePt or CoPt nanoparticles in ionic liquids, which in certain embodiments constitutes a direct method for the preparation of such nanoparticles having the face-centred tetragonal (fct) crystalline form. The invention also provides FePt or CoPt nanoparticles obtainable by a method of the invention.
    Type: Application
    Filed: August 17, 2010
    Publication date: June 21, 2012
    Inventors: Pascal Andre, Shu Chen, Kris Anderson, Mark James Muldoon
  • Publication number: 20120128528
    Abstract: The present invention is directed to a precious metal recovery process in which an acid sulfidic feed material is subjected to acid pressure oxidation and an alkaline sulfidic feed material is subjected to alkaline pressure oxidation, with the discharge slurries from the pressure oxidation processes being combined to reduce neutralization requirements prior to precious metal recovery.
    Type: Application
    Filed: November 21, 2011
    Publication date: May 24, 2012
    Applicant: Barrick Gold Corporation
    Inventors: John William Langhans, JR., Wilson Chung-Yeh Tsu
  • Patent number: 8178463
    Abstract: A multimetallic nanoscale catalyst having a sore portion enveloped by a shell portion and exhibiting high catalytic activity and improved catalytic durability. In various embodiments, the core/shell nanoparticles comprise a gold particle coated with a catalytically active platinum bimetallic material. The shape of the nanoparticles is substantially defined by the particle shape of the core portion. The nanoparticles may be dispersed on a high surface area substrate for use as a catalyst and is characterized by no significant loss in surface area and specific activity following extended potential cycling.
    Type: Grant
    Filed: April 5, 2010
    Date of Patent: May 15, 2012
    Assignee: UChicago Argonne, LLC
    Inventors: Vojislav Stamenkovic, Nenad M. Markovic, Chao Wang, Hideo Daimon, Shouheng Sun
  • Patent number: 8173306
    Abstract: A catalyst is provided and includes fine catalyst particles of a composition represented by formula (1): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Hf, W, Ni, and V; u, x, y, and z are 10 to 98.9 atm %, 0.1 to 50 atm %, 0.5 to 35 atm %, and 0.5 to 35 atm %, respectively, or formula (2): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Ct, Mo, Nb, Zr, and T; u, x, y, and z are 40 to 70 atm %, 0.1 to 50 atm %, 0.5 to 15 atm %, and 0.5 to 15 atm %, respectively.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: May 8, 2012
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Itsuko Mizutani, Wu Mei, Taishi Fukazawa, Takahiro Sato, Yoshihiko Nakano
  • Patent number: 8158276
    Abstract: Disclosed are magnetic thin films, sputtering targets and vapor deposition materials, each of which is composed of 40-60 at % of Pt, 40-60 at % of Fe, 0.05-1.0 at % of P and furthermore depending on the occasions, 0.4-19.5 at % of Cu and/or Ni.
    Type: Grant
    Filed: August 3, 2007
    Date of Patent: April 17, 2012
    Assignee: Ishifuku Metal Industry Co., Ltd.
    Inventor: Koichi Hasegawa
  • Patent number: 8133432
    Abstract: Provided is a conductive material to be used for a resistor and a sensor, which is enhanced its mechanical strength while maintaining a stable resistance ratio. In the conductive material used for the resistor and the sensor, 400 to 10,000 ppm of Sr is contained in Pt, and the balance is an inevitable impurity. An intermetallic compound phase formed of Pt and Sr is precipitated and dispersed in Pt.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: March 13, 2012
    Assignee: Ishifuku Metal Industry Co., Ltd.
    Inventor: Koichi Hasegawa
  • Publication number: 20110318662
    Abstract: The present disclosure relates to a catalyst including platinum phosphide having a cubic structure, a method of making the catalyst, and a fuel cell utilizing the catalyst. The present disclosure also relates to method of making electrical power utilizing a PEMFC incorporating the catalyst. Also disclosed herein is a catalyst including a platinum complex wherein platinum is complexed with a nonmetal or metalloid. The catalyst with the platinum complex can exhibit good electro-chemically active properties.
    Type: Application
    Filed: March 12, 2010
    Publication date: December 29, 2011
    Applicants: FORD MOTOR COMPANY, DAIMLER AG
    Inventors: Natalia Kremliakova, Scott McDermid, Stephen Campbell
  • Patent number: 8076261
    Abstract: The present invention features a method for preparing a PtCo nanocube catalyst, the method comprising dissolving a platinum (Pt) precursor, a cobalt (Co) precursor, a surface stabilizer and a reducing agent in a solvent to prepare a solution; heating the solution under an inert gas atmosphere; maintaining the temperature of the solution to obtain PtCo alloy nanocubes; adsorbing the PtCo alloy nanocubes on a carbon support to obtain a catalyst; and removing the surface stabilizer from the catalyst. The disclosed method for preparing a PtCo nanocube catalyst enables preparation of nanocubes with uniform size and cubic shape through a simple process and application for development of high-efficiency fuel cells by preventing change in shape, surface area and composition caused by agglomeration of the nanocubes.
    Type: Grant
    Filed: July 20, 2010
    Date of Patent: December 13, 2011
    Assignees: Hyundai Motor Company, Korea Advanced Institute of Science and Technology
    Inventors: Inchul Hwang, Nak Hyun Kwon, Jae Seung Lee, Joon Taik Park, Sang-Il Choi
  • Patent number: 8071503
    Abstract: An electrocatalyst, suitable for use in a fuel cell, comprises an alloy having a single crystalline phase, wherein the alloy consists of 5-95 at % palladium, 5-95 at % ruthenium and less than 10 at % of other metals, provided that the alloy does not consist of 50 at % palladium and 50 at % ruthenium.
    Type: Grant
    Filed: July 20, 2007
    Date of Patent: December 6, 2011
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Janet Mary Fisher, David Thompsett
  • Patent number: 7993762
    Abstract: The present invention relates to a magnetic thin film containing a L11 type Co—Pt—C alloy in which atoms are orderly arranged, and can realize an order degree excellent in regard to the L11 type Co—Pt—C alloy to achieve excellent magnetic anisotropy of the magnetic thin film. Therefore, in the various application devices using the magnetic thin film, it is possible to achieve a large capacity process and/or a high density process thereof in a high level.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: August 9, 2011
    Assignees: Tohoku University, Fuji Electric Device Technology Co., Ltd.
    Inventors: Takehito Shimatsu, Hideo Sato, Osamu Kitakami, Satoshi Okamoto, Hajime Aoi, Hiroyasu Kataoka
  • Patent number: 7923402
    Abstract: A method of producing a finely divided ruthenium-platinum alloy catalyst comprising: (i) forming a mixture of platinum ?-diketone and ruthenium ?-diketone on a carbon support, (ii) both, platinum ?-diketone and ruthenium ?-diketone having a decomposition temperature within 20° C. of each other, (iii) decomposing said platinum ?-diketone and ruthenium ?-diketone on a carbon support at a temperature of at least 260° C. in the absence of a reducing agent (iv) followed by a reduction effected with a hydrogen containing gas mixture and a method from oxidizing methanol.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: April 12, 2011
    Assignee: BASF Fuel Cell GmbH
    Inventors: Lixin Cao, Yu-Min Tsou, Emory De Castro
  • Patent number: 7910512
    Abstract: To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less. A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: March 22, 2011
    Assignee: Cataler Corporation
    Inventors: Hiroaki Takahashi, Sozaburo Ohashi, Tetsuo Kawamura, Yousuke Horiuchi, Toshiharu Tabata, Tomoaki Terada, Takahiro Nagata, Susumu Enomoto
  • Publication number: 20110064825
    Abstract: The present invention is directed to a method for preparing colloidal dispersions of precious metal nanoparticles selected from the group consisting of Pt, Au, Pd, Ag, Rh, Ru and mixtures or alloys thereof, and to a method for isolating such precious metal nanoparticles from these colloidal dispersions. The colloidal dispersions are prepared by reducing suitable precious metal precursor compounds in aqueous alkaline solutions at reaction temperatures between 40 and 70° C. and a pH?12.0 in the presence of polysaccharides with average molecular weights (Mw) in the range of 300,000 to 1,000,000. The precious metal nanoparticles are isolated after decomposing the polysaccharide by heating the colloidal dispersions to temperatures >80° C. The nanoparticles can be used for the manufacture of core/shell-type catalyst materials and for electronic, decorative and medical applications.
    Type: Application
    Filed: January 9, 2009
    Publication date: March 17, 2011
    Applicant: Umicore AG & Co. KG
    Inventors: Dan V. Goia, Benjamin Morrow, Egon Matijevic, Krishna Balantrapu, Brendan P. Farrell
  • Publication number: 20110020170
    Abstract: The invention relates to metal nanoparticles and a process for the preparation thereof, in which a metal salt solution is reduced with a reducing agent in the presence of the derivatized polyethyleneimines or polyvinylamines. Metal salt solutions of two or more different metals can be reduced simultaneously or in succession, metal nanoparticles comprising two or more different metals being obtained. Preferred metals are silver, palladium, and platinum. Suitable reducing agents are, for example, formic acid, formaldehyde, diethanolamine, 5-pentenoic acid and sodium borohydride. Silver can be used in the form of silver oxide and/or silver nitrate, palladium in the form of alkali metal tetrachloropalladate or palladium(II) nitrate and platinum in the form of alkali metal tetrachloroplatinate or tetraamineplatinum(II) nitrate.
    Type: Application
    Filed: March 17, 2009
    Publication date: January 27, 2011
    Applicant: BASF SE
    Inventors: Gerrit Luinstra, Wolfgang Schrof, Udo Gödert, Robert Feuerhake, Tobias Joachim Koplin, Imme Domke
  • Patent number: 7875569
    Abstract: A supported catalyst includes a carbonaceous catalyst support and first metal-second metal alloy catalyst particles adsorbed on the surface of the carbonaceous catalyst support, wherein the difference between a D10 value and a D90 value is in the range of 0.1 to 10 nm, wherein the D10 value is a mean diameter of a randomly selected 10 wt % of the first metal-second metal alloy catalyst particles and the D90 value is a mean diameter of a randomly selected 90 wt % of the alloy catalyst particles. The supported catalyst has excellent membrane efficiency in electrodes for fuel cells due to uniform alloy composition of a catalyst particle and supported catalysts that do not agglomerate.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: January 25, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Victor Roev, Sang-hyuk Suh, Kyung-jung Kwon, Hae-kyoung Kim
  • Patent number: 7846862
    Abstract: A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula 1: PtxRuyTzQu ??formula 1 In the formula 1, the T-element is at least one selected from a group consisting of Mo, W and V and the Q-element is at least one selected from a group consisting of Nb, Cr, Zr and Ti, x is 40 to 90 at. %, y is 0 to 9.9 at. %, z is 3 to 70 at. % and u is 0.5 to 40 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: December 7, 2010
    Assignees: Kabushiki Kaisha Toshiba, Intematix Corporation
    Inventors: Wu Mei, Taishi Fukazawa, Itsuko Mizutani, Tsuyoshi Kobayashi, Yoshihiko Nakano, Mina Farag, Yi-Qun Li, Shinji Aoki