Iron Or Cobalt Containing Patents (Class 420/496)
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Patent number: 10772680Abstract: One aspect relates to an ablation electrode for high-frequency ablation in medical technology, whereby the ablation electrode includes a gold alloy. One aspect relates to a catheter tip for use with a catheter device, including an ablation electrode, as well as a catheter device for high-frequency ablation, including a catheter tip, as well as the use of an ablation electrode, a catheter tip or a catheter device for high-frequency ablation; as well as a process for production of an ablation electrode.Type: GrantFiled: July 14, 2017Date of Patent: September 15, 2020Assignee: Heraeus Deutschland GmbH & Co. KGInventors: Christiane Leitold, Thorsten Keller, Lydia Buckow, Christian Hammermeister, Winfried Krämer
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Publication number: 20150004052Abstract: A copper alloy having high strength and a high electrical conductivity in combination and a copper alloy wire are provided. A copper alloy contains 50 percent by mass or more and 95 percent by mass or less of Cu, 5 percent by mass or more and 50 percent by mass or less of Fe, and the remainder composed of deoxidizer elements and incidental impurities and has a texture exhibiting large diffraction peaks in the <111> orientation of Cu and in the <110> orientation of Fe when a cross-section is subjected to X-ray diffraction. The intensity ratio ICu( 111) of the diffraction peak in the <111> orientation of Cu to the intensity of the whole diffraction lines of Cu is 0.70 or more and 1.0 or less and the intensity ratio IFe(110) of the diffraction peak in the <110> orientation of Fe to the intensity of the whole diffraction lines of Fe is 0.90 or more and 1.0 or less.Type: ApplicationFiled: December 28, 2012Publication date: January 1, 2015Inventors: Hiromu Izumida, Kenichi Shimizu, Shinei Takamura
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Patent number: 8790549Abstract: An object of the present invention is to provide an electronic component using a Cu-based conductive material that can suppress oxidization even in a heat treatment in an oxidizing atmosphere and that can suppress an increase in an electrical resistance. In an electronic component having an electrode or a wiring, a ternary alloy made from three elements consisting of Cu, Al, and Co is used as a Cu-based wiring material that can prevent oxidization of the electrode or the wiring. Specifically, part or the whole of the electrode or the wiring has a chemical composition in which an Al content is 10 at % to 25 at %, a Co content is 5 at % to 20 at %, and the balance is composed of Cu and unavoidable impurities, and the chemical composition represents a ternary alloy in which two phases of a Cu solid solution formed by Al and Co being dissolved into Cu and a CoAl intermetallic compound coexist together.Type: GrantFiled: April 8, 2010Date of Patent: July 29, 2014Assignee: Hitachi, Ltd.Inventors: Takahiko Kato, Takashi Naito, Hiroki Yamamoto, Takuya Aoyagi, Seiichi Watanabe, Seiji Miura, Norihito Sakaguchi, Kazuki Aoshima, Kenji Ohkubo
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Publication number: 20140199204Abstract: There are provided a cuprous oxide powder having a smaller particle diameter than that of conventional cuprous oxide powders, and a method for producing the cuprous oxide powder by a chemical reducing process. In a method for producing a cuprous oxide powder by adding a reducing agent, such as a reducing sugar, to a solution containing copper hydroxide, which is formed by adding one of an alkali solution and a copper ion containing solution to the other thereof, to deposit cuprous oxide particles by reduction, 0.00001 to 0.04 moles (10 to 40000 ppm) of ferrous ions with respect to the amount of copper ions in the copper ion containing solution are added to the copper ion containing solution before forming copper hydroxide, to produce a cuprous oxide powder which has a mean primary particle diameter of not greater than 0.5 micrometers when it is measured by a scanning electron microscope (SEM), the cuprous oxide powder having a 50% particle diameter (D50 diameter) of not greater than 0.Type: ApplicationFiled: September 13, 2012Publication date: July 17, 2014Applicant: DOWA ELECTRONICS MATERIALS CO., LTD.Inventors: Yuki Kaneshiro, Shinichi Suenaga, Akihiro Asano
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Publication number: 20140193655Abstract: Provided is a copper alloy plate that is for an FPC substrate and that has superior heat dissipation, repeated bending workability, shape retaining properties, and heat resistance. The copper alloy plate contains at least 0.01 mass % of the total of at least one element selected from the group consisting of Ag, Cr, Fe, In, Ni, P, Si, Sn, Ti, Zn, and Zr, contains no more than 1.0 mass % of Ag, no more than 0.08 mass % of Ti, no more than 2.0 mass % of Ni, no more than 3.5 mass % of Zn, and no more than 0.5 mass % of Cr, Fe, In, P, Si, Sn, and Zr by the total of the at least one element selected from the group, the remainder comprising Cu and impurities, has a conductivity of at least 60% IACS, has a tensile strength of at least 350 MPa, and has I(311)/IO(311) determined by X-ray diffraction in the thickness direction of the plate surface that satisfies the formula I(311)/IO(311)?0.5.Type: ApplicationFiled: February 28, 2012Publication date: July 10, 2014Applicant: JX NIPPON MINING & METALS CORPORATIONInventor: Ikuya Kurosaki
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Patent number: 8715431Abstract: A Cu—Fe—P copper alloy sheet which has the high strength and the high electrical conductivity compatible with excellent bendability is provided. The Cu—Fe—P copper alloy sheet contains 0.01% to 3.0% of Fe and 0.01% to 0.3% of P on a percent by mass basis, wherein the orientation density of the Brass orientation is 20 or less and the sum of the orientation densities of the Brass orientation, the S orientation, and the Copper orientation is 10 or more and 50 or less in the microstructure of the copper alloy sheet.Type: GrantFiled: August 11, 2005Date of Patent: May 6, 2014Assignee: Kobe Steel, Ltd.Inventors: Yasuhiro Aruga, Katsura Kajihara
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Publication number: 20130149189Abstract: The present invention is a Cu—Fe—P system copper alloy plate comprising Fe: 0.02-0.5% and P: 0.01-0.25% in mass % with the balance consisting of copper and unavoidable impurities and having the ratio Fe/P of Fe to P in mass % being 2.0 to 5.0, wherein: a ratio of the area of fine crystal grains less than 0.5 ?m in equivalent circle diameter to an observation area when a surface is observed by EBSD analysis is 0.90 or less; and the ratio C1s/Cu2p of a peak area of C1s to a peak area of Cu2p on the surface by XPS analysis is 0.35 or less.Type: ApplicationFiled: November 20, 2012Publication date: June 13, 2013Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventor: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
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Publication number: 20120270069Abstract: A method for making a coated article includes the steps of: providing a substrate; forming a copper-iron target by a hot isostatic pressing process using copper powder and iron powder; forming a copper-iron alloy layer on the substrate by vacuum sputtering using the copper-iron target. A coated article is also described.Type: ApplicationFiled: September 15, 2011Publication date: October 25, 2012Applicants: HON HAI PRECISION INDUSTRY CO., LTD., HONG FU JIN PRECISION INDUSTRY (ShenZhen) CO.,LTD.Inventors: HSIN-PEI CHANG, WEN-RONG CHEN, HUANN-WU CHIANG, CHENG-SHI CHEN, SHUN-MAO LIN
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Patent number: 8293033Abstract: A rolled copper foil consisted of at least either of silicon (Si) and iron (Fe), boron (B), silver (Ag), oxygen (O) of 0.002 mass % or less, and a balance consisted of copper (Cu) and inevitable impurities.Type: GrantFiled: December 17, 2010Date of Patent: October 23, 2012Assignee: Hitachi Cable, Ltd.Inventors: Takemi Muroga, Satoshi Seki, Noboru Hagiwara
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Publication number: 20120039743Abstract: A Cu—Fe—P alloy sheet that is provided with the high strength and with the improved resistance of peel off of oxidation film, in order to deal with problems such as package cracks and peeling, is provided. A copper alloy sheet for electric and electronic parts according to the present invention is a copper alloy sheet containing Fe: 0.01 to 0.50 mass % and P: 0.01 to 0.15 mass %, respectively, with the remainder of Cu and inevitable impurities. A centerline average roughness Ra is 0.2 ?m or less and a maximum height Rmax is 1.5 ?m or less, and Kurtosis (degree peakedness) Rku of roughness curve is 5.0 or less, in measurement of the surface roughness of the copper alloy sheet in accordance with JIS B0601.Type: ApplicationFiled: October 27, 2011Publication date: February 16, 2012Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yasuhiro ARUGA, Ryoichi Ozaki, Yosuke Miwa
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Publication number: 20120039742Abstract: A Cu—Fe—P alloy sheet that is provided with the high strength and with the improved resistance of peel off of oxidation film, in order to deal with problems such as package cracks and peeling, is provided. A copper alloy sheet for electric and electronic parts according to the present invention is a copper alloy sheet containing Fe: 0.01 to 0.50 mass % and P: 0.01 to 0.15 mass %, respectively, with the remainder of Cu and inevitable impurities. A centerline average roughness Ra is 0.2 ?m or less and a maximum height Rmax is 1.5 ?m or less, and Kurtosis (degree peakedness) Rku of roughness curve is 5.0 or less, in measurement of the surface roughness of the copper alloy sheet in accordance with JIS B0601.Type: ApplicationFiled: October 27, 2011Publication date: February 16, 2012Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd)Inventors: Yasuhiro ARUGA, Ryoichi Ozaki, Yosuke Miwa
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Publication number: 20120039741Abstract: A Cu—Fe—P alloy sheet that is provided with the high strength and with the improved resistance of peel off of oxidation film, in order to deal with problems such as package cracks and peeling, is provided. A copper alloy sheet for electric and electronic parts according to the present invention is a copper alloy sheet containing Fe: 0.01 to 0.50 mass % and P: 0.01 to 0.15 mass %, respectively, with the remainder of Cu and inevitable impurities. A centerline average roughness Ra is 0.2 ?m or less and a maximum height Rmax is 1.5 ?m or less, and Kurtosis (degree peakedness) Rku of roughness curve is 5.0 or less, in measurement of the surface roughness of the copper alloy sheet in accordance with JIS B0601.Type: ApplicationFiled: October 27, 2011Publication date: February 16, 2012Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yasuhiro ARUGA, Ryoichi OZAKI, Yosuke MIWA
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Patent number: 7998230Abstract: A multi-metal powder, in particular for producing diamond tools comprises iron copper, cobalt and molybdenum whose contents are expressed in the following mass percentages: Fe+Cu+Co+Mo=98 mass %, the rest being oxygen and production impurities, wherein 15%=Cu=35%, 0.03=Mo/(Co+Fe+Mo)=0.10, —Fe/Co=2. A sintered compact is obtained by hot compaction of said multi-metal powder, for example, in the form of a diamond cutting tool.Type: GrantFiled: November 3, 2006Date of Patent: August 16, 2011Assignee: Eurotungstene PoudresInventors: Maxime Bonneau, Jean-François Lartigue, Thierry Commeau, Christian Huet
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Patent number: 7910512Abstract: To provide a production process of an electrode catalyst for fuel cell whose initial voltage is high and whose endurance characteristics, especially, whose voltage drop being caused by high-potential application is less. A production process according to the present invention of an electrode catalyst for fuel cell is characterized in that: it includes: a dispersing step of dispersing a conductive support in a solution; a loading step of dropping a platinum-salt solution, a base-metal-salt solution and an iridium-salt solution to the resulting dispersion liquid, thereby loading respective metallic salts on the conductive support as hydroxides under an alkaline condition; and an alloying step of heating the conductive support with metallic hydroxides loaded in a reducing atmosphere to reduce them, thereby alloying them.Type: GrantFiled: September 26, 2008Date of Patent: March 22, 2011Assignee: Cataler CorporationInventors: Hiroaki Takahashi, Sozaburo Ohashi, Tetsuo Kawamura, Yousuke Horiuchi, Toshiharu Tabata, Tomoaki Terada, Takahiro Nagata, Susumu Enomoto
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Patent number: 7883588Abstract: In a Cu—Bi based sintered alloy, to which hard particles, such as Fe3P, are added, the main constituent components of the microstructure are a Cu matrix, Bi phase and the hard particles. In the sintering method of the present invention, the flow of the Bi phase is suppressed to as low level as possible. The novel structure is that the contact between the Bi phase and hard particles is kept to a low ratio. A lead-free bearing used for a fuel injection pump according to the present invention contains from 1 to 30 mass % of Bi and from 0.1 to 10 mass % of hard particles having from 10 to 50 ?m of the average particle diameter, the balance being Cu and unavoidable impurities. The properties of the main component phases are utilized at a high level such that the sliding properties are equivalent to those of a Pb containing Cu-based sintered alloy.Type: GrantFiled: June 9, 2005Date of Patent: February 8, 2011Assignees: Taiho Kogyo Co., Ltd., Denso CorporationInventors: Hiromi Yokota, Daisuke Yoshitome, Hiroaki Hayakawa, Naruhiko Inayoshi, Youichi Murakami, Masashi Suzuki, Takahiro Nozu
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Patent number: 7842288Abstract: A marine anti-bio-fouling coating 10, for application onto the surface of a marine article 12. The coating 10 comprises a self-levelling, self-curing epoxy resin primer adhesive 14, an adhesive modified epoxy resin binder adhesive 16 and granulated Copper Nickel alloy 18. When a coated marine article 12 is immersed in water a chemical reaction occurs between the water and the Copper Nickel alloy 18 which causes a film of a complex metal oxide 20 to form on the exterior surface of the layer of Copper Nickel alloy granules 18. The oxide film 20 forms an inhospitable environment to aquatic organisms and aquatic borers, thereby preventing bio-fouling occurring on the coated marine article. A method of applying the coating 10 to a marine article 12 is also provided.Type: GrantFiled: December 10, 2004Date of Patent: November 30, 2010Inventor: Gareth Weed
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Publication number: 20100284852Abstract: Equestrian bits are manufactured with the mouthpiece component comprising a copper alloy with composition; 65-80% by weight copper, 0-2% tin and the remainder being zinc including other elements. In a further embodiment, the copper alloy comprises 70-73% copper, 0.9-1.2% tin, 28% zinc the remainder being other elements at a %, by weight, of less than 1%. The alloy of the invention provides a horse bit mouthpiece which rapidly achieves thermal equilibration when placed in, or moved within, the mouth and has characteristic strength sufficient for the intended use.Type: ApplicationFiled: September 10, 2008Publication date: November 11, 2010Inventor: Graham Hugh Cross
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Publication number: 20100206509Abstract: Described are wrought forms of copper alloys for infiltrating powder metal parts, the method for preparing the copper alloys and their wrought forms, the method for their infiltration into a powder metal part, and the infiltrated metal part infiltrated with the novel alloys having a generally uniform distribution of copper throughout and exhibiting high transverse rupture strength, tensile strength and yield strength. Infiltrated metal parts prepared by infiltrating powder metal parts with reduced amounts of the novel infiltrant typically weigh less and have superior strengths compared to similarly prepared infiltrated metal parts prepared with standard methods and conventional infiltration.Type: ApplicationFiled: July 31, 2009Publication date: August 19, 2010Inventor: Paul Rivest
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Patent number: 7736448Abstract: The present invention relates to a nanocrystalline metallic material, particularly to nano-twin copper material with ultrahigh strength and high electrical conductivity and its preparation method. High-purity polycrystalline Cu material with a microstructure of roughly equiaxed submicron-sized grains (300-1000 nm) has been produced by pulsed electrodeposition technique, by which high density of growth-in twins with nano-scale twin spacing were induced in the grains. Inside each grain, there are high densities of growth-in twin lamellae. The twin lamellae with the same orientations are inter-parallel, and the twin spacing ranges from several nanometers to 100 nm with a length of 100-500 nm. This Cu material invented has more excellent performance than existing ones.Type: GrantFiled: October 16, 2003Date of Patent: June 15, 2010Assignee: Institute of Metal Research Chinese Academy of SciencesInventors: Lei Lu, Xiao Si, Yongfeng Shen, Ke Lu
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Patent number: 7678173Abstract: In a Pb-free copper-based sintered alloy containing from 1 to 30% of Bi and from 0.1 to 10% of hard matter particles having from 10 to 50 ?m of average particle diameter, the Bi phase has a smaller average particle diameter than that of the hard matter particles and is dispersed in the Cu matrix, or the hard matter particles having 50% or less of a contact length ratio with the Bi phase based on the total circumferential length of the hard particle, which are in contact with said Bi phase, are present in a ratio of 70% or more based on the entire number of the hard matter particles.Type: GrantFiled: January 13, 2005Date of Patent: March 16, 2010Assignee: Taiho Kogyo Co., Ltd.Inventors: Hiromi Yokota, Daisuke Yoshitome, Hiroaki Kobayashi, Hiroyuki Kawaguti
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Publication number: 20100061884Abstract: Disclosed is a white-colored copper alloy comprising by weight up to 30% zinc, up to 20% manganese, up to 5% nickel with the balance copper. This alloy may have from 6% to 25% zinc, from 4% to 17% manganese, from 0.1% to 3.5% nickel and the balance copper. The balance copper in the alloy may further contain at least one of: up to 0.5% of at least one of the group which consists of Sn, Si, Co, Ti, Cr, Fe, Mg, Zr, and Ag; and up to 0.1% of at least one of the group which consists of P, B, Ca, Ge, Se, Te. It may also contain up to 0.3% Zr by weight. The alloy may have an electrical conductivity greater than 2.5% IACS at eddy current gauge exciting frequencies between 60 kHz and 480 kHz.Type: ApplicationFiled: September 8, 2009Publication date: March 11, 2010Applicant: PMX INDUSTRIES INC.Inventors: CRAIG CLARK, THOMAS D. JOHNSON, RICHARD PRATT, TIMOTHY SUH
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Patent number: 7666246Abstract: Hard phase particles including Co alloy particles, carbide alloy particles, and silicide particles are dispersed substantially uniformly throughout a matrix composed of Cu self-fluxing alloy of a cladded portion. The cladded portion contains 6 to 15% by weight of Co, 3 to 8% by weight of one of Cr and Mo, 0.3 to 1% by weight of W, 0.5 to 1.8% by weight of Fe, 8 to 15% by weight of Ni, 0.08 to 0.2% by weight of C, 1.5 to 4% by weight of Si, 0.5 to 0.8% by weight of Al, and 0.1 to 0.3% by weight of P, and inevitable impurities and Cu as a balance. The hard phase particles have an average particle diameter of 8 to 20 ?m and a particle size distribution width of 0.1 to 100 ?m, and to occupy 10 to 20% in an arbitrary cross section of the cladded portion.Type: GrantFiled: August 21, 2006Date of Patent: February 23, 2010Assignee: Honda Motor Co., Ltd.Inventors: Shogo Matsuki, Yositaka Tsujii
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Publication number: 20090311128Abstract: A shear plane ratio is reduced by a dislocation density in which a value obtained by dividing the half-value width ? of the intensity of diffraction of {311} plane in the surface of a Cu—Fe—P alloy sheet, by its peak height H, is 0.015 or more. In addition, a Cu—Fe—P alloy sheet with relatively small Fe content is provided with a texture in which a ratio (I(200)/I(220)) of intensity of diffraction of (I(200)) from the (200) plane in the sheet surface to intensity of diffraction of (I(220)) from the (220) plane, is 0.3 or less. In addition, a Cu—Fe—P alloy sheet with relatively small Fe content is provided with a texture in which the orientation distribution density of Brass orientation measured by the crystal orientation analysis method using an EBSP by an FE-SEM, is 25% or more; and an average grain size in the sheet is 6.0 ?m or less.Type: ApplicationFiled: June 20, 2007Publication date: December 17, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho(Kobe Steel, Ltd)Inventors: Yasuhiro Aruga, Ryoichi Ozaki, Yosuke Miwa
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Publication number: 20090224379Abstract: A QFN package is provided with a lead frame formed by processing a copper alloy sheet containing 0.01 to 0.50% by mass Fe, 0.01 to 0.20% by mass P, and Cu and inevitable impurities as other components, having a micro Vickers hardness of 150 or above, a uniform elongation of 5% or below and a local elongation of 10% or below, or a copper alloy sheet containing 0.05 to 2% by mass Ni, 0.001 to 0.3% by mass P, 0.005 to 5% by mass Zn, and Cu and inevitable impurities as other components, having a micro Vickers hardness of 150 or above, a uniform elongation of 5% or below and a local elongation of 10% or below. Lead burrs formed during the dicing of the QFN package are short, and a dicing blade used for dicing the QFN package is abraded at a low wear-out rate.Type: ApplicationFiled: February 2, 2009Publication date: September 10, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel Ltd.)Inventors: Yosuke MIWA, Masayasu Nishimura, Ryoichi Ozaki, Shinya Katsura
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Publication number: 20090142010Abstract: Provided are a sintered metal material improved in sliding property and wear resistance with respect to an associated sliding member to be supported, and a sintered oil-impregnated bearing formed of this metal material. A bearing sleeve is formed by compacting a mixed metal powder composed of not less than 5 wt % and not more than 94.3 wt % of Cu powder, not less than 5 wt % and not more than 94.3 wt % of SUS powder, not less than 0.2 wt % and not more than 10 wt % of Sn powder, and not less than 0.5 wt % and not more than wt % of graphite, and then performing sintering on a compact of the mixed metal powder.Type: ApplicationFiled: December 27, 2005Publication date: June 4, 2009Applicant: NTN CORPORATIONInventors: Fuyuki Ito, Kazuo Okamura, Toshihiko Tanaka
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Publication number: 20090010797Abstract: A Cu—Fe—P copper alloy sheet which has the high strength and the high electrical conductivity compatible with excellent bendability is provided. The Cu—Fe—P copper alloy sheet contains 0.01% to 3.0% of Fe and 0.01% to 0.3% of P on a percent by mass basis wherein the orientation density of the Brass orientation is 20 or less and the sum of the orientation densities of the Brass orientation, the S orientation, and the Copper orientation is 10 or more and 50 or less in the microstructure of the copper alloy sheet.Type: ApplicationFiled: August 11, 2005Publication date: January 8, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yasuhiro Aruga, Katsura Kajihara
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Publication number: 20080095658Abstract: [PROBLEMS] To provide a Cu—Bi—hard substance base sintered alloy in which the respective properties of Bi and hard substance can be satisfactorily exerted. [MEANS FOR SOLVING PROBLEMS] There is provided a Ph free copper base sintered alloy, comprising 1 to 30% of Bi and 0.1 to 10% of hard substance particles of 10 to 50 ?m average diameter, (1) wherein a Bi phase having an average particle diameter smaller than that of the hard substance particles is dispersed in a matrix of Cu, or wherein with respect to a Bi phase in contact with the hard substance particles, the ratio of presence of hard substance particles exhibiting a ratio of hard substance particle contact length to entire circumference of Bi phase of 50% or less is 70% or greater based on the total number of hard substance particles.Type: ApplicationFiled: January 13, 2005Publication date: April 24, 2008Inventors: Hiromi Yokota, Daisuke Yoshitome, Hiroaki Kobayashi, Hiroyuki Kawaguti
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Publication number: 20080075625Abstract: The invention relates to a conductive material consisting of an alloy that contains copper, for use as a plug-in or clip connection. Said material comprises a cover layer that is deposited on at least some sections of the contact surface, said layer consisting at least of a support layer and an adhesive layer. The anti-friction layer has a carbon content greater or less than 40 and less than or equal to 70 atomic percent.Type: ApplicationFiled: June 15, 2005Publication date: March 27, 2008Applicants: OC OERLIKON BALZERS AG, WIELAND-WERKE AGInventors: Thomas Jabs, Michael Scharf, Martin Grischke, Orlaw Massler
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Patent number: 7180176Abstract: Heat dissipating plate (4) made of copper-base alloy is proposed that exhibits high degree of flatness after joining in the step of assembling power semiconductor modules, IC packages, etc., that will not crack in the solder (3) joint if subjected to heat cycles during joining or in an environment of use, and that has high heat conductivity and cost effectiveness. The heat dissipating plate (4) uses a copper-base alloy having a 0.2% yield strength of at least 300 N/mm2 which is characterized in that the 0.2% yield strength after heating at 400° C. for 10 minutes is at least 90% of the 0.2% yield strength before heating and that said copper-base alloy has a heat conductivity of at least 350 W/m·K and contains at least one element of the group consisting of Fe, Co and Ni plus P in a total amount of 0.01–0.3%; the heat dissipating plate (4) is 10–200 mm long on each side, 0.Type: GrantFiled: August 22, 2002Date of Patent: February 20, 2007Assignee: Dowa Mining Co., Ltd.Inventors: Hideki Endou, Shingo Yanase
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Publication number: 20030159763Abstract: An age-hardenable copper alloy made of 1.2 to 2.7% cobalt, which is able to be partially replaced by nickel, 0.3 to 0.7% beryllium, 0.01 to 0.5% zirconium, optionally 0.005 to 0.1% magnesium and/or iron and in some instances up to a maximum of 0.15% of at least one element from the group including niobium, tantalum, vanadium, hafnium, chromium, manganese, titanium and cerium. The remainder is copper and includes production-conditioned impurities and usual processing additives. This copper alloy is used as the material for producing mold blocks for the side dams of continuous strip-casting installations.Type: ApplicationFiled: February 10, 2003Publication date: August 28, 2003Inventors: Thomas Helmenkamp, Dirk Rode
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Patent number: 6413649Abstract: The present invention is directed to brazing filler metals that can be used in the infiltration brazing of porous matrix materials without the need for a flux. The brazing filler metals contain two different Group II metals and a third metal of Group 9 and 10. A particular brazing filler metal of the invention contains silver, copper, and nickel. The invention is also directed to composite materials formed by infiltration of the brazing material into a porous matrix, and to methods for preparing the composite materials. The invention is further directed to composite articles fabricated from composite materials, including steel bearings or bushings, and to methods of preparing the composite articles.Type: GrantFiled: March 6, 1998Date of Patent: July 2, 2002Assignee: The Morgan Crucible Company plcInventors: David J. Kepniss, Toshimasa Oyama
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Patent number: 6391163Abstract: The present invention provides a method and apparatus for forming a copper layer on a substrate, preferably using a sputtering process. The sputtering process involves bombarding a conductive member of enhanced hardness with ions to dislodge the copper from the conductive member. The hardness of the target may be enhanced by alloying the copper conductive member with another material and/or mechanically working the material of the conductive member during its manufacturing process in order to improve conductive member and film qualities. The copper may be alloyed with magnesium, zinc, aluminum, iron, nickel, silicon and any combination thereof.Type: GrantFiled: March 2, 2000Date of Patent: May 21, 2002Assignee: Applied Materials, Inc.Inventors: Vikram Pavate, Murali Abburi, Murali Narasimhan, Seshadri Ramaswami
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Publication number: 20020044881Abstract: A copper alloy having improved stress relaxation resistance is formed from a copper base alloy that consists, by weight, essentially of 1.8%-3.0% iron, 0.01%-1.0% zinc, 0.001 %-0.25% phosphorus, 0.1 %-0.35% magnesium and the balance is copper and unavoidable impurities. When compared to other copper base alloys that include iron, zinc and phosphorous, the disclosed alloy has improved resistance to stress relaxation. In addition, directionality of stress relaxation resistance (where stress relaxation resistance is typically poorer in a transverse strip direction relative to a longitudinal strip direction for a copper alloy that is strengthened by cold rolling) is reduced to being nearly equivalent, regardless of strip direction. The alloy is particularly useful for electronic applications, such as being formed into an electrical connectors.Type: ApplicationFiled: June 12, 2001Publication date: April 18, 2002Applicant: OLIN CORPORATIONInventors: John F. Breedis, Dennis R. Brauer, Peter W. Robinson
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Patent number: 6280541Abstract: A seamless pipe made of copper alloy consisting of, by weight % , a total amount of 0.02 to 0.2% of Co, 0.01 to 0.05% of P, 1 to 20 ppm of C if needed, and remainder Cu, and unavoidable impurities and, as said impurities, the total oxygen content is regulated to 50 ppm or less, and useful for a heat transfer pipe of a heat exchanger and especially, when HFC-type fluorocarbon is used as a heating medium.Type: GrantFiled: April 4, 2000Date of Patent: August 28, 2001Assignee: Mitsubishi Materials CorporationInventors: Yuichiro Sudo, Tetsuo Yamaji, Yutaka Saito
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Patent number: 6241831Abstract: The present invention relates to copper-magnesium-phosphorous alloys. In a first embodiment, copper-magnesium-phosphorous alloys in accordance with the present invention consist essentially of magnesium in an amount from about 0.01 to about 0.25% by weight, phosphorous in an amount from about 0.01 to about 0.2% by weight, silver in an amount from about 0.001 to about 0.1% by weight, iron in an amount from about 0.01 to about 0.25% by weight, and the balance copper and inevitable impurities. Preferably, the magnesium to phosphorous ratio is greater than 1.0. In a second embodiment, copper-magnesium-phosphorous alloys in accordance with the present invention consist essentially of magnesium in an amount from about 0.01 to about 0.25% by weight, phosphorous in an amount from about 0.01 to about 0.2% by weight, optionally silver in an amount from about 0.001 to about 0.1% by weight, at least one element selected from the group consisting of nickel, cobalt, and mixtures thereof in an amount from about 0.Type: GrantFiled: June 7, 1999Date of Patent: June 5, 2001Assignee: Waterbury Rolling Mills, Inc.Inventor: Ashok K. Bhargava
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Patent number: 6197432Abstract: A sliding material which is used for bearings, washers and other parts of automobiles, industrial machines, agricultural machines and the like, possesses an excellent abrasion resistance, and is useful under sever boundary lubricating conditions. The sliding material comprises a back plate (5) of a steel plate and a sinter bearing layer integrally provided on one surface of the back plate (5). A powder (2) of a hard material is dispersed in an amount of 0.5 to 20% by weight in a matrix (4) of the sinter bearing layer. The matrix (4) comprises 1 to 30% by weight of Pb and 1 to 15% by weight of Sn with the balance consisting of Cu. The powder (2) of a hard material comprises 7.5 to 9.5% by weight of Cr, 27 to 30% by weight of Mo, and 2.0 to 3.0% by weight of Si with the balance consisting of Co.Type: GrantFiled: December 29, 1998Date of Patent: March 6, 2001Assignee: NDC Company, Ltd.Inventors: Masahito Fujita, Yasushi Saitou
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Patent number: 6197433Abstract: A rolled copper foil for flexible printed circuits contains not more than 10 ppm by weight of oxygen and has a softening-temperature rise index T defined as T=0.60[Bi]+0.55[Pb]+0.60[Sb]+0.64 [Se]+1.36[S]+0.32[As]+0.09[Fe]+0.02[Ni]+0.76[Te]+0.48[Sn]+0.16[Ag]+1.24[P] (each symbol in the brackets representing the concentration in ppm by weight of the element) in the range of 4 to 34. The concentrations of the elements are in the ranges of[Bi]<5, [Pb]<10, [Sb]<5, [Se]<5, [S]<15, [As]<5, [Fe]<20, [Ni]<20, [Te]<5, [Sn]<20, [Ag]<50, and [P]<15 (each symbol in the brackets representing the concentration in ppm by weight of the element).Type: GrantFiled: January 12, 2000Date of Patent: March 6, 2001Assignee: Nippon Mining & Metals Co., Ltd.Inventor: Takaaki Hatano
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Patent number: 6103188Abstract: We provide a new copper microalloy with high-conductivity, excellent heat resistance and high strain strength, which can be obtained by conventional continuous or semi-continuous casting, which essentially consists of at least one element selected from the following list:______________________________________ 5-800 mg/Kg Pb (lead) 10-100 mg/Kg Sb (antimony) 5-1000 mg/Kg Ag (silver) 5-700 mg/Kg Sn (tin) 1-25 mg/Kg Cd (cadmium) 1-30 mg/Kg Bi (bismuth) 20-500 mg/Kg Zn (zinc) 10-400 mg/Kg Fe (iron) 15-500 mg/Kg Ni (nickel) 1-15 mg/Kg S (sulfur) ______________________________________in all cases, with 20-500 mg/Kg O (oxygen). The alloy is suitable for all the applications that require an electrical conductivity similar to that of pure copper, but with a better heat resistance, better mechanical properties and lower standard deviation values in strain strength.Type: GrantFiled: March 4, 1999Date of Patent: August 15, 2000Assignee: La Farga Lacambra, S.A.Inventors: Jose Oriol Guixa Arderiu, Miquel Garcia Zamora, Ferran Espiell Alvarez, Miquel Angel Fernandez Lopez, Araceli Esparducer Broco, Merce Segarra Rubik, Josep M.sup.a Chimenos Ribera
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Patent number: 6093265Abstract: A copper alloy having improved resistance to stress relaxation contains controlled additions of iron, phosphorous and magnesium. Free magnesium, in solid solution with the copper, increases the alloy's resistance to stress relaxation. Copper alloys of the invention retain at least 70% of the initial stress following exposure to a temperature of 105.degree. C. for 3000 hours, making the alloys particulary useful for electrical connector components.Type: GrantFiled: June 18, 1998Date of Patent: July 25, 2000Assignee: Olin CorporationInventor: William L. Brenneman
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Patent number: 6093499Abstract: Copper alloy foils are provided having far greater strength and heat resistance than conventional copper foils, and having better productivity, are characterized by a composition comprising, all by weight, from 0.01 to 0.4% Cr, from 0.01 to 0.25% Zr, from 0.02 to 2.0% Zn; and when necessary from 0.05 to 1.8% Fe and from 0.05 to 0.8% Ti; and when further necessary one or more elements selected from the group consisting of Ni, Sn, In, Mn, P, Mg, Al, B, As, Cd, Co, Te, Ag, and Hf in a total amount of from 0.005 to 1.5%; the balance being copper and unavoidable impurities. Inclusions in the copper foil not larger than 10 .mu.m in size, and the inclusions between 0.5 and 10 .mu.m in size number less than 100 pieces/mm.sup.2.Type: GrantFiled: April 2, 1999Date of Patent: July 25, 2000Assignee: Nippon Mining & Metals Co., Ltd.Inventor: Yasuo Tomioka
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Patent number: 6083328Abstract: A hardenable copper alloy, suitable as a material for manufacturing casting rolls and casting wheels that are subjected to changing temperature stresses, is disclosed. The hardenable copper alloy comprises 1.0 to 2.6% nickel, 0.1 to 0.45% beryllium, and the remainder of copper, inclusive of impurities resulting from manufacturing and the customary processing additives, and has a Brinell hardness of at least 200 and an electric conductivity of over 38 m/.OMEGA. mm.sup.2.Type: GrantFiled: May 6, 1994Date of Patent: July 4, 2000Assignee: KM Europa Metal AGInventors: Horst Gravemann, Thomas Helmenkamp
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Patent number: 5980656Abstract: A copper alloy achieves high electrical conductivity, in excess of 70% IACS; high strength, ultimate tensile strength in excess of 75 ksi; good surface cosmetics; and good stampability, above 25% break, by controlled additions of magnesium, iron and phosphorous. There is a critical iron content to achieve both good stampability and high electrical conductivity and a critical phosphorous content to achieve high strength and relatively small metal phosphide particles. There is further, a critical relationship between the amount of iron and phosphorous. An additions of magnesium, in amounts of more than 0.03%, broadens the effective ratio of iron to phosphorous, widening the composition box of the alloys of the invention.Type: GrantFiled: July 22, 1997Date of Patent: November 9, 1999Assignee: Olin CorporationInventors: William L. Brenneman, John F. Breedis
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Patent number: 5868877Abstract: A copper alloy having improved resistance to stress relaxation contains controlled additions of iron, phosphorous and magnesium. Free magnesium, in solid solution with the copper, increases the alloy's resistance to stress relaxation. Copper alloys of the invention retain at least 70% of the initial stress following exposure to a temperature of 105.degree. C. for 3000 hours, making the alloys particularly useful for electrical connector components.Type: GrantFiled: July 22, 1997Date of Patent: February 9, 1999Assignee: Olin CorporationInventor: William L. Brenneman
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Patent number: 5858125Abstract: A magnetoresistive material of the present invention has a structure in which many clusters are surrounded by a crystal phase of Cu and/or Ag, where each cluster has a grain size of 20 nm or less and composed of an amorphous phase containing at least one ferromagnetic metal element T as a main component selected from Fe, Co and Ni, and at least one element M selected from Ti, Zr, Hf, V, Nb, Ta, Mo and W.Type: GrantFiled: October 15, 1996Date of Patent: January 12, 1999Assignee: Alps Electric Co., Ltd.Inventor: Naoya Hasegawa
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Patent number: 5489417Abstract: Spray cast copper-manganese-zirconium alloys are disclosed. In one embodiment, the alloy is spray cast in nitrogen and contains from about 1 ppm to about 20 ppm of dissolved nitrogen. In a second embodiment, the alloy contains an addition selected from the group consisting of chromium, titanium, erbium and mixtures thereof. The alloys are useful for sound damping as the combination of zirconium and the addition inhibits degradation of the specific damping capacity of the alloy.Type: GrantFiled: April 14, 1994Date of Patent: February 6, 1996Assignee: Olin CorporationInventors: William G. Watson, Harvey P. Cheskis, Sankaranarayanan Ashok
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Patent number: 5470373Abstract: Oxidation resistant particles composed of copper and at least one metal having a valence of +2 or +3 and having an intermediate lattice energy for the metal in its hydroxide form. The metal is selected from nickel, cobalt, iron, manganese, cadmium, zinc, tin, magnesium, calcium and chromium. In one embodiment, the phases of copper and at least one metal in the particles are separate and the concentration of the metal is greater near the surface of the particles than inwardly thereof. Process for making the oxidation resistant copper particles includes the steps of dissolving a copper salt and a salt of at least one of the metals in a suitable solvent or diluent; forming primary particles of copper and at least one metal in basic form by mixing a base and the salt solution; separating, washing and drying the primary particles; reducing the primary particles to metallic form; and heat treating the particles in metallic form at an elevated temperature.Type: GrantFiled: November 15, 1993Date of Patent: November 28, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Alan S. Edelstein, Forrest H. Kaatz, Vincent G. Harris
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Patent number: 5435828Abstract: A dispersion-strengthened copper alloy is disclosed having an exceptional combination of strength, ductility, and thermal conductivity. The copper alloy comprises: copper, 0.01 to 2.0 weight % boron and 0.1 to 6.0 weight % cobalt, and cobalt-boride disperoids that range in size between 0.025 and 0.25 microns in diameter. A copper alloy is made by rapid solidification of the melt into a powder. Strong, thermally conductive articles can be made by compacting the powder at temperatures below the melting temperature of the copper alloy.Type: GrantFiled: December 21, 1993Date of Patent: July 25, 1995Assignee: United Technologies CorporationInventor: James S. Andrus
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Patent number: 5336342Abstract: A copper based alloy and method for the manufacture thereof having improved properties. The copper alloy contains iron and zirconium with the iron being present as a uniformly dispersed second phase of the dispersoids. The dispersoids have a mean particle size of from about 0.1 micron to about 1.0 micron. The iron is present in the amount of from about 0.25 to about 5.0% by weight.Type: GrantFiled: October 31, 1990Date of Patent: August 9, 1994Assignee: Olin CorporationInventor: Sankaranarayanan Ashok
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Patent number: 5259898Abstract: An alloy, in particular for the manufacture of spectacle frames, and a spectacle wire or a spectacle frame and connecting wires for electronic component parts manufactured using the alloy of the invention. In order to obtain good mechanical characteristics, for example, of the spectacle frame at low expense, the invention provides the following alloy which, in percentage by weight, is composed as follows: 63-78% copper, 3-7% nickel, 1-3% iron, 0.01-0.20% phosphorus, the remainder being zinc.Type: GrantFiled: December 13, 1991Date of Patent: November 9, 1993Assignee: Berkenhoff GmbHInventors: Klaus Tauber, Wolfgang Brandstaetter, Erich Dommer, Juergen Fackert, Bruno Rechtziegel
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Patent number: 5205878Abstract: Electric and electronic parts, including leadframes made of a copper-based alloy having high strength and high electric conductivity said copper-based alloy is produced by a process which comprises the steps of preparing a copper-based alloy consisting essentially of 0.01-3.0 wt % Co and 0.01-0.5 wt % P with the balance being Cu and incidental impurities, quenching said alloy from a temperature not lower than 750.degree. C. down to 450.degree. C. and below at a cooling rate of at least 1.degree. C./sec, heat treating the quenched alloy at a temperature of 480.degree.-600.degree. C. for 30-600 minutes, cold working said alloy for a working ratio of 20-80%, further heat treating the alloy at a temperature of 440.degree.-470.degree. C. for 30-600 minutes, and subsequently performing cold working for a working ratio of at least 50% and heat treatment at 380.degree. C. and below. The electric and electronic parts preferably contain a plurality of conductive leads.Type: GrantFiled: December 16, 1991Date of Patent: April 27, 1993Assignee: Dowa Mining Co., Ltd.Inventors: Toshihiro Kanzaki, Akira Sugawara, Isamu Amatsu, Kouichi Hatakeyama