Copper Containing Patents (Class 420/515)
  • Patent number: 9707664
    Abstract: This invention provides a zinc-based alloy shot having a new formation and it also provides a method of manufacturing it. The zinc-based alloy shot has Cu added, and it is likely to have a relatively high hardness, and it is less likely to corrode (reduce color change) when it functions as a shot. The zinc-based alloy shot of the present invention comprises Cu as the main additive element for increasing the Vickers hardness, etc., and Fe as a co-additive element for increasing the Vickers hardness and for preventing corrosion. It gives a Vickers hardness of 40-150 HV. The chemical composition of the zinc-based alloy shot is usually Cu: 0.1˜13.0%; Fe: 0.0025˜0.25%; Zn: balance; and 1?Cu/Fe (measured in mass)?1000.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: July 18, 2017
    Assignee: SINTOKOGIO, LTD.
    Inventors: Masayuki Ishikawa, Kaoru Hirai
  • Patent number: 8834652
    Abstract: Provided is a zinc base alloy having high strength, and being excellent in toughness and abrasion resistance. The zinc base alloy contains 3.5% by weight or more and 4.5% by weight or less of Al, 3.0% by weight or more and 4.0% by weight or less of Cu, 0.01% by weight or more and 0.08% by weight or less of Mg, 0.005% by weight or more and 0.1% by weight or less of Ca, and, as necessary, 0.005% by weight or more and 0.1% by weight or less of Sr, and balance of Zn and inevitable impurities. Also provided is a die-cast product made from the zinc base alloy.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: September 16, 2014
    Assignee: Nisso Metallochemical Co., Ltd.
    Inventors: Koukichi Takahashi, Satoshi Katagiri
  • Patent number: 8637163
    Abstract: An alloy with a high glass forming ability characterized by containing a group of elements A with atomic radii of less than 0.145 nm of a total of 20 to 85 atm %, a group of elements B with atomic radii of 0.145 nm to less than 0.17 nm of a total of 10 to 79.7 atm %, and a group of elements C with atomic radii of 0.17 nm or more of a total of 0.3 to 15 atm %; when the elements with the greatest contents in the group of elements A, group of elements B, and group of elements C are respectively designated as the “element a”, “element b”, and “element c”, by the ratio of the content of the element a in the group of elements A (for example, Zn and/or Al), the ratio of the content of the element b in the group of elements B (for example, Mg), and the ratio of the content of the element c in the group of elements C (for example, Ca) all being 70 atm % or more; and by the liquid forming enthalpy between any two elements selected from the element a, element b, and element c being negative.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: January 28, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Kohei Tokuda, Koichi Nose, Yuichi Sato, Makoto Nakazawa
  • Publication number: 20120313230
    Abstract: A solder alloy is providing, the solder alloy including zinc, aluminum, magnesium and gallium, wherein the aluminum constitutes by weight 8% to 20% of the alloy, the magnesium constitutes by weight 0.5% to 20% of the alloy and the gallium constitutes by weight 0.5% to 20% of the alloy, the rest of the alloy including zinc.
    Type: Application
    Filed: June 7, 2011
    Publication date: December 13, 2012
    Applicant: INFINEON TECHNOLOGIES AG
    Inventors: Manfred MENGEL, Alexander HEINRICH, Steffen ORSO, Thomas BEHRENS, Oliver EICHINGER, Lim FONG, Evelyn NAPETSCHNIG, Edmund RIEDL
  • Publication number: 20120294756
    Abstract: Shots made from a zinc-based alloy is provided, wherein no risk for explosion caused by powder dusts exists. They achieve a high performance in deflashing and grinding and cleaning by shot blasting and a high ability to create a high compressive residual stress. The lost amounts of them by shooting are small. The shots are made from a zinc-based alloy that contains three components that include A1 of 0.5 to 6.5 mass % and Cu of 0.5 to 4.5 mass % as additional elements, or that contains four components that further include Mg of 0.01 to 0.2 mass % as additional elements, wherein the ratio of the mass of A1 to Cu (A1/Cu) is 1.0 to 13.0, wherein the total amount of A1 and Cu (A1+Cu) is 1.5 to 10.5 mass %, and wherein the Vickers hardness of the shots is 90 to 190 HV.
    Type: Application
    Filed: March 30, 2012
    Publication date: November 22, 2012
    Inventors: Eiji Yamaguchi, Tatsuya Takegami, Suguru Goto, Hayato Taniguchi
  • Publication number: 20110192502
    Abstract: Provided is a zinc base alloy having high strength, and being excellent in toughness and abrasion resistance. The zinc base alloy comprises 3.5% by weight or more and 4.5% by weight or less of Al, 3.0% by weight or more and 4.0% by weight or less of Cu, 0.01% by weight or more and 0.08% by weight or less of Mg, 0.005% by weight or more and 0.1% by weight or less of Ca, and, as necessary, 0.005% by weight or more and 0.1% by weight or less of Sr, and balance of Zn and inevitable impurities. Also provided is a die-cast product made from the zinc base alloy.
    Type: Application
    Filed: February 4, 2011
    Publication date: August 11, 2011
    Applicant: NISSO METALLOCHEMICAL CO. LTD.
    Inventors: Koukichi TAKAHASHI, Satoshi KATAGIRI
  • Publication number: 20110014084
    Abstract: Provided are high strength, creep resistant zinc alloys with superior mechanical and other properties.
    Type: Application
    Filed: November 16, 2009
    Publication date: January 20, 2011
    Applicant: EASTERN ALLOYS, INC.
    Inventors: Ryan WINTER, John MALMGREEN
  • Publication number: 20080149297
    Abstract: The objective of the present invention is to provide a product that is superior in barrier properties (for example, zinc erosion resistance and anti-adhesive property), abrasion resistant property, surface hardening property, thermal stability and life-time prolonging property. The product, which is made in direct contact with molten metal containing zinc in a molten state, is characterized by including an iron-tungsten alloy coating that is applied to a part or the whole of the surface of the product that comes directly in contact with the molten metal.
    Type: Application
    Filed: February 1, 2006
    Publication date: June 26, 2008
    Inventors: Keiji Nakai, Tokumi Ikeda, Takahiro Hamada, Tsutomu Morikawa, Takashi Nishimura, Takuo Nakade
  • Patent number: 6514308
    Abstract: An alloy feedstock for semi-solid metal injection molding. The alloy feedstock is an alloy material in particulate form and has a heterogeneous structure, a temperature range at 20% of the height of the peak of the main melting reaction greater than 40° C., and having a ratio of the height of the peak of the eutectic reaction to the height of the main melting reaction of less than 0.5.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: February 4, 2003
    Assignee: Thixomat, Inc.
    Inventors: Stephen E. LeBeau, D. Matthew Walukas, Raymond F. Decker
  • Patent number: 6139654
    Abstract: Master alloy with 20-80% strontium, preferably 0.01-2.0% of aluminum and/or copper, and the balance essentially zinc plus impurities, and a method for preparing same and a method for modifying the microstructure of nonferrous alloys with said master alloy.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: October 31, 2000
    Assignee: KB Alloys, Inc.
    Inventors: Gary W. Boone, Philip G. Vais, Daniel B. Franklin
  • Patent number: 6071359
    Abstract: Tin and zinc based shot for use as ammunition having a diameter of from 1.5 to 5.5 mm, containing, by weight, in addition to tin and the usual unavoidable contaminants, from 12 to 60% of zinc and from 0 to 5% of aluminum, but less than 0.1% of copper, less than 0.1% of iron, and less than 1% of lead.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: June 6, 2000
    Assignee: Grillo-Werke AG
    Inventors: Jurgen Wisniewski, Jochen Spriestersbach
  • Patent number: 5858132
    Abstract: The invention provides a new method for casting alloys containing a finely divided phase. A bath of the molten metal having a melting point is provided. A finely divided solid metal having a melting point greater than the melting point of molten metal is introduced into the molten metal. The finely divided metal is reacted with the molten metal to form a solid phase within the molten metal. The molten bath is then mixed to distribute the solid phase within the molten metal. The molten alloy is then cast into a solid object containing the solid phase. The solid phase is insoluble in the matrix and has a size related to the initial size of the finely divided solid. The alloy of the invention advantageously consists essentially of, by weight percent, about 3 to 40 aluminum, about 0.8 to 25 nickel, about 0 to 12 copper and balance zinc and incidental impurities. The alloy has a zinc-containing matrix with nickel-containing aluminides distributed throughout the matrix.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: January 12, 1999
    Assignee: Inco Limited
    Inventors: Malcolm Charles Evert Bell, James Alexander Evert Bell, Carlos Manuel Diaz, Thijs Eerkes, Thomas Francis Stephenson, Scott Thomas Campbell, John Francis Brennan, Anthony Edward Moline Warner
  • Patent number: 5658401
    Abstract: A copper-zinc alloy for semi-finished products and articles which are highly loaded and subjected to extreme wear especially synchronizing rings. The alloy possesses a composition of 40 to 65% Cu, 8 to 25% Ni, 2.5 to 5% Si, 0 to 3% Al, 0 to 3% Fe, 0 to 2% Mn and 0 to 2% Pb, with the balance being zinc and unavoidable impurities. The Ni:Si ratio is about 3 to 5:1, and the structure consists of at least 75% .beta.-phase, with the balance .alpha.-phase, in the absence of a .gamma.-phase. Nickel silicides occur predominantly as a round intermetallic phase. The alloy provides quite substantially higher levels of resistance to wear.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: August 19, 1997
    Assignee: Diehl GmbH & Co.
    Inventors: Norbert Gaag, Peter Ruchel
  • Patent number: 5071620
    Abstract: A zinc/low aluminum alloy with lithium additions demonstrating improved creep resistance and suitable for hot chamber pressure die casting. The alloy preferably contains from about 0.1-2% Al, 0.07-0.19% Li, the balance zinc. The alloy also may contain Cu, Mn and Mg.
    Type: Grant
    Filed: August 31, 1990
    Date of Patent: December 10, 1991
    Assignee: International Lead Zinc Research Organization, Inc.
    Inventor: Cedric H. Thornton
  • Patent number: 4990310
    Abstract: A creep-resistant die casting is formed of a zinc-base alloy comprising about 4 to 12 percent copper and about 2 to 4 percent aluminum. The die casting is characterized by an intimate dispersion of fine epsilon and eta phases effective to retard slip and thereby enhance creep resistance.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: February 5, 1991
    Assignee: General Motors Corporation
    Inventors: Moinuddin S. Rashid, M. David Hanna
  • Patent number: 4863686
    Abstract: There is provided a high-strength, easily-castable zinc alloy consisting substantially of, by weight, from 1 to 30 percent aluminum, from 1 to 20 percent copper, from 0.01 to 1 percent titanium, from 0.01 to 1 percent zirconium, and the balance zinc, and also is provided a high-strength, easily-castable zinc alloy further including from 0.01 to 0.1 percent magnesium. These alloys are useful in the manufacture of molds for injection molding of plastics or also useful as die casting products.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: September 5, 1989
    Assignee: Nippon Mining Co., Ltd.
    Inventors: Yasunori Yamamoto, Eiji Nishimura
  • Patent number: 4789522
    Abstract: An improved castable hypereutectic zinc-aluminum alloy which is free from underside shrinkage is described. Small additions, from about 0.25% and up to about 2 wt% of rare earth metal, preferably in the form of misch metal, to known zinc-aluminum alloys containing from about 20% and up to about 40 wt% aluminum have been found to prevent underside shrinkage in castings with a cross section up to about six inches.
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: December 6, 1988
    Assignee: Queen's University at Kingston
    Inventors: Reginald W. Smith, Mansor Ghoreshy
  • Patent number: 4722871
    Abstract: A zinc-aluminum alloy coating having desirable ductile properties and a uniform fine grain structure having excellent wettability for a ferrous metal substrate comprises greater than about 25 percent by weight aluminum and zinc, wherein the alloy further includes from about 0.1 to about 1.0 percent by weight of a rare earth alloy for enhancing the wettability of the alloy to the ferrous metal and the balance comprises additional additives and impurities. With alloys having increased concentration of aluminum, the solubility of the rare earth alloy is increased, thereby increasing wettability.
    Type: Grant
    Filed: August 14, 1986
    Date of Patent: February 2, 1988
    Assignee: Cosmos Engineering, Inc.
    Inventor: Schrade F. Radtke
  • Patent number: 4717430
    Abstract: A method of joining metal surfaces is provided which comprises contacting the metal surfaces with a zinc-based composition and joining the metal surfaces, the zinc-based composition comprising, by weight:from about 0.1 to about 4 percent copper;from about 0.1 to about 1 percent nickel;from about 0.01 to less than 0.5 percent aluminum;0 to about 0.5 percent chromium;0 to about 0.5 percent titanium; and the remainder being zinc is also provided. The composition is useful for coating metal surfaces, particularly metals formed of or containing copper.The above composition and method may be used with or without a flux. Particularly beneficial results are obtained when a flux having a composition comprising, by weight:from about 5 to about 70 percent ZnCl.sub.2 ;from about 1 to about 28 percent NH.sub.4 Cl;from about 0.1 to about 10 percent SnCl.sub.2 ;from about 0 to about 10 percent HCl;from about 0 to about 10 percent Li.sub.2 B.sub.4 O.sub.7 ;from about 0 to about 5 percent MgBr.sub.
    Type: Grant
    Filed: October 29, 1986
    Date of Patent: January 5, 1988
    Assignee: Copper Development Association, Inc.
    Inventor: Roy E. Beal
  • Patent number: 4647308
    Abstract: A zinc-based composition comprising, by weight:from about 0.1 to 4 percent copper;from about 0.1 to about 1 percent nickel;from about 0.01 to less than 0.5 percent aluminum;0 to about 0.5 percent chromium;0 to about 0.5 percent titanium; and the remainder being zinc is provided. The composition is useful for coating or joining metal surfaces, particularly metals formed of or containing copper.The above composition may be used with or without a flux. Particularly beneficial results are obtained when a flux having a composition comprising, by weight:from about 5 to about 70 percent ZnCl.sub.2 ;from about 1 to about 28 percent NH.sub.4 Cl;from about 0.1 to about 10 percent SnCl.sub.2 ;from about 0 to about 10 percent HCl;from about 0 to about 10 percent Li.sub.2 B.sub.4 O.sub.7 ;from about 0 to about 5 percent MgBr.sub.2 ;from about 0 to about 5 percent ZnBr.sub.2 ; and about 0 to about 94 percent water is used.
    Type: Grant
    Filed: June 18, 1984
    Date of Patent: March 3, 1987
    Assignee: Copper Development Association, Inc.
    Inventor: Roy E. Beal
  • Patent number: 4609529
    Abstract: The ductility and/or tensile strength of certain zinc-based alloys (25 to 40 wt. % aluminum, 0.5 to 5 wt. % copper, and up to 0.1 wt. % magnesium) are improved when various elements are added. A first series of improved alloys is comprised of boron (between 5 ppm and 0.1 wt. %), possibly along with titanium (25 ppm to 0.5 wt. %), or possibly along with zirconium and/or strontium (up to 0.1 wt. %), and titanium (up to 0.1 wt. %). A second series of improved alloys is comprised of rare earths, principally lanthanum and/or cerium, in a total amount between 5 ppm and 0.1 wt. %.
    Type: Grant
    Filed: October 11, 1984
    Date of Patent: September 2, 1986
    Assignee: Centre de Recherches Metallurgiques
    Inventors: Andre Skenazi, Dimitri Coutsouradis, Andre Rasquin
  • Patent number: 4599279
    Abstract: A zinc alloy, having a copper layer coated thereon, consists essentially of from about 0.1 to about 0.8 weight percent copper, about 0.01 or more weight percent aluminum; up to about 0.05 weight percent magnesium, the balance being essentially zinc. The copper coated zinc alloy is advantageously employed to produce various cast, extruded, molded articles and the like including trim, fixtures as well as coin blanks. Further, the present invention relates to a metal article comprising a zinc base alloy having a copper overlayer in direct contact with the zinc base alloy, said alloy comprising about 1.5 weight percent or less aluminum and the remainder zinc. From another aspect, the subject invention contemplates a method for reducing the diffusion between a copper layer and a zinc base metal, said layer being in direct contact with the zinc base metal, said method comprising incorporating at least about 0.01 weight percent aluminum in said zinc base metal.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: July 8, 1986
    Assignee: Ball Corporation
    Inventors: Michael J. Mirra, Jon W. Headrick, Raymond E. Giuliani
  • Patent number: 4448748
    Abstract: There is disclosed an alloy for use in a zinc galvanizing bath comprising zinc, aluminum and a rare earth-containing alloy such as mischmetal. According to the preferred embodiments, the alloy contains from about 85% to about 97% zinc, from about 3% to about 15% aluminum and from about 5 ppm to about 1.0% mischmetal. The alloy may also contain one or more of the elements Fe, Pb, Sb, Mg, Sn, Cu and Si.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: May 15, 1984
    Assignee: International Lead Zinc Research Organization, Inc.
    Inventors: Schrade F. Radtke, Dimitri Coutsouradis, Jacques Pelerin