Alkali, Or Alkaline Earth Metal Containing Patents (Class 420/549)
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Patent number: 5565169Abstract: A substantially lithium-free aluminum base alloy product having improved combinations of elongation and fracture toughness in an aged condition, the aluminum alloy product comprising at least 0.5 wt. % magnesium; 0.01 to 1 ppm Na; 0.01 to 1 ppm K; less than 0.1 ppm Rb; and less than 0.1 ppm Cs, the remainder comprising aluminum, the amount of Na, K, Rb and Cs measured by GDMS, the product in an aged condition having a grain boundary region substantially free of liquid phase eutectics comprised of Na and K that form embrittlement phases at room temperature; and an increase in fracture toughness compared to an aluminum magnesium alloy having greater amounts of Na, K, Rb and Cs.Type: GrantFiled: December 29, 1994Date of Patent: October 15, 1996Assignee: Comalco Aluminium LimitedInventor: Donald Webster
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Patent number: 5551997Abstract: Disclosed is a practical aluminum based alloy containing 1 to 99 weight percent beryllium, and improved methods of semi-solid processing of aluminum alloys containing beryllium. The present methods avoid molten beryllium, agitation of molten aluminum-beryllium alloys and the need for introducing shear forces by utilizing atomized or ground particles of beryllium mixed with solid, particulate or liquidus aluminum.Type: GrantFiled: March 31, 1994Date of Patent: September 3, 1996Assignee: Brush Wellman, Inc.Inventors: James M. Marder, Warren J. Haws
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Patent number: 5494540Abstract: An abrasion-resistant aluminum alloy consists of 13.0 to 16.0 percent by weight of Si, 4.0 to 5.0 percent by weight of Cu, at least 0.8 and less than 1.4 percent by weight of Mg, not more than 0.8 percent by weight of Fe, not more than 0.1 percent by weight of either P or at least one of Na, Sb and Sr and a remainder of Al and unavoidable impurities. The alloy's microstructure contains coarse Si particles of 15 to 40 .mu.m mean particle diameter, fine Si particles of not more than 5 .mu.m mean particle diameter and other fine particles, with a homogeneous dispersion of all of these particles. This abrasion-resistant aluminum alloy has specific abrasion loss of not more than 10.times.10.sup.-7 mm.sup.2 /kg.Type: GrantFiled: January 26, 1995Date of Patent: February 27, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Shigeki Ochi, Tosio Fujiwara
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Patent number: 5484492Abstract: A cast hypereutectic Al-Si alloy having 12% to 15% Si, and a method of producing such alloy. The alloy and a melt used in the method has at least one element of a first group of elements and at least one element of a second group of elements and further comprises Cu 1.5 to 5.5%; Ni 1.0 to 3.0%; Mg 0.1 to 1.0%; Fe 0.1 to 1.0%; Mn 0.1 to 0.8%; Zr 0.01 to 0.1; Zn 0 to 3.0%; Sn 0 to 0.2%; Pb 0 to 0.2%; Cr 0 to 0.1; Si modifier (Na, Sr) 0.001 to 0.1%; B (elemental) 0.05% maximum; Ca 0.03% maximum; P 0.05% maximum; and others 0.05% maximum each, the balance, apart from incidental impurities being Al. The element of the first group provides stable nucleant particles in the melt. The element of the second groups forms an intermetallic phase such that crystals of the phase form in advance of and nucleate primary Si to provide complex particles which promote nucleation of Al-Si eutectic on cooling of the melt below the eutectic solidification temperature.Type: GrantFiled: July 7, 1994Date of Patent: January 16, 1996Assignee: Comalco Aluminum LimitedInventors: Kevin P. Rogers, Christian Simensen
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Patent number: 5453244Abstract: There is disclosed a novel aluminum alloy bearing which exhibits a more excellent fatigue resistance than conventional bearings even under such conditions of use as at a high temperature and under a high load. The aluminum alloy bearing has an aluminum bearing alloy layer containing, by weight, 1 to 10% Zn, 0.1 to 5% Cu, 0.05 to 3% Mg, 0.1 to 2% Mn, 0.1 to 5% Pb, 0.1 to 2% V, and 0.03 to 0.5% in total of Ti--B, and further may optionally contain not more than 8% Si, 0.05 to 0.5% Sr, and Ni, Co and Cr. The alloy may be bonded to a steel metal back sheet, and a surface layer may be formed on the surface of the bearing. By use of the composition of the alloy of the invention, the fatigue resistance of the aluminum alloy bearings has been improved, and such an improved bearing can fully achieve a bearing performance even under severe conditions of use as at high temperature and under a high load.Type: GrantFiled: November 10, 1994Date of Patent: September 26, 1995Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Tohru Kato, Yoshiaki Sato
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Patent number: 5405576Abstract: A hypereutectic aluminum-silicon alloy produced by a powder metallurgy technique disclosed herein comprises 12 to 50% by weight of silicon, 1.0 to 5.0% by weight of copper and 0.01 to 0.05% by weight of phosphorus, the content of Ca as an impurity being controlled to be 0.03% by weight or less. The hyereutectic aluminum-silicon alloy of the present invention is excellent in machinability and mechanical strength.Type: GrantFiled: July 16, 1992Date of Patent: April 11, 1995Assignees: Toyo Aluminum Kabushiki Kaisha, Sumitomo Electric Industries, Ltd.Inventors: Jun Kusui, Akiei Tanaka, Kohei Kubo, Takashi Watsuji, Takamasa Yokote
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Patent number: 5368629Abstract: The rapidly solidified aluminum alloy powder is preformed in a cold or warm environment to form a powder compact having a relative density of 75-93%. Then, the preformed compact is heated and degassed in the atmosphere of an inert gas at temperature of 300.degree. C. to 560.degree. C. for 0.25-3 hours. Immediately thereafter, the compact is subjected to hot coining at 300.degree.-560.degree. C. to obtain a solidified compact having pores at a rate of 2-5%. The solidified compact is then subjected to sizing. Since the inorganic gas prevents reaction between the evaporated water and aluminum while preheating the compact, the hot coining can be carried out in a state where solid state diffusion easily occurs. Thus, the powder particles can be bonded together strongly with a single forging. Also, at the end of hot coining, pores remain in the solidified compact at the rate of 2-5%. Utilizing these pores, the compact can be subjected to sizing to improve its dimensional accuracy.Type: GrantFiled: December 3, 1992Date of Patent: November 29, 1994Assignee: Sumitomo Electric Industries, Ltd.Inventors: Katsuyoshi Kondo, Yoshinobu Takeda
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Patent number: 5332455Abstract: A rapidly solidified brazing alloy consists essentially of about 14 to 45 weight percent magnesium and 0 to 10 weight percent of at least one element selected from the group consisting of silicon, bismuth, strontium, lithium, copper, calcium, zinc and tin, the balance being aluminum and incidental impurities. The alloy has a microcrystalline structure containing uniformly distributed intermetallic particles. It has the form of a foil (liquidus temperature <570.degree. C.) and can be used to braze non-heat-treatable rapidly solidified Al-Fe-V-Si alloy foil, sheet, plate, and tubing to produce components such as deicing duct, overduct, radiator, heat exchanger, evaporator, honeycomb panel for elevated temperature applications.Type: GrantFiled: December 18, 1992Date of Patent: July 26, 1994Assignee: AlliedSignal Inc.Inventors: Chin-Fong Chang, Santosh K. Das, Michael S. Zedalis
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Patent number: 5258081Abstract: Artificially aged aluminum-lithium alloys are given an auxiliary heat treatment at or after completion of ageing to improve short-transverse properties, particularly fracture toughness. The auxiliary heat treatment comprises heating the material steadily to a reversion temperature above the ageing temperature by at least 20.degree. C. but not higher than 250.degree. C., retaining the material briefly at temperature then cooling to room temperature. Typically the treatment involves heating to a reversion temperature in the range 190.degree.-230.degree. C. with a hold at this temperature of around 5 minutes. Boosted properties decay with extended exposure to temperatures of 60.degree. C. and above but may be restored by reimposition of the auxiliary heat treatment.Type: GrantFiled: June 11, 1992Date of Patent: November 2, 1993Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Christopher J. Peel, Stanley P. Lynch
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Patent number: 5230754Abstract: Improved aluminum master alloys containing strontium and boron are provided for simultaneously modifying and grain refining Al alloys, and in particular, hypoeutectic Al-Si alloys. The improved master alloy contains, by weight percent, about 0.20-20% Sr, 0.10-10% B, and the balance Al with impurities. The master alloy may also contain about 0.20 to about 20% Si by weight percent. The master alloys have a high degree of ductility for purposes of forming continuously rolled master alloy rod stock.Type: GrantFiled: March 4, 1991Date of Patent: July 27, 1993Assignee: KB Alloys, Inc.Inventors: William C. Setzer, David K. Young, Bryan T. Dunville, Frank P. Koch, Richard J. Malliris
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Patent number: 5217546Abstract: A cast hypereutectic Al-Si alloy with from 12-15% Si, having excellent wear resistance and machinability, improved fatigue strength and good levels of ambient and elevated temperature properties is provided, as well as a method of producing such alloy. The alloy and a melt used in the method contains Sr in excess of 0.10% and Ti in excess of 0.005%, the alloy further comprising: Cu 1.5 to 5.5%, Ni 1.0 to 3.00%, Mg 0.1 to 1.0%, Fe 0.1 to 1.0%, Mn 0.1 to 0.8%, Zr 0.01 to 0.1%, Zn 0 to 3.0%, Sn 0 to 0.2%, Pb 0 to 0.2%, Cr 0 to 0.1%, Na 0 to 0.01%, B (elemental) 0.05% maximum, Ca 0.003% maximum, P 0.003% maximum. Others 0.05 maximum each, the balance, apart from incidental impurities, being Al. The level of Sr in excess of 0.10% and Ti in excess of 0.Type: GrantFiled: May 21, 1992Date of Patent: June 8, 1993Assignee: Comalco Aluminum LimitedInventors: John A. Eady, Christopher J. Heathcock, Peter L. Kean, Kevin P. Rogers, Rodney A. Legge
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Patent number: 5205986Abstract: A process is described for the preparation of an aluminum-strontium master alloy suitable for use as structure refiner during the solidification of molten aluminum-silicon alloys, comprising atomizing a stream of molten alloy containing aluminum and 5 to 35% by weight of strontium and collecting atomized particles as solid material on a collecting surface.Type: GrantFiled: October 5, 1990Date of Patent: April 27, 1993Assignee: Shell Research LimitedInventors: Jan Noordegraaf, Piet Krahmer, Martin Donnelly
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Patent number: 5123973Abstract: A worked rod extrusion product for fabricating into products having high wear resistance surfaces, the product comprised of 11 to 13.5 wt. % Si, 0.5 to 1.45 wt % Cu, 0.8 to 3 wt. % Mg, 0.5 to 2.95 wt. % Ni, max 1 wt. % Fe, max 0.1 wt. % Cr, max 0.25 wt. % Zn, the balance aluminum, incidental elements and impurities.Type: GrantFiled: February 26, 1991Date of Patent: June 23, 1992Assignee: Aluminum Company of AmericaInventors: Gerald D. Scott, James A. Brock, Thomas J. Klemp
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Patent number: 5110371Abstract: An aluminum alloy consists of, by weight, from 0.08 to 0.50 percent silicon, from 0.15 to 0.90 percent iron, the weight ratio of iron to silicon being from 1.4 to 2.2, and the remainder aluminum, intermetallic compounds of .alpha.-type Al-Fe-Si system being contained in the alloy. A light gray oxide film is formed on the alloy by anodic treatment.Type: GrantFiled: July 9, 1991Date of Patent: May 5, 1992Assignee: Nippon Light Metal Company, Ltd.Inventors: Takeshi Moriyama, Katsuji Ogawa, Fumio Ohtake, Akito Nishizawa
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Patent number: 5083602Abstract: A cast composite material is made from particles and a matrix alloy of preselected composition that is difficult to wet to the particles. A wetting alloy having a composition that readily wets the particles is first mixed with the particles under conditions that wet the wetting alloy to the particles. The wetting alloy is selected so that is has no alloying elements in excess of that in the preselected matrix alloy, and preferably with wettability inhibiting elements reduced. After wetting and mixing have been achieved, the remaining alloying ingredients are added to the melt to adjust the matrix to the desired composition. The approach is applicable to cast composite materials containing both reactive and nonreactive particles. (aluminum matrix with silicon additions).Type: GrantFiled: July 26, 1990Date of Patent: January 28, 1992Assignee: Alcan Aluminum CorporationInventor: Michael D. Skibo
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Patent number: 5069875Abstract: Disclosed is a method of adding silicon to aluminum. The method is characterized in that silicon particles having a diameter ranging between 2 mm and 50 mm are added to a molten aluminum together with a flux represented by the general formula XaMFb, where "X" represents an element included in the third or fourth period of the Periodic Table, "M" is a III or IV group element of the Periodic Table, and "F" is fluorine. A part of the flux may be added in the form of coating on the surface of the silicon particle.Type: GrantFiled: October 16, 1990Date of Patent: December 3, 1991Assignee: Nikkin Flux Inc.Inventors: Koji Ohyama, Masaki Tsunoda
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Patent number: 5045110Abstract: A process is described for the preparation of an aluminium-strontium master alloy suitable for use as structure refiner during the solidification of molten aluminium-silicon alloys, comprising atomizing a molten alloy containing 3 to 30% by weight of strontium, the balance being aluminium, quick cooling of the atomized droplets to obtain solid particles and consolidation of the obtained solid particles.Type: GrantFiled: May 21, 1990Date of Patent: September 3, 1991Assignee: Shell Research LimitedInventors: Mattheus Vader, Jan Noordegraaf, Edward H. Klein Nagelvoort, Jan P. Mulder
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Patent number: 5023051Abstract: A hypoeutectic aluminum silicon magnesium alloy includes 4-5.5% silicon, 0.15-3.5% magnesium, 0.005 to 0.08% phosphorus and aluminum. The presence of the phosphorus causes formation of a spherical percipitates of silicon magnesium and the aluminum. The phosphorus suppresses the magnesium silicon aluminum eutectic which allows the aluminum to remain liquid for a longer period of time and consequently providing a better fill of casting during the time the alloy is solidifying in a die or a mold. This alloy which preferably includes nickel is particularly useful for marine, hydraulic and refrigeration components.Type: GrantFiled: December 4, 1989Date of Patent: June 11, 1991Assignee: Leggett & Platt IncorporatedInventor: Richard S. Lindberg
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Patent number: 4902475Abstract: An Al-Si base alloy to which is added predetermined amounts of Ti, preferably in the range from 0.2 to 1.0 weight percent Ti to significantly improve grain refinement and eutectic modification and to improve soundness and ductility of castings made of such an alloy, as well as reducing wear resistance of the casting. An Al-Ti or Al-Ti-B master alloy is utilized to produce the aforesaid alloy and is added to the melt to achieve the desired Ti level to produce a hypoeutectic and hypereutectic alloys. Alternatively, an Al-Ti-Si master alloy is added to the melt to obtain the desired Ti level for producing hypereutectic alloys.Type: GrantFiled: September 30, 1987Date of Patent: February 20, 1990Assignee: Metallurgical Products & Technologies, Inc.Inventors: Diran Apelain, Jung-Jen A. Cheng
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Patent number: 4785092Abstract: Aluminum brazing alloys for assembling aluminum heat exchangers by brazing which consist essentially of 4.5 to 13.5% of Si, from 0.005% to less than 0.1% of Sr and the balance essentially Al and, further, optionally may contain at least one element selected from the group consisting of 0.3 to 3.0% of Mg, 2.3 t0 4.7% of Cu and 9.3 to 10.7% of Zn. The aluminum brazing alloys provide high strength brazed joints with highly refined microstructure and brazing operation can be performed in a good condition without causing any detrimental cavity. Such excellent properties make the brazing alloys especially suited for the fabrication of superhigh pressure heat exchangers.Type: GrantFiled: March 15, 1985Date of Patent: November 15, 1988Assignees: Sumitomo Light Metal Industrial, Ltd., Sumitomo Precision Products Co., Ltd.Inventors: Keizo Nanba, Michiki Hagiwara, Shosuke Iwasaki, Tetsuo Abiko
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Patent number: 4781888Abstract: Aluminum brazing alloys for assembling aluminum heat exchangers by brazing which consist essentially of 4.5 to 13.5% of Si, 0.05 to 0.5% of Ca and the balance essentially Al and, additionally may contain Mg in the range of 0.3 to 3.0% or at least Cu component of 2.3 to 4.7% of Cu and 9.3 to 10.7% of Zn. The aluminum brazing alloys have an excellent brazability and provide high strength brazed joints with highly refined microstructure. Such superior properties make the brazing alloys especially suited for the fabrication of superhigh pressure heat exchangers.Type: GrantFiled: April 5, 1985Date of Patent: November 1, 1988Assignee: Sumitomo Precision Products Co., Ltd.Inventors: Michiki Hagiwara, Keizo Nanba, Shosuke Iwasaki, Tetsuo Abiko
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Patent number: 4734130Abstract: The present invention provides a method for producing an aluminum alloy which includes the step of carbothermically reducing an aluminous material to provide an alloy consisting essentially of the formula Al.sub.bal TM.sub.d Si.sub.e, wherein TM is at least one element selected from the group consisting of Fe, Ni, Co, Ti, V, Zr, Cu and Mn, "d" ranges from about 2-20 wt %, "e" ranges from about 2.1-20 wt %, and the balance is aluminum and incidental impurities. The alloy is placed in the molten state and rapidly solidified at a quench rate of at least about 10.sup.6 K/sec to produce a rapidly solidified alloy composed of a predominately microeutectic and/or microcellular structure.Type: GrantFiled: August 10, 1984Date of Patent: March 29, 1988Assignee: Allied CorporationInventors: Colin M. Adam, Kenji Okazaki, David J. Skinner, Robert G. Corey
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Patent number: 4631172Abstract: Alloys for galvanic anode of this invention include those which contain zinc of 1.0 to 10%, magnesium of 0.1 to 6%, indium of 0.01 to 0.04%, tin of 0.005 to 0.15%, silicon of 0.09 to 1.0%, and calcium or barium or both of 0.005 to 0.45%, the balance being aluminum, and those which contain zinc of 1.0 to 10%, indium of 0.01 to 0.05%, magnesium of 0.05 to 6%, silicon of 0.07 to 1.0%, and calcium or barium or both of 0.01 to 0.5%, the balance being aluminum. The above mentioned alloys of this invention exhibit an exceedingly large output of electric current as compared with conventional alloys, hold the dissolving surfaces uniformly and are exceedingly useful for anticorrosion of large-sized steel structures.Type: GrantFiled: May 1, 1985Date of Patent: December 23, 1986Assignees: Nadagawa Corrosion Protecting Co., Ltd., Mitsui Mining & Smelting Co.Inventors: Ikuo Yamamoto, Takehito Umino, Yoshio Shinoda, Hisao Yoshino
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Patent number: 4554131Abstract: Aluminum alloys suitable for use as anode structures in electrochemical cs are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.Type: GrantFiled: September 28, 1984Date of Patent: November 19, 1985Assignee: The United States of America as represented by the Department of EnergyInventors: David S. Thompson, Darwin H. Scott
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Patent number: 4394348Abstract: Strontium-modified aluminium alloys may be produced by using strontium peroxide as the source of strontium. The strontium peroxide may be mixed with molten aluminium or molten aluminium alloy in a quantity sufficient to give the desired strontium metal content in the alloy being produced. The temperature of the molten aluminium or aluminium alloy with which the strontium peroxide is mixed is preferably at least 1000.degree. C.The strontium peroxide alloys produced may be master alloys for use in the production of casting alloys, or may be casting alloys. Strontium acts as a grain refiner in such alloys.Type: GrantFiled: September 22, 1980Date of Patent: July 19, 1983Assignee: Interox Chemicals Ltd.Inventors: Francis R. F. Hardy, Martin G. Griffiths