Titanium, Zirconium, Hafnium, Vanadium, Noobium Or Tantalum Containing Patents (Class 420/551)
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Patent number: 6471794Abstract: An aluminum alloy fin material for brazing which is composed of an aluminum alloy comprising above 0.1 wt % to 3 wt % of Ni, above 1.5 wt % to 2.2 wt % of Fe, and 1.2 wt % or less of Si, and at least one selected from the group consisting of 4 wt % or less of Zn, 0.3 wt % or less of In, and 0.3 wt % or less of Sn, and further comprising, optionally, at least one selected from the group consisting of co, Cr, Zr, Ti, Cu, Mn, and Mg in given amounts, the balance being unavoidable impurities and aluminum, wherein a ratio of the grain length in the right angle direction/the grain length in the parallel direction is 1/30 or less, an electric conductivity is 50 to 55 %IACS, and a tensile strength is 170 to 280 MPa.Type: GrantFiled: May 18, 2001Date of Patent: October 29, 2002Assignees: The Furukawa Electric Co., Ltd., Denso CorporationInventors: Takeyoshi Doko, Akira Kawahara, Sunao Fukuda, Yoshihiko Kamiya, Masaki Shimizu, Kenji Negura
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Patent number: 6458224Abstract: An aluminum alloy article containing the alloying amounts of iron, silicon, manganese, titanium, and zinc has controlled levels of iron and manganese to produce an alloy article that combines excellent corrosion resistant with good formability. The alloy article composition employs a controlled ratio of manganese to iron and controlled total amounts of iron and manganese to form intermetallic compounds in the final alloy article. The electrolytic potential of the intermetallic compounds match the aluminum matrix of the article to minimize corrosion. The levels of iron and manganese are controlled so that the intermetallic compounds are present in a volume fraction that allows the alloy article to be easily formed. The aluminum alloy composition is especially adapted for extrusion processes, and tubing that are used in heat exchanger applications.Type: GrantFiled: May 3, 2000Date of Patent: October 1, 2002Assignee: Reynolds Metals CompanyInventors: Baolute Ren, Subhasish Sircar, William A. Cassada, III
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Patent number: 6440583Abstract: Disclosed is an Al alloy for a welded construction having excellent welding characteristics, which Al alloy comprises 1.5 to 5 wt % of Si (hereinafter, wt % is referred to as %), 0.2 to 1.5% of Mg, 0.2 to 1.5% of Zn, 0.2 to 2% of Cu, 0.1 to 1.5% of Fe, and at least one member selected from the group consisting of 0.01 to 1.0% of Mn, 0.01 to 0.2% of Cr, 0.01 to 0.2% of Ti, 0.01 to 0.2% of Zr, and 0.01 to 0.2% of V, with the balance being Al and inevitable impurities. Also disclosed is a welded joint having this Al alloy base metal welded with an Al—Mg- or Al—Si-series filler metal.Type: GrantFiled: October 26, 2000Date of Patent: August 27, 2002Assignees: The Furukawa Electric Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Seizo Ueno, Yoichiro Bekki, Noboru Hayashi
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Patent number: 6352789Abstract: The invention relates to a brazing sheet with a two-layer structure or a three-layer structure, having a core sheet made of an aluminium alloy core material and on one side or both sides thereof a brazing layer of an aluminium alloy containing silicon as main alloying element, wherein the aluminium alloy of the core sheet has the composition (in weight %) Mn 0.5 to 1.5 Cu 0.5 to 2.0 Si 0.3 to 1.5 Mg <0.05 Fe <0.4 Ti <0.15 Cr <0.35 Zr and/or V <0.35 in total Zn <0.25 balance aluminium and unavoidable impurities, and wherein said brazing sheet has a post-braze 0.2% yield strength of at least 50 MPa and having a corrosion life of more than 12 days in a SWAAT test without perforations in accordance with ASTM G-85, and further to a method of its manufacture.Type: GrantFiled: March 31, 2000Date of Patent: March 5, 2002Assignee: Corus Aluminium Walzprodukte GmbHInventors: Timothy John Hurd, Nicolaas Dirk Adrianus Kooij, Achim Bürger, Klaus Vieregge
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Publication number: 20010032688Abstract: A corrosion resistant aluminum alloy has controlled amounts of iron, manganese, chromium, and titanium along with levels of copper, silicon, nickel, and no more than impurity levels of zinc. The alloy chemistry is tailored such that the electrolytic potential of the grain boundaries matches the alloy matrix material to reduce intergranular corrosion. The alloy is particularly suited for the manufacture of tubing for heat exchangers using extrusion and brazing techniques.Type: ApplicationFiled: April 23, 2001Publication date: October 25, 2001Inventor: Baolute Ren
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Patent number: 6294272Abstract: An aluminium alloy for use as a core material in brazing sheet, comprising, in weight %: Mn 0.7-1.5, Cu 0.6-1.0, Fe not more than 0.4, Si less than 0.1, Mg 0.05-0.8, Ti 0.02-0.3, Cr 0.1-0.25, Zr 0.1-0.2, balance Al and unavoidable impurities, wherein 0.20<(Cr+Zr)≦0.4, the alloy being capable of obtaining in the post-brazing state 0.2% yield strength of at least 65 MPa and having a corrosion life of more than 11 days in a SWAAT test without perforations in accordance with ASTM G-85.Type: GrantFiled: March 24, 1999Date of Patent: September 25, 2001Assignee: Corus Aluminium Walzprodukte GmbHInventors: Jeroen Andreas Helmuth Söntgerath, Achim Bürger, Klaus Vieregge
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Patent number: 6194082Abstract: A support for a lithographic printing plate in which uniform pits are efficiently formed by electrochemically graining treatment, always independently of electrolytic conditions to give excellent printing performance, which comprises an aluminum alloy plate containing 0.05% to 0.5% by weight of Fe, 0.03% to 0.15% of Si, 0.006% to 0.03% by weight of Cu and 0.010% to 0.040% by weight of Ti, wherein the Cu concentration of a surface layer portion of from a surface to a depth of 2 &mgr;m of the aluminum alloy plate is at least 20 ppm higher than that of a region deeper than the surface layer portion.Type: GrantFiled: September 29, 1999Date of Patent: February 27, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirokazu Sawada, Hirokazu Sakaki
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Patent number: 5900210Abstract: A high-strength and high-ductility aluminum-base alloy consisting of a composition of general formula: Al.sub.ba1 Mn.sub.a Si.sub.b or Al.sub.ba1 Mn.sub.a Si.sub.b TM.sub.c (wherein TM is one or more elements selected from the group consisting of Ti, V, Cr, Fe, Co, Ni, Cu, Y, Zr, La, Ce and Mm; and a, b and c are, in atomic percentages, 2.ltoreq.a.ltoreq.8, 0.5.ltoreq.b.ltoreq.6, 0<c.ltoreq.4, and a.gtoreq.b), wherein the alloy contains quasi-crystals. The an aluminum-base alloy have superior mechanical properties such as high hardness, high strength and high ductility.Type: GrantFiled: March 7, 1997Date of Patent: May 4, 1999Assignee: YKK CorporationInventors: Erik Buchler, Kazuhiko Kita
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Patent number: 5858131Abstract: An aluminum-based alloy having the general formula Al.sub.100 -(a+b)Q.sub.a M.sub.b (wherein Q is V, Mo, Fe, W, Nb, and/or Pd; M is Mn, Fe, Co, Ni, and/or Cu; and a and b, representing a composition ratio in atomic percentages, satisfy the relationships 1.ltoreq.a.ltoreq.8, 0<b<5, and 3.ltoreq.a+b.ltoreq.8) having a metallographic structure comprising a quasi-crystalline phase, wherein the difference in the atomic radii between Q and M exceeds 0.01 .ANG., and said alloy does not contain rare earths, possesses high strength and high rigidity. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.Type: GrantFiled: May 14, 1997Date of Patent: January 12, 1999Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yamaha Corp.Inventors: Akihisa Inoue, Hisamichi Kimura, Yuma Horio
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Patent number: 5809393Abstract: A sputtering target comprising a body of metal such as aluminum and its alloy with an ultrafine grain size and small second phase. Also described is a method for making an ultra-fine grain sputtering target comprising melting, atomizing, and depositing atomized metal to form a workpiece, and fabricating the workpiece to form a sputtering target. A method is also disclosed that includes the steps of extruding a workpiece through a die having contiguous, transverse inlet and outlet channels of substantially identical cross section, and fabricating the extruded article into a sputtering target. The extrusion may be performed several times, producing grain size of still smaller size and controlled grain texture.Type: GrantFiled: October 30, 1995Date of Patent: September 15, 1998Assignee: Johnson Matthey Electronics, Inc.Inventors: John Alden Dunlop, Jun Yuan, Janine Kiyabu Kardokus, Roger Alan Emigh
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Patent number: 5795541Abstract: An aluminum alloy sheet for printing plate contains Fe: 0.2 to 0.6 Wt %, Si: 0.03 to 0.15 Wt %, Ti: 0.005 to 0.05 Wt %, Ni: 0.005 to 0.20 Wt %, and remainder of Al and inevitable impurity, wherein a ratio of Ni content and Si content satisfies 0.1.ltoreq.Ni/Si.ltoreq.3.7. The aluminum alloy sheet is manufactured by homogenizing an aluminum alloy ingot at a temperature in a range of 500.degree. to 630.degree. C., after performing hot rolling at start temperature in a range of 400.degree. to 450.degree. C., providing cold rolling and intermediate annealing, and further performing final cold rolling. By this, the aluminum alloy sheet for printing plate is prevented from pit generation upon dipping in electrolytic solution in a condition where an electric power is not applied. Uniformity of grained surface of the aluminum alloy sheet by electrolytic treatment can be improved.Type: GrantFiled: December 26, 1996Date of Patent: August 18, 1998Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Masaki Tanigawa, Shinichiro Hosono, Kozo Hoshino, Yoshihiko Asakawa
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Patent number: 5779824Abstract: An aluminum alloy support for a planographic printing plate is disclosed, which is an aluminum alloy plate comprising 0<Fe.ltoreq.0.20 wt %, 0.ltoreq.Si.ltoreq.0.13 wt %, Al.gtoreq.99.7 wt % and the balance of inevitable impurity elements, wherein the number of intermetallic compounds present in the arbitrary thickness direction with in 10 .mu.m from the plate surface is from 100 to 3,000 per mm.sup.2 and the intermetallic compound has an average particle size of from 0.5 to 8 .mu.m, with the intermetallic compounds having a particle size of 10 .mu.m or more being in a proportion by number of 2% or less. Also disclosed is a method for producing the above-described aluminum alloy support.Type: GrantFiled: July 20, 1995Date of Patent: July 14, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirokazu Sawada, Hirokazu Sakaki, Tsutomu Kakei, Akio Uesugi, Masaya Matsuki
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Patent number: 5776617Abstract: A diffusion barrier to help protect titanium aluminide alloys, including the coated alloys of the TiAl.gamma.+Ti.sub.3 Al (.alpha..sub.2) class, from oxidative attack and interstitial embrittlement at temperatures up to at least 1000.degree. C. is disclosed. The coating may comprise FeCrAlX alloys. The diffusion barrier comprises titanium, aluminum, and iron in the following approximate atomic percent:Ti-(50-55)Al-(9-20)Fe.This alloy is also suitable as an oxidative or structural coating for such substrates.Type: GrantFiled: October 21, 1996Date of Patent: July 7, 1998Assignee: The United States of America Government as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Michael P. Brady, James L. Smialek, William J. Brindley
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Patent number: 5718777Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from the refractory metals Mo, W, Nb, and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.Type: GrantFiled: July 23, 1996Date of Patent: February 17, 1998Assignees: Koji Hashimoto, YKK CorporationInventors: Koji Hashimoto, Hiroki Habazaki, Stanislaw Mrowec, Marek Danielewski
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Patent number: 5714018Abstract: A high-strength and high-toughness aluminum-based alloy having a composition represented by the general formula: Al.sub.a Ni.sub.b X.sub.c M.sub.d Q.sub.e, wherein X is at least one element selected from the group consisting of La, Ce, Mm, Ti and Zr; M is at least one element selected from the group consisting of V, Cr, Mn, Fe, Co, Y, Nb, Mo, Hf, Ta and W; Q is at least one element selected from the group consisting of Mg, Si, Cu and Zn; and a, b, c, d and e are, in atomic percentage, 83.ltoreq.a.ltoreq.94,3, 5.ltoreq.b.ltoreq.10, 0.5.ltoreq.c.ltoreq.3, 0.1.ltoreq.d.ltoreq.2, and 0.1.ltoreq.e.ltoreq.2. The aluminum-based alloy has a high strength and an excellent toughness and can maintain the excellent characteristics provided by a quench solidification process even when subjected to thermal influence at the time of working. In addition, it can provide an alloy material having a high specific strength by virtue of minimized amounts of elements having a high specific gravity to be added to the alloy.Type: GrantFiled: October 27, 1992Date of Patent: February 3, 1998Assignee: YKK CorporationInventors: Kazuhiko Kita, Hidenobu Nagahama, Takeshi Terabayashi, Makoto Kawanishi
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Patent number: 5693897Abstract: A high strength, heat resistant aluminum-based alloy having a composition represented by the general formula Al.sub.bal Ti.sub.a Fe.sub.b or the general formula Al.sub.bal Ti.sub.a Fe.sub.b M.sub.c, wherein M represents at least one element selected from among V, Cr, Mn, Co, Y, Zr, Nb, Mo, Ce, La, Mm (misch metal), Hf, Ta and W; and a, b and c are, in weight percentage, 7.ltoreq.a.ltoreq.20, 0.2.ltoreq.b.ltoreq.6 and 0<c.ltoreq.6. A compacted and consolidated aluminum-based alloy having high strength and heat resistance is produced by melting a material having the above-specified composition, rapidly solidifying the melt into powder or flakes, compacting the resulting powder or flakes, and compressing, forming and consolidating the compacted powder or flakes by conventional plastic working.Type: GrantFiled: February 22, 1996Date of Patent: December 2, 1997Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5667600Abstract: Disclosed is a practical aluminum-based alloy containing 1 to 99 weight percent beryllium and improved methods for the investment casting of net shape aluminum-beryllium alloy parts.Type: GrantFiled: March 31, 1994Date of Patent: September 16, 1997Assignee: Brush Wellman, Inc.Inventors: Fritz C. Grensing, James M. Marder, Jere H. Brophy
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Patent number: 5647919Abstract: A high strength, rapidly solidified alloy consisting of aluminum and, added thereto, additive elements. The mean crystal grain size of the aluminum is 40 to 1000 nm, the mean size of particles of a stable phase or a metastable phase of various intermetallic compounds formed from the aluminum and the additive element and/or various intermetallic compounds formed from the additive elements themselves is 10 to 800 nm, and the intermetallic compound particles are distributed in a volume fraction of 20 to 50% in a matrix consisting of aluminum. The rapidly solidified alloy has an improved strength at room temperature and a high toughness and can maintain the properties inherent in a material produced by the rapid solidification process even when it undergoes a thermal influence during working.Type: GrantFiled: October 5, 1994Date of Patent: July 15, 1997Assignee: YKK CorporationInventors: Kazuhiko Kita, Hidenobu Nagahama
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Patent number: 5618358Abstract: A new aluminum based alloy having properties which mimic homogenized DC cast 3003 alloy and a low-cost method for manufacturing it are described. The alloy contains 0.40% to 0.70% Fe, 0.10% to less than 0.30% Mn, more than 0.10% to 0.25% Cu, less than 0.10% Si, optionally up to 0.10% Ti and the balance Al and incidental impurities. The alloy achieves properties similar to homogenized DC cast 3003 when continuously cast followed by cold rolling and if desired annealing at final gauge. Suprisingly no other heat treatments are required.Type: GrantFiled: March 1, 1995Date of Patent: April 8, 1997Inventors: Thomas Davisson, Sadashiv Nadkarni, Douglas Reesor
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Patent number: 5616189Abstract: An alloy of aluminum containing magnesium, silicon and optionally copper in amounts in percent by weight falling within one of the following ranges:(1) 0.4.ltoreq.Mg.ltoreq.0.8, 0.2.ltoreq.Si.ltoreq.0.5, 0.3.ltoreq.Cu.ltoreq.3.5;(2) 0.8.ltoreq.Mg.ltoreq.1.4, 0.2.ltoreq.Si.ltoreq.0.5, Cu.ltoreq.2.5; and(3) 0.4.ltoreq.Mg.ltoreq.1.0, 0.2.ltoreq.Si.ltoreq.1.4, Cu.ltoreq.2.0; said alloyhaving been formed into a sheet having properties suitable for automotive applications. The alloy may also contain at least one additional element selected from the group consisting of Fe in an amount of 0.4 percent by weight or less, Mn in an amount of 0.4 percent by weight or less, Zn in an amount of 0.3 percent by weight or less and a small amount of at least one other element, such as Cr, Ti, Zr and V.Type: GrantFiled: July 22, 1994Date of Patent: April 1, 1997Assignee: Alcan International LimitedInventors: Iljoon Jin, John Fitzsimon, Michael J. Bull, Pierre H. Marois, Alok K. Gupta, David J. Lloyd
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Patent number: 5614036Abstract: A high heat resisting and high abrasion resisting aluminum alloy and aluminum alloy powder have superior toughness, abrasion resistance, high temperature strength, and creep resistance and are useful to form engine parts for automobiles, airplanes, etc. The high heat resisting and high abrasion resisting aluminum alloy comprises 2 to 15 wt % of Ni, 0.2 to 15 wt % of Si, 0.6 to 8.0 wt % of Fe, one or two of 0.6 to 5.0 wt % of Cu and 0.5 to 3 wt % of Mg, the total amount of Cu and Mg being equal to or less than 6 wt %, one or two of 0.3 to 3 wt % of Zr and 0.3 to 3 wt % of Mo, the total amount of Zr and Mo being equal to or less than 4 wt %, 0.05 to 10 wt % of B, and the balance of Al and unavoidable impurities, and is produced by powder metallurgy.Type: GrantFiled: January 30, 1996Date of Patent: March 25, 1997Assignees: Toyota Jidosha Kabushiki Kaisha, Toyo Aluminium Kabushiki KaishaInventors: Kunihiko Imahashi, Hirohisa Miura, Yasuhiro Yamada, Hirofumi Michioka, Jun Kusui, Akiei Tanaka
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Patent number: 5593515Abstract: A high strength aluminum-based alloy, which having a composition of the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c T.sub.d, wherein Q represents at least one element selected from the group consisting of Mn, Cr, V, Mo and W; M represents at least one element selected from the group consisting of Co, Ni, Cu and Fe; X represents at least one element selected from rare earth elements including Y or Mm; T represents at least one element selected from the group consisting of Ti, Zr and Hf; and a, b, c and d represent the following atomic percentages: 1.ltoreq.a.ltoreq.7, 0>5, 0>c.ltoreq.5 and 0>d.ltoreq.2, and contains quasi-crystals in the structure thereof. The alloy of the present invention is excellent in the hardness and strength at both room temperature and a high temperature, and also in thermal resistance and ductility.Type: GrantFiled: March 27, 1995Date of Patent: January 14, 1997Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Teikoku Piston Ring Co., Ltd., Yamaha Corporation, YKK CorporationInventors: Tsuyoshi Masumoto, Akihisa Inoue, Hisamichi Kimura, Yoshiyuki Shinohara, Yuma Horio, Kazuhiko Kita
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Patent number: 5578144Abstract: To provide a high-strength, high-ductility cast aluminum alloy, which enables a near-net shape product to be produced by improving the casting structure of an aluminum alloy, particularly by using specific constituents and controlling the cooling rate, and a process for producing the same. The high-strength, high-ductility cast aluminum alloy of the present invention is characterized in that it has a structure comprising fine grains of .alpha.-Al, having an average grain diameter of not more than 10 .mu.m, surrounded by a network of a compound of Al-lanthanide-base metal, the .alpha.-Al grains forming a domain, that the domain comprises an aggregate of .alpha.-Al grains which have been refined, cleaved, and ordered in a single direction and that it has a composition represented by the general formula Al.sub.a Ln.sub.b M.sub.c wherein a, b, and c are, in terms of by weight, respectively 75%.ltoreq.a.ltoreq.95%, 0.5%.ltoreq.b<15%, and 0.5%.ltoreq.c<15%.Type: GrantFiled: June 14, 1995Date of Patent: November 26, 1996Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kazuaki Satou, Yukio Okochi
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Patent number: 5554234Abstract: The present invention provides a high strength aluminum alloy suitable for use in the manufacture of a fin, said aluminum alloy containing at most 0.1% by weight of Si, 0.10 to 1.0% by weight of Fe, 0.1 to 0.50% by weight of Mn, 0.01 to 0.15% by weight of Ti, and the balance of Al and unavoidable impurities, intermetallic compounds having a diameter not larger than 0.1 .mu.m being distributed within the metal texture of the alloy in a number density of at least 10/.mu.m.sup.3. The present invention also provides a method of manufacturing a high strength aluminum alloy suitable for use in the manufacture of a fin, comprising the steps of heating to 430.degree. to 580.degree. C. an aluminum alloy ingot of the composition noted above, applying a hot rolling treatment to said aluminum alloy ingot to obtain a plate material before the temperature of the aluminum alloy ingot is lowered by at most 50.degree. C.Type: GrantFiled: December 22, 1994Date of Patent: September 10, 1996Assignee: Furukawa Aluminum Co., Ltd.Inventors: Hiroaki Takeuchi, Hiroshi Kano
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Patent number: 5547633Abstract: The specification describes a ternary alloy of aluminium. The alloy described comprises from 80 to 96% by weight of aluminium and from 4 to 20% by weight of titanium and a third element selected from the group consisting of cobalt, chromium, copper, magnesium, nickel and iron. The weight ratio of titanium to ternary alloying element lies in the range from 1:1 to 6:1. The alloy can be aged at a temperature in the range from 300.degree. to 450.degree. C.Type: GrantFiled: September 23, 1994Date of Patent: August 20, 1996Assignee: Monash UniversityInventors: Barry C. Muddle, Jianfeng Nie
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Patent number: 5523050Abstract: A method is described for preparing a refined or reinforced eutectic or hyper-eutectic metal alloy, comprising: melting the eutectic or hyper-eutectic metal alloy, adding particles of non-metallic refractory material to the molten metal matrix, mixing together the molten metal alloy and the particles of refractory material, and casting the resulting mixture under conditions causing precipitation of at least one intermetallic phase from the molten metal matrix during solidification thereof such that the intermetallics formed during solidification wet and engulf said refractory particles. The added particles may be very small and serve only to refine the precipitating intermetallics in the alloy or they may be larger and serve as reinforcing particles in a composite with the alloy. The products obtained are also novel.Type: GrantFiled: March 15, 1993Date of Patent: June 4, 1996Assignee: Alcan International LimitedInventors: David J. Lloyd, Iljoon Jin
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Patent number: 5516382Abstract: An aluminum alloy useful for drawing and/or ironing, particularly of drink cans. The alloy consists essentially of, in weight percent, Fe<0.25; Si<0.25; Mn from 1.05 to 1.6; Mg from 0.7 to 2.5; Cu from 0.20 to 0.6; Cr from 0 to 0.35; Ti from 0 to 0.1; V from 0 to 0.1; other elements: each <0.05; total<0.15; and remainder Al.Type: GrantFiled: October 20, 1994Date of Patent: May 14, 1996Assignee: Pechiney RhenaluInventor: Guy-Michel Raynaud
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Patent number: 5509978Abstract: The present invention provides a high strength and anti-corrosive aluminum-based alloy essentially consisting of an amorphous structure or a multiphase amorphous/fine crystalline structure, which is represented by the general formula Al.sub.x M.sub.y R.sub.z. In this formula, M represents at least one metal element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Cu, Zr, Nb, Mo and Ni, and R represents at least one element or mixture selected from the group consisting of Y, Ce, La, Nd and Mm (misch metal). Additionally, in the formula, x, y and z represent the composition ratio, and are atomic percentages satisfying the relationships of x+y+z=100, 64.5.ltoreq.x.ltoreq.95, 5.ltoreq.y.ltoreq.35, and 0<z.ltoreq.0.4.Type: GrantFiled: February 9, 1995Date of Patent: April 23, 1996Assignee: Yamaha CorporationInventors: Tsuyoshi Masumoto, Akihisa Inoue, Yuma Horio
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Patent number: 5489418Abstract: An Al-based alloy represented by the general formula Al.sub.bal Ti.sub.a M.sub.b and Al.sub.bal Ti.sub.a M.sub.b Q.sub.c wherein M represents at least one element selected from among V, Cr, Mn, Co, Cu, Y, Zr, Nb, Mo, Hf, Ta and W; Q represents at least one element selected from Mg and Si; and a, b and c are, in percentages by weight, 7.ltoreq.a.ltoreq.20, 0.2.ltoreq.b.ltoreq.20 and 0.1.ltoreq.c.ltoreq.5. A compacted and consolidated material are produced by melting a material having the above alloy composition, rapidly solidifying the melt into powder or flakes; compacting the resultant powder or flakes; and subjecting the compacted powder or flakes to press forming and consolidating by a conventional plastic working. The aluminum-based alloy and the compacted and consolidated material thereof have a high strength and a good ductility and an excellent strength at high temperature.Type: GrantFiled: October 26, 1994Date of Patent: February 6, 1996Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5489347Abstract: An aluminum alloy fin material for heat-exchanger with excellent thermal conductance and strength after brazing comprising 0.005 to 0.8 wt. % of Si, 0.5 to 1.5 wt. % of Fe, 0.1 to 2.0 wt. % of Ni, and a balance of Al and inevitable impurities is disclosed. The aluminum alloy fin material can additionally contain 0.01 to 0.2 wt. % of Zr and/or at least one element of the group consisting of not more than 2.0 wt. % of Zn, not more than 0.3 wt. % of In, and not more than 0.3 wt. % of Sn.Type: GrantFiled: July 27, 1994Date of Patent: February 6, 1996Assignees: Furukawa Electric Co., Ltd., Nippondenso Co., Ltd.Inventors: Fujio Himuro, Takeyoshi Doko
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Patent number: 5478418Abstract: An aluminum alloy powder for sliding members includes Fe in an amount of from 0.5 to 5.0% by weight, Cu in an amount of from 0.6 to 5.0% by weight, B in an amount of from 0.1 to 2.0% by weight and the balance of Al. An aluminum alloy includes a matrix made from the aluminum alloy powder and at least one member dispersed, with respect to whole of the matrix taken 100% by weight, in the matrix, and selected from the group consisting of B in an amount of from 0.1 to 5.0% by weight, boride in an amount of from 1.0 to 15% by weight and iron compound in an amount of from 1.0 to 15% by weight, and thereby it exhibits the tensile strength of 400 MPa or more. The aluminum alloy powder and the aluminum alloy are suitable for making sliding members like valve lifters for automobiles.Type: GrantFiled: April 28, 1994Date of Patent: December 26, 1995Assignees: Toyota Jidosha Kabushiki Kaisha, Toyo Aluminum Kabushiki KaishaInventors: Hirohisa Miura, Yasuhiro Yamada, Hirohumi Michioka, Jun Kusui, Akiei Tanaka
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Patent number: 5458700Abstract: A high-strength aluminum alloy consisting of an amorphous phase containing quasicrystals constituted of aluminum as the principal element, a first additive element consisting of at least one rare earth element and a second additive element consisting of at least one element other than aluminum and rare earth elements, and a crystalline phase consisting of the principal element and the first additive element and the second additive element contained in a supersaturated solid solution form, the amorphous phase containing quasicrystals being contained in a volume percentage of 60 to 90%. The contents of the additive elements preferably fall within a hatched range in the figure, still preferably within a range covered with dot-dash lines in the figure.Type: GrantFiled: April 28, 1994Date of Patent: October 17, 1995Assignees: Tsuyoshi Masumoto, Akihisa Inoue, Yoshida Kogyo K.K.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Mitsuru Watanabe, Junichi Nagahora, Toshisuke Shitata
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Patent number: 5454855Abstract: A compacted and consolidated material of an aluminum-based alloy obtained by compacting and consolidating a rapidly solidified material having a composition represented by the general formula: Al.sub.a Ni.sub.b X.sub.c M.sub.d, Al.sub.a Ni.sub.b X.sub.c Q.sub.e or Al.sub.a 'Ni.sub.b X.sub.c M.sub.d Q.sub.e, wherein X represents at least one element selected from the group consisting of La, Ce, Mm (misch metal), Ti and Zr; M represents at least one element selected from the group consisting of V, Cr, Mn, Fe, Co, Y, Nb, Mo, Hf, Ta and W; Q represents at least one element selected from the group consisting of Mg, Si, Cu and Zn; and a, a', b, c, d and e are, in atomic percentages, 85.ltoreq.a.ltoreq.94.4, 83.ltoreq.a.ltoreq.94.3, 5.ltoreq.b.ltoreq.10, 0.5.ltoreq.c.ltoreq.3, 0.1.ltoreq.d.ltoreq.2 and 0.1.ltoreq.e.ltoreq.2.Type: GrantFiled: October 27, 1992Date of Patent: October 3, 1995Assignee: YKK CorporationInventors: Kazuhiko Kita, Hidenobu Nagahama, Takeshi Terabayashi, Makoto Kawanishi
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Patent number: 5453244Abstract: There is disclosed a novel aluminum alloy bearing which exhibits a more excellent fatigue resistance than conventional bearings even under such conditions of use as at a high temperature and under a high load. The aluminum alloy bearing has an aluminum bearing alloy layer containing, by weight, 1 to 10% Zn, 0.1 to 5% Cu, 0.05 to 3% Mg, 0.1 to 2% Mn, 0.1 to 5% Pb, 0.1 to 2% V, and 0.03 to 0.5% in total of Ti--B, and further may optionally contain not more than 8% Si, 0.05 to 0.5% Sr, and Ni, Co and Cr. The alloy may be bonded to a steel metal back sheet, and a surface layer may be formed on the surface of the bearing. By use of the composition of the alloy of the invention, the fatigue resistance of the aluminum alloy bearings has been improved, and such an improved bearing can fully achieve a bearing performance even under severe conditions of use as at high temperature and under a high load.Type: GrantFiled: November 10, 1994Date of Patent: September 26, 1995Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Tohru Kato, Yoshiaki Sato
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Patent number: 5431751Abstract: A high strength aluminum alloy is expressed by a general formula, Al.sub.a X.sub.b Mm.sub.c, in which "X" stands for at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zr, "Mm" stands for a misch metal, a content "a" of aluminum falls in a range of from 95.2 to 97.5 atomic %, and a content "b" of "X" and a content "c" of the "Mm" fall in a hatched area enclosed by points "A," "B," "C" and "D" of accompanying FIG. 1 on atomic % basis, and whose metallic phase includes microcrystalline phases or mixed phases containing amorphous phases in a volume content of less than 50% and the balance of microcrystalline phases. As a result, the amorphous phases or the microcrystalline phases are dispersed uniformly in its base microcrystalline phases appropriately, and at the same time the thus generating base microcrystalline phases are reinforced by forming solid solutions including the "Mm" and the transition metal element "X" as well.Type: GrantFiled: February 5, 1993Date of Patent: July 11, 1995Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yukio Okochi, Kazuaki Sato, Tetsuya Suganuma, Akira Kato, Tsuyoshi Masumoto, Akihisa Inoue
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Patent number: 5419789Abstract: An aluminum-based alloy which consists Al and 0.1 to 25 atomic % of at least two transition metal elements and has a structure in which at least quasicrystals are homogeneously dispersed in a matrix composed of Al or a supersaturated Al solid solution. The quasicrystals are preferably composed of an I-phase alone or a mixed phase of an I-phase and a D-phase and preferably has a volume nfraction of 20% or less. Specifically, the aluminum-based alloy has the composition represented by the general formula Al.sub.bal Ni.sub.a X.sub.b or Al.sub.bal Ni.sub.a X.sub.b M.sub.c wherein X is one or two elements selected between Fe and Co; M is at least one element selected from among Cr, Mn, Nb, Mo, Ta and W; 5.ltoreq.a.ltoreq.10; 0.5.ltoreq.b.ltoreq.10; and 0.1.ltoreq.c.ltoreq.5. The alloy is excellent in hardness and strength both at room temperature and high temperature and in heat resistance and has a high specific strength. It can retain the excellent characteristics even when affected by the heat of working.Type: GrantFiled: September 3, 1993Date of Patent: May 30, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5415709Abstract: The present invention provides a high-strength, abrasion resistant aluminum alloy having a composition represented by the general formula Al.sub.a M.sub.b X.sub.c Z.sub.d Si.sub.e, wherein M is at least one element selected from the group consisting of Fe, Co, and Ni; X is at least one element selected from the group consisting of Y, La, Ce and Mm (mischmetal); Z is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; and a, b, c, d and e are all expressed by atom percent and range from 50 to 89 %, 0.5 to 10 %, 0.5 to 10 %, 0 to 10 % and 10 to 49 %, respectively, with the proviso that a+b+c+d+e =100 %, the alloy containing fine Si precipitates and fine particles of intermetallic compounds dispersed in an aluminum matrix. The aluminum alloy may further contain not greater than 5 % of at least one element selected from the group consisting of Cu, Mg, Zn and Li. The alloy can be warm-worked at 300.degree.-500.degree. C.Type: GrantFiled: December 7, 1993Date of Patent: May 16, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5407636Abstract: An Al-based alloy represented by the general formula Al.sub.bal Ti.sub.a M.sub.b and Al.sub.bal Ti.sub.a M.sub.b Q.sub.c wherein M represents at least one element selected from among V, Cr, Mn, Co, Cu, Y, Zr, Nb, Mo, Hf, Ta and W; Q represents at least one element selected from Mg and Si; and a, b and c are, in percentages by weight, 7.ltoreq.a.ltoreq.20, 0.2.ltoreq.b.ltoreq.20 and 0.1.ltoreq.c.ltoreq.5. A compacted and consolidated material is produced by melting a material having the above alloy composition, rapidly solidifying the melt into powder or flakes; compacting the resultant powder or flakes; and subjecting the compacted powder or flakes to press forming and consolidating by a conventional plastic working. The aluminum-based alloy and the compacted and consolidated material thereof have a high strength, a good ductility and an excellent strength at high temperatures.Type: GrantFiled: January 25, 1993Date of Patent: April 18, 1995Assignee: YKK CorporationInventor: Kazuhiko Kita
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Patent number: 5380379Abstract: There is claimed an aluminum alloy sheet product having a composition consisting essentially of: about 1.35-1.6 wt. % iron; about 0.3-0.6 wt. % manganese; about 0.1-0.4 (and preferably about 0.22-0.4) wt. % copper; about 0.05-0.1 wt. % titanium; about 0.01-0.02 wt. % boron; up to about: 0.2 wt. % silicon, 0.02 wt. % chromium, 0.005 wt. % magnesium and 0.05 wt. % zinc; and a balance of aluminum, incidental elements and impurities. This composition is cast to an initial thickness greater than about 3 mm (0.12 inch). The end product exhibits improved strength and surface properties through a manufacturing process which includes: heat treating at one or more temperatures above about 450.degree. C. (842.degree. F.), and preferably below about 500.degree. C. (932.degree. F.); before rolling to final gauge. When cold rolled to various thicknesses, this sheet product exhibits ultimate tensile strength values ranging from 11-15 kg/mm.sup.2 for thin and intermediate gauge products, to about 27-30 kg/mm.sup.2 (38.4-42.Type: GrantFiled: August 18, 1993Date of Patent: January 10, 1995Assignee: Alcoa Aluminio Do Nordeste S.A.Inventors: Klaus P. Maiwald, Marcio D. Soares, Aldenir J. Clemente
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Patent number: 5374295Abstract: Disclosed are heat resistant aluminum alloy powders and alloys including Ni, Si, either at least one of Fe and Zr or at least one of Zr and Ti. For instance, the alloy powders or alloys consist essentially of Ni in an amount of from 5.7 to 20% by weight, Si in an amount of from 0.2 to 25% by weight, at least one of Fe in an amount of from 0.6 to 8.0% by weight and Cu in an amount of from 0.6 to 5.0% by weight, and the balance of Al. The alloy powders or alloys are optimum for a matrix of heat and wear resistant aluminum alloy-based composite materials including at least one of nitride particles and boride particles in an amount of 0. 5 to 10% by weight with respect to the whole composite material taken as 100% by weight. The alloy powders, alloys and composite materials are satisfactory applicable to the component parts of the recent automobile engines which should produce a high output.Type: GrantFiled: March 3, 1993Date of Patent: December 20, 1994Assignees: Toyota Jidosha Kabushiki Kaisha, Toyo Aluminum Kabushiki KaishaInventors: Hirohisa Miura, Kunihiko Imahashi, Yasuhiro Yamada, Hirohumi Michioka, Jun Kusui, Akiei Tanaka
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Patent number: 5372780Abstract: Aluminium alloys are described which after suitable processing can be used to produce lithographic printing plates of improved stoving resistance. The alloys consist es",Vially of at least 99.00% by weight of aluminium, from 0.02 to 0.15% by weight in total of zirconium and/or hafnium and from 0.05 to 0.25% by weight of manganese, with the remainder being incidental impurities. Improved stoving resistance is particularly shown with 0.02 to 0.08% zirconium and from 0.05 to 0.15% manganese, especially when stoving takes place at 240.degree. C. or above.Type: GrantFiled: July 15, 1992Date of Patent: December 13, 1994Assignee: Alcan International LimitedInventors: Peter K. F. Limbach, Graeme J. Marshall, Ricky A. Ricks
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Patent number: 5368658Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula: Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Hf, Nb, and Ta; anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25, the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.Type: GrantFiled: February 19, 1993Date of Patent: November 29, 1994Assignees: Yoshida Kogyo K.K., Tsuyoshi MasumotoInventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
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Patent number: 5344507Abstract: An aluminum-alloy, which is wear-resistant and does not wear greatly the opposed cast iron or steel, and which can be warm worked. The alloyings the following composition and structure. Composition: Al.sub.a Si.sub.b M.sub.c X.sub.d T.sub.e (where M is at least one element selected from the group consisting of Fe, Co and. Ni; X is at least one element selected from the group consisting of Y, Ce, La and Mm (misch metal); Y is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; a=50-85 atomic %, b=10-49 atomic %, c=0.5-10 atomic %, d=0.5-10 atomic %, e=0-10 atomic %, and a+b+c+d+e=100 atomic %. Structure: super-saturated face-centered cubic crystals and fine Si precipitates.Type: GrantFiled: March 16, 1992Date of Patent: September 6, 1994Assignees: Tsuyoshi Masumoto, Yoshida Kogyo KK, Teikoku Piston Ring Co., Ltd.Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Hitoshi Yamaguchi
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Patent number: 5334266Abstract: High strength, heat resistant aluminum-based alloys have a composition consisting of the following general formula Al.sub.a M.sub.b X.sub.d or Al.sub.a' M.sub.b Q.sub.c X.sub.d, wherein M is at least one metal element selected from the group consisting of Co, Ni, Cu, Zn and Ag; Q is at least one metal element selected from the group consisting of V, Cr, Mn and Fe; X is at least one metal element selected from the group consisting of Li, Mg, Si, Ca, Ti and Zr; and a, a', b, c and d are, in atomic percentages; 80.ltoreq.a.ltoreq.94.5, 80.ltoreq.a'.ltoreq.94, 5.ltoreq.b.ltoreq.15, 0.5.ltoreq.c.ltoreq.3 and 0.5.ltoreq.d.ltoreq.10. In the above specified alloys, aluminum intermetallic compounds are finely dispersed throughout an aluminum matrix and, thereby, the mechanical properties, especially strength and heat resistance, are considerably improved.Type: GrantFiled: November 23, 1992Date of Patent: August 2, 1994Assignee: Yoshida Kogyo K.K.Inventors: Makoto Kawanishi, Hidenobu Nagahama
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Patent number: 5332415Abstract: The present invention provides a compacted and consolidated aluminum-based alloy material which has been obtained by compacting and consolidating a rapidly solidified material having a composition represented by the general formula: Al.sub.a Ni.sub.b X.sub.c wherein X is one or two elements selected from Zr and Ti and a, b and c are, in atomic percentages, 87.5.ltoreq.a.ltoreq.92.5, 5 .ltoreq.b.ltoreq.10, and 0.5.ltoreq.c.ltoreq.5; and a production process comprising melting a material of the above composition; quenching and solidifying the resultant molten material into powder or flakes; compacting, compressing, forming and consolidating the powder or flakes by conventional plastic working. The consolidated material of the present invention has. elongation (toughness) sufficient to withstand secondary working, even when secondary working is applied. Moreover, the material allows the secondary working to be performed easily while retaining the excellent properties of its raw material.Type: GrantFiled: August 14, 1992Date of Patent: July 26, 1994Assignee: Yoshida Kogyo K.K.Inventor: Kazuhiko Kita
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Patent number: 5320688Abstract: The present invention provides high strength, heat resistant aluminum-based alloys having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.cwherein:M is at least one metal element selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si;X is at least one metal element selected from the group consisting of Y, La, Ce, Sm, Nd, Hf, Nb, Ta and Mm (misch metal); anda, b and c are atomic percentages falling within the following ranges:50.ltoreq.a.ltoreq.95, 0.5.ltoreq.b.ltoreq.35 and 0.5.ltoreq.c.ltoreq.25,the aluminum-based alloy being in an amorphous state, microcrystalline state or a composite state thereof. The aluminum-based alloys possess an advantageous combination of properties of high strength, heat resistance, superior ductility and good processability which make then suitable for various applications.Type: GrantFiled: February 19, 1993Date of Patent: June 14, 1994Assignees: Yoshida Kogyo K. K., Tsuyoshi MasumotoInventors: Tsuyoshi Masumoto, Akihisa Inoue, Katsumasa Odera, Masahiro Oguchi
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Patent number: 5286316Abstract: An aluminum-based alloy composition having improved corrosion resistance and high extrudability consists essentially of about 0.1-0.5% by weight of manganese, about 0.05-0.12% by weight of silicon, about 0.10-0.20% by weight of titanium, about 0.15-0.25% by weight of iron and the balance aluminum, wherein the aluminum alloy is essentially copper free. The inventive alloy is useful in automotive applications, in particular, heat exchanger tubing and finstock, and foil packaging. The process provided by the invention uses a high extrusion ratio and produces a product having high corrosion resistance.Type: GrantFiled: April 3, 1992Date of Patent: February 15, 1994Assignee: Reynolds Metals CompanyInventor: Kenneth D. Wade
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Patent number: 5284532Abstract: A rapidly solidified aluminum based alloy consists essentially of the formula Al.sub.bal Fe.sub.a M.sub.b Si.sub.c R.sub.d, wherein M is at least one element selected from the group consisting of V, Mo, Cr, Mn, Nb, Ta, and W; R is at least one element selected from the group consisting of La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, and Y; "a" ranges from 3.0 to 7.1 atom %; "b" ranges from 0.25 to 1.25 atom %; "c" ranges from 1.0 to 3.0 atom %; "d" ranges from 3.0 to 0.3 atom % and the balance is aluminum plus incidental impurities, with the provisos that (i) the ratio [Fe+M]:Si ranges from about 2.0:1 to 5.0:1 and (ii) the ratio Fe:M ranges from about 16:1 to 5:1. The alloy exhibits improved elevated temperature strength due to the rare earth element additions without an increase in the volume fraction of dispersed intermetallic phase precipitates therein.Type: GrantFiled: January 14, 1993Date of Patent: February 8, 1994Assignee: Allied Signal Inc.Inventor: David J. Skinner
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Patent number: 5279642Abstract: Disclosed herein is a process for producing a high strength aluminum-based alloy powder comprising mixing Al or Al alloy powder with an Al--T--X alloy powder, wherein T is at least one selected from the group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, W, Ca, Li, Mg and Si; X is at least one selected from the group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd, Zr and Ti or Mm; and mechanically alloying the formed powder mixture. The aluminum-based alloy powder is excellent in workability and reliability by virtue of its high strength stability in the temperature range of from room temperature to an elevated temperature, its excellent ductility in the same temperature range and its low thermal expansion coefficient in the same temperature range.Type: GrantFiled: July 7, 1992Date of Patent: January 18, 1994Assignee: Yoshida Kogyo K.K.Inventor: Katsumasa Ohtera
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Patent number: 5264021Abstract: A compacted and consolidated aluminum-based alloy material is obtained by compacting and consolidating a rapidly-solidified material having a composition represented by the general formula: Al.sub.a Ni.sub.b X.sub.c M.sub.d or Al.sub.a' Ni.sub.b X.sub.c M.sub.d Q.sub.e, where X is one or two elements selected from La and Ce or an Mm; M is Zr or Ti; Q is one or more elements selected from Mg, Si, Cu and Zn, and a, a', b, c, d and e are, in atomic percentages, 84.ltoreq.a.ltoreq.94.8, 82.ltoreq.a'.ltoreq.94.6, 5.ltoreq.b .ltoreq.10, 0.1.ltoreq.c.ltoreq.3, 0.1.ltoreq.d.ltoreq.3, and 0.2.ltoreq.e.ltoreq.2. According to the production process of the invention, powder or flakes obtained by rapidly solidifying are compacted, followed by compressing, forming and consolidating by conventional plastic working operations. The consolidated material has an elongation sufficient to withstand secondary working operations. Moreover, the material retains the excellent properties of its raw material as they are.Type: GrantFiled: August 14, 1992Date of Patent: November 23, 1993Assignee: Yoshida Kogyo K.K.Inventors: Kazuhiko Kita, Makoto Kawanishi, Hidenobu Nagahama