Titanium, Zirconium, Hafnium, Vanadium, Niobium, Or Tantalum Containing Patents (Class 420/552)
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Patent number: 4847047Abstract: A method of increasing the dissolution rate of titanium or titanium alloys in molten aluminum is disclosed which comprises placing a titanium rod into molten aluminum and applying ultrasonic energy to the rod. The ultrasonic energy enhances the dissolution of the titanium in aluminum, homogenizes the molten alloy, and breaks up particles such as TiAl.sub.3 which form into a layer at the surface of the melt. The application of ultrasonic energy increases the dissolution rate of solid titanium in molten aluminum, decreases the amount of time needed to achieve homogeneity, and results in a titanium-aluminum alloy with a reduction in grain size and improved properties.Type: GrantFiled: May 29, 1987Date of Patent: July 11, 1989Assignee: The United States of America as represented by the Secretary of the InteriorInventors: John G. Groetsch, Jr., Timothy H. Elkins, Jr., Charles A. Sorrell
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Patent number: 4842821Abstract: The invention provides a method of producing an alloy containing titanium carbide particles, the method comprising thoroughly dispersing carbon powder particles into a metal melt, and causing the dispersed carbon particles to react with titanium within the metal melt so as to produce a dispersion of fine particles comprising titanium carbide within the melt. A preferred use for alloys produced by the invention is as a grain refiner for aluminium-based metals, especially those containing zirconium, chromium and/or manganese, which tend to poison current titanium-boron-aluminium grain refiners.Type: GrantFiled: March 29, 1988Date of Patent: June 27, 1989Assignee: London & Scandinavian Metallurgical Co. LimitedInventors: Abinash Banerji, Winfried Reif
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Patent number: 4834942Abstract: An aluminum-titanium alloy and a process of making it, the alloy consisting ssentially of aluminum, 4-6 wt. % titanium, 1-2 wt. % carbon, and 0.1-0.2 wt % oxygen. The alloy is an aluminum matrix supersaturated with titanium, and having throughout a fine, homogeneous dispersion of Al.sub.3 Ti particles. It is fine grained and has grain boundary dispersoids of carbides and oxides, predominantly of aluminum. An aluminum-titanium melt is rapidly solidified and then mechanically alloyed in the presence of a carbon-bearing agent. The resulting powder is degassed and hot consolidated to form articles which exhibit high strength, ductility, and creep resistance at temperatures greater than 200.degree. C.Type: GrantFiled: January 29, 1988Date of Patent: May 30, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: William E. Frazier, Michael J. Koczak
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Patent number: 4812290Abstract: Provided is an improved aluminum-titanium master alloy containing carbon in a small but effective content and not more than about 0.1%. After melting, the master alloy is superheated to about 1200.degree.-1250.degree. C. to put the carbon into solution, then the alloy is cast in a workable form. The master alloy in final form is substantially free of carbides greater than about 5 microns in diameter. The alloy of this invention is used to refine aluminum products that may be rolled into thin sheet, foil, or fine wire and the like.Type: GrantFiled: September 8, 1986Date of Patent: March 14, 1989Assignee: KB Alloys, Inc.Inventor: Geoffrey K. Sigworth
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Patent number: 4808372Abstract: An in situ process is provided for producing a composite comprising a refractory material dispersed in a solid matrix. A molten composition comprising a matrix liquid, and at least one refractory carbide-forming component are provided, and a gas is introduced into the molten composition. A reactive component is also provided for reaction with the refractory material-forming component. The refractory material-forming component and reactive component react to form a refractory material dispersed in the matrix liquid, and the liquid composite is cooled to form a solid composite material. In one embodiment, the reactive component is a carbonaceous component in the form of a component of the gas, a solid in the gas or the molten composition, or both. The carbonaceous component is provided for reaction with a refractory carbide-forming component to yield a refractory carbide. In a preferred embodiment, the matrix liquid is molten aluminum and the refractory carbide-forming component is tantalum.Type: GrantFiled: January 23, 1986Date of Patent: February 28, 1989Assignee: Drexel UniversityInventors: Michael J. Koczak, K. Sharvan Kumar
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Patent number: 4787943Abstract: An aluminum alloy containing about 2 to 6 weight percent titanium, about 3 to 11 weight percent of a rare earth of the Lanthanide Series and up to about 3 weight percent of at least one Group VIII metal, balance aluminum, is disclosed. The alloy is preferably prepared by rapid solidification in powder, particulate or ribbon form, and is subsequently compacted under controlled conditions.Type: GrantFiled: April 30, 1987Date of Patent: November 29, 1988Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Yashwant R. Mahajan, Susan D. Kirchoff, Francis H. Froes
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Patent number: 4765851Abstract: An aluminum alloy for the production of powders having increased high-temperature strength by rapid quenching, the said alloy containing 1.5 to 5% by weight of Li, 4 to 11% by weight of Fe and 1 to 6% by weight of at least one of the elements Mo, V or Zr, the remainder being Al, or 1.5 to 5% by weight of Li, 4 to 7% by weight of Cr and 1 to 4% by weight of at least one of the elements V or Mn, the remainder being Al. A low density and good high-temperature strength as well as good thermal stability up to 400.degree. C. coupled with Vickers hardnesses of up to 180 (HV) are achieved. Hardness-imparting dispersoids in the form of the phases Al.sub.3 Li and Al.sub.3 Zr, as well as other intermetallic compounds of Al with Mo, V or Mn, having a particle diameter of no more than 0.1 .mu.m, constitute a large volume fraction.Type: GrantFiled: June 18, 1986Date of Patent: August 23, 1988Assignee: BBC Brown, Boveri & Company, LimitedInventor: Malcolm J. Couper
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Patent number: 4749627Abstract: Al and Al alloy materials for a fin are disclosed which contain Fe of 0.2% or less and Si of 0.1% or less and exhibit improved thermal conductivity, sacrificial anode effect and sagging resistance. Also, a heat exchanger having a fin made of the Al and Al alloy material incorporated therein is disclosed. The heat exchanger is lightweight and excellent in corrosion resistance and heat radiation.Type: GrantFiled: February 27, 1985Date of Patent: June 7, 1988Assignees: Furukawa Aluminum Co., Ltd., Sanden CorporationInventors: Kazunori Ishikawa, Hiroshi Kawase, Tooru Yamaguchi, Mikio Koisuka, Toshio Aoki
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Patent number: 4748001Abstract: The invention provides a method of producing an alloy containing titanium carbide particles, the method comprising thoroughly dispersing carbon powder particles into a metal melt, and causing the dispersed carbon particles to react with titanium within the metal melt so as to produce a dispersion of fine particles comprising titanium carbide within the melt. A preferred use for alloys produced by the invention is as a grain refiner for aluminium-based metals, especially those containing zirconium, chromium and/or manganese, which tend to poison current titanium-boron-aluminium grain refiners.Type: GrantFiled: March 3, 1986Date of Patent: May 31, 1988Assignee: London & Scandinavian Metallurgical Co LimitedInventors: Abinash Banerji, Winfried Reif
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Patent number: 4735867Abstract: A novel aluminum alloy contains vanadium as an alloying element, at a concentration ranging from about 0.02% to about 0.4% by weight. The vanadium imparts corrosion resistance to the alloy, particularly when the alloy is used as a core alloy in a vacuum brazing sheet. A further improvement in corrosion resistance is achieved by processing the alloy or brazing sheet in such a manner that the final processing step is a cold work to a reduction of about 10% to about 20%.Type: GrantFiled: December 6, 1985Date of Patent: April 5, 1988Assignee: Kaiser Aluminum & Chemical CorporationInventor: Walter D. Finnegan
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Patent number: 4729790Abstract: A rapidly solidified aluminum-base alloy consists essentially of the formula Al.sub.bal Fe.sub.a Si.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of Mn, V, Cr, Mo, W, Nb, Ta, "a" ranges from 1.5 to 7.5 atom percent, "b" ranges from 0.75 to 9.0 atom percent, "c" ranges from 0.25 to 4.5 atom percent and the balance is aluminum plus incidental impurities, with the proviso that the ratio [Fe+X]:Si ranges from about 2.01:1 to 1.0:1. The alloy exhibits high strength, ductility and fracture toughness and is especially suited for use in high temperature structural applications such as gas turbine engines, missiles, airframes and landing wheels.Type: GrantFiled: March 30, 1987Date of Patent: March 8, 1988Assignee: Allied CorporationInventor: David J. Skinner
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Patent number: 4726843Abstract: Aluminum alloy, suitable for rapid quenching from a melt supersaturated with alloy components, which contains 2 to 5.5% by weight of Cr and 2 to 5.5% by weight of V, the remainder being Al, and may contain further added amounts of Mo, Zr, Ti or Fe, individually or in combination, up to a total content of not more than 1% by weight, the total content of all alloy elements being no more than 10% by weight. The simultaneous occurrence of the phases Al.sub.13 Cr.sub.2 and Al.sub.10 V in silid solution and as hardness-imparting dispersoids having a particle diameter of not more than 0.1 .mu.m results in good high-temperature strength and thermal stability coupled with good ductility and toughness of the material. The comparatively Low Vickers hardness of, on average, only about 130 (HV) for the rapidly solidified alloys initially obtained make the powders readily processable. After the heat treatment, the Vickers hardness of the workpiece reaches values up to about 200 (HV).Type: GrantFiled: June 18, 1986Date of Patent: February 23, 1988Assignee: BBC Brown, Boveri & Company LimitedInventor: Malcolm J. Couper
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Patent number: 4684506Abstract: A master alloy for producing titanium-based alloys with high molybdenum content and capable of ensuring the solution and distribution of the molybdenum in the titanium based alloy consists essentially of 25 through 36% by weight molybdenum, 15 to 18% by weight vanadium, up to about 7% by weight titanium, the balance aluminum and wherein the molybdenum content is at least 1.4 times the vanadium content and the melting point is at most 1500.degree. C.Type: GrantFiled: November 6, 1985Date of Patent: August 4, 1987Assignee: GFE Gesellschaft fur Elektrometallurgie mbHInventors: Reinhard Hahn, Hermann Andorfer
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Patent number: 4668470Abstract: A method for forming intermetallic and intermetallic-type precursor alloys for subsequent mechanical alloying applications. Elemental powders are blended in proportions approximately equal to their respective intermetallic compounds. Heating of the blend results in the formation of intermetallic compounds whereas lack of heating results in intermetallic-type powder without the intermetallic structure. The resultant powder is then blended to form a final alloy. Examples involving aluminum-titanium alloys are discussed.Type: GrantFiled: December 16, 1985Date of Patent: May 26, 1987Assignee: Inco Alloys International, Inc.Inventors: Paul S. Gilman, Arun D. Jatkar, Stephen Donachie, Winfred L. Woodard, III, Walter E. Mattson
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Patent number: 4624705Abstract: Aluminum-base alloys and a method of preparing aluminum-base alloys by mechanical alloying in the presence of a carbidiferous processing aid wherein a strong carbide former such as titanium is included so as to produce carbides in the final alloy more thermally stable at temperatures in excess of 100.degree. C. than Al.sub.4 C.sub.3.Type: GrantFiled: April 4, 1986Date of Patent: November 25, 1986Assignee: Inco Alloys International, Inc.Inventors: Arun D. Jatkar, Paul S. Gilman, Raymond C. Benn
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Patent number: 4624831Abstract: A composition of matter comprises aluminium or aluminium alloy, such as LM 13, into which has been incorporated between 5 and 50% by volume of zirconia. The zirconia may be in the form of fibres or of powder. As compared with the aluminium alloy, this reduces the thermal conductivity and coefficient of expansion, and provides a material which has, particularly at elevated temperatures above 300.degree. C., improved tensile strength, compressive strength, and hardness and reduced elongation.Type: GrantFiled: August 12, 1985Date of Patent: November 25, 1986Assignee: Ae PlcInventor: Norman Tommis
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Patent number: 4623513Abstract: Titanium-silver alloys containing specified amounts of silver and titanium and controlled amounts of copper, aluminum and mixtures thereof are suitable for brazing ceramics, other non-metallic and metallic materials. These alloys also may contain controlled amounts of tin, palladium, indium and mixtures thereof.Type: GrantFiled: September 20, 1984Date of Patent: November 18, 1986Assignee: GTE Products CorporationInventor: Howard Mizuhara
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Patent number: 4576791Abstract: A master alloy for modifying the eutectic phase of an aluminium-silicon eutectic or hypo-eutectic casting alloy, and consisting essentially of, in weight percent: 4-20% strontium, 0.2-5% titanium, up to 1% boron, the balance being aluminium and impurities.Type: GrantFiled: February 27, 1984Date of Patent: March 18, 1986Assignee: Anglo Blackwells LimitedInventor: Stuart R. Thistlethwaite
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Patent number: 4448605Abstract: Brazing alloys containing up to a specified amount of a reactive metal selected from the group consisting of titanium, zirconium, vanadium and mixtures thereof and only one metal selected from the group consisting of silver, gold, palladium, iron, nickel, copper and aluminum are ductile and can be rolled into foils.Type: GrantFiled: December 2, 1982Date of Patent: May 15, 1984Assignee: GTE Products CorporationInventor: Howard Mizuhara
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Patent number: 4383970Abstract: A process for preparation of graphite-containing aluminum alloys includes incorporating graphite particles into an aluminum containing melt. When the graphite particles are incorporated, floating of the graphite particles to the surface of the melt is prevented by the use of certain additive metals. Before the graphite particles are incorporated into the melt, titanium, chromium, zirconium, nickel, vanadium, cobalt, manganese, niobium or phosphorus is incorporated and dispersed into the melt. The produced aluminum alloys are suitable to use as dry frictional contacts such as bearings.Type: GrantFiled: April 11, 1980Date of Patent: May 17, 1983Assignees: Hitachi, Ltd., Hitachi Chemical Company, Ltd.Inventors: Katsuhiro Komuro, Masateru Suwa, Koh Soeno, Masato Ohsawa
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Patent number: 4377425Abstract: An improved cast ingot of aluminum alloy satisfactorily available for rolling operation containing Fe is disclosed which has no fir-tree structure or has only a very small region of fir-tree structure. This cast ingot of aluminum alloy contains calcium in the range of 0.0005 to 0.05% and has a grain size smaller than 150 microns in the region extended inward of a coarse cell phase on the surface area of the cast ingot, particularly in the vicinity of said coarse cell phase. The cast ingot is manufactured by way of the steps of addition of the above amount of calcium to molten aluminum alloy, supplementary addition of 0.005 to 0.1% Ti and 0.0001 to 0.02% B to the molten aluminum alloy and then continuous D.C. casting.Type: GrantFiled: November 19, 1980Date of Patent: March 22, 1983Assignees: Showa Aluminum Ind. K.K., Showa Aluminum Corp.Inventors: Takeshi Otani, Osamu Watanabe, Masashi Sakaguchi
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Patent number: 4375500Abstract: An aluminum-tin (Al-Sn) base bearing alloy and a bearing material which is made by applying the Al-Sn base bearing alloy to a backing steel sheet by pressure welding. The Al-Sn base bearing alloy of the invention is characterized in that the coarsening of tin particles and the lowering of the hardness under high temperature conditions are quite small so that the wear resistance as well as the fatigue strength of the alloy are quite excellent. The Al-Sn base bearing alloy comprises 3.0-35 wt. % of Sn; at least 0.1 wt. % of Cr; at least 1.0 wt. % of Zr, with the proviso that the total amount of Cr and Zr is not more than 10 wt. %; and the remainder of aluminum. The Al-Sn base bearing alloy of the invention can further contain 3 wt. % or less in total of Cu and/or Mg and 9 wt. % or less in total of one or more members of Pb, Bi, In, Tl and Cd, thereby improving the bearing characteristics.Type: GrantFiled: January 26, 1981Date of Patent: March 1, 1983Assignee: Taiho Kogyo Co., Ltd.Inventors: Tamotsu Nara, Soji Kamiya