Rare Earth Metal Containing Patents (Class 420/83)
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Patent number: 4773950Abstract: A magnetically anisotropic sintered permanent magnet of the FeBR system in which R is sum of R.sub.1 and R.sub.2 wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2 and the balance of at least one of other rare earth elements exclusive of R.sub.1,said system comprising by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B, and the balance being Fe with impurities. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W,) may be present.Type: GrantFiled: September 15, 1983Date of Patent: September 27, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
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Patent number: 4770702Abstract: A rare earth-iron-boron alloy powder which consists essentially of:12.5 to 20 at % R wherein R.sub.1 is 0.05 to 5 at %, 4 to 20 at % B, and 60 to 83.5 at % Fe,wherein R.sub.1 is at least one heavy rare earth element selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm and Yb, 80 to 100 at % of R.sub.2 consists of Nd and/or Pr, the balance in the R.sub.2 being at least one element selected from the group consisting of rare earth elements including Y and except for R.sub.1, and R=R.sub.1 =R.sub.2 by atomic %, wherein a major phase of at least 80 vol % of the entire alloy coinsists of a tetragonal structure, and wherein oxygen does not exceed 10,000 ppm, carbon does not exceed 1000 ppm and calcium does not exceed 2000 ppm. The alloy powder is produced by directly reducing a mixture comprising rare earth oxide, iron and other ingredients or oxide thereof with a reducing agent Ca and CaCl.sub.2, putting the reduced product into water, then treating with water. Up to 35 at % Co may be substituted for Fe.Type: GrantFiled: January 20, 1988Date of Patent: September 13, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
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Patent number: 4770723Abstract: Magnetic materials comprising Fe, B and R (rare earth elements) having a major phase of Fe--B--R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe--B--R--M type materials and magnets.Type: GrantFiled: February 10, 1987Date of Patent: September 13, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Masato Sagawa, Setsuo Fujimura, Yutaka Matsuura
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Patent number: 4769063Abstract: A rare earth alloy for producing permanent magnet comprised of: 15-65 atomic % R.sub.1, 35-83 atomic % Fe, and 0-15 atomic % B, where R.sub.1 represents at least one of heavy rare earth elements Gd, Tb, Dy, Ho, Er, Tm and Yb. This alloy is produced by reducing a mixture of correspoding rare earth oxides, Fe, and a boron containing material by Ca, contacting the reduced mass with water, and treating the resultant slurry with water. Using this alloy, Fe-B-R base magnets wherein R.sub.1 is substituted for part of R (R representing lanthanide and/or Y) having a high performance are produced with a reduced cost.Type: GrantFiled: February 26, 1986Date of Patent: September 6, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
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Patent number: 4767450Abstract: A rare earth-iron-boron alloy powder which consists essentially of:12.5 to 20 at % R wherein R.sub.1 is 0.05 to 5 at %, 4 to 20 at % B, and 60 to 83.5 at % Fe,wherein R.sub.1 is at least one heavy rare earth element selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm, and Yb, 80 to 100 at % of R.sub.2 consists of Nd and/or Pr, the balance in the R.sub.2 being at least one element selected from the group consisting of rare earth elements including Y and except for R.sub.1, and R=R.sub.1 +R.sub.2 by atomic %, wherein a major phase of at least 80 vol % of the entire alloy coinsists of a tetragonal structure, and wherein oxygen does not exceed 10,000 ppm, carbon does not exceed 1000 ppm and calcium does not exceed 2000 ppm. The alloy powder is produced by directly reducing a mixture comprising rare earth oxide, iron and other ingredients or oxide thereof with a reducing agent Ca and CaCl.sub.2, putting the reduced product into water, then treating with water. Up to 35 at % Co may be substituted for Fe.Type: GrantFiled: November 25, 1985Date of Patent: August 30, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
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Patent number: 4767474Abstract: Isotropic permanet magnet formed of a sintered body having a mean crystal grain size of 1-130 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B, no more than 50% of Co and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder meallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.Type: GrantFiled: December 30, 1983Date of Patent: August 30, 1988Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
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Patent number: 4765848Abstract: In the rare earth-iron-boron permanent magnet, Ce and La decrease the magnetic properties when used alone but synergistically enhance iHc when used in combination.The composition provided by the present invention is generally expressed by [(Ce.sub.x La.sub.1-x).sub.y R.sub.1-y ].sub.z [(Fe.sub.1-u-w Co.sub.w M.sub.u).sub.1-v B.sub.v ].sub.1-z with a proviso of 0.4.ltoreq.x.ltoreq.0.9, 0.2<y.ltoreq.1.0, 0.05.ltoreq.z.ltoreq.0.3, 0.01.ltoreq.v.ltoreq.0.3, 0.ltoreq.u.ltoreq.0.2, 0.ltoreq.w.ltoreq.0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag.Type: GrantFiled: December 27, 1985Date of Patent: August 23, 1988Assignee: Kaneo MohriInventors: Kaneo Mohri, Jiro Yamasaki
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Patent number: 4756775Abstract: Magnetically hard compositions having high values of coercivity, remanence and energy product contain rare earth elements, transition metal elements and boron in suitable proportions. The preferred rare earth elements are neodymium and praseodymium, and the preferred transition metal element is iron. The magnetic alloys have characteristic very finely crystalline microstructures.Type: GrantFiled: October 26, 1983Date of Patent: July 12, 1988Assignee: General Motors CorporationInventor: John J. Croat
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Patent number: 4721538Abstract: A rare-earth element permanent magnet alloy characterized by good magnetic alignment and high energy product, said magnet consisting essentially of, in atomic percent, at least one rare earth element didymium, mischmetal, neodymium and thorium 12 to 20, boron 4 to 14 and balance iron.Type: GrantFiled: June 20, 1986Date of Patent: January 26, 1988Assignee: Crucible Materials CorporationInventors: Kalathur S. V. L. Narasimhan, Bao-Min Ma
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Patent number: 4670353Abstract: A magnetooptical recording medium comprises a ternary amorphous magnetic alloy of Tb-Fe-Co.Type: GrantFiled: October 1, 1985Date of Patent: June 2, 1987Assignee: Canon Kabushiki KaishaInventor: Yoshifumi Sakurai
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Patent number: 4668310Abstract: Amorphous alloys having high strength, high hardness, high crystallization temperature, high saturation magnetic induction, low coercive force, high magnetic permeability and particularly low deterioration of magnetic properties with lapse of time, have a composition formula ofT.sub.a X.sub.b Z.sub.c or T.sub.a' X.sub.b' Z.sub.c' M.sub.d,whereinT is at least one of Fe, Co and Ni,X is at least one of Zr, Ti, Hf and Y,Z is at least one of B, C, Si, Al, Ge, Bi, S and P,a is 70-98 atomic %,b is not more than 30 atomic %,c is not more than 15 atomic %,sum of a, b and c is 100 atomic %,M is at least one Mo, Cr, W, V, Nb, Ta, Cu, Mn, Zn, Sb, Sn, Be, Mg, Pd, Pt, Ru, Os, Rh, Ir, Ce, La, Pr, Nd, Sm, Eu, Gd, Tb and Dy,a' is 70-98 atomic %,b' is not more than 30 atomic %,c' is not more than 15 atomic %,d is not more than 20 atomic %, andsum of a', b', c' and d is 100 atomic %.Type: GrantFiled: March 14, 1983Date of Patent: May 26, 1987Assignees: Hitachi Metals, Ltd., Hitachi, Ltd.Inventors: Mitsuhiro Kudo, Shinji Takayama, Yoshizo Sawada, Yasunobu Ogata
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Patent number: 4664724Abstract: A permanent magnetic alloy essentially consists of 10 to 40% by weight of R, 0.1 to 8% by weight of boron, 50 to 300 ppm by weight of oxygen and the balance of iron, where R is at least one component selected from the group consisting of yttrium and the rare-earth elements.An alloy having this composition has a high coercive force .sub.I H.sub.C and a high residual magnetic flux density and therefore has a high maximum energy product.Type: GrantFiled: September 9, 1985Date of Patent: May 12, 1987Assignee: Kabushiki Kaisha ToshibaInventors: Tetsuhiko Mizoguchi, Koichiro Inomata, Toru Higuchi, Isao Sakai
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Patent number: 4663066Abstract: New magnetic hydride Nd.sub.2 Fe.sub.14 BH.sub.x (0<x<5) and family corresponding to other rare earths and yttrium. Possible substitution of Fe by Co. Preparation from Nd.sub.2 Fe.sub.14 B by hydrogenation (ambient temperature; pH.sub.2 >20 bar), which can be reversed to give powdered Nd.sub.2 Fe.sub.14 B. Remarkable magnetic properties.Type: GrantFiled: June 19, 1985Date of Patent: May 5, 1987Assignee: Centre National de la Recherche ScientifiqueInventors: Robert Fruchart, Roland Madar, Alain Rouault, Philippe L'Heritier, Pierre Taunier, Daniel Boursier, Daniel Fruchart, Patrick Chaudouet
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Patent number: 4650645Abstract: A heat-resisting steel suitable for use in valve parts of internal combustion engine is disclosed, which consists essentially by weight percentage of 0.3-0.5% of C, more than 1.0% to 2.5% of Si, 0.1-2.0% of Mn, 0.5-7.0% of Cr, 0.3-2.0% of Mo and 0.1-1.0% of V as basic ingredients, at least one of 0.3-2.0% of Cu and 0.001-0.05% of REM as sub-ingredients and if necessary, at least one of 0.1 to less than 2.0% of Ni, 0.1-1.5% of W and 0.03-1.0% of Nb+Ta, and the balance of Fe and inevitable impurities.Type: GrantFiled: December 3, 1984Date of Patent: March 17, 1987Assignee: Daido Steel Company LimitedInventors: Tetsuo Kato, Susumu Isobe, Kenkichi Matsunaga
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Patent number: 4623387Abstract: Amorphous alloys containing zirconium as an amorphous forming metal and having teh formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.Type: GrantFiled: February 5, 1985Date of Patent: November 18, 1986Assignee: Shin-Gijutsu Kaihatsu JigyodanInventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
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Patent number: 4620872Abstract: A novel composite target material that is composed of a rare earth metal and a transition metal (iron-group metal) and which is used in the formation of a thin magnetooptical recording film by sputtering is disclosed. Also disclosed is a process for producing such composite target material.The process comprises the steps of providing a rare earth metal and an iron-group transition metal as separate entities, mixing these metals without alloying, and hot-forming the mixture at a temperature lower than the eutectic point of the system of metallic components in the mixture, thereby forming an intermetallic compound at the interface between the rare earth metal and the transition metal while causing said metals to be bonded together.The target material produced by this process contains 30-50 wt % of the rare earth metal, with the balance being made of the iron-group transition metal and incidental impurities.Type: GrantFiled: October 15, 1985Date of Patent: November 4, 1986Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Kenichi Hijikata, Katsuyuki Sato, Hitoshi Maruyama, Ryoko Furuhashi
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Patent number: 4612068Abstract: Amorphous thin film with easy magnetization axis perpendicular to film surface for magneto-optical recording with low recording power and high S/N in reading signal is set forth. The medium is an alloy of heavy rare earth element and iron with substitution of some heavy rare earth elements by light rare earth element, and the preferable chemical formula of the thin film is (R.sub.z A.sub.1-z).sub.x Fe.sub.1-x, or [(R.sub.z A.sub.1-z).sub.y B.sub.1-y ].sub.x Fe.sub.1-x where R is a light rare earth element, A and B are heavy rare earth elements, and the atom ratios satisfy 0.15.ltoreq.x.ltoreq.0.35, 0.00<y<1.00, 0.00<z<1.00. Recording is effected by using Curie point, or magnetic compensation temperature, and reading of information is effected by using the Kerr effect.Type: GrantFiled: March 20, 1984Date of Patent: September 16, 1986Assignee: Kokusai Denshin Denwa Co., Ltd.Inventors: Shinsuke Tanaka, Nobutake Imamura
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Patent number: 4612047Abstract: An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.Type: GrantFiled: October 28, 1985Date of Patent: September 16, 1986Assignee: The United States of America as represented by the United States Department of EnergyInventors: Frederick A. Schmidt, David T. Peterson, John T. Wheelock