Using Organic Carboxylic Acid Or Salt Thereof Patents (Class 422/17)
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Patent number: 9758880Abstract: A method for controlling water chemistry in a power generation plant including a low-pressure feedwater heater (18), a deaerator (19), and a high-pressure feedwater heater (20) disposed sequentially along a feedwater pipe (16) from a condenser (15) to a steam generator or a boiler (11) to control the chemistry of feedwater guided to the steam generator or the boiler includes the steps of: injecting an oxidant through an oxidant injection line (31) into feedwater flowing through the feedwater pipe disposed downstream of the condenser in such a way that a dissolved oxygen concentration in the feedwater ranges from 3 to 100 ppb while the feedwater is maintained to be neutral to form an oxide film on surfaces of the feedwater pipe, the low-pressure feedwater heater, the deaerator, the high-pressure feedwater heater, and other structural members that come into contact with the feedwater; and injecting a deoxidant through a deoxidant injection line (35) into the feedwater flowing through the feedwater pipe disposedType: GrantFiled: March 9, 2010Date of Patent: September 12, 2017Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Toyoaki Miyazaki, Masato Okamura, Osamu Shibasaki, Hajime Hirasawa
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Publication number: 20150118105Abstract: Pitting corrosion of stainless steel occurs in solutions of organic acid, such as tartaric acid, in an electrolyte solution with methanol. However, methanolic solutions containing at least one organic halide and at least one organic hydroxyacid and some water provide reduced pitting corrosion of stainless steel. The organic hydroxyacid may be a hydroxy acid containing 2 to 10 carbon atoms with at least one hydroxyl group and at least one carboxylic acid group, in a non-limiting example, glycolic acid. The pH of the methanolic solution may range from about 3.5 to about 8.Type: ApplicationFiled: October 15, 2014Publication date: April 30, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: Zhengwei Liu, Sunder Ramachandran, Vaithilingam Panchalingam, Timothy Z. Garza, Paul Robert Stead, Stuart Edward Cook, Gordon T. Rivers, Vu Thieu, Heather Mceachern
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Patent number: 8951467Abstract: An embodiment prevents equipment fouling (deposition of unwanted material) in an oil recovery system via implementing passivation of metallic components. By preventing or at least slowing or inhibiting corrosion of equipment or components via passivation, such as passivating heat exchangers, metallic piping, and the like, an embodiment in turn reduces fouling thereof. Other embodiments are described and claimed.Type: GrantFiled: March 15, 2013Date of Patent: February 10, 2015Assignee: Chemtreat, Inc.Inventors: Robert Wright Bedinger, III, Benjamin Edward Niemaseck, Mark Jason Puchovich, John Richardson
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Patent number: 8940227Abstract: The present invention relates to the use of a polyesteramine or a polyester polyquaternary ammonium compound as a corrosion inhibitor for metal surfaces, and to a method for protecting a metal surface from corrosion by contacting the metal surface with said corrosion inhibitor.Type: GrantFiled: August 26, 2011Date of Patent: January 27, 2015Assignee: Akzo Nobel Chemical International B.V.Inventors: Per-Erik Hellberg, Natalija Gorochovceva
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Publication number: 20150004054Abstract: There are provided methods of suppressing corrosion of a corrodible metal surface that contacts a water stream in a water system, the method comprising: (a) introducing into the water stream a shot dose of a treatment composition comprising a corrosion inhibitor, the shot dose being introduced into the water stream over a first time period and the water stream having a first concentration of corrosion inhibitor during the first time period; (b) then reducing the amount of treatment composition that is introduced into the water stream; and (c) after the first time period, maintaining a second concentration of corrosion inhibitor in the water stream over a second time period, the second concentration being less than 25% of the concentration of corrosion inhibitor during the first time period.Type: ApplicationFiled: June 26, 2014Publication date: January 1, 2015Inventors: John RICHARDSON, Rajendra KALAKODIMI, DeAnn WILLS-GUY
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Patent number: 8920714Abstract: A corrosion prevention and control composition and method comprises combining primarily two-component polyurethane foam formed by reacting polyols with an isocyanate compound, and a 2 to 10 percent by weight of either an organic or inorganic gas-phase corrosion inhibitor. The closed cell foam provides a barrier protection for the underlying corrodible surface, while the inhibitor protects the metal from the absorbed moisture vapor, thereby preventing corrosion from occurring at the foam/metal interface. The resulting foam and inhibitor composition maintains better adhesion to the underlying corrodible structure in corrosive environments.Type: GrantFiled: November 5, 2012Date of Patent: December 30, 2014Assignee: The United States of America as represented by the Secretary of the ArmyInventor: John V. Kelley, II
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Publication number: 20140314620Abstract: An oxygen scavenger composition is effective in reducing oxygen-induced corrosion in aqueous systems that contain water, oxygen and a significant proportion (at least about 20 wt %) of a glycol, such as monoethylene glycol (MEG). The oxygen scavenger composition contains a sulfite, a transition metal salt, and a stabilizer to enhance the kinetics of oxygen removal (scavenging). The oxygen scavenger composition is particularly suitable when the transition metal salt component includes at least two different transition metals together, such as Ni and Co, or Ni and Mn.Type: ApplicationFiled: April 19, 2013Publication date: October 23, 2014Applicant: Baker Hughes IncorporatedInventors: Marc N. Lehmann, Christopher William Bowman, Wai Yeung Mok, Neil Jonathan Barr
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Patent number: 8828273Abstract: Disclosed is a concentrated cooling water additive that is substantially non-corrosive within a pH range of 2-12 and contains polymeric dispersant(s) and aromatic azole(s) that exhibits improved stability, possibly as a result of the interaction of the hydrophobic groups in the dispersant polymer and the aromatic azole(s). This improved stability allows for both reduced corrosivity of the formula and reduced manufacturing costs. Benefits of the disclosed formulations include improved safety for handling and shipment, more concentrated formulations available in liquid form, reduced shipping costs and storage space, reduced heat of neutralization during product manufacture, reduced costs of manufacture due to removal of need for caustic or acid addition and reduced environmental compliance costs associated with washing and waste handling step.Type: GrantFiled: May 28, 2010Date of Patent: September 9, 2014Assignee: Chemtreat, Inc.Inventors: John Richardson, Dale P. Stuart
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Publication number: 20140241939Abstract: A new corrosion inhibitor composition containing a carboxylic acid and its water soluble salts with zinc can be used for corrosion inhibition on the carbon steel pipe and heat exchangers in industrial cooling water. This new composition of matter contains less carboxylic acid and Zn2+ than previous formulations and still have >90% corrosion inhibition. It is disclosed that the synergistic effect of combining the carboxylic acid with very small amounts of Zn results in a product with good corrosion inhibition properties that is more environmentally friendly than the current common phosphonate corrosion inhibitors; particularly for use in cooling water applications.Type: ApplicationFiled: February 25, 2014Publication date: August 28, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Haiping Lu, Bing Bing Guo, David N. Fulmer
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Patent number: 8758789Abstract: The present invention relates to compositions including medium chain peroxycarboxylic acid, methods for making these compositions, and methods for reducing the population of a microorganism. The compositions can include advantageously high levels of the medium chain peroxycarboxylic acid, can be readily made, and/or can exhibit reduced odor.Type: GrantFiled: October 22, 2012Date of Patent: June 24, 2014Assignee: Ecolab USA Inc.Inventors: Victor F. Man, Joshua P. Magnuson, Steven E. Lentsch
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Publication number: 20140131283Abstract: A method for treating in an industrial water treatment system for at least two of metal corrosion inhibition, scale inhibition, suspended matter dispersion, biocide efficacy, or biofilm removal/biofilm dispersion is taught by the use of at least one compound which is a salt derived from a thioamine or an oxyamine and an acid.Type: ApplicationFiled: March 28, 2013Publication date: May 15, 2014Applicant: AMSA, INC.Inventors: Attila G Relenyi, Anthony P Haag
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Patent number: 8651010Abstract: The invention relates to the trigger and firing mechanisms for pistols. The inventive pistol comprises a frame (1), a barrel (2) with a cartridge chamber (3), a cartridge feeding mechanism (4), a fired case removing mechanism and a breech block return spring (12). The breech block (13) is slidable parallel to the barrel axis and comprises a firing mechanism, which consists of a firing spring stop (14), a firing spring (15), a striker (16) having a firing pin tip (17), a cocking notch (18) and rest pads for a firing spring (19) and for a striker spring (20). The breech block (13) includes a mechanism for sinking the firing pin tip (17) in a position, which makes possible the chambering of a cartridge, said mechanism having a striker spring (21), the force of which in a precompressed condition is greater than the precompressed force of the firing spring (15). The striker spring stop (22) is installed in the breech block (13) for fixing the precompressed force of the striker spring (21).Type: GrantFiled: August 18, 2008Date of Patent: February 18, 2014Inventor: Volodymyr Igorovych Smirnov
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Patent number: 8512433Abstract: Disclosed are ceramic honeycomb articles which possess a unique microstructure characterized by porosity between 40% and 70%, and the presence of coarse pores exhibiting a depth equivalent to the thickness of the cell wall and a dimensional width, in the plane of the cell wall, exhibiting a diameter that is at least as large as the thickness of the cell wall. The articles exhibits reduced filtration efficiency coupled with low pressure drop across the filter, and a reduced regeneration need. Such ceramic articles are particularly well suited for filtration applications, such as off-road and retro-fit diesel exhaust filters or DPFs. Also disclosed is a method for manufacturing the ceramic article wherein the pore former is capable of forming coarse pores.Type: GrantFiled: May 29, 2009Date of Patent: August 20, 2013Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Achim Karl-Erich Heibel, Pushkar Tandon, David John Thompson
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Methods for inhibiting corrosion in brazed metal surfaces and coolants and additives for use therein
Patent number: 8066902Abstract: Disclosed are coolants comprising brazed metal corrosion inhibitors. In one embodiment, the disclosed brazed metal corrosion inhibitor will comprise a polycarboxylic acid functional compound having the structure: wherein R1, R2, R3, and R4 are each independently selected from the group consisting of H, OH, COOH, C1-C10alkyl groups, glycol esters, anhydride groups, —COOM, and combinations thereof, wherein M is at least one of H, alkali metal ions, alkali earth metal ions, NH4+, amines, imidazoline, polyalcohol esters, C1 to C12 alkyl groups, and combinations thereof; wherein (1) at least three of R1, R2, R3, and R4 contain the group —COOM, wherein M is defined above; or (2) at least two of R1, R2, R3, and R4 contain an anhydride group, and at least one of R1, R2, R3, and R4 contain the group —COOM, wherein M is defined above.Type: GrantFiled: June 26, 2006Date of Patent: November 29, 2011Assignee: Prestone Products CorporationInventors: Bo Yang, Peter M. Woyciesjes, Aleksei V. Gershun, Filipe J. Marinho -
Patent number: 8025840Abstract: Methods and compositions are provided for corrosion inhibition treatment of aqueous systems such as cooling water systems. The methods include conjoint use of a polyvalent metal ion, such as Al or Mn and a corrosion inhibitor/deposit control agent (DCA) to the water system. The corrosion inhibitor DCA agent may be an organic compound such as a hydroxyacid, phosphonocarboxylic acid, polyhydroxysuccinic acid, or polymaleic acid or anhydride.Type: GrantFiled: October 31, 2008Date of Patent: September 27, 2011Assignee: General Electric CompanyInventors: Rosa Crovetto, Claudia C. Pierce, Philip D. Deck
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Patent number: 8021607Abstract: Methods are provided to inhibit corrosion of metals in contact with aqueous systems such as cooling water systems. In accordance with the methods, a hydroxyacid compound and orthophosphates are used to treat the system. Additionally, an adjuvant including poly(epoxysuccinic acids), an additional hydroxy acid, and a polycarboxylic acid, may be added to the system water.Type: GrantFiled: October 31, 2008Date of Patent: September 20, 2011Assignee: General Electric CompanyInventors: Claudia C. Pierce, Philip D. Deck, Rosa Crovetto, Beena George, Rajendra Prasad Kalakodimi, Guruprasad Sundararajan, Donald Wayne Whisenhunt, Jr.
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Patent number: 7919122Abstract: The invention provides a composition for production of a sterilizer having a water content of 1 to 25% by weight and comprising (A) an ester of a polyhydric alcohol and an organic acid having a hydrocarbon group which may have a hydroxyl group and (B1) hydrogen peroxide. From the composition, a sterilizer is obtained as an aqueous solution containing an organic peracid.Type: GrantFiled: April 1, 2004Date of Patent: April 5, 2011Assignee: Kao CorporationInventors: Tetsuya Okano, Noboru Matsuo, Chihiro Iwaki, Shigeru Tamura
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Patent number: 7837931Abstract: A corrosion inhibitor package containing an acetylenic amine or acetylenic alcohol enables a sulfur-free method for protecting metal tubulars and equipment. The package has particular applicability in the protection of carbon steel tubulars in high density brines at elevated temperatures. The corrosion inhibitor package may contain a transition metal oxide as a corrosion inhibitor intensifier.Type: GrantFiled: May 4, 2007Date of Patent: November 23, 2010Assignee: BJ Services Company LLCInventors: Richard F. Stevens, Jr., Mingjie Ke, Qi Qu
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Patent number: 7744775Abstract: In one embodiment, a corrosion inhibiting composition is formed by combining: (a) an inorganic phosphate; (b) a water soluble polyelectrolyte polymer dispersant; (c) a tri or tetracarboxylic acid; and (d) at least one additional component comprising at least one of a C4-C22 aliphatic or aromatic mono- or dicarboxylic acid, a silicate and at least one of a silicone or a silicate stabilizing siloxane compound, and mixtures thereof. Also disclosed are heat transfer fluids that include about 5% to about 99% by weight of freezing point-depressing agent; about 1% to about 95% by weight of water; and the disclosed corrosion inhibitor composition. A method of reducing corrosion in a heat transfer system containing one or more components that contain magnesium or a magnesium alloy requires that the system and the magnesium containing components be in contact with the disclosed heat transfer fluid.Type: GrantFiled: November 17, 2009Date of Patent: June 29, 2010Assignee: Honeywell International Inc.Inventors: Bo Yang, Filipe J. Marinho
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Publication number: 20100111757Abstract: Methods are provided to inhibit corrosion of metals in contact with aqueous systems such as cooling water systems. In accordance with the methods, a hydroxyacid compound and orthophosphates are used to treat the system. Additionally, an adjuvant including poly(epoxysuccinic acids), an additional hydroxy acid, and a polycarboxylic acid, may be added to the system water.Type: ApplicationFiled: October 31, 2008Publication date: May 6, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Claudia C. Pierce, Philip D. Deck, Rosa Crovetto, Beena George, Rajendra Prasad Kalakodimi, Guruprasad Sundararajan, Donald Wayne Whisenhunt, JR.
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Publication number: 20100111756Abstract: Methods and compositions are provided for corrosion inhibition treatment of aqueous systems such as cooling water systems. The methods include conjoint use of a polyvalent metal ion, such as Al or Mn and a corrosion inhibitor/deposit control agent (DCA) to the water system. The corrosion inhibitor DCA agent may be an organic compound such as a hydroxyacid, phosphonocarboxylic acid, polyhydroxysuccinic acid, or polymaleic acid or anhydride.Type: ApplicationFiled: October 31, 2008Publication date: May 6, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Rosa Crovetto, Claudia C. Pierce, Philip D. Deck
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Patent number: 7699991Abstract: A conditioning process and equipment are provided for removing hardness from water circulated in a system. A sidestream from such system is routed to a reaction chamber and back to the system. A conditioner is added to the sidestream water and in some embodiments is routed through a sidestream inlet from the top of the reaction chamber to its lower portion in a swirling motion. A buffer is added to the sidestream exiting the reaction chamber, and in some embodiments is added upstream of a pH sensor. In some embodiments a polymer is added. A fluid bed develops in the reaction chamber consisting of conditioner, buffer, precipitated solids and sidestream water. An upper outlet on the reaction chamber regulates the height of the fluid bed, and a drain provides for periodic discharge of the lower fluid bed. In some embodiments, a corrosion inhibitor blend is pre-mixed with the buffer.Type: GrantFiled: July 17, 2007Date of Patent: April 20, 2010Inventor: Samuel Rupert Owens
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Patent number: 7658855Abstract: A conditioning process and equipment are provided for removing hardness from water circulated in a system, such as an evaporative cooling system. A sidestream from such system is routed to a reaction chamber and back to the system. A conditioner is added to the sidestream water and in some embodiments is routed through a sidestream inlet from the top of the reaction chamber to its lower portion. A buffer is added to the sidestream exiting the reaction chamber, and in some embodiments is added upstream of a pH sensor. A fluid bed develops in the reaction chamber consisting of conditioner, buffer, precipitated solids and sidestream water. An upper outlet on the reaction chamber regulates the height of the fluid bed, and a drain provides for periodic discharge of the lower fluid bed. In another embodiment, a corrosion inhibitor blend is pre-mixed with the buffer.Type: GrantFiled: December 27, 2006Date of Patent: February 9, 2010Inventor: Samuel Rupert Owens
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Patent number: 7632458Abstract: The present invention provides an effective method of inhibiting corrosion on metallic surfaces in contact with a fluid contained in a closed loop industrial fluid system, which comprises adding to such fluid an effective corrosion controlling amount of a combination of an organic diacid, a triamine and a phosphonate compound.Type: GrantFiled: January 31, 2006Date of Patent: December 15, 2009Assignee: General Electric CompanyInventors: Rosa Crovetto, William S. Carey, Roger C. May, Ping Lue, Kristof Kimpe
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Patent number: 7407623Abstract: Lecithin and 2-bromo-2-nitropropane-1,3 diol (BNPD) are used to inhibit corrosion in boiler steam condensate systems. Aqueous steam condensate corrosion inhibiting compositions of these components are also disclosed. BNPD is also used as a preservative in lecithin containing and in other GRAS additive containing compositions.Type: GrantFiled: October 5, 2004Date of Patent: August 5, 2008Assignee: GE Betz, Inc.Inventors: Wilson K. Whitekettle, Rosa Crovetto
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Process for the solvent-free preparation of ethercarboxylic acids having a low residual salt content
Patent number: 7208118Abstract: The invention provides a process for preparing compounds of the formula (1) where A is C2- to C4-alkylene, B is C1- to C4-alkylene, n is a number from 1 to 100, and R is C1- to C30-alkyl, C2- to C30-alkenyl, or C6— to C30-aryl, by a) alkylating a basic mixture of oxoalkylated alcohols of the formula R—O-(-A-O—)n—H and alkoxides thereof with a C2- to C5-chlorocarboxylic acid in the absence of a solvent, b) converting the thus obtained ethercarboxylic acid salt to the free ethercarboxylic acid by adding an acid, the pH being adjusted to 3 or less, c) freeing the thus obtained ethercarboxylic acid, without washing, of water present down to a residual water content of <0.30% by distillation under reduced pressure, and d) removing the precipitated metal salts by filtration, so that the resulting product has a residual salt content of <0.2%.Type: GrantFiled: March 4, 2005Date of Patent: April 24, 2007Assignee: Clariant Produkte (Deutschland) GmbHInventors: Dirk Leinweber, Uwe Dahlmann, Rainer Kupfer -
Patent number: 7205438Abstract: A diene production stream comprising a solvent recovery blend from diene production comprising one or more fouling agent, one or more extractive distillation solvent, and from about 1 ppm to about 1000 ppm of N,N-disubstituted amide.Type: GrantFiled: March 9, 2005Date of Patent: April 17, 2007Assignee: Baker Hughes IncorporatedInventor: Marilyn Wood Blaschke
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Patent number: 7182839Abstract: Methods and compositions effective to prevent deposition of fouling agents, preferably polymerization precursors, on handling equipment, particularly during solvent recovery.Type: GrantFiled: August 6, 2001Date of Patent: February 27, 2007Assignee: Baker Hughes IncorporatedInventor: Marilyn Wood Blaschke
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Patent number: 7157008Abstract: A conditioning process and equipment are provided for removing hardness from water circulated in a system, such as an evaporative cooling system. A sidestream from such system is routed to a reaction chamber and back to the system. A conditioner is added to the sidestream before entering the reaction chamber and a buffer is added to the sidestream exiting the reaction chamber. Since some of the buffered sidestream is re-circulated, a fluid bed develops in the reaction chamber consisting of conditioner, buffer, precipitated solids and sidestream water. Continued sidestream water entry mixes with the fluid bed causing additional precipitation of solids. An upper outlet on the reaction chamber regulates the height of the fluid bed, and a drain provides for periodic discharge of the lower fluid bed. In another embodiment, a corrosion inhibitor blend is pre-mixed with the buffer, resulting in a softer, more readily drainable fluid bed.Type: GrantFiled: March 21, 2005Date of Patent: January 2, 2007Inventor: Samuel Rupert Owens
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Bactericide for use in water treatment, method for water treatment and apparatus for water treatment
Patent number: 7090780Abstract: A water-treating microbicide, containing an inorganic acid and a corrosion inhibitor, and further containing a carboxylic acid having 8 or less carbon atoms or any of alkali metal salts thereof. The present invention can provide a water-treating microbicide, water treatment method and water treatment apparatus exhibiting a high sterilization effect in a membrane separation device for seawater desalination, etc.Type: GrantFiled: April 2, 2002Date of Patent: August 15, 2006Assignee: Toray Industries, Inc.Inventors: Akihiko Ito, Katsufumi Oto, Kazuya Sugita, Yoshinari Fusaoka -
Patent number: 6861032Abstract: A boiler water treatment chemical includes a heterocyclic compound with N-substituted amino group, or the salt thereof, and alkaline agent and/or water soluble polymer.Type: GrantFiled: December 19, 2002Date of Patent: March 1, 2005Assignee: Kurita Water Industries Ltd.Inventors: Yukimasa Shimura, Shiro Taya
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Patent number: 6846452Abstract: This invention relates to a composition and a method for inhibiting the formation of scale, particularly complex scale, in an aqueous system where more than one type of scale is present. The scale typically present in the aqueous system includes silica, silicates, and carbonates. The scale inhibiting composition comprises (1) 2-phosphonobutane-1,2,4-tricarboxylic acid and salts thereof, and (2) a copolymer of (1) one or more allyloxybenzenesulfonate monomers, and (2) one or more water-soluble acrylic monomers, substituted acrylic monomers, or mixtures thereof.Type: GrantFiled: May 29, 2002Date of Patent: January 25, 2005Assignee: Ashland Inc.Inventors: Pavol Kmec, Dwight E. Emerich
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Patent number: 6814930Abstract: A white rust inhibiting composition and method of inhibiting white rust for evaporative water coolers are disclosed. The composition includes, in combination, a blend of one or more organophosphorus compounds and one or more tannin compounds.Type: GrantFiled: June 10, 2002Date of Patent: November 9, 2004Inventors: Michael T. Oldsberg, Bruce D. Busch
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Patent number: 6811747Abstract: The present invention relates to water treatment chemical formulations, and more particularly to chemical formulations used to treat water containing halogens as a sanitizing agent. The water treatment chemical formulations contain cyanuric acid and an alkali metal molybdate or silicate as an anticorrosion agent.Type: GrantFiled: June 4, 2003Date of Patent: November 2, 2004Assignee: Bioquest, LLCInventor: Michael A. Silveri
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Publication number: 20040135124Abstract: Fluorescent monomers are described and claimed which are synthesized by reacting a substituted or non-substituted naphthalic anhydride with an amine and with a moiety containing a polymerizable group. Such monomers are useful for the preparation of tagged treatment polymers. Such tagged treatment polymers are useful as scale inhibitors in industrial water systems.Type: ApplicationFiled: September 9, 2003Publication date: July 15, 2004Inventors: John D. Morris, Barbara E. Moriarty, Mingli Wei, Patrick G. Murray, Jerry L. Reddinger
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Publication number: 20040135125Abstract: Fluorescent monomers are described and claimed which are synthesized by reacting a substituted or non-substituted naphthalic anhydride with an amine and with a moiety containing a polymerizable group. Such monomers are useful for the preparation of tagged treatment polymers. Such tagged treatment polymers are useful as scale inhibitors in industrial water systems.Type: ApplicationFiled: September 9, 2003Publication date: July 15, 2004Inventors: John D. Morris, Barbara E. Moriarty, Mingli Wei, Patrick G. Murray, Jerry L. Reddinger
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Patent number: 6680001Abstract: A composition for lubricating, preventing mineral deposit buildup, and expelling any standing water from the internal parts of a pressure washer, as well as a pressurized container for applying such composition across the internal parts of the pressure washer through the water inlet valve is provided.Type: GrantFiled: April 30, 2002Date of Patent: January 20, 2004Inventor: David J. Krueger
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Publication number: 20030215353Abstract: This invention relates to a process for scale inhibition using random copolymers of acrylic acid and a monomer that is hydrophobic.Type: ApplicationFiled: May 16, 2002Publication date: November 20, 2003Inventors: Srideve Narayan-Sarathy, Laurence G. Dammann, Davor Zidovec
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Patent number: 6583091Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of 4-sulfophthalic acid, typically up to 1000 wppm, to the metal surface.Type: GrantFiled: July 13, 2001Date of Patent: June 24, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
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Publication number: 20030091467Abstract: This invention relates to a composition and a method for inhibiting the formation of scale, particularly complex scale, in an aqueous system where more than one type of scale is present. The scale typically present in the aqueous system includes silica, silicates, and carbonates. The scale inhibiting composition comprises (1) 2-phosphonobutane-1,2,4-tricarboxylic acid and salts thereof, and (2) a copolymer of (1) one or more allyloxybenzenesulfonate monomers, and (2) one or more water-soluble acrylic monomers, substituted acrylic monomers, or mixtures thereof.Type: ApplicationFiled: May 29, 2002Publication date: May 15, 2003Inventors: Pavol Kmec, Dwight E. Emerich
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Publication number: 20030086816Abstract: This invention relates to a process for removing iron oxide deposit from a metal surface in contact with an aqueous system, in particular the metal surface of a boiler operating at high pressures. The process comprises adding an elevated dosage of an oxime to the aqueous system in an amount effective to partially or entirely remove iron oxide deposits from the metal surface.Type: ApplicationFiled: June 20, 2002Publication date: May 8, 2003Inventors: Douglas B. Dewitt-Dick, Kaj D. Rondum
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Patent number: 6551553Abstract: A process is provided for disinfecting articles at temperatures below 5° C. with an aqueous alcoholic salt solution. The process provides a fast reduction of microorganisms at low temperatures with a wide degree of efficacy.Type: GrantFiled: October 4, 1999Date of Patent: April 22, 2003Assignee: Ecolab GmbH & Co. oHGInventors: Friedrich von Rheinbaben, Klaus-Peter Bansemir, Holger Biering
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Publication number: 20030049161Abstract: Methods and compositions effective to prevent deposition of fouling agents, preferably polymerization precursors, on handling equipment, particularly during solvent recovery.Type: ApplicationFiled: August 6, 2001Publication date: March 13, 2003Inventor: Marilyn Wood Blaschke
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Publication number: 20030012685Abstract: The invention relates to synergistic mixtures of o-phenylphenol and additional bactericides.Type: ApplicationFiled: August 23, 2002Publication date: January 16, 2003Inventors: Peter Wachtler, Martin Kugler
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Patent number: 6475431Abstract: A low toxic, biodegradable, water soluble and dispersant series of corrosion inhibitors are described. The method of inhibiting corrosion in aqueous medium by incorporating the inhibitor in PPM is provided. The corrosion inhibitor compromises an acrylic acid and chloroacetic acid adduct of 2-substituted imidazolines or primary, secondary or tertiary amines with carbon chain of twelve to twenty-two saturated or unsaturated carbon atoms. The molar ratio of acrylic acid to chloroacetic acid was methodically changed while keeping the concentration of imidazoline or the amine a constant. The product is made water soluble by raising the pH to 8-9 at the end of the synthesis by adding aqueous sodium hydroxide.Type: GrantFiled: April 9, 1999Date of Patent: November 5, 2002Assignee: Champion Technologies, Inc.Inventors: Ali Naraghi, Nihal U. Obeyesekere
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Patent number: 6468470Abstract: A white rust inhibiting composition and method of inhibiting white rust for evaporative water coolers are disclosed. The composition includes, in combination, a blend of one or more organophosphorus compounds, one or more tannin compounds, and one or more water soluble metal compounds.Type: GrantFiled: June 18, 1999Date of Patent: October 22, 2002Assignee: Fremont Industries, Inc.Inventors: Michael T. Oldsberg, Bruce D. Busch
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Patent number: 6458320Abstract: This invention relates to a galvanized metal, typically steel, corrosion inhibitor concentrate comprising (a) an amine salt of a fatty acid or an amine salt of a derivative of a fatty acid, (b) preferably a salt of a non polymeric aromatic acid, and (c) preferably a nonionic or anionic surfactant, and water. The invention also relates to a process for inhibiting corrosion and/or stripping of galvanized steel subjected to acidic conditions, e.g. an amine citrate or citric acid cleaning solution.Type: GrantFiled: April 5, 1999Date of Patent: October 1, 2002Assignee: Ashland Inc.Inventors: Bruce L. Libutti, Joseph Mihelic
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Patent number: 6447717Abstract: Carbon dioxide induced corrosion of ferrous metals in aqueous systems is inhibited by treatment of the aqueous system with corrosion inhibiting amino thiol and amino disulfide compounds. Particularly effective inhibitors are the natural amino acids cysteine and cystine and their decarboxylated analogues cysteamine and cystamine. Novel corrosion inhibiting compositions comprising a combination of amino thiol or amino disulfide compounds with acidic amino acid polymers are also disclosed.Type: GrantFiled: June 4, 1999Date of Patent: September 10, 2002Assignee: Donlar CorporationInventors: Joseph C. Fan, Lai-Duien Grace Fan, Jacob Mazo
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Patent number: 6436344Abstract: The present invention introduces a class of compounds, 2-substituted carbonyl compounds, that are useful as disinfecting agents, and particularly useful in methods for the disinfection of biological fluids. Members of the class of compounds have been found to possess pathogen inactivating properties against a variety of pathogens. The compounds and methods disclosed herein are useful for disinfecting biological fluids such as blood and blood fractions, among others.Type: GrantFiled: November 2, 1999Date of Patent: August 20, 2002Assignees: American National Red Cross, Amersham Pharmacia Biotech ABInventors: Shirley I. Miekka, William H. Drohan, Herbert Baumann, Ingrid Drevin, Jean-Luc Maloisel
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Patent number: 6419850Abstract: An apparatus and composition of matter for treating tap or distilled water prior to use in irrigation during surgical and medical operations.Type: GrantFiled: January 10, 1997Date of Patent: July 16, 2002Assignee: Airel-WestInventor: Henri Rouleau