And Means Heating Or Cooling Loop Or Reaction Mass Located Therein Patents (Class 422/235)
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Patent number: 11421192Abstract: A process for infusing a consumable substance is described. The process includes the steps of placing a desired amount of an infusion material into a chamber at atmospheric pressure, placing a desired amount of consumable substance into said chamber, sealing said chamber from the surrounding atmosphere, and applying at least one reduced pressure cycle within said chamber. Methods for separating the infusion material from the consumable substance after completion of the infusion process are also described. In addition, devices for infusing liquids or consumable substances, and/or brewing beverages are described.Type: GrantFiled: October 26, 2018Date of Patent: August 23, 2022Assignee: BKON LLCInventors: Dean J. Vastardis, Lou Vastardis
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Patent number: 9982199Abstract: The invention relates to a process for continuously converting carbonaceous material contained in one or more feedstocks into a liquid hydrocarbon product, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water, the process comprising: converting at least part of the carbonaceous material by pressurising the feed mixture to an operational pressure in the range 150-400 bar, heating the feed mixture to an operational temperature in the range 300-450° C., and maintaining said pressurized and heated feed mixture in the desired pressure and temperature ranges in a reaction zone for a predefined time; cooling the feed mixture to a temperature in the range 25-200° C.Type: GrantFiled: August 29, 2013Date of Patent: May 29, 2018Assignee: STEEPER ENERGY APSInventor: Steen Brummerstedt Iversen
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Patent number: 9011814Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.Type: GrantFiled: February 22, 2013Date of Patent: April 21, 2015Assignee: GTLpetrol LLCInventors: Shoou-I Wang, John Michael Repasky, Shankar Nataraj, Xiang-Dong Peng
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Patent number: 8968574Abstract: A method and device for the wet oxidation treatment of liquid waste laden with mineral matter in suspension. The device comprises a reactor including a treatment column, first and second heat exchangers placed upstream and downstream, respectively, of the reactor. The solution to be treated, laden with mineral matter to which an oxidizing gas has been added, is injected into the reactor for treatment after being preheated in the first heat exchanger. When the solution exits the reactor, the hot treated mixture is divided into two hot stream fragments. The first hot treated mixture stream fragment, the flow rate of which is kept constant by a diaphragm column, is used for controlling the temperature of the first heat exchanger and then discharged after being used in the first heat exchanger. The second hot treated mixture stream fragment is directly cooled and discharged when the second hot treated mixture stream fragment leaves the reactor.Type: GrantFiled: March 15, 2010Date of Patent: March 3, 2015Assignee: Granit Technologies S.A.Inventor: Boris Correa
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Patent number: 8951407Abstract: A simplified process is provided for creating hybrid crude oils and hybrid crude fractions with characteristics superior to the original. The process uniquely combines gases with crude oil or crude fractions in an effervescent turbulent manner at low temperatures and pressures and without the further aid of catalysts. The process breaks large chain hydrocarbons into smaller chain hydrocarbons, molecularly combines carbon, hydrogen, and/or hydrocarbon molecules from the gases with and into hydrocarbon molecules of the crude or crude fraction, and separates contaminants and impurities.Type: GrantFiled: March 19, 2014Date of Patent: February 10, 2015Assignee: Clean Global Energy, Inc.Inventors: Robert Miller, Delmar Guenther, Rick Lutterbach, Jeff Nichols
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Patent number: 8673244Abstract: The present invention relates to an apparatus for producing alcohols from olefins, comprising: a hydroformylation reactor wherein aldehydes are produced from olefins; a catalyst/aldehydes separator; a hydrogenation reactor wherein the aldehydes are hydrogenated to produce alcohols; and a distillation column. The hydroformylation reactor is equipped with a distributor plate, which has a broad contact surface for providing sufficient reaction area for reactants such as olefins and synthesis gas, and allows the reaction mixture to circulate and mix sufficiently, which contribute to excellent efficiency in terms of production of aldehydes. In addition, the hydrogenation reactor suppresses sub-reactions to improve the production yield of alcohols.Type: GrantFiled: March 30, 2011Date of Patent: March 18, 2014Assignee: LG Chem, Ltd.Inventors: Dong-Hyun Ko, Sung-Shik Eom, Yong-Jin Choe, Chan-Hong Lee, Moo-Ho Hong, O-Hak Kwon, Dae-Chul Kim, Jae-Hui Choi
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Patent number: 8673227Abstract: A system for removal of carbon dioxide from a process gas includes an absorption arrangement arranged to allow contact between the process gas and an ammoniated solution within the absorption arrangement such that at least a part of the carbon dioxide of the process gas is captured by the ammoniated solution. The absorption arrangement is arranged to, with regard to the ammoniated solution, only accommodate ammoniated solution without solids. A first heat exchanger is arranged to cool the ammoniated solution including captured carbon dioxide after it has exited the absorption arrangement. A separator is arranged to remove at least a part of any solids in the cooled ammoniated solution. A second heat exchanger is arranged to heat the ammoniated solution after it has exited the separator and returned to the absorption arrangement.Type: GrantFiled: October 8, 2012Date of Patent: March 18, 2014Assignee: ALSTOM Technology LtdInventors: Sean E. Black, Sanjay K. Dube, David J. Muraskin, Frederic Z. Kozak
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Patent number: 8658123Abstract: Method for the production of a coarse-grained ammonium sulphate product by crystallization and installation for carrying out the method from an ammonium sulphate solution in a DTB type crystallizer having an internal suspension circuit and a clarifying zone, from which a clarified partial flow of solution is constantly drawn off into an external circuit, is heated in a heat exchanger to dissolve the solids contained therein and is guided back as a clear solution into the lower region of the crystallizer. A fine crystal suspension flow is drawn off from the clarifying zone as a further partial flow and guided back into the internal circuit of the crystallization stage without any previous dissolution of the solid proportion contained therein.Type: GrantFiled: February 28, 2013Date of Patent: February 25, 2014Assignee: GEA Messo GmbHInventors: Günter Hofmann, Holger Leptien, Johannes Widua
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Patent number: 8563756Abstract: In an embodiment of the invention, an apparatus for preparing hydroxymethylfurfural (HMF) is provided. The apparatus includes a reaction area including a first organic layer including sugar and a solvent and a second organic layer including a solvent mixture with azeotropy and extractability, a boiling area including a mixing solution formed by the hydroxymethylfurfural and the solvent mixture, connected with the reaction area, and a distilling area including water and a liquid layer including the solvent mixture, connected to the reaction area. In another embodiment of the invention, a method for preparing hydroxymethylfurfural (HMF) is provided.Type: GrantFiled: December 20, 2010Date of Patent: October 22, 2013Assignee: Industrial Technology Research InstituteInventors: Ruey-Fu Shih, Hsi-Yen Hsu
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Patent number: 8519094Abstract: Process for heating a polymer-containing stream being transferred from a polymerization reactor to a separation zone or device, by passing the stream through at least two heaters operating in parallel, each heater having at least one transfer line for the stream and a heater for heating the transfer line. The average particle of the polymer is below 3 mm, the temperature of the polymer-containing stream at the outlet of all heaters is maintained above the dew point of the stream, and no heater has a volumetric flowrate of polymer-containing stream more than three times that of any other heater.Type: GrantFiled: April 15, 2009Date of Patent: August 27, 2013Assignee: Ineos Manufacturing Belgium NVInventors: Daniel Marissal, Marc Parisel, Brent Walworth
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Patent number: 8449848Abstract: Production of polycrystalline silicon in a substantially closed-loop process is disclosed. The processes generally include decomposition of trichlorosilane produced from metallurgical grade silicon.Type: GrantFiled: October 22, 2010Date of Patent: May 28, 2013Assignee: MEMC Electronic Materials, Inc.Inventors: Satish Bhusarapu, Yue Huang, Puneet Gupta
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Patent number: 8383078Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.Type: GrantFiled: February 11, 2010Date of Patent: February 26, 2013Assignee: GTLpetrol LLCInventors: Shoou-I Wang, John Michael Repasky, Shankar Nataraj, Xiang-Dong Peng
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Patent number: 8298490Abstract: The present invention is directed to systems and methods of synthesizing trichlorosilane. The disclosed systems and methods can involve increasing the concentration of the solids in the slurry to recover or separate the volatilized metal salts and reduce the obstructions created by the solidification of the metal salts in downstream operations of the during trichlorosilane synthesis. Rather than heating to raise the temperature to vaporize chlorosilane compounds, and subsequently condensing the volatilized chlorosilane compounds, the present invention can involve increasing the solids concentration in the slurry stream by utilizing a non-condensable gas, such as hydrogen, to volatilize the chlorosilane components, which can consequently promote evaporative conditions that can reduce the slurry temperature. The lower slurry temperature results in a lower volatility of the metal salts, which reduces the likelihood of carryover to downstream unit operations.Type: GrantFiled: November 6, 2009Date of Patent: October 30, 2012Assignee: GTAT CorporationInventors: Scott Fahrenbruck, Bruce Hazeltine
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Patent number: 8105400Abstract: A process for treating biomass comprises providing a material that contains an amount of residual moisture. The material is heated to a torrefying temperature in a low-oxygen atmosphere in a torrefaction reactor to convert it into a torrefied material. The material with the contained residual moisture is essentially fully dried in a drying chamber by evaporation of residual moisture. The torrefaction reactor comprises a torrefying chamber, in which the torrefaction of this dried material is essentially carried out. The material is conveyed through the torrefaction reactor. The drying of the material in the drying chamber is carried out by introducing into it a hot drying gas that flows therethrough cocurrently with the material. The torrefaction of the material in the torrefying chamber of the torrefaction reactor is carried out by introducing into it a hot torrefying gas that flows through the torrefying chamber countercurrently with the material.Type: GrantFiled: January 8, 2007Date of Patent: January 31, 2012Assignee: Stichting Energieonderzoek Centrum NederlandInventor: Peter Christiaan Albert Bergman
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Publication number: 20110260113Abstract: The present application thus provides an integrated gasification combined cycle system. The integrated gasification combined cycle system may include a water gas shift reactor system and a heat recovery steam generator. The water gas shift reactor system may include a recirculation system with a recirculation heat exchanger to heat a flow of syngas. The heat recovery steam generator may include a diverted water flow in communication with the recirculation heat exchanger.Type: ApplicationFiled: April 26, 2010Publication date: October 27, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Ashok Kumar Anand, Mahendhra Muthuramalingam, Jegadeesan Maruthamuthu
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Patent number: 8034884Abstract: Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.Type: GrantFiled: September 7, 2009Date of Patent: October 11, 2011Inventors: Rainer Karer, Kaspar Evertz, Wolfgang Micklitz, Hans-Jacob Feindt, Philipp Rosendorfer, Peter Kölle
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Publication number: 20110135544Abstract: The present invention relates to a method for preparing aldehydes by reacting olefins with a synthesis gas including carbon monoxide and hydrogen, and to an apparatus therefore. More particularly, the present invention relates to a method for preparing aldehydes, characterized by spraying and supplying olefins, synthesis gas including carbon monoxide and hydrogen, and a catalyst composition into an oxo reactor through a nozzle, and to an apparatus therefore. According to the present invention, the hydroformylation efficiency can be improved, thereby obtaining desirable aldehydes with a high yield.Type: ApplicationFiled: January 17, 2011Publication date: June 9, 2011Applicant: LG CHEM, LTD.Inventors: Moo-Ho Hong, Dong-Hyun Ko, Sang-Oeb Na, Sung-Shik Eom, Sang-Gi Lee, O-Hark Kwon, Dae-Chul Kim, JAE-Hui Choi
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Publication number: 20110110839Abstract: The present invention is directed to systems and methods of synthesizing trichlorosilane. The disclosed systems and methods can involve increasing the concentration of the solids in the slurry to recover or separate the volatilized metal salts and reduce the obstructions created by the solidification of the metal salts in downstream operations of the during trichlorosilane synthesis. Rather than heating to raise the temperature to vaporize chlorosilane compounds, and subsequently condensing the volatilized chlorosilane compounds, the present invention can involve increasing the solids concentration in the slurry stream by utilizing a non-condensable gas, such as hydrogen, to volatilize the chlorosilane components, which can consequently promote evaporative conditions that can reduce the slurry temperature. The lower slurry temperature results in a lower volatility of the metal salts, which reduces the likelihood of carryover to downstream unit operations.Type: ApplicationFiled: November 6, 2009Publication date: May 12, 2011Applicant: GT SOLAR INCORPORATEDInventors: Scott Fahrenbruck, Bruce Hazeltine
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Patent number: 7931795Abstract: The present invention relates to a novel economical on-site electrochemical based membrane cell based process with the capability of producing high strength sodium hypochlorite and/or elemental chlorine gas in any ratio as required by the needs of a water or wastewater treatment plant. The system is compact and modular, using membrane cell based electrolyzers and utilizing novel process modifications and sensors to allow for the unattended control and safe operation of the process. The process allows the operator to produce elemental chlorine gas and sodium hypochlorite in any product ratio, such that 5% to 100% of the total chlorine produced by the process can be converted to high strength bleach. The process has the flexibility to produce stable high quality, low to high strength sodium hypochlorite solutions in concentrations ranging from about 2 to 15% trade as NaOCl.Type: GrantFiled: September 10, 2009Date of Patent: April 26, 2011Assignee: Electrolytic Technologies Corp.Inventors: Jerry J. Kaczur, Derek B. Lubie, Edmund M. Cudworth, Charles W. Clements, Martin E. Nelson
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Patent number: 7871577Abstract: Higher molecular weight hydrocarbon compounds or oxygenates are produced from a gas comprising methane in a process comprising the steps of generating synthesis gas (“syngas”) comprising carbon monoxide and hydrogen by reaction of a gas comprising methane with steam and/or an oxidant gas comprising oxygen, producing higher molecular weight hydrocarbon compounds or oxygenates in a syngas conversion process, removing offgas comprising unreacted hydrogen and unreacted carbon monoxide from said syngas conversion process and separating cryogenically unreacted hydrogen from said offgas or from a gas derived therefrom to produce separated hydrogen product that is substantially free of unreacted carbon monoxide and a first cryogenic liquid comprising unreacted carbon monoxide. The unreacted hydrogen is preferably separated from the offgas in a liquid methane wash column.Type: GrantFiled: August 6, 2003Date of Patent: January 18, 2011Assignee: GTLpetrol LLCInventors: Rodney Allam, Andrew Weaver, Vincent White, David B. Byard
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Patent number: 7862783Abstract: A separation system for a methyl acetate hydrolysis is provided. The separation system comprises a reactive distillation system, a reflux system, a first separation system and a second separation. The reactive distillation system allows the hydrolysis of a methyl acetate solution to generate a first mixture and a second mixture. The reflux system is packed with a heterogeneous catalyst and coupled to the reactive distillation system, which refluxes the first mixture to the reactive distillation system. The first separation system is coupled to the reactive distillation system, which directs the second mixture thereinto so as to isolate an acetic acid and a third mixture therefrom. The second separation system is coupled to the first separation system, which directs the third mixture thereintio so as to separate a methanol therefrom. The methyl acetate feeding system is coupled to, one of the reactive distillation system and the reflux system, which feeds the methyl acetate solution thereinto.Type: GrantFiled: January 30, 2007Date of Patent: January 4, 2011Assignee: National Taiwan UniversityInventors: Hsiao-Ping Huang, Cheng-Ching Yu, Ming-Jer Lee, Yu-De Lin, Jian-Kai Cheng
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Patent number: 7749468Abstract: An apparatus is provided for carrying out a cavitation induced reaction comprising a reaction chamber for a liquid reaction medium, means for producing cavitation in the liquid reaction medium, at least one reactant inlet to the reaction chamber, an inert gas inlet conduit with a sparger for injecting a flowing stream of dry inert gas into the reaction chamber, a venting outlet for removal of a stream of the inert gas from the reaction chamber, and a recirculation conduit for re-circulating a stream of the inert gas from the venting outlet to the inert gas inlet conduit.Type: GrantFiled: April 24, 2007Date of Patent: July 6, 2010Assignee: GM Global Technology Operations, Inc.Inventor: Ion C. Halalay
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Patent number: 7722844Abstract: An exhaust smoke denitrating apparatus in which using an NH3 injection unit, compressed air is fed from blower to ejector for extracting of exhaust gas from HRSG1, and with thus obtained mixed gas, NH3-containing gas is produced from NH3 water by NH3 water evaporator, the NH3-containing gas injected through NH3-containing gas injection nozzle of the HRSG1 disposed on a front stream side of denitration catalyst layer. As any high-temperature exhaust gas is cooled and diluted by compressed air, there is no danger of oxidation of NH3 during the stage of evaporation of NH3 water. The moisture level of exhaust gas can be lowered, thereby enabling inhibition of any drain generation in exhaust gas extraction piping. Air warming within NH3 water evaporation system can be carried out at an early stage.Type: GrantFiled: December 10, 2004Date of Patent: May 25, 2010Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Ryosuke Nakagawa, Tetsurou Hikino
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Patent number: 7713499Abstract: Apparatuses and methods for preparing sol-gel solutions are provided. Specifically, apparatuses include a vessel optionally containing a stirrer; a pump; a fluidized bed reaction column; and multiple fluid lines. The multiple fluid lines connect the vessel and the pump in a first circulation loop and connect the vessel, the pump and the fluidized bed reaction column in a second circulation loop. Processes for preparing sol-gel solutions using such apparatuses are also disclosed.Type: GrantFiled: April 28, 2006Date of Patent: May 11, 2010Assignee: Xerox CorporationInventors: Timothy P. Bender, David T. Borbely, Frank Ping-Hay Lee, Nan-Xing Hu
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Publication number: 20100074811Abstract: The integrated processes of the dry reforming or partial oxidation upstream of the carbon nanotube-producing reactor are described allowing the carbon monoxide to be produced on an as-needed basis, negating the need to transport carbon monoxide to the production site or store large quantities of carbon monoxide on-site. The apparatuses allowing to carry out such integrated processes are also provided. Carbon dioxide emissions may be eliminated from the carbon nanotube production process. This may be achieved by recycling the carbon dioxide byproduct and mixing it with the feed to the partial oxidation process.Type: ApplicationFiled: May 6, 2009Publication date: March 25, 2010Inventors: Kevin MCKEIGUE, Weibin JIANG, Ramachandran KRISHNAMURTHY
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Patent number: 7682574Abstract: The present invention relates to a thermal reactor apparatus used to treat industrial effluent fluids, for example waste effluent produced in semiconductor and liquid crystal display manufacturing processes. Specifically, the present invention relates to improved monitoring and control features for the thermal reactor apparatus, including a flame sensing device, an intrinsically safe flammable gas sensing device, and a sequential mode of operation having built-in safety redundancy. The improved monitoring and control features ensure the safe and efficient abatement of waste effluent within the thermal reactor apparatus.Type: GrantFiled: November 18, 2004Date of Patent: March 23, 2010Assignee: Applied Materials, Inc.Inventors: Ho-Man Rodney Chiu, Daniel O. Clark, Shaun W. Crawford, Jay J. Jung, Youssef A. Loldj, Robbert Vermeulen
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Patent number: 7682597Abstract: The invention relates to a method for extracting hydrogen from a gas containing methane, especially natural gas. Hydrocarbons contained in the gas are catalytically broken down in a reformer (4) by steam in order to form hydrogen, carbon monoxide and carbon dioxide. Catalytic conversion of the obtained carbon monoxide with steam occurs in a downstream conversion step in order to form carbon monoxide and water. Carbon dioxide is removed from the converted gas flow (8) by gas washing (7), and the washed hydrogen-rich gas flow (10) is subsequently divided in a pressure-swing adsorption system (11) into a product gas flow (12) made of hydrogen and a waste gas flow (13). The waste gas flow (13) is introduced with hydrogen (14), which is separated from the gas flow (10) after gas washing, into a reformer (4) which is essentially a carbon-free combustible gas, and is combusted there. The invention also relates to a system for carrying out the method.Type: GrantFiled: July 24, 2004Date of Patent: March 23, 2010Assignee: Uhde GmbHInventors: Michael Blumenfeld, Vincent Liu, Bernd Mielke, Marcus Michel
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Publication number: 20100056742Abstract: The present invention relates to a process for preparing alkyl methacrylates and their conversion products which can be used in a multitude of chemical synthesis processes which can lead to a wide variety of different further processing products, and to an apparatus for performing this process.Type: ApplicationFiled: August 31, 2007Publication date: March 4, 2010Applicant: Evonik Roehm GmbHInventors: Udo Gropp, Robert Weber, Thomas Schaefer, Andreas Perl, Rudolf Sing, Thomas Mertz
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Patent number: 7670586Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.Type: GrantFiled: February 24, 2003Date of Patent: March 2, 2010Assignee: GTLpetrol LLCInventors: Shoou-I Wang, John Repasky, Shankar Nataraj, Xiang-Dong Peng
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Patent number: 7604720Abstract: The present invention relates to a novel economical on-site electrochemical based membrane cell based process with the capability of producing high strength sodium hypochlorite and/or elemental chlorine gas in any ratio as required by the needs of a water or wastewater treatment plant. The system is compact and modular, using membrane cell based electrolyzers and utilizing novel process modifications and sensors to allow for the unattended control and safe operation of the process. The process allows the operator to produce elemental chlorine gas and sodium hypochlorite in any product ratio, such that 5% to 100% of the total chlorine produced by the process can be converted to high strength bleach. The process has the flexibility to produce stable high quality, low to high strength sodium hypochlorite solutions in concentrations ranging from about 2 to 15% trade as NaOCl.Type: GrantFiled: April 27, 2007Date of Patent: October 20, 2009Assignee: Electrolytic Technologies Corp.Inventors: Jerry J. Kaczur, Derek B. Lubie, Edmund M. Cudworth, Charles W. Clements, Martin E. Nelson
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Patent number: 7601303Abstract: Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.Type: GrantFiled: May 4, 1999Date of Patent: October 13, 2009Assignee: Elenac GmbHInventors: Rainer Karer, Kaspar Evertz, Wolfgang Micklitz, Hans-Jacob Feindt, Philipp Rosendorfer, Peter Kölle
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Patent number: 7556784Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically producing aromatic discarboxylic acids. The process reduces costs associated with hydrogenation by forming a final composite product containing unhydrogenated acid particles.Type: GrantFiled: March 18, 2008Date of Patent: July 7, 2009Assignee: Eastman Chemical CompanyInventors: Robert Lin, Marcel de Vreede
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Patent number: 7507384Abstract: According to the present invention, a temperature profile within a preferential oxidation reactor is controlled using a two phase water/steam system to provide a temperature range within the reactor (10) which favors the selective oxidation of CO in a hydrogen rich reformate stream. The reformate is flowed in a mixture with oxygen over a preferential oxidation catalyst (17). The temperature profile is controlled by flowing a stream of water proximate to the preferential oxidation catalyst (17) so as the stream of water and the reformate stream passing over the catalyst (17) are in a heat transfer arrangement. The stream of water is maintained as a two phase stream from a point at which the water reaches its boiling temperature to a point proximate an outlet from which the stream of water exits the reactor (10).Type: GrantFiled: June 13, 2003Date of Patent: March 24, 2009Assignee: Nuvera Fuel Cells, Inc.Inventors: Darryl Pollica, William F. Northrop, Chunming (Frank C.) Qi, Mark R. Hagan, Alexis Smith, Lawrence Clawson
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Publication number: 20090029846Abstract: The regeneration of HF alkylation acid in an alkylation unit is improved by withdrawing a vapor stream from the HF regenerator tower and condensing the stream to form a liquid fraction which is accumulated in a side distillation zone; the collected liquid fraction, comprising HF acid, water and some stripping medium is distilled in a batch or continuous type operation to drive off the HF acid (along with stripping medium) and the vapor is returned to the regenerator-stripper vessel. The distillation of the sidedraw liquid is continued until the composition of the liquid attains the azeotropic value or as near to that value as desired. The azeotrope, comprising water and acid can then be dropped out of the distillation vessel for disposal by neutralization in the conventional way.Type: ApplicationFiled: July 27, 2007Publication date: January 29, 2009Applicant: ExxonMobil Research and Engineering CompanyInventors: Jeffrey M. Fitt, Curtis A. Lawrence, Richard M. Janclaes, Brett Keegan Johnson, Michael W. Boyea, Nicholas Steiner Conley
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Patent number: 7442348Abstract: A sulfur-bearing residue treatment system is provided for the recovery of valuable organic components and the reduction of capital costs and operating costs. The treatment system involves the use of a stripping vessel in conjunction with a heating apparatus. All elements of the treatment system may be coupled together to form one integral piece of equipment.Type: GrantFiled: June 17, 2005Date of Patent: October 28, 2008Assignee: Rohm and Haas CompanyInventors: Curtis Instad Carlson, Jr., Michael Stanley DeCourcy, Jamie Jerrick John Juliette, Thomas Albert Kaminski, Nelson Ivan Quiros, Paul Benjamin Schladenhauffen
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Patent number: 7435864Abstract: Disclosed is a device for the production of alkylate(s) by sulfuric acid alkylation of at least one isoparaffin such as isobutane with at least one olefin, such as butylenes. The device includes a mixing chamber for preparing a mixture of the isoparaffin with recycled reaction products. It also includes an emulsion chamber for preparing a first hydrocarbons-in-sulfuric acid emulsion, where the mixture prepared in the mixing chamber is injected in multiple parallel jets into a sulfuric acid composition. The device further includes a pre-reaction chamber for preparing a second emulsion, where a given portion of the olefin is injected in jet streams into the first hydrocarbons-in-sulfuric acid emulsion coming from the emulsion chamber.Type: GrantFiled: June 1, 2001Date of Patent: October 14, 2008Assignee: Orgral International Technologies CorporationInventor: Semen Gershuni
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Patent number: 7311885Abstract: A batch reaction system for simultaneously conducting reactions in at least two separate reactors (CSTR reactors), is provided wherein the at least two batch reactors, containing mixing means and a fluid inlet, a fluid feed common conduit is present for feed fluid to the reactors, which is connected to the inlet of each reactor of a fluid inlet conduits, and further includes a fluid discharge common conduit which is connected to the outlet of each reactor wherein in each fluid inlet conduit and/or in each fluid outlet conduit a non-return valve is arranged to prevent contamination but can provide simultaneous reactions wherein the reactors can be easily isolated from one another during reaction.Type: GrantFiled: June 4, 2004Date of Patent: December 25, 2007Assignee: Avantium International A.B.Inventors: Anton John Nagy, Peter John van den Brink, Bashir Husein Harji
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Patent number: 7226565Abstract: Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.Type: GrantFiled: August 9, 2004Date of Patent: June 5, 2007Assignee: Basell Polyolefine GmbHInventors: Benno Knauer, Peter Hennenberger, Klaus Hilligardt, Eckard Schauss, Horst Bullack
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Patent number: 7220290Abstract: The present invention relates to a composition and method for storage and controlled release of hydrogen. In particular, the present invention relates to the use of borohydride based solutions as a hydrogen storage source and a catalyst system to release hydrogen therefrom.Type: GrantFiled: August 11, 2003Date of Patent: May 22, 2007Assignee: Millennium Cell, Inc.Inventors: Steven C. Amendola, Michael Binder, Stefanie L. Sharp-Goldman, Michael T. Kelly, Phillip J. Petillo
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Patent number: 7008707Abstract: A fuel cell system including a fuel reforming processor having a catalyst therein constructed and arranged to produce a reformate stream including hydrogen and carbon monoxide, a water gas shift reactor downstream of the fuel reforming processor and wherein the water gas shift reactor includes a catalyst therein constructed and arranged to reduce the amount of carbon monoxide in the reformate stream, a preferential oxidation reactor downstream of the water gas shift reactor and wherein the preferential oxidation reactor includes a catalyst therein constructed and arranged to preferentially oxidize carbon monoxide into carbon dioxide and to produce a hydrogen-rich stream, and a fuel cell stack downstream of the preferential oxidation reactor constructed and arranged to produce electricity from the hydrogen-rich stream, a first direct water vaporizing combustor constructed and arranged to combust fuel producing a high-temperature fuel combustion byproducts exhaust and to produce steam from water sprayed into thType: GrantFiled: February 15, 2002Date of Patent: March 7, 2006Assignee: General Motors CorporationInventor: Steven G. Goebel
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Patent number: 6986797Abstract: An auxiliary reactor for use with a reformer reactor having at least one reaction zone, and including a burner for burning fuel and creating a heated auxiliary reactor gas stream, and heat exchanger for transferring heat from auxiliary reactor gas stream and heat transfer medium, preferably two-phase water, to reformer reaction zone. Auxiliary reactor may include first cylindrical wall defining a chamber for burning fuel and creating a heated auxiliary reactor gas stream, the chamber having an inlet end, an outlet end, a second cylindrical wall surrounding first wall and a second annular chamber there between. The reactor being configured so heated auxiliary reactor gas flows out the outlet end and into and through second annular chamber and conduit which is disposed in second annular chamber, the conduit adapted to carry heat transfer medium and being connectable to reformer reaction zone for additional heat exchange.Type: GrantFiled: May 2, 2000Date of Patent: January 17, 2006Assignee: Nuvera Fuel Cells Inc.Inventors: Lawrence G. Clawson, Matthew H. Dorson, William L. Mitchell, Brian J. Nowicki, Jeffrey M. Bentley, Robert Davis, Jennifer W. Rumsey
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Patent number: 6872368Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage.Type: GrantFiled: July 11, 2001Date of Patent: March 29, 2005Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Cécile Barrere-Tricca
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Patent number: 6872367Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F1 comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.Type: GrantFiled: July 3, 2001Date of Patent: March 29, 2005Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Daniel Benayoun, Cécile Barrere-Tricca
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Patent number: 6818186Abstract: A recycling and recovery system and process comprising a flash gas separator that receives a slurry comprising liquid medium and solid polymer particles. The flash gas separator separates the diluent from the solid polymer particles as a vapor stream comprising at least diluent and heavies. A line receives the vapor stream from the flash gas separator. The line leads to a heavies removal system that yields a liquid that is relatively concentrated in heavies and a diluent vapor that is relatively free of heavies. The liquid is passed to a heavies column, while the diluent vapor is passed to a diluent recycle chamber and then recycled to a slurry polymerization reactor without additional treatment to remove heavies.Type: GrantFiled: September 15, 2003Date of Patent: November 16, 2004Assignee: Chevron Phillips Chemical Company, LPInventors: David H. Burns, Donald W. Verser
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Patent number: 6818190Abstract: An apparatus for preparing non-photosensitive fatty acid silver salt grains having a first feeding device for feeding a silver ion-containing solution, the solvent of which is water or a mixture of water and an organic solvent, to a closed mixing device; a second feeding device for feeding a solution of a fatty acid alkali metal salt, the solvent of which is water, an organic solvent, or a mixture of water and an organic solvent, to the closed mixing device; a third feeding device for feeding water, or a mixture of water and an organic solvent to the closed mixing device; and the closed mixing device for mixing matter fed from the first, second and third feeding devices, and discharging a liquid containing non-photosensitive fatty acid silver salt grains.Type: GrantFiled: August 14, 2002Date of Patent: November 16, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoyuki Kawanishi, Takashi Ando
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Patent number: 6800120Abstract: A recovery plant for recovery of a gaseous component from a process gas has an absorber employing a lean solvent and a semi-lean solvent that absorb the gaseous component from the process gas, thereby producing a rich solvent, a semi-rich solvent, and a lean process gas. A regenerator extracts the gaseous component from the rich solvent, thereby regenerating the lean solvent and the semi-lean solvent. A solvent flow control element combines at least part of the semi-rich solvent and the semi-lean solvent to form a mixed solvent, and a cooler cools the mixed solvent that is subsequently fed into the absorber. In a method of removing a gaseous component from a process gas, a stream of lean solvent and a stream of semi-lean solvent are provided. In another step, the stream of lean solvent and the stream of semi-lean solvent contact the process gas in an absorber to produce a stream of semi-rich solvent and rich solvent.Type: GrantFiled: December 30, 2003Date of Patent: October 5, 2004Assignee: Fluor CorporationInventors: Ray Won, Peter Condorelli, Jeffrey Scherffius, Carl L. Mariz
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Patent number: 6746497Abstract: A waste is dry-distilled in a gasification furnace and generated combustible gas is combusted in a combustion furnace. A temperature in the combustion furnace is set to be substantially constant at a first preset temperature or more. When the temperature in the combustion furnace is greater than the first preset temperature by combustion of other fuels, the combustible gas is introduced. When the temperature in the combustion furnace reaches a second preset temperature or more by the combustion of only the combustible gas, the combustion of the other fuels is finished. When the temperature in the combustion furnace falls below a third preset temperature the combustion of the other fuels is resumed. When the temperature in the gasification furnace falls below a fourth preset temperature, the combustion of the other fuels is finished.Type: GrantFiled: February 27, 2001Date of Patent: June 8, 2004Assignee: Kinsei Sangyo Co., Ltd.Inventor: Masamoto Kaneko
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Patent number: 6730278Abstract: In a process for the production of urea, substantially pure ammonia and carbon dioxide are reacted in a reaction space (1) from which comes out a reaction mixture subjected to stripping (2) to obtain a partially purified mixture sent to a urea recovery section (3, 4, 7, 8). From the recovery section (3, 4, 7, 8) it is obtained a dilute carbamate solution, which is subjected to stripping (9) with recycling of vapors to the reaction space (1) after condensation (6). This process achieves high conversion yield with reduced energy consumption and low implementation costs.Type: GrantFiled: April 5, 1999Date of Patent: May 4, 2004Assignee: Urea CasaleInventors: Giorgio Pagani, Umberto Zardi
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Patent number: 6712908Abstract: Method and apparatus for producing purified bulk silicon from highly impure metallurgical-grade silicon source material at atmospheric pressure. Method involves: (1) initially reacting iodine and metallurgical-grade silicon to create silicon tetraiodide and impurity iodide byproducts in a cold-wall reactor chamber; (2) isolating silicon tetraiodide from the impurity iodide byproducts and purifying it by distillation in a distillation chamber; and (3) transferring the purified silicon tetraiodide back to the cold-wall reactor chamber, reacting it with additional iodine and metallurgical-grade silicon to produce silicon diiodide and depositing the silicon diiodide onto a substrate within the cold-wall reactor chamber. The two chambers are at atmospheric pressure and the system is open to allow the introduction of additional source material and to remove and replace finished substrates.Type: GrantFiled: September 13, 2002Date of Patent: March 30, 2004Assignee: Midwest Research InstituteInventors: Tihu Wang, Theodore F. Ciszek
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Patent number: 6689330Abstract: Apparatus suitable for the conversion of synthesis gas to liquid hydrocarbon products, comprising a plurality of injector-mixing nozzles, a tank reactor, a gas recycle line having a first end and a second end and a slurry recycle line having a first end and a second end. The plurality of injector-mixing nozzles is arranged at or near the top of the tank reactor, each injector mixing nozzle having a first inlet for a suspension of a catalyst in a liquid medium, at least one second inlet for synthesis gas and an outlet positioned within the tank reactor for discharging a mixture of synthesis gas and the suspension from the injector-mixing nozzles in a downwards direction into the tank reactor. The tank reactor has a first outlet for discharging a product suspension at or near the bottom thereof and a second outlet for a gaseous recycle stream at or near the top thereof.Type: GrantFiled: June 18, 2003Date of Patent: February 10, 2004Assignee: BP Exploration Operating Company LimitedInventors: Graham Walter Ketley, Barry Nay, David Newton